WO2017194292A1 - A cosmetic composition - Google Patents
A cosmetic composition Download PDFInfo
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- WO2017194292A1 WO2017194292A1 PCT/EP2017/059591 EP2017059591W WO2017194292A1 WO 2017194292 A1 WO2017194292 A1 WO 2017194292A1 EP 2017059591 W EP2017059591 W EP 2017059591W WO 2017194292 A1 WO2017194292 A1 WO 2017194292A1
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- WIPO (PCT)
- Prior art keywords
- composition
- polymer
- hydrophobically modified
- modified silica
- silicone
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Classifications
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/25—Silicon; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/0241—Containing particulates characterized by their shape and/or structure
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/06—Emulsions
- A61K8/064—Water-in-oil emulsions, e.g. Water-in-silicone emulsions
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/29—Titanium; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/896—Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate
- A61K8/898—Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate containing nitrogen, e.g. amodimethicone, trimethyl silyl amodimethicone or dimethicone propyl PG-betaine
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q13/00—Formulations or additives for perfume preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q15/00—Anti-perspirants or body deodorants
Definitions
- the present invention is in the field of cosmetic compositions, in particular compositions comprising antiperspirant actives.
- the present invention more particularly relates to providing enhanced and long lasting perfumery impact to the skin surface in addition to the anti-perspirancy benefits.
- the present invention relates to cosmetic compositions, which are formulated at low pH in the range of 2 to 6.
- One class of such compositions are those that contain antiperspirant actives. These actives are added to compositions to reduce perspiration on application to the surface of the body, particularly to the underarm regions of the human body.
- Antiperspirant actives are typically astringent metal salts such as aluminium or zirconium salts. Such salts are incorporated in compositions at low pH in the range of 2 to 6. It has been found that in addition to looking for good anti-perspirancy benefits especially in the underarm region, consumers also seek to have enhanced and long lasting perfume impact from such surfaces. Usually these benefits are delivered through what are known as deodourant compositions.
- compositions that in addition to anti-perspirancy also deliver enhanced positive odour impact, after the composition is applied to the skin.
- the present inventors have now developed a composition in which such low pH antiperspirant actives can be incorporated along with perfumery molecules and these can be delivered in a composition comprising an emulsion comprising hydrophobically modified silica, amino-functionalised silicone and water by the incorporation of a film forming polymer of select classes.
- a cosmetic composition comprising an emulsion comprising
- the cosmetic composition further comprising
- polymer a urethane polymer, aliphatic polyurethane resin, silicone resin, polyquaternium or co-polymers thereof;
- pH of the composition at 25 °C is from 2 to 6.
- the pH of the composition is from 2 to 4.
- a method of delivering long lasting perfumery impact from a cosmetic composition comprising the step of topically applying to the skin the composition of the first aspect.
- a Cosmetic Composition is meant to include a composition for topical application to the skin of mammals, especially humans.
- a composition is preferably of the leave-on type.
- a leave-on composition is meant a composition that is applied to the desired skin surface and left on for a period of time (say from one minute to 24 hours) after which it may be wiped or rinsed off with water, usually during the regular course of personal washing.
- the composition may also be formulated into a product which is applied to a human body for improving the appearance, cleansing, odor control or general aesthetics.
- the composition of the present invention can be in the form of a liquid, lotion, cream, foam, scrub, gel or stick form and may be delivered through a roll- on device or using a propellant containing aerosol can.
- Skin as used herein is meant to include skin on any part of the body (e.g., neck, chest, back, arms, underarms, hands, legs, buttocks and scalp) especially the underarms.
- the cosmetic composition of the invention is delivered through an emulsion comprising hydrophobically modified silica, amino functionalized silicone; and water.
- the cosmetic composition further comprises a perfumery molecule, a film forming polymer selected from an acrylate polymer, a methacrylate polymer, a urethane polymer, aliphatic polyurethane resin, silicone resin, polyquaternium or co-polymers thereof.
- the pH of the composition at 25°C is from 2 to 6.
- the pH is preferably from 2 to 4.
- hydrophobically modified silica that may be used in this invention is that the same is suitable for use in an antiperspirant composition by consumers at a pH from 2 to 6.
- the hydrophobically modified silica comprises at least one of the following groups:
- the hydrophobically modified silica most preferably comprises
- R is a C 4 to Cis alkyl group, more preferably a CsH alkyl group.
