WO2017023051A1 - Drain pipe cleaning kit and cleaning method using same - Google Patents

Drain pipe cleaning kit and cleaning method using same Download PDF

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Publication number
WO2017023051A1
WO2017023051A1 PCT/KR2016/008407 KR2016008407W WO2017023051A1 WO 2017023051 A1 WO2017023051 A1 WO 2017023051A1 KR 2016008407 W KR2016008407 W KR 2016008407W WO 2017023051 A1 WO2017023051 A1 WO 2017023051A1
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WO
WIPO (PCT)
Prior art keywords
cleaning
agent
foam
pipe
drain pipe
Prior art date
Application number
PCT/KR2016/008407
Other languages
French (fr)
Korean (ko)
Inventor
유인기
김치회
곽상운
이상민
신승일
권혁수
조민경
Original Assignee
주식회사 엘지생활건강
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from KR1020160029739A external-priority patent/KR20170015100A/en
Priority claimed from KR1020160041660A external-priority patent/KR101857117B1/en
Priority claimed from KR1020160086883A external-priority patent/KR102540064B1/en
Priority claimed from KR1020160086875A external-priority patent/KR20170101084A/en
Priority claimed from KR1020160089926A external-priority patent/KR20180008090A/en
Application filed by 주식회사 엘지생활건강 filed Critical 주식회사 엘지생활건강
Priority to JP2018504849A priority Critical patent/JP6960902B2/en
Priority to CN201680044945.0A priority patent/CN107923165B/en
Publication of WO2017023051A1 publication Critical patent/WO2017023051A1/en
Priority to HK18113386.5A priority patent/HK1254243A1/en

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B08CLEANING
    • B08BCLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
    • B08B3/00Cleaning by methods involving the use or presence of liquid or steam
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B08CLEANING
    • B08BCLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
    • B08B3/00Cleaning by methods involving the use or presence of liquid or steam
    • B08B3/04Cleaning involving contact with liquid
    • B08B3/08Cleaning involving contact with liquid the liquid having chemical or dissolving effect
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B08CLEANING
    • B08BCLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
    • B08B9/00Cleaning hollow articles by methods or apparatus specially adapted thereto 
    • B08B9/02Cleaning pipes or tubes or systems of pipes or tubes
    • B08B9/027Cleaning the internal surfaces; Removal of blockages
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D1/00Containers having bodies formed in one piece, e.g. by casting metallic material, by moulding plastics, by blowing vitreous material, by throwing ceramic material, by moulding pulped fibrous material, by deep-drawing operations performed on sheet material
    • B65D1/22Boxes or like containers with side walls of substantial depth for enclosing contents
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D1/00Containers having bodies formed in one piece, e.g. by casting metallic material, by moulding plastics, by blowing vitreous material, by throwing ceramic material, by moulding pulped fibrous material, by deep-drawing operations performed on sheet material
    • B65D1/40Details of walls
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D25/00Details of other kinds or types of rigid or semi-rigid containers
    • B65D25/38Devices for discharging contents
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D11/00Special methods for preparing compositions containing mixtures of detergents ; Methods for using cleaning compositions
    • EFIXED CONSTRUCTIONS
    • E03WATER SUPPLY; SEWERAGE
    • E03CDOMESTIC PLUMBING INSTALLATIONS FOR FRESH WATER OR WASTE WATER; SINKS
    • E03C1/00Domestic plumbing installations for fresh water or waste water; Sinks
    • E03C1/12Plumbing installations for waste water; Basins or fountains connected thereto; Sinks
    • E03C1/26Object-catching inserts or similar devices for waste pipes or outlets
    • E03C1/264Separate sieves or similar object-catching inserts
    • EFIXED CONSTRUCTIONS
    • E03WATER SUPPLY; SEWERAGE
    • E03CDOMESTIC PLUMBING INSTALLATIONS FOR FRESH WATER OR WASTE WATER; SINKS
    • E03C1/00Domestic plumbing installations for fresh water or waste water; Sinks
    • E03C1/12Plumbing installations for waste water; Basins or fountains connected thereto; Sinks
    • E03C1/30Devices to facilitate removing of obstructions in waste-pipes or sinks

Definitions

  • the present invention relates to a foam cleaning drain pipe cleaner, a cleaning container capable of continuously supplying the same to the drain pipe, and a cleaning method using the same, and more specifically, to continuously supply the foam cleaning drain pipe cleaner to the drain pipe to maximize the cleaning effect.
