WO2017035106A1 - Laser sealed housing for electronic device - Google Patents
Laser sealed housing for electronic device Download PDFInfo
- Publication number
- WO2017035106A1 WO2017035106A1 PCT/US2016/048103 US2016048103W WO2017035106A1 WO 2017035106 A1 WO2017035106 A1 WO 2017035106A1 US 2016048103 W US2016048103 W US 2016048103W WO 2017035106 A1 WO2017035106 A1 WO 2017035106A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- laser
- chamber
- substrate
- electronic device
- weld
- Prior art date
Links
- 239000000758 substrate Substances 0.000 claims abstract description 119
- 238000000034 method Methods 0.000 claims abstract description 25
- 239000000463 material Substances 0.000 claims description 45
- 238000002844 melting Methods 0.000 claims description 18
- 230000008018 melting Effects 0.000 claims description 18
- 239000011521 glass Substances 0.000 claims description 16
- 230000015572 biosynthetic process Effects 0.000 claims description 11
- 238000005530 etching Methods 0.000 claims description 11
- 238000001429 visible spectrum Methods 0.000 claims description 4
- 238000002329 infrared spectrum Methods 0.000 claims description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 2
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 2
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 2
- 229910052802 copper Inorganic materials 0.000 claims description 2
- 239000010949 copper Substances 0.000 claims description 2
- AMGQUBHHOARCQH-UHFFFAOYSA-N indium;oxotin Chemical compound [In].[Sn]=O AMGQUBHHOARCQH-UHFFFAOYSA-N 0.000 claims description 2
- 229910052750 molybdenum Inorganic materials 0.000 claims description 2
- 239000011733 molybdenum Substances 0.000 claims description 2
- 229910052709 silver Inorganic materials 0.000 claims description 2
- 239000004332 silver Substances 0.000 claims description 2
- 229910052723 transition metal Inorganic materials 0.000 claims description 2
- 150000003624 transition metals Chemical class 0.000 claims description 2
- 238000002211 ultraviolet spectrum Methods 0.000 claims description 2
- 238000007789 sealing Methods 0.000 description 8
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
- 229910052760 oxygen Inorganic materials 0.000 description 4
- 239000001301 oxygen Substances 0.000 description 4
- 230000008569 process Effects 0.000 description 4
- 230000008901 benefit Effects 0.000 description 3
- 238000009792 diffusion process Methods 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 239000004020 conductor Substances 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 239000007888 film coating Substances 0.000 description 2
- 238000009501 film coating Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 239000005361 soda-lime glass Substances 0.000 description 2
- 230000005068 transpiration Effects 0.000 description 2
- 241000282575 Gorilla Species 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 238000004026 adhesive bonding Methods 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000005538 encapsulation Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 238000005304 joining Methods 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000003701 mechanical milling Methods 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000002096 quantum dot Substances 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K26/00—Working by laser beam, e.g. welding, cutting or boring
- B23K26/02—Positioning or observing the workpiece, e.g. with respect to the point of impact; Aligning, aiming or focusing the laser beam
- B23K26/06—Shaping the laser beam, e.g. by masks or multi-focusing
- B23K26/062—Shaping the laser beam, e.g. by masks or multi-focusing by direct control of the laser beam
- B23K26/0622—Shaping the laser beam, e.g. by masks or multi-focusing by direct control of the laser beam by shaping pulses
- B23K26/0624—Shaping the laser beam, e.g. by masks or multi-focusing by direct control of the laser beam by shaping pulses using ultrashort pulses, i.e. pulses of 1ns or less
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K26/00—Working by laser beam, e.g. welding, cutting or boring
- B23K26/08—Devices involving relative movement between laser beam and workpiece
- B23K26/082—Scanning systems, i.e. devices involving movement of the laser beam relative to the laser head
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K26/00—Working by laser beam, e.g. welding, cutting or boring
- B23K26/08—Devices involving relative movement between laser beam and workpiece
- B23K26/0869—Devices involving movement of the laser head in at least one axial direction
- B23K26/0876—Devices involving movement of the laser head in at least one axial direction in at least two axial directions
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K26/00—Working by laser beam, e.g. welding, cutting or boring
- B23K26/20—Bonding
- B23K26/206—Laser sealing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K26/00—Working by laser beam, e.g. welding, cutting or boring
- B23K26/20—Bonding
- B23K26/21—Bonding by welding
- B23K26/211—Bonding by welding with interposition of special material to facilitate connection of the parts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K26/00—Working by laser beam, e.g. welding, cutting or boring
- B23K26/20—Bonding
- B23K26/32—Bonding taking account of the properties of the material involved
- B23K26/324—Bonding taking account of the properties of the material involved involving non-metallic parts
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K50/00—Organic light-emitting devices
- H10K50/80—Constructional details
- H10K50/84—Passivation; Containers; Encapsulations
- H10K50/842—Containers
- H10K50/8426—Peripheral sealing arrangements, e.g. adhesives, sealants
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K59/00—Integrated devices, or assemblies of multiple devices, comprising at least one organic light-emitting element covered by group H10K50/00
- H10K59/80—Constructional details
- H10K59/87—Passivation; Containers; Encapsulations
- H10K59/871—Self-supporting sealing arrangements
- H10K59/8722—Peripheral sealing arrangements, e.g. adhesives, sealants
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K71/00—Manufacture or treatment specially adapted for the organic devices covered by this subclass
- H10K71/40—Thermal treatment, e.g. annealing in the presence of a solvent vapour
- H10K71/421—Thermal treatment, e.g. annealing in the presence of a solvent vapour using coherent electromagnetic radiation, e.g. laser annealing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K2101/00—Articles made by soldering, welding or cutting
- B23K2101/36—Electric or electronic devices
- B23K2101/42—Printed circuits
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K2103/00—Materials to be soldered, welded or cut
- B23K2103/08—Non-ferrous metals or alloys
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K2103/00—Materials to be soldered, welded or cut
- B23K2103/50—Inorganic material, e.g. metals, not provided for in B23K2103/02 – B23K2103/26
- B23K2103/54—Glass
Definitions
- the disclosure relates generally to sealed electronic device housing and specifically to hermetically sealed, glass structures for electronic devices, such as organic LEDs
- OLEDs In general, hermetic sealing of OLED displays is needed to provide barriers against materials, such as water and oxygen. Typically, frit sealing is used to adhesively bond together two substrates around each OLED cell in an OLED display.
- the housing includes a first substrate having a first surface and a second substrate having a second surface facing the first surface.
- the housing includes a recess formed in the first substrate, and the recess faces the second surface such that the second surface and the recess define a chamber.
- the housing includes a laser weld bonding the first surface to the second surface, and the laser weld surrounds the chamber.
