WO2017202660A1 - Système d'installations interconnectées destiné à la fabrication de matériaux de construction minéraux et procédé de fonctionnement de ce système - Google Patents

Système d'installations interconnectées destiné à la fabrication de matériaux de construction minéraux et procédé de fonctionnement de ce système Download PDF

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Publication number
WO2017202660A1
WO2017202660A1 PCT/EP2017/061797 EP2017061797W WO2017202660A1 WO 2017202660 A1 WO2017202660 A1 WO 2017202660A1 EP 2017061797 W EP2017061797 W EP 2017061797W WO 2017202660 A1 WO2017202660 A1 WO 2017202660A1
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WO
WIPO (PCT)
Prior art keywords
plant
gas
production
building materials
carbon dioxide
Prior art date
Application number
PCT/EP2017/061797
Other languages
German (de)
English (en)
Inventor
Reinhold ACHATZ
Georg LOCHER
Ralph Kleinschmidt
Original Assignee
Thyssenkrupp Ag
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Filing date
Publication date
Application filed by Thyssenkrupp Ag filed Critical Thyssenkrupp Ag
Publication of WO2017202660A1 publication Critical patent/WO2017202660A1/fr

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Classifications

    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27—FURNACES; KILNS; OVENS; RETORTS
    • F27B—FURNACES, KILNS, OVENS, OR RETORTS IN GENERAL; OPEN SINTERING OR LIKE APPARATUS
    • F27B7/00—Rotary-drum furnaces, i.e. horizontal or slightly inclined
    • F27B7/20—Details, accessories, or equipment peculiar to rotary-drum furnaces
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B7/00—Hydraulic cements
    • C04B7/36—Manufacture of hydraulic cements in general
    • C04B7/364—Avoiding environmental pollution during cement-manufacturing
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B7/00—Hydraulic cements
    • C04B7/36—Manufacture of hydraulic cements in general
    • C04B7/43—Heat treatment, e.g. precalcining, burning, melting; Cooling
    • C04B7/47—Cooling ; Waste heat management
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B7/00—Hydraulic cements
    • C04B7/36—Manufacture of hydraulic cements in general
    • C04B7/43—Heat treatment, e.g. precalcining, burning, melting; Cooling
    • C04B7/47—Cooling ; Waste heat management
    • C04B7/475—Cooling ; Waste heat management using the waste heat, e.g. of the cooled clinker, in an other way than by simple heat exchange in the cement production line, e.g. for generating steam
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27—FURNACES; KILNS; OVENS; RETORTS
    • F27D—DETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS, OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
    • F27D17/00—Arrangements for using waste heat; Arrangements for using, or disposing of, waste gases
    • F27D17/001—Extraction of waste gases, collection of fumes and hoods used therefor
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27—FURNACES; KILNS; OVENS; RETORTS
    • F27D—DETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS, OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
    • F27D17/00—Arrangements for using waste heat; Arrangements for using, or disposing of, waste gases
    • F27D17/001—Extraction of waste gases, collection of fumes and hoods used therefor
    • F27D17/002—Details of the installations, e.g. fume conduits or seals
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P40/00—Technologies relating to the processing of minerals
    • Y02P40/10—Production of cement, e.g. improving or optimising the production methods; Cement grinding
    • Y02P40/121—Energy efficiency measures, e.g. improving or optimising the production methods
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P40/00—Technologies relating to the processing of minerals
    • Y02P40/10—Production of cement, e.g. improving or optimising the production methods; Cement grinding
    • Y02P40/18—Carbon capture and storage [CCS]

Definitions

  • Plant network for the production of mineral building materials and a method for operating the
  • the present invention relates to a plant network for the production of mineral building materials and a method for operating the plant network.
  • Equipment for the production of mineral building materials comprising a kiln for producing mineral building materials and a cooler for cooling the mineral building materials are known in the prior art in a variety of embodiments.
  • a cement plant may be such a plant or component of such a plant.
