WO2017058890A1 - Gomme à mâcher comprenant du xylitol liquide en tant qu'agent ramollissant - Google Patents

Gomme à mâcher comprenant du xylitol liquide en tant qu'agent ramollissant Download PDF

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Publication number
WO2017058890A1
WO2017058890A1 PCT/US2016/054141 US2016054141W WO2017058890A1 WO 2017058890 A1 WO2017058890 A1 WO 2017058890A1 US 2016054141 W US2016054141 W US 2016054141W WO 2017058890 A1 WO2017058890 A1 WO 2017058890A1
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WIPO (PCT)
Prior art keywords
chewing gum
xylitol
weight
solids
solution
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Application number
PCT/US2016/054141
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English (en)
Inventor
Enrique Valdez
Carol SINOPLE
Original Assignee
Wm. Wrigley Jr. Company
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
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Publication of WO2017058890A1 publication Critical patent/WO2017058890A1/fr

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Classifications

    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23GCOCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
    • A23G4/00Chewing gum
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23GCOCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
    • A23G4/00Chewing gum
    • A23G4/06Chewing gum characterised by the composition containing organic or inorganic compounds
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23GCOCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
    • A23G4/00Chewing gum
    • A23G4/06Chewing gum characterised by the composition containing organic or inorganic compounds
    • A23G4/10Chewing gum characterised by the composition containing organic or inorganic compounds characterised by the carbohydrates used, e.g. polysaccharides
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23GCOCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
    • A23G4/00Chewing gum
    • A23G4/18Chewing gum characterised by shape, structure or physical form, e.g. aerated products
    • A23G4/20Composite products, e.g. centre-filled, multi-layer, laminated