  • the strainer and drain pipe of the sink remain in the process of cooking or discarding food, and it is always wet with water, so it is easy to grow microorganisms, causing dirty and bad smell. Cleaning them to keep the strainer or drainpipe clean is inconvenient and time consuming and labor intensive. However, there is a problem because there is no special alternative to replacing the strainer or the drain pipe.
  • US patent application 14/529388 discloses a two-part system for foaming hydrogen peroxide with a hydrolase such as amylase to clean a pipe.
  • a hydrolase such as amylase
  • US Patent Publication No. US2003 / 0171234 A1 discloses a method of cleaning a pipe by pouring and foaming a sodium hypochlorite composition having a viscosity and a blowing agent at the same time.
  • sodium hypochlorite and the blowing agent are difficult to be uniformly mixed, and there is a limit in maintaining the cleaning power by quickly discharging bubbles in the pipe of the sink installed vertically for a long time.
  • the sodium hypochlorite composition is mixed with acidic hydrogen peroxide to obtain a foaming effect, there is a problem that a large amount of chlorine gas harmful to the human body is generated.
  • the problem to be solved by the present invention is a cleaning container that can continuously generate the cleaning effect on the drain pipe by washing the strainer with foam generated by using the foam pipe for cleaning the drain pipe, and flowing the cleaner to the drain pipe To provide.
  • the problem to be solved by the present invention is to provide a drain pipe cleaning composition in which the cleaning effect on the drain pipe is maximized and the generation of chlorine gas is suppressed.
  • the problem to be solved by the present invention is to provide a kit comprising a foam pipe cleaning drain pipe cleaning agent and foam cleaning pipe cleaning pipe.
  • the problem to be solved by the present invention is to provide a method for effectively cleaning the kitchen sink sieve and drain pipe at the same time using the cleaning container.
  • the present invention provides a cleaning container capable of slowly flowing the foaming pipe for cleaning the drain pipe to the drain to solve the above problems, and a method for effectively foam cleaning the strainer and drain pipe of the kitchen sink using the same.
  • the inventors of the present invention as a result of earnest research efforts to overcome the problems of the prior art, has developed a cleaning container including an inlet and a discharge port that can slowly flow the foam cleaning cleaner to the strainer, drain and drain pipe.
  • the foam cleaning cleaner is used together with the cleaning container, the foam-rich cleaner is discharged through the inlet to effectively clean the strainer and the drain, and the foam pipe is gradually discharged through the discharge port, thereby foaming the drain pipe for a long time. It is possible to complete the present invention by making a surprising discovery that the cleaning effect on the strainer, drain and drain pipe of the kitchen sink is remarkably improved.
  • the present invention provides a container body having a receiving space formed therein; An inlet for introducing a foamed washing drain pipe cleaner into the accommodation space; And at least one discharge port formed in the container body to communicate the receiving space accommodated in the container main body with the drain pipe, and discharging the detergent contained in the receiving space into the drain pipe.
  • a drain pipe cleaning container for foaming cleaning which is discharged at a slower speed.
  • the cleaning agent is directly treated on the drain pipe, it means that the cleaning agent is directly disposed on the drain port or the drain pipe without using the cleaning container.
  • the cleaning container may be installed in a drain hole provided to be connected to the drain pipe.