  • the resulting so-called raw meal is then fired in a kiln, such as a rotary kiln to produce mineral building materials at temperatures of about 1400 - 1450 ° C to the so-called clinker.
  • the clinker is then cooled down to a temperature below 200 ° C in a cooler.
  • Carbon dioxide (CO2) is a greenhouse gas and, when it enters the atmosphere, contributes as one of the major factors in enhancing the greenhouse effect.
  • C0 2 emissions are levied on greenhouse gas emissions in some countries.
  • the present invention is therefore based on the object to further improve the sustainability, in particular the economic and ecological conditions of the overall process and in particular to provide a plant network for the production of mineral building materials, with which it is possible, associated with the production and use of mineral building materials release of C0 2 into the atmosphere and / or cost of producing and / or using mineral building materials to reduce.
  • efforts are being made to reduce C0 2 emissions during the production of mineral building materials.
  • the profitability of the overall process should be further improved. Disclosure of the invention
  • the plant network according to the invention has the advantage that individual plants are combined in a plant network and material flows, in particular gas flow rates, thermal energy and energy flows can be combined.
  • the further use or processing of carbon dioxide is possible before it is released into the atmosphere. In this way, the environmental impact is reduced and / or increases the cost of production of mineral building materials and / or achieved an overall optimum in terms of economic and / or ecological production and / or use of mineral building materials for a plant network.
  • the invention relates to a plant network for the production of mineral building materials with a kiln for producing mineral building materials, a cooler for cooling the mineral building materials, and
  • the plant network has a connected to the gas line system chemical plant and / or biotechnology plant and the plant composite a production plant with a carbon dioxide source and a C0 2 gas line system for at least one of the production plant with a Carbon dioxide-containing gas flow rate, wherein the C0 2 -Gas effetssystem is connected to the gas line system.
  • Another object of the invention relates to a method for operating a plant network for the production of mineral building materials, a kiln for producing mineral building materials, a cooler for cooling the mineral building materials and a gas line system for gases incurred in the production of mineral building materials, and an the gas line system connected chemical plant and / or biotechnology plant and the plant network has a production plant with a carbon dioxide source and a C0 2 -Gastechnischssystem for at least one resulting from the production plant with a carbon dioxide source carbon dioxide gas flow comprises at least a subset of the resulting in the production of mineral building materials gas and / or arising from the production plant with a carbon dioxide source carbon dioxide-containing gas as a useful gas for operation the chemical plant and / or biotechnology plant is used.
  • mineral building materials are understood as meaning building materials which comprise a composition of minerals.
  • Examples include calcium-containing building materials, such as cement, lime, gypsum and calcined clays, as well as already treated residues from production processes, especially from metal production, especially iron and steel production, such as slag (s) and combinations thereof.
  • synthesis gas produced by the process according to the invention are gas mixtures which are used for synthesis.
  • synthesis gas mixtures of N 2 and H 2 for ammonia synthesis and especially gas mixtures containing mainly CO and H 2 or C0 2 and H 2 or CO, C0 2 and H 2 .
  • chemical products can be produced in a chemical plant, which each contain the components of the educt.
  • Chemical products may be, for example, ammonia or methanol or other hydrocarbon compounds.
  • a synthesis gas For the production of ammonia, a synthesis gas must be provided which contains nitrogen and hydrogen in the correct ratio.
  • an air separation plant for the at least partial separation of ambient air into an at least partially oxygen-containing gas and an at least partially nitrogen-containing gas can additionally be provided as the nitrogen source.
  • a hydrogen source for example, an additional plant for hydrogen production, such as a Wasserelektrolysestrom be provided.
  • a synthesis gas consisting essentially of CO and / or CO 2 and -H 2 must be provided, which contains the components carbon monoxide and / or carbon dioxide and hydrogen in the correct ratio. The ratio is often described by the module (H 2 -C0 2 ) / (CO + C0 2 ).
  • the hydrogen can, for example, by an additional attachment to Hydrogen production can be provided.
