WO2017023217A1

WO2017023217A1 - Detection of pesticide residues in agricultural plants

Info

Publication number: WO2017023217A1
Application number: PCT/TR2016/000107
Authority: WO
Inventors: Betül Yasemin AKAR
Original assignee: Akar Betül Yasemin
Priority date: 2015-07-31
Filing date: 2016-07-29
Publication date: 2017-02-09
Also published as: US20180275109A1

Abstract

Before the harvest in agricultural production, pesticide residies in the plants are detected using electrochemical methods and/or portable electronic devices.

Description

DETECTION OF PESTICIDE RESIDUES IN AGRICULTURAL PLANTS

Technical Field This invention, before the harvest in agricultural production in the plants live on the land in place of pesticide active ingredient pesticide and/or metabolites residue analysis of pesticides residue analysis of portable electronic device and the device is related to the analysis method to be used.

Previous Technical

Pesticides are harmful to the environment and human health due to the effects of pesticide use all over the world are bound to certain rules and control is provided by applying serious sanctions. Continuous training is provided to the manufacturer from the harmful effects of pesticides being studied increasing of awareness. How to apply pesticides subject expert discusses them with technical staff, after harvest time of medication effects of pesticides is said to be very important to be taken from the plant. Both producers are made as well as training in agricultural products from the training phase specific term residue analysis are subject to.

Analysis of pesticide residue in agricultural products in laboratories. These labs are each country's official institutions and accredited associations. Products according to specified legal sampling method of production is being imported and brought to the lab. After a preliminary process for analysis here related devices, analysis and final report. Agricultural products, pesticide residue analysis must be brought to the lab the samples taken for. Laboratory analysis is a highly advanced, comprehensive and sensitive analysis in the devices. Chromatographic analysis methods based on analysis of these devices is a large and complex- structured devices consists of more than one component system. System analysis is made of the main device, you can find the entrance to the monitor device information and registration system, the data is processed on a separate computer, printer and provides energy to the system cable is all composed require an energy source to work. In addition, all systems are connected with each other. Examples from the lab, washing, crushing, ready for later analysis of the centrifugal process covers it. This pretreatment chemicals used in human and environmental health.

Ongoing analysis of agricultural products process long; during peak season the analysis report time to find a few days sometimes. Especially when dealing with people buying and selling agricultural products and exports and accounts for this situation creates difficulties from time to time.

In some cases the load products shipping tool firms the amount of pesticide residue in samples sent to the lab, the legal limit is on the difficult position of falling; have to call back the shipping tool. Body-worn operation, it should not export product is export done, sometimes even if a buyer as a result of the analysis made at the border of the country remains high due to the problem is the destruction of products.

Encountered in these cases the company both financially and loss of business reputation, and to the black list of countries about the next job connections are affected by negative incident. In addition, countries are also loss of prestige. Despite the training sometimes manufacturers commercial concerns to the fore. With your own statements in analysis of the outbound product manufacturers on sale is said to be of a different party of outgoing products. Agricultural products is generally larger tonnage truck transport tools installed, and other such tools is in the vault is more than one manufacturer products. It is legal for an analysis that apply to products in the vehicle's procedure case examples from different parts of the mixed analysis samples taken in the event of the vehicle remains due to the provision of all products remain in the case to be destroyed. In such a case the manufacturer can not be found and an exception he used drugs and no manufacturer does not accept any liability at all for legal sanctions are applied to the merchant at the last owner of the agricultural product.

Traces of pesticides in agricultural production losses and difficulties encountered in the application of the land due to be made in the analysis remains a lot of work.

KR20070004500 A Korea patent no. 20070109 tutorials suitable for hand-held pesticide residue analysis in the field who is mentioned from the device. Storage bin, water store, a water sample on the device to water pump, the motor shaft on an electric power supply or battery to rotate, rotating part of the motor are included, and a link that provides the theme of part of the sample, measuring part and an electric current by comparing the value of standard load changes to pesticide analysis made the decision there is a section. Patent documents in question in agricultural land in the vegetable and fruit analysis of any pesticide is mentioned to be on the surface. The patent in question, said the device found in vegetables and fruits of multiple systemic pesticide active substances and active ingredients are not available in the analysis of metabolites.

CN 1544916 A in Chinese patent documents No. 20041110 portable is mentioned a pesticide residue device. A monochromatic light source, a detector, monochromatic light is sent and the colorimetric analysis samples in solution tank, 37 degrees Celsius heat to keep the temperature is held this device analysis each sample stabilization for the preset color wavelength light for example sent and where the parts are read with the reaction occurred photoelectric sensor through the converter to the computer on the device beingsent and data are processed.

Spectrophotometry, electrochemical analysis method is not one of the. Unlike the electrochemical methods with pesticide analysis made with this device made by Spectrophotometric method in analysis of pesticide active ingredient to be searched, for example, genus and specific wavelengths is found to be required only a single example at one time for an item is disabled. The patent in question, "said a group of more than one pesticide active ingredient device and search of multiple pesticide active ingredient metabolites analysis.

WO 99/United States patent documents available to the land in numbered 08554 appropriate narrative about a portable analysis device. Contains the microprocessor, this is written in the device's memory card and sensors through the blood, urea, glucose, proteins, pharmaceuticals, pesticides, and water soluble lead, cadmium, mercury, heavy metal ions, such as analyses. Colloidal gold-plated sensors on the device, gold-plated electrodes and electrochemical analysis techniques are used to work. In patent documents in question the connection between devices and PCs through the RS232 port will be provided through cable. The most important problem of the signal line RS232 noise is not adversely affected by. For this reason, the data transfer of up to 15 metres in length must be used between cables. This is the analysis sensitivity of negative at that time. In addition, electrical voltage fluctuations RS232 port is very sensitive. Computer and Analyzer to avoid common grounding voltage fluctuation between the line and the selected protection despite GND sudden voltage value changes will lead to very serious problems. Considering that agricultural areas land conditions, always very different field conditions to ensure a standard voltage value to 10, it is impossible to make precise and accurate analysis. The patent in question is mentioned in software and hardware, is shouldering from a computer for running the device and has to be updated. The device does not have its own computer operating system.

