WO2017172044A3 - Composite de noir de carbone pyrolytique et procédé de production dudit composite - Google Patents

Composite de noir de carbone pyrolytique et procédé de production dudit composite Download PDF

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Publication number
WO2017172044A3
WO2017172044A3 PCT/US2017/016541 US2017016541W WO2017172044A3 WO 2017172044 A3 WO2017172044 A3 WO 2017172044A3 US 2017016541 W US2017016541 W US 2017016541W WO 2017172044 A3 WO2017172044 A3 WO 2017172044A3
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WIPO (PCT)
Prior art keywords
carbon black
making
same
pyrolytic carbon
black composite
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PCT/US2017/016541
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English (en)
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WO2017172044A2 (fr
Inventor
Amit K. Naskar
Mariappan Parans Paranthaman
Original Assignee
Ut-Battelle, Llc
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Publication date
Priority claimed from US15/056,184 external-priority patent/US10320000B2/en
Application filed by Ut-Battelle, Llc filed Critical Ut-Battelle, Llc
Publication of WO2017172044A2 publication Critical patent/WO2017172044A2/fr
Publication of WO2017172044A3 publication Critical patent/WO2017172044A3/fr

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09CTREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C1/00Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
    • C09C1/44Carbon
    • C09C1/48Carbon black
    • C09C1/482Preparation from used rubber products, e.g. tyres
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09CTREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C1/00Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
    • C09C1/44Carbon
    • C09C1/48Carbon black
    • C09C1/487Separation; Recovery
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01GCAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
    • H01G11/00Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
    • H01G11/22Electrodes
    • H01G11/30Electrodes characterised by their material
    • H01G11/32Carbon-based
    • H01G11/34Carbon-based characterised by carbonisation or activation of carbon
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01GCAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
    • H01G11/00Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
    • H01G11/22Electrodes
    • H01G11/30Electrodes characterised by their material
    • H01G11/32Carbon-based
    • H01G11/44Raw materials therefor, e.g. resins or coal
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/58Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/583Carbonaceous material, e.g. graphite-intercalation compounds or CFx
    • H01M4/587Carbonaceous material, e.g. graphite-intercalation compounds or CFx for inserting or intercalating light metals
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00Crystal-structural characteristics
    • C01P2002/70Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
    • C01P2002/72Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by d-values or two theta-values, e.g. as X-ray diagram
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00Crystal-structural characteristics
    • C01P2002/80Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70
    • C01P2002/85Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70 by XPS, EDX or EDAX data
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00Particle morphology
    • C01P2004/01Particle morphology depicted by an image
    • C01P2004/04Particle morphology depicted by an image obtained by TEM, STEM, STM or AFM
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00Physical properties of inorganic compounds
    • C01P2006/12Surface area
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00Physical properties of inorganic compounds
    • C01P2006/14Pore volume
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00Physical properties of inorganic compounds
    • C01P2006/16Pore diameter
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00Physical properties of inorganic compounds
    • C01P2006/16Pore diameter
    • C01P2006/17Pore diameter distribution
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00Physical properties of inorganic compounds
    • C01P2006/40Electric properties
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01GCAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
    • H01G11/00Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
    • H01G11/22Electrodes
    • H01G11/30Electrodes characterised by their material
    • H01G11/32Carbon-based
    • H01G11/38Carbon pastes or blends; Binders or additives therein
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/052Li-accumulators
    • H01M10/0525Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/054Accumulators with insertion or intercalation of metals other than lithium, e.g. with magnesium or aluminium
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Power Engineering (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Carbon And Carbon Compounds (AREA)
  • Inert Electrodes (AREA)
  • Battery Electrode And Active Subsutance (AREA)

