WO2017155535A1

WO2017155535A1 - Chain having an electroless nickel coating containing hard particles

Info

Publication number: WO2017155535A1
Application number: PCT/US2016/021701
Authority: WO
Inventors: Matthew E. Junker; Mohammadreza BATENIGHASRMANESH; Yumin Wang
Original assignee: Borgwarner Inc.
Priority date: 2016-03-10
Filing date: 2016-03-10
Publication date: 2017-09-14
Also published as: EP3426821A1; JP2019509398A; US20190071780A1; EP3426821A4; CN108699697A

Abstract

A method of applying a wear resistant surface to chain links and pins of a chain by the application of an electroless nickel coating containing hard particles. The coating reduces the friction on the chain links and associated chain components, such as pins, bushings, rockers and other components. The hard particles contained in the coating may be a carbide or nitride formed using the following elements: silicon, boron, chromium or vanadium. The coating may contain a combination of carbide or nitrides. The hard particles may additional include natural diamond and/or synthetic diamond like carbon (DLC) particles.

Description

CHAIN HAVING AN ELECTROLESS NICKEL COATING

CONTAINING HARD PARTICLES

BACKGROUND OF THE INVENTION

FIELD OF THE INVENTION The invention pertains to the field of chains. More particularly, the invention pertains to a chain having an electroless nickel coating containing hard particles for improved resistance to corrosion and wear.

DESCRIPTION OF RELATED ART

Electroless nickel (EN) plating is an auto-catalytic chemical technique used to deposit a layer of nickel-phosphorus or nickel-boron alloy on a solid workpiece which may be made of metal or plastic. The process relies on the presence of a reducing agent, for example hydrated sodium hypophosphite (NaP0₂H₂- ¾0) which reacts with the metal ions to deposit metal on the workpiece. Unlike electroplating, it is not necessary to pass an electric current through the solution to form a deposit on the workpiece. This plating technique is used to prevent corrosion and wear. EN techniques can also be used to manufacture composite coatings by suspending powder in a bath.

Another coating that may be applied to an article or workpiece is a plasma vapor deposition (PVD). PVD is a vacuum deposition method which may be used to produce thin films on an article. PVD uses a physical process, such as heating or sputtering, to produce a vapor of material which is then deposited on the article or object.

SUMMARY OF THE INVENTION

A method of improving the wear and corrosion characteristics of a chain by applying a wear resistant electroless nickel coating containing hard particles to chain links and pins of a chain. The coating reduces the friction on the chain links and associated chain components, such as pins, bushings, rockers and other components. The hard particles contained in the coating may be a carbide or nitride formed using the following elements: silicon, boron, chromium or vanadium. The coating may contain a combination of carbide or nitrides. The hard particles may additional include natural diamond and/or synthetic diamond-like carbon (DLC) particles.

BRIEF DESCRIPTION OF THE DRAWING

Figs, la- lb show a method of coating chain components with an electroless nickel coating containing hard particles.

Fig. 2 shows a schematic of a chain link.

Fig. 3 shows a section of the chain link.

Fig. 4 shows a graph of wear performance of a chain with Ni-SiC electroless coated chain links and carbo-nitrided pins vs. a chain without coated links with carbo-nitrided pins, with performance measured by the percent of chain elongation and test hours.

Fig. 5 shows a graph of wear performance of a chain with Ni-SiC electroless coated links and vanadium carbide coated pins vs. chain without coated links with vanadium carbide coated pins, with performance measured by the percent of chain elongation and test hours.

Fig. 6 shows a graph of chain efficiency vs. input speed for chains with and without

electroless nickel coated links.

Fig. 7a shows a top view of a chain with rollers.

Fig. 7b shows a side view of the chain with rollers of Figure 7a.

Fig. 7c shows a section of the chain with rollers along line 7c-7c of Figure 7a.

Fig. 8a shows a top view of a chain without rollers.

Fig. 8b shows a side view of the chain without rollers of Figure 8a.

Fig. 8c shows a section of the chain without rollers along line 8c-8c of Figure 8a. DETAILED DESCRIPTION OF THE INVENTION

Chain links and chain pins when assembled together form a chain. Chains undergo wear due to friction between the chain links and other engine components, friction between associated chain links of the same chain and friction between the links and associated chain components, which can include bushings, rollers, pins and rocker pins.

