WO2018040548A1 - Silicone rubber cable for rail transit and intelligent preparation method therefor - Google Patents

Silicone rubber cable for rail transit and intelligent preparation method therefor Download PDF

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WO2018040548A1
WO2018040548A1 PCT/CN2017/078008 CN2017078008W WO2018040548A1 WO 2018040548 A1 WO2018040548 A1 WO 2018040548A1 CN 2017078008 W CN2017078008 W CN 2017078008W WO 2018040548 A1 WO2018040548 A1 WO 2018040548A1
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silicone rubber
parts
cable
rubber
rail transit
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PCT/CN2017/078008
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French (fr)
Chinese (zh)
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姜青松
周佳龙
郑成
刘凤勤
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中天科技装备电缆有限公司
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L9/00Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04Homopolymers or copolymers of ethene
    • C08L23/06Polyethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L83/00Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
    • C08L83/04Polysiloxanes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/18Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
    • H01B3/28Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances natural or synthetic rubbers
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B7/00Insulated conductors or cables characterised by their form
    • H01B7/17Protection against damage caused by external factors, e.g. sheaths or armouring
    • H01B7/18Protection against damage caused by wear, mechanical force or pressure; Sheaths; Armouring
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B7/00Insulated conductors or cables characterised by their form
    • H01B7/17Protection against damage caused by external factors, e.g. sheaths or armouring
    • H01B7/28Protection against damage caused by moisture, corrosion, chemical attack or weather
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B7/00Insulated conductors or cables characterised by their form
    • H01B7/17Protection against damage caused by external factors, e.g. sheaths or armouring
    • H01B7/29Protection against damage caused by extremes of temperature or by flame
    • H01B7/295Protection against damage caused by extremes of temperature or by flame using material resistant to flame
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/002Physical properties
    • C08K2201/004Additives being defined by their length
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/02Flame or fire retardant/resistant
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/20Applications use in electrical or conductive gadgets
    • C08L2203/202Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00Properties characterising the ingredient of the composition
    • C08L2207/06Properties of polyethylene
    • C08L2207/062HDPE

Definitions

  • the invention relates to the technical field of cables, in particular to a silicon rubber cable for rail transit and an intelligent preparation method thereof.
  • the existing silicone rubber high temperature cable for rail vehicles meets the European standard EN 50382-2:2008 "railway equipment - high temperature power cables for rolling stock with special fire performance, Part 2: 120 ° C or 150 ° C single core silicone rubber insulated cable ⁇ .
  • the cable core structure of the cable is made of the tinned or non-tinned stranded soft conductor of Class 5 or Class 6 of GB/T 3956-2008 "Conductor of Cable” and extruded with a temperature rating of 150 °C. Silicone rubber insulation material composition.
  • the tensile strength of the silicone rubber insulating material is not less than 8.0 MPa, and the elongation at break is not less than 200%.
  • the insulation and the sheath are relatively opposed. Sliding, and the two ends of the installation cable are fixed, the inner ring of the sheath is wrinkled, and the stress at the wrinkles is concentrated, which will cause the sheath to crack during the long-term operation of the vehicle and reduce the physical and mechanical properties of the cable.
  • the existing rail transit vehicle cable generally adopts a thermosetting low-smoke halogen-free flame-retardant low-toxic polyolefin material with a tensile strength of not less than 10 MPa.
  • the material In order to satisfy the excellent flame retardant performance of the cable, the material generally adopts an aluminum-magnesium flame-retardant system, but The large amount of metal minerals is added to improve the moisture absorption performance of the cable.
  • the cable is usually protected by a network tube cushion during the laying process.
  • the mesh tube cushion is made of polyester material, and the nitrogen-phosphorus flame retardant system is generally used.
  • the nitrogen-phosphorus flame retardant has the characteristics of water migration and migrates to the network tube cushion. After the surface, it will react with magnesium hydroxide in the aluminum-magnesium flame retardant system cable to form magnesium hydrogen phosphate, which will cause spots on the cable surface and affect the long-term flame retardant performance of the cable.
  • the utility model In order to improve the mechanical margin when laying single insulated silicon rubber cable, instead of the insulated sheath cable, the utility model has the advantages of small volume and light weight.
  • the single insulated cable has no sheath structure, so it is repeatedly bent without wrinkles. Avoid the hidden danger of cracking the jacket during long-term operation of the vehicle.
  • the object of the present invention is to provide a performance that can meet the requirements of the jumper cable of the traction motor power cable and the car joint in the bogie, and improve the performance of the traditional silicone rubber cable material, so as to have high strength, high temperature resistance, cold resistance and resistance. Excellent performance such as aging, waterproof and moisture-proof, and long service life to solve the problems raised in the above background art.
  • a silicone rubber cable for rail transit comprising a conductor and an insulating layer, the insulating layer covering the outside of the conductor, and the surface of the insulating layer is provided with n ridges of the same structure, phase The angle between the adjacent ridges is 40-60°, and the height of the ribs is 0.1-0.5 mm.
  • An intelligent preparation method of silicone rubber for silicone rubber cable for rail transit comprising the following steps:
  • the corresponding quality of silicone rubber and butadiene rubber are transported to the designated place by AGV smart car, and then the machine is fed with the mechanical kneading machine to open the nitrogen gas, and the steam is heated to 92-98 ° C for 5 min.
  • the robot is used to automatically feed the A component to the kneading machine, and at the same time, the oil is weighed with the corresponding quality of epoxy soybean oil, paraffin oil and hydroxy silicone oil, and then heated to 135-145 ° C for kneading, 5-10 min;
  • the robot automatically adds the cross-linking agent group B, maintains 135-145 ° C for kneading for 20-30 min, then cools to 70 ° C, and then automatically discharges to the mixer;
  • the silicone rubber delivered by the kneading machine is kneaded by means of rubber turning, triangle packing, etc., and kneaded for 4 to 5 times, and then the rubber material is transported by a conveyor belt to a three-roll calendering and eight-roll cooling device.
  • the tablet is cooled, and the final sheet thickness is 1 to 3 mm;
  • the silicone rubber formulation comprises the following components: 100 parts by weight of base silicone rubber; 25-30 parts of butadiene rubber; 10-15 parts of white carbon black; 12-18 parts of carbon black N550; composite flame retardant 12 ⁇ 15 parts; 12 to 15 parts of talc; 3 to 5 parts of zinc oxide; 2 to 3 parts of chopped glass fiber; 8 to 10 parts of stearic acid; 4 to 8 parts of high density polyethylene; and promoter M 0.5 to 0.8 Parts; antioxidants 1 to 3 parts; crosslinker 0.1 to 0.3 parts; epoxy soybean oil 4 to 5 parts; paraffin oil 4 to 5 parts; hydroxy silicone oil 2 to 3 parts; zinc stearate 0.15 to 0.25 parts.
  • the composite flame retardant is made of nano aluminum hydroxide, hexa(DOPO hydroxymethylbenzyloxy)cyclotriphosphazene, ammonium polyphosphate and polyester resin, and the mass percentage is 60-80: 8 ⁇ 15: ⁇ 20:5:35 ⁇ 38 prepared a new composite flame retardant material.
  • the crosslinking agent is 1,1-di(tert-butylperoxy)cyclohexane, bis(1-methyl-1phenylethyl) peroxide; 1,3 (t-butyl) At least one of oxyisopropyl)benzene.
  • the chopped glass fibers have a length of from 0.1 to 0.2 mm, preferably a length of 0.15 mm.
  • the antioxidant is selected from: N-phenyl-N'-cyclohexyl p-phenylenediamine, N-phenyl-N'-isopropyl-p-phenylenediamine, At least one of N-N'-diphenyl-p-phenylenediamine and 6-di-tert-butyl-p-cresol.
  • the invention provides an intelligent preparation method of silicone rubber for rail transit, and the silicon rubber is used for the insulation and sheathing material of the high temperature cable of the rail transit vehicle, and the performance thereof can satisfy the traction motor power cable and the car joint in the bogie.
  • the jumper cable indicator requirements are provided.