In the aforementioned patent documents in a variety of analysis and device liquid pesticides analysis are reported. Heavy metal and pesticide residue in the natural water sources contaminated with imported metal and pesticide residues developed to detect this device just like the other examples on the market organophosphates and carbamates analyses of pesticides. Organophosphates and carbamates in agricultural production not only pesticide also used drugs other chemical groups. These drugs are organophosphates and carbamates drugs are pharmaceutical group other than whether the chlorinated compounds, synthetic pretroid, Amen and hydrazine derivatives, organic Tin, sulfur compounds, triazoles are pesticides, etc. This natural water sources of pesticide residue detection cannot be concluded that the plant residue in the not related at all.

Made from liquid pesticide analysis outside device analysis blood, urine, water is liquid fluid structure material. Plants by their very nature is different from the urine and blood of water SAPs viscosities of liquid is not the same as mentioned. A pepper is very different from blood serum with the SAP instance.

If you have already passed some preliminary operations plant laboratory conditions samples are turned into the appropriate device in the lab standard serum pesticide analysis. The appropriate software and mechanism, computer-related examples from the lab in any lab device that analyses already performed.

Example analysis during operation of the device belongs to the location of the land taken, for example, manufacturer information, analyze important information such as the date recorded on the device system there is no device in question. Natural water resources in heavy metals, chemical contaminants, organophosphates and carbamates determination of pesticide residue and lab environment, blood, urine, urea, glucose analysis of human body fluids, such as for the principle of this device working conditions, developed the method and purpose of work, herbal plant tissue during harvest live example of pesticide residue analysis is different from portable to do residue analyses.

Of agricultural products of the aforementioned device harvest farmland conditions taken directly from the in vivo environment non-liquid plant examples analysis of multiple pesticides.

Developed by a group of researchers MyDx (My Diagnostic) hand-held device made of pesticide residue analysis. The device in question is a mini olphactometric analysis. Pesticide active ingredient essential items in the ruins of the gas molecule belonging to the electronic nose technology is identified with sensors designed and chemical processes in the cell within the mini device. It's not the reaction that occurs with a wired or wireless connection device that communicates with a mobile device converted data can be read through the software. Cell phones, tablet devices such as the extra software to be uploaded to the measuring data can be taken. Suspected remains of vegetable or fruit at the supermarket or at home is a tiny piece of analysis from the tank to the sensors are substituted by a series of perceived assets processed through other device installed through software appear in the result. The testing phase yet this device is used in agricultural production pesticide active ingredients, only organophosphates and carbamateshave been reported in the analysis of pesticides. The sensor used in the organofosfath and karbamath are designed for determination of pesticides. Organophosphates and carbamates pesticides in agricultural production not only another 25 chemical groups also used drugs. These drugs are organophosphates and carbamates drugs are pharmaceutical group other than whether the chlorinated compounds, synthetic pretroid, Amen and hydrazine derivatives, organic Tin, sulfur compounds, triazoles are pesticides, etc.

Electronic nose systems if essential compounds in the environment. It does not include every pesticide active ingredient molecule essential gas molecule. In such a case, the non-pesticide active substances in the sample received essential molecules are undetectable and the device will give false negative results.

The examples used in the device measured the device according to the sales points in the promotion of agricultural products. On the shelf in the store for a while and got ripped off from waited for an agricultural product ranges of serum concentration of SAP. Depending on the product to the wait time has an in-house pesticide active ingredients can be measured within the biological destruction and decreasing the amount of active substance and structure changing, indicating that it is a very dangerous pesticide metabolites.

Pesticide active ingredient in agricultural production falls below a certain figure of time pretending to do so due to hormones in the human body, serious health problems caused by a variety of medical research. In addition, the pesticide metabolites harmful to human health that may occur in the device according to the introduction, analysis.

Recently at the point of sale analysis of agricultural production of this device from harvested yet, targeting the land located within a product live in the tissue of the pesticide active ingredient consisting of metabolites in the early period of the and it is not possible to determine.

Electronic nose sensors on the device are land conditions, ambient temperature and humidity, the whole company is negative, (iv) the device calibration. This device is installed in a very short period of time makes the need for harvesting agricultural products they couldn't afford the user's amount; a very small amount of household user and limited analysis of pesticide active ingredient group is giving the product make it possible for field conditions are not suitable for the analysis of in vivo live tap. There is no display and operating system device itself. Process data can be read of the second needs a mobile device; analysis is not the main device to a second device prepared for software.

Turkish Patent Institute 2010 - 05568 with the number recorded in the patent application documents of reference before the harvest will make Multiple Pesticide Residue analysis of plant Hand-held measurement device is mentioned from.

We use the reference to the documents in question belonging to the desired specifications and prompts that patenting in technically insufficient and additional regulations made by us drafting exceeds the scope and prompts to have not been continue processing by us. The device in question, analysed the introduction of recording program information for the land and the land will detect satellite connections, and the coordinates of the GPS system. A separate registration system for data entry, and there is a need for a computer. Device communication with different terrain conditions in the main central computer and internet connection will allow the sim card to the card slot and there is no connection on the motherboard, system required. The results of the analysis to be done within the device as there is no mini printer that will allow writing; You must be connected to a separate printer device as needed. On the screen and the menu control keypad located separately, without the keypad on the touch screen menu single use and it is not possible to use vertical, horizontal screen when needed.

Durable and lightweight material mentioned in the outer surface of the device, and display device to protect from external factors corresponds to water, dust and moisture proof is not on the property. For this reason, open field conditions in wet weather, intensive moisture in greenhouse environment use the summer term, the prevailing wind is blowing open to agricultural land can be experienced difficulties in protecting against dust in the camera's penetrating and unnoticed, dust particles, water droplets and moisture on the inside of the device, malfunction of electronic components located on metal particle with time cause oxidation device, depending on the moisture in the compromise, the analysis will lead to incorrect results in.