An example of a chain 38 with rollers is shown in Figures 7a-7c and an example of a chain 48 without rollers is shown in Figures 8a-8c. This friction also occurs at the interface between the apertures of the chain links and bushings, the apertures and rollers or apertures and pins. One example of a chain link and its associated components is shown in Figures 7a-

7c. Figures 7a-7c show an example of a chain with rollers. The chain links 30, 31 of the chain 38 each have a body 36, 37 and apertures 34. The apertures 34 receive bushings 35 and pins 33 to connect link 30 to link 31 together into a chain. A roller 32 is also present on the pin 33 between the chain links 30. It should be noted that the shape of the link is for example purposes only. Deviations in the shape of the link may be possible and would be within the scope of the invention.

Figures 8a- 8c shows an example of a chain without rollers and is another example of chain links and associated components. The chain links 40, 41 of the chain 48 each have a body 46, 47 and apertures 44. The apertures 44 receive bushings 45 and pins 43 to connect link 40 to link 41 together into a chain. It should be noted that the shape of the link is for example purposes only. Deviations in the shape of the link may be possible and would be within the scope of the invention.

Figures 2-3 show yet another example of a chain link 10 and its associated components, such as pins 14 and/or bushings 15. The chain link 10 has a body 11 with teeth 12 and apertures 13. The apertures 13 may receive bushings 15, or just receive pins 14 to connect multiple chain links together into a chain (not shown). While a round pin is shown, any shaped pin including a rocker pin and rollers may be placed in the apertures 13. Furthermore, it should be noted that the shape of the link is for example purposes only. Deviations in the shape of the link may be possible and would be within the scope of the invention. In the present invention, a chain link 10, 30, 31, 40, 41 and/or associated components such as chain pins 14, 33, 43, roller 32, and bushings 15, 35, 45 receive an electroless nickel coating which has embedded hard particles. The electroless nickel coating with hard particles creates a wear resistant and low friction coating which decreases wear and friction in the portions of the chain that contact each other or contact other chain or engine components, improving the performance of the chain. Furthermore, by applying the electroless nickel coating with hard particles to the link surfaces that come into contact with engine components, such as arms, guides and sprockets, the wear performance (e.g. resisting wear) is improved. Referring to Figure 3, the base material 20 of the chain link 10, 30, 31, 40, 41 is of a first material indicated by the angled lines. In one embodiment, the base material may be steel and/or other ferrous alloys. In alternate embodiment, the base material may be one or a combination of: aluminum, aluminum alloy, copper, copper alloy, magnesium alloy, titanium alloys, zinc alloy, or non-metallic substrates such as ceramics. The electroless nickel coating 21 is applied to the surface of the base material 20 by a method described below. The electroless nickel coating 21 comprises a second material different than the first material, and includes hard particles 22 indicated by the hexagons in Figure 3.

A first step in the method of applying an electroless nickel coating including hard particles to a base material of the chain link and/or chain components is to rinse the base metal of the chain links and/or components with water. Tap water at room temperature is preferably used at this step (step 100), although it will be understood that the water could be filtered and recycled, or heated or cooled, and solvents or surfactants might be added, as might be desired for a particular application. The rinsing of the chain links and/or chain components may take place for at least two minutes. The rinse time may be longer than two minutes and may be influenced by the rinse quality, temperatures and agitation.

Then, the chain links and/or chain components are cleaned using an alkaline agent (step 102) to prevent and cleanse any dirt and remove any foreign contaminants including rust. The alkaline cleaning agent may contain a combination of hydroxide, carbonate, silicates, phosphates and other organic surfactants and is applied at a temperature of 160- 180°F for 5 minutes. The alkaline agent is then rinsed from the chain links and/or chain components, again preferably using tap water at room temperature (step 104). The alkaline agent is rinsed from the chain links and/or chain components for two minutes or greater.

After the chain links and/or chain components are rinsed, they undergo electro- cleaning. In this process, the chain links and/or chain components are connected to a positive (anode) side of a rectifier.

