WO2018076524A1

WO2018076524A1 - Preparation method for laminated structure of photovoltaic assembly, laminated structure, and photovoltaic assembly

Info

Publication number: WO2018076524A1
Application number: PCT/CN2016/112545
Authority: WO
Inventors: 施正荣; 龙国柱; 刘皎彦; 练成荣; 王伟力
Original assignee: 上迈（香港）有限公司
Priority date: 2016-10-31
Filing date: 2016-12-28
Publication date: 2018-05-03
Also published as: CN108376717B; CN108376717A

Abstract

A preparation method for a laminated structure of a photovoltaic assembly, the laminated structure and the photovoltaic assembly, which are prepared by using a lamination process. The lamination process comprises a first heating stage, a second heating stage, and a third pressurization and cooling stage. In the first stage, the heating temperature range is from 110ºC to 130ºC, and the heating time range is from 100 seconds to 600 seconds; in the second stage, the hating temperature range is from 131ºC to 200ºC, and the heating time range is from 100 seconds to 1200 seconds; and in the third stage, the cooling temperature range is from 25ºC to 60ºC, and the pressurization range is from 0.05 Mpa to 0.25 Mpa. The lamination process is implemented in a low-temperature environment, power consumption is reduced, and the flatness of the laminated structure of the photovoltaic assembly is ensured, thereby further facilitating the mounting, enforcement and application of the photovoltaic assembly.

Description

Method for preparing photovoltaic module laminated structure and laminated structure, photovoltaic module

[0001] The present invention relates to the field of photovoltaics, and in particular to a method for preparing a photovoltaic module laminate structure, and to a photovoltaic module assembly structure and a photovoltaic module.

Background technique

[0002] In the current society, energy contradictions and environmental problems are becoming more and more prominent, and the development of various types of clean energy is an inevitable trend. In recent years, the photovoltaic industry has developed rapidly and the technology update has been gradually accelerated. At present, the photovoltaic industry is diversifying into products. The research on various functional components with high reliability, high power and low installation cost has become a direction for the development of photovoltaic modules. .

[0003] Solar photovoltaic power generation relies on solar cells to directly convert light energy into electrical energy. In the past decade, the total global production of photovoltaic cells has increased at an average annual growth rate of more than 40%. By the end of 2012, the installed capacity of photovoltaic systems worldwide has reached 100 GW. Photovoltaic power generation is expected to account for 10% of the world's energy supply by 2030, making a substantial contribution to the world's energy supply and energy mix.

[0004] As a packaging material used in the field of photovoltaics, it is required to have anti-UV, anti-aging and other properties, as shown in Figure 1, the existing typical photovoltaic module laminate structure (also commonly referred to as laminate) is by The ultra-white tempered embossed glass 21, the first EVA film 22, the solar cell string 23, the second EVA film 24, and the back sheet 25 are laminated and laminated, wherein: the ultra-white tempered embossed glass has a density of 2.5 g/ Cm 3

The common thickness is 3.2mm, so the tempered glass glass has a weight of up to 8Kg per square meter, and the photovoltaic module assembled from the photovoltaic module laminate structure is generally of high quality, and the weight thereof is more than 10Kg per square meter, the photovoltaic module Then, the supporting structure is installed, and the weight of the photovoltaic module is at least 12Kg per square meter. When it is applied to the top of the building or the wall surface, the support structure of the photovoltaic module is put forward, which increases the difficulty of construction and The cost of installation is as follows: In the process of installing the top of the building or the wall, there is heavy weight, the installation is labor intensive, and the implementation is difficult; especially in some cases, due to the limitation of the load bearing capacity of the building, the photovoltaic module cannot be installed. At the same time, the existing photovoltaic module package structure has a single appearance, which is not easy to change to meet the requirements of different architectural aesthetics.

[0005] At present, some technical solutions propose to solve the problem of lightweighting photovoltaic modules by changing packaging materials. That is, the high-transparent film and the transparent back plate are used instead of the tempered glass. However, in practical applications, since these high-transparent films and transparent back plates are mostly only made of EVA, POE, etc., the packaged photovoltaic modules are Anti-shock, fireproof and other performance can not meet the technical standards of the photovoltaic industry.

[0006] There are also some technical solutions for reducing the weight of photovoltaic modules. For example, the Chinese invention patent of CN102516852A discloses a weather-resistant, high-heat-conducting coating and a heat-dissipating solar backsheet, but the coating is in production. A large amount of solvent is used in the process, which is very polluting to the environment and does not meet the green environmental standards. Another example is the Chinese invention patent of CN102610680A, which discloses a UV-curable weather-resistant coating solar cell backsheet, but the liquid coating process used is complicated, the defect rate is high, and the equipment investment is large. Further, fluoropolymers are used in a series of Chinese invention patents such as CN102712184A, CN103346182A, CN102969382B, CN101290950B, CN103958196A, etc., but the fluoropolymer is expensive and increases the production cost, and the above patents It is only a material for photovoltaic backsheets, which is opaque, low in hardness and weak in rigidity, and is not suitable for replacing existing tempered glass.

[0007] The closest prior art to the present invention is the Chinese patent issued under the number CN105637653A, which discloses a photovoltaic panel and a method for manufacturing the same, specifically based on an epoxy group-containing group. The acrylate and glass fiber reinforced plastic is used as a packaging material for the surface of the solar cell string and the backlight surface. Although the method solves the problem of heavy weight of the photovoltaic module laminate structure packaging material, all of them adopt the price. As an encapsulating material, expensive acrylate is not only costly, but also causes a single color of the photovoltaic module. The technology also has a high lamination temperature during lamination, high energy consumption, and the resulting laminated structure of the photovoltaic module is curved and has a certain The curvature and unevenness are not conducive to the installation and implementation of the PV modules, and the appearance is beautiful.

[0008] Therefore, there is an urgent need to find a method to solve the problems of heavy weight, high cost, complicated lamination process and poor lamination effect of the existing packaging materials in the laminated structure of the photovoltaic module, and satisfy the anti-UV and anti-UV resistance. Requirements for photovoltaic industry technical standards such as aging, impact resistance, fire protection, and insulation.

technical problem

[0009] In view of the above, an object of the present invention is to provide a method for preparing a laminated structure of a photovoltaic module, which realizes a lamination process in a low temperature environment, reduces energy consumption, and ensures the laminated structure of the photovoltaic module. The flatness further facilitates the installation and implementation of photovoltaic modules.

[0010] Another object of the present invention is to provide a photovoltaic module laminate structure, which is not only low in cost but also satisfied Under the premise of anti-UV, anti-aging, anti-shock, fireproof, anti-insulation and other technical standards of the photovoltaic industry, it effectively solves the problem of reducing the weight of photovoltaic module packaging materials, improving the convenience of installation, reducing installation costs, and is very suitable for photovoltaics. Field scale promotion application.

Problem solution

Technical solution

[0011] Before introducing the technical solution of the present invention, it is necessary for the applicant to introduce the development of the technical solution of the present invention.

Based on years of accumulated expertise and extensive experiments in the field of photovoltaic packaging, the applicant's inventors have found that the packaging materials used in the laminated structure of photovoltaic modules need not only light weight, low cost, but also need to meet the requirements of anti-UV, anti-aging, Anti-shock, fire-proof and other technical standards for the photovoltaic industry, and the need to facilitate the installation of subsequent PV modules, while the Chinese patent No. CN105637653A discloses the use of epoxy-containing acrylates and is reinforced with glass fibers. Plastics are used as encapsulating materials, but the high cost of acrylates directly leads to an increase in the cost of photovoltaic modules, which is unacceptable in the photovoltaic industry; further, the lamination process of this patent uses lamination at 150-200 ° C and a certain pressure. The resulting photovoltaic module laminate structure is curved, has a certain curvature, and is uneven, which is not conducive to the installation and implementation of the photovoltaic module, and affects the appearance; and the patent uses the epoxy group-containing acrylate powder to be applied to the glass. On the fiber, in order to improve the connection between the two, only the tempering The powder is applied evenly applied and density are not guaranteed, which affect the encapsulation layer is UV, aging, impact, fire, insulation performance factors.