- the housing includes a functional film supported by at least one of the first surface and the second surface, and the functional film extends from the chamber and across the laser weld.
- An additional embodiment of the disclosure relates to a sealed electronic device.
- the device includes a first glass substrate having a first surface and a second glass substrate having a second surface facing the first surface.
- the device includes a chamber defined between the first surface and the second surface.
- the device includes a hermetic seal surrounding the chamber, and the seal is formed from a portion of the first substrate joined together with a portion of the second substrate.
- the device includes a functional film forming extending from the chamber and across the seal.
- An additional embodiment of the disclosure relates to a method of forming a sealed electronic device housing.
- the method includes providing a first substrate having a first surface.
- the method includes providing a second substrate having a second surface.
- the method includes forming a recess in the first surface of the first substrate.
- the method includes placing the first substrate adjacent to the second substrate such that first surface l faces the second surface and the recess forms a chamber with an opposing portion of the second surface of the second substrate.
- the method includes providing a functional film on at least one of the first surface and the second surface.
- the method includes forming a weld between the first surface and the second surface using a laser, wherein the weld surrounds the chamber and traverses the functional film, and the functional film extends from the chamber across the weld.
- FIG. 1 shows a top view of a laser sealed electronic device according to an exemplary embodiment.
- FIG. 2 shows a side cross-sectional view of a laser sealed electronic device according to an exemplary embodiment.
- FIG. 3 shows a detailed view of a lead traversing a laser weld of the electronic device of FIG. 2 according to an exemplary embodiment.
- FIGS. 4A-4D shows a schematic view of a process for forming a laser sealed electronic device according to an exemplary embodiment.
- the sealed electronic device discussed herein includes two opposing substrates (e.g., glass sheet substrates) with a recess or chamber formed between the two substrates, and an active component, such as an OLED, located within the chamber.
- a weld surrounds the chamber hermetically sealing the active component within the chamber.
- the weld is a laser weld formed by portions of the first and second substrates that are joined or melted together using a laser.
- the laser welds discussed herein are cohesive structures which form a strong and hermetic seal around the chamber.
- a functional film is located on at least one of the substrates and forms a path extending from the chamber and across the laser weld, and in specific embodiments, the functional film is a conductive material forming first and second electrically conductive leads extending across the laser weld providing electrical conduction to the active component located with the chamber.
- sealing of conventional electronic devices that utilize frit-based sealing is based on adhesive bonding between the frit and the adjacent substrate materials.
- the laser-welded electronic devices discussed herein provides cohesive laser welds having low thickness and high weld strength as compared to frit sealed devices.
- OLED device 10 includes first and second substrates, shown as bottom substrate 12 and upper substrate 14.
- Bottom substrate 12 includes a first surface, shown as upper surface 16, facing a second surface, shown as lower surface 18, of upper substrate 14.
- substrates 12 and 14 are sheets of a glass material (e.g., soda- lime glass, Gorilla ® glass sheet material available from Corning, Inc, Eagle XG® glass sheet material available from Coming, Inc., etc.).
- upper surface 16 and lower surface 18 are major surfaces of the substrates.
- At least one of substrates 12 and 14 includes a recess formed in the material of the substrate.
- a recess 20 is formed in upper substrate 14.
- a chamber 22 is defined between the portion of the lower surface of upper substrate 14 defining recess 20 and a portion of upper surface 16 of lower substrate 12.
- Chamber 22 includes a space within which an active component, such as an active electronic component, shown as OLED 24, is located. While FIG. 2 shows recess 20 and chamber 22 as substantially rectangular in cross- sectional shape, recess 20 and chamber 22 may be any suitable shape for containing an active electronic component, such as OLED 24, including various curved or dome shapes.
- the active electronic component may also be an organic electronic device or organic-inorganic hybrid electronic device.
- OLED device 10 may be used in a variety of applications such as electronic displays, and may be used in small displays such as mobile device displays or large displays such as TV displays, monitors, etc.
- the active component may be any electronic component, including various semi-conductor devices, including photovoltaic devices.
- the hermetic encapsulation of an active component using the materials and methods disclosed here can facilitate long-lived operation of devices otherwise sensitive to degradation by oxygen and/or moisture.
- device 10 includes flexible, rigid or semi-rigid organic LEDs, OLED lighting, OLED televisions, MEMs displays, electrochromic windows, fluorophores, alkali metal electrodes, transparent conducting oxides, quantum dots, etc.
- Device 10 includes a hermetic seal, shown as laser weld 26 surrounding chamber 22.
- laser weld 26 bonds together substrates 12 and 14 coupling the substrates relative to each other and hermetically sealing OLED 24 within chamber 22.
- laser weld 26 is a closed perimeter seal formed between substrates 12 and 14.
- frit sealed electronic devices include a bead of frit that is melted between opposing substrates such that adhesive bonds are formed between the frit and both of the opposing substrates, and in this type of arrangement, the frit material adhesively bonded between the substrates act to form the hermetic seal around the OLED.
- laser weld 26 is a cohesive structure formed from opposing portions of substrates 12 and 14 that are joined together, such as by melting. It is believed that the cohesive weld structure of laser weld 26 provides stronger bonding with a lower overall thickness as compared to the adhesive-based bonding structure of a frit sealed electronic device.
- joining together of substrates includes a weld formed by one or both of the substrates attaining viscoelastic flow from increased temperatures (e.g., laser induced temperatures) and being thermo-compressed together, a diffusion weld and/or a weld formed where the melting point of the substrates is exceeded.
- the fictive temperature of the material of substrates 12 and 14 is changed relative to the fictive temperature of the material of substrates 12 and 14 outside of laser weld 26.
- the fictive temperature of the material of substrates 12 and 14 is greater than the fictive temperature of the material of substrates 12 and 14 outside of laser weld 26.
- laser weld 26 can be reinforced with a perimeter seal surrounding OLED 24.
- Device 10 includes at least one functional film material supported by at least one of substrates 12 and 14 and that forms a path extending from within chamber 22 and across laser weld 26.
- the functional film is a material located on (e.g., in direct contact with) upper surface 16 of lower substrate 12 forming a first lead 30 and a second lead 32.
- Leads 30 and 32 provide electrically conductive paths extending from within chamber 22 and across laser weld 26, and in particular, leads 30 and 32 are electrically coupled OLED 24, such as to deliver electrical power to OLED 24.
- leads 30 and 32 are formed from one or more material that maintains electrical conductivity even after formation of laser weld 26 while also allowing hermetic sealing of the melted portions of substrates 12 and 14 around the leads.
- laser weld 26 may be formed in a variety of suitable ways in which the materials of substrates 12 and 14 are melted together through the use of laser energy shown schematically in FIG. 2 as laser 34.