The electro-cleaning tales place between 165°F-185°F for 5 minutes at 30 amps per square foot (ASF) (step 106). Alkaline cleaning blends use an electrolyte which contains a mixture of alkaline material to provide high conductivity and alkalinity. Due to the lower cost, sodium salts are frequently used. However, potassium based electro-cleaners have better solubility, lower electrical resistance, and better throwing power.

Prior to immersing the chain links and/or chain components into the acid bath of step 112, it is important to remove any contaminants that cause destabilization of the acid bath. Therefore, the chain links and/or chain components preferably rinsed at least twice after the cleaning, again preferably with tap water at room temperature (steps 108, 110). The advantage to rinsing the chain links and/or chain components twice is to get rid of any solution that may have stayed with the chain links and/or chain components which might be carried to the next step.

Next, the chain links and/or chain components are immersed in an acid bath (step 112). The acid bath may contain sulfuric and/or hydrochloric acid, which is activated by diluting the acid at room temperature with distilled water until an appropriate

concentration range is reached. The concentration range is preferably 5-10% for sulfuric acid and 30-50% for hydrochloric acid.

The chain links and/or chain components are then rinsed at least twice, again preferably with tap water at room temperature, for at least one minute each (steps 114, 116).

The chain links and/or chain components are then deposited in a bath to receive the electroless nickel coating including hard particles (step 118). In one embodiment, the bath includes de-ionized water and silicon carbide (SiC) of 0.5 Kg/L at a temperature of 180°F- 190°F at a pH of 4.8-5.2. In another embodiment, the bath includes de-ionized water and silicon carbide (SiC) of 0.5 Kg/L at a temperature of 185°F at a pH of 5.0. The coating time varies and depends on the coating thickness preferred. The coating rate is approximately 6 microns per hour. A thickness between 14 to 25 microns is ideal to reduce chain wear, with 25 microns being preferred.

The bath solution is agitated when the coating is being applied to the chain links and/or chain components to maintain bath homogeneity and consistent finish, for example by air blowers or mechanical agitation. A filter of at least 10 microns or finer may be used with the bath and may be part of a filter bag system.

In other embodiments, other carbides or nitrides formed using the following elements: boron, chromium or vanadium may be used to form boron nitrate, boron carbide, chromium carbide, chromium nitride, and vanadium carbide, and vanadium nitride. The temperature and the pH as discussed above would be used for these other carbide and nitrides. Additionally, the hard particles may also be comprised of natural diamond and synthetic diamond-like carbon (DLC) particles.

It should be noted that the concentration of hard particles in the plating bath and plating rate would change based on particle type. For example, for boron nitride particles, the concentration of boron nitride particles needs to be lOOg/L of solution and plating rate is about 19 microns per hour.

The chain links and/or chain components are then rinsed at least twice, again preferably with tap water at room temperature (steps 120, 122) for at least two minutes.

The chain links and/or chain components are then dried (step 124), for example by compressed air, and the method ends.

Evaluations were performed to determine the wear characterization of electroless nickel coated links containing hard particles of silicon carbide. The wear test results have shown improvement in wear performance.

Figure 4 shows a graph comparing the wear performance of two chains: a chain with Ni-SiC electroless coated chain links and carbo-nitrided pins, and a chain with carbo- nitrided pins but without coated links. The base material of the chain links is 1055 steel. The chains were run at 5000 rpm for 100 hours using oil with 0.2% soot and 1000N of torque. The performance was measured by percent of chain elongation and test hours.

In order to measure chain wear, the center distance (CD) elongation of chain at a given speed and tension over time is measured. Center distance is the distance between the shaft centers of a chain and two-sprocket system. Chain center distance is measured at time intervals during the test. The amount of chain elongation from a new chain can be calculated at each time interval using the following equation:

/chain CD at t_t— chain CD at t₀ \

% Chain elongation = - xlOO

V chain CD at t₀ )

Where: to = time when the chain center distance is measured at the start of the test and is considered to be a "new" chain ti = time when the chain center distance is measured after wear at each time interval

As shown in Figure 4, the center distance (CD) elongation was shown to be higher as the test hours increased. A chain with electroless nickel coating containing hard particles is shown by the line with circles in Figure 4. A chain without the electroless coating is shown by the line with squares. The chain with the electroless nickel coating containing hard particles has less chain elongation than the chain without the coating, therefore demonstrating decreased wear. Figure 5 shows a graph of wear performance of two chains: a chain with Ni-SiC electroless coated links and vanadium carbide coated pins, and a. chain with vanadium carbide coated pins, but without coated links. The base material of the chain links is 1055 steel.