In the land of the aforementioned device to dust, water and moisture is blowing against the manufacturer during harvest, before the land and location information of agricultural products over the same device analysis recorded and live plant tissue the pesticide active ingredient pesticide and/or metabolites analysis is not suitable to be done.

TAIWO SCIENCE. Inc - A CHEMICAL SENSOR COMPANY developed by the company named micro electro mechanical systems MEMS based analysis in organic compounds, toxic industrial chemicals, nitro compounds, and carbon dioxide can escape analysis are reported. The device in question is designed as a sensor of electronic nose with a variety of ingredients including essential compounds at the molecular level between the device found in the mini course by action is taken when the gas chamber. Used sensors on the device in question if only the requested analyte gas is volatile organic compound able to, in the form of organophosphated and carbamates compounds can be analysed. Organophased and carbamates in agricultural production not only pesticide also used drugs other chemical groups. These drugs are organophosphates and carbamates drugs are pharmaceutical group other than whether the chlorinated compounds, synthetic pretroid, Amen and hydrazine derivatives, organic Tin, sulfur compounds, triazoles are pesticides, etc.

Agricultural products, protective and/or on-site of pesticides used for fighting plant suffered destruction and/or plant SAP when they react with the substance and too dangerous for human health, is olciilememektedir of electronic nose sensor metabolites.

The aforementioned device% 0-60% relative humidity in the range and 25o - 35o C is used in the range have been reported, with relevant results made under these conditions. Agricultural products are harvested and climatic conditions may not fit the device working conditions in question all the time. In the greenhouse during the summer period the temperature during harvest at least 45o C, humidity is 70%.

Open field may not be able to provide these conditions at harvest time. In the morning heat Oo C to 50 C changes between periods and/or intense rainfall is 100% relative humidity environment during intensive harvest land affected by electronic nose sensor sensitivity of this device is to be done with the results of the analysis will not be healthy.

The basic premise of the device in question using sensitive electronic nose sensor gas form essential compound molecule containing harmful chemicals is to detect this device only carbamates pesticide Carbaryl of s practice through; the other group that does not contain a gas molecule pesticide and pesticide active substances, it is impossible to identify the metabolites. Electronic nose systems if essential gas form compounds in the environment.

It does not include every pesticide active ingredient molecule essential gas molecule. In such a case, the non-pesticide active substances in the sample received essential molecules are undetectable and the device will give false negative results.

Electronic nose sensor on the device in question with the measurement method, electrochemical analysis methods of voltametrik analysis methods. 900 MHZ wireless connection has been made through the device in question have been reported. 900 MHZ is not a connection of land in rural areas is more efficient than indoors, and this technology is no longer increasing population and given the growing data communications technologies is a technology have completed technological life. The topography of different terrains and agricultural production outside of downtown. You may not have the necessary infrastructure to transmit data for each production area.

Open field measurement results using quality data processing, and transfer to a minimum of 1800 MHZ connection speed required and in cases where there is insufficient technical infrastructure for the transmission of data to avoid the problem contact your own systems via satellite must be the main centre.

Active ingredient group and different pesticide pesticide metabolites device at the same time as the device does not have the software belong to the methodology that will show the basic design, software and electronics from moisture only 0%-60 agents and 25o C - 35o C degrees air temperature is to run.

Analysis done on the device with the information, where it was received, and the date and time, to whom belongs the pesticide residue analysis, monitoring and recording of data providing device entry is not possible, these processes there is a need for a separate computer for recording system. Device is read from or output does not have this information in the analysis results obtained analysis other than a person who makes someone else-was not created a separate registration system-as he is not familiar with the analysis and contact person by whom any sanction at that time in negative consequences to humans.

The above-mentioned reasons in agricultural products in the land of the aforementioned device multi is not suitable to make pesticides and pesticide metabolites analysis.

Is currently being sold in the market for hand-held pesticide analysis devices. Organophosphates and carbamates according to the enzyme activity of pesticides that detect the presence of kits color converts numeric data that can be read the exchange of these devices work on the basis of analysis of enzyme activation time sometimes 10 minutes.

These drugs are organophosphates and carbamates drugs are pharmaceutical group other than whether the chlorinated compounds, synthetic pretroid, Amen and hydrazine derivatives, organic Tin, sulfur compounds, triazoles are pesticides, etc. These active ingredients are not different with the enzyme reaction analysis methods, it is possible to identify with.

Diagnosis value of at least the legal MRL (Maximum Residue Limit) limits 100 solid level is started from the devices for optimal conditions of enzyme kits. Changing climate and geographic conditions, kit is broken app for enzyme activity of healthy results can no longer be. Example analysis-related information from devices titling, and the potential need for a separate registration system for this process. Wireless and data transfer are carried out using a separate computer.

Involved in all kinds of terrain, climate and geographical devices under any circumstances in the analysis of pesticides and/or is not suitable for using the pesticide metabolites.

TAIWO SCIENCE, Inc. by USDA-National Institute of food and agriculture in the United States (National Institute of Food and Agriculture) takes advantage of the grants funds supported by An Inexpensive Mems-Based Pesticide Detector For Long Term Monitoring and titled 2006 - United States Department of Agriculture USDA's reference number-00188 project web page, its subsidiaries, is The Research, Education and Economics Information System (REEIS) and The Current Research Information System (CRIS) page www.reeis.usda.gov/crisprojectpages 0206567 with the number accepted. This project is selected in 3 target detection of electronic nose-enabled sensors effects of pesticides for work. Dichloropropene, methyl bromide and selected pesticides methyl isocyanate. All three are applied to all creatures in the area featured in the formulation of essential gas fumigant that kills compounds. Is applied commercially in the form of a tablet or tube into effect by passing gas in the environment. Human and all other living creatures due to the dangerous storage conditions and subject to the conditions are heavy pesticide application principles. During application it is not attention and conscious application isolation is not done with the acute effects can lead to mass deaths. In the long term, human, nature and all living creatures can lead to chronic problems, air, soil and water may cause poisoning. Mentioned in the project selected in the presence of ambient air tepit this 3 effects of pesticides for sensors, are aimed at the development of analysis methods and devices.