- laser 34 may be a short pulse laser of sufficient energy to melt together portions of substrates 12 and 14 to form laser weld 26, and in such embodiments, a laser absorption film is not used to form laser weld 26.
- at least one of substrates 12 and 14 includes a laser absorbing film 38.
- laser absorbing film 38 is located on lower surface 18 of upper substrate 14 opposing the material of leads 30 and 32. In this specific arrangement, leads 30 and 32 have surfaces that are in contact with laser absorbing film 38.
- laser absorbing film 38 absorbs energy from laser 34 facilitating melting of substrates 12 and 14 and formation of laser weld 26.
- substrates 12 and 14 are translucent/transparent (e.g., 60%, 70%, 80%, 90% transmission) to laser 34 allowing laser 34 to pass through at least one of the substrates and to interact with laser absorbing film 38.
- laser weld 26, leads 30 and 32, and laser absorbing film 38 are sized and structured to facilitate formation of a low-thickness, hermetically sealed electronic device.
- laser weld 26 has a width, Wl , and leads 30 and 32 have widths, W2.
- Wl is between 20 ⁇ and 700 ⁇
- W2 is between 50 ⁇ and 20 mm.
- widths of the components discussed herein are the minor dimensions of the components measured in a direction parallel to the major surfaces of the substrates.
- FIG. 3 a detailed view of a portion of device 10 at laser weld 26 is shown according to an exemplary embodiment.
- lead 30 has a thickness, Tl
- laser absorbing film 38 has a thickness
- T2 has a height, HI .
- Tl is between 20 nm and 1 ⁇ , and in a specific embodiment, both leads 30 and 32 have thicknesses within this range.
- T2 is less than 1.5 ⁇ , and in a specific embodiment, is between 0.2 ⁇ and 1 ⁇ .
- HI is between 0.3 ⁇ and 500 ⁇ , specifically is between 1 ⁇ and 10 ⁇ , and more specifically is between 1 ⁇ and 5 ⁇ . In a specific embodiment, HI is between 3 ⁇ and 4 ⁇ .
- the relative sizes of leads 30 and 32, chamber 22 and laser weld 26 facilitate formation of device 10 having a low total thickness.
- T2 is less than 20% of HI .
- Tl is less than 20% of H2.
- both Tl and T2 are less than 20% of HI .
- thicknesses or heights of the components discussed herein are the dimensions of the components measured in a direction perpendicular to the major surfaces of the substrates.
- the widths, thicknesses and heights discussed herein represent maximum measured dimensions, and in other embodiments, the widths, thicknesses and heights discussed herein represent average measured dimensions.
- the width of laser weld 26 is larger than absorbing film 38 thickness.
- the width and/or thickness of the portion of the substrates that have a change in glass Active temperature around laser weld 26 is greater than the thickness of absorbing film 38.
- the width and/or thickness of of the entire weld region (including the residual stress portion) exceeds the thickness of the absorbing film 38.
- a survey of the local density distribution, or fictive temperature distribution, in the vicinity of the weld can be used to determine this relative dimensions.
- leads 30 and 32 are structured to maintain a satisfactory level of conductivity following formation of laser weld 26.
- leads 30 and 32 are structured such that the temperature needed to cause the melting of the materials of substrates 12 and 14 does not eliminate or significantly reduce the conductivity of leads 30 and 32.
- leads 30 and 32 are formed from a material having a melting temperature that is greater than the melting temperature of the material of substrates 12 and 14.
- leads 30 and 32 are formed from a material having a melting temperature that is at least 10% greater than the melting point temperature and/or the softening point temperature of the material of substrates 12 and 14.
- leads 30 and 32 are formed from a material having a melting temperature that is greater than 700 degrees C, and in another embodiment, leads 30 and 32 are formed from a material having a melting temperature that is greater than 800 degrees C. In a specific embodiment, leads 30 and 32 are formed from a material having a melting temperature that is between 800 degrees C and 900 degrees C. In such embodiments, substrates 12 and 14 may be made from a soda-lime glass material having a softening point of about 700 degrees C, and in other embodiments, substrates 12 and 14 may be made from Eagle XG® glass sheet material available from Corning, Inc. which has a softening point of about 970 degrees C. In various embodiments, leads 30 and 32 are made from a material that experiences an increase in resistivity following formation of laser weld 26 that is less than 30%.
- leads 30 and 32 may be formed from any suitable conductive material.
- leads 30 and 32 are formed from at least one of indium tin oxide (ITO), molybdenum, silver, or copper.
- laser absorbing film 38 is formed from any material suitable for absorbing laser energy to facilitate melting of substrates 12 and 14 to form laser weld 26.
- laser absorbing film 38 is a material that absorbs any suitable wavelength of laser energy including ultraviolet spectrum laser energy, infrared spectrum laser energy, near infrared spectrum laser energy and visible spectrum laser energy.
- laser absorbing film 38 is a material that absorbs in the 200-410 nm wavelength range, and in other embodiments, , laser absorbing film 38 is a material that absorbs in the 800 - 1900 nm wavelength range.
- laser absorbing film 38 is formed from at least one of a low melting glass (LMG) having a Tg less than 600 degrees C, ZnO, SnO, T1O2, ⁇ Os, and a glass film doped with a transition metal, such as Fe, Mn, Cu, Va, Cr.
- LMG low melting glass
- transition metal such as Fe, Mn, Cu, Va, Cr.
- laser absorbing film 38 is absorbing at a non-visible spectrum of laser 34 while being transparent/translucent to visible light.
- the laser absorbing film and substrates 12 and 14 are transparent to light within a wavelength range of 420 nm to 750 nm.
- laser absorbing film 38 is absorbing at a non-visible spectrum of laser 34 while being opaque to visible light.
- device 10 may include other functional films.
- the functional film traversing laser weld 26 may be a protective film material, such as an SiN film.
- FIGS. 2 and 3 show leads 30 and 32 as a single layered film, in other embodiments, the functional films discussed herein may include multiple layers, such as a film stack.
- the functional films and/or laser absorbing films discussed herein may be supported from substrates 12 and 14 via one or more intervening layer, and in other embodiments, the functional films and/or laser absorbing films discussed herein may be supported from substrates 12 and 14 via direct contact with the material of the substrates.
- FIGS. 4A-4D a method of forming a sealed electronic device, such as device 10, is shown according to an exemplary embodiment.
- a first substrate such as upper substrate 14, and a second substrate, such as lower substrate 12, are provided.
- a recess is formed in one of the substrates, and in the specific embodiment shown, recess 20 is formed in substrate 14.
- substrate 14 is placed adjacent to substrate 12 such that recess 20 will form a chamber (e.g., chamber 22) with the opposing upper surface of substrate 12.