Abstract

La présente invention concerne un procédé de récupération de noir de carbone comprenant l'étape consistant à obtenir un matériau source carboné contenant du noir de carbone. Le matériau source carboné est mis en contact avec un bain de sulfonation pour produire un matériau sulfoné. Le matériau sulfoné est pyrolysé pour produire un produit contenant du noir de carbone constitué d'une phase matrice vitreuse carbonée dans laquelle du noir de carbone est dispersé. La pyrolyse peut être menée à une température de 1100 °C à 1490 °C. La présente invention concerne également un procédé de fabrication d'une électrode de batterie et une batterie lithium-ion ou sodium-ion.
PCT/US2017/016541 2016-02-29 2017-02-03 Composite de noir de carbone pyrolytique et procédé de production dudit composite WO2017172044A2 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US15/056,184 US10320000B2 (en) 2013-07-18 2016-02-29 Pyrolytic carbon black composite and method of making the same
US15/056,184 2016-02-29

Publications (2)

Publication Number Publication Date
WO2017172044A2 WO2017172044A2 (fr) 2017-10-05
WO2017172044A3 true WO2017172044A3 (fr) 2017-12-07

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Application Number Title Priority Date Filing Date
PCT/US2017/016541 WO2017172044A2 (fr) 2016-02-29 2017-02-03 Composite de noir de carbone pyrolytique et procédé de production dudit composite

Country Status (1)

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WO (1) WO2017172044A2 (fr)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2024117254A (ja) * 2023-02-17 2024-08-29 住友ゴム工業株式会社 カーボンブラックの判別方法

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20140038034A1 (en) * 2012-08-06 2014-02-06 Ut-Battelle, Llc Lignin-based active anode materials synthesized from low-cost renewable resources
WO2014162267A1 (fr) * 2013-04-02 2014-10-09 Israzion Ltd. Procédé de conversion de déchets solides de type textile ou plastique en charbon actif
US20150021525A1 (en) * 2013-07-18 2015-01-22 Ut-Battelle, Llc Pyrolytic carbon black composite and method of making the same
US20150221947A1 (en) * 2012-08-29 2015-08-06 Sumitomo Bakelite Co., Ltd. Negative-electrode material, negative-electrode active material, negative electrode, and alkali metal ion battery
CA2908768A1 (fr) * 2015-10-16 2017-04-16 The Governors Of The University Of Alberta Stockage d'energie electrique

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20140038034A1 (en) * 2012-08-06 2014-02-06 Ut-Battelle, Llc Lignin-based active anode materials synthesized from low-cost renewable resources
US20150221947A1 (en) * 2012-08-29 2015-08-06 Sumitomo Bakelite Co., Ltd. Negative-electrode material, negative-electrode active material, negative electrode, and alkali metal ion battery
WO2014162267A1 (fr) * 2013-04-02 2014-10-09 Israzion Ltd. Procédé de conversion de déchets solides de type textile ou plastique en charbon actif
US20150021525A1 (en) * 2013-07-18 2015-01-22 Ut-Battelle, Llc Pyrolytic carbon black composite and method of making the same
CA2908768A1 (fr) * 2015-10-16 2017-04-16 The Governors Of The University Of Alberta Stockage d'energie electrique

Non-Patent Citations (4)

* Cited by examiner, † Cited by third party
Title
ARIYADEJWANICH ET AL.: "Preparation and characterization of mesoporous activated carbon from waste tires", CARBON, vol. 41, no. 1, 25 October 2002 (2002-10-25), pages 157 - 164, XP004398612 *
HUANG ET AL.: "Pyrolysis treatment of waste tire powder in a capacitively coupled RF plasma reacto r", ENERGY CONVERSION AND MANAGEMENT, vol. 50, 21 December 2008 (2008-12-21), pages 611 - 617, XP025922271 *
LI ET AL.: "Amorphous monodispersed hard carbon micro-spherules derived from biomass as a high performance negative electrode material for sodium-ion batteries", J OURNAL OF MATERIALS CHEMISTRY A, vol. 3, 23 October 2014 (2014-10-23), pages 71 - 77, XP055447298 *
WEN ET AL.: "Expanded graphite as superior anode for sodium-ion batteries", NATURE COMMUNICATIONS, vol. 5, 4 June 2014 (2014-06-04), pages 1 - 10, XP055447296 *

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Publication number Publication date
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