WO2017114340A1 - Anti-mildew coating material - Google Patents

Anti-mildew coating material Download PDF

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Publication number
WO2017114340A1
WO2017114340A1 PCT/CN2016/112034 CN2016112034W WO2017114340A1 WO 2017114340 A1 WO2017114340 A1 WO 2017114340A1 CN 2016112034 W CN2016112034 W CN 2016112034W WO 2017114340 A1 WO2017114340 A1 WO 2017114340A1
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Prior art keywords
parts
coating material
trithiocarbonate
polyester resin
titanium dioxide
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PCT/CN2016/112034
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French (fr)
Chinese (zh)
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李栋军
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李栋军
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Publication of WO2017114340A1 publication Critical patent/WO2017114340A1/en

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D4/00Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
    • C09D4/06Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/14Paints containing biocides, e.g. fungicides, insecticides or pesticides
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic

Definitions

  • the present invention relates to a mildew resistant coating material.
  • the problem to be solved by the present invention is to provide an anti-mite coating material, which has good weather resistance and mildew resistance, strong resilience, and greatly improved sterilization performance. long-term use.
  • the problem to be solved by the present invention is to provide an anti-mite coating material, which has good weather resistance and mildew resistance, strong resilience, and greatly improved sterilization performance. long-term use.
  • the technical solution of the present invention is an anti-mite coating material which is made of the following raw materials by weight: 15-25 parts of ethyl acrylate, 1-3 parts of serpentine powder , 12-20 parts of acrylic adhesive, 6-17 parts of polyester resin, 0.4-0.8 parts of polyaluminum chloride, 25-36 parts of nano titanium dioxide, 4-6 parts of viscosity reducer, dioctyl phthalate 15 -26 parts, 14-26 parts of calcium carbonate, 8-14 parts of natural latex, 2-4 parts of casein, oxygen 13-20 parts of zinc, 5-10 parts of potassium fluorosilicate, 3-6 parts of trithiocarbonate, and 4-8 parts of octyl epoxy stearate.
  • an anti-mite coating material made of the following parts by weight of raw materials: 20 parts of ethyl acrylate, 2 parts of serpentine powder, 16 parts of acrylic adhesive, 11 parts of polyester resin, poly 0.6 parts of aluminum chloride, 30 parts of nano titanium dioxide, 5 parts of viscosity reducer, 20 parts of dioctyl phthalate, 20 parts of calcium carbonate, 11 parts of natural latex, 3 parts of glycyrrhizin, 16 parts of zinc oxide, fluorine 7.5 parts of potassium silicate, 4.5 parts of trithiocarbonate, and 6 parts of octyl epoxy stearate.
  • the invention has the beneficial effects that the anti-mite coating material of the invention has good weather resistance and mildew resistance, strong resilience, greatly improved bactericidal performance, and can be used for a long time.
  • An anti-mite coating material made of the following parts by weight of raw materials: 15 parts of ethyl acrylate, 1 part of serpentine powder, 12 parts of acrylic adhesive, 6 parts of polyester resin, polyaluminum chloride 0.4 parts, 25 parts of nano titanium dioxide, 4 parts of viscosity reducer, 15 parts of dioctyl phthalate, 14 parts of calcium carbonate, 8 parts of natural latex, 2 parts of glycyrrhizin, 13 parts of zinc oxide, potassium fluorosilicate 5 parts, 3 parts of trithiocarbonate, 4 parts of octyl epoxy stearate.
  • An anti-mite coating material made of the following parts by weight of raw materials: 25 parts of ethyl acrylate, 3 parts of serpentine powder, 20 parts of acrylic adhesive, 17 parts of polyester resin, polyaluminum chloride 0.8 parts, 36 parts of nano titanium dioxide, 6 parts of viscosity reducer, 26 parts of dioctyl phthalate, 26 parts of calcium carbonate, 14 parts of natural latex, 4 parts of casein, 20 parts of zinc oxide, potassium fluorosilicate 10 parts, 6 parts of trithiocarbonate, 8 parts of octyl epoxy stearate.
  • An anti-mite coating material made of the following parts by weight of raw materials: 20 parts of ethyl acrylate, 2 parts of serpentine powder, 16 parts of acrylic adhesive, 11 parts of polyester resin, polyaluminum chloride 0.6 parts, 30 parts of nano titanium dioxide, 5 parts of viscosity reducer, 20 parts of dioctyl phthalate, 20 parts of calcium carbonate, 11 parts of natural latex, 3 parts of glycyrrhizin, 16 parts of zinc oxide, potassium fluorosilicate 7.5 parts, 4.5 parts of trithiocarbonate, 6 parts of octyl epoxy stearate.