Pesticides are applied to agricultural land near the settlements and schools were asked to be created inspired air related security criteria. Gaseous pesticides in active, continuous measurement of user information level of farmers and improve their use of.

The study is featured on electronic nose developed sensors that can detect volatile compounds. Using sensors and sensor has been developed on the principle of operation of the devices. All of the pesticides used in agricultural production does not contain volatile gas compounds and not in the air released directly from the plant is within: analysis methods are also different.

This project studies carried out in the presence of pesticides in the form of dangerous gas detection devices and sensors used to have to live the pesticide plant tissue and/or it is not suitable to detect pesticide metabolites. Agricultural products harvested the plants cannot be used for the determination of pesticides in the fabric of order.

Measurement, 2008, vol. 41, p. 44-54 in an article published between hand-held spectrometric measurement applications spectrometer. Spectrometers measure the color change of the example absorb substances that help devices and analysis the analysis of accuracy and to ensure the accuracy and each time a single example is based on a single analysis. The publication in question within multiple pesticide active substances and plant spectrometer that is not available in the analysis of item-specific active metabolites.

Analytica Chimica Acta, 2007, vol. 596, p. 1-8 in plant articles published between on-site of pesticides can be seen with optical methods for studies. The effect of plant physiological spectral matrix in order to overcome, in the form of nano and micro Crystal fluorescent labeling agent are granted and this crystal as the interaction of pesticides with spectral examined, within the existing pesticide plant of Fourier transform spectral method of more specific and accurate display. The publication in question according to the spectral wavelength of pesticides technical in the light color detection is a method of analysis based on the aforementioned methods are pesticide analysis and electrochemical analysis methods is not only to ensure the accuracy of the detection of an active ingredient is mainly because more than one so multiple pesticide active ingredient in the analysis of the active substance and metabolites of electrochemical unavailable.

The Purpose Of Invention

Offered to the market of agricultural products in the amount of pesticides harmful to human health and/or remains of pesticide active ingredient classified whether fixing metabolite is time consuming and costly, in the latest case, or transport of the product of the analysis when the sample random sampling due to the problematic products be backward is impossible in practice to the final manufacturer's follow-up detection, the return and destruction of the remains discovered product operations, caused by the waste of time, cost and the size of the workforce, is presented for sale on the domestic market without being destroyed sometimes gossip, agricultural product trade in the products of people dealing with high amounts of residue when their commercial and economic losses, their exposure given the legal sanctions; agricultural products harvested yet more land with an electronic handheld portable Analyzer while the live instance from given land information of the product of the plant, the identity of the owner of the land, the history and analysis of the information of the person who made the analysis at the same time, register and get your own GPS system coordinates of the device the device is developed for conducting on-the-spot analysis with electrochemical analysis methods, the pesticide active substances and/or live plant active substances determination of metabolites and detection, the device can be read from the screen, together with the producers and land information printed output, with its own operating system of the device and sim card when necessary, without the need to transfer data to another computer, sharing of information, is intended to provide backup and storage. Description Of The Invention

Before the harvest in agricultural production in the field and live plant will be chosen in the electrochemical methods pesticide active ingredient pesticide metabolites residue analysis and/or do portable electronic pesticide residue analysis device is made of durable and lightweight material, water, dust, and moisture-proof, short term water drops, splashes, resistant to water pressure low and high intensity short term external body part; the system will run inland and will perform the analysis process, the resulting data can be read on digital devices will convert the values to the device software enhancement MRI SCANS installed graphene and/or super fast high carriers containing compound transition metals-based micro-processor, graphics processor, microcontroller, memory and electronic circuit chips, hard drive on which the operating system is installed, the screen of the GPS microchip card, micro sim card slot on the printer processor, a motherboard and/or card from the group; bumps, drops and so on cases analysis done on the device in order to take the fall to protect the process of multiplication by detecting negative situations, etc about the procedure automatically until the device will freeze and normal use deletion to protect against sudden motion sensor motion sensor puts the protective system; according to the level of light in the environment that sets the screen brightness of the device ambient light sensor to adjust; the use of the programs for the operating system of the device and allows access to, water, dust, and moisture-proof, short term water drops, splashes, resistant to low and high intensity short term water pressure, fingerprint stain repellent, the entire process, information introduction was written by tapping the on-screen keyboard of the finger and the finger movements of the menu dial, can be made both numerical and graphical image operations, vertical and horizontal use capacitive touch screen; will multiple pesticide analysis device off when not in use and water, protection against dust and humidity, and automatically locked mini sliding lid preserved one or more of the test kit is to be used for regular calibration calibration the device of the kit to be worn while working and possible external factors that enable protection from water, dust, and moisture repellent nano-material, covered with full contact on the tip and entry kit slot sitting on each other is locked and sealed when covered with protective nano material provided the featured input socket; on the main body to dust, water and moisture resistant standard sim card and memory card is installed, press a couple of card holder of the extraction system; it's in the back of the protective device, water, dust and moisture- resistant protective cover made of durable and lightweight material that featured; when the paper roll is located under the hood that allows a change of a mini printer roll holder; when not in use, protection against water, dust and humidity property on the output of the printer paper closes snugly with seat cover; when you need additional data to the device in order to provide the entry of water when not in use, protection against dust and humidity sitting snugly on the property when installed under the hood to provide a complete sealing mini protector-Bay data cable entrance; have the same protective cover the protective property RS485 and/or different port entrance; the battery is located under the protective cover of the back of the device pane; it is located under the protective cover of the back of the device 5 field battery pane; smart battery can be recharged with the properties and at least 1000 enables at least 8 hours continuous measurement device capable of running and active stand by position, they can expect at least 24 hours have various power battery; located on the side of the device and a device to turn on/off button.