[0012] In order to solve the above technical problems, the present invention finally finds out that the packaging material as the surface layer needs to have good anti-UV, anti-aging, anti-impact properties, etc. as a backlight layer through a large number of experimental explorations and theoretical knowledge. The packaging materials need to have good impact resistance, fireproofing, anti-insulation and other properties, so as to meet the requirements of the technical standards of the photovoltaic industry, and the applicants have shown through experiments on different materials, conventional epoxy, polyurethane, epoxy / poly The ester mixing system could not meet the above requirements, and the cost of the fluorocarbon powder coating was also too high, and the applicant was surprised to find that when controlling the parameters of the super weather resistant polyester resin, the relevant parameters range (glass transition temperature and viscosity and hydroxyl value and The range of acid value 吋), the super weather resistant polyester obtained by cross-linking and curing as the encapsulating material of the surface layer and the backlight layer can meet the requirements of the technical standards of the photovoltaic industry. Of course, since the acrylic powder coating has good penetration Photonic, acrylic powder coating is still excellent as a packaging material for the face layer Materials, but also meet the requirements of the standard techniques; [0013] It is to be noted that, in particular, the Chinese patented method of CN105637653A does not specifically disclose the raw material weight ratio of the epoxy group-containing acrylate and glass fiber and the epoxy group-containing acrylate. In the density of glass fiber, the applicants found through extensive experiments that these technical contents are also the key factors to meet the strength of packaging materials and meet the technical standards of photovoltaic technology. If the weight of acrylate on glass fiber is too low, it can not meet the packaging technical requirements. However, if the weight is too high, the material cost will be high.

[0014] The technical solution adopted by the present invention is as follows:

[0015] A method for preparing a photovoltaic module laminate structure, the laminate structure comprising a first encapsulation layer, a solar cell string and a second encapsulation layer, wherein the first encapsulation layer comprises 30-50 parts by weight of fiber cloth And 50-70 parts by weight of the first packaged powder coating, the first packaged powder coating is uniformly coated on the fiber cloth; the second encapsulation layer is 30-50 parts by weight of fiber cloth And 50-70 parts by weight of the second packaged powder coating, the second packaged powder coating is uniformly coated on the fiber cloth;

[0016] The laminated structure of the photovoltaic module is prepared by a lamination process, wherein the laminating process includes a first heating stage, a second heating stage, and a third pressurized cooling stage, and the heating temperature range of the first stage For 110-130 ° C, the heating range is 100-600 seconds; the second stage heating temperature range is 131-200 ° C, the force enthalpy range is 100-1200 seconds; the third stage cooling temperature range The pressure range is from 0.05 to 0.25 MPa at 25-60 °C.

[0017] Preferably, the first encapsulated powder coating is an acrylic powder coating or a super weather resistant polyester powder coating, and the second packaged powder coating is an acrylic powder coating or a super weather resistant polyester powder coating; The powder coating comprises an acrylic resin and an acrylic resin curing agent, and the super weather resistant polyester powder coating comprises a super weather resistant polyester resin and a super weather resistant polyester resin curing agent; the fiber cloth is woven from a fiber material.

[0018] Preferably, the first encapsulated powder coating is an acrylic powder coating or a super weather resistant polyester powder coating, and the second encapsulated powder coating is a super weather resistant polyester powder coating; the acrylic powder coating comprises acrylic The resin and the acrylic resin curing agent, the super weather resistant polyester powder coating comprises a super weather resistant polyester resin and a super weather resistant polyester resin curing agent; the fiber cloth is woven from a fiber material.

[0019] Preferably, the method for preparing the first encapsulation layer and the second encapsulation layer comprises the following steps:

[0020] a) uniformly coating the first packaged powder coating or the second packaged powder coating through a coating device Covered on the fiber cloth;

[0021] b) thermally bonding the first packaged powder coating or the second packaged powder coating to the fiber cloth by pressure heating;

[0022] c), the above step b) finish the thermally bonded powder coating and the fiber cloth is cut in sections;

[0023] d), obtaining the first encapsulation layer or the second encapsulation layer; wherein, the thermal bonding process has a pressurization range of 0.05-0.25 MPa, and the thermal bonding process has a heating temperature range of 90 -130 ° C, the heating range is 5-20 seconds.

[0024] Preferably, the acrylic resin curing agent parts by weight is 5.25% by weight of the acrylic powder coating, and the curing agent is blocked isocyanate, phthalic anhydride, trimellitic anhydride, bismuth Acid, undecanedioic acid, dodecanedioic acid, tridecanedioic acid, tetradecanedioic acid, pentadecanedioic acid, hexadecandioic acid, carboxylated polyester, hydrogenated epoxy, GMA acrylic acid Any combination of one or several of any ratio.

[0025] Preferably, the acrylic powder coating further comprises an auxiliary agent, wherein the auxiliary component is 5-50% by weight of the acrylic powder coating, and the auxiliary agent is a polyamide wax and a poly Olefin wax, amide modified phenol urea surfactant, benzoin, polydimethylsiloxane, vinyltrichlorosilane, n-butyltriethoxysilane, methyl orthosilicate, monoalkoxy coke Phosphate ester, acrylate resin, phenolic resin, urea resin, melamine formaldehyde resin, distearyl ethylenediamine, a mixture of ethylene oxide and propylene oxide, hindered phenol, thiodipropionate, benzophenone Any one or a mixture of any of a ratio of a salicylate derivative, a hindered amine, an alumina, a fumed silica, and a silica.

[0026] Preferably, the super weather resistant polyester resin is a hydroxyl super weather resistant polyester resin or a carboxyl super weather resistant polyester resin, and has a glass transition temperature ranging from 50 to 75 ° C and a viscosity ranging from 15 to 200 Pa, s. The hydroxyl super weather resistant polyester resin has a hydroxyl value ranging from 30 to 300 mgKOH/g, and the carboxyl super weather resistant polyester resin has an acid value ranging from 15 to 85 mgKOH/g.

[0027] Preferably, the super weather resistant polyester powder coating further comprises an auxiliary agent, wherein the auxiliary component comprises 3-40% by weight of the super weather resistant polyester powder coating, and the auxiliary agent Is a polyamide wax, a polyolefin wax, an amide-modified phenol urea surfactant, benzoin, polydimethylsiloxane, vinyltrichlorosilane, n-butyltriethoxysilane, methyl orthosilicate , monoalkoxy pyrophosphate, acrylate, phenolic resin, urea formaldehyde resin, melamine formaldehyde resin, distearyl ethylenediamine, a mixture of ethylene oxide and propylene oxide, hindered phenol, thiodipropionic acid Diester, benzophenone, salicylate derivative, hindered amine, alumina, gas phase Any one or more of any of silicon dioxide, tetrabromobisphenol octadecyl, decabromodiphenylethane, tricresyl phosphate, aluminum hydroxide, magnesium hydroxide, barium sulfate, titanium dioxide, and carbon black. mixing.

[0028] Preferably, a laminated structure of a photovoltaic module, wherein the laminated structure is obtained by the preparation method as described above.

[0029] Preferably, in order to further enhance the weather resistance, the laminate structure comprises a fluoroplastic film layer, and the fluoroplastic film layer is located above the first encapsulation layer.

[0030] Preferably, in order to provide tough protection for the solar cell string, the laminate structure comprises an encapsulation film layer, and the encapsulation film layer may be separately disposed on the first encapsulation layer and the solar energy Between the battery strings or between the solar cell string and the second encapsulation layer, the solar cell strings and the solar cell strings may be disposed between the first encapsulation layer and the solar cell string. Between the second encapsulation layer and the second encapsulation layer. Further preferably, the encapsulating film layer of the present patent may be made of EVA, POE or PVB materials. Of course, those skilled in the art may also use other suitable encapsulating film materials.

[0031] It should be noted that the EVA appearing in this patent text refers to an ethylene-vinyl acetate copolymer, which is obtained by copolymerization of ethylene (E) and vinyl acetate (VA). The English name is: Ethylene Vinyl Acetate, abbreviation It is EVA; the POE appearing in this patent text refers to a polyolefin elastomer, the English name is Polyolefi n Elastomer, abbreviated as POE; the PVB appearing in this patent text refers to polyvinyl butyral, the English name is Poly vinyl Butyral, Referred to as PVB.

[0032] Preferably, in order to increase the insulation performance of the photovoltaic module and reduce the water vapor transmission, the laminated structure comprises a backing layer, and the backing layer is located below the second encapsulating layer.

[0033] Preferably, a photovoltaic module comprising a laminate structure, a connector and a junction box, the electrical connection of the laminate structure to the junction box is achieved by a connector, wherein the photovoltaic component comprises a photovoltaic component as described above Laminated structure.

[0034] Preferably, the connector comprises a crimping terminal and a heat shrinkable sleeve, and a cable card located at two ends of the connector is connected to the crimping terminal, and the heat shrinkable sleeve surrounds the pressure Connect the terminal.