  • the provision of CO can be carried out with an additional reverse water gas shift reactor (RWGS reactor).
  • RWGS reactor reverse water gas shift reactor
  • the carbon dioxide released during the manufacturing process can serve as a CC source.
  • the C content of the gases resulting from the production of mineral building materials can not be fully utilized, since there is a hydrogen deficit.
  • hydrogen is metered according to the invention, which is formed in a plant for hydrogen production.
  • the hydrogen production is preferably carried out by electrolysis of water, the electrolysis of water is suitably operated with electric power generated from renewable energy.
  • oxygen which can be used in the kiln for the production of mineral building materials.
  • the supply of oxygen is also known as oxyfuel process, in which particularly high flame temperatures can be achieved.
  • the oxyfuel process is applicable to both gaseous and liquid and solid fuels.
  • a biotechnological plant can be used in the invention. This is a plant for the fermentation of the aforementioned gases.
  • the supplied gas flow rates and / or useful gases and / or synthesis gases are used biochemically via a fermentation, wherein products such as alcohols (ethanol, butanol), acetone or organic acids can be produced.
  • products which are produced by fermentation of synthesis gas, are mentioned in the present case only as an example.
  • the hydrogen essentially comes from the water used as a medium during fermentation.
  • the provision of CO can be carried out with an additional reverse water gas shift reactor (RWGS reactor). Consequently, by means of a biotechnological process, it is possible to produce products which contain carbon from the CO and / or CO 2 fraction of the raw gases produced in the production of mineral building materials and hydrogen from the water used in a fermentation process.
  • the performance of the chemical plant or the biotechnological plant is regulated as a function of the gas flow rates supplied to this plant, in particular the used gases and / or the synthesis gases.
  • a major challenge for the chemical plant is the dynamic driving style with changing plant loads.
  • the mode of operation with changing plant loads can be realized, in particular, by the fact that the chemical plant has a plurality of small units connected in parallel, which are switched on or off individually depending on the available useful gas flow rate.
  • the plant network comprises a production plant with a carbon dioxide source and a C0 2 -Gas effetssystem for at least one resulting from the production plant with a carbon dioxide source carbon dioxide-containing gas flow rate, the C0 2 gas line system is connected to the gas line system.
  • a production plant with a carbon dioxide source is, for example, a power plant, a bioethanol plant, a metallurgical plant and / or other plants for producing mineral building materials or a combination thereof.
  • a controllable gas switch means a device with which the supply quantity of gases to the systems arranged in the network can be controlled. For example, according to certain requirements, in particular available gas quantities, gas compositions, energy and electricity, the admission of one and / or several plants in the plant network can take place as required.
  • the plant composite can optionally additionally have an oxygen supply device in the composite, which is connected to the kiln for producing mineral building materials.
  • the oxygen supply device may be the exit of a pipeline, a nozzle, or a combination thereof.
  • This, for example, also known as oxyfuel process method is applicable to both gaseous and liquid and solid fuels.
  • oxyfuel process method is applicable to both gaseous and liquid and solid fuels.
  • the plant composite additionally has a plant for C0 2 separation of the resulting from the production plant with a carbon dioxide source carbon dioxide-containing gas and / or resulting in the production of mineral building materials gas.
  • the plant for C0 2 separation for the separation of C0 2 from the at least one carbon dioxide-containing gas flow stream resulting from the production plant with a carbon dioxide source comprises an absorber device and a desorbing device connected downstream of the absorber device.
  • the plant network additionally has a facility for C0 2 purification and / or C0 2 conditioning, wherein the plant for C0 2 - cleaning and / or C0 2 conditioning with the production plant with a carbon dioxide source and / or the plant is connected to the C0 2 separation.
  • gas purification in particular C0 2 purification and gas conditioning, in particular C0 2 conditioning, means the treatment of the gases for the plants downstream of the plant network.