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Plant Pathology (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Adhesives Or Adhesive Processes (AREA)

Abstract

An anti-mildew coating material is made from, in parts by weight, 15-25 parts of ethyl acrylate, 1-3 parts of serpentine powder, 12-20 parts of acrylic adhesive, 6-17 parts of polyester resin, 0.4-0.8 parts of polyaluminum chloride, 25-36 parts of nano-titanium dioxide, 4-6 parts of viscosity reducer, 15-26 parts of dioctyl phthalate, 14-26 parts of calcium carbonate, 8-14 parts of natural latex, 2-4 parts of casein, 13-20 parts of zinc oxide, 5-10 parts of potassium fluorosilicate, 3-6 parts of trithiocarbonate and 4-8 parts of 2-ethylhexyl epoxystearate.

Description

发明名称:一种防霉涂层材料  Title of the invention: an anti-mold coating material
技术领域  Technical field
[0001] 本发明涉及一种防霉涂层材料。  [0001] The present invention relates to a mildew resistant coating material.
背景技术  Background technique
[0002] 人们的生活条件越来越好, 对于房屋的装饰也越来越重视, 建筑装饰是应用装 饰材料, 依据一定的方法对建筑物进行美的设计和美的包装。 在某种程度上它 可以反映社会某一吋代的科技水平、 生活水平、 民族文化和城市风格等。 人们 对装饰材料的要求越来越高, 尤其对涂层材料的要求随着使用量的增加, 对其 要求越来越严格, 不仅要求改善室内外的艺术环境, 使人们得到美的享受, 同 吋还兼有绝热、 防潮、 防霉、 防火、 吸声等多种功能, 起着保护建筑物主体结 构, 延长其使用寿命以及满足某些特殊要求的作用, 是现代建筑中不可缺少的 一类材料。 尤其像室内用的涂层材料更注重防霉性, 因为霉菌的存在直接影响 到人们的身心健康。  [0002] People's living conditions are getting better and better, and more and more attention is paid to the decoration of houses. Building decoration is the application of decorative materials, and the beautiful design and beautiful packaging of buildings are carried out according to certain methods. To a certain extent, it can reflect the technological level, living standards, national culture and urban style of a certain generation of society. People are increasingly demanding decorative materials. In particular, the requirements for coating materials are becoming more and more strict with the increase in usage. It is not only required to improve the indoor and outdoor art environment, but also to make people enjoy the beauty. It also has many functions such as heat insulation, moisture proof, mildew proof, fire prevention and sound absorption. It plays an important role in protecting the main structure of the building, prolonging its service life and meeting certain special requirements. It is an indispensable material in modern architecture. . Especially for indoor coating materials, more attention is paid to mold resistance, because the presence of mold directly affects people's physical and mental health.
技术问题  technical problem