Advantageous effects of the invention

Beneficial effect

[0035] The present invention proposes a lamination process of a photovoltaic module laminate structure, specifically setting the lamination process to the first heating a stage, a second heating stage and a third pressurized cooling stage, wherein the first heating stage is arranged such that the first packaged powder coating and the second packaged powder coating have sufficient inter-turn melting, leveling, and sufficient removal of bubbles, The arrangement of the two heating stages allows the first packaged powder coating and the second packaged powder coating to be fully crosslinked and cured, while the critical third pressurized cooling stage balances the cooling rate and shrinkage of the different materials in the photovoltaic module laminate structure. In order to obtain a flat component, the lamination process in a low temperature environment is finally realized, the energy consumption is reduced, and the flatness of the laminated structure of the photovoltaic module is ensured, and the installation of the photovoltaic module is further facilitated under the aesthetic appearance. application.

[0036] The present invention further proposes to use 30-50 parts by weight of fiber cloth and 50-70 parts by weight of acrylic powder coating or super weather resistant polyester powder coating uniformly coated on the fiber cloth as the first encapsulating layer material of the photovoltaic module. 30-50 parts by weight of fiber cloth and 50-70 parts by weight of super weather resistant polyester powder coating uniformly coated on the fiber cloth as the first encapsulating layer material of the photovoltaic module, when the super weather resistant polyester resin controls the glass The temperature and viscosity, as well as the range of hydroxyl value and acid value 吋, the super weather-resistant polyester obtained after cross-linking and curing is coated on the fiber cloth and can be used as a packaging material for the surface layer and the backlight layer to meet the technical standards of the photovoltaic industry. The requirement is that, because the cost of the super weather resistant polyester powder coating is much lower than the cost of the acrylic powder coating, and the present invention adopts a powder coating and a fiber cloth in a suitable weight ratio range, and uniformly coating, thereby satisfying the anti-UV and anti-aging. Under the premise of technical standards for photovoltaic industry such as impact resistance, fire prevention and anti-insulation, it has effectively solved the solution of photovoltaic module packaging materials. Lightweight and low in manufacturing cost, it replaces the traditional packaged structure of tempered glass to provide a certain rigidity to the photovoltaic module to protect the photovoltaic cell. Thus, not only can the weight of the photovoltaic module be greatly reduced, thereby adapting to more occasions of photovoltaic power generation products. The installation also reduces the labor intensity of the product installation and the ease of installation, thereby reducing the installation cost of the photovoltaic module as a whole.

[0037] After extensive experimentation, the present invention further proposes that the super weather resistant polyester resin is a hydroxyl super weather resistant polyester resin or a carboxyl super weather resistant polyester resin, and the glass transition temperature range is controlled at 50-75 ° C, and the viscosity range is controlled at 1 5-200Pa-s; When using hydroxyl super weather resistant polyester resin, its hydroxyl value range should be controlled at 30-300mgKOH/g. When using carboxyl super weather resistant polyester resin, its acid value range should be controlled at 15-85mgKOH. /g, this can effectively ensure the performance of super weather resistant polyester powder coating in anti-UV, anti-aging, impact resistance, fireproof, anti-insulation, etc., the cost of the same material is much lower than the cost of acrylic resin.

[0038] The present invention also uniformly coats the first packaged powder coating or the second packaged powder coating by a coating device. On the fiber cloth, the use of the coating device can ensure the uniform coating effect of the first packaged powder coating or the second packaged powder coating on the fiber cloth, and then the first package powder coating or the second package powder coating is heated by pressure heating. The fiber cloth is pre-bonded, and finally cut into a first package layer and a second package layer of a suitable size of the photovoltaic module, so that any change in the package size of the photovoltaic module laminate structure can be realized to adapt to the installation of different buildings. Requirements, further facilitating the installation and application of photovoltaic modules.

Brief description of the drawing

DRAWINGS

1 is a schematic view showing a laminated structure of a typical photovoltaic module of the prior art;

2 is a schematic view showing a laminated structure of a photovoltaic module according to Embodiment 1 of the present invention;

3 is a schematic view showing a laminated structure of a photovoltaic module according to Embodiment 2 of the present invention;

4 is a schematic view showing a laminated structure of a photovoltaic module according to Embodiment 3 of the present invention;

5 is a schematic view showing a laminated structure of a 4-volt module of an embodiment of the present invention;

6 is a schematic view showing a laminated structure of a photovoltaic module according to Embodiment 5 of the present invention;

7 is a schematic view showing a laminated structure of a photovoltaic module according to Embodiment 6 of the present invention;

8 is a schematic view showing a laminated structure of a photovoltaic module according to Embodiment 7 of the present invention;

9 is a schematic view showing a laminated structure of a photovoltaic module according to Embodiment 8 of the present invention;

10 is a schematic structural view of a preparation device for a first package layer and a second package layer for a photovoltaic module according to an embodiment of the present invention;

11 is a schematic view showing a structural arrangement of a lamination process of a laminate structure of the photovoltaic module shown in FIG. 8;

12 is a schematic structural view of a connector of a photovoltaic module according to an embodiment of the present invention.

Embodiments of the invention

[0051] Embodiments of the present invention disclose a method of fabricating a photovoltaic module laminate structure, the laminate structure including a first encapsulation layer, a solar cell string, and a second encapsulation layer, the first encapsulation layer comprising 30-50 parts by weight of fibers The cloth and 50-70 parts by weight of the first packaged powder coating are prepared, the first packaged powder coating is uniformly coated on the fiber cloth; the second encapsulation layer is composed of 30-50 parts by weight of the fiber cloth and 50-70 parts by weight of the second The packaged powder coating is prepared, and the second packaged powder coating is uniformly coated on the fiber cloth; the laminated structure of the photovoltaic module is prepared by a lamination process, wherein the laminating process includes a first heating stage and a second heating stage And a third pressurized cooling step The heating temperature range of the first stage is 110-130 ° C, the heating range is 100-600 seconds; the heating temperature range of the second stage is 131-200 ° C, and the heating range is 100-1200 seconds; The third stage has a cooling temperature range of 25-60 ° C and an applied pressure range of 0.05-0.25 MPa.

[0052] Embodiments of the present invention provide a lamination process of a photovoltaic module laminate structure, specifically, the lamination process is set to a first heating phase, a second heating phase, and a third pressurized cooling phase, wherein the first heating phase The arrangement is such that the first packaged powder coating and the second packaged powder coating have sufficient daytime melting and leveling to fully remove the bubbles, and the second heating stage is set such that the first packaged powder coating and the second packaged powder coating are fully crosslinked. And curing, while the critical third pressurized cooling stage balances the cooling rate and shrinkage of the different materials in the photovoltaic module laminate structure to obtain a flat component, ultimately achieving a lamination process in a low temperature environment, reducing energy The consumption and the same ensure the flatness of the laminated structure of the photovoltaic module, and further facilitate the installation and application of the photovoltaic component under the appearance aesthetics.

[0053] Embodiments of the present invention also disclose a laminate structure of a photovoltaic module obtained by the above-described preparation method.

[0054] Embodiments of the present invention also disclose a photovoltaic module including a laminate structure, a connector and a junction box, and electrical connection of the laminate structure to the junction box through the connector, wherein the photovoltaic module includes the above The laminated structure of the photovoltaic module uses a standard rapid electrical connection joint with respect to the conventional photovoltaic module of the prior art, which is costly, and the connected machine structure of the embodiment of the invention can make the electrical connection reliable and low in cost.

[0055] In order to more clearly illustrate the embodiments of the present invention or the technical solutions in the prior art, the drawings to be used in the embodiments or the prior art description will be briefly described below, and obviously, in the following description The drawings are only some of the embodiments described in the present invention, and those skilled in the art can obtain other drawings based on these drawings without any creative work.

Embodiment 1:

[0057] Referring to FIG. 2, a laminated structure of a photovoltaic module, the laminated structure includes a first encapsulation layer la, a solar cell string 13a, and a second encapsulation layer 14a, wherein

[0058] Preferably, in order to further enhance the weather resistance, the laminate structure comprises a fluoroplastic film layer, and the fluoroplastic film layer is located above the first encapsulation layer. Preferably, in order to provide tough protection for the solar cell string, the laminate structure comprises an encapsulation film layer, and the encapsulation film layer may be separately disposed on the first encapsulation layer and the solar cell string Between the solar cell string and the second encapsulation layer, it may also be disposed between the first encapsulation layer and the solar cell string and between the solar cell string and the second encapsulation layer. Further preferably, the encapsulating film layer involved in the patent may be made of EVA, POE or PVB materials. Of course, other suitable encapsulating film materials may be used by those skilled in the art. Preferably, in order to increase the insulating properties of the photovoltaic module and reduce water vapor transmission, the laminate structure comprises a backing layer, the backing layer being located below the second encapsulating layer.