  • the invention improves the performance of the traditional silicone rubber cable material, and has the advantages of high strength, high temperature resistance, cold resistance, anti-aging, waterproof and moisture proof, long service life, etc., and can be used for car body wiring in the railway vehicle power system, especially adding a new type
  • the composite flame retardant can ensure the normal power supply performance of the cable in a long time under the flame condition and achieve the flame retardant effect.
  • the new silicone rubber cable material preparation adopts intelligent batching production, which not only saves labor cost, but also achieves accurate batching and meets batch uniformity.
  • Figure 1 is a schematic view of the structure of the present invention.
  • a silicone rubber cable for rail transit comprising a conductor 1 and an insulating layer 2 , the insulating layer 2 covering the outside of the conductor 1 , the surface of the insulating layer 2 is provided with the same structure
  • the n ribs 3 have an angle of 40 to 60° between the adjacent ribs 3, and the height of the ribs 3 is 0.1 to 0.5 mm.
  • the invention mainly relates to an intelligent preparation method of silicone rubber for rail transit vehicles, and the formula silicone rubber cable material is used as a high strength and high flame retardant silicone rubber cable sheathing material for rail transit vehicles.
  • the formula is as follows: 100 parts by mass of base silicone rubber; 25-30 parts of butadiene rubber; 10-15 parts of white carbon black; 12-18 parts of carbon black N550; 12-15 parts of composite flame retardant; talc 12 to 15 parts of powder; 3 to 5 parts of zinc oxide; 2 to 3 parts of chopped glass fiber; 8 to 10 parts of stearic acid; 4 to 8 parts of high density polyethylene; 0.5 to 0.8 parts of accelerator M; ⁇ 3 parts; cross-linking agent 0.1-0.3 parts; epoxidized soybean oil 4-5 parts; paraffin oil 4-5 parts; hydroxy silicone oil 2-3 parts; zinc stearate 0.15-0.25 parts.
  • the composite flame retardant in formula a is a novel composite flame retardant material prepared by using nano aluminum hydroxide, hexa(DOPO hydroxymethylbenzyloxy)cyclotriphosphazene, ammonium polyphosphate and polyester resin as raw materials.
  • the particle size of the nano-aluminum hydroxide is selected from 10 to 20 nm, and the particle size aluminum hydroxide can be sufficiently dispersed in the composite flame retardant; as shown in Table 1, the optimal three-group formula of the composite flame retardant in the formulation :
  • the crosslinking agent is 1,1-two. (tert-butylperoxy)cyclohexane, bis(1-methyl-1phenylethyl)peroxide; at least one of 1,3-di(tert-butylperoxyisopropyl)benzene ;
  • the short-cut glass fiber has obvious reinforcing effect on the silicone rubber cable material, and the length of the chopped glass fiber is required to be 0.1-0.2 mm.
  • the chopped glass fiber in the range is favorable for uniform dispersion in the silicone rubber cable material, and preferably the length. Is 0.15mm;
  • the antioxidant can be selected: N-phenyl-N'-cyclohexyl p-phenylenediamine (anti-aging agent 4010), N-phenyl-N'-isopropyl-p-phenylenediamine (anti-aging agent 4010NA) , at least one of NN ⁇ -diphenyl-p-phenylenediamine (anti-aging agent H) and 6-di-tert-butyl-p-cresol (anti-aging agent 264);
  • the invention mainly relates to an intelligent preparation method of silicone rubber for rail transit vehicles, and the main preparation thereof mainly adopts intelligent control from the raw material weighing to the final collection rubber compound, and the specific process is as follows:
  • the corresponding quality of silicone rubber and butadiene rubber are transported to the designated place by AGV smart car, and then the machine is fed with the mechanical kneading machine to open the nitrogen gas, and the steam is heated to 92-98 ° C for 5 min.
  • the robot is used to automatically feed the A component to the kneading machine, and at the same time, the oil is weighed with the corresponding quality of epoxy soybean oil, paraffin oil and hydroxy silicone oil, and then heated to 135-145 ° C for kneading, 5-10 min;
  • the robot automatically added the cross-linking agent group B, and after kneading at 135-145 ° C for 20-30 min, the temperature was lowered to 70 ° C, and then automatically discharged to the mixer.
  • the silicone rubber delivered by the kneading machine is kneaded by means of rubber turning, triangle packing, etc., and kneaded for 4 to 5 times, and then the rubber material is transported by a conveyor belt to a three-roll calendering and eight-roll cooling device.
  • the tablet is cooled, and the final sheet thickness is 1 to 3 mm.
  • the silicone rubber delivered by the kneading machine is kneaded by means of rubber turning, triangle packing, etc., and kneaded for 4 to 5 times, and then the rubber material is transported by a conveyor belt to a three-roll calendering and eight-roll cooling device for tablet cooling.
  • the final sheet thickness is 1 to 3 mm;
  • the folded piece At the position of the folded piece, it is automatically transported to the corresponding glue storage position by the AGV smart car.
  • the AGV smart car When the sulphur section is used, it is only necessary to input the type of the required rubber material through the industrial tablet computer, and the AGV smart car can automatically take out the rubber material in the rubber warehouse;
  • the silicone rubber delivered by the kneading machine is kneaded by means of rubber turning, triangle packing, etc., and kneaded for 4 to 5 times, and then the rubber material is transported by a conveyor belt to a three-roll calendering and eight-roll cooling device for tablet cooling.
  • the final sheet thickness is 1 to 3 mm;
  • the folded piece At the position of the folded piece, it is automatically transported to the corresponding glue storage position by the AGV smart car.
  • the AGV smart car When the sulphur section is used, it is only necessary to input the type of the required rubber material through the industrial tablet computer, and the AGV smart car can automatically take out the rubber material in the rubber warehouse;
  • the silicone rubber delivered by the kneading machine is kneaded by means of rubber turning, triangle packing, etc., and kneaded for 4 to 5 times, and then the rubber material is transported by a conveyor belt to a three-roll calendering and eight-roll cooling device for tablet cooling.
  • the final sheet thickness is 1 to 3 mm;
  • the folded piece At the position of the folded piece, it is automatically transported to the corresponding glue storage position by the AGV smart car.
  • the AGV smart car can automatically take out the glue in the rubber warehouse.
  • the invention improves the performance of the traditional silicone rubber cable material, and has the advantages of high strength, high temperature resistance, cold resistance, anti-aging, waterproof and moisture proof, long service life, etc., and can be used for the vehicle body wiring in the railway vehicle power system, especially added
  • a new type of composite flame retardant made of magnesium hydroxide which can quickly extinguish the cable in flame condition, does not prolong flame, and achieve high flame retardant effect.
  • the new silicone rubber cable material preparation adopts intelligent batching production, which not only saves labor cost, but also achieves accurate batching and meets batch uniformity.
  • the single insulated cable has no sheath structure, so it is repeatedly bent without wrinkles. Avoid the hidden danger of cracking the jacket during long-term operation of the vehicle.

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Abstract

Provided are a silicone rubber cable for rail transit and an intelligent preparation method for the silicone rubber. The silicone rubber cable for rail transit comprises a conductor and an insulation layer. The outer side of the conductor is covered by the insulation layer. The surface of the insulation layer is provided with n ribs with the same structure, an angle between adjacent ribs is 40-60 °, and the height of the ribs is 0.1-0.5 mm. The silicone rubber, when used for insulation and sheathing materials of high temperature cables for rail transit vehicles, can produce good performance which meets norms required by power cables for drawing a motor in a bogie and by jumper cables cables in the railroad car connecting part, thereby enhancing the performance of the traditional silicone rubber cable materials, providing high strength, high temperature resistance, cold resistance, anti-aging, waterproof, damp-proof, long service life and other excellent performance. In the conditions with flame, the silicone rubber can ensure that the cable remains normal power supply in a longer period, reaching a flame retardant effect. The new silicone rubber cable material is prepared using intelligent batching operation, which saves labor costs, and achieves accurate batching and uniformity of each batch.

Description

[根据细则37.2由ISA制定的发明名称] 轨道交通用硅橡胶电缆及其硅橡胶智能化制备方法[Name of invention made by ISA according to Rule 37.2] Silicone rubber cable for rail transit and intelligent preparation method thereof 技术领域Technical field
本发明涉及电缆技术领域,具体为一种轨道交通用硅橡胶电缆及其硅橡胶智能化制备方法。The invention relates to the technical field of cables, in particular to a silicon rubber cable for rail transit and an intelligent preparation method thereof.