  • the plant for the C0 2 purification may comprise a C0 2 WASHER for the separation of C0. 2
  • the plant network additionally comprises a gasification device for concentration of C0 2 -Anteils, wherein the gasification C0 2 -Waschstrom for separating C0 2 from the at least one arising from the production plant with a carbon dioxide source carbon dioxide-containing gas flow upstream is arranged.
  • the plant network additionally comprises an S0 2 separation device for separating S0 2 from the at least one carbon dioxide-containing gas flow stream resulting from the production plant with a carbon dioxide source, in particular the S0 2 separation device has a cooling device.
  • the system composite additionally comprises a water vapor separator.
  • the system composite additionally comprises a CGy separator, in particular a membrane filter.
  • the plant network additionally comprises a CGy compressor for compressing carbon dioxide-containing gas arising from the production plant with a carbon dioxide source and / or gas produced during the production of the mineral building materials.
  • the plant network additionally comprises a plant for hydrogen production and a H 2 gas line system for arising from the plant for hydrogen production hydrogen-containing gas flow rates.
  • the plant for hydrogen production is an electrolysis plant for water electrolysis.
  • the electrolysis plant for water electrolysis is connected by means of an oxygen return line with the oxygen supply device.
  • the oxygen produced during the electrolysis of water can be supplied to the kiln for producing mineral building materials, for example via the oxygen return line and the oxygen supply device.
  • the water electrolysis plant is preferably electrically connected to an energy store and at least part of the electrical energy necessary for water electrolysis is taken from the energy store.
  • external power can be used, preferably from renewable sources.
  • the gas line system in the flow direction after the controllable gas switch is connected to the H 2 gas line system via a mixing device for producing one of gases arising from the production plant with a carbon dioxide source and / or in the production of mineral Building materials and resulting hydrogen-containing gases from the plant for hydrogen production existing mixed gases and are the chemical plant and / or biotechnology plant supplied gas flow rates controlled by the controllable gas switch.
  • the H 2 - gas line system on a controllable H 2 gas soak and are the chemical plant and / or biotechnology plant supplied hydrogen-containing gas flow rates controllable by means of the controllable H 2 gas soak.
  • a controllable H 2 gas switch is understood to mean a device with which the supply quantity of H 2 gases to the systems arranged in the network can be controlled.
  • the admission of one or more plants in the plant network with H 2 can take place as required.
  • system network can additionally have a H 2 storage for storing at least a portion of emitted hydrogen-containing gases from the plant for hydrogen production, wherein the H 2 storage is connected to the H 2 gas line system.
  • the system network additionally has an energy store, in particular an electrochemical store to cover at least part of the power requirement of the system network.
  • the plant composite additionally comprises an air separation plant for at least partially decomposing ambient air into an at least partially oxygen-containing gas and an at least partially nitrogen-containing gas with an oxygen-containing gas leading line and a nitrogen-containing gas leading line.
  • the oxygen-containing gas leading pipe is connected to the oxygen supply means by means of an oxygen return pipe.
  • Oxygen-containing gas in the oxygen-containing gas-carrying line can be supplied to the kiln for producing mineral building materials, for example, via the oxygen return line and the oxygen supply device.
  • Nitrogen-containing gas of the nitrogen-containing gas-carrying line can be supplied in particular as a nitrogen source of a downstream system of the plant network, such as the chemical plant and / or the biotechnology plant.
  • the nitrogen-containing gas-carrying line is connected by means of a mixing device with the H 2 gas line system, in particular for the production of ammonia.
  • the system network additionally comprises a reverse water gas shift system and a CO gas line system for carbon monoxide-containing gas flow streams arising from the reverse water gas shift system, the reverse water gas shift system following in the flow direction the controllable gas switch is connected to the gas line system and the H 2 gas line system and that the gas flow and / or biotechnology plant supplied gas flow rates are controlled by the controllable gas switch.
  • a reverse water gas shift plant is understood to mean a plant which comprises carbon dioxide-containing gas flow streams, in particular gases which are produced during the production of the mineral building materials, from the carbon dioxide fraction by a reverse water gas shift reaction (C0 2 + H 2 CO + H 2 O) at least partially convert to carbon monoxide.