Therefore, in combination with the above content, those skilled in the art can select a specific laminated structure of the photovoltaic module according to actual needs, and of course, other types of material layers can also be disposed, as long as the core technical features of the present invention are adopted. All are within the scope of protection of the present invention. The following examples of the invention are merely illustrative of embodiments of laminated structures of some preferred photovoltaic modules.

Specifically, in the present embodiment, as shown in FIG. 2, the laminated structure further includes a first encapsulation film layer 12a, and the first encapsulation film layer 12a is located on the first encapsulation layer 11a and the solar cell string. Between 13a. Further preferably, the first encapsulating film layer 12a is made of an EVA material.

[0061] The first encapsulating layer is prepared by 30-50 parts by weight of fiber cloth and 50-70 parts by weight of the first encapsulating powder coating, the first encapsulating powder coating is uniformly coated on the fiber cloth; the second encapsulating layer is 30 - 50 parts by weight of fiber cloth and 50 - 70 parts by weight of the second packaged powder coating, the second packaged powder coating is uniformly coated on the fiber cloth, and it is more preferably obtained by a large number of experimental results, the first encapsulation layer Prepared from 35-45 parts by weight of fiber cloth and 55-65 parts by weight of the first packaged powder coating, and the second encapsulating layer is prepared by 35-45 parts by weight of fiber cloth and 55-65 parts by weight of the second package powder coating. Specifically, in the present embodiment, the first encapsulating layer is prepared by using 30 parts by weight of the fiber cloth and 70 parts by weight of the first encapsulating powder coating, and the second encapsulating layer is composed of 50 parts by weight of the fiber cloth and 50 parts by weight of the second encapsulating powder. Preparation of paint;

[0062] wherein the fiber cloth is woven from a fiber material, preferably, in the embodiment of the present invention, the fiber cloth is made of any one of a plain weave, a twill weave, a rib, a rib, or a mat. The combination of several kinds of weaving methods is made. Specifically, in the embodiment, the fiber cloth is made of a fiber material by a plain weaving method. Of course, those skilled in the art can select other well-known weaving methods according to actual needs;

[0063] Preferably, in the embodiment of the present invention, the fiber cloth has a basis weight ranging from 30 to 400 g/m 2 , and the weight of the fiber cloth is ensured under the strength of the fiber cloth, specifically, in the embodiment. Medium fiber cloth The weight per unit area is 100 g/m 2 ; preferably, the first packaged powder coating and the second packaged powder coating are coated on the fiber cloth in a weight range of 70-400 g/m 2 , specifically, in the present In an embodiment, the first packaged powder coating has a basis weight of 233 g/m 2 coated on the fiber cloth, and the second packaged powder coating has a basis weight of 100 g/m 2 coated on the fiber cloth;

[0064] Preferably, in the embodiment of the present invention, the fiber material is any one or a combination of glass fiber, carbon fiber and aramid fiber to ensure good insulation and weather resistance of the fiber cloth, and is compatible with photovoltaic Relevant standard requirements, and most preferably, in the present embodiment, the fiber material is glass fiber. Of course, those skilled in the art can select other types of fiber materials according to actual needs, and the embodiments of the present invention are no longer displayed one by one. Description

[0065] Preferably, in the embodiment of the present invention, the diameter of the filament of the fiber material ranges from 3 to 23 μm, and specifically, in the embodiment, the diameter of the filament of the fiber material is 5 μm, which facilitates the weaving of the fiber material, and Easily obtain the required basis weight of the fiber cloth;

[0066] The first encapsulated powder coating is an acrylic powder coating or a super weather resistant polyester powder coating. Specifically, in the embodiment, the first packaged powder coating is an acrylic powder coating, and the acrylic powder coating comprises an acrylic resin and an acrylic curing agent. Preferably, in the embodiment of the present invention, the acrylic resin has a refractive index ranging from 1.40 to 1.50, an epoxy equivalent ranging from 300 to 800 g/eq, a hydroxyl value ranging from 15 to 70 mgKOH/g, and an acid value ranging from 15 to 85 mgKOH/ g, glass transition temperature range of 40-70 ° C, viscosity range of 75-600Pa, s, softening point temperature range of 100-120 ° C, to ensure good insulation and weather resistance of acrylic resin, in line with PV related standards Further, particularly preferably, in the embodiment of the present invention, the acrylic resin is any one of a hydroxy acrylic resin and a carboxy acrylic resin, or a combination of two arbitrary ratios, because the hydroxy acrylic resin is excellent in impact resistance. GMA (glycidyl methacrylate) acrylic resin, and carboxy acrylic resin has excellent yellowing resistance to G MA (glycidyl methacrylate) acrylic resin, as a less preferred embodiment, GMA (glycidyl methacrylate) acrylic resin or bifunctional acrylic resin may be used. Specifically, in the present embodiment, acrylic acid The resin is a hydroxy acrylic resin. Of course, those skilled in the art can select other types of acrylic resin according to actual needs, and the embodiment of the present invention is no longer an example.

[0067] Preferably, in the embodiment of the present invention, the acrylic resin curing agent is 5-25% by weight of the acrylic powder coating, and the acrylic curing agent is blocked isocyanate, phthalic anhydride, trimellitic anhydride. , azelaic acid, undecanedioic acid, dodecanedioic acid, tridecanedioic acid, tetradecanedioic acid, pentadecanedioic acid, hexadecandioic acid, carboxylated polyester, hydrogenated epoxy, GMA Any one or a mixture of any of the acrylic acids, specifically, in the embodiment, the acrylic resin curing agent is phthalic anhydride, and the phthalic anhydride accounts for 10% by weight of the acrylic powder coating. Of course, those skilled in the art can select other types of acrylic curing agents according to the type and actual conditions of the acrylic resin and cure the acrylic resin in the range of 5-25% by weight (including the end values of 5% and 25%). The same technical effect can be obtained in the same manner. In the embodiment of the present invention, the preferred acrylic resin curing agent has a weight ratio ranging from 10 to 20%, and the cross-linking curing effect is better, and the embodiments of the present invention are no longer displayed one by one. Description

Preferably, in the embodiment, the acrylic powder coating further comprises a certain amount by weight of the auxiliary agent, preferably, the auxiliary part by weight is 5-50% by weight of the acrylic powder coating, more preferably, The auxiliary part by weight is 10-40% by weight of the acrylic powder coating, and most preferably, the auxiliary part by weight is 15-25% by weight of the acrylic powder coating, which is used for further improving the acrylic powder coating. Transparency, weather resistance, insulation and flame retardancy, wherein the additives are polyamide wax, polyolefin wax, amide modified phenol urea surfactant, benzoin, polydimethylsiloxane, vinyl three Chlorosilane, n-butyltriethoxysilane, methyl orthosilicate, monoalkoxy pyrophosphate, acrylate, phenolic resin, urea formaldehyde resin, melamine formaldehyde resin, distearyl ethylenediamine, epoxy Mixture of ethane and propylene oxide, hindered phenol, thiodipropionate, benzophenone, salicylate derivative, hindered amine, alumina, fumed silica, silica Or several Any ratio of mixing, among them, polyamide wax, polyolefin wax, amide modified phenol urea surfactant, benzoin, polydimethylsiloxane, vinyltrichlorosilane, n-butyltriethoxy Silane, methyl orthosilicate, monoalkoxy pyrophosphate, acrylate, phenolic resin, urea formaldehyde resin, melamine formaldehyde resin, distearyl ethylenediamine, a mixture of ethylene oxide and propylene oxide, blocked Phenol, thiodipropionic acid diester, benzophenone, salicylate derivative, hindered amine are preferred additives, and can significantly improve the weather resistance, insulation and flame retardancy of the acrylic powder coating. Preferably, In the present embodiment, the auxiliary part by weight is 18.8% by weight of the acrylic powder coating, and the auxiliary agent is a polyamide wax, an amide-modified phenol urea surfactant, benzoin, alumina and silica. mixture. Of course, the present invention only lists the preferred types of auxiliaries. In other embodiments, those skilled in the art may select other types of auxiliaries according to actual needs, which are not specifically described in the embodiments of the present invention; further preferably, Embodiments of the present invention may also be based on actual needs of photovoltaic component installation. Adding pigments and fillers as additives to adjust the color of acrylic powder coatings further facilitates the practical installation of photovoltaic modules. Specifically, additives can be used as pigments in blue or yellow or yellow The pigment and filler, of course, can also be adjusted by color or special hue with mixed color pigments.