背景技术Background technique
现有轨道交通车辆用硅橡胶高温电缆满足欧盟标准EN 50382-2:2008《铁道装备-具有特殊防火性能的机车车辆用高温电力电缆,第2篇:120℃或150℃单芯硅橡胶绝缘电缆》。其电缆的缆芯结构由GB/T 3956-2008《电缆的导体》中第5类或第6类的镀锡或非镀锡的绞合软导体和挤包一层耐温等级为150℃的硅橡胶绝缘材料组成。其中硅橡胶绝缘材料的抗张强度不小于8.0MPa,断裂伸长率不小于200%。The existing silicone rubber high temperature cable for rail vehicles meets the European standard EN 50382-2:2008 "railway equipment - high temperature power cables for rolling stock with special fire performance, Part 2: 120 ° C or 150 ° C single core silicone rubber insulated cable 》. The cable core structure of the cable is made of the tinned or non-tinned stranded soft conductor of Class 5 or Class 6 of GB/T 3956-2008 "Conductor of Cable" and extruded with a temperature rating of 150 °C. Silicone rubber insulation material composition. The tensile strength of the silicone rubber insulating material is not less than 8.0 MPa, and the elongation at break is not less than 200%.
长期以来,电缆在复杂、恶劣的环境条件下敷设时,尤其是整车通长度敷设,为了避免施工过程中对电缆绝缘造成机械损伤,通常要在缆芯外挤包一层硅橡胶护套材料,通过提升非金属材料厚度的方式来提高电缆的机械性能余量。但同时这增加了电缆的尺寸、重量,违背了电缆产品体积小、重量轻的发展思路。并且为了使硅橡胶绝缘与硅橡胶护套间容易分离便于施工,通常在二者之间增加隔离层结构。但由于在复杂的机车车辆的布线环境中,多处电缆不可避免的会保持90℃弯曲、甚至更小角度弯曲的状态,此时由于电缆隔离层结构的存在,绝缘和护套之间产生相对滑动,并且安装电缆两端固定,护套内圈便有褶皱现象的产生,褶皱处应力集中,在车辆的长期运行过程中将导致护套开裂,降低电缆的物理机械性能。For a long time, when the cable is laid under complicated and harsh environmental conditions, especially the length of the whole vehicle, in order to avoid mechanical damage to the cable insulation during the construction process, it is usually necessary to squeeze a layer of silicone rubber sheathing material outside the core. Improve the mechanical performance margin of the cable by increasing the thickness of the non-metallic material. But at the same time, this increases the size and weight of the cable, which is contrary to the development idea that the cable product is small in size and light in weight. In order to facilitate the separation between the silicone rubber insulation and the silicone rubber sheath, it is common to increase the isolation layer structure between the two. However, in the wiring environment of complex rolling stock, multiple cables inevitably maintain a 90°C bending or even a smaller angle bending state. At this time, due to the existence of the cable isolation layer structure, the insulation and the sheath are relatively opposed. Sliding, and the two ends of the installation cable are fixed, the inner ring of the sheath is wrinkled, and the stress at the wrinkles is concentrated, which will cause the sheath to crack during the long-term operation of the vehicle and reduce the physical and mechanical properties of the cable.
现有的轨道交通车辆电缆一般采用拉伸强度不小于10MPa的热固性低烟无卤阻燃低毒聚烯烃材料,为满足电缆优异的阻燃性能,该材料普遍采用铝镁阻燃体系,但由于金属矿物质的大量添加,提高了电缆的吸湿性能,在电缆长期通电过程中,电缆受潮后,有表面爬电的隐患。同时该电缆在敷设过程中,通常采用网管垫层作为保护,网管垫层为聚酯材料,普遍采用氮磷阻燃体系,而氮磷阻燃剂有遇水迁移的特点,迁移到网管垫层表面后,将与铝镁阻燃体系电缆中的氢氧化镁发生反应,生成磷酸氢镁,导致电缆表面产生斑点,影响电缆长期运行的阻燃性能。The existing rail transit vehicle cable generally adopts a thermosetting low-smoke halogen-free flame-retardant low-toxic polyolefin material with a tensile strength of not less than 10 MPa. In order to satisfy the excellent flame retardant performance of the cable, the material generally adopts an aluminum-magnesium flame-retardant system, but The large amount of metal minerals is added to improve the moisture absorption performance of the cable. During the long-term electrification of the cable, there is a hidden danger of surface creepage after the cable is wet. At the same time, the cable is usually protected by a network tube cushion during the laying process. The mesh tube cushion is made of polyester material, and the nitrogen-phosphorus flame retardant system is generally used. The nitrogen-phosphorus flame retardant has the characteristics of water migration and migrates to the network tube cushion. After the surface, it will react with magnesium hydroxide in the aluminum-magnesium flame retardant system cable to form magnesium hydrogen phosphate, which will cause spots on the cable surface and affect the long-term flame retardant performance of the cable.
随着互联网+智能制造理念的普及和广泛应用、大数据的收集、整理、分析以及纳米技术的突破。为研发出拉伸强度不小于10MPa硅橡胶材料配方及批量生产提供了更合适的方案。With the popularization and widespread application of the Internet + intelligent manufacturing concept, the collection, collation, analysis and breakthrough of nanotechnology. In order to develop a formula of silicone rubber material with tensile strength of not less than 10 MPa and a more suitable solution for mass production.
以提高单绝缘硅橡胶电缆敷设时的机械余量,代替绝缘护套电缆,实现体积小、重量轻的特点。In order to improve the mechanical margin when laying single insulated silicon rubber cable, instead of the insulated sheath cable, the utility model has the advantages of small volume and light weight.
单绝缘电缆无护套结构,因此反复弯曲无褶皱现象。避免车辆长期运行中,护套开裂的隐患。The single insulated cable has no sheath structure, so it is repeatedly bent without wrinkles. Avoid the hidden danger of cracking the jacket during long-term operation of the vehicle.
替代聚烯烃电缆产品,避免因电缆与网管匹配问题而产生的防火性能降低的隐患。 Instead of polyolefin cable products, avoid the hidden dangers of fire performance caused by cable and network tube matching problems.
发明内容Summary of the invention
本发明的目的在于提供一种性能可满足转向架内牵引电机动力电缆和车厢连接处的跨接电缆指标要求,提升传统硅橡胶电缆料的性能,使其具备高强度、耐高温、耐寒、抗老化、防水防潮、使用寿命长等优异性能,以解决上述背景技术中提出的问题。The object of the present invention is to provide a performance that can meet the requirements of the jumper cable of the traction motor power cable and the car joint in the bogie, and improve the performance of the traditional silicone rubber cable material, so as to have high strength, high temperature resistance, cold resistance and resistance. Excellent performance such as aging, waterproof and moisture-proof, and long service life to solve the problems raised in the above background art.
为实现上述目的,本发明提供如下技术方案:一种轨道交通用硅橡胶电缆,包括导体和绝缘层,绝缘层覆盖在导体外侧,所述绝缘层表面设置有结构相同的n条凸条,相邻凸条之间夹角为40~60°,所述凸条的高度为0.1~0.5mm。In order to achieve the above object, the present invention provides the following technical solution: a silicone rubber cable for rail transit, comprising a conductor and an insulating layer, the insulating layer covering the outside of the conductor, and the surface of the insulating layer is provided with n ridges of the same structure, phase The angle between the adjacent ridges is 40-60°, and the height of the ribs is 0.1-0.5 mm.