- a a functional film, such as leads 30 and 32, is provided on one of the surfaces of substrates 12 and 14.
- a weld such as laser weld 26 is formed between the opposing surfaces of substrates 12 and 14.
- a laser such as laser 34 may be moved, aimed or otherwise directed onto substrates 12 and 14 such that laser weld 26 is formed surrounding chamber 22.
- leads 30 and 32 extend into chamber 22.
- substrate 14 may be provided with laser absorbing film 38 along one surface of the substrate.
- a portion of laser absorbing film 38 is removed from within the region that forms recess 20, and in this arrangement, the remaining portion of laser absorbing film 38 surrounds recess 20.
- the portion of laser absorbing film 38 is removed from substrate 14 via an etching process, and, recess 20 is formed in substrate 14 via an etching process.
- the same etching step both removes laser absorbing film 38 and forms recess 20.
- etching may be performed with acid or via reactive etching.
- etching depth (HI , shown in FIG. 3 above) is controlled by controlling timing of etching.
- substrates 12 and 14 may be provided to a OLED device manufacturer, and etching will occur locally immediately prior to sealing with laser 34.
- the device and methods discussed herein may provide various benefits including: 1) less steps in the manufacturing process, 2) using less expensive phosphor material, and also using less expensive scattering material, 3) better scattering uniformity attributes.
- laser 34 has a wavelength selected to interact with the particular laser absorbing film.
- laser 34 may be a UV, IR or visible light laser, and laser absorbing film 38 is selected to absorb within the wavelength of laser 34.
- various aspects of laser 34 may be controlled to facilitate formation of laser weld 36 while maintaining the functionality of leads 30 and 32.
- the power and scanning speed of laser 34 may be controlled during formation of laser weld 26.
- laser 34 is a 355 nm laser with a power between 0.1 W and 1.0 W, and specifically, 0.1 W and 0.5 W.
- laser 34 is a 355 nm laser with a power of 0.6 W and a scanning speed of between 10 mm/s and 50 mm/s, and specifically of 25 mm/s, and laser absorbing film 38 is LMG film coating.
- the LMG film coating 38 has a thickness of 1 ⁇
- leads 30 and 32 are ITO leads that have a thickness of 150 nm.
- laser 34 may be a laser, such as a short pulse laser, capable of forming laser weld 26 without the absorbing film.
- the lasers, processes and materials may be any of those disclosed in U.S. Publication No. 2015/0027168 (U. S. Application No. 14/271 ,797, filed May 7, 2014), which is incorporated herein by reference in its entirety.
- a hermetic seal and/or hermetically sealed device is one which, for practical purposes, is considered substantially airtight and substantially impervious to moisture and/ or oxygen.
- laser weld 26 can be configured to limit the transpiration (diffusion) of oxygen to less than about 10 cm 3 /m /day (e.g., less than about 1(P cm7m 2 /day), and limit the transpiration (diffusion) of water to about 10 ⁇ g m7day (e.g., less than about 10 3 , 10 4 , 10 5 or 10 ⁇ ° g/ni7day).
- the hermetic seal substantially inhibits air and water from contacting a pretectal active element, such as OLED 24.
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- Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Engineering & Computer Science (AREA)
- Plasma & Fusion (AREA)
- Mechanical Engineering (AREA)
- Electromagnetism (AREA)
- Manufacturing & Machinery (AREA)
- Electroluminescent Light Sources (AREA)
Abstract
A laser-welded, sealed electronic device housing and related systems and methods are provided. The sealed housing includes a first substrate having a first surface and a second substrate having a second surface facing the first surface. The sealed housing includes a recess formed in the first substrate. The recess faces the second surface such that the second surface and the recess define a chamber. A laser weld bonds the first surface to the second surface, and the laser weld surrounds the chamber. A functional film is supported by at least one of the first surface and the second surface, and the functional film extends from the chamber and across the laser weld. In exemplary arrangements the device is an OLED device and the functional film form conductive leads in communication with the OLED.
Description
LASER SEALED HOUSING FOR ELECTRONIC DEVICE
[0001] This application claims the benefit of priority under 35 U.S.C. § 119 of U.S.
Provisional Application Serial No. 62/208900, filed on August 24, 2015, the content of which is relied upon and incorporated herein by reference in its entirety.
BACKGROUND
[0002] The disclosure relates generally to sealed electronic device housing and specifically to hermetically sealed, glass structures for electronic devices, such as organic LEDs
(OLEDs). In general, hermetic sealing of OLED displays is needed to provide barriers against materials, such as water and oxygen. Typically, frit sealing is used to adhesively bond together two substrates around each OLED cell in an OLED display.
SUMMARY
[0003] One embodiment of the disclosure relates to a laser-welded, sealed electronic device housing. The housing includes a first substrate having a first surface and a second substrate having a second surface facing the first surface. The housing includes a recess formed in the first substrate, and the recess faces the second surface such that the second surface and the recess define a chamber. The housing includes a laser weld bonding the first surface to the second surface, and the laser weld surrounds the chamber. The housing includes a functional film supported by at least one of the first surface and the second surface, and the functional film extends from the chamber and across the laser weld.
[0004] An additional embodiment of the disclosure relates to a sealed electronic device. The device includes a first glass substrate having a first surface and a second glass substrate having a second surface facing the first surface. The device includes a chamber defined between the first surface and the second surface. The device includes a hermetic seal surrounding the chamber, and the seal is formed from a portion of the first substrate joined together with a portion of the second substrate. The device includes a functional film forming extending from the chamber and across the seal.
[0005] An additional embodiment of the disclosure relates to a method of forming a sealed electronic device housing. The method includes providing a first substrate having a first surface. The method includes providing a second substrate having a second surface. The method includes forming a recess in the first surface of the first substrate. The method includes placing the first substrate adjacent to the second substrate such that first surface l
faces the second surface and the recess forms a chamber with an opposing portion of the second surface of the second substrate. The method includes providing a functional film on at least one of the first surface and the second surface. The method includes forming a weld between the first surface and the second surface using a laser, wherein the weld surrounds the chamber and traverses the functional film, and the functional film extends from the chamber across the weld.
[0006] Additional features and advantages will be set forth in the detailed description that follows, and, in part, will be readily apparent to those skilled in the art from the description or recognized by practicing the embodiments as described in the written description and claims hereof, as well as the appended drawings.
[0007] It is to be understood that both the foregoing general description and the following detailed description are merely exemplary, and are intended to provide an overview or framework to understand the nature and character of the claims.
[0008] The accompanying drawings are included to provide a further understanding and are incorporated in and constitute a part of this specification. The drawings illustrate one or more embodiment(s), and together with the description serve to explain principles and the operation of the various embodiments.