  • the hydrogen required for the reaction may be provided from a hydrogen production plant.
  • the CO gas line system has a controllable CO gas switch and the carbon monoxide-containing gas flow streams supplied to the chemical plant and / or biotechnology plant can be controlled by means of the controllable CO gas switch.
  • a controllable CO gas switch is understood to mean a device with which the supply quantity of CO gases to the plants arranged in the network can be controlled. For example, according to certain requirements, the admission of one or more plants in the plant network with CO can take place as required.
  • the plant network additionally has a biomass storage for storing biomass, in particular from the biotechnology plant, wherein at least a subset of the biomass from the biomass storage and / or the biotechnology plant of the secondary fuel supply of the plant network is supplied.
  • the plant network additionally has a material storage.
  • a material storage are a methanol storage, a synthetic natural gas (SNG) storage, substitute natural gas storage, FT-fuel storage (Fischer-Tropsch synthesis fuels), ethanol storage.
  • the plant network in particular the kiln for producing mineral building materials, is additionally supplied with an oxygen stream with an oxygen supply device.
  • the plant network has a kiln for producing mineral building materials, a cooler for cooling the mineral building materials, a gas line system for gases that are produced in the production of mineral building materials, a connected to the gas line system biotechnology plant and a Sekundärbrennstoffzucht landmark observed for at least partial operation of the plant network, in particular the kiln for producing mineral building materials with secondary fuels, wherein at least a subset of the resulting in the production of mineral building materials gas is used as a useful gas for operating the biotechnology plant.
  • At least a portion of the resulting in the production of mineral building materials gas is mixed with at least a subset of resulting hydrogen-containing gases from the plant for hydrogen production and the mixed gas is used as a useful gas for operating the chemical plant and / or biotechnology plant.
  • At least part of the useful gas after gas conditioning and / or gas purification is used as synthesis gas for the production of chemical products and / or supplied to the biotechnology plant and used for biochemical processes.
  • a synthesis gas is produced from at least a subset of the gas produced during the production of the mineral building materials after gas conditioning and / or gas purification.
  • At least part of the synthesis gas produced after gas conditioning and / or gas purification is used for the production of chemical products or supplied to the biotechnology plant and used for biochemical processes.
  • the power of the chemical plant and / or the biotechnology plant is regulated as a function of the amount of useful gas supplied to this plant (s).
  • a plant network for the production of mineral building materials for the production of mineral building materials, a kiln for the production of mineral building materials, a cooler for cooling the mineral building materials, a gas line system for gases resulting from the production of mineral building materials, a to the Gas line system connected to chemical plant and / or biotechnology plant, at least one connected to the gas line system controllable gas switch for dividing the chemical plant and / or biotechnology plant gas flow rates and as a plant for hydrogen production an electrolysis plant for water electrolysis and a H 2 - gas line system emitted from the electrolysis plant for water electrolysis Has hydrogen-containing gas flow rates, a) at least a subset of the resulting in the production of mineral building materials gas with b) at least a subset of the d c) mixed and d) wherein the mixed gas is used as a useful gas for operation of the chemical plant and / or biotechnology plant and e) wherein at least a portion of the resulting from the electrolysis plant for electrolysis water
  • the plant network additionally comprises an air separation plant for at least partially decomposing ambient air into an at least partially oxygen-containing gas and an at least partially nitrogen-containing gas with an oxygen-containing gas leading line and a nitrogen-containing gas Having at least a portion of the at least partially oxygen-containing gas from the air separation plant in the plant composite for the production of mineral building materials, in particular is recycled to the kiln for producing mineral building materials and / or at least a subset of the at least partially nitrogen-containing from the air separation plant Gas mixed with at least a portion of the emitted from the electrolysis plant for water electrolysis hydrogen-containing gas, in particular for the production of ammonia.