  • the foam pipe cleaning vessel for cleaning the foam can effectively wash the drain or the strainer by allowing the bubbles generated from the foaming detergent composition to overflow into the drain and the strainer through the inlet, and by slowly flowing the cleaner through a small discharge port to the cleaning effect to the drainage pipe It maintains continuously, and the drain pipe cleaning effect is remarkably excellent.
  • the foam cleaning drain pipe cleaning vessel may clean the drain pipe or the sieve with foamed foam and at the same time, clean the drain pipe with a cleaner through a small discharge port.
  • the foam pipe washing vessel for cleaning the foam may be in the form of a cup including a discharge port for cleaning the drain and the sieve with foam generated from the foaming detergent and flowing the cleaning agent to the drain pipe slowly,
  • Figure 1 the cup form One embodiment of the water pipe cleaning vessel for foaming cleaning is shown.
  • the foam cleaning drain pipe cleaning vessel may be a container of the type that gradually decreases in diameter from the upper surface to the lower surface.
  • 5 is a view of a foam pipe washing vessel cleaning vessel having the characteristics as described above.
  • the diameter of the upper surface may be the same or somewhat smaller diameter than the drain or the strainer.
  • the diameter of the upper surface may have a predetermined diameter to be inserted into the drain hole or the strainer to be fitted.
  • the upper surface may further include a locking step that can be caught in the drain hole along the circumference of the upper end. Since the diameter of the container gradually decreases from the upper surface to the lower surface as described above, the upper end of the container may be spread over the drain or the strainer, and the lower end may enter the strainer.
  • the foam pipe cleaning vessel may include a concave-convex structure in which the concave-convex grooves are provided at predetermined intervals so that the cleaning agent discharged through the inlet flows on the outer surface.
  • the concave-convex structure as described above, even if the container is tightly fitted into the strainer or the drain, the discharged detergent flows down the concave-convex structure to improve the cleaning effect on the strainer or the drain.
  • the cleaning agent contained in the accommodation space may be discharged at a slower speed than when the cleaning agent is directly treated in the drain pipe, and the speed is not particularly limited, but the cleaning agent contained in the accommodation space is
  • the discharge rate may be 10 to 180 minutes, preferably 20 to 150 minutes, more preferably 30 to 120 minutes.
  • the discharge port of the cleaning container is predetermined so that the cleaning agent is discharged through the discharge port at 1 to 100 ml / min, preferably 5 to 50 ml / min, more preferably 7 to 20 ml / min It may have a diameter.
  • the predetermined diameter of the discharge port may be 0.1 to 10 mm, preferably 0.3 to 5 mm, more preferably 0.5 to 3 mm. If the diameter of the discharge port is less than 0.1 mm there is a problem that the cleaning agent flows out too slowly and the cleaning time is longer than necessary, if more than 10 mm flows out too quickly, the cleaning force increase effect expected in the present invention may be insignificant.
  • the cleaning vessel has a predetermined diameter such that the cleaning agent is discharged through the discharge port for 10 minutes to 180 minutes, preferably 20 minutes to 150 minutes, more preferably 30 minutes to 120 minutes and It may have a number of discharge ports.
  • the foaming cleaning agent is discharged within 30 minutes, the average killing rate of microorganisms is low, and if more than 120 minutes, it is appropriate to discharge between 30 minutes to 120 minutes because the effect of increasing the sterilization power is insignificant.
  • the predetermined diameter of the discharge port may be 0.1 to 10 mm, preferably 0.3 to 5 mm, more preferably 0.5 to 3 mm, most preferably 1 to 2.5 mm.
  • the number of the discharge openings may be 1 to 8, preferably 1 to 6, more preferably 2 to 5.
  • the cleaning agent can be discharged for 30 to 120 minutes through the discharge port, the drain pipe cleaning effect is the best Can be exercised. More preferably, the cleaning agent of the present invention exhibits a sufficient cleaning effect when the drainage pipe is cleaned for 50 minutes or more, and there is no difference in the effect even if the cleaning of the drain pipe is performed for more than 50 minutes.