BRIEF DESCRIPTION OF THE DRAWINGS
[0009] FIG. 1 shows a top view of a laser sealed electronic device according to an exemplary embodiment.
[0010] FIG. 2 shows a side cross-sectional view of a laser sealed electronic device according to an exemplary embodiment.
[0011] FIG. 3 shows a detailed view of a lead traversing a laser weld of the electronic device of FIG. 2 according to an exemplary embodiment.
[0012] FIGS. 4A-4D shows a schematic view of a process for forming a laser sealed electronic device according to an exemplary embodiment.
DETAILED DESCRIPTION
[0013] Referring generally to the figures, various embodiments of a sealed electronic device, such as a sealed OLED device, are shown and described. In general, the sealed electronic device discussed herein includes two opposing substrates (e.g., glass sheet substrates) with a recess or chamber formed between the two substrates, and an active component, such as an OLED, located within the chamber. A weld surrounds the chamber hermetically sealing the active component within the chamber. In specific embodiments, the
weld is a laser weld formed by portions of the first and second substrates that are joined or melted together using a laser. Thus, in general the laser welds discussed herein are cohesive structures which form a strong and hermetic seal around the chamber. In various
embodiments, a functional film is located on at least one of the substrates and forms a path extending from the chamber and across the laser weld, and in specific embodiments, the functional film is a conductive material forming first and second electrically conductive leads extending across the laser weld providing electrical conduction to the active component located with the chamber. As will be understood, sealing of conventional electronic devices that utilize frit-based sealing is based on adhesive bonding between the frit and the adjacent substrate materials. In contrast to the conventional frit sealed devices, the laser-welded electronic devices discussed herein provides cohesive laser welds having low thickness and high weld strength as compared to frit sealed devices.
[0014] Referring to FIGS. 1 and 2, a sealed electronic device housing an electronic device, shown as OLED device 10, is shown. OLED device 10 includes first and second substrates, shown as bottom substrate 12 and upper substrate 14. Bottom substrate 12 includes a first surface, shown as upper surface 16, facing a second surface, shown as lower surface 18, of upper substrate 14. In general, substrates 12 and 14 are sheets of a glass material (e.g., soda- lime glass, Gorilla ® glass sheet material available from Corning, Inc, Eagle XG® glass sheet material available from Coming, Inc., etc.). In the arrangement shown, upper surface 16 and lower surface 18 are major surfaces of the substrates.
[0015] At least one of substrates 12 and 14 includes a recess formed in the material of the substrate. In the embodiment shown, a recess 20 is formed in upper substrate 14. When upper substrate 14 is located on lower substrate 12, as shown in FIG. 2, a chamber 22 is defined between the portion of the lower surface of upper substrate 14 defining recess 20 and a portion of upper surface 16 of lower substrate 12. Chamber 22 includes a space within which an active component, such as an active electronic component, shown as OLED 24, is located. While FIG. 2 shows recess 20 and chamber 22 as substantially rectangular in cross- sectional shape, recess 20 and chamber 22 may be any suitable shape for containing an active electronic component, such as OLED 24, including various curved or dome shapes. In various embodiments, the active electronic component may also be an organic electronic device or organic-inorganic hybrid electronic device.
[0016] In various embodiments, OLED device 10 may be used in a variety of applications such as electronic displays, and may be used in small displays such as mobile device displays
or large displays such as TV displays, monitors, etc. In various embodiments, the active component may be any electronic component, including various semi-conductor devices, including photovoltaic devices. In various embodiments, the hermetic encapsulation of an active component using the materials and methods disclosed here can facilitate long-lived operation of devices otherwise sensitive to degradation by oxygen and/or moisture. In exemplary embodiments, device 10 includes flexible, rigid or semi-rigid organic LEDs, OLED lighting, OLED televisions, MEMs displays, electrochromic windows, fluorophores, alkali metal electrodes, transparent conducting oxides, quantum dots, etc.
[0017] Device 10 includes a hermetic seal, shown as laser weld 26 surrounding chamber 22. In general, laser weld 26 bonds together substrates 12 and 14 coupling the substrates relative to each other and hermetically sealing OLED 24 within chamber 22. In one embodiment, laser weld 26 is a closed perimeter seal formed between substrates 12 and 14.
[0018] As will be understood, frit sealed electronic devices include a bead of frit that is melted between opposing substrates such that adhesive bonds are formed between the frit and both of the opposing substrates, and in this type of arrangement, the frit material adhesively bonded between the substrates act to form the hermetic seal around the OLED. In contrast to frit sealed devices, laser weld 26 is a cohesive structure formed from opposing portions of substrates 12 and 14 that are joined together, such as by melting. It is believed that the cohesive weld structure of laser weld 26 provides stronger bonding with a lower overall thickness as compared to the adhesive-based bonding structure of a frit sealed electronic device. It should be understood that as used herein joining together of substrates includes a weld formed by one or both of the substrates attaining viscoelastic flow from increased temperatures (e.g., laser induced temperatures) and being thermo-compressed together, a diffusion weld and/or a weld formed where the melting point of the substrates is exceeded. In various embodiments, within laser weld 26, the fictive temperature of the material of substrates 12 and 14 is changed relative to the fictive temperature of the material of substrates 12 and 14 outside of laser weld 26. In specific embodiments, within laser weld 26, the fictive temperature of the material of substrates 12 and 14 is greater than the fictive temperature of the material of substrates 12 and 14 outside of laser weld 26. In one embodiment, laser weld 26 can be reinforced with a perimeter seal surrounding OLED 24.
[0019] Device 10 includes at least one functional film material supported by at least one of substrates 12 and 14 and that forms a path extending from within chamber 22 and across laser weld 26. In the embodiment shown in FIGS. 1 and 2, the functional film is a material located
on (e.g., in direct contact with) upper surface 16 of lower substrate 12 forming a first lead 30 and a second lead 32. Leads 30 and 32 provide electrically conductive paths extending from within chamber 22 and across laser weld 26, and in particular, leads 30 and 32 are electrically coupled OLED 24, such as to deliver electrical power to OLED 24. As will be explained in more detail below, leads 30 and 32 are formed from one or more material that maintains electrical conductivity even after formation of laser weld 26 while also allowing hermetic sealing of the melted portions of substrates 12 and 14 around the leads.