Definitions

  • the present invention relates chewing gums which contain a xylitol solution as a softener.
  • the xylitol solution is obtained by hydrogenation of a xylose solution and is used without crystallization or other purification or concentration steps.
  • Traditional chewing gums comprise a water insoluble portion (essentially the gum base) and a water soluble portion which consists mostly of sugars and or sugar alcohols and which typically constitutes 60 to 75% of the product.
  • the bulking agent also softens the initial texture of the product.
  • Other ingredients including flavor, softeners, colors acidulants and the like are also considered to be part of the water-soluble portion.
  • a liquid softener which is a carbohydrate solution which serves to soften the composition and improve processing by reducing load on the mixer. Depending on the softener chosen, it may also serve to bind the gum ingredients together and control moisture loss or pick up of the final composition during storage.
  • these softeners are a corn (dextrose) syrup, a hydrogenated corn syrup (often called hydrogenated starch hydrolysate) or a solution of one or more sugar alcohols such as a 70% sorbitol solution which is commonly used in sugarless gums.
  • Crystalline xylitol is often used as a bulking agent in sugarless chewing gums.
  • This sugar alcohol or polyhydric alcohol or polyol
  • This sugar alcohol has benefits of sugarlike sweetness, low hygroscopicity and non-cariogenicity or even anti-cariogenicity which make it extremely desirable and useful for this purpose.
  • xylitol does have some disadvantages, such as higher cost than other sugar alcohols. I also may take more energy to produce xylitol than other sugar alcohols making it less environmentally friendly.
  • This invention is directed to chewing gums which include a liquid xylitol softener which is produced by hydrogenating a xylose solution without the subsequent crystallization step that is commonly employed to produce xylitol in a crystalline form. This significantly reduces the cost of the ingredient and the 'carbon footprint' of producing it.
  • this xylitol solution is sometimes referred to as a 'mother liquor'.
  • the present invention provides several advantages over prior art compositions. It is an advantage of the present invention to reduce the cost of a xylitol-containing chewing gum composition. It is an advantage of the present invention to reduce the cost of a chewing gum composition as compared to chewing gum compositions which employ glycerin or coevaporated glycerin/sugar alcohol solutions. It is an advantage of the present invention to reduce the energy and mixing torque necessary to prepare a chewing gum composition. It is an advantage of the present invention to reduce the carbon footprint of a xylitol- containing chewing gum.
  • Chewing gums in which the present invention is useful will include sugar and sugarless chewing gums in stick, tab, pellet, chunk and other forms.
  • the product may be a bubblegum, a liquid or powder filled gum or other novelty product
  • the chewing gum will be surrounded by a coating, such as a pan coating of sugar or sugar alcohol or wax or chocolate.
  • a coating such as a pan coating of sugar or sugar alcohol or wax or chocolate.
  • Such coatings may be applied, for example, by enrobing with a molten coating or by spraying or atomizing the coating material in solution or molten form.
  • a coating layer may be coextruded around the gum mass using a concentric die.
  • FIGURE 1 shows a graph of moisture uptake by control and inventive chewing gum compositions when stored at 45°C and 85% RH for a period of seven days.
  • FIGURE 2 shows a graph of Moisture activity (Aw) of control and inventive chewing gum compositions after storage at 45°C and 85% RH for a period of seven days.
  • the present invention provides chewing gums containing a xylitol solution as a softener for the chewing gum mass.
  • the chewing gum will contain at least 1 wt.% of the xylitol solution. In some embodiments of the present invention, the chewing gum will contain at least 1.5 wt.% of the xylitol solution. In some embodiments of the present invention, the chewing gum will contain at least 2 wt.% of the xylitol solution. In some embodiments of the present invention, the chewing gum will contain at least 2.5 wt.% of the xylitol solution. In some embodiments of the present invention, the chewing gum will contain at least 3 wt.% of the xylitol solution.
  • the chewing gum will contain less than 6 wt.% of the xylitol solution. In some embodiments of the present invention, the chewing gum will contain less than 5 wt.% of the xylitol solution. In some embodiments of the present invention, the chewing gum will contain less than 4.5 wt.% of the xylitol solution. In some embodiments of the present invention, the chewing gum will contain less than 4 wt.% of the xylitol solution.
  • the xylitol solution used in the present invention can be prepared as part of a conventional xylitol manufacturing process.
  • biomass containing high levels of xylan a polymer of xylose
  • Suitable biomass sources for this purpose may include corn cobs, birch wood or other suitable sources, are subjected to acid or enzyme hydrolysis to break the xylan polymer into individual xylose sugar molecules.
  • the biomass is subjected to acid or enzyme hydrolysis to convert the xylan polymer into xylose.
  • xylose solution is then subjected to hydrogenation to convert xylose and any other sugars present into their corresponding sugar alcohols (polyols).
  • Xylose which forms the majority of the sugars present, it is converted into xylitol during the hydrogenation process.
  • the solution would normally be subjected to an energy intensive crystallization step to produce crystalline xylitol.
  • the solution is used directly in a chewing gum composition, with or without concentration by evaporation/cooking.
  • the xylitol solution may be cooked or evaporated to adjust the level of solids.
  • the syrup may be evaporated to a solids content of 70% or 75% or 80% or 85% or even 90% by weight of the solution, the balance being water.
