WO2018017418A3 - Oligomerization of ethylene to liquid transportation fuels with post synthesis treated zsm-5 catalyst - Google Patents

Oligomerization of ethylene to liquid transportation fuels with post synthesis treated zsm-5 catalyst Download PDF

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Publication number
WO2018017418A3
WO2018017418A3 PCT/US2017/042166 US2017042166W WO2018017418A3 WO 2018017418 A3 WO2018017418 A3 WO 2018017418A3 US 2017042166 W US2017042166 W US 2017042166W WO 2018017418 A3 WO2018017418 A3 WO 2018017418A3
Authority
WO
WIPO (PCT)
Prior art keywords
catalyst
ethylene
oligomerization
transportation fuels
liquid transportation
Prior art date
Application number
PCT/US2017/042166
Other languages
French (fr)
Other versions
WO2018017418A2 (en
Inventor
Jianhua Yao
Bruce Randolph
Original Assignee
Phillips 66 Company
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US15/216,362 external-priority patent/US10214462B2/en
Priority claimed from US15/216,382 external-priority patent/US10214426B2/en
Priority claimed from US15/216,330 external-priority patent/US10207962B2/en
Application filed by Phillips 66 Company filed Critical Phillips 66 Company
Priority to CN201780044094.4A priority Critical patent/CN110088245B/en
Priority to CA3027244A priority patent/CA3027244A1/en
Publication of WO2018017418A2 publication Critical patent/WO2018017418A2/en
Publication of WO2018017418A3 publication Critical patent/WO2018017418A3/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G50/00—Production of liquid hydrocarbon mixtures from lower carbon number hydrocarbons, e.g. by oligomerisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/026—After-treatment
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G57/00—Treatment of hydrocarbon oils, in the absence of hydrogen, by at least one cracking process or refining process and at least one other conversion process
    • C10G57/02—Treatment of hydrocarbon oils, in the absence of hydrogen, by at least one cracking process or refining process and at least one other conversion process with polymerisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/37—Acid treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/38—Base treatment
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/02—Gasoline
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/04—Diesel oil

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

A process for converting ethylene to liquid fuel products utilizing a ZSM-5 catalyst that is essentially free of catalyst metals other than silica and alumina, where the catalyst has been subjected to a post-synthesis treatment comprising contacting the catalyst with a solution comprising at least one of an acid or a base to increase the resistance of the catalyst to accumulation of coke in the zeolite crystallite and extend catalyst life. The base treatment is provided by a weak sodium hydroxide of less than 1 Molar. The acid treatment comprises a hydrogen chloride solution exceeding 2 Molar.
PCT/US2017/042166 2016-07-21 2017-07-14 Oligomerization of ethylene to liquid transportation fuels with post synthesis treated zsm-5 catalyst WO2018017418A2 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
CN201780044094.4A CN110088245B (en) 2016-07-21 2017-07-14 Oligomerization of ethylene to liquid transportation fuels with synthetically-treated ZSM-5catalyst
CA3027244A CA3027244A1 (en) 2016-07-21 2017-07-14 Oligomerization of ethylene to liquid transportation fuels with post synthesis treated zsm-5 catalyst

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
US15/216,362 2016-07-21
US15/216,362 US10214462B2 (en) 2016-07-21 2016-07-21 Oligomerization of ethylene to liquid transportation fuels with post synthesis treated ZSM-5 catalyst
US15/216,382 US10214426B2 (en) 2016-07-21 2016-07-21 Oligomerization of ethylene to liquid transportation fuels with post synthesis treated ZSM-5 catalyst
US15/216,382 2016-07-21
US15/216,330 2016-07-21
US15/216,330 US10207962B2 (en) 2016-07-21 2016-07-21 Oligomerization of ethylene to liquid transportation fuels with post synthesis treated ZSM-5 catalyst

Publications (2)