一种轨道交通用硅橡胶电缆的硅橡胶智能化制备方法,包括以下步骤:An intelligent preparation method of silicone rubber for silicone rubber cable for rail transit, comprising the following steps:
(1)按照常规工艺使用机械臂自动给白炭黑、炭黑N550、滑石粉、氧化锌,硬脂酸五个储料罐自动投料;在电脑生产系统中输入配方的组分、生产的车次数进行智能化投料,下料到混合储蓄罐;(1) Automatically feed the five storage tanks of white carbon black, carbon black N550, talc powder, zinc oxide and stearic acid according to the conventional process; input the components of the formula and the car produced in the computer production system. The number of times is intelligently fed, and the material is fed to the mixed storage tank;
(2)智能化自动称取复合型阻燃剂、短切玻璃纤维、高密度聚乙烯、促进剂M、防老剂、硬脂酸锌各自打包,并命名为A组;交联剂打包为B组;(2) Intelligent automatic weighing composite flame retardant, chopped glass fiber, high density polyethylene, accelerator M, anti-aging agent, zinc stearate are packaged separately and named as group A; cross-linking agent is packaged as B group;
(3)按配方比例将相应质量的硅橡胶、顺丁橡胶用AGV智能小车运送到指定地点后用机械臂向真空捏合机投料,开氮气,通蒸汽加热升温到92~98℃保持5min后;使用机械手自动向捏合机投A组料,并同时油料采用自动上料油泵称取相应质量的环氧大豆油、石蜡油及羟基硅油,后升温到135~145℃进行捏合,5~10min;并用机械手自动加入交联剂B组,保持135~145℃进行捏合20~30min后,降温至70℃,后自动放料至混炼机;(3) According to the formula ratio, the corresponding quality of silicone rubber and butadiene rubber are transported to the designated place by AGV smart car, and then the machine is fed with the mechanical kneading machine to open the nitrogen gas, and the steam is heated to 92-98 ° C for 5 min. The robot is used to automatically feed the A component to the kneading machine, and at the same time, the oil is weighed with the corresponding quality of epoxy soybean oil, paraffin oil and hydroxy silicone oil, and then heated to 135-145 ° C for kneading, 5-10 min; The robot automatically adds the cross-linking agent group B, maintains 135-145 ° C for kneading for 20-30 min, then cools to 70 ° C, and then automatically discharges to the mixer;
(4)将捏合机下发的硅橡胶,通过翻胶、打三角包等方式进行混炼,并混炼4~5次后,通过传送带将胶料运输至三辊压延、八辊冷却装置进行压片冷却,最终片厚度为1~3mm;(4) The silicone rubber delivered by the kneading machine is kneaded by means of rubber turning, triangle packing, etc., and kneaded for 4 to 5 times, and then the rubber material is transported by a conveyor belt to a three-roll calendering and eight-roll cooling device. The tablet is cooled, and the final sheet thickness is 1 to 3 mm;
(5)在收叠片的位置,通过AGV智能小车自动运输至相应的胶料库位里面。连硫工段在领用胶料时,只需通过工业平板电脑输入所需胶料的型号,AGV智能小车便能自动在胶料仓库里面将胶料领出;(5) At the position of the folded piece, it is automatically transported to the corresponding glue storage position by the AGV smart car. When the sulphur section is used, it is only necessary to input the type of the required rubber material through the industrial tablet computer, and the AGV smart car can automatically take out the rubber material in the rubber warehouse;
(6)产品信息的追溯:在EPR系统中将胶料的信息生成条形码,然后通过打印机进行打印,张贴在每箱胶料的包装箱上,方便生产追溯;混橡车间实现无线网络全覆盖,通过手持终端对胶料的条形码信息进行扫描。(6) Traceability of product information: In the EPR system, the information of the rubber material is generated into a barcode, and then printed by the printer, posted on the packaging box of each box of rubber to facilitate the production traceability; the mixed rubber workshop realizes full coverage of the wireless network, The barcode information of the rubber is scanned by the handheld terminal.
优选的,硅橡胶配方包括以下组分:基料硅橡胶质量份100份;顺丁橡胶25~30份;白炭黑10~15份;炭黑N550 12~18份;复合型阻燃剂12~15份;滑石粉12~15份;氧化锌3~5份;短切玻璃纤维2~3份;硬脂酸8~10份;高密度聚乙烯4~8份;促进剂M 0.5~0.8份;防老剂1~3份;交联剂0.1~0.3份;环氧大豆油4~5份;石蜡油4~5份;羟基硅油2~3份;硬脂酸锌0.15~0.25份。Preferably, the silicone rubber formulation comprises the following components: 100 parts by weight of base silicone rubber; 25-30 parts of butadiene rubber; 10-15 parts of white carbon black; 12-18 parts of carbon black N550; composite flame retardant 12 ~15 parts; 12 to 15 parts of talc; 3 to 5 parts of zinc oxide; 2 to 3 parts of chopped glass fiber; 8 to 10 parts of stearic acid; 4 to 8 parts of high density polyethylene; and promoter M 0.5 to 0.8 Parts; antioxidants 1 to 3 parts; crosslinker 0.1 to 0.3 parts; epoxy soybean oil 4 to 5 parts; paraffin oil 4 to 5 parts; hydroxy silicone oil 2 to 3 parts; zinc stearate 0.15 to 0.25 parts.
优选的,复合型阻燃剂是以纳米氢氧化铝、六(DOPO羟甲基苯甲基氧基)环三磷腈、聚磷酸铵和聚酯树脂为原料,按质量百分比为60~80∶8~15∶~20∶5∶35~38制备新型复合阻燃材料。Preferably, the composite flame retardant is made of nano aluminum hydroxide, hexa(DOPO hydroxymethylbenzyloxy)cyclotriphosphazene, ammonium polyphosphate and polyester resin, and the mass percentage is 60-80: 8~15:~20:5:35~38 prepared a new composite flame retardant material.
优选的,交联剂为1,1-二(叔丁基过氧基)环己烷、双(1-甲基-1苯基乙基)过氧化物;1,3二(叔丁基过氧异丙基)苯中的至少一种。Preferably, the crosslinking agent is 1,1-di(tert-butylperoxy)cyclohexane, bis(1-methyl-1phenylethyl) peroxide; 1,3 (t-butyl) At least one of oxyisopropyl)benzene.
优选的,短切玻璃纤维长度为0.1~0.2mm,优选长度为0.15mm。Preferably, the chopped glass fibers have a length of from 0.1 to 0.2 mm, preferably a length of 0.15 mm.
优选的,防老剂选用:N苯基-N`-环己基对苯二胺、N-苯基-N`-异丙基-对苯二胺, N-N`-二苯基-对苯二胺、6-二叔丁基对甲酚中至少一种。Preferably, the antioxidant is selected from: N-phenyl-N'-cyclohexyl p-phenylenediamine, N-phenyl-N'-isopropyl-p-phenylenediamine, At least one of N-N'-diphenyl-p-phenylenediamine and 6-di-tert-butyl-p-cresol.
与现有技术相比,本发明的有益效果是:Compared with the prior art, the beneficial effects of the present invention are:
本发明提出了一种轨道交通用硅橡胶智能化制备方法,并将该硅橡胶用于轨道交通车辆高温电缆的绝缘和护套材料,其性能可满足转向架内牵引电机动力电缆和车厢连接处的跨接电缆指标要求。The invention provides an intelligent preparation method of silicone rubber for rail transit, and the silicon rubber is used for the insulation and sheathing material of the high temperature cable of the rail transit vehicle, and the performance thereof can satisfy the traction motor power cable and the car joint in the bogie. The jumper cable indicator requirements.
本发明提升传统硅橡胶电缆料的性能,使其具备高强度、耐高温、耐寒、抗老化、防水防潮、使用寿命长等优异性能,可用于轨道交通车辆动力系统中车体布线,特别添加新型复合型阻燃剂,在火焰条件中可确保电缆在较长时间内正常供电性能,达到阻燃效果。该新型硅橡胶电缆料制备采用智能化进行配料生产,既节约劳动力成本,又可达到精确配料、满足各批次均一性。The invention improves the performance of the traditional silicone rubber cable material, and has the advantages of high strength, high temperature resistance, cold resistance, anti-aging, waterproof and moisture proof, long service life, etc., and can be used for car body wiring in the railway vehicle power system, especially adding a new type The composite flame retardant can ensure the normal power supply performance of the cable in a long time under the flame condition and achieve the flame retardant effect. The new silicone rubber cable material preparation adopts intelligent batching production, which not only saves labor cost, but also achieves accurate batching and meets batch uniformity.
附图说明DRAWINGS
图1为本发明结构示意图。Figure 1 is a schematic view of the structure of the present invention.
