WO2017106152A3 - Branched polyester-urethane resins and coatings comprising the same - Google Patents

Branched polyester-urethane resins and coatings comprising the same Download PDF

Info

Publication number
WO2017106152A3
WO2017106152A3 PCT/US2016/066303 US2016066303W WO2017106152A3 WO 2017106152 A3 WO2017106152 A3 WO 2017106152A3 US 2016066303 W US2016066303 W US 2016066303W WO 2017106152 A3 WO2017106152 A3 WO 2017106152A3
Authority
WO
WIPO (PCT)
Prior art keywords
coatings
same
branched polyester
urethane resins
disclosed
Prior art date
Application number
PCT/US2016/066303
Other languages
French (fr)
Other versions
WO2017106152A2 (en
Inventor
Francesco Ciaccio
Annamaria Antonaci
Eddy Bonello
Stephane Schoch
Wolfgang Klaeger
Beate Seiler
Jose CAMERANO
Debra L. Singer
John E. Schwendeman
Shanti Swarup
Original Assignee
Ppg Industries Ohio, Inc.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US14/967,763 external-priority patent/US10035872B2/en
Application filed by Ppg Industries Ohio, Inc. filed Critical Ppg Industries Ohio, Inc.
Priority to CA3008414A priority Critical patent/CA3008414C/en
Priority to EP16867415.8A priority patent/EP3390484A2/en
Priority to CN201680073282.5A priority patent/CN108473655B/en
Priority to KR1020187019638A priority patent/KR102080423B1/en
Priority to RU2018125548A priority patent/RU2018125548A/en
Priority to MX2018007177A priority patent/MX2018007177A/en
Publication of WO2017106152A2 publication Critical patent/WO2017106152A2/en
Publication of WO2017106152A3 publication Critical patent/WO2017106152A3/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D1/00—Processes for applying liquids or other fluent materials
    • B05D1/02—Processes for applying liquids or other fluent materials performed by spraying
    • B05D1/04—Processes for applying liquids or other fluent materials performed by spraying involving the use of an electrostatic field
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/0804—Manufacture of polymers containing ionic or ionogenic groups
    • C08G18/0819—Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups
    • C08G18/0823—Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups containing carboxylate salt groups or groups forming them
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/34—Carboxylic acids; Esters thereof with monohydroxyl compounds
    • C08G18/348—Hydroxycarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/4236—Polycondensates having carboxylic or carbonic ester groups in the main chain containing only aliphatic groups
    • C08G18/4238—Polycondensates having carboxylic or carbonic ester groups in the main chain containing only aliphatic groups derived from dicarboxylic acids and dialcohols
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/75—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic
    • C08G18/751—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring
    • C08G18/752—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group
    • C08G18/753—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group containing one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group having a primary carbon atom next to the isocyanate or isothiocyanate group
    • C08G18/755—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group containing one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group having a primary carbon atom next to the isocyanate or isothiocyanate group and at least one isocyanate or isothiocyanate group linked to a secondary carbon atom of the cycloaliphatic ring, e.g. isophorone diisocyanate
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04—Polyurethanes
    • C09D175/06—Polyurethanes from polyesters
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/44—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for electrophoretic applications
    • C09D5/4419—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for electrophoretic applications with polymers obtained otherwise than by polymerisation reactions only involving carbon-to-carbon unsaturated bonds
    • C09D5/4465—Polyurethanes

Abstract

An uncured branched polyester-urethane resin prepared by free radical polymerization of an unsaturated polyester prepolymer having a polyol segment, an unsaturated polycarboxylic acid and/or an anhydride and/or ester thereof, and a urethane segment, wherein the polymerization occurs primarily by reaction of the unsaturation is disclosed. Coatings comprising the same are also disclosed, as are substrates coated at least in part with such coatings.
PCT/US2016/066303 2015-12-14 2016-12-13 Branched polyester-urethane resins and coatings comprising the same WO2017106152A2 (en)

Priority Applications (6)

Application Number Priority Date Filing Date Title
CA3008414A CA3008414C (en) 2015-12-14 2016-12-13 Branched polyester-urethane resins and coatings comprising the same
EP16867415.8A EP3390484A2 (en) 2015-12-14 2016-12-13 Branched polyester-urethane resins and coatings comprising the same
CN201680073282.5A CN108473655B (en) 2015-12-14 2016-12-13 Branched polyester-urethane resins and coatings comprising the same
KR1020187019638A KR102080423B1 (en) 2015-12-14 2016-12-13 Branched polyester-urethane resins and coatings comprising the same
RU2018125548A RU2018125548A (en) 2015-12-14 2016-12-13 BRANCHED POLYESTER-URETANE RESINS AND INCLUDING THEIR COATINGS
MX2018007177A MX2018007177A (en) 2015-12-14 2016-12-13 Branched polyester-urethane resins and coatings comprising the same.

