WO2017222420A3 - Block nanoporous carbon material for storing natural gas or methane, and a method for obtaining said material - Google Patents

Block nanoporous carbon material for storing natural gas or methane, and a method for obtaining said material Download PDF

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Publication number
WO2017222420A3
WO2017222420A3 PCT/RU2017/000412 RU2017000412W WO2017222420A3 WO 2017222420 A3 WO2017222420 A3 WO 2017222420A3 RU 2017000412 W RU2017000412 W RU 2017000412W WO 2017222420 A3 WO2017222420 A3 WO 2017222420A3
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WO
WIPO (PCT)
Prior art keywords
natural gas
increasing
methane
carbon material
volume
Prior art date
Application number
PCT/RU2017/000412
Other languages
French (fr)
Russian (ru)
Other versions
WO2017222420A2 (en
Inventor
Анатолий Алексеевич ФОМКИН
Аслан Юсупович ЦИВАДЗЕ
Олег Евгеньевич АКСЮТИН
Александр Гаврилович ИШКОВ
Евгений Михайлович СТРИЖЕНОВ
Андрей Вячеславович ШКОЛИН
Илья Евгеньевич МЕНЬЩИКОВ
Александр Онуфриевич ШЕВЧЕНКО
Original Assignee
Публичное акционерное общество "Газпром"
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Публичное акционерное общество "Газпром" filed Critical Публичное акционерное общество "Газпром"
Priority to CN201780038228.1A priority Critical patent/CN109689202B/en
Priority to DE112017003150.8T priority patent/DE112017003150T5/en
Priority to JP2018559822A priority patent/JP6972455B2/en
Publication of WO2017222420A2 publication Critical patent/WO2017222420A2/en
Publication of WO2017222420A3 publication Critical patent/WO2017222420A3/en

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28002—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their physical properties
    • B01J20/28011—Other properties, e.g. density, crush strength
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28014—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their form
    • B01J20/2803—Sorbents comprising a binder, e.g. for forming aggregated, agglomerated or granulated products
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28014—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their form
    • B01J20/28042—Shaped bodies; Monolithic structures
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J20/28069—Pore volume, e.g. total pore volume, mesopore volume, micropore volume
    • B01J20/28073—Pore volume, e.g. total pore volume, mesopore volume, micropore volume being in the range 0.5-1.0 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J20/28069—Pore volume, e.g. total pore volume, mesopore volume, micropore volume
    • B01J20/28076—Pore volume, e.g. total pore volume, mesopore volume, micropore volume being more than 1.0 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J20/28078—Pore diameter
    • B01J20/2808—Pore diameter being less than 2 nm, i.e. micropores or nanopores
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/3007—Moulding, shaping or extruding
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/3021—Milling, crushing or grinding
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/3042—Use of binding agents; addition of materials ameliorating the mechanical properties of the produced sorbent
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/3078—Thermal treatment, e.g. calcining or pyrolizing
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C11/00—Use of gas-solvents or gas-sorbents in vessels
    • F17C11/007—Use of gas-solvents or gas-sorbents in vessels for hydrocarbon gases, such as methane or natural gas, propane, butane or mixtures thereof [LPG]
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/20—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising free carbon; comprising carbon obtained by carbonising processes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Analytical Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Thermal Sciences (AREA)
  • General Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Mechanical Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Nanotechnology (AREA)
  • Inorganic Chemistry (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Carbon And Carbon Compounds (AREA)
  • Filling Or Discharging Of Gas Storage Vessels (AREA)