[0003] 针对现有技术的不足, 本发明要解决的问题是, 提供一种防霉涂层材料, 具有 良好的耐候效果和防霉性能, 回弹力强, 杀菌性能得到很大的提高, 能长期使 用。  [0003] In view of the deficiencies of the prior art, the problem to be solved by the present invention is to provide an anti-mite coating material, which has good weather resistance and mildew resistance, strong resilience, and greatly improved sterilization performance. long-term use.
问题的解决方案  Problem solution
技术解决方案  Technical solution
[0004] 针对现有技术的不足, 本发明要解决的问题是, 提供一种防霉涂层材料, 具有 良好的耐候效果和防霉性能, 回弹力强, 杀菌性能得到很大的提高, 能长期使 用。  [0004] In view of the deficiencies of the prior art, the problem to be solved by the present invention is to provide an anti-mite coating material, which has good weather resistance and mildew resistance, strong resilience, and greatly improved sterilization performance. long-term use.
[0005] 为解决上述技术问题, 本发明的技术方案是, 一种防霉涂层材料, 其由以下重 量份数的原料制成: 丙烯酸乙酯 15-25份, 蛇纹石粉 1-3份, 丙烯酸黏合剂 12-20 份, 聚酯树脂 6-17份, 聚氯化铝 0.4-0.8份, 纳米钛白粉 25-36份, 降粘剂 4-6份, 邻苯二甲酸二辛脂 15-26份, 碳酸钙 14-26份, 天然胶乳 8-14份, 甘酪素 2-4份, 氧 化锌 13-20份, 氟硅酸钾 5-10份, 三硫代碳酸酯 3-6份, 环氧硬脂酸辛酯 4-8份。 [0005] In order to solve the above technical problem, the technical solution of the present invention is an anti-mite coating material which is made of the following raw materials by weight: 15-25 parts of ethyl acrylate, 1-3 parts of serpentine powder , 12-20 parts of acrylic adhesive, 6-17 parts of polyester resin, 0.4-0.8 parts of polyaluminum chloride, 25-36 parts of nano titanium dioxide, 4-6 parts of viscosity reducer, dioctyl phthalate 15 -26 parts, 14-26 parts of calcium carbonate, 8-14 parts of natural latex, 2-4 parts of casein, oxygen 13-20 parts of zinc, 5-10 parts of potassium fluorosilicate, 3-6 parts of trithiocarbonate, and 4-8 parts of octyl epoxy stearate.
[0006] 优化的, 一种防霉涂层材料, 其由以下重量份数的原料制成: 丙烯酸乙酯 20份 , 蛇纹石粉 2份, 丙烯酸黏合剂 16份, 聚酯树脂 11份, 聚氯化铝 0.6份, 纳米钛白 粉 30份, 降粘剂 5份, 邻苯二甲酸二辛脂 20份, 碳酸钙 20份, 天然胶乳 11份, 甘 酪素 3份, 氧化锌 16份, 氟硅酸钾 7.5份, 三硫代碳酸酯 4.5份, 环氧硬脂酸辛酯 6 份。 [0006] Optimized, an anti-mite coating material made of the following parts by weight of raw materials: 20 parts of ethyl acrylate, 2 parts of serpentine powder, 16 parts of acrylic adhesive, 11 parts of polyester resin, poly 0.6 parts of aluminum chloride, 30 parts of nano titanium dioxide, 5 parts of viscosity reducer, 20 parts of dioctyl phthalate, 20 parts of calcium carbonate, 11 parts of natural latex, 3 parts of glycyrrhizin, 16 parts of zinc oxide, fluorine 7.5 parts of potassium silicate, 4.5 parts of trithiocarbonate, and 6 parts of octyl epoxy stearate.
发明的有益效果  Advantageous effects of the invention
有益效果  Beneficial effect