- the silica particles comprise the group represented by formula III. More preferably, the silica particles comprise octylsilane (sold under the name Aerosil R805, Aerosil R974, Aerosil R202, Aerosil R805, Aerosil R812 from Evonik; HDK H1 13L, HDK H15, HDK H20, HDK H30 for Wacker.
- the hydrophobically modified silica according to the present invention can be of different sizes and shapes.
- Particle size refers to particle diameter unless otherwise stated. Diameter is meant to mean the largest measurable distance on a particle in the event a well-defined sphere is not generated. Particle size can be measured, for example, by dynamic light scattering (DLS) or transmission electron microscope (TEM).
- the volume average primary particle size of hydrophobically modified silica is often from 1 nm to 100 nm, more preferably from 5 nm to 70 nm, most preferably from 5 nm to 20 nm, including all ranges subsumed therein.
- the antiperspirant composition of the present invention comprises from 0.05 to 20% by weight of the hydrophobically modified silica, more preferably from 0.05 to 15%, further more preferably from 0.1 to 10%, most preferably from 0.2 to 5% based on the total weight of the antiperspirant composition and including all ranges subsumed therein.
- the cosmetic composition of this invention comprises an amino functionalized silicone.
- amino functionalized silicone is meant a silicone containing at least one primary, secondary or tertiary amine group, or a quaternary ammonium group.
- the primary, secondary, tertiary and/or quaternary amine groups may either form part of the main polymer chain or more preferably be carried by a side or pendant group carried by the polymeric backbone.
- Such polymers are described, for example, in US 4 185 087.
- the amino functionalized silicone has the general formula:
- each R is independently H, OH, OCH3 or C1-4 alkyl
- each R 1 is independently OR, or a C1-4 alkyl
- each R 2 is independently OR, or a C1-4 alkyl
- each x is independently an integer from 1 to 4 and each y is greater than zero and independently an integer to yield a polymer having a molecular weight from 500 to 1 million, and preferably, from 750 to 25,000, and most preferably from 1 ,000 to 15,000.
- silicone cationic polymers represented by the formula:
- Z is hydrogen, phenyl, OH or a C1-C10 alkyl group
- n+m are integers whereby the sum of n+m ranges from 1 to 3,500, and preferably from 10 to 160;
- each R 2 is independently a monovalent radical of formula -CqH 2q L where each q is independently a number from 2 to 10 and L is an amine or a quaternized amine represented by one of the following groups:
- each R 3 is independently hydrogen, phenyl, benzyl or a Ci to Ci 2 alkyl; and each A " is independently fluoride, chloride, bromide or iodide anion.
- Still other amino functionalized silicone suitable for use includes those having the formula:
- each R 4 is independently a Ci to C 2 o alkyl or C 2 to C 2 o alkenyl
- R 5 is a divalent C1-C18 group
- r is an integer from 2 to 20;
- s is an integer from 15 to 75.
- the amino functionalized silicone has the INCI designation amodimethicone.
- the amodimethicone is represented by formula (V) and made commercially available, for example, as DC 8500 by Dow Corning. It is also within the scope of this invention for the amino functionalized silicone to comprise trimethylsilylamodimethicone represented by formula (VI).
- the cosmetic composition of the present invention comprises amino functionalized silicone in an amount from 0.01 to 25%, more preferably from 0.03 to 15%, more preferably still from 0.05 to 10%, most preferably from 0.1 to 5% by total weight of the composition and including all ranges subsumed therein.
- the weight ratio of hydrophobically modified silica to amino functionalized silicone is from 10:1 to 1 :3, more preferably from 5:1 to 1 :3 and most preferably from 2:1 to 1 :2..
- the cosmetic composition of the invention comprises an emulsion.
- the water content is from 10 to 80%, more preferably from 15 to 70%, most preferably from 20 to 60% based on the total weight of the cosmetic composition and including all ranges subsumed therein.
- the cosmetic composition of the invention comprises a perfumery molecule which may be included in the composition as a fragrance.
- fragment is defined as a mixture of odoriferous components, optionally mixed with a suitable solvent diluent or carrier, which is employed to impart a desired odor.
- a perfumery molecule or a group of perfumery molecules formulated as a perfume is generally incorporated in most personal care compositions. Any perfumery molecule which is cosmetically acceptable may be included in the composition of the invention.
- Fragrance components and mixtures thereof may be obtained from natural products such as essential oils, absolutes, resinoids, resins and concretes, as well as synthetic products such as hydrocarbons, alcohols, aldehydes, ketones, ethers, carboxylic acids, esters, acetals, ketals, nitriles and the like, including saturated and unsaturated compounds, aliphatic, carbocyclic and heterocyclic compounds.