[0020] In various embodiments, laser weld 26 may be formed in a variety of suitable ways in which the materials of substrates 12 and 14 are melted together through the use of laser energy shown schematically in FIG. 2 as laser 34. In one embodiment, laser 34 may be a short pulse laser of sufficient energy to melt together portions of substrates 12 and 14 to form laser weld 26, and in such embodiments, a laser absorption film is not used to form laser weld 26. In another embodiment, at least one of substrates 12 and 14 includes a laser absorbing film 38. In the specific embodiment shown, laser absorbing film 38 is located on lower surface 18 of upper substrate 14 opposing the material of leads 30 and 32. In this specific arrangement, leads 30 and 32 have surfaces that are in contact with laser absorbing film 38. In general, laser absorbing film 38 absorbs energy from laser 34 facilitating melting of substrates 12 and 14 and formation of laser weld 26. In specific embodiments, substrates 12 and 14 are translucent/transparent (e.g., 60%, 70%, 80%, 90% transmission) to laser 34 allowing laser 34 to pass through at least one of the substrates and to interact with laser absorbing film 38.
[0021] In various embodiments, laser weld 26, leads 30 and 32, and laser absorbing film 38 are sized and structured to facilitate formation of a low-thickness, hermetically sealed electronic device. As shown in FIG. 1 , laser weld 26 has a width, Wl , and leads 30 and 32 have widths, W2. In various embodiments, Wl is between 20 μιτι and 700 μιτι, and W2 is between 50 μιτι and 20 mm. In such embodiments, widths of the components discussed herein are the minor dimensions of the components measured in a direction parallel to the major surfaces of the substrates.
[0022] Referring to FIG. 3, a detailed view of a portion of device 10 at laser weld 26 is shown according to an exemplary embodiment. As shown in FIG. 3, lead 30 has a thickness, Tl , laser absorbing film 38 has a thickness, T2, and chamber 22 has a height, HI . In various embodiments, Tl is between 20 nm and 1 μιη, and in a specific embodiment, both leads 30 and 32 have thicknesses within this range. In various embodiments, T2 is less than 1.5 μιτι,
and in a specific embodiment, is between 0.2 μιτι and 1 μιτι. In various embodiments, HI is between 0.3 μιτι and 500 μιτι, specifically is between 1 μιτι and 10 μιτι, and more specifically is between 1 μιτι and 5 μιτι. In a specific embodiment, HI is between 3 μιτι and 4 μιτι.
[0023] In various embodiments, the relative sizes of leads 30 and 32, chamber 22 and laser weld 26 facilitate formation of device 10 having a low total thickness. For example, in one embodiment, T2 is less than 20% of HI . In another embodiment, Tl is less than 20% of H2. In a specific embodiment, both Tl and T2 are less than 20% of HI . In such embodiments, thicknesses or heights of the components discussed herein are the dimensions of the components measured in a direction perpendicular to the major surfaces of the substrates. In some embodiments, the widths, thicknesses and heights discussed herein represent maximum measured dimensions, and in other embodiments, the widths, thicknesses and heights discussed herein represent average measured dimensions. In various embodiments, the width of laser weld 26 is larger than absorbing film 38 thickness. For example, the width and/or thickness of the portion of the substrates that have a change in glass Active temperature around laser weld 26 is greater than the thickness of absorbing film 38. In various embodiments, the width and/or thickness of of the entire weld region (including the residual stress portion) exceeds the thickness of the absorbing film 38. A survey of the local density distribution, or fictive temperature distribution, in the vicinity of the weld can be used to determine this relative dimensions.
[0024] As noted above, in various embodiments, because laser 34 forms laser weld 26 over and around leads 30 and 32, leads 30 and 32 are structured to maintain a satisfactory level of conductivity following formation of laser weld 26. In particular, leads 30 and 32 are structured such that the temperature needed to cause the melting of the materials of substrates 12 and 14 does not eliminate or significantly reduce the conductivity of leads 30 and 32. In various exemplary embodiments, leads 30 and 32 are formed from a material having a melting temperature that is greater than the melting temperature of the material of substrates 12 and 14. In various embodiments, leads 30 and 32 are formed from a material having a melting temperature that is at least 10% greater than the melting point temperature and/or the softening point temperature of the material of substrates 12 and 14. In a specific
embodiment, leads 30 and 32 are formed from a material having a melting temperature that is greater than 700 degrees C, and in another embodiment, leads 30 and 32 are formed from a material having a melting temperature that is greater than 800 degrees C. In a specific embodiment, leads 30 and 32 are formed from a material having a melting temperature that is
between 800 degrees C and 900 degrees C. In such embodiments, substrates 12 and 14 may be made from a soda-lime glass material having a softening point of about 700 degrees C, and in other embodiments, substrates 12 and 14 may be made from Eagle XG® glass sheet material available from Corning, Inc. which has a softening point of about 970 degrees C. In various embodiments, leads 30 and 32 are made from a material that experiences an increase in resistivity following formation of laser weld 26 that is less than 30%.
[0025] In various embodiments, leads 30 and 32 may be formed from any suitable conductive material. In specific embodiments, leads 30 and 32 are formed from at least one of indium tin oxide (ITO), molybdenum, silver, or copper. In various embodiments, laser absorbing film 38 is formed from any material suitable for absorbing laser energy to facilitate melting of substrates 12 and 14 to form laser weld 26. In various embodiments, laser absorbing film 38 is a material that absorbs any suitable wavelength of laser energy including ultraviolet spectrum laser energy, infrared spectrum laser energy, near infrared spectrum laser energy and visible spectrum laser energy. In specific embodiments, laser absorbing film 38 is a material that absorbs in the 200-410 nm wavelength range, and in other embodiments, , laser absorbing film 38 is a material that absorbs in the 800 - 1900 nm wavelength range.
[0026] In specific embodiments, laser absorbing film 38 is formed from at least one of a low melting glass (LMG) having a Tg less than 600 degrees C, ZnO, SnO, T1O2, ^Os, and a glass film doped with a transition metal, such as Fe, Mn, Cu, Va, Cr. In some
embodiments, laser absorbing film 38 is absorbing at a non-visible spectrum of laser 34 while being transparent/translucent to visible light. In a specific embodiment, the laser absorbing film and substrates 12 and 14 are transparent to light within a wavelength range of 420 nm to 750 nm. In some other embodiments, laser absorbing film 38 is absorbing at a non-visible spectrum of laser 34 while being opaque to visible light.
[0027] It should be understood that while most of the embodiments discussed herein discuss formation of a device having a functional film material that acts as leads for an active device such as OLED 24, in other embodiments, device 10 may include other functional films. For example, in one embodiment, the functional film traversing laser weld 26 may be a protective film material, such as an SiN film. Further, it should be understood that while FIGS. 2 and 3, show leads 30 and 32 as a single layered film, in other embodiments, the functional films discussed herein may include multiple layers, such as a film stack. Further, the functional films and/or laser absorbing films discussed herein may be supported from substrates 12 and 14 via one or more intervening layer, and in other embodiments, the
functional films and/or laser absorbing films discussed herein may be supported from substrates 12 and 14 via direct contact with the material of the substrates.