具体实施方式detailed description
下面将结合本发明实施例中的附图,对本发明实施例中的技术方案进行清楚、完整地描述,显然,所描述的实施例仅仅是本发明一部分实施例,而不是全部的实施例。基于本发明中的实施例,本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其他实施例,都属于本发明保护的范围。The technical solutions in the embodiments of the present invention are clearly and completely described in the following with reference to the accompanying drawings in the embodiments of the present invention. It is obvious that the described embodiments are only a part of the embodiments of the present invention, but not all embodiments. All other embodiments obtained by those skilled in the art based on the embodiments of the present invention without creative efforts are within the scope of the present invention.
请参阅图1,本发明提供一种技术方案:一种轨道交通用硅橡胶电缆,包括导体1和绝缘层2,绝缘层2覆盖在导体1外侧,所述绝缘层2表面设置有结构相同的n条凸条3,相邻凸条3之间夹角为40~60°,所述凸条3的高度为0.1~0.5mm。Referring to FIG. 1 , the present invention provides a technical solution: a silicone rubber cable for rail transit, comprising a conductor 1 and an insulating layer 2 , the insulating layer 2 covering the outside of the conductor 1 , the surface of the insulating layer 2 is provided with the same structure The n ribs 3 have an angle of 40 to 60° between the adjacent ribs 3, and the height of the ribs 3 is 0.1 to 0.5 mm.
本发明主要涉及到轨道交通车辆用硅橡胶智能化制备方法,其配方硅橡胶电缆料做为轨道交通车辆用高强度、高阻燃硅橡胶电缆护套料使用。The invention mainly relates to an intelligent preparation method of silicone rubber for rail transit vehicles, and the formula silicone rubber cable material is used as a high strength and high flame retardant silicone rubber cable sheathing material for rail transit vehicles.
a.配方如下:以基料硅橡胶质量份100份;顺丁橡胶25~30份;白炭黑10~15份;炭黑N550 12~18份;复合型阻燃剂12~15份;滑石粉12~15份;氧化锌3~5份;短切玻璃纤维2~3份;硬脂酸8~10份;高密度聚乙烯4~8份;促进剂M 0.5~0.8份;防老剂1~3份;交联剂0.1~0.3份;环氧大豆油4~5份;石蜡油4~5份;羟基硅油2~3份;硬脂酸锌0.15~0.25份。a. The formula is as follows: 100 parts by mass of base silicone rubber; 25-30 parts of butadiene rubber; 10-15 parts of white carbon black; 12-18 parts of carbon black N550; 12-15 parts of composite flame retardant; talc 12 to 15 parts of powder; 3 to 5 parts of zinc oxide; 2 to 3 parts of chopped glass fiber; 8 to 10 parts of stearic acid; 4 to 8 parts of high density polyethylene; 0.5 to 0.8 parts of accelerator M; ~3 parts; cross-linking agent 0.1-0.3 parts; epoxidized soybean oil 4-5 parts; paraffin oil 4-5 parts; hydroxy silicone oil 2-3 parts; zinc stearate 0.15-0.25 parts.
b.配方a中复合型阻燃剂是以纳米氢氧化铝、六(DOPO羟甲基苯甲基氧基)环三磷腈、聚磷酸铵和聚酯树脂为原料制备新型复合阻燃材料,其中纳米氢氧化铝的粒径选用10~20nm,该粒径大小氢氧化铝可在该复合型阻燃剂中充分分散;如表一所示,配方中复合型阻燃剂最优三组配方: b. The composite flame retardant in formula a is a novel composite flame retardant material prepared by using nano aluminum hydroxide, hexa(DOPO hydroxymethylbenzyloxy)cyclotriphosphazene, ammonium polyphosphate and polyester resin as raw materials. The particle size of the nano-aluminum hydroxide is selected from 10 to 20 nm, and the particle size aluminum hydroxide can be sufficiently dispersed in the composite flame retardant; as shown in Table 1, the optimal three-group formula of the composite flame retardant in the formulation :
Figure PCTCN2017078008-appb-000001
Figure PCTCN2017078008-appb-000001
表一Table I
c.该配方中在基料硅橡胶的基础上添加了顺丁橡胶后并结合交联剂作用,使硅橡胶电缆料耐寒性、防水防潮性能明显提高,其中交联剂为1,1-二(叔丁基过氧基)环己烷、双(1-甲基-1苯基乙基)过氧化物;1,3-二(叔丁基过氧异丙基)苯中的至少一种;c. In this formula, after adding butadiene rubber to the base silicone rubber and bonding with the crosslinking agent, the cold resistance and waterproof moisture resistance of the silicone rubber cable material are obviously improved, wherein the crosslinking agent is 1,1-two. (tert-butylperoxy)cyclohexane, bis(1-methyl-1phenylethyl)peroxide; at least one of 1,3-di(tert-butylperoxyisopropyl)benzene ;
d.其中短切玻璃纤维对硅橡胶电缆料补强效果明显,要求短切玻璃纤维长度为0.1~0.2mm,该范围内的短切玻璃纤维有利于其在硅橡胶电缆料分散均匀,优选长度为0.15mm;d. Among them, the short-cut glass fiber has obvious reinforcing effect on the silicone rubber cable material, and the length of the chopped glass fiber is required to be 0.1-0.2 mm. The chopped glass fiber in the range is favorable for uniform dispersion in the silicone rubber cable material, and preferably the length. Is 0.15mm;
e.其中防老剂可以选择选用:N-苯基-N`-环己基对苯二胺(防老剂4010)、N-苯基-N`-异丙基-对苯二胺(防老剂4010NA),N-N`-二苯基-对苯二胺(防老剂H)、6-二叔丁基对甲酚(防老剂264)中至少一种;e. Among them, the antioxidant can be selected: N-phenyl-N'-cyclohexyl p-phenylenediamine (anti-aging agent 4010), N-phenyl-N'-isopropyl-p-phenylenediamine (anti-aging agent 4010NA) , at least one of NN`-diphenyl-p-phenylenediamine (anti-aging agent H) and 6-di-tert-butyl-p-cresol (anti-aging agent 264);
本发明主要涉及轨道交通车辆用硅橡胶智能化制备方法,其主要制备主要采用从原材料称取到最终收集胶料全程智能化控制,具体工艺过程如下:The invention mainly relates to an intelligent preparation method of silicone rubber for rail transit vehicles, and the main preparation thereof mainly adopts intelligent control from the raw material weighing to the final collection rubber compound, and the specific process is as follows:
(1)使用机械臂自动给白炭黑、炭黑N550、滑石粉、氧化锌,硬脂酸五个储料罐自动投料;在电脑生产系统中输入配方的组分、生产的车次数进行智能化投料,下料到混合储蓄罐;(1) Automatically feeding five storage tanks of white carbon black, carbon black N550, talc powder, zinc oxide and stearic acid using a robot arm; inputting the composition of the formula and the number of cars produced in the computer production system for intelligence Feeding, feeding to a mixed storage tank;
(2)智能化自动称取复合型阻燃剂、短切玻璃纤维、高密度聚乙烯、促进剂M、防老剂、硬脂酸锌各自打包(如图1),并命名为A组;交联剂打包为B组;(2) Intelligent automatic weighing of composite flame retardant, chopped glass fiber, high density polyethylene, accelerator M, anti-aging agent, zinc stearate, respectively (as shown in Figure 1), and named as group A; The combination agent is packaged into group B;
(3)按配方比例将相应质量的硅橡胶、顺丁橡胶用AGV智能小车运送到指定地点后用机械臂向真空捏合机投料,开氮气,通蒸汽加热升温到92~98℃保持5min后;使用机械手自动向捏合机投A组料,并同时油料采用自动上料油泵称取相应质量的环氧大豆油、石蜡油及羟基硅油,后升温到135~145℃进行捏合,5~10min;并用机械手自动加入交联剂B组,保持135~145℃进行捏合20~30min后,降温至70℃,后自动放料至混炼机。(3) According to the formula ratio, the corresponding quality of silicone rubber and butadiene rubber are transported to the designated place by AGV smart car, and then the machine is fed with the mechanical kneading machine to open the nitrogen gas, and the steam is heated to 92-98 ° C for 5 min. The robot is used to automatically feed the A component to the kneading machine, and at the same time, the oil is weighed with the corresponding quality of epoxy soybean oil, paraffin oil and hydroxy silicone oil, and then heated to 135-145 ° C for kneading, 5-10 min; The robot automatically added the cross-linking agent group B, and after kneading at 135-145 ° C for 20-30 min, the temperature was lowered to 70 ° C, and then automatically discharged to the mixer.