[0007] 本发明的有益效果是, 本发明的防霉涂层材料, 具有良好的耐候效果和防霉性 育 , 回弹力强, 杀菌性能得到很大的提高, 能长期使用。  [0007] The invention has the beneficial effects that the anti-mite coating material of the invention has good weather resistance and mildew resistance, strong resilience, greatly improved bactericidal performance, and can be used for a long time.
本发明的实施方式 Embodiments of the invention
[0008] 实施例 1 Embodiment 1
[0009] 一种防霉涂层材料, 其由以下重量份数的原料制成: 丙烯酸乙酯 15份, 蛇纹石 粉 1份, 丙烯酸黏合剂 12份, 聚酯树脂 6份, 聚氯化铝 0.4份, 纳米钛白粉 25份, 降粘剂 4份, 邻苯二甲酸二辛脂 15份, 碳酸钙 14份, 天然胶乳 8份, 甘酪素 2份, 氧化锌 13份, 氟硅酸钾 5份, 三硫代碳酸酯 3份, 环氧硬脂酸辛酯 4份。  [0009] An anti-mite coating material made of the following parts by weight of raw materials: 15 parts of ethyl acrylate, 1 part of serpentine powder, 12 parts of acrylic adhesive, 6 parts of polyester resin, polyaluminum chloride 0.4 parts, 25 parts of nano titanium dioxide, 4 parts of viscosity reducer, 15 parts of dioctyl phthalate, 14 parts of calcium carbonate, 8 parts of natural latex, 2 parts of glycyrrhizin, 13 parts of zinc oxide, potassium fluorosilicate 5 parts, 3 parts of trithiocarbonate, 4 parts of octyl epoxy stearate.
[0010] 实施例 2  [0010] Example 2
[0011] 一种防霉涂层材料, 其由以下重量份数的原料制成: 丙烯酸乙酯 25份, 蛇纹石 粉 3份, 丙烯酸黏合剂 20份, 聚酯树脂 17份, 聚氯化铝 0.8份, 纳米钛白粉 36份, 降粘剂 6份, 邻苯二甲酸二辛脂 26份, 碳酸钙 26份, 天然胶乳 14份, 甘酪素 4份 , 氧化锌 20份, 氟硅酸钾 10份, 三硫代碳酸酯 6份, 环氧硬脂酸辛酯 8份。  [0011] An anti-mite coating material made of the following parts by weight of raw materials: 25 parts of ethyl acrylate, 3 parts of serpentine powder, 20 parts of acrylic adhesive, 17 parts of polyester resin, polyaluminum chloride 0.8 parts, 36 parts of nano titanium dioxide, 6 parts of viscosity reducer, 26 parts of dioctyl phthalate, 26 parts of calcium carbonate, 14 parts of natural latex, 4 parts of casein, 20 parts of zinc oxide, potassium fluorosilicate 10 parts, 6 parts of trithiocarbonate, 8 parts of octyl epoxy stearate.
[0012] 实施例 3  [0012] Example 3
[0013] 一种防霉涂层材料, 其由以下重量份数的原料制成: 丙烯酸乙酯 20份, 蛇纹石 粉 2份, 丙烯酸黏合剂 16份, 聚酯树脂 11份, 聚氯化铝 0.6份, 纳米钛白粉 30份, 降粘剂 5份, 邻苯二甲酸二辛脂 20份, 碳酸钙 20份, 天然胶乳 11份, 甘酪素 3份 , 氧化锌 16份, 氟硅酸钾 7.5份, 三硫代碳酸酯 4.5份, 环氧硬脂酸辛酯 6份。  [0013] An anti-mite coating material made of the following parts by weight of raw materials: 20 parts of ethyl acrylate, 2 parts of serpentine powder, 16 parts of acrylic adhesive, 11 parts of polyester resin, polyaluminum chloride 0.6 parts, 30 parts of nano titanium dioxide, 5 parts of viscosity reducer, 20 parts of dioctyl phthalate, 20 parts of calcium carbonate, 11 parts of natural latex, 3 parts of glycyrrhizin, 16 parts of zinc oxide, potassium fluorosilicate 7.5 parts, 4.5 parts of trithiocarbonate, 6 parts of octyl epoxy stearate.