[0069] The second encapsulated powder coating is a super weather resistant polyester powder coating, and the super weather resistant polyester powder coating comprises a super weather resistant polyester resin and a super weather resistant polyester resin curing agent; preferably, in the embodiment of the invention, the super weather resistant polymerization The ester resin is a mixture of one or two of a hydroxyl super weather resistant polyester resin or a carboxyl super weather resistant polyester resin to ensure that the super weather resistant polyester resin has good insulation and weather resistance, and meets the requirements of photovoltaic related standards. In the present embodiment, the super weather resistant polyester resin is a hydroxyl super weather resistant polyester resin;

[0070] Preferably, in the embodiment of the present invention, the hydroxyl super weather resistant polyester resin has a hydroxyl value ranging from 30 to 300 mg KO H/g, a glass transition temperature ranging from 50 to 75 ° C, and a viscosity ranging from 15 to 200 Pa. s, the implementation of other parameter ranges is not effective, and can not meet the requirements of photovoltaic technology standards. Specifically, in the present embodiment, the hydroxyl value of the hydroxyl super weather resistant polyester resin is 100 mgKOH/g, the glass transition temperature is 60 ° C, and the viscosity 80 Pa, s _; further preferably, in the embodiment of the present invention, the hydroxy super weather resistant polyester resin is a mixture of one or more monomers of neopentyl glycol, adipic acid, and ethylene glycol. Certainly, those skilled in the art can select other types of monomers to polymerize to obtain a hydroxyl super weather resistant polyester resin according to actual needs, and the embodiment of the present invention is no longer an example. Specifically, in the present embodiment, the hydroxyl group The super weather resistant polyester resin is polymerized from adipic acid monomer;

[0071] Preferably, in the embodiment of the present invention, the weight of the super weather resistant polyester resin curing agent accounts for 2-20% by weight of the super weather resistant polyester powder coating, and the super weather resistant polyester resin curing agent is isocyanuric acid three. a mixture of any one or a combination of glycidyl ester, trimellitic acid triglycidyl ester, diglycidyl terephthalate, glycidyl methacrylate, hydroxyalkylamide, isocyanate, In the present embodiment, the super weather resistant polyester resin curing agent is triglycidyl isocyanurate, and the triglycidyl isocyanurate accounts for 5% by weight of the hydroxyl super weather resistant polyester powder coating. Those skilled in the art can select other types of super weather resistant polyester resin curing agents according to the type and actual condition of the super weather resistant polyester resin and in the range of 2-20% by weight (including end points of 2% and 20%). The super weather-resistant polyester resin curing agent can also achieve substantially the same technical effect. In the embodiment of the present invention, the preferred super weather resistant polyester resin curing agent has a weight ratio ranging from 5-15%, and the cross-linking curing effect is better. Inventive Example not going to be described show Jian [0072] Preferably, in the embodiment, the super weather resistant polyester powder coating provided by the embodiment of the present invention further adds a certain amount of auxiliary agent, and preferably, the auxiliary weight portion accounts for the super weather resistant polymerization. 3-40% by weight of the ester powder coating is used to further improve the insulation and weather resistance of the super weather resistant polyester powder coating. The same can also be used to adjust the super weather resistant polyester powder by adding additives according to the actual requirements of the installation of the photovoltaic module. The color of the coating further facilitates the practical installation of the photovoltaic module. Specifically, in the practice of the present invention, the auxiliary agent is a polyamide wax, a polyolefin wax, an amide-modified phenol urea surfactant, a benzoin, a polydimethyl group. Silicone, vinyltrichlorosilane, n-butyltriethoxysilane, methyl orthosilicate, monoalkoxy pyrophosphate, acrylate, phenolic resin, urea formaldehyde resin, melamine formaldehyde resin, distearyl Acetylenediamine, a mixture of ethylene oxide and propylene oxide, hindered phenol, thiodipropionate, benzophenone, salicylate derivative, hindered amine, alumina, gas phase Any one or a mixture of any of a mixture of silicon oxide, tetrabromobisphenol octadecyl, decabromodiphenylethane, tricresyl phosphate, aluminum hydroxide, magnesium hydroxide, barium sulfate, titanium dioxide, and carbon black Among them, preferred auxiliaries are polyamide wax, polyolefin wax, amide modified phenol urea surfactant, benzoin, polydimethylsiloxane, vinyltrichlorosilane, n-butyltriethoxy Silane, methyl orthosilicate, monoalkoxy pyrophosphate, acrylate, phenolic resin, urea formaldehyde resin, melamine formaldehyde resin, distearyl ethylenediamine, a mixture of ethylene oxide and propylene oxide, blocked Mixing any one or several of the phenol, thiodipropionate, benzophenone, salicylate derivative, and hindered amine, of course, those skilled in the art can select other according to actual needs. The auxiliaries of the type are not specifically described in the embodiments of the present invention; similarly to the acrylic powder coating, it is further preferred that the embodiment of the invention can also be supplemented by adding the pigment filler according to the actual needs of the installation of the photovoltaic module. The agent is specially used to adjust the color of the super weather resistant polyester powder coating, and further facilitates the practical installation and application of the photovoltaic component. Specifically, the additive may be a pigmented filler in a blue hue or a pigmented filler in a red or yellow hue. Of course, it is also possible to adjust the color or the special hue by using a mixed color pigment filler.

The first packaged powder coating and the second packaged powder coating according to the embodiments of the present invention can be prepared by using a known preparation technique of any of the existing powder coatings, and the typical method can be premixing, melt extrusion, and grinding. Specifically, in the present embodiment, the acrylic resin or the hydroxyl super weather resistant polyester resin is premixed with the curing agent and the auxiliary agent. Preferably, the premixed crucible can be selected for 2-10 minutes. And then pre-mixing the mixture with a screw extruder and pressing into a sheet, preferably, extruding The length to diameter ratio of the machine can be selected between 15: 1-50: 1, the heating temperature of the extruder is selected between 80-120 ° C, the screw speed is selected at 200-800 rpm; finally, the sheet is pulverized into small pieces to enter The mill grinds into a powder coating of a certain particle size. Preferably, the rotational speed of the mill is selected from 50 to 150 rpm. Preferably, the particle size range of the first packaged powder coating and the second packaged powder coating is controlled at 35-300 μm. Between these, the preferred preparation process parameters are to ensure the particle size uniformity of the powder coating, and provide the basic conditions for the subsequent coating uniformity effect on the fiber cloth. Of course, other process parameters or powder coating preparation processes may also be used to prepare the first packaged powder coating or the second packaged powder coating, which is believed to be a routine choice of those skilled in the art, and thus, the first packaged powder coating or The preparation process of the second encapsulated powder coating is not described in detail herein.

In this embodiment, the method for preparing the first encapsulation layer and the second encapsulation layer as described above includes the following steps:

a), uniformly coating the first packaged powder coating or the second packaged powder coating on the fiber cloth by a coating device;

[0076] b) thermally bonding the first packaged powder coating or the second packaged powder coating to the fiber cloth by pressure heating;

[0077] c), step b) finishing the thermally bonded powder coating and the fiber cloth;

[0078] d) obtaining a first encapsulation layer or a second encapsulation layer;

[0079] It should be noted that, in the embodiment of the present invention, the thermal bonding process needs to adopt a suitable range of pressurization and heating control, because the first package powder coating or the first can only be made under the appropriate pressure and temperature conditions. A good hot-melt bonding process between the two-packaged powder coating and the fiber cloth ensures that the lamination process in the process of preparing the photovoltaic module package is ensured, thereby obtaining a packaging material that is truly applicable to the photovoltaic cell module package. Therefore, preferably, in the embodiment of the present invention, the press range of the thermal bonding process is 0.05-0.25 Mpa, the heating temperature range of the thermal bonding process is 90-130 ° C, and the heating range is 5-20 seconds. Specifically, in the present embodiment, the pressing pressure of the thermal bonding process is 0.05 MPa, the heating temperature of the thermal bonding process is 130 ° C, and the heating enthalpy range is 5 seconds.