(4)将捏合机下发的硅橡胶,通过翻胶、打三角包等方式进行混炼,并混炼4~5次后,通过传送带将胶料运输至三辊压延、八辊冷却装置进行压片冷却,最终片厚度为1~3mm。(4) The silicone rubber delivered by the kneading machine is kneaded by means of rubber turning, triangle packing, etc., and kneaded for 4 to 5 times, and then the rubber material is transported by a conveyor belt to a three-roll calendering and eight-roll cooling device. The tablet is cooled, and the final sheet thickness is 1 to 3 mm.
(5)在收叠片的位置,通过AGV智能小车自动运输至相应的胶料库位里面。连硫工段在领用胶料时,只需通过工业平板电脑输入所需胶料的型号,AGV智能小车便能自动在胶 料仓库里面将胶料领出。(5) At the position of the folded piece, it is automatically transported to the corresponding glue storage position by the AGV smart car. When the sulphur section is used, it is only necessary to input the type of the required compound through the industrial tablet. The AGV smart car can automatically be glued. The material is led out in the material warehouse.
(6)产品信息的追溯:在EPR系统中将胶料的信息生成条形码,然后通过打印机进行打印,张贴在每箱胶料的包装箱上,方便生产追溯。混橡车间实现无线网络全覆盖,通过手持终端对胶料的条形码信息进行扫描,可以清楚的知道本箱胶料的门尼、焦烧时间和正硫化时间等参数,然后更好的控制产品质量。(6) Traceability of product information: In the EPR system, the information of the rubber material is generated into a barcode, and then printed by the printer, and posted on the packaging box of each box of rubber to facilitate the traceability of production. The mixed rubber workshop realizes full coverage of the wireless network. By scanning the barcode information of the rubber material through the handheld terminal, the parameters such as Mooney, scorch time and positive curing time of the rubber compound can be clearly known, and then the product quality is better controlled.
实施例1Example 1
原材料准备Raw material preparation
自动化称取白炭黑12份;炭黑16份、滑石粉13份、氧化锌4份,硬脂酸9份,智能化进行投到混合储蓄罐;Automatically weigh 12 parts of silica; 16 parts of carbon black, 13 parts of talc, 4 parts of zinc oxide, 9 parts of stearic acid, and intelligently put into a mixed storage tank;
自动称取复合型阻燃剂13份、短切玻璃纤维2份、高密度聚乙烯6份、促进剂M 0.6份、防老剂2份、硬脂酸锌0.15份各自打包,并命名为A组;交联剂0.2份打包为B组;Automatically weighed 13 parts of composite flame retardant, 2 parts of chopped glass fiber, 6 parts of high density polyethylene, 0.6 part of accelerator M, 2 parts of antioxidant, 0.15 parts of zinc stearate, and were packaged as group A. 0.2 parts of the crosslinking agent are packaged into group B;
硅橡胶制备Silicone rubber preparation
自动称取硅橡胶100份、顺丁橡胶25份并用机械臂向真空捏合机投料,开氮气,通过蒸汽加热升温到92~98℃保持5min后;并使用机械手自动向捏合机投A组料,自动上料油泵称取环氧大豆油4份、石蜡油4份及羟基硅油2份,后升温到135~145℃进行捏合,5~10min后机械手自动加入交联剂B组,保持135~145℃进行捏合20~30min后,降温至70℃,后自动放料至混炼机;100 parts of silicone rubber and 25 parts of butadiene rubber were automatically weighed and fed with a mechanical arm to a vacuum kneader, nitrogen gas was opened, and the temperature was raised to 92 to 98 ° C for 5 minutes by steam heating; and a batch of material was automatically fed to the kneading machine using a robot. The automatic oil pump weighed 4 parts of epoxy soybean oil, 4 parts of paraffin oil and 2 parts of hydroxy silicone oil, and then heated to 135-145 °C for kneading. After 5-10 minutes, the robot automatically added the cross-linking agent group B to maintain 135-145. After kneading at °C for 20 to 30 minutes, the temperature is lowered to 70 ° C, and then automatically discharged to the mixer;
将捏合机下发的硅橡胶,通过翻胶、打三角包等方式进行混炼,并混炼4~5次后,通过传送带将胶料运输至三辊压延、八辊冷却装置进行压片冷却,最终片厚度为1~3mm;The silicone rubber delivered by the kneading machine is kneaded by means of rubber turning, triangle packing, etc., and kneaded for 4 to 5 times, and then the rubber material is transported by a conveyor belt to a three-roll calendering and eight-roll cooling device for tablet cooling. The final sheet thickness is 1 to 3 mm;
在收叠片的位置,通过AGV智能小车自动运输至相应的胶料库位里面。连硫工段在领用胶料时,只需通过工业平板电脑输入所需胶料的型号,AGV智能小车便能自动在胶料仓库里面将胶料领出;At the position of the folded piece, it is automatically transported to the corresponding glue storage position by the AGV smart car. When the sulphur section is used, it is only necessary to input the type of the required rubber material through the industrial tablet computer, and the AGV smart car can automatically take out the rubber material in the rubber warehouse;
实施例2Example 2
原材料准备Raw material preparation
自动化称取白炭黑10份;炭黑12份、滑石粉12份、氧化锌3份,硬脂酸8份,智能化进行投到混合储蓄罐;10 parts of white carbon black were automatically weighed; 12 parts of carbon black, 12 parts of talcum powder, 3 parts of zinc oxide, and 8 parts of stearic acid were intelligently put into a mixed storage tank;
自动称取复合型阻燃剂12份、短切玻璃纤维2份、高密度聚乙烯4份、促进剂M 0.5份、防老剂1份、硬脂酸锌0.15份各自打包,并命名为A组;交联剂0.1份打包为B组;Automatically weighed 12 parts of composite flame retardant, 2 parts of chopped glass fiber, 4 parts of high density polyethylene, 0.5 part of accelerator M, 1 part of antioxidant, 0.15 parts of zinc stearate, and were packaged as group A. 0.1 part of the crosslinking agent is packaged into group B;
硅橡胶制备Silicone rubber preparation
自动称取硅橡胶100份、顺丁橡胶25份并用机械臂向真空捏合机投料,开氮气,通过蒸汽加热升温到92~98℃保持5min后;并使用机械手自动向捏合机投A组料,自动上料油泵称取环氧大豆油4份、石蜡油4份及羟基硅油2份,后升温到135~145℃进行捏合,5~10min后机械手自动加入交联剂B组,保持135~145℃进行捏合20~30min后,降温至70℃,后自动放料至混炼机;100 parts of silicone rubber and 25 parts of butadiene rubber were automatically weighed and fed with a mechanical arm to a vacuum kneader, nitrogen gas was opened, and the temperature was raised to 92 to 98 ° C for 5 minutes by steam heating; and a batch of material was automatically fed to the kneading machine using a robot. The automatic oil pump weighed 4 parts of epoxy soybean oil, 4 parts of paraffin oil and 2 parts of hydroxy silicone oil, and then heated to 135-145 °C for kneading. After 5-10 minutes, the robot automatically added the cross-linking agent group B to maintain 135-145. After kneading at °C for 20 to 30 minutes, the temperature is lowered to 70 ° C, and then automatically discharged to the mixer;
将捏合机下发的硅橡胶,通过翻胶、打三角包等方式进行混炼,并混炼4~5次后,通过传送带将胶料运输至三辊压延、八辊冷却装置进行压片冷却,最终片厚度为1~3mm;The silicone rubber delivered by the kneading machine is kneaded by means of rubber turning, triangle packing, etc., and kneaded for 4 to 5 times, and then the rubber material is transported by a conveyor belt to a three-roll calendering and eight-roll cooling device for tablet cooling. The final sheet thickness is 1 to 3 mm;