  • the xylitol solution useful in the present invention will also contain other polyols in small quantities. Typically, these will include arabitol, galactitol and sorbitol. In some embodiments, the xylitol solution will contain at least 1 .5% of polyols other than xylitol. In some embodiments, the xylitol solution will contain at least 1 .8% of polyols other than xylitol. In some embodiments, the xylitol solution will contain at least 2.2% of polyols other than xylitol. In some embodiments, the xylitol solution will contain at less than 3.0% of polyols other than xylitol. In some embodiments, the xylitol solution will contain at less than 2.5% of polyols other than xylitol. These percentages are based on the weight of dry solids in the solution.
  • the xylitol solutions of the present invention may also contain a small quantity of un-hydrogenated xylose. It is important that this amount be minimize, particularly in the case where the chewing gum is a sugarless chewing gum.
  • the xylitol solution will contain less than 0.5% un- hydrogenated xylose.
  • the xylitol solution will contain at less than 0.25% of un-hydrogenated xylose.
  • the xylitol solution will contain at less than 0.20% of un-hydrogenated xylose.
  • the xylitol solution will contain at less than 0.15% of un-hydrogenated xylose. Again, these percentages are based on the weight of dry solids in the solution.
  • the remainder of the solids in the xylitol solution will comprise xylitol.
  • the solids in the xylitol solution will comprise xylitol will comprise at least 97% by weight xylitol.
  • the solids in the xylitol solution will comprise xylitol will comprise at least 97.5% by weight xylitol.
  • the solids in the xylitol solution will comprise xylitol will comprise at least 98% by weight xylitol.
  • the solids in the xylitol solution will comprise xylitol will comprise at least 98.5% by weight xylitol.
  • Xylitol solutions suitable for use in the present invention may be obtained from crystalline xylitol manufacturers such as Danisco of Europe and Huakang Pharmaceutical Co in Zhejiang, China.
  • the polymers used in chewing gums of the present invention be food grade. While requirements for being food grade vary from country to country, food grade polymers intended for use as masticatory substances (i.e. gum base) will typically have to meet one or more of the following criteria. They may have to be specifically approved by local food regulatory agencies for this purpose. They may have to be manufactured under "Good Manufacturing Practices" (GMPs) which may be defined by local regulatory agencies, such practices ensuring adequate levels of cleanliness and safety for the manufacturing of food materials. Materials (including reagents, catalysts, solvents and antioxidants) used in the manufacture will desirably be food grade (where possible) or at least meet strict standards for quality and purity.
  • GMPs Good Manufacturing Practices
  • the finished product may have to meet minimum standards for quality and the level and nature of any impurities present, including residual monomer content.
  • the manufacturing history of the material may be required to be adequately documented to ensure compliance with the appropriate standards.
  • the manufacturing facility itself may be subject to inspection by governmental regulatory agencies. Again, not all of these standards may apply in all jurisdictions.
  • the term "food grade” will mean that the polymers meet all applicable food standards in the locality where the ingredient or the product incorporating it is manufactured and/or sold.
  • the fundamental components of a chewing gum typically are a water- insoluble gum base portion and a water-soluble bulking agent portion.
  • the primary component of the gum base is an elastomeric polymer which provides the characteristic chewy texture of the product.
  • the gum base will typically include other ingredients which modify the chewing properties or aid in processing the product. These include plasticizers, softeners, fillers, emulsifiers, plastic resins, as well as colorants and antioxidants.
  • the water soluble portion of the chewing gum typically includes a bulking agent together with minor amounts of secondary components such as flavors, high-intensity sweeteners, colorants, water-soluble softeners, gum emulsifiers, acidulants and sensates. Typically, the water-soluble portion, sensates, and flavors dissipate during chewing and the gum base is retained in the mouth throughout the chew.
  • Any suitable chewing gum base and chewing gum formula may be used to produce a shell for center-filled chewing gums of the present invention.
  • suitable it is meant that the formula is capable of being processed through the selected equipment.
  • the insoluble gum base typically may contain any combination of elastomers, vinyl polymers, elastomer plasticizers, fillers, softeners, waxes and other optional ingredients such as colorants and antioxidants.
  • the variety of gum base ingredients typically used provide the ability to modify the chewing characteristics of gums made from the gum base.
  • Elastomers provide the rubbery, cohesive nature to the gum which varies depending on this ingredient's chemical structure and how it may be compounded with other ingredients.
  • Natural elastomers may include natural rubber such as smoked or liquid latex and guayule, natural gums such as jelutong, lechi caspi perillo, massaranduba balata, massaranduba chocolate, nispero, rosidinha, chicle, gutta percha, gutta kataiu, niger gutta, tenu, chilte, chiquibul, gutta hang kang.
  • Synthetic elastomers may include high molecular weight elastomers such as butadiene-styrene copolymers and isobutylene-isoprene copolymers.
  • Other polymers which sometimes serve as elastomers include polybutadiene and polyisobutylene, vinyl polymers such as polyvinyl acetate, polyethylene, vinyl copolymeric elastomers such as vinyl acetate/vinyl laurate, vinyl acetate/vinyl stearate, ethylene/vinyl acetate, polyvinyl alcohol or mixtures thereof. These polymers perform best when used in combination with butadiene-styrene copolymers and isobutylene-isoprene copolymers.