  • the Gas line system in the flow direction after the controllable gas switch is connected to the H 2 gas line system via a H 2 mixing device for producing a mixed gas comprising gases, arising in the production of mineral building materials and resulting hydrogen-containing gases from the plant for hydrogen production and a reverse water gas shift system and a CO gas line system for emitted from the reverse Wassergas shift system carbon monoxide gas flow rates, the reverse Water gas shift system in the flow direction after the controll
  • the hydrogen content of the C0 2 - H 2 -Nutzgasstromes and / or CO-H 2 -Nutzgasstromes and / or C0 2 -CO-H 2 -Nutzgasstromes to a ratio is set in the range of 5% by volume to 95% by volume based on the total volume of the associated Nutzgasstroms.
  • the mixed gas is used as CO-H 2 -Nutzgas and / or CO-H 2 -Nutzgas and / or C0 2 -C0-H 2 -Nutzgas for operating the chemical plant and / or biotechnology plant and / or e ) wherein at least a portion of the resulting from the reverse water gas shift plant carbon monoxide-containing gas is used as CO-Nutzgas for operating the chemical plant and / or biotechnology plant.
  • the hydrogen content of the C0-H 2 -Nutzgasstromes and / or CO-H 2 -Nutzgasstromes and / or C0 2 -CO-H 2 -Nutzgasstromes to a ratio in Range of 5 vol% to 95 vol% based on the total volume of the associated Nutzgasstromes set.
  • the inventive method for operating a plant network for the preparation of mineral building materials is / are the Mischnutzgas and / or the C0 2 -Nutzgas and / or the C0 2 -H 2 -Nutzgas and / or the CO useful gas and / or the C0-H 2 -Nutzgas and / or the C0-C0 2 -H 2 -Nutzgas processed, wherein the treatment comprises a gas purification and / or a gas conditioning.
  • the inventive method for operating a plant network for the preparation of mineral building materials is / are the Mischnutzgas and / or the C0 2 -Nutzgas and / or the C0 2 -H 2 -Nutzgas and / or the CO useful gas and / or the C0-H 2 -NG and / or the C0-C0 2 -H 2 -Nutzgas processed, wherein the processing comprises a compression.
  • the power of the chemical plant and / or the biotechnology plant depending on the / n plant (s) supplied Nutzgasmenge of mixed commercial gas and / or C0 2 -Nutzgas and / or C0 2 -H 2 -Nutzgas and / or CO-Nutzgas and / or CO-H 2 -Nutzgas and / or the CO-CO 2 -H 2 -Nutzgas regulated.
  • a plant network for the production of mineral building materials comprising a kiln for producing mineral building materials, a cooler for the cooling of mineral building materials, and a gas line system for gases resulting from the production of mineral building materials, and a to the Has gas line system connected chemical plant and / or biotechnology plant and the plant network comprises a production plant with a carbon dioxide source and a C0 2 -Gastechnischssystem for at least one resulting from the production plant with a carbon dioxide carbon dioxide gas stream, at least a subset of the resulting in the production of mineral building materials gas and / or arising from the production plant with a carbon dioxide source carbon dioxide-containing gas as a useful gas for the operation of the chemical plant and / or biotechnology plant is used.
  • the plant network in particular the kiln for producing mineral building materials, is additionally supplied with an oxygen stream with an oxygen supply device.
  • the method according to the invention for operating a plant network for the production of mineral building materials of the plant network additionally comprising a plant for hydrogen production and a H 2 gas line system for arising from the plant for hydrogen production hydrogen-containing gas flow rates, at least a subset of the in the production of mineral building materials accumulating gas and / or arising from the production plant with a carbon dioxide source carbon dioxide containing gas mixed with at least a subset of resulting hydrogen-containing gases from the plant for hydrogen production and the mixed gas is used as a useful gas for operating the chemical plant and / or biotechnology plant.
  • At least a portion of the useful gas is used after a gas conditioning and / or gas purification as synthesis gas for the production of chemical products and / or the biotechnology plant is fed and used for biochemical processes.