The chains were run at 5000 rpm for 100 hours using a high acid number oil (acidic oil) with 0.2% soot and 1000N of torque. In order to measure chain wear, the center distance (CD) elongation of chain at a given speed and tension over time is measured. Center distance is the distance between the shaft centers of a chain and two-sprocket system. Chain center distance is measured at each time interval. The amount of chain elongation that is representative of chain wear is calculated using the equation below.

As shown in Figure 5, the center distance (CD) elongation was shown to be higher as the test hours increased. A chain with electroless nickel coating containing hard particles is shown by the line with circles in Figure 5. A chain without the electroless coating is shown by the line with squares. The chain with the electroless nickel coating containing hard particles has less chain elongation than the chain without the coating, therefore demonstrating decreased wear.

Figure 6 shows the efficiency of chains with and without electroless nickel coated links after performing wear tests. The chains with the electroless nickel SiC coated links (indicated by the solid lines) and in group 1 have a higher efficiency compared to chains without electroless nicked coated links (indicated by the dash-dot-dot lines) and in group 2 under different loads (indicated by the difference symbols) and speeds.

Accordingly, it is to be understood that the embodiments of the invention herein described are merely illustrative of the application of the principles of the invention. Reference herein to details of the illustrated embodiments is not intended to limit the scope of the claims, which themselves recite those features regarded as essential to the invention.

Claims

What is claimed is:

1. A method of improving the wear characteristics of chain links and/or chain components comprising the steps of: a) cleaning the chain links and/or chain components with an alkaline agent to remove any foreign contaminants; b) rinsing the chain links and/or chain components to remove the alkaline agent from the chain links and/or chain components; c) cleaning of the chain links and/or chain components; d) rinsing the chain links and/or chain components at least once; e) subjecting the chain links and/or chain components to acid activation by immersing the chain links and/or chain components in an acid bath; f) rinsing the chain links and/or chain components with tap water at least once to remove acid from the acid bath on the chain links/and or chain components; g) applying an electroless nickel coating containing hard particles of a carbide or nitride formed using elements chosen from a group consisting of silicon, boron, chromium and vanadium to the chain links and/or chain components by immersing the chain links and/or chain components in a bath at a temperature of 180-190°F with a pH of 4.8 to 5.2; and h) rinsing the coated chain links and/or chain components at least once; wherein the chain components comprise bushings, pins, rockers and rollers.

2. The method of claim 1, wherein prior to step (a) of cleaning the chain links and/or chain components with the alkaline agent, the chain links and/or chain components are rinsed with tap water for at least two minutes at room temperature.

3. The method of claim 1, wherein the alkaline agent in step (a) is a combination of

hydroxide, carbonate, silicates, phosphates and other organic surfactants.

4. The method of claim 1, wherein in step (a) the alkaline agent is applied at a temperature of 160-180°F for 5 minutes.

5. The method of claim 1, wherein the cleaning in step (c) is electro-cleaning, and the cleaning is carried out at a temperature of 165-185°F for 5 minutes at 30 ASF.

6. The method of claim 1, wherein the acid bath of step (e) contains sulfuric acid a

concentration range of 5-10%.

7. The method of claim 1, wherein the acid bath of step (e) contains hydrochloric acid at a concentration range of 30-50%.

8. The method of claim 1 in which the acid bath in step (e) is diluted at room temperature with distilled water.

9. The method of claim 1, wherein the hard particles applied in step (g) further comprise synthetic diamond-like carbon particles.

10. The method of claim 1, wherein the coating applied to the chain components and/or chain links in step (g) is applied until the coating reaches a thickness between 14 to 25 microns

11. The method of claim 1, further comprising the step, after step (h), of drying the links and/or chain components.

12. The method of claim 1 in which the steps of rinsing are done with tap water at room temperature.