  • Vinyl polymeric and copolymeric type elastomers provide tack resistance, vary the chew characteristics of gums made from these bases and offer hydrophilic properties beneficial to sensory perception of the final gums.
  • the amount of vinyl laurate, vinyl stearate, or ethylene present in the vinyl laurate/vinyl acetate (VLNA), vinyl stearate/vinyl acetate (VSNA), or ethylene/vinyl acetate (EVA) copolymers respectively typically ranges from about 10 to about 60 percent by weight of the copolymer. Average molecular weights of these polymers may range from about 2,000 to about 80,000. Ball and ring softening points of these polymers may range from about to 50 to 120°C.
  • Polyvinyl acetate having an average molecular weight from about 8,000 to about 52,000 are preferred for use in the gum base and gum of the present invention. More preferred for chewing gum bases are those of from about 10,000 to about 35,000 molecular weight, and for bubble gum bases, those having from about 30,000 to about 60,000 molecular weight. Vinyl polymers typically release flavor quickly, and using iso-alkanic waxes exhibiting small crystalline structure with these vinyl polymers extends flavor release.
  • Petroleum waxes aid in the curing of the finished gum made from the gum base as well as improve shelf-life and texture. Wax crystal size when hard also improves the release of flavor. Those waxes high in iso-alkanes have a smaller crystal size than those waxes high in normal-alkanes, especially those with normal-alkanes of carbon numbers less than 30. The smaller crystal size allows slower release of flavor since there is more hindrance of the flavor's escape from this wax versus a wax having larger crystal sizes.
  • Synthetic waxes are produced by means atypical of petroleum wax production
  • the synthetic waxes may include waxes containing branched alkanes and copolymerized with monomers such as, but not limited to, propylene and polyethylene and Fischer-Tropsch type waxes.
  • Polyethylene wax is not in the same category as polyethylene, a polymer of ethylene monomers.
  • Elastomer solvents sometimes called elastomer plasticizers
  • Elastomer plasticizers vary the firmness of the gum base. Their specificity on elastomer inter-molecular chain breaking (plasticizing) along with their varying softening points cause varying degrees of finished gum firmness when used in base. This is also important when one wishes to provide more elastomeric chain exposure to the alkanic chains of the waxes.
  • Elastomer solvents include natural rosin esters such as glycerol ester of partially hydrogenated rosin, glycerol ester of polymerized rosin, glycerol ester of partially dimerized rosin, glycerol ester of rosin, glycerol ester of tall oil rosin, pentaerythritol esters of partially hydrogenated rosin, partially hydrogenated methyl esters of rosin, pentaerythritol ester of rosin, synthetic elastomer plasticizers such as terpene resins derived from .aipha- pinene, beta-pinene and/or d-limonene, and mixtures thereof.
  • natural rosin esters such as glycerol ester of partially hydrogenated rosin, glycerol ester of polymerized rosin, glycerol ester of partially dimerized rosin, glycerol ester of rosin,
  • the elastomer solvents used may be of one type or of combinations of more than one. Typically, the ratios of one to the other are dependent on each respective softening point, on each effect on flavor release, and on each respective degree of tack they cause to the gum.
  • Ball and ring softening points of the rosin ester types described above may range from about 60 to about 120°C. Softening points of the terpene resins may range from about 60 to about 130°C and an average molecular weight of from about 500 to 2,000. Occasionally, both terpene and rosin ester resins may be used together.
  • Softeners modify the texture, cause the hydrophobic and hydrophilic components of the base to be miscible, and may further plasticize the synthetic elastomers of the gum base.
  • Softeners include fully hydrogenated oils of cottonseed, soybean, palm, palm kernel, coconut, safflower and the like, as well as monoglycerides, diglycerides, acetylated monoglycerides, distilled mono- and digiycerides and de-oiled or "powdered” lecithin.
  • the glycerides and lecithin are sometimes referred to as emulsifiers.
  • Fillers used in gum base modify the texture of the gum base and aid in processing.
  • Fillers include carbonate or precipitated carbonated types such as magnesium and calcium carbonate, ground limestone and silicate types such as magnesium and aluminum silicate, clay, alumina, talc, as well as titanium oxide, mono- di- and tricalcium phosphate, cellulose polymers such as ethyl, methyl and wood or mixtures thereof.
  • antioxidants and colorants may also be used in the gum base.
  • Antioxidants prolong shelf-life and storage of gum base, finished gum or their respective components including fats and flavor oils.
  • Antioxidants suitable for use in gum base or gum of the present invention include butyiated hydroxyanisole (BHA), butylated hydroxytoluene (BHT), beta -carotenes, tocopherols, acidulants such as Vitamin C, propyl gallate, other synthetic and natural types or mixtures thereof in free-flowing ground or pulverized form.
  • the water-insoluble (gum base) portion of the chewing gum may constitute 5 to 90% by weight of the product. More typically, the gum base will constitute 10 to 50% or 15 to 40% or 20 to 35% by weight of the chewing gum.
  • the soluble portion of chewing gums is composed of flavoring agents (including sensates such as physiological cooling agents, warming agents and tingling agents), bulking agents (also called bulk sweeteners), high intensity sweeteners, colors, acidulants, fillers, emulsifiers, water soluble softening agents and binders.
  • Bulk sweeteners include both sugars and sugar alcohols. Bulk sweeteners typically constitute about 5% to about 90% by weight of the chewing gum, more typically, about 20% to about 80% by weight, and more commonly, about 30% to about 60% by weight of the gum. Sugar sweeteners generally include saccharide-containing components commonly known in the chewing gum art, including but not limited to, sucrose, dextrose, maltose, dextrin, dried invert sugar, fructose, galactose, corn syrup solids, and the like, alone or in combination.