Abstract

The invention relates to activated carbon material for the storage, distribution, and transport of natural gas or methane. The technical result of the claimed invention consists in increasing the amount of natural gas stored by the material per unit volume of the storage system, increasing the bulk density of the adsorptive material, and increasing the packing density of the adsorptive material in specialized portable adsorbers, thereby enabling the storage system to be filled to 95% or more of its volume while maintaining diffusion properties. The technical result of the claimed invention is achieved by creating block nanoporous carbon material that has a number of technological properties: a high bulk density, greater than 600 kg/m3; a special block shape in the form of a cube, rectangular prism, cylinder, three-dimensional sector, or tetrahedron; an optimum combination of mean effective pore width in the material and nanopore volume, which enables a large amount of gas to be stored by the material and allows maximally dense packing of the material in specialized portable adsorbers.
PCT/RU2017/000412 2016-06-22 2017-06-14 Block nanoporous carbon material for storing natural gas or methane, and a method for obtaining said material WO2017222420A2 (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
CN201780038228.1A CN109689202B (en) 2016-06-22 2017-06-14 Bulk porous carbon material for accumulating natural gas or methane and method for producing same
DE112017003150.8T DE112017003150T5 (en) 2016-06-22 2017-06-14 Nanoporous carbon material in blocks for the accumulation of natural gas or methane, and a method for their production
JP2018559822A JP6972455B2 (en) 2016-06-22 2017-06-14 Block-shaped nanoporous carbon material for accumulating natural gas or methane, and methods for obtaining that material

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
RU2016124918A RU2625671C1 (en) 2016-06-22 2016-06-22 Block nanoporous carbon material for accumulation of natural gas, methane and method of its production
RU2016124918 2016-06-22

Publications (2)

Publication Number Publication Date
WO2017222420A2 WO2017222420A2 (en) 2017-12-28
WO2017222420A3 true WO2017222420A3 (en) 2018-02-08

Family

ID=59495402

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/RU2017/000412 WO2017222420A2 (en) 2016-06-22 2017-06-14 Block nanoporous carbon material for storing natural gas or methane, and a method for obtaining said material

Country Status (5)

Country Link
JP (1) JP6972455B2 (en)
CN (1) CN109689202B (en)
DE (1) DE112017003150T5 (en)
RU (1) RU2625671C1 (en)
WO (1) WO2017222420A2 (en)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2701908C2 (en) * 2017-12-25 2019-10-02 Федеральное государственное бюджетное учреждение науки "Федеральный исследовательский центр "Институт катализа им. Г.К. Борескова Сибирского отделения Российской академии наук" (Институт катализа СО РАН, ИК СО РАН) Method of producing carbon material
RU2744400C2 (en) * 2018-12-24 2021-03-09 Публичное акционерное общество "Газпром" Blocky microporous carbon adsorbent and method for production thereof
RU2736586C1 (en) * 2019-07-09 2020-11-18 Федеральное государственное бюджетное образовательное учреждение высшего образования "Тамбовский государственный технический университет" (ФГБОУ ВО "ТГТУ") Molded nanostructured microporous carbon sorbent and a method for production thereof
CN111686735A (en) * 2020-06-30 2020-09-22 中国石油大学(华东) Hydrogenation co-refining catalyst for preparing high-dispersion briquette/heavy oil by modifying carrier coal

Citations (3)

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US4999330A (en) * 1988-03-22 1991-03-12 Universite Du Quebec A Trois-Rivieres High-density adsorbent and method of producing same
WO1994001714A1 (en) * 1992-07-01 1994-01-20 Allied-Signal Inc. Storage of natural gas
US20130190542A1 (en) * 2006-11-08 2013-07-25 The Curators Of The University Of Missouri High surface area carbon and process for its production

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RU2151737C1 (en) * 1997-05-30 2000-06-27 Акционерное общество закрытого типа "Карбид" Method of preparing porous carbon product and porous carbon product obtained by said method
EP1064996A4 (en) * 1998-02-17 2006-05-10 Air Water Inc Activated carbon for adsorption and storage of gaseous compound
GB0506278D0 (en) * 2005-03-29 2005-05-04 British American Tobacco Co Porous carbon materials and smoking articles and smoke filters therefor incorporating such materials
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WO1994001714A1 (en) * 1992-07-01 1994-01-20 Allied-Signal Inc. Storage of natural gas
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Also Published As

Publication number Publication date
CN109689202B (en) 2022-04-01
RU2625671C1 (en) 2017-07-18
JP2019521837A (en) 2019-08-08
JP6972455B2 (en) 2021-11-24
WO2017222420A2 (en) 2017-12-28
DE112017003150T5 (en) 2019-05-29
CN109689202A (en) 2019-04-26

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