在收叠片的位置,通过AGV智能小车自动运输至相应的胶料库位里面。连硫工段在领用胶料时,只需通过工业平板电脑输入所需胶料的型号,AGV智能小车便能自动在胶料仓库里面将胶料领出; At the position of the folded piece, it is automatically transported to the corresponding glue storage position by the AGV smart car. When the sulphur section is used, it is only necessary to input the type of the required rubber material through the industrial tablet computer, and the AGV smart car can automatically take out the rubber material in the rubber warehouse;
实施例3Example 3
原材料准备Raw material preparation
自动化称取白炭黑15份;炭黑18份、滑石粉15份、氧化锌5份,硬脂酸10份,智能化进行投到混合储蓄罐;15 parts of white carbon black were automatically weighed; 18 parts of carbon black, 15 parts of talcum powder, 5 parts of zinc oxide, and 10 parts of stearic acid were intelligently put into a mixed storage tank;
自动称取复合型阻燃剂15份、短切玻璃纤维3份、高密度聚乙烯8份、促进剂M 0.8份、防老剂3份、硬脂酸锌0.25份各自打包,并命名为A组;交联剂0.3份打包为B组;Automatically weighed 15 parts of composite flame retardant, 3 parts of chopped glass fiber, 8 parts of high density polyethylene, 0.8 part of accelerator M, 3 parts of antioxidant, 0.25 parts of zinc stearate, and were packaged as group A. The cross-linking agent 0.3 parts is packaged into group B;
硅橡胶制备Silicone rubber preparation
自动称取硅橡胶100份、顺丁橡胶25份并用机械臂向真空捏合机投料,开氮气,通过蒸汽加热升温到92~98℃保持5min后;并使用机械手自动向捏合机投A组料,自动上料油泵称取环氧大豆油5份、石蜡油5份及羟基硅油2份,后升温到135~145℃进行捏合,5~10min后机械手自动加入交联剂B组,保持135~145℃进行捏合20~30min后,降温至70℃,后自动放料至混炼机;100 parts of silicone rubber and 25 parts of butadiene rubber were automatically weighed and fed with a mechanical arm to a vacuum kneader, nitrogen gas was opened, and the temperature was raised to 92 to 98 ° C for 5 minutes by steam heating; and a batch of material was automatically fed to the kneading machine using a robot. The automatic feeding oil pump weighs 5 parts of epoxy soybean oil, 5 parts of paraffin oil and 2 parts of hydroxy silicone oil, and then heats up to 135-145 °C for kneading. After 5-10 minutes, the robot automatically adds the cross-linking agent group B to maintain 135-145. After kneading at °C for 20 to 30 minutes, the temperature is lowered to 70 ° C, and then automatically discharged to the mixer;
将捏合机下发的硅橡胶,通过翻胶、打三角包等方式进行混炼,并混炼4~5次后,通过传送带将胶料运输至三辊压延、八辊冷却装置进行压片冷却,最终片厚度为1~3mm;The silicone rubber delivered by the kneading machine is kneaded by means of rubber turning, triangle packing, etc., and kneaded for 4 to 5 times, and then the rubber material is transported by a conveyor belt to a three-roll calendering and eight-roll cooling device for tablet cooling. The final sheet thickness is 1 to 3 mm;
在收叠片的位置,通过AGV智能小车自动运输至相应的胶料库位里面。连硫工段在领用胶料时,只需通过工业平板电脑输入所需胶料的型号,AGV智能小车便能自动在胶料仓库里面将胶料领出。At the position of the folded piece, it is automatically transported to the corresponding glue storage position by the AGV smart car. When the sulphur section is used, it is only necessary to input the type of the required compound through the industrial tablet. The AGV smart car can automatically take out the glue in the rubber warehouse.
通过本发明实施例得出的电缆测试结果如表二所示:The cable test results obtained by the embodiment of the present invention are shown in Table 2:
序号Serial number 测试项目名称Test project name 实施例1Example 1 实施例2Example 2 实施例3Example 3
11 拉伸强度MpaTensile strength Mpa 13.513.5 12.612.6 13.813.8
22 断裂伸长率%Elongation at break % 325325 360360 308308
33 200±3℃240h老化后的拉伸强度MpaTensile strength Mpa after aging at 200±3°C240h 12.612.6 11.811.8 12.812.8
44 200±3℃240h老化后的断裂伸长率%Elongation at break after aging at 200±3°C for 240h 308308 343343 298298
55 20℃体积电阻率Ω.M20 ° C volume resistivity Ω.M 1.45×1014 1.45×10 14 1.43×1014 1.43×10 14 1.47×1014 1.47×10 14
66 95±2℃24h吸水性mg/cm3 95±2°C24h water absorption mg/cm 3 1.21.2 1.41.4 1.51.5
77 低温脆化温度℃Low temperature embrittlement temperature °C -42-42 -39-39 -43-43
表二Table II
本发明提升传统硅橡胶电缆料的性能,使其具备高强度、耐高温、耐寒、抗老化、防水防潮、使用寿命长等优异性能,可用于轨道交通车辆动力系统中车体布线,特别添加无氢氧化镁材质的新型复合型阻燃剂,使电缆在火焰条件中可快速熄灭、不延燃,达到高阻燃效果。该新型硅橡胶电缆料制备采用智能化进行配料生产,既节约劳动力成本,又可达到精确配料、满足各批次均一性。The invention improves the performance of the traditional silicone rubber cable material, and has the advantages of high strength, high temperature resistance, cold resistance, anti-aging, waterproof and moisture proof, long service life, etc., and can be used for the vehicle body wiring in the railway vehicle power system, especially added A new type of composite flame retardant made of magnesium hydroxide, which can quickly extinguish the cable in flame condition, does not prolong flame, and achieve high flame retardant effect. The new silicone rubber cable material preparation adopts intelligent batching production, which not only saves labor cost, but also achieves accurate batching and meets batch uniformity.
通过采用硅橡胶绝缘电缆产品替代聚烯烃电缆产品,避免因电缆与网管匹配问题而产生的防火性能降低的隐患。By replacing the polyolefin cable products with silicone rubber insulated cable products, the risk of fire performance degradation caused by the problem of cable and network management matching is avoided.
通过新型高强度硅橡胶绝缘材料的配方研究,以提高单绝缘硅橡胶电缆敷设时的机械余量,代替绝缘护套结构电缆,实现体积小、重量轻的科学发展。Through the formulation research of the new high-strength silicone rubber insulation material, the mechanical margin of the single-insulating silicone rubber cable laying is improved, and the insulating sheath structure cable is replaced, so that the scientific development of small volume and light weight is realized.
单绝缘电缆无护套结构,因此反复弯曲无褶皱现象。避免车辆长期运行中,护套开裂的隐患。The single insulated cable has no sheath structure, so it is repeatedly bent without wrinkles. Avoid the hidden danger of cracking the jacket during long-term operation of the vehicle.
该产品将全力配合贵我国完成“全面质量升级、打造中国装备‘金名片’”的使命。 This product will fully cooperate with your country to complete the mission of “total quality upgrade and build Chinese equipment ‘gold business card”.
尽管已经示出和描述了本发明的实施例,对于本领域的普通技术人员而言,可以理解在不脱离本发明的原理和精神的情况下可以对这些实施例进行多种变化、修改、替换和变型,本发明的范围由所附权利要求及其等同物限定。 While the embodiments of the present invention have been shown and described, it will be understood by those skilled in the art The scope of the invention is defined by the appended claims and their equivalents.

Claims (7)

  1. 一种轨道交通用硅橡胶电缆,其特征在于:包括导体和绝缘层,所述绝缘层覆盖在导体外侧,所述绝缘层表面设置有结构相同的n条凸条,所述相邻凸条之间夹角为40~60°,所述凸条的高度为0.1~0.5mm。A silicone rubber cable for rail transit, comprising: a conductor and an insulating layer, wherein the insulating layer covers an outer side of the conductor, and the surface of the insulating layer is provided with n ridges of the same structure, and the adjacent ribs The angle between the two is 40 to 60°, and the height of the ridge is 0.1 to 0.5 mm.