Claims

权利要求书 Claim
[权利要求 1] 一种防霉涂层材料, 其特征在于: 其由以下重量份数的原料制成: 丙 烯酸乙酯 15-25份, 蛇纹石粉 1-3份, 丙烯酸黏合剂 12-20份, 聚酯树脂 6-17份, 聚氯化铝 0.4-0.8份, 纳米钛白粉 25-36份, 降粘剂 4-6份, 令 苯二甲酸二辛脂 15-26份, 碳酸钙 14-26份, 天然胶乳 8-14份, 甘酪素 2 -4份, 氧化锌 13-20份, 氟硅酸钾 5-10份, 三硫代碳酸酯 3-6份, 环氧 硬脂酸辛酯 4-8份。  [Attach 1] An anti-mite coating material, which is prepared from the following parts by weight: 15-25 parts of ethyl acrylate, 1-3 parts of serpentine powder, 12-20 of acrylic adhesive Parts, 6-17 parts of polyester resin, 0.4-0.8 parts of polyaluminum chloride, 25-36 parts of nano titanium dioxide, 4-6 parts of viscosity reducing agent, 15-26 parts of dioctyl phthalate, calcium carbonate 14 -26 parts, natural latex 8-14 parts, glycyrrhizin 2-4 parts, zinc oxide 13-20 parts, potassium fluorosilicate 5-10 parts, trithiocarbonate 3-6 parts, epoxy stearate octyl Ester 4-8 parts.
[权利要求 2] 根据权利要求 1所述的防霉涂层材料, 其特征在于: 其由以下重量份 数的原料制成: 丙烯酸乙酯 20份, 蛇纹石粉 2份, 丙烯酸黏合剂 16份 , 聚酯树脂 11份, 聚氯化铝 0.6份, 纳米钛白粉 30份, 降粘剂 5份, 邻 苯二甲酸二辛脂 20份, 碳酸钙 20份, 天然胶乳 11份, 甘酪素 3份, 氧 化锌 16份, 氟硅酸钾 7.5份, 三硫代碳酸酯 4.5份, 环氧硬脂酸辛酯 6份  [Claim 2] The mold-proof coating material according to claim 1, which is made of the following raw materials by weight: 20 parts of ethyl acrylate, 2 parts of serpentine powder, 16 parts of acrylic adhesive , 11 parts of polyester resin, 0.6 parts of polyaluminum chloride, 30 parts of nano titanium dioxide, 5 parts of viscosity reducer, 20 parts of dioctyl phthalate, 20 parts of calcium carbonate, 11 parts of natural latex, casein 3 Parts, 16 parts of zinc oxide, 7.5 parts of potassium fluorosilicate, 4.5 parts of trithiocarbonate, 6 parts of octyl epoxy stearate
PCT/CN2016/112034 2015-12-31 2016-12-26 Anti-mildew coating material WO2017114340A1 (en)

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CN103450723A (en) * 2013-08-21 2013-12-18 苏州康华净化系统工程有限公司 Ageing-resistant corrosion-resistant ultra-clean workbench coating
CN103589208A (en) * 2013-10-22 2014-02-19 江苏博思源防火材料科技有限公司 Weather-proof curtain wall coating and preparation method thereof
CN103865308A (en) * 2014-03-12 2014-06-18 广东普赛特电子科技股份有限公司 Creep-resistant and electrically conductive coating and preparation method thereof
CN104212281A (en) * 2014-09-22 2014-12-17 句容亿格纳米材料厂 Nano decorative coating and preparation method thereof
CN104263154A (en) * 2014-09-22 2015-01-07 句容亿格纳米材料厂 Nano ceramic simulating coating and preparation method thereof
CN104817861A (en) * 2015-04-16 2015-08-05 青岛保利康新材料有限公司 Heat insulation coating
CN105504917A (en) * 2015-12-31 2016-04-20 李栋军 Mold-proof coating material

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112708320A (en) * 2021-01-08 2021-04-27 杭州廖仕科技有限公司 Anti-aging nano TiO2Modified acrylic resin composite material and preparation method thereof
CN112708320B (en) * 2021-01-08 2022-06-21 合肥市丽红塑胶材料有限公司 Anti-aging nano TiO2Modified acrylic resin composite material and preparation method thereof

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