Before the harvest in agricultural production in the field and live plant will be chosen in the electrochemical methods pesticide active ingredient pesticide metabolites residue analysis and/or do portable electronic pesticide residue analysis device will be used in the analysis method: opening of the device with the on/off button,

in the process, the device screen by entering the user code and password onto the page that opens,

in the process, with the adoption of the code and password opening analysis home page, to begin the process, analysis on the main window is registered in the database of the Ministry of the manufacturer ID and/or the manufacturer's registration number must be written,

in the process, on the page that opens the gps system is activated by the system brought to harvest and saving of measurement will be made of land information,

in the process, selecting the product to do the analysis menu analysis,

in the process, placing the device installed on the device for the analysis kit system software by opening the slide auto kit holder,

in the process, the analysis set should be placed in the slot of the tip,

with the introduction of the software installed on the device the process analysis kit instance located at the selected products occurs on the pesticide we brought the reaction of active kit electric signals according to the pesticide active ingredient will be chosen automatically installed on the device the analysis program into electrochemical analysis methods of data, in the process, the pesticide active ingredient contained in the analysis kit metabolites detected in electrochemical sensors of detection of installed software on the device according to the metabolite will be activated automatically by analyzing data from into, in the process, at the end of the time set, the data obtained through the software on the device can be read, processed and converted to numeric values,

the numeric value of the process, analysis, data detected with active ingredient turned into a chart table with values of the device memory to be saved, in the process, the analysis of installed software on the device state provider program and wireless internet connections and related land, the company's database product manufacturer, along with the site by registering,

in the process, with mini printer installed on the device to print on the election of the results of the analysis, the results are printed all the analysis and/or risk,

more on the device screen analysis process page for an example of the analysis process of concluding that,

in the process, the process analysis on the analysis menu routing and analysis kit from the device with the cover of automatic closure kit,

the current membership of the user code and password to begin processing, product manufacturer, and the system of land and although this pretreatment steps then analysis program can be started,

during the process, as required by the installed software on the device program feature analysis once the user process any data in the case of faulty operation, not being able to delete, cancel the error during device screen warning and error correction can be continue with; this process can also be saved to system memory,

the reduction of the device during device installed protective software analysis and so on cases with the introduction of the sensor that detects the screen blurring and executed the procedure as freeze protection process; normal conditions of use, it is advisable to continue where it left off when it comes to processing,

at the level of 10% of the battery power level device, in which case it is audible and light warning,

the battery power level is 2% of cases, audible and light warning and critical power levels can be made only in the analysis device, the previous and the current data taken steps to protect.

Meet the preferred application, will be taken just before the harvest from plant SAP, sap, trunk, leaves, bark, fruit pieces with the help of mechanisms based on the analysis, such as Kit set apart through a series of process in the set and kit Kit into electro-sensors within the interaction as a result of reaction on the device to be obtained and processed numeric data that can be read from the on- site plant harvested yet plant pesticides and pesticide active ingredient is intended to detect the presence of metabolites.

As a method of analysis on the device to be identified according to the pesticide active ingredient, a variable of the desired electro-chemical analysis techniques will be used. Electro-chemical method of electrode-solution system response of the system is measured by performing the electrical effect. This method has been and still are being performed on the scientific research in the most economical and appropriate analysis for pesticide analysis methods.

Electrochemical analysis methods voltammetryc methods are the preferred technique for the device is of advantage; very little work is even possible sampling, sample preparation process always needs to be built, some specimens can be rolled directly into analysis, the lower limit of determination is much more sensitive analysis of low, linearity field thanks to the selectivity and accuracy is better, hand-held device for multiple pesticide analysis for non-liquid and liquid samples allow the development of new analysis methods, differ from each other in order with the electrode is doing electronic portable hand-held device is intended for use in the analysis of multiple pesticides. Voltammetryc method, especially in add Dithiocarbamate group of pesticides degradation product made of the electronic nose sensor ETU metabolites essential method of detecting gas molecule and enzyme-based methods of analysis but don't have the biological analysis it is possible to detect during and at the same time.

Voltammetry is an indicator or work under the circumstances applied polarized electrode potential as a function of flow measurement from the analysis sample from a group obtained information about electro analytical method. Voltammetryc analysis method it is performed at the electrode system experiments trio. Three of the potential modified over time indicator electrode or electrode working electrode.

Voltammetryc analysis methods as the indicator electrode mercury, Platinum, gold, Palladium, carbon electrode (electrode, glassy carbon graphite, carbon cake) are widely used as electrodes. During the second electrode electrode system, potential experiment that remains constant is the reference electrode.

Saturated calomel reference electrode is usually, Ag/AgCl or. Electrode if contrast or auxiliary electrode third electrode system. As the electrode is usually opposed to PI wire is used.

Voltammetryc analysis method it is current, working electrode occurs as a result of the reduction of the items or increased. Decrdased due to a stream is a stream caused by cathodic current Anodic current is called the increased. As a system of analysis of the requested pesticides analysis device electrode active material group specific to shorten the analysis time and prepared process increases the speed of Graphene nanopolymer and/or transition metal compound high carrier weight Super fast electrode and electronic circuit components will be used. Analysis set sets within the analysis work in electrochemical sensor reacting with samples, reference and comparison of electrodes on the surface of the sensor and/or located on either side of the device will connect to the party that the surface of the electrodes are thin cables. Device is being contacted and analysis Kit that part appear to be occurring in the reaction device sensor to connect a separate computer with the processor on the device without having to read electronic and computer software is software that is processed with capacitive touch screen can be read as both numeric and graphic table, visible, printable, forwarded data.