- Suitable characteristics of fragrances can include one or more of lavender, violet, rose, jasmin, pine, woody, floral, fruity, lemon, lime, apple, peach, raspberry, strawberry, banana, plum, apricot, vanilla, pear, eucalyptus, aromatic, aldehydic, tutti frutti, oriental, sweet, amber, Paola, Muguet, Citronella (lime), and the like.
- Typical fragrance components which may be are one or more of: 2-methoxy naphthalene; allyl cyclohexane propionate; alpha-citronellal; alpha-ionone; alpha- santalol; alpha- terpineol; ambrettolide; amyl benzoate; amyl cinnamate; amyl cinnamic aldehyde; aurantiol; benzaldehyde; benzophenone; benzyl acetate; benzyl salicylate; beta- caryophyllene; beta-methyl naphthyl ketone; cadinene; cavacrol; cedrol; cedryl acetate; cedryl formate; cinnamyl cinnamate; cis-jasmone; coumarin; cyclamen aldehyde; cyclohexyl salicylate; d-limonene; delta-nonalactone
- Suitable solvents, diluents or carriers for perfumes as mentioned above are, for example, ethanol, isopropanol, diethylene glycol monoethyl ether, dipropyl glycol, triethyl citrate and the like.
- fragrance components used in cosmetic compositions are cyclic and acyclic terpenes and terpenoids. These materials are based upon isoprene repeating units. Examples include alpha and beta pinene, myrcene, geranyl alcohol and acetate, camphene, dl-limonene, alpha and beta phellandrene, tricyclene, terpinolene, allocimmane, geraniol, nerol, linanool, dihydrolinanool, citral, ionone, methyl ionone, citronellol, citronellal, alpha terpineol, beta terpineol, alpha fenchol, borneol, isoborneol, camphor, terpinen- 1 -ol, terpin-4-ol, dihydroterpineol, methyl chavicol, anethole, 1 ,4- and 1 ,8-
- the perfumery molecule is preferably selected from a compound having an aldehyde, an alcohol, or an ester functional group or combinations thereof.
- Amounts of the fragrance may range from 0.0001 to 5%, usually from 0.001 to 1.5%, more usually from 0.5 to 0.8% by weight of the personal care composition.
- the cosmetic composition of the invention comprises a film forming polymer selected from an acrylate polymer, a methacrylate polymer, a urethane polymer, aliphatic polyurethane resin, silicone resin, polyquaternium or co-polymers thereof.
- Film-forming polymer refers to a polymer which is capable of forming a cohesive and continuous covering over the hair and/or skin when applied to the surface.
- Contact angle means the angle at which a water/vapor interface meets a solid surface at a temperature of 25°C. Such an angle may be measured with a goniometer or other water droplet shape analysis systems with water droplet of 5 ⁇ and at 25°C.
- the requirement for film-forming polymer, as per the present invention is that the film-forming polymer is suitable to be employed in cosmetic composition.
- the film- forming polymer, for use in the present invention preferably has a contact angle of at least 85°.
- the film forming polymer is generally water insoluble and is distinct from water soluble polymers like cross-linked polyacrylic acid polymers sold as Carbopol which are commonly used in cosmetic product as thickeners.
- the skilled person knows what is meant by the water-insolubility of a polymer.
- the solubility of the polymer in water at 25 °C is less than 1 wt%, more preferably less than 0.5 wt%, even more preferably less than 0.1 wt% and most preferably less than 0.01 wt%.
- Especially preferred film forming polymers are acrylate co-polymer, silicone resin and a urethane- acrylic co-polymer.
- film forming polymers which may be used in the present invention are KOBO-50N, KOBO-HPRC, KOBO-5400 available from Kobo; Dow-UPU-1 from Dow, lnduchem-U6, lnduchem-U15, lnduchem-U1946 from Induchem; PIB 1000 from Evonik and MQ-1640 from Dow Corning.
- the film forming polymer is preferably included in 0.5-10%, more preferably 0.5 to 8%, even further more preferably 1-6%, most preferably 2-6% by weight of the composition.
- the inventors believe the oil in water emulsion formed by the combination of the hydrophobic silica and the amino functionalized silicone with water in combination with the acidic condition in water continuous phase will prevent the film forming polymer to form a film directly on the skin surface. Rather, it is believed that the film forming can be better dispersed in the silicone oil which can be stable in the very acidic condition. Thus, the film forming polymer in the silicone oil phase can form a better film on the skin surface ensuring that the fragrance molecules are held for a longer time even at very acidic conditions and ensure enhanced resistance to rinsing with water,
- the cosmetic composition of the invention works in the pH range of 2 to 6.