[0080] Preferably, in the embodiment of the present invention, the method for preparing the first encapsulating layer and the second encapsulating layer as described above adopts the device shown in FIG. 10, and in actual implementation, the fiber cloth is put into the fiber into the fiber. In the hopper 51, the first packaged powder coating or the second packaged powder coating is uniformly applied to the fiber feeder 5 by the coating device 52. 1 of the output fiber cloth, and then heated by the hot melt laminator 53 to thermally bond the first packaged powder coating or the second packaged powder coating to the fiber cloth, and the first packaged powder coating or the thermally bonded first package powder coating or The second packaged powder coating and the fiber cloth are cut in sections to obtain a packaging material for the photovoltaic module, which is not only easy to operate but also achieves uniform coating. In other embodiments of the present invention, the coating device may also adopt a dusting head, and the coating device realizes the coating process in the form of dusting, thereby uniformly or uniformly coating the first package powder coating or the second package powder coating. Coated on a fiber cloth. Certainly, as a less preferred solution, those skilled in the art may also select any known device according to actual needs to complete the preparation of the first encapsulation layer and the second encapsulation layer disclosed in the present invention, as long as the implementation is The technical effect of uniformly coating the first encapsulated powder coating or the second encapsulated powder coating on the fiber cloth is sufficient.

[0081] Preferably, in the present embodiment, for example, a method for preparing a laminated structure of a photovoltaic module, the laminated structure of the photovoltaic module is prepared by a lamination process, wherein the laminating process includes a first heating stage, a second heating stage, and In the third pressurized cooling stage, the heating temperature range of the first stage is 110-130 ° C, the heating range is 100-600 seconds; the heating temperature range of the second stage is 131-200 ° C, and the heating range is 100-1200 seconds; the third stage has a cooling temperature range of 25-60 ° C, an applied pressure range of 0.05-0.25 MPa, and more preferably, the first stage has a heating temperature range of 115-125 ° C. 300-500 seconds; the second stage heating temperature range is 140-180 ° C, the heating range is 400-1000 seconds; the third stage cooling temperature range is 40-50 ° C, the applied pressure range is 0.1- 0.2Mpa, specifically, in the present embodiment, the heating temperature in the first stage is 120 ° C, and the heating time is 400 seconds; the heating temperature in the second stage is 160 ° C, and the heating time is 700 seconds; The cooling temperature of the stage is 45 ° C, and the applied pressure is 0.15 MPa. _;

Preferably, the embodiment further provides a photovoltaic module, comprising a laminated structure, a connector and a junction box, the electrical connection of the laminated structure and the junction box is realized by a connector, wherein the photovoltaic component comprises the above The laminated structure of the photovoltaic module.

[0083] Preferably, referring to FIG. 12, in the embodiment, the connector includes a crimping terminal 72 and a heat shrinkable sleeve 73, and the cable wires 71, 74 at the two ends of the connector are inserted into the crimping terminal 72. The heat shrink sleeve 73 surrounds the crimp terminal 72 to make the electrical connection of the photovoltaic module laminate structure reliable and low in cost.

Example 2:

Referring to FIG. 3, in the second embodiment, the laminated structure includes a fluoroplastic film layer l lb, a first encapsulation layer 12b, a first EVA layer 13b, a solar cell string 14b, and a second encapsulation layer 15b. , fluoroplastic film layer l ib Located in the upper portion of the first encapsulation layer 12b, the remaining technical solutions of the second embodiment are the same as those of the first embodiment.

Example 3:

[0087] Referring to FIG. 4, in the third embodiment, the laminated structure includes a first encapsulation layer 11c, a first EVA layer 12c, a solar cell string 13c, a second encapsulation layer 14c, and a back sheet layer 15c. The backing layer 15c is located below the second encapsulating layer 14c. The remaining technical solutions of the third embodiment are the same as those of the first embodiment.

Example 4:

[0089] Referring to FIG. 5, in the fourth embodiment, the laminated structure includes a first encapsulation layer 111, a first EVA layer 12d, a solar cell string 13d, a second EVA layer 14d, and a second encapsulation layer. 15d, the second EVA layer 14d is located between the solar cell string 13d and the second encapsulation layer 15d. The remaining technical solutions of the fourth embodiment are the same as those of the first embodiment.

Example 5:

[0091] Referring to FIG. 6, in the fifth embodiment, the laminated structure includes a fluoroplastic film layer l le, a first encapsulation layer 12e, a first EVA layer 13e, a solar cell string 14e, and a second EVA layer 15e. And the second encapsulation layer 16e, wherein the fluoroplastic film layer lie is located above the first encapsulation layer 12e, and the second EVA layer 15e is located between the solar cell string 14e and the second encapsulation layer 16e, and the remaining technology of the embodiment 5 The scheme is the same as that of the above embodiment 1.

Example 6:

Referring to FIG. 7, in the sixth embodiment, the laminated structure includes a first encapsulation layer 1 If, a first EVA layer 12f, a solar cell string 13f, a second EVA layer 14f, and a second encapsulation layer. 15f and the backing layer 16f, wherein the backing layer 16f is located below the second encapsulating layer 15f, and the second EVA layer 14f is located between the solar cell string 13f and the second encapsulating layer 15f, and the remaining technical solutions of the sixth embodiment The above embodiment 1 is the same.

Example 7:

Referring to FIG. 8 and FIG. 11, in the seventh embodiment, the laminated structure includes a fluoroplastic film layer l lg, a first encapsulation layer 12g, a first EVA layer 13g, a solar cell string 14g, and a second The EVA layer 15g, the second encapsulation layer 16g and the back sheet layer 17g, wherein the fluoroplastic film layer l lg is located above the first encapsulation layer 12g, the back sheet layer 17g is located below the second encapsulation layer 16g, and the second EVA layer 15g The remaining technical solution of the seventh embodiment is the same as that of the first embodiment described above, between the solar cell string 14g and the second encapsulation layer 16g.

Example 8: [0097] Referring to FIG. 9, in the eighth embodiment, the laminated structure includes a first encapsulation layer l lh, a solar cell string 12h, and a second encapsulation layer 13h, wherein the solar cell string 12h is located in the first encapsulation layer. Between l lh and the second encapsulation layer 13h, the remaining technical solutions of the eighth embodiment are the same as those of the first embodiment.

Example 9:

[0099] In the present embodiment 9, the first encapsulated powder coating is a super weather resistant polyester powder coating, and the super weather resistant polyester powder coating is the same as the super weatherable polyester powder coating used in the second packaged powder coating; During the process, the heating temperature in the first stage is 125 ° C, and the heating time is 350 seconds; the heating temperature in the second stage is 16 5 ° C, the heating time is 750 seconds; the cooling temperature in the third stage is 48 ° C, the applied pressure is 0.13 MPa _; the remaining technical solutions of the embodiment 9 and any one of the above embodiments 1 to 8.

Example 10:

[0101] In the present embodiment 10, the first encapsulating layer is prepared by using 35 parts by weight of fiber cloth and 65 parts by weight of acrylic powder coating, and the second encapsulating layer is composed of 30 parts by weight of fiber cloth and 70 parts by weight of super weather resistant polyester powder. The coating is prepared, wherein the acrylic resin is a carboxy acrylic resin, and the super weather resistant polyester resin is a carboxyl super weather resistant polyester resin, which is formed by polymerizing one or two monomers of terephthalic acid and isophthalic acid. The mixture, the carboxyl super weather resistant polyester resin has an acid value in the range of 15-85 mg KOH/g, a glass transition temperature in the range of 50-75 ° C, and a viscosity in the range of 15-200 Pa s. Specifically, in the present embodiment, the carboxyl group The super weather resistant polyester resin is polymerized from terephthalic acid monomer, and the carboxyl group super weather resistant polyester resin has an acid value of 85 mgKOH/g, a glass transition temperature of 75 ° C, and a viscosity of 200 Pa.s _; super weather resistant polyester resin The curing agent is triglycidyl trimellitate, and the weight fraction of trimellitic acid triglycidyl ester accounts for 8% by weight of the super weather resistant polyester powder coating;

[0102] During the lamination process, the heating temperature of the first stage is 115 ° C, and the heating time is 500 seconds; the heating temperature of the second stage is 180 ° C, and the heating time is 400 seconds; the third stage of cooling The temperature is 50 ° C, the applied pressure is 0.2 Mpa;

[0103] The remaining technical solutions of Embodiment 10 and any one of Embodiments 1 to 8 above.

Example 11:

[0105] In the present embodiment 11, the first encapsulating layer is prepared from 40 parts by weight of the fiber cloth and 60 parts by weight of the acrylic powder coating, and the second encapsulating layer is composed of 35 parts by weight of the fiber cloth and 65 parts by weight of the super weather resistant polyester powder. The coating is prepared, wherein the acrylic resin is a GMA acrylic resin, the acrylic resin curing agent is a blocked isocyanate, and the blocked isocyanate is 10% by weight of the acrylic powder coating; [0106] During the laminating process, the heating temperature of the first stage is 120 ° C, and the heating time is 400 seconds; the heating temperature of the second stage is 160 ° C, and the heating time is 700 seconds; the third stage of cooling The temperature is 45 ° C, the applied pressure is 0.15 Mpa;

[0107] The remaining technical solutions of Embodiment 11 and any one of Embodiments 1 to 8 above.