These electrodes and the surface area of both working, reference and auxiliary electrodes gold, silver, Platinum, carbon, and more are preparing to be the desired item, the various nano materials can be found in the standardization of the Tiger, have provided easy, due to the precision of the measuring values voltammetryc analysis rather than used.

The market is still being sold to various companies in various makes and models were fitted with power because they weren't capable of foldable electrodes and device- specific field conditions suitable, easy storage compatible intended by developing electrodes.

The main voltametrik appointed to be used on the device methods;

Linear Scanning Voltammetry LSV

Differential Pulse Voltammetry DPV

Square- Wave Voltammetry SWV

Normal Pulse Voltammetry NPV

AC Voltammetry ACV Cyclic Voltammetry CV

Anodic Stripping Voltammetry ASV

Adsorptif Stripping Voltammetry AdSV

Adsorptif Catalytic Stripping Voltammetry AdCSV

Chronopotentiometric Stripping SCP

Voltammetryc analysis of the device, the measuring bar electrode technology, new production techniques and developments in nanotechnology is held in front of the eyes of amperometryc intended analysis.

The device is also used as a measuring stick on the set of the analysis Kit electrochemical electrode sensor will be developed with new kit systems and facilitating the use of the software program moving mercury and mercury electrode type is based on the principle of polarographic study of the kit system analysis is intended to be done.

With the device's hand-held device can carry the user always and at any possible analysis is intended to be able to do this.

The device's dust, water and moisture-proof, short water falls and water resistant material-coated lightweight and resistant to water pressure inside made from material that has different climates and topography terrain conditions of the device from external factors is intended to ensure the protection and ease of transport to the user.

On the inside of the device on the A/D, D/A converter, SPI, Graphene and/or super fast high carriers containing compound transition metals-based micro-and graphics-processor electronic circuits, RS485 and/or other ports, the operating system hard disk, the sudden motion sensors set up ambient light sensors, processor processor, the video card, mini printer processor is the use of multiple card system can be shrunk to the size of the device, only one device can be executed simultaneously by more than one analysis, digital-to-analog conversion of digital-to-analog data of the data, graphics software program integrated spreadsheet operations can be run, micro processors, converter and capacitive touch sensors work in a synchronized format of the screen, the screen is capacitive touch screen of the software run, simplifying the analysis processes, a sudden drop in such cases, the impact of the device the device must be taken to protect the process, analysis, operation of the device made to normal working conditions until the freezing without loss of data, the analysis of the results can be printed from the device and, if necessary, the device can be sent to external printer with a wireless internet connection.

Graphene nanopolymer of electronic circuits and processors are and/or super fast high is a compound that contains metals-based carriers less of a duration analysis, processing speed is intended to increase the sensitivity of the analysis.

With the sudden motion sensors on the device, a sudden drop in such cases, the sensor-driven employee impact protector made at that time by sticking of the software program analysis, process steps, in order to protect the device from damage data adverse conditions until the ice cream to the normal operation of the device ends, protection, and when it is out of the normal conditions intended to ensure continued operation is disabled.

Set the ambient light sensors on the device with automatic adjustment of display brightness according to ambient light and the battery life saver is intended to provide. The device is the product made the GPS processor analysis of land satellite links is intended to be saved to the device coordinate plane by utilizing.

The device is the main card printer program within the processor, use a mini printer and the analysis results with the required data on the device using the specially developed device printer program without having to own a separate printer connection printer paper is intended to be printed.

The device is a mini printer roll in the slot, the analysis of the results across devices as needed using the program typed the printer processor document can be retrieved in order to hook up the printer output is intended for mini rolls.

To analyze the device on the market that is currently used and analysis in addition to the need to use a separate computer programs, rather than device-ready to be developed through the use of program analysis and simulation analysis of reaction from one computer to another on the screen on the device Kit set without the need for a readable and can be simulated is intended to be.

Anroid on the device, Windows, IOS etc. through the use of the operating program, different geographical conditions and protected production areas in open terrain data, sharing information, program updates, location positioning and operating-system update for downloads without a separate device connected to the computer through touch-capacitive screen related programs can be loaded and can be done using the device menu of operations.

Device with sim card slot in the different geographic conditions for wireless data transfer as needed, some of the nearby base station will provide satellite connections, internet connection and/or sim card can be used to hang out and operating programs.

In the device memory card slot that belongs to the process data is stored on the device can be enlarged capacity of the memory card can be inserted and the device in order to be used. The capacitive touch screen the user has a separate keypad and key keyboard without the need to capacitive screens with multi-touch feature using your fingers across the screen can be selected and installed before the system menu in order to make the system reach the data entry to the program, transactions can follow through on the screen again, the use of the page on the screen device horizontally and vertically in order to select the relevant menu and can use the operating system installed on the device.

The kit is the input slot on the end, will make multiple pesticide analysis analysis set set/sets and routine calibration operations for attaching analysis and calibration calibration kit is intended to be made. The data transfer cable (USB) and R485 and/or other person using the device of the entrance to the port and the business centre of institutions when necessary, upon receipt of the data obtained and to share, in cases where the software and the device are required outside of a wireless internet connection to the aim and a separate computer can install new programs, the additional hardware device and when the need to be able to connect to the devices, the need arises to projectors by connecting directly with the information reflected on the device can be used in presentations and both approaches with the same component on the device, and to achieve savings.

Other ports are RS485 device and/or through the use of the device will work on field conditions and grounding problems voltage fluctuations in the RS232 interface, signal to noise caused by the prevention of the problem of security analysis, communicate with each other with the card protocol converter RS485 device providing the connection between the unit and the sensor and scientific developments can be used of the cards other than depending on the RS485.

The device's printer roll, kit entry, sim card and memory card, USB and port entrances self sliding caps through the use of the device ensuring the preservation and analysis accuracy protection from external factors.

With the battery of the device pane, will provide power to the device can be attached to the device of various power battery.