- the benefits of the present invention can be utilized when the composition comprises an antiperspirant skin care active which are generally acidic substances.
- the antiperspirant actives which could be used herein are astringent active salts including aluminium, zirconium and mixed aluminium/zirconium salts. Such salts include both inorganic salts and salts with organic anions and complexes.
- the antiperspirant actives are aluminium, zirconium and aluminium/zirconium halides and halohydrate salts, such as chlorohyd rates and activated aluminium chlorohydrates.
- Zirconium actives can usually be represented by the empirical general formula: in which z is a variable in the range of from 0.9 to 2.0 so that the value 2n-nz is zero or positive, n is the valency of B, and B is selected from the group consisting of chloride, other halide, sulfamate, sulfate and mixtures thereof. Possible hydration to a variable extent is represented by whbO.
- B represents chloride and the variable z lies in the range from 1.5 to 1 .87.
- zirconium salts are usually not employed by themselves, but as a component of a combined aluminium and zirconium-based antiperspirant.
- aluminium and zirconium salts may have coordinated and/or bound water in various quantities and/or may be present as polymeric species, mixtures or complexes.
- zirconium hydroxy salts often represent a range of salts having various amounts of the hydroxy group.
- Aluminium zirconium chlorohydrate may be particularly preferred.
- Antiperspirant complexes based on the above-mentioned astringent aluminium and/or zirconium salts can be employed.
- the complex often employs a compound with a carboxylate group, and advantageously this is an amino acid.
- suitable amino acids include dl-tryptophan, dl-3-phenylalanine, dl-valine, dl-methionine and ⁇ - alanine, and preferably glycine which has the formula CH2(NH2)COOH.
- AZG actives generally contain aluminium, zirconium and chloride with an Al/Zr ratio in a range from 2 to 10, especially 2 to 6, an AI/CI ratio from 2.1 to 0.9 and a variable amount of glycine. Actives of this type are available from suppliers that include Summit Reheis. In one preferred embodiment the active is enhanced activity or activated aluminium/zirconium halohydrate, in particular, activated aluminium-zirconium tetrachlorohydrex glycine (AAZG).
- AAZG activated aluminium-zirconium tetrachlorohydrex glycine
- the antiperspirant skin care active is preferably selected from aluminium chlorohydrate, aluminum-zirconium tetrachlorohydrex glycine complex, aluminum-zirconium octachlorohydrex glycine complex, aluminum-zirconium pentachlorohydrate, aluminum sesquichlorohydrate or mixtures thereof. More preferred antiperspirant actives are aluminum-zirconium tetrachlorohydrex glycine complex, aluminum-zirconium octachlorohydrex glycine complex, aluminum-zirconium pentachlorohydrate, aluminum sesquichlorohydrate or mixtures thereof.
- the antiperspirant active comprises water soluble calcium salt, such as calcium chloride. It is particularly preferred that the antiperspirant active comprises water soluble calcium salt. Further preferably the antiperspirant active comprises an amino acid, such as glycine. It is especially preferred that the antiperspirant active is heated with the water soluble calcium salt and preferably amino acid prior to or during formulation of the antiperspirant composition. In this way, the antiperspirant active may become 'activated', that is to say, have higher antiperspirant efficacy.
- the molar ratio of calcium to aluminium is at least 1 :20, more preferably at least 1 :15 and most preferably at least 1 :10.
- an amino acid such as glycine
- the molar ratio of amino acid to aluminium is at least 1 :20 and more preferably at least 1 :10.
- the antiperspirant active comprises an aluminium sesquichlorohydrate salt of formula AI2OH4.4CI1.6 to AI2OH4.9CI1.1 and more preferably of formula AI2OH4.7CI1.3 to AI2OH4.9CI1.1.
- Such actives are particularly suited to use in the compositions of the present invention.
- the composition comprises antiperspirant active in an amount from 0.1 to 40%, more preferably from 1 to 30%, most preferably from 5 to 20% by total weight of the antiperspirant composition and including all ranges subsumed therein.
- the antiperspirant active is dissolved in the water present in the composition giving an aqueous solution of the antiperspirant active.
- an optical particle preferably a whitening particle
- the optical particle is preferably one of a polymer bead or an inorganic particle with a refractive index higher than 1.8.