Example 12:

[0109] In the present embodiment, the first encapsulating layer is prepared from 45 parts by weight of fiber cloth and 55 parts by weight of super weather resistant polyester powder coating, and the second encapsulating layer is composed of 40 parts by weight of fiber cloth and 60 parts by weight of super weathering. Prepared from a polyester powder coating, wherein the super weather resistant polyester resin is a carboxyl super weather resistant polyester resin, which is polymerized from an isophthalic acid monomer, and has an acid value of 60 mgKOH/g and a glass transition temperature of 60 ° C. The viscosity is 100 Pa- _S;

[0110] During the lamination process, the heating temperature of the first stage is 110 ° C, and the heating time is 600 seconds; the heating temperature of the second stage is 180 ° C, and the heating time is 300 seconds; the third stage of cooling The temperature is 60 ° C, the applied pressure is 0.06 Mpa;

[0111] The remaining technical solutions of Embodiment 12 and any one of Embodiments 1 to 8 above.

Example 13:

[0113] In the present embodiment 13, the first encapsulating layer is prepared from 50 parts by weight of the fiber cloth and 50 parts by weight of the first encapsulating powder coating, and the second encapsulating layer is composed of 45 parts by weight of the fiber cloth and 65 parts by weight of the second package. The powder coating is prepared by using a hydroxyl super weather resistant resin and polymerized from a neopentyl glycol monomer. The hydroxyl super weather resistant resin has a hydroxyl value of 180 mgKOH/g and a glass transition temperature of 70 ° C. The viscosity is 120Pa-s. The first packaged powder coating also contains 16% by weight of the powder coating, the additive is a mixture of polyolefin wax and methyl orthosilicate, and the second package powder coating is made of carboxyl. super weather resin from terephthalic acid monomers, the acid value of the carboxyl resin is super weather 50mgKOH / g, a glass transition temperature of 5 5 ° C, a viscosity of 80 Pa. _S, the second powder coating package Also added is 13% by weight of the powder coating by weight of the auxiliary agent, the additive is a mixture of a polyolefin wax, an amide-modified phenol urea surfactant and a hindered phenol;

[0114] During the laminating process, the heating temperature of the first stage is 125 ° C, and the heating time is 200 seconds; the heating temperature of the second stage is 190 ° C, and the heating time is 150 seconds; the third stage of cooling The temperature is 60 ° C, the applied pressure is 0.05 Mpa;

[0115] The remaining technical solutions of Embodiment 13 and any one of Embodiments 1 to 7 above.

Example 14: [0117] In the present embodiment 14, the first encapsulating layer is prepared from 35 parts by weight of the fiber cloth and 65 parts by weight of the first encapsulating powder coating, and the second encapsulating layer is composed of 35 parts by weight of the fiber cloth and 65 parts by weight of the second package. The powder coating is prepared; the first packaged powder coating and the second packaged powder coating both adopt a hydroxyl super weather resistant resin;

[0118] During the laminating process, the heating temperature of the first stage is 120 ° C, and the heating time is 400 seconds; the heating temperature of the second stage is 160 ° C, and the heating time is 700 seconds; the third stage of cooling The temperature is 45 ° C, the applied pressure is 0.15 Mpa;

[0119] The remaining technical solutions of the embodiment 14 and any one of the first embodiment to the eighth embodiment.

Example 15:

[0121] In the present embodiment 15, the first encapsulating layer is prepared from 40 parts by weight of the fiber cloth and 60 parts by weight of the first encapsulating powder coating, and the second encapsulating layer is composed of 40 parts by weight of the fiber cloth and 60 parts by weight of the second package. The powder coating is prepared; the first packaged powder coating and the second packaged powder coating both adopt a carboxyl super weather resistant resin;

[0122] During the lamination process, the heating temperature of the first stage is 112 ° C, and the heating time is 180 seconds; the heating temperature of the second stage is 131 ° C, and the heating time is 1200 seconds; the third stage of cooling The temperature is 25 ° C, the applied pressure is 0.25 Mpa;

[0123] The remaining technical solutions of Embodiment 15 and any one of Embodiments 1 to 8 above.

Example 16:

[0125] In the present embodiment 16, during the laminating process, the heating temperature in the first stage is 125 ° C, and the heating time is 600 seconds; the heating temperature in the second stage is 155 ° C, and the heating time is 600. Second; the third stage cooling temperature is 40 ° C, the applied pressure is 0.18Mpa;

[0126] The remaining technical solutions of Embodiment 16 and any one of Embodiments 1 to 9 above.

Example 17:

[0128] The remaining technical solutions of the present embodiment 17 are the same as those of the foregoing embodiment 7, except that in the first embodiment, the first encapsulation layer and the second encapsulation layer are each composed of 35 parts by weight including fiber cloth and conventional commercialization. The epoxy powder coating was prepared in an amount of 65 parts by weight.

Example 18:

[0130] The remaining technical solutions of the embodiment 18 are the same as those of the above-described embodiment 7, except that in the embodiment 18, the encapsulating material includes 25 parts of the fiber cloth and 75 parts of the powder coating.

Example 19: [0132] The remaining technical solutions of the present embodiment 19 are the same as those of the above-described embodiment 7, except that in the present embodiment 19, the encapsulating material includes 55 parts of the fiber cloth and 45 parts of the powder coating.

Example 20:

[0134] This embodiment 20 employs the most preferred embodiment laminate structure disclosed in CN105637653A, except that the lamination process of the present patent embodiment 1 is employed.

Comparative Example 1:

[0136] This Comparative Example 1 employs an encapsulation material of a conventional typical photovoltaic module described in the background art.

Comparative Example 2:

[0138] This Comparative Example 2 employs the most preferred embodiment disclosed in CN105637653A, and employs its preferred lamination process.

Comparative Example 3:

[0140] The remaining technical solutions of the third comparative example are the same as the above-described seventh embodiment, and the only difference is that the CN1056376 is adopted.

The preferred lamination process disclosed in 53A is laminated to obtain a laminate structure of the photovoltaic module.

Industrial applicability

The present invention has carried out an effect test on the above-described embodiments and comparative examples, and the test results thereof are shown in Tables 1 and 2 below.

[0142] Table 1 Comparison of the implementation effects of the laminated structure of various types of photovoltaic modules in terms of photovoltaic technology standards

[]

Table 2 Comparison of the implementation effects of the laminated structure of various types of photovoltaic modules in terms of cost and preparation process

[Table 1]

Comparative Example 3 is a low-complex operation, and the unevenness can be adjusted and changed by assisting and laminating the temperature agent to achieve the color r3⁄4.

[0144] The weight of the package structure described in the full text of the present invention refers to the weight per square meter of the packaging material for the photovoltaic module; the impact resistance test refers to the ice ball with a standard diameter of 25 mm and a mass of 7.53 g at 23.0 m/ The speed of s is emitted, impacting 11 locations of the packaged PV modules, and the impact resistance of the PV modules is judged by three aspects: appearance, maximum power attenuation and insulation resistance. The fire resistance is detected by UL1703 standard. The pencil hardness is the result of the ASTM D3363-2005 (R2011) standard test; the tensile strength is the result of the GB/T 1040.3-2006 standard test; the elongation at break is passed GB/T 1040.3-2006 standard test results.

[0145] It can be clearly seen from the data in Table 1 that the embodiment of the present invention effectively solves the photovoltaic module package under the premise of meeting the technical standards of the photovoltaic industry such as anti-ultraviolet, anti-aging, anti-shock, fireproof, anti-insulation, etc. The lightweight material replaces the traditional packaged tempered glass to provide a certain rigidity to the photovoltaic module to protect the photovoltaic cell. Thus, not only can the weight of the photovoltaic module be greatly reduced, thereby adapting to the installation of photovoltaic power generation products in more occasions, Moreover, the labor intensity of the product installation and the ease of installation can be reduced, and the installation cost of the photovoltaic module can be reduced as a whole.