[0028] Referring to FIGS. 4A-4D, a method of forming a sealed electronic device, such as device 10, is shown according to an exemplary embodiment. In general, FIGS. 4A-4D show that a first substrate, such as upper substrate 14, and a second substrate, such as lower substrate 12, are provided. As shown in FIG. 4B, a recess is formed in one of the substrates, and in the specific embodiment shown, recess 20 is formed in substrate 14. As shown FIG. 4C, substrate 14 is placed adjacent to substrate 12 such that recess 20 will form a chamber (e.g., chamber 22) with the opposing upper surface of substrate 12. A a functional film, such as leads 30 and 32, is provided on one of the surfaces of substrates 12 and 14.
[0029] As shown in FIG. 4D, a weld, such as laser weld 26, is formed between the opposing surfaces of substrates 12 and 14. A laser, such as laser 34 may be moved, aimed or otherwise directed onto substrates 12 and 14 such that laser weld 26 is formed surrounding chamber 22. As discussed above, leads 30 and 32 extend into chamber 22.
[0030] As shown in FIG. 4 A and 4B, substrate 14 may be provided with laser absorbing film 38 along one surface of the substrate. As shown in FIG. 4B, a portion of laser absorbing film 38 is removed from within the region that forms recess 20, and in this arrangement, the remaining portion of laser absorbing film 38 surrounds recess 20. In various embodiments, the portion of laser absorbing film 38 is removed from substrate 14 via an etching process, and, recess 20 is formed in substrate 14 via an etching process. In a specific embodiment, the same etching step both removes laser absorbing film 38 and forms recess 20. In various embodiments, etching may be performed with acid or via reactive etching. In other embodiments, CNC mechanical milling may be used to form recess 20 and/or remove the portion of laser absorbing film 38. In such embodiments, etching depth (HI , shown in FIG. 3 above) is controlled by controlling timing of etching. In some embodiments, substrates 12 and 14 may be provided to a OLED device manufacturer, and etching will occur locally immediately prior to sealing with laser 34. In various embodiments, it is believed that the device and methods discussed herein may provide various benefits including: 1) less steps in the manufacturing process, 2) using less expensive phosphor material, and also using less expensive scattering material, 3) better scattering uniformity attributes.
[0031] As will be understood, in embodiments in which a laser absorbing film 38 is used, laser 34 has a wavelength selected to interact with the particular laser absorbing film. As noted above, laser 34 may be a UV, IR or visible light laser, and laser absorbing film 38 is
selected to absorb within the wavelength of laser 34. In addition, various aspects of laser 34 may be controlled to facilitate formation of laser weld 36 while maintaining the functionality of leads 30 and 32. In various embodiments, the power and scanning speed of laser 34 may be controlled during formation of laser weld 26. For example in some embodiments, laser 34 is a 355 nm laser with a power between 0.1 W and 1.0 W, and specifically, 0.1 W and 0.5 W. In a specific embodiment, laser 34 is a 355 nm laser with a power of 0.6 W and a scanning speed of between 10 mm/s and 50 mm/s, and specifically of 25 mm/s, and laser absorbing film 38 is LMG film coating. In such embodiments, the LMG film coating 38 has a thickness of 1 μιτι, and leads 30 and 32 are ITO leads that have a thickness of 150 nm. In other embodiments, laser 34 may be a laser, such as a short pulse laser, capable of forming laser weld 26 without the absorbing film. In various specific embodiments, the lasers, processes and materials may be any of those disclosed in U.S. Publication No. 2015/0027168 (U. S. Application No. 14/271 ,797, filed May 7, 2014), which is incorporated herein by reference in its entirety.
[0032] As used herein, a hermetic seal and/or hermetically sealed device is one which, for practical purposes, is considered substantially airtight and substantially impervious to moisture and/ or oxygen. By way of example, laser weld 26 can be configured to limit the transpiration (diffusion) of oxygen to less than about 10 cm3/m /day (e.g., less than about 1(P cm7m2/day), and limit the transpiration (diffusion) of water to about 10~ g m7day (e.g., less than about 10 3, 10 4, 10 5 or 10~° g/ni7day). In such embodiments, the hermetic seal substantially inhibits air and water from contacting a pretectal active element, such as OLED 24.
[0033] Unless otherwise expressly stated, it is in no way intended that any method set forth herein be construed as requiring that its steps be performed in a specific order. Accordingly, where a method claim does not actually recite an order to be followed by its steps or it is not otherwise specifically stated in the claims or descriptions that the steps are to be limited to a specific order, it is in no way intended that any particular order be inferred. In addition, as used herein, the article "a" is intended to include one or more than one component or element, and is not intended to be construed as meaning only one.
[0034] It will be apparent to those skilled in the art that various modifications and variations can be made without departing from the spirit or scope of the disclosed
embodiments. Since modifications, combinations, sub-combinations and variations of the disclosed embodiments incorporating the spirit and substance of the embodiments may occur
to persons skilled in the art, the disclosed embodiments should be construed to include everything within the scope of the appended claims and their equivalents.
Claims
1. A laser-welded, sealed electronic device housing comprising: a first substrate having a first surface;
a second substrate having a second surface facing the first surface;
a recess formed in the first substrate, wherein the recess faces the second surface such that the second surface and the recess define a chamber;
a laser weld bonding the first surface to the second surface, wherein the laser weld surrounds the chamber; and
a functional film supported by at least one of the first surface and the second surface, the functional film extending from the chamber and across the laser weld.
2. The laser-welded, sealed electronic device housing of claim 1 , wherein the laser weld forms a hermetic seal between the first surface and second surface and around the functional film.
3. The laser- welded, sealed electronic device housing of claim 2, wherein the hermetic seal is formed from a portion of the first substrate joined together with a portion of the second substrate, wherein the hermetic seal completely surrounds a perimeter of the chamber.
4. The laser- welded, sealed electronic device housing of claim 3 , further comprising:
a laser absorbing film supported by at least one of the first surface and the second surface and surrounding the chamber, wherein the laser weld bonds the first substrate to the second substrate at the location of the laser absorbing film;
wherein the functional film forms a first lead forming a conductive path extending from the chamber and across the laser weld and a second lead forming a conductive path extending from the chamber and across the laser weld such that the first and second leads are configured to deliver electrical power to a device located in the chamber.
5. The laser- welded, sealed electronic device housing of claim 4, wherein the laser absorbing film is located on the first surface, wherein the first lead and the second lead are located on the second surface, wherein the first lead and the second lead each have a
surface in contact with the laser absorbing film at the position where the first and second leads extend across the laser weld.
6. The laser- welded, sealed electronic device housing of claim 4, wherein the width of the laser weld is between 20 μιτι and 700 μιτι and the width of each of the first lead and the second lead is between 50 μιτι and 20 mm.