  • a gas conditioning and / or gas purification as synthesis gas for the production of chemical products and / or the biotechnology plant is fed and used for biochemical processes.
  • a plant network for the production of mineral building materials is from at least a subset of the resulting in the production of mineral building materials gas and / or arising from the production plant with a carbon dioxide source carbon dioxide-containing gas accumulation after gas conditioning and / or Gas purification produced a synthesis gas.
  • At least part of the synthesis gas produced after gas conditioning and / or gas purification is used for the production of chemical products or is supplied to the biotechnology plant and is used for biochemical processes.
  • At least a subset of the biofuel biomass is supplied as secondary fuel with the secondary fuel supply to the plant network, in particular the kiln for producing mineral building materials and / or the plant network additionally has a biomass storage for storing biomass, in particular from the biotechnology plant, wherein at least a subset of the biomass stored in the biomass storage is supplied as a secondary fuel with the secondary fuel supply means the plant network, in particular the kiln for producing mineral building materials.
  • the supply of at least a subset of accumulating in the biotechnology plant and / or biomass stored in the biomass storage as secondary fuel with the secondary fuel supply in the system network, in particular the kiln for production mineral building materials controlled depending on the calorific value of the biomass.
  • compressors for compressing the gases may be arranged.
  • the subject matter of the invention also encompasses all combinations of the aforementioned embodiments, in particular of the plants within the plant network.
  • Fig. 1 shows a schematic, highly simplified block diagram of a plant network for the production of mineral building materials according to an embodiment of the invention.
  • FIG. 1 shows an overview of a plant network for producing mineral building materials.
  • the plant network comprises a kiln 1 for the production of mineral building materials, a cooler 2 for cooling the mineral building materials and a gas pipe system 3 for gases that are produced in the production of mineral building materials.
  • a chemical plant 4 and a biotechnology plant 5 is connected to the gas line system 3.
  • the gas line system 3 comprises a controllable gas diverter 6 which divides the gas flow streams supplied to the chemical plant 4 and / or biotechnology plant 5.
  • an oxygen supply device 14 is additionally shown via which air with an increased oxygen content and / or oxygen can be supplied to the kiln 1.
  • the plant network may have a plant for hydrogen production 7, 7 'and a H 2 gas line system 8 for from the plant for hydrogen production 7, T accumulating hydrogen-containing gas flow rates.
  • the gas line system 3 may be connected via a mixing device, in particular arranged in the flow direction after the controllable gas switch (6).
  • mixed gases consisting of gases obtained in the production of mineral building materials and resulting hydrogen-containing gases from the plant for hydrogen production 7, T mixed and the chemical plant 4 and / or biotechnology plant 5 are supplied.
  • the H 2 gas line system 8 may comprise a controllable H 2 -gas diverter 9, wherein the hydrogen-containing gas flow streams supplied to the chemical plant 4 and / or the biotechnology plant 5 can be controlled by means of the controllable H 2 -gas diverter 9.
  • the H 2 gas line system 8 for storing at least a partial amount of resulting hydrogen-containing gases from the plant for generating hydrogen 7, T include a H 2 memory 10, wherein the H 2 memory 10 is connected to the H 2 - gas line 8.
  • the plant for hydrogen production 7, T can also as an electrolysis plant for water electrolysis 7 'may be formed, wherein the electrolysis plant for water electrolysis 7' is connected to the oxygen supply device 14 by means of an oxygen return line 15.
  • the plant network may comprise a reverse water gas shift plant 11 (RWGS plant) and a CO gas line system 12 for carbon monoxide-containing gas flow streams arising from the reverse water gas shift plant 11.
  • RWGS plant reverse water gas shift plant
  • CO gas line system 12 for carbon monoxide-containing gas flow streams arising from the reverse water gas shift plant 11.
  • the reverse water gas shift system 11 is connected in the flow direction after the controllable gas switch 6 with the gas line system 3 and the H 2 gas line system 8.
  • the plant composite can have a plant for C0 2 separation 16 of the gas produced during the production of the mineral building materials.