  • the present invention is a container body having a receiving space formed therein; An inlet for introducing a foamed washing drain pipe cleaner into the accommodation space; At least one discharge port formed in the container body such that the accommodation space accommodated in the container body communicates with the drain pipe, and discharge the cleaning agent contained in the accommodation space to the drain pipe; And a mesh member through which the foam cleaning drain pipe cleaner passes, and provides a foam cleaning drain pipe cleaning container for discharging the cleaning agent at a slower speed than when the cleaning agent is directly processed into the drain pipe.
  • the foam cleaning drain pipe cleaning container may have a mesh member through which the drain pipe cleaner passes, at the inlet. This allows the first and second agents of the cleaning agent introduced through the mesh member of the inlet to be spread evenly inside the cleaning container and mixed uniformly.
  • the foam of the foamed detergent is discharged to the outside through the mesh member formed in the inlet, the denser foam is formed can be greatly improved cleaning effect.
  • the mesh member may be a mesh.
  • a member made of a non-woven fabric having a nonuniform spacing may be used instead of a mesh member having a uniform spacing, but is not limited thereto.
  • the pore size of the mesh member can be used in the range of 100 to 10000 microns, preferably 300 to 4000 microns, more preferably 400 to 2000 microns, and most preferably 400 to 900 microns. If the mesh member is less than 100 microns, the cleaning composition does not pass well and is inappropriate. If the mesh member is more than 10000 microns, the uniformity of the cleaning mixture and the density of the discharged bubbles are inferior.
  • the mesh member may be made of a wire including any one or more materials selected from the group consisting of stainless steel, fiber glass, polyethylene (PE) and the like.
  • the mesh member may be used to form a square mesh of the vertical cross and vertical lines of the wire.
  • the foam cleaning drain pipe cleaning container includes a discharge port for cleaning the drain and the sieve with foam generated from the foaming detergent and flowing the cleaning agent to the drain pipe slowly, and may be in the form of a cup with a mesh member formed in the inlet 12 shows an embodiment of the cup washing container for foam cleaning in the form of a cup.
  • the material for the foam cleaning drain pipe cleaning container is HDPE (high density polyethylene), LDPE (low density polyethylene), PET (polyethylene terephthalate), PP (polypropylene), PE (polyethylene), PC (polycarbonate), Commonly used plastic materials such as PS (polystyrene) or ABS (acrylonitrile butadiene styrene), paper, glass, or metal may be used.
  • any foaming cleaning drain pipe cleaning composition may be used without any particular limitation as long as it is a cleaning composition that is commonly used, such as a composition including lacx for cleaning a strainer, a drain or a drain pipe.
  • the present invention provides a drainage cleaning agent for foam cleaning comprising separately separating a first composition comprising a chlorine-based cleaning agent component, preferably hypochlorite and a second composition comprising a blowing agent, preferably hydrogen peroxide.
  • the foam pipe for cleaning the drainage pipe may be separately contained a one-component composition comprising a chlorine-based cleaner component and a two-component composition comprising a blowing agent.
  • the first agent composition or second agent composition may include anionic surfactants, nonionic surfactants, or mixtures thereof.
  • the first agent composition and the second agent composition can be used by mixing in the receiving space of the foam pipe washing vessel cleaning vessel of the present invention in use.
  • the first agent composition and the second agent composition are 10: 1 to 1:10, preferably 5: 1 to 1: 5, more preferably 3: 1 to 1: 3 (one agent composition: second agent composition). It can be used as, the foaming force and the cleaning power is the best within this weight ratio range.
  • the reaction of the chlorine-based detergent component and the blowing agent may be used to generate oxygen by foaming as shown in Scheme 1 below.
  • the foaming reaction can be generated in various ways. For example, there is a reaction between sodium carbonate or sodium bicarbonate and an organic acid (citric acid or lactic acid) or an inorganic acid (sulfamic acid, etc.) and a similar effect by combining a surfactant or a bactericide. Can be obtained.