Publication Number Publication Date
WO2018017418A2 WO2018017418A2 (en) 2018-01-25
WO2018017418A3 true WO2018017418A3 (en) 2019-06-27

Family

ID=60996046

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2017/042166 WO2018017418A2 (en) 2016-07-21 2017-07-14 Oligomerization of ethylene to liquid transportation fuels with post synthesis treated zsm-5 catalyst

Country Status (3)

Country Link
CN (1) CN110088245B (en)
CA (1) CA3027244A1 (en)
WO (1) WO2018017418A2 (en)

Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4511747A (en) * 1984-02-01 1985-04-16 Mobil Oil Corporation Light olefin conversion to heavier hydrocarbons with sorption recovery of unreacted olefin vapor
US4568786A (en) * 1984-04-09 1986-02-04 Mobil Oil Corporation Production of lubricant range hydrocarbons from light olefins
US4675460A (en) * 1983-02-11 1987-06-23 The Broken Hill Propietary Company Limited Process
US5043499A (en) * 1990-02-15 1991-08-27 Mobil Oil Corporation Fluid bed oligomerization of olefins
US6596912B1 (en) * 2000-05-24 2003-07-22 The Texas A&M University System Conversion of methane to C4+ aliphatic products in high yields using an integrated recycle reactor system
EP2272939A1 (en) * 2009-07-03 2011-01-12 BP Corporation North America Inc. Alkene oligomerization process
EP2386354A1 (en) * 2010-05-14 2011-11-16 Bp Oil International Limited Alkene oligomerization process
US20110282092A1 (en) * 2006-03-10 2011-11-17 John Stephen Godsmark Lowering Nitrogen-Containing Lewis Bases In Molecular Sieve Oligomerisation
WO2013013885A2 (en) * 2011-07-25 2013-01-31 Exxonmobil Chemical Patents Inc. Integrated nitrile poison adsorption and desorption system
US20130183230A1 (en) * 2012-01-13 2013-07-18 Rive Technology, Inc. Introduction of mesoporosity into low silica zeolites
US20160176777A1 (en) * 2014-12-19 2016-06-23 Phillips 66 Company Catalyst lifetime

Patent Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4675460A (en) * 1983-02-11 1987-06-23 The Broken Hill Propietary Company Limited Process
US4511747A (en) * 1984-02-01 1985-04-16 Mobil Oil Corporation Light olefin conversion to heavier hydrocarbons with sorption recovery of unreacted olefin vapor
US4568786A (en) * 1984-04-09 1986-02-04 Mobil Oil Corporation Production of lubricant range hydrocarbons from light olefins
US5043499A (en) * 1990-02-15 1991-08-27 Mobil Oil Corporation Fluid bed oligomerization of olefins
US6596912B1 (en) * 2000-05-24 2003-07-22 The Texas A&M University System Conversion of methane to C4+ aliphatic products in high yields using an integrated recycle reactor system
US20110282092A1 (en) * 2006-03-10 2011-11-17 John Stephen Godsmark Lowering Nitrogen-Containing Lewis Bases In Molecular Sieve Oligomerisation
EP2272939A1 (en) * 2009-07-03 2011-01-12 BP Corporation North America Inc. Alkene oligomerization process
EP2386354A1 (en) * 2010-05-14 2011-11-16 Bp Oil International Limited Alkene oligomerization process
WO2013013885A2 (en) * 2011-07-25 2013-01-31 Exxonmobil Chemical Patents Inc. Integrated nitrile poison adsorption and desorption system
US20130183230A1 (en) * 2012-01-13 2013-07-18 Rive Technology, Inc. Introduction of mesoporosity into low silica zeolites
US20160176777A1 (en) * 2014-12-19 2016-06-23 Phillips 66 Company Catalyst lifetime

Also Published As

Publication number Publication date
CA3027244A1 (en) 2018-01-25
CN110088245A (en) 2019-08-02
CN110088245B (en) 2022-10-11
WO2018017418A2 (en) 2018-01-25

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