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US14/967,763 US10035872B2 (en) 2010-04-01 2015-12-14 Branched polyester-urethane resins and coatings comprising the same
US14/967,763 2015-12-14

Publications (2)

Publication Number Publication Date
WO2017106152A2 WO2017106152A2 (en) 2017-06-22
WO2017106152A3 true WO2017106152A3 (en) 2017-09-14

Family

ID=58745340

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2016/066303 WO2017106152A2 (en) 2015-12-14 2016-12-13 Branched polyester-urethane resins and coatings comprising the same

Country Status (7)

Country Link
EP (1) EP3390484A2 (en)
KR (1) KR102080423B1 (en)
CN (1) CN108473655B (en)
CA (1) CA3008414C (en)
MX (1) MX2018007177A (en)
RU (1) RU2018125548A (en)
WO (1) WO2017106152A2 (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115717018A (en) * 2022-12-05 2023-02-28 德清县金秋塑粉有限公司 Special anticorrosive powder coating for suspension spring of automobile shock absorber

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20020002237A1 (en) * 1998-08-17 2002-01-03 Christoph Irle Aqueous coating compositions, their preparation and use in stoving lacquers
US20110021694A1 (en) * 2009-07-23 2011-01-27 E.I. Du Pont De Nemours And Company Polyesterurethane for coating compositions
US20150064476A1 (en) * 2012-04-03 2015-03-05 Kansai Paint Co., Ltd. Aqueous paint composition and method for forming coating
WO2015153844A1 (en) * 2014-04-04 2015-10-08 Ppg Industries Ohio, Inc. Branched polyester polymers and soft touch coatings comprising the same

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4650718A (en) 1985-08-19 1987-03-17 Ppg Industries, Inc. Color plus clear coatings employing polyepoxides and polyacid curing agents
US4933056A (en) 1988-09-26 1990-06-12 Ppg Industries, Inc. Cationic electrodepositable compositions through the use of sulfamic acid and derivatives thereof
TW242644B (en) 1992-10-30 1995-03-11 Ppg Industries Inc
DE4317981A1 (en) 1993-05-28 1994-12-01 Ranco Inc Gas-air ratio control device for a temperature control loop for gas appliances
US5530043A (en) 1994-05-25 1996-06-25 Ppg Industries, Inc. Low volatile organic content pigment grind composition
US5582704A (en) 1994-11-04 1996-12-10 Ppg Industries, Inc. Cationic resin and capped polyisocyanate curing agent suitable for use in electrodeposition
AU5633296A (en) 1995-05-01 1996-11-21 Ppg Industries, Inc. Curable compositions composite coatings and process for having iproved MAR abrasion resistancee
US5820987A (en) 1996-08-21 1998-10-13 Ppg Industries, Inc. Cationic electrocoating compositions, method of making, and use
US6565978B1 (en) 1998-02-18 2003-05-20 Ppg Industries Ohio, Inc. Multi-component composite coating composition and coated substrate
US6875800B2 (en) 2001-06-18 2005-04-05 Ppg Industries Ohio, Inc. Use of nanoparticulate organic pigments in paints and coatings
US6894086B2 (en) 2001-12-27 2005-05-17 Ppg Industries Ohio, Inc. Color effect compositions
BR0307663B1 (en) 2002-02-13 2013-10-01 process to form a multilayer composite coating on a substrate
US7438972B2 (en) 2004-06-24 2008-10-21 Ppg Industries Ohio, Inc. Nanoparticle coatings for flexible and/or drawable substrates
FR2903412B1 (en) * 2006-07-07 2012-10-05 Cray Valley Sa URETHANE PRE-POLYMER - UNSATURATED POLYESTER AND APPLICATIONS THEREOF
US8846156B2 (en) 2013-02-28 2014-09-30 Ppg Industries Ohio, Inc. Methods and compositions for coating substrates

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20020002237A1 (en) * 1998-08-17 2002-01-03 Christoph Irle Aqueous coating compositions, their preparation and use in stoving lacquers
US20110021694A1 (en) * 2009-07-23 2011-01-27 E.I. Du Pont De Nemours And Company Polyesterurethane for coating compositions
US20150064476A1 (en) * 2012-04-03 2015-03-05 Kansai Paint Co., Ltd. Aqueous paint composition and method for forming coating
WO2015153844A1 (en) * 2014-04-04 2015-10-08 Ppg Industries Ohio, Inc. Branched polyester polymers and soft touch coatings comprising the same

Also Published As

Publication number Publication date
EP3390484A2 (en) 2018-10-24
CA3008414C (en) 2021-05-18
CN108473655A (en) 2018-08-31
CA3008414A1 (en) 2017-06-22
KR102080423B1 (en) 2020-02-21
RU2018125548A (en) 2020-01-16
RU2018125548A3 (en) 2020-01-16
WO2017106152A2 (en) 2017-06-22
MX2018007177A (en) 2018-08-01
CN108473655B (en) 2021-08-03
KR20180093032A (en) 2018-08-20

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