  • hypochlorite and hydrogen peroxide may be reacted as a main component to generate a foaming cleaning effect. In this case, the effect is the most excellent compared to other foaming cleaning methods.
  • the first agent may include a chlorine-based detergent component, preferably hypochlorite as a main component, which is excellent in sterilization and bleaching effect, and when diluted, has a fast decomposition rate, low persistence, and low oral toxicity. It can be effectively used for disinfection.
  • a chlorine-based detergent component preferably hypochlorite as a main component, which is excellent in sterilization and bleaching effect, and when diluted, has a fast decomposition rate, low persistence, and low oral toxicity. It can be effectively used for disinfection.
  • hypochlorite used as the active ingredient of the sterilization or disinfection may be used one or more selected from the group consisting of sodium hypochlorite ion (NaOCl), potassium hypochlorite, calcium hypochlorite and magnesium hypochlorite.
  • NaOCl sodium hypochlorite ion
  • potassium hypochlorite potassium hypochlorite
  • calcium hypochlorite calcium hypochlorite
  • magnesium hypochlorite preferably sodium hypochlorite can be used as hypochlorite.
  • the chlorine cleaner component preferably hypochlorite may be used in an amount of 0.1 to 30% by weight, preferably 5 to 27% by weight, and more preferably 15 to 25% by weight, based on the total weight of the first composition.
  • the chlorine-based cleaner component is used in less than 0.1% by weight, the function as a disinfectant or disinfectant is weak, and when used in excess of 30% by weight, the compatibility with the surfactant is not good, and the stability of the chlorate ion itself is disadvantageous.
  • hypochlorite and hydrogen peroxide are 1: 1 to 10: 1, preferably 1.25: 1 to 9: 1, more preferably 2: 1 to 7: 1, in order to improve the foam cleaning effect of the cleaning composition. Most preferably, it may be included in the equivalent ratio (hypochlorite: hydrogen peroxide) of 3: 1 to 5: 1.
  • the cleaning composition containing such an equivalent ratio range has the best foaming power and the cleaning power.
  • the present invention also provides a drain pipe cleaner composition
  • a drain pipe cleaner composition comprising a chlorine-based cleaner component, a two agent comprising a blowing agent, and a pH adjusting agent, preferably a two-component foam cleaner for drain pipe cleaning.
  • the chlorine-based cleaner may be used hypochlorite, etc.
  • the blowing agent may be used hydrogen peroxide and the like.
  • the pH adjusting agent is additionally included so that the pH of the chlorine-based cleaner component is mixed with the blowing agent, the generation of chlorine gas harmful to the human body is significantly suppressed.
  • the drain pipe cleaner composition of the present invention can maintain the pH of the composition containing one chlorine cleaner component, preferably sodium hypochlorite by 12 or more by including a pH adjuster.
  • the pH of the mixture can be maintained at 9 or more, so that a large amount of chlorine gas is not generated, so that the human body is safe for the kitchen sink and drain pipe Can be foamed and washed.
  • a large amount of harmful chlorine gas may be generated in the process of mixing the first agent comprising sodium hypochlorite as the main ingredient and the second agent containing acidic hydrogen peroxide as the main ingredient, which may be very dangerous to the human body, thereby minimizing the generation of chlorine gas.
  • drugs 1 and 2 should be designed carefully. In particular, it is preferable to reduce the amount of generation of chlorine gas to a minimum even when mixing the first agent and the second agent.
  • Sodium hypochlorite generates a large amount of chlorine gas under the condition below pH 9 can be very dangerous to the human body, chlorine gas may suddenly occur even at the time of mixing the first and second agents, to prevent It is very important to adjust the pH of the mixed solution.
  • part of the sodium hypochlorite contained in the first agent may be converted into sodium chloride, water and oxygen by reacting with hydrogen peroxide.