Run the device for at least 8 hours provide the power to the device is opened if the device holds a 24 hour stand by ready for analysis, the test can do about 1000 life, rechargeable and use the smart battery specifications battery, the device field conditions proper to study long hours and needed to be ready at any moment measuring aimed to provide.

The on/off button when prompted by pressing the button the device by opening the analysis needs to be done in 10 seconds and finished within 10 seconds by pressing the button completely the closure is intended to provide.

The Invention To Industry Application Format

That will serve the purposes mentioned above, Analyzer, can be produced and used in any branch of industry, can be applied to industry qualified.

Claims

1. Before the harvest in agricultural production in the field and live plant will be chosen in the electro-chemical methods pesticide active ingredient pesticide metabolites residue analysis and/or do portable electronic pesticide residue analysis is the analysis method to be used in property:

opening of the device with the on/off button,

- in the process, with the adoption of the code and password opening analysis home page, to begin the process, analysis on the main window is registered in the database of the Ministry of the manufacturer ID and/or the manufacturer's registration number must be written,

in the process, selecting the product to do the analysis menu analysis,

in the process, the analysis set should be placed in the slot of the tip,

- with the introduction of the software installed on the device the process analysis kit instance located at the selected products occurs on the pesticide we brought the reaction of active kit electric signals according to the pesticide active ingredient will be chosen automatically installed on the device the analysis program into electrochemical analysis methods of data, in the process, the pesticide active ingredient contained in the analysis kit metabolites detected in electrochemical sensors of detection of installed software on the device according to the metabolite will be activated automatically by analyzing data from into, in the process, at the end of the time set, the data obtained through the software on the device can be read, processed and converted to numeric values,

the numeric value of the process, analysis, data detected with active ingredient turned into a chart table with values of the device memory to be saved,

in the process, the analysis of installed software on the device state provider program and wireless internet connections and related land, the company's database product manufacturer, along with the site by registering,

- the current membership of the user code and password to begin processing, product manufacturer, and the system of land and although this pretreatment steps then analysis program can be started,

during the process, as required by the installed software on the device program feature analysis once the user process any data deletion, cancellation, in case of faulty operation during the device screen warning and error correction can be continue with; This process can also be saved to system memory,

SUBSTITUTE SHEETS (RULE 26) the reduction of the device during device installed protective software analysis and so on cases with the introduction of the sensor that detects the screen blurring and executed the procedure as freeze protection process; normal conditions of use, it is advisable to continue where it left off when it comes to processing,

the battery power level is 2% of cases, audible and light warning and critical power levels can be made only at the device analysis, taking the previous and current data protection process steps.

Before the harvest in agricultural production in the field and live plant will be chosen in electrochemical methods remains of pesticide active ingredient pesticide and/or metabolites analysis is pesticide residue analysis of portable electronic device will feature: durable and lightweight material, water, dust, and moisture-proof, short term water drops, splashes, resistant to water pressure low and high intensity short term external body part; the system will run inland and will perform the analysis process, the resulting data can be read on digital devices will convert the values to the device software enhancement MRI SCANS installed Graphene and/or super fast high carriers containing compound transition metals - based micro-processor, graphics processor, microcontroller, memory and electronic circuit chips, hard disk on which the operating system is installed, a card is the microchip, GPS, micro sim card slot on the printer processor, a motherboard and/or cards group; bumps, drops and so on cases analysis done on the device in order to take the fall to protect the process of multiplication by detecting negative situations, etc about the procedure automatically until the device will freeze and normal use deletion to protect against sudden motion sensor motion sensor puts the protective system; sets the screen brightness according to ambient light ambient light sensors; the use of the programs for the operating system of the device and allows access to, water, dust, and moisture-proof, short term water drops, splashes, resistant to low and high intensity short term water pressure, fingerprint stain repellent, the entire process, information introduction was written by tapping the on-screen keyboard of the finger and the finger movements of the menu dial, both numerical and graphical images can be made suitable for the vertical and horizontal operation of capacitive touch screen; will multiple pesticide analysis device off when not in use and water, protection against dust and humidity, and automatically locked mini sliding lid preserved one or more of the test kit is to be used for regular calibration calibration the device of the kit to be worn while working and possible external factors that enable protection from water, dust, and moisture repellent nano-material, covered with full contact on the tip and entry kit slot sitting on each other is locked and sealed when covered with protective nano material provided the featured input slot; on the main body to dust, water and moisture resistant standard sim card and memory card is inserted, discharge of the sticker system a dual card slot; It's in the back of the protective device, water, dust and moisture-resistant protective cover made of durable and lightweight material that featured; when the paper roll is located under the hood that allows a change of a mini printer roll slots; when not in use, protection against water, dust and humidity property on the output of the printer paper closes snugly seated valve; when you need additional data to the device in order to provide input when not in use, protection against water, dust and humidity sitting snugly on the property when installed under the hood to provide a complete sealing mini protector-Bay data cable entry; have the same protective cover the protective property RS485 and/or different port entry;

SUBSTITUTE SHEETS (RULE 26) located at the bottom of the back cover of the device's various protective power battery compartment; at least 1000 enables at least 8 hours continuous measurement device capable of running and active stand by position, they can expect at least 24 hours have rechargeable and smart battery characteristics battery; located on the side of the device and a device to turn on/off button.

According to claim 2, before the harvest in agricultural production, in the field and live plant will be chosen in the electro-chemical methods pesticide active ingredient pesticide metabolites residue analysis and/or portable electronic pesticide residue analysis is the device that will make property: durable and lightweight material, water, dust, and moisture- proof, short term water drops, splashes, resistant to water pressure low and high intensity short term external body part.