  • the plant composite can additionally have a plant for C0 2 cleaning 17, T and / or a plant for C0 2 conditioning 18, wherein the plant for C0 2 cleaning 17, T and / or the system for C0 2 conditioning 18 with the system for C0 2 separation 16 are connected / is.
  • the CO gas line system 12 may have a controllable CO gas switch 13, wherein by means of the controllable CO gas switch 13, the the gas plant 4 and / or the biotechnology plant 5 supplied carbon monoxide-containing gas flow rates are controllable.
  • the plant network may additionally have an energy storage 19, in particular an electrochemical storage to cover at least part of the power requirement of the system network.
  • the plant network can include a plant for producing ammonia 26, which is connected to the plant network by means of the nitrogen-containing gas-carrying line 25.
  • the plant network, a production plant with a carbon dioxide source 21 and a C0 2 - gas line system 22 for at least one resulting from the production plant with a carbon dioxide source 21 carbon dioxide-containing Gas quantities comprise electricity, wherein the C0 2 -Gastechnischssystem 22 is connected to the gas line system 3.
  • the plant network may additionally have a secondary fuel supply device 23 for supplying biomass for at least partial operation of the plant network, in particular the kiln 1 for producing mineral building materials with secondary fuels.
  • the plant network may have a biomass storage 24 for storing biomass, in particular from the biotechnology plant 5, wherein at least a subset of the Biomass from the bio mass storage 24 and / or the biotechnology plant 5 can be supplied as a secondary fuel via the Sekundärbrennstoffzu classroom Road 23 the kiln 1 for the production of mineral building materials.
  • the isosceles trapezoidal elements exemplified are compressors for compressing gas (s).

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Ceramic Engineering (AREA)
  • Environmental & Geological Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • General Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Biodiversity & Conservation Biology (AREA)
  • Ecology (AREA)
  • Environmental Sciences (AREA)
  • Public Health (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Cultivation Of Plants (AREA)

Abstract

La présente invention concerne un système d'installations interconnectées destiné à la fabrication de matériaux de construction minéraux, comprenant un four (1) destiné à la fabrication de matériaux de construction minéraux, un dispositif de refroidissement (2) destiné au refroidissement des matériaux de construction minéraux, et un système de conduites de gaz (3) pour des gaz se produisant lors de la fabrication des matériaux de construction minéraux, le système d'installations interconnectées présentant une installation de chimie (4) et/ou une installation de biotechnologie reliée(s) au système de conduites de gaz (3), et le système d'installation interconnectées comportant une installation de production pourvue d'une source de dioxyde de carbone (21) et un système de conduites de gaz CO2 (22) destiné à au moins un flux massique de gaz contenant du dioxyde de carbone, se produisant à partir de l'installation de production pourvue d'une source de dioxyde de carbone (21), le système de conduites de gaz CO2 (22) étant relié au système de conduites de gaz (3).
PCT/EP2017/061797 2016-05-24 2017-05-17 Système d'installations interconnectées destiné à la fabrication de matériaux de construction minéraux et procédé de fonctionnement de ce système WO2017202660A1 (fr)

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DE102016209029.1A DE102016209029A1 (de) 2016-05-24 2016-05-24 Anlagenverbund zur Herstellung mineralischer Baustoffe sowie ein Verfahren zum Betreiben des Anlagenverbundes

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DE102021210114A1 (de) 2021-09-14 2022-09-22 Thyssenkrupp Ag Verfahren zur Reduktion der Kohlendioxidemission einer Emittervorrichtung
BE1029753B1 (de) 2021-09-14 2023-04-11 Thyssenkrupp Ind Solutions Ag Verfahren zur Reduktion der Kohlendioxidemission einer Emittervorrichtung

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WO2014009487A1 (fr) * 2012-07-12 2014-01-16 Khd Humboldt Wedag Gmbh Procédé de traitement de biomasse dans une installation de fabrication de ciment et installation correspondante
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