  • the pH of the mixture of the first agent and the second agent is preferably 9-14, more preferably pH 11-14. It is safer to be.
  • the drain pipe cleaning composition of the present invention can suppress the generation of chlorine gas when mixing the first agent and the second agent by including a pH adjuster.
  • the amount of chlorine gas generated in the use of the drain pipe cleaner composition may be less than 300 ppm, preferably less than 100 ppm, more preferably less than 50 ppm.
  • the toxic concentration (LC50) of chlorine gas is 293 ppm.
  • the drain pipe cleaning composition of the present invention significantly suppresses the amount of chlorine gas generated when used compared to the toxic concentration (LC50), thereby providing excellent safety for the human body.
  • the drainage pipe cleaning composition may be a pH adjusting agent to minimize the generation of chlorine gas by maintaining a pH of 9 or more after mixing the first agent and the second agent.
  • the pH adjusting agent any one or more selected from the group consisting of sodium hydroxide (NaOH), potassium hydroxide (KOH), sodium silicate (Na 3 SiO 3 , Na 4 SiO 4 ), sodium carbonate (Na 2 CO 3 ), and the like may be used. And preferably sodium hydroxide may be used.
  • the drainage pipe cleaning composition of the present invention may be maintained at a pH of 9 to 14 when mixing the first agent and the second agent by including a pH adjuster.
  • the pH adjusting agent may be included in the first agent, in which case the first agent may be maintained at a pH of 12 to 14.
  • the pH adjusting agent is equivalent to the ratio of the total hydrogen ions of the acidic material contained in the second agent to 1.1 to 10: 1, preferably 1.1 to 5: 1, more preferably 1.1 to 3: 1 (pH regulator: 2 Total hydrogen ion equivalent weight of the acidic material included in the agent).
  • pH adjuster is included in an equivalent ratio of 1.1: 1 (pH adjuster: total hydrogen ion equivalents of the acidic substances included in the second agent)
  • the pH after mixing may be less than 9, thereby rapidly increasing the amount of chlorine gas generated.
  • the pH adjusting agent is included in an amount of more than 10: 1 equivalent ratio (pH adjusting agent: total hydrogen ion equivalents of the acidic substances included in the second agent)
  • the reactivity of the chlorine-based cleaner component and the blowing agent may decrease.
  • the single-agent composition may include anionic surfactants, nonionic surfactants or mixtures thereof to increase the sterilization or disinfection power of hypochlorite ions and to improve the cleaning effect and viscosity.
  • anionic surfactant may include an alkyl ether sulfate of Formula 1, preferably SLES (sodium lauryl ether sulfate).
  • R is an alkyl group of C10 to C16, n is an integer of 1 to 5, M represents sodium or potassium
  • the anionic surfactant may include a mixture of the alkyl ether sulfate of Formula 1 and the alkyl amine oxide of Formula 2 below.
  • the alkyl amine oxide of Formula 2 may be used lauramine oxide (lauramine oxide).
  • the synergistic effect between the surfactants and the interaction with the surfactant and hypochlorite compared with the case of using each alone Excellent detergency and viscosity can be formed.
  • the weight ratio of the alkyl ether sulfate and alkyl amine oxide is 1:20 to 20: 1, preferably 1:10 to 10: 1, more preferably 1: 1 to 10: 1, most preferably 3: 1 to 7: 1 (alkyl ether sulfate: alkyl amineoxide).
  • the viscosity of the first composition of the present invention may be best formed.
  • the one-component composition may further include an inorganic alkali salt in order to promote viscosity formation by the interaction between the surfactant and the hypochlorite ion while maintaining alkalinity.
  • the alkali free salt is at least one selected from the group consisting of sodium carbonate (Na 2 CO 3 ), sodium bicarbonate (NaHCO 3 ), sodium silicate (Na 3 SiO 3 , Na 4 SiO 4 ) and sodium hydroxide (NaOH) and the like. And preferably sodium hydroxide may be used.