7. The laser-welded, sealed electronic device housing of claim 6, wherein a thickness of each of the first and second leads is between 20 nm and 1 μιτι.
8. The laser- welded, sealed electronic device housing of claim 7, wherein the thicknesses of the laser absorbing film is less than 1.5 μιτι.
9. The laser- welded, sealed electronic device housing of claim 8, wherein a maximum height of the chamber measured between a surface of the recess and the second surface is greater than 0.3 μιτι and less than 500 μιτι, wherein the laser absorbing film has a thickness that is less than 20% of the maximum height of the chamber, wherein the thickness of the first and second leads are less than 20 % of the maximum height of the chamber.
10. The laser-welded, sealed electronic device housing of claim 4, wherein the melting temperature of the material of the first and second leads is greater than the softening point of the first and second substrates such that an increase in a resistivity of the first and second leads following formation of the laser weld is less than 30%.
11. The laser- welded, sealed electronic device housing of claim 4, wherein material of the leads has a melting temperature greater than 700 degrees C.
12. The laser-welded, sealed electronic device housing of claim 11 , wherein the first and second leads are formed from at least one of indium tin oxide, molybdenum, silver or copper, wherein the laser absorbing film has a thickness between 0.2 μιτι and 1 μιτι and is formed from at least one of a low melting glass (LMG) having a Tg less than 600 degrees C, ZnO, SnO, T1O2, Nb205, and a glass film doped with a transition metal.
13. The laser- welded, sealed electronic device housing of claim 4, wherein the laser absorbing film absorbs energy in at least one of the ultraviolet, infrared or visible spectrums.
14. The laser-welded, sealed electronic device housing of claim 4, further comprising at least one of an OLED, organic electronic device or organic-inorganic hybrid electronic device within the chamber and coupled to the first and second leads.
15. A sealed electronic device comprising:
a first glass substrate having a first surface;
a second glass substrate having a second surface facing the first surface;
a chamber defined between the first surface and the second surface;
a hermetic seal surrounding the chamber, the seal formed from a portion of the first substrate joined together with a portion of the second substrate; and
a functional film extending from the chamber and across the seal.
16. The sealed device of claim 15 further comprising a laser absorbing film located on at least one of the first surface and the second surface and surrounding the chamber, wherein the hermetic seal is a laser weld, wherein the functional film defines a first lead forming a conductive path extending from the chamber and across the laser weld and a second lead forming a conductive path extending from the chamber and across the laser weld.
17. The sealed device of claim 16, wherein a thickness of each of the first and second leads is between 20 nm and 1 μιτι, wherein the thicknesses of the laser absorbing film is less than 1.5 μιτι.
18. The sealed device of claim 17 wherein the melting temperature of the material of the first and second leads is greater than the softening point of the first and second substrates, wherein material of the leads has a melting temperature greater than 700 degrees C.
19. A method of forming a sealed electronic device housing comprising: providing a first substrate having a first surface;
providing a second substrate having a second surface;
forming a recess in the first surface of the first substrate;
placing the first substrate adjacent to the second substrate such that first surface faces the second surface and the recess forms a chamber with an opposing portion of the second surface of the second substrate;
providing a functional film on at least one of the first surface and the second surface; and
forming a weld between the first surface and the second surface using a laser, wherein the weld surrounds the chamber and traverses the functional film, wherein the functional film extends from the chamber across the weld.
20. The method of claim 19, wherein the first substrate includes a laser absorbing film located on the first surface, the method further comprising:
removing a portion of the laser absorbing film from the first surface of the first substrate; and
placing the first substrate adjacent to the second substrate such that a remaining portion of the laser absorbing film surrounds the chamber;
wherein the functional film defines a first lead forming a conducting path extending from the chamber and across the weld and a second lead forming a conducting path extending from the chamber and across the seal.
21. The method of claim 20, wherein removing the portion of the laser absorbing film occurs via etching, and forming the recess occurs via etching.
22. The method of claim 21 , wherein the same etching step both removes the portion of the laser absorbing film and also forms the recess.
23. The method of claim 20, wherein the laser weld is formed across the first lead and the second lead by directing a laser toward the laser absorbing film causing the material of the first and second substrates to melt together, wherein the first and second substrates are both a glass material.
24. The method of claim 23, wherein a resistivity of the first lead and the second lead remains the same or increases following formation of the laser weld across the first and second leads, wherein the increase of the resistivity is less than 30%.
25. The method of claim 19, wherein forming the weld comprises directing a short pulse laser on to a portion of at least one of the first substrate and second substrate surrounding the chamber causing the material of the first and second substrates to melt together.
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EP16839962.4A EP3341983A4 (en) | 2015-08-24 | 2016-08-23 | Laser sealed housing for electronic device |
US15/754,975 US20200238437A1 (en) | 2015-08-24 | 2016-08-23 | Laser sealed housing for electronic device |
CN201680049450.7A CN107995883A (en) | 2015-08-24 | 2016-08-23 | Package sealing with laser shell for electronic device |
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US201562208900P | 2015-08-24 | 2015-08-24 | |
US62/208,900 | 2015-08-24 |
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US10746937B2 (en) | 2018-02-15 | 2020-08-18 | Corning Incorporated | Assemblies, optical connectors and methods of bonding optical elements to substrates |
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CN112203795A (en) * | 2018-05-22 | 2021-01-08 | 康宁股份有限公司 | Laser welding of coated substrates |
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- 2016-08-23 CN CN201680049450.7A patent/CN107995883A/en active Pending
- 2016-08-23 EP EP16839962.4A patent/EP3341983A4/en not_active Withdrawn
- 2016-08-23 KR KR1020187008016A patent/KR20180034683A/en unknown
- 2016-08-23 US US15/754,975 patent/US20200238437A1/en not_active Abandoned
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US20130111953A1 (en) * | 2010-04-27 | 2013-05-09 | Ferro Corporation | Hermetic Sealing of Glass Plates |
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US10345533B1 (en) | 2018-02-15 | 2019-07-09 | Corning Incorporated | Assemblies, optical connectors and methods of bonding optical fibers to substrates |
US10545293B2 (en) | 2018-02-15 | 2020-01-28 | Corning Incorporated | Assemblies, optical connectors and methods of bonding optical fibers to substrates |
US10746937B2 (en) | 2018-02-15 | 2020-08-18 | Corning Incorporated | Assemblies, optical connectors and methods of bonding optical elements to substrates |
Also Published As
Publication number | Publication date |
---|---|
US20200238437A1 (en) | 2020-07-30 |
EP3341983A1 (en) | 2018-07-04 |
EP3341983A4 (en) | 2019-04-24 |
CN107995883A (en) | 2018-05-04 |
KR20180034683A (en) | 2018-04-04 |
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