- a polymer bead is included, it is preferably a hollow sphere.
- Suitable hollow spheres are those made of a styrene/ acrylate co-polymer, polyurethane, or polyethylene most preferably a styrene/ acrylate co-polymer.
- Polymer beads which may be included in the composition of the invention preferably have a particle size in the range of 80 to 700 nm.
- the optical particles are inorganic particles with a refractive index higher than 1.8, preferably higher than 2.0, more preferably higher than 2.5.
- Preferred inorganic particles as per the invention are titanium dioxide, zinc oxide, boron nitride, iron oxide, mica, mica coated with titanium dioxide or mixtures thereof, more preferred being titanium dioxide, zinc oxide, boron nitride or mixtures thereof.
- Most preferred inorganic particle is titanium dioxide.
- the optical particles for inclusion in the composition of the invention preferably have a mean particle size from 15 nm to 30 micron, preferably 15 nm to 1 micron, more preferably 80 to 400 nm.
- titanium dioxide are available as Korons1 171 from Korons and KowetTiO 203975 from Sensient, MT700Z from Tayca; and JTTO MS-7 from KOBO.
- the optical particle is preferably included in 0.1 to 20%, more preferably 0.2 to 10%, further more preferably 0.5 to 8% by weight of the composition.
- the composition is substantially free of surfactants.
- substantially free of, as used herein means less than 1.5%, and preferably less than 1.0%, and more preferably less than 0.75% and more preferably still less than 0.5%, and even more preferably less than 0.1 % and most preferably from 0.0 to 0.01 % by weight, based on total weight of the cosmetic composition, including all ranges subsumed therein.
- composition of the present invention can comprise a wide range of other optional components.
- CTFA Personal care Ingredient Handbook Second Edition, 1992, which is incorporated by reference herein in its entirety, describes a wide variety of non- limiting personal care and pharmaceutical ingredients commonly used in the skin care industry, which are suitable for use in the compositions of the present invention. Examples include: antioxidants, binders, biological additives, buffering agents, colorants, optical particles, thickeners, polymers, astringents, conditioners, exfoliating agents, pH adjusters, preservatives, natural extracts, essential oils, skin sensates, skin soothing agents, and skin healing agents.
- compositions of the present invention when comprising anti-perspirant actives are particularly suitable for dispensing from cosmetic roll-on dispensers that involve a container with a roll-on ball on a dispensing end.
- a cosmetic composition of the invention preferably has a viscosity at 25 °C of from 1000 to 200000 cps, preferably 3000 to 60000 cps.
- the above viscosity is as measured using the following procedure.
- the invention further provides for a method of delivering long lasting perfumery impact from a cosmetic composition
- a cosmetic composition comprising the step of topically applying to the skin the composition of the invention.
- the skin surface may thereafter be rinsed with water 10 minutes to 24 hours after the step of applying the composition.
- compositions were prepared using BASE 1 as shown in table 1 below.
- the compositions were tested for perfumery impact 0, 7, and 24 hours after application of the composition on a vitro skin substrate using the following protocol.
- MQ1640 is a film forming polymer of the silicone resin class sourced from Dow Corning.
- Table 1 indicates that the perfume impact for compositions of the invention having the film forming polymer (Examples 1 to 3) provides for enhanced perfume impact at 7 and 24 hours compared to compositions without film forming polymer (Examples A to C).
- compositions were prepared using BASE 1 or BASE 2 as shown in table 2 below using bioskin samples similar to the Examples 1 to 3.
- compositions were tested for perfumery impact after the end of a certain number of hours by a panel of 10 people to give an opinion as to the sample where the perfume impact was better.
- compositions D and 4 were compared for perfumery impact by a panel of 10 persons at the end of 48 hours of storage who graded the samples to give an opinion as to which sample had a higher perfume impact.
- Table 3 The data is summarized in Table 3 below: Table - 3
- Table 3 The data in Table 3 above indicates that seven out of ten people preferred the composition as per the invention for perfume impact while three were uncertain.
- the compositions E and F were tested for perfumery impact by a panel of 10 persons at the end of 72 hours of storage who graded the samples to give an opinion as to which sample had a higher perfume impact.