  • the inorganic alkali salt may be used in 0.1 to 10% by weight, preferably 0.5 to 7% by weight relative to the total weight of the first composition.
  • the inorganic alkali salt is used at less than 0.1% by weight, the effect of promoting alkaline retention and viscosity formation is weak, and when it exceeds 10% by weight, the reactivity of hypochlorite and hydrogen peroxide may be reduced.
  • the type and amount of the inorganic alkali salt may be selected to maintain the pH of the formulation of 1 to 10, wherein maintaining the pH above 10 is not only an important factor in maximizing the chemical stability of the formulation This is a factor to improve the decontamination ability of the surfactant.
  • maintaining the pH of the first composition at 10-14 helps to minimize chemical degradation of the hypochlorite compound in aqueous solution and to minimize chemical interaction between the hypochlorite compound and the surfactant.
  • the foam pipe for cleaning the drainage pipe, it may further include a fragrance in order to reduce the strong odor of hypochlorite ions and satisfy the aesthetic requirements.
  • the fragrance may be used that is stable to hypochlorite ions, it may be used in 0.01 to 2% by weight relative to the total weight of the first composition.
  • the pH of the single-agent composition according to the present invention is preferably maintained at 10 to 14, when the pH of the prepared single-agent composition is not within this range, additionally, a pH adjusting agent may be used. 14 can be adjusted. Citric acid, sodium hydroxide, calcium hydroxide, or triethanolamine may be used as the pH adjusting agent.
  • the foam pipe for cleaning the drain pipe uses a two-component composition, which is an oxygen-based foamable composition, for the purpose of generating bubbles, and hydrogen peroxide that reacts with hypochlorite of the one-component composition to generate oxygen. It can be included as.
  • the two-component composition may include anionic surfactants, nonionic surfactants, or mixtures thereof to improve the cleaning effect while maintaining a viscosity of 100 cps or more, and a radical stabilizer to stably distribute hydrogen peroxide. It may include.
  • the hydrogen peroxide may be included in 0.1 to 30% by weight, preferably 5 to 27% by weight, more preferably 15 to 25% by weight relative to the total weight of the second composition.
  • the hydrogen peroxide is less than 0.1% by weight, the foaming effect and the increase in the cleaning effect thereof are insignificant.
  • the hydrogen peroxide is more than 30% by weight, the stability of the second agent composition is lowered, making it difficult to distribute.
  • the second composition stabilizes hydrogen peroxide, which is a main component, and for this purpose, the second composition may further include a radical stabilizer.
  • the radical stabilizer may be used salicylic acid represented by the following formula (3), but is not limited thereto.
  • the radical stabilizer may be included in 0.01 to 15% by weight, preferably 0.1 to 5% by weight, more preferably 0.5 to 3% by weight relative to the total weight of the second composition.
  • the radical stabilizer is less than 0.01% by weight, the hydrogen peroxide stabilization effect is not sufficient, and when the radical stabilizer is more than 15% by weight, there is a problem of lowering the stability of the second composition.
  • the two-component composition may further include inorganic salts such as sodium carbonate and sodium sulfate, polymers, or fragrances, which are commonly used in detergent compositions, in addition to the aforementioned components.
  • inorganic salts such as sodium carbonate and sodium sulfate, polymers, or fragrances, which are commonly used in detergent compositions, in addition to the aforementioned components.
  • the first composition and the second composition may each include an anionic surfactant, a nonionic surfactant, or a mixture thereof. have.
  • the anionic surfactant may be included in 0.1 to 10% by weight, preferably 0.5 to 7% by weight relative to the total weight of each of the first agent composition or second agent composition.
  • the nonionic surfactant may be included in an amount of 0.1 to 10% by weight, preferably 0.5 to 7% by weight, based on the total weight of each of the first agent composition or the second agent composition.