  • Sugarless sweeteners include, but are not limited to, sugar alcohols such as sorbitol, mannitol, xylitol, hydrogenated starch hydrolysates, maltitol, erythritol, isomalt and the like, alone or in combination.
  • sugar alcohols such as sorbitol, mannitol, xylitol, hydrogenated starch hydrolysates, maltitol, erythritol, isomalt and the like, alone or in combination.
  • High-intensity artificial sweeteners can also be used, alone or in combination, with the above.
  • Preferred sweeteners include, but are not limited to, sucralose, aspartame, N-substituted APM derivatives such as neotame, salts of acesulfame, alitame, saccharin and its salts, cyclamic acid and its salts, glycyrrhizin, dihydrochalcones, thaumatin, monellin, stevia and the like, alone or in combination.
  • Such techniques as wet granulation, wax granulation, spray drying, spray chilling, fluid bed coating, coacervation, and fiber extrusion may be used to achieve the desired release characteristics.
  • Softeners are added to the chewing gum in order to optimize the chewability and mouth feel of the gum.
  • the softeners which are also known as plasticizers and plasticizing agents, generally constitute between approximately 0.5% to about 15% by weight of the chewing gum.
  • the softeners may include glycerin, lecithin, and combinations thereof.
  • Aqueous sweetener solutions such as those containing sorbitol, hydrogenated starch hydrolysates, corn syrup and combinations thereof, may also be used as softeners and binding agents in chewing gum.
  • Combinations of sugar and/or sugarless sweeteners may be used in chewing gum. Additionally, the softener may also provide additional sweetness such as with aqueous sugar or alditol solutions.
  • a low calorie bulking agent can be used.
  • low calorie bulking agents include: polydextrose; oligofructose (Raftilose); inulin (Raftilin); fructooligosaccharides (NutraFlora); palatinose oligosaccharide; guar gum hydrolysate (BeneFiber); or indigestible dextrin (Fibersol).
  • other low calorie bulking agents can be used.
  • a variety of flavoring agents can also be used, if desired. The flavor can be used in amounts of about 0.1 to about 15 weight percent of the gum, and preferably, about 0.2% to about 5% by weight.
  • Flavoring agents may include essential oils, synthetic flavors or mixtures thereof including, but not limited to, oils derived from plants and fruits such as citrus oils, fruit essences, peppermint oil, spearmint oil, other mint oils, clove oil, oil of wintergreen, anise and the like. Artificial flavoring agents and components may also be used. Natural and artificial flavoring agents may be combined in any sensorially acceptable fashion. Included in the general category of flavors are sensates, chemicals which impart physiological sensations in the mouth such as cooling agents, warming agents and tingling agents. Examples of cooling agents include menthol, WS-23, WS-3, WS- 5, isopulegol, esters of menthol such as menthyl succinate, menthyl lactate and menthyl glutarate, among others. Warming and tingling agents include capsaicin, piperine, jambu and spilanthol.
  • the chewing gum ingredients will include one or more high intensity sweeteners.
  • the term 'high intensity sweetener' refers to any substance that is at least twenty times sweeter than sucrose.
  • Such sweeteners include saccharin, cyclamate, aspartame, alitame, neotame, other peptide-based sweeteners, sucralose, acesulfame K, stevia (including purified extracts such as rebaudioside A), glycyrrhizin, neohesperidin dihydrochalcone and mixtures thereof.
  • at least a portion of the high intensity sweetener will be encapsulated.
  • Such encapsulations may be produced by granulation, agglomeration, extrusion and grinding, spray drying, fluid bed encapsulation or any other known means. Usage levels will depend on the potency of the sweetener, degree and effectiveness of the encapsulation (if any) as well as the sensory profile desired for the product. Generally, the sweetener will be used at levels as low as 0.005% or as low as 0.05% or at least 0.2% to as high 5% or 3% or 2% in the chewing gum composition. In some embodiments, the high intensity sweetener will be present at a level of 0.1 to 1 .0% of the chewing gum ingredients. [0042] In the case of savory flavors such as popcorn, cheese, beef jerky, bacon or potato chip flavors, it may be desirable to include salt in the formula.
  • a coating may be applied to the extruded chewing gum. Normally this will be accomplished by pan coating the chewing gum piece.
  • a coating syrup typically a sugar or sugar alcohol solution
  • the pellets are dried, preferably by passing a current of heated and/or dried air over or through the pellet bed.
  • Numerous layers of coating are built up, often alternating with applications of powdered coating material or an inert filler to accelerate the build-up of the coating.
  • a final layer of a polishing compound for example carnauba wax, may be applied.
  • coating materials include maltitol, isomalt, xylitol, sorbitol and erythritol, although others may be used as well.
  • coating syrup may include film forming agents such as Gum Arabic, high intensity sweeteners, flavors and colors.
  • Control Run 1 included 2% powder xylitol to eliminate any effect form the xylitol itself.
  • a sample of xylitol solution having 30% moisture (70% solids) was obtained from Huakang Pharmaceutical Co in Zhejiang, China. The solution contained at least 1 .7% of polyols other than xylitol and less than 0.25% xylose by weight of dry solids.
  • the chewing gums were mixed by conventional processing techniques and formed into tabs for testing.
  • the bare tabs were stored under conditions of 45°C, 85% RH for a period of seven days, then tested for moisture content (percent moisture uptake or loss) and moisture activity to determine their moisture stability.
  • the inventive examples were found to be about as good or slightly better at resisting moisture absorption during the test.