- Table 4 The data is summarized in Table 4 below:
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Abstract
Description
Claims
Priority Applications (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AU2017264375A AU2017264375B2 (en) | 2016-05-11 | 2017-04-24 | A cosmetic composition |
MYPI2018704149A MY186757A (en) | 2016-05-11 | 2017-04-24 | A cosmetic composition |
MX2018013628A MX2018013628A (en) | 2016-05-11 | 2017-04-24 | A cosmetic composition. |
BR112018072303-7A BR112018072303B1 (en) | 2016-05-11 | 2017-04-24 | COSMETIC COMPOSITION AND METHOD FOR DELIVERING LASTING IMPACT OF PERFUMERY |
ZA2018/06868A ZA201806868B (en) | 2016-05-11 | 2018-10-15 | A cosmetic composition |
PH12018502215A PH12018502215A1 (en) | 2016-05-11 | 2018-10-17 | A cosmetic composition |
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
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CN2016081646 | 2016-05-11 | ||
CNPCT/CN2016/081646 | 2016-05-11 | ||
EP16179890.5 | 2016-07-18 | ||
EP16179890 | 2016-07-18 |
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WO2017194292A1 true WO2017194292A1 (en) | 2017-11-16 |
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PCT/EP2017/059591 WO2017194292A1 (en) | 2016-05-11 | 2017-04-24 | A cosmetic composition |
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AU (1) | AU2017264375B2 (en) |
BR (1) | BR112018072303B1 (en) |
MX (1) | MX2018013628A (en) |
PH (1) | PH12018502215A1 (en) |
WO (1) | WO2017194292A1 (en) |
ZA (1) | ZA201806868B (en) |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2020094489A1 (en) * | 2018-11-08 | 2020-05-14 | Unilever Plc | Antiperspirant compositions comprising fragrance |
WO2020094490A1 (en) * | 2018-11-08 | 2020-05-14 | Unilever Plc | Antiperspirant compositions and methods |
US10959933B1 (en) | 2020-06-01 | 2021-03-30 | The Procter & Gamble Company | Low pH skin care composition and methods of using the same |
US11110049B2 (en) | 2017-06-23 | 2021-09-07 | The Procter & Gamble Company | Composition and method for improving the appearance of skin |
US11583488B2 (en) | 2020-06-01 | 2023-02-21 | The Procter & Gamble Company | Method of improving penetration of a vitamin B3 compound into skin |
US11622963B2 (en) | 2018-07-03 | 2023-04-11 | The Procter & Gamble Company | Method of treating a skin condition |
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WO2011056623A1 (en) * | 2009-11-06 | 2011-05-12 | Avon Products, Inc. | Methods and compositions for preventing or reducing frizzy appearance of hair |
WO2013064367A1 (en) | 2011-11-04 | 2013-05-10 | Unilever N.V. | Cosmetic composition |
WO2013064365A1 (en) * | 2011-11-04 | 2013-05-10 | Unilever N.V. | Cosmetic composition |
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2017
- 2017-04-24 MX MX2018013628A patent/MX2018013628A/en unknown
- 2017-04-24 WO PCT/EP2017/059591 patent/WO2017194292A1/en active Application Filing
- 2017-04-24 BR BR112018072303-7A patent/BR112018072303B1/en active IP Right Grant
- 2017-04-24 AU AU2017264375A patent/AU2017264375B2/en active Active
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2018
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Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US11110049B2 (en) | 2017-06-23 | 2021-09-07 | The Procter & Gamble Company | Composition and method for improving the appearance of skin |
US11622963B2 (en) | 2018-07-03 | 2023-04-11 | The Procter & Gamble Company | Method of treating a skin condition |
WO2020094489A1 (en) * | 2018-11-08 | 2020-05-14 | Unilever Plc | Antiperspirant compositions comprising fragrance |
WO2020094490A1 (en) * | 2018-11-08 | 2020-05-14 | Unilever Plc | Antiperspirant compositions and methods |
US10959933B1 (en) | 2020-06-01 | 2021-03-30 | The Procter & Gamble Company | Low pH skin care composition and methods of using the same |
US11583488B2 (en) | 2020-06-01 | 2023-02-21 | The Procter & Gamble Company | Method of improving penetration of a vitamin B3 compound into skin |
US11911498B2 (en) | 2020-06-01 | 2024-02-27 | The Procter & Gamble Company | Low pH skin care composition and methods of using the same |
Also Published As
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ZA201806868B (en) | 2020-01-29 |
BR112018072303A2 (en) | 2019-02-12 |
MX2018013628A (en) | 2019-04-25 |
AU2017264375A1 (en) | 2018-11-01 |
PH12018502215A1 (en) | 2019-08-05 |
AU2017264375B2 (en) | 2019-06-06 |
BR112018072303B1 (en) | 2021-11-16 |
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