4. According to claim 3, before the harvest in agricultural production, in the field and live plant will be chosen in the electro-chemical methods pesticide active ingredient pesticide metabolites residue analysis and/or portable electronic pesticide residue analysis is the device that will make property: the system will run inland and will perform the analysis process, the resulting data can be read on digital devices will convert the values to the device software enhancement MRI SCANS installed Graphene and/or super fast high carriers containing compound transition metals-based micro-processor, graphics processor, microcontroller, memory and electronic circuits, chips, the hard disk on which the operating system is installed, the GPS microchip, the video card, the processor micro -printer, movement and ambient light adjustment sensor processors, the motion sensors comes in now will get software to protect data in the device, set the ambient light sensor is now sticking of environment will set the screen brightness according to software brightness and a sim card slot on the mainboard.

According to claim 4, before the harvest in agricultural production, in the field and live plant will be chosen in the electro-chemical methods pesticide active ingredient pesticide metabolites residue analysis and/or portable electronic pesticide residue analysis is the device that will make property: setting up the GPS device, movement and ambient light sensors, circuits, depending on the motherboard of the printer circuit and processing electronic circuit boards. 6. According to claim 5, before the harvest in agricultural production, in the field and live plant will be chosen in the electro-chemical methods pesticide active ingredient pesticide metabolites residue analysis and/or portable electronic pesticide residue analysis is the device that will make property: bumps, drops and so on cases analysis done on the device in order to take the fall to protect the process of multiplication by detecting negative situations, etc about the procedure automatically until the device will freeze and normal use deletion to protect against sudden motion sensor that puts protective system motion sensors.

According to claim 6, before the harvest in agricultural production, in the field and live plant will be chosen in the electro-chemical methods pesticide active ingredient pesticide metabolites residue analysis and/or portable electronic pesticide residue analysis is the device that will make property: detects the device display environment lightness brightness automatically adjusts the ambient light detection sensors.

SUBSTITUTE SHEETS (RULE 26)

8. According to claim 7, before the harvest in agricultural production, in the field and live plant will be chosen in the electro-chemical methods pesticide active ingredient pesticide metabolites residue analysis and/or portable electronic pesticide residue analysis is the device that will make property: the use of the programs for the operating system of the device and allows access to, water, dust, and moisture-proof, short term water drops, splashes, resistant to low and high intensity short term water pressure, fingerprint stain repellent, the entire process, information introduction was written by tapping the on-screen keyboard of the finger and the finger movements of the menu dial, both numerical and graphical images can be made suitable for the vertical and horizontal operation of capacitive touch screen.

9. According to claim 8, before the harvest in agricultural production, in the field and live plant will be chosen in the electro-chemical methods pesticide active ingredient pesticide metabolites residue analysis and/or portable electronic pesticide residue analysis is the device that will make property: will multiple pesticide analysis device off when not in use and water, protection against dust and humidity, and automatically locked mini sliding lid preserved one or more of the test kit is to be used for regular calibration calibration the device of the kit to be worn while working and possible external factors that enable protection from water, dust, and moisture repellent nano-material, covered with full contact on the tip and entry kit slot sitting on each other is locked and sealed when covered with protective nano material provided the featured input slot.

10. According to claim 9, before the harvest in agricultural production, in the field and live plant will be chosen in the electro-chemical methods pesticide active ingredient pesticide metabolites residue analysis and/or portable electronic pesticide residue analysis is the device that will make property: on the main body to dust, water and moisture resistant standard sim card and memory card is inserted, discharge of the sticker system a dual card slot.

11. According to claim 10, before the harvest in agricultural production, in the field and live plant will be chosen in the electro-chemical methods pesticide active ingredient pesticide metabolites residue analysis and/or portable electronic pesticide residue analysis is the device that will make property: it's in the back of the protective device, water, dust and moisture-resistant protective cover made of durable and lightweight material featured on the.

12. According to claim 11, before the harvest in agricultural production, in the field and live plant will be chosen in the electro-chemical methods pesticide active ingredient pesticide metabolites residue analysis and/or portable electronic pesticide residue analysis is the device that will make property: when the paper roll is located under the hood that allows a change of a mini printer roll slot.

13. According to claim 12, before the harvest in agricultural production, in the field and live plant will be chosen in the electro-chemical methods pesticide active ingredient pesticide metabolites residue analysis and/or portable electronic pesticide residue analysis is the device that will make property: when not in use, protection against water, dust and humidity property on the output of the printer paper closes snugly with seat cover.

SUBSTITUTE SHEETS (RULE 26)

14. According to claim 13, before the harvest in agricultural production, in the field and live plant will be chosen in the electro-chemical methods pesticide active ingredient pesticide metabolites residue analysis and/or portable electronic pesticide residue analysis is the device that will make property: when you need additional data to the device in order to provide input when not in use, protection against water, dust and humidity sitting snugly on the property when installed under the hood to provide a complete sealing mini protector-Bay data cable entry.

15. According to claim 14, before the harvest in agricultural production, in the field and live plant will be chosen in the electro-chemical methods pesticide active ingredient pesticide metabolites residue analysis and/or portable electronic pesticide residue analysis is the device that will make property: have the same protective cover the protective property RS485 and/or different port entry.

16. According to claim 15, before the harvest in agricultural production, in the field and live plant will be chosen in the electro-chemical methods pesticide active ingredient pesticide metabolites residue analysis and/or portable electronic pesticide residue analysis is the device that will make property: sundry power battery compartment.

17. According to claim 16, before the harvest in agricultural production, in the field and live plant will be chosen in the electro-chemical methods pesticide active ingredient pesticide metabolites residue analysis and/or portable electronic pesticide residue analysis is the device that will make property: device for a period of at least 8 hours provide the power to run the device is opened if the device holds a 24 hour stand by ready for analysis, the test can do about 1000 life, rechargeable and smart battery features battery.

18. According to claim 17, before the harvest in agricultural production, in the field and live plant will be chosen in the electro-chemical methods pesticide active ingredient pesticide metabolites residue analysis and/or portable electronic pesticide residue analysis is the device that will make property: located on the side of the device and a device to turn on/off button.

SUBSTITUTE SHEETS (RULE 26)