  2. 实现权利要求1所述的一种轨道交通用硅橡胶电缆的硅橡胶智能化制备方法,其特征在于:包括以下步骤:A method for intelligently preparing a silicone rubber for a silicone rubber cable for rail transit according to claim 1, comprising the steps of:
    按照常规工艺使用机械臂自动给白炭黑、炭黑N550、滑石粉、氧化锌,硬脂酸五个储料罐自动投料;在电脑生产系统中输入配方的组分、生产的车次数进行智能化投料,下料到混合储蓄罐;According to the conventional process, the mechanical arm is used to automatically feed the five storage tanks of white carbon black, carbon black N550, talc powder, zinc oxide and stearic acid; the components of the formula and the number of cars produced in the computer production system are intelligent. Feeding, feeding to a mixed storage tank;
    智能化自动称取复合型阻燃剂、短切玻璃纤维、高密度聚乙烯、促进剂M、防老剂、硬脂酸锌各自打包,并命名为A组;交联剂打包为B组;The intelligent automatic weighing composite flame retardant, chopped glass fiber, high density polyethylene, accelerator M, anti-aging agent and zinc stearate are respectively packaged and named as group A; the crosslinking agent is packaged into group B;
    按配方比例将相应质量的硅橡胶、顺丁橡胶用AGV智能小车运送到指定地点后用机械臂向真空捏合机投料,开氮气,通蒸汽加热升温到92~98℃保持5min后;使用机械手自动向捏合机投A组料,并同时油料采用自动上料油泵称取相应质量的环氧大豆油、石蜡油及羟基硅油,后升温到135~145℃进行捏合,5~10min;并用机械手自动加入交联剂B组,保持135~145℃进行捏合20~30min后,降温至70℃,后自动放料至混炼机;According to the formula ratio, the corresponding quality of silicone rubber and butadiene rubber are transported to the designated place by AGV smart car, and then the machine is used to feed the vacuum kneader with nitrogen gas. After heating, the temperature is raised to 92-98 °C for 5 minutes. The A group material is fed to the kneading machine, and at the same time, the oil is weighed by the automatic feeding oil pump to weigh the corresponding quality epoxy soybean oil, paraffin oil and hydroxy silicone oil, and then heated to 135-145 ° C for kneading, 5-10 min; and automatically added by a robot The cross-linking agent group B is kept at 135-145 ° C for 20-30 min, and then cooled to 70 ° C, and then automatically discharged to the mixer;
    将捏合机下发的硅橡胶,通过翻胶、打三角包等方式进行混炼,并混炼4~5次后,通过传送带将胶料运输至三辊压延、八辊冷却装置进行压片冷却,最终片厚度为1~3mm;The silicone rubber delivered by the kneading machine is kneaded by means of rubber turning, triangle packing, etc., and kneaded for 4 to 5 times, and then the rubber material is transported by a conveyor belt to a three-roll calendering and eight-roll cooling device for tablet cooling. The final sheet thickness is 1 to 3 mm;
    在收叠片的位置,通过AGV智能小车自动运输至相应的胶料库位里面;In the position of the stacking piece, it is automatically transported to the corresponding glue storage position by the AGV smart car;
    连硫工段在领用胶料时,只需通过工业平板电脑输入所需胶料的型号,AGV智能小车便能自动在胶料仓库里面将胶料领出;When the sulphur section is used, it is only necessary to input the type of the required rubber material through the industrial tablet computer, and the AGV smart car can automatically take out the rubber material in the rubber warehouse;
    产品信息的追溯:在EPR系统中将胶料的信息生成条形码,然后通过打印机进行打印,张贴在每箱胶料的包装箱上,方便生产追溯;混橡车间实现无线网络全覆盖,通过手持终端对胶料的条形码信息进行扫描。Traceability of product information: In the EPR system, the information of the rubber material is generated into a barcode, and then printed by the printer, posted on the packaging box of each box of rubber to facilitate the production traceability; the mixed rubber workshop realizes the full coverage of the wireless network, through the handheld terminal Scan the barcode information of the compound.
  3. 根据权利要求2所述的一种轨道交通用硅橡胶电缆的硅橡胶智能化制备方法,其特征在于:所述硅橡胶配方包括以下组分:基料硅橡胶质量份100份;顺丁橡胶25~30份;白炭黑10~15份;炭黑N550 12~18份;复合型阻燃剂12~15份;滑石粉12~15份;氧化锌3~5份;短切玻璃纤维2~3份;硬脂酸8~10份;高密度聚乙烯4~8份;促进剂M 0.5~0.8份;防老剂1~3份;交联剂0.1~0.3份;环氧大豆油4~5份;石蜡油4~5份;羟基硅油2~3份;硬脂酸锌0.15~0.25份。The silicone rubber intelligent preparation method for a silicone rubber cable for rail transit according to claim 2, wherein the silicone rubber formulation comprises the following components: base silicone rubber mass parts 100 parts; butadiene rubber 25 ~ 30 parts; 10 to 15 parts of white carbon black; 12 to 18 parts of carbon black N550; 12 to 15 parts of composite flame retardant; 12 to 15 parts of talc; 3 to 5 parts of zinc oxide; 3 parts; 8 to 10 parts of stearic acid; 4 to 8 parts of high density polyethylene; 0.5 to 0.8 parts of accelerator M; 1 to 3 parts of antioxidant; 0.1 to 0.3 parts of crosslinking agent; 4 to 5 parts of epoxy soybean oil Parts; 4 to 5 parts of paraffin oil; 2 to 3 parts of hydroxy silicone oil; 0.15 to 0.25 parts of zinc stearate.
  4. 根据权利要求3所述的一种轨道交通用硅橡胶电缆的硅橡胶智能化制备方法,其特征在于:所述复合型阻燃剂是以纳米氢氧化铝、六(DOPO羟甲基苯甲基氧基)环三磷腈、聚磷酸铵和聚酯树脂为原料,按质量百分比为60~80∶8~15∶~20∶5∶35~38制备新型复合阻燃材料。The method for intelligently preparing silicone rubber for a silicone rubber cable for rail transit according to claim 3, wherein the composite flame retardant is nanometer aluminum hydroxide and six (DOPO hydroxymethylbenzyl group) The oxy)cyclotriphosphazene, ammonium polyphosphate and polyester resin are used as raw materials, and a novel composite flame retardant material is prepared by mass percentage of 60-80:8-15:20:5:35-38.
  5. 根据权利要求3所述的一种轨道交通用硅橡胶电缆的硅橡胶智能化制备方法,其特征在于:所述交联剂为1,1-二(叔丁基过氧基)环己烷、双(1-甲基-1苯基乙基)过氧化物;1,3-二(叔丁基过氧异丙基)苯中的至少一种。The method for intelligently preparing a silicone rubber for a silicone rubber cable for rail transit according to claim 3, wherein the crosslinking agent is 1,1-di(tert-butylperoxy)cyclohexane. At least one of bis(1-methyl-1phenylethyl) peroxide; 1,3-di(tert-butylperoxyisopropyl)benzene.
  6. 根据权利要求3所述的一种轨道交通用硅橡胶电缆的硅橡胶智能化制备方法,其特征在于:所述短切玻璃纤维长度为0.1~0.2mm,优选长度为0.15mm。The method for intelligently preparing a silicone rubber for a silicone rubber cable for rail transit according to claim 3, wherein the chopped glass fiber has a length of 0.1 to 0.2 mm, preferably a length of 0.15 mm.
  7. 根据权利要求3所述的一种轨道交通用硅橡胶电缆的硅橡胶智能化制备方法,其特征在于:所述防老剂选用:N-苯基-N`-环己基对苯二胺、N-苯基-N`-异丙基-对苯二胺,N-N `-二苯基-对苯二胺、6-二叔丁基对甲酚中至少一种。 The method for preparing an intelligent silicone rubber for a silicone rubber cable for rail transit according to claim 3, wherein the anti-aging agent is selected from the group consisting of: N-phenyl-N'-cyclohexyl p-phenylenediamine, N- phenyl-N'-isopropyl-p-phenylenediamine, NN At least one of `-diphenyl-p-phenylenediamine and 6-di-tert-butyl-p-cresol.
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