[0146] Further, as can be seen from Table 2, the present invention is low in cost and has excellent scratch resistance characteristics, and finally realizes a lamination process in a low temperature environment, reduces energy consumption, and ensures photovoltaic power. The flatness of the laminated structure of the component further facilitates the installation and implementation of the photovoltaic module under the aesthetic appearance. According to the data of this Table 2, it is further pointed out that when the first packaged powder coating is used in the embodiment of the present invention, the cost is lower than that of the acrylic powder coating, and the scratch resistance is superior to the acrylic powder. coating. When the first encapsulating layer and the second encapsulating layer of the embodiment of the present invention adopt the laminated structure disclosed in CN1056376 53A, although there is no advantage in scratch resistance, cost, and variety of color types, lamination is still realized. The process is simple, the lamination temperature is low, the energy consumption is low, and the smooth technical effect of the laminated structure of the photovoltaic module is ensured, and the technical progress is relatively advanced compared to CN105637653A.

[0147] It should be further emphasized that the first package powder coating or the second package powder coating is evenly coated on the fiber cloth by the coating device, and the use of the coating device can ensure the first package powder. Applying a uniform effect of the coating or the second packaged powder coating on the fiber cloth, and then pre-bonding the first packaged powder coating or the second packaged powder coating to the fiber cloth by pressure heating, and finally cutting the segmentation The first encapsulation layer and the second encapsulation layer of a suitably sized photovoltaic module can achieve any change in the package size of the photovoltaic module laminate structure to suit the installation requirements of different buildings, and further facilitate the installation application of the photovoltaic module.

[0148] Although the layer structure obtained in this embodiment is a partially preferred embodiment, it is not limited to those skilled in the art according to the needs of the actual application field, and other layer structures can be completely added based on the contents disclosed in the present invention. Such applications still fall within the spirit of the invention, and such applications are also considered to be within the scope of the invention.

The present invention is not limited to the details of the above-described exemplary embodiments, and the present invention can be embodied in other specific forms without departing from the spirit or essential characteristics of the invention. Therefore, the present embodiments are to be considered as illustrative and not restrictive, and the scope of the invention is defined by the appended claims All changes in the meaning and scope of equivalent elements are included in the present invention. Any reference signs in the claims should not be construed as limiting the claim.

In addition, it should be understood that although the description is described in terms of embodiments, not every embodiment includes only one independent technical solution, and the description of the specification is merely for the sake of clarity, and those skilled in the art should As a whole, the technical solutions in the embodiments may also be combined as appropriate to form other embodiments that can be understood by those skilled in the art.

Claims

Claim

[Claim 1] A method of fabricating a photovoltaic module laminate structure, the laminate structure comprising a first package layer

a solar cell string and a second encapsulation layer, characterized in that

The first encapsulating layer is prepared by using 30-50 parts by weight of fiber cloth and 50-70 parts by weight of the first encapsulating powder coating, and the first encapsulating powder coating is uniformly coated on the fiber cloth;

The second encapsulating layer is prepared by using 30-50 parts by weight of fiber cloth and 50-70 parts by weight of the second encapsulating powder coating, and the second encapsulating powder coating is uniformly coated on the fiber cloth;

The laminated structure of the photovoltaic module is prepared by a lamination process, wherein the laminating process comprises a first heating stage, a second heating stage and a third pressurized cooling stage, and the heating temperature range of the first stage is 110- 130 ° C, the heating range is 100-600 seconds; the second stage heating temperature range is 131-200 ° C, the heating range is 100-1200 seconds; the third stage cooling temperature range is 25-60 ° C, the applied pressure ranges from 0.05 to 0.25 MPa.

[Claim 2] The method for preparing a photovoltaic module laminate structure according to claim 1, wherein the first packaged powder coating is an acrylic powder coating or a super weather resistant polyester powder coating, the second The encapsulated powder coating is an acrylic powder coating or an ultra weather resistant polyester powder coating; the acrylic powder coating comprises an acrylic resin and an acrylic resin curing agent, and the super weather resistant polyester powder coating comprises a super weather resistant polyester resin and a super weather resistant polyester. Resin curing agent; the fiber cloth is woven from a fiber material.

[Claim 3] The method for preparing a photovoltaic module laminate structure according to claim 1, wherein the first packaged powder coating is an acrylic powder coating or a super weather resistant polyester powder coating, the second The encapsulated powder coating is a super weather resistant polyester powder coating; the acrylic powder coating comprises an acrylic resin and an acrylic resin curing agent, and the super weather resistant polyester powder coating comprises a super weather resistant polyester resin and a super weather resistant polyester resin curing agent; The fiber cloth is woven from a fibrous material.

[Claim 4] The method for fabricating a photovoltaic module laminate structure according to claim 1 or 2 or 3, wherein the method for preparing the first encapsulation layer and the second encapsulation layer comprises the following steps: a) uniformly coating the first packaged powder coating or the second packaged powder coating on the fiber cloth by a coating device;

b) thermally bonding the first packaged powder coating or the second packaged powder coating to the fiber cloth by pressure heating;

c), step b) finishing the thermally bonded powder coating and the fiber cloth are segmented; d) obtaining the first encapsulation layer or the second encapsulation layer;

Wherein, the press bonding range of the thermal bonding process is 0.05-0.25 MPa, the heating temperature range of the thermal bonding process is 90-130 ° C, and the heating enthalpy range is 5-20 seconds.

[Claim 5] The method for preparing a photovoltaic module laminate structure according to claim 2 or 3, wherein the acrylic resin curing agent is in an amount of 5 to 25% by weight based on the weight of the acrylic powder coating. The curing agent is blocked isocyanate, phthalic anhydride, trimellitic anhydride, sebacic acid, undecanedioic acid, dodecanedioic acid, tridecanedioic acid, tetradecanedioic acid, pentadecane Any one or a mixture of any of a mixture of diacid, hexadecandioic acid, carboxypolyester, hydrogenated epoxy, GMA acrylic acid.

[Claim 6] The method for preparing a photovoltaic module laminate structure according to claim 2 or 3, wherein the acrylic powder coating further comprises an auxiliary agent, and the auxiliary component of the auxiliary component accounts for the acrylic acid. 5-50% by weight of the powder coating, the auxiliaries are polyamide wax, polyolefin wax, amide modified phenol urea surfactant, benzoin, polydimethylsiloxane, vinyl trichlorosilane , n-butyltriethoxysilane, methyl orthosilicate, monoalkoxy pyrophosphate, acrylate, phenolic resin, urea formaldehyde resin, melamine formaldehyde resin, distearyl ethylenediamine, ethylene oxide Any one or more of a mixture with propylene oxide, hindered phenol, thiodipropionate, benzophenone, salicylate derivative, hindered amine, alumina, fumed silica, silica Any combination of ratios.

[Claim 7] The method for preparing a photovoltaic module laminate structure according to claim 2 or 3, wherein the super weather resistant polyester resin is a hydroxyl super weather resistant polyester resin or a carboxyl super weather resistant polyester resin. The glass transition temperature ranges from 50 to 75 ° C, and the viscosity ranges from 15 to 200 Pa, s. The hydroxyl super weather resistant polyester resin has a hydroxyl value ranging from 30 to 300 mg KOH/g, and the carboxyl super weather resistant polyester. The acid value of the resin ranges from 15 to 85 mg KOH/g.

[Claim 8] The method for preparing a photovoltaic module laminate structure according to claim 2 or 3, wherein the super weather resistant polyester powder coating further comprises an auxiliary agent, wherein the auxiliary component accounts for 3-40% by weight of the super weather resistant polyester powder coating, the auxiliary agent is a polyamide wax, a polyolefin wax, an amide modified phenol urea surfactant, benzoin, polydimethylsiloxane , vinyl trichlorosilane, n-butyltriethoxysilane, methyl orthosilicate, monoalkoxy pyrophosphate, acrylate, phenolic resin, urea-formaldehyde resin, melamine formaldehyde resin, distearyl ethane Amine, a mixture of ethylene oxide and propylene oxide, hindered phenol, thiodipropionate, benzophenone, salicylate derivative, hindered amine, alumina, fumed silica, tetrabromobisphenol A, a mixture of any one or a combination of decabromodiphenylethane, tricresyl phosphate, aluminum hydroxide, magnesium hydroxide, barium sulfate, titanium dioxide, and carbon black.

[Claim 9] A laminated structure of a photovoltaic module, characterized in that the laminated structure is obtained by the production method according to any one of claims 1-8.

[Claim 10] A photovoltaic module comprising a laminate structure, a connector and a junction box, wherein the electrical connection of the laminate structure to the junction box is achieved by a connector, wherein the photovoltaic module comprises the device of claim 9. The laminated structure of the photovoltaic module.

The photovoltaic module according to claim 10, wherein the connector comprises a crimping terminal and a heat shrinkable sleeve, and a cable card located at both ends of the connector is connected to the crimping terminal The heat shrinkable sleeve surrounds the crimp terminal.