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Food Science & Technology (AREA)
  • Polymers & Plastics (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Confectionery (AREA)

Abstract

Une gomme à mâcher selon l'invention contient une solution de xylitol en tant que ramollissant pour la masse de gomme à mâcher. La solution de xylitol est le produit d'hydrogénation du xylose et comprend des impuretés telles que d'autres sucres ou alcools de sucre qui sont les sous-produits naturels du processus de production de xylitol. La solution de xylitol fournit des avantages de durée de conservation sensorielle et environnementaux par comparaison aux formules de gomme à mâcher de l'art antérieur.
PCT/US2016/054141 2015-09-30 2016-09-28 Gomme à mâcher comprenant du xylitol liquide en tant qu'agent ramollissant WO2017058890A1 (fr)

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US201562235454P 2015-09-30 2015-09-30
US62/235,454 2015-09-30

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Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5144024A (en) * 1990-10-11 1992-09-01 Tammy Pepper Shelf stable liquid xylitol compositions
US5536511A (en) * 1994-05-06 1996-07-16 Wm. Wrigley Jr. Company Chewing gum pellet coated with a hard coating containing erythritol and xylitol

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5144024A (en) * 1990-10-11 1992-09-01 Tammy Pepper Shelf stable liquid xylitol compositions
US5536511A (en) * 1994-05-06 1996-07-16 Wm. Wrigley Jr. Company Chewing gum pellet coated with a hard coating containing erythritol and xylitol

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