  • the first agent composition and the second agent composition may each include a mixture of anionic surfactant and nonionic surfactant. More preferably, the weight ratio of the anionic surfactant and nonionic surfactant in the mixture is 1:10 to 10: 1, preferably 1: 5 to 5: 1, more preferably 1: 3 to 3: 1 (anionic surfactant : Nonionic surfactant), and the effect of improving viscosity and cleaning power is most excellent within this weight ratio range.
  • the anionic surfactant, nonionic surfactant, or a mixture thereof may be included in an amount of 1 to 40% by weight, preferably 3 to 30% by weight, and more preferably 5 to 20% by weight, based on the total weight of the detergent. .
  • the content of the surfactant is less than 1% by weight, the detergent performance is insignificant, and when the content of the surfactant is more than 40% by weight, the solubility of the detergent is reduced.
  • the nonionic surfactant is, for example, fatty alkoxypolyoxyethylene glycol (R5-CH- (O-CH 2 -CH 2 ) 1 -OH, wherein R5 is C11-C18 alkyl, l is 5-25 Integer), fatty acid polyoxyethylene glycol (R6-CO- (O-CH 2 -CH 2 ) m-OH, where R6 is C11-C18 alkyl, m is an integer of 5-25), alkylphenylpolyoxyethylene Glycol (R7-Ar-O- (CH 2 0CH 2 -O) nH, wherein R7 is C11-C18 alkyl, Ar is a benzene ring, n is an integer of 5-25), or polyoxyethylene glycol (H- (O-CH 2 -CH 2 ) i-OH, where i is an integer having a total molecular weight of 1,000 to 30,000) and the like may include any one or more selected from, but is not limited there
  • the present invention may further include any ingredients within the scope of not impairing the object of the present invention, preservatives, thickeners and viscosity modifiers, fragrances commonly used in detergent compositions to maintain basic physical properties and quality as a detergent composition. Or a dye may be further included.
  • a preservative may be a mixture of methyl paraoxybenzoate, methylchloroisothiazolinone and methylisothiazolinone (trade name: Kathon CG, manufactured by Rohm & Haas, USA).
  • Kathon CG methylchloroisothiazolinone
  • methylisothiazolinone trade name: Kathon CG, manufactured by Rohm & Haas, USA.
  • the thickener and the viscosity modifier hydroxypropyl methyl cellulose, hydroxymethyl cellulose, sodium chloride, ammonium chloride, propylene glycol, hexylene glycol and the like can be used.
  • the dye a water-soluble tar dye may be used.
  • the foam cleaning drain pipe cleaner may further include a thickener to slow the release rate.
  • the viscosity of the detergent composition containing the thickener may be 100 ⁇ 10,000 cps.
  • the thickener may be, for example, one or more selected from the group consisting of xanthan gum, locust bean gum, carrageenan, pectin, gelatin, and the like, but is not limited thereto.
  • the present invention comprises 0.1 to 30% by weight of hypochlorite, 0.1 to 10% by weight of anionic surfactant, 0.1 to 10% by weight of nonionic surfactant, and 0.05 to 10% by weight of inorganic alkali salts relative to the total weight of the first composition Agent composition; And separating the two-component composition comprising 0.1-30 wt% of hydrogen peroxide, 0.1-10 wt% of anionic surfactant, 0.1-10 wt% of nonionic surfactant, and 0.05-10 wt% of radical stabilizer, based on the total weight of the second composition.
  • It provides a drainage pipe cleaning agent for foam cleaning.
  • the foam pipe drainage cleaning agent is very good sterilization and disinfection of the strainer and drain pipe of the kitchen sink and has an excellent viscosity of more than 100 cps.
  • the foam cleaning drain pipe cleaner has a pH adjusting agent in one agent and a total ratio of hydrogen ions of the acidic substance contained in the second agent and an equivalent ratio of 1.1 to 10: 1 (pH regulator: total hydrogen ions of the acidic substance contained in the second agent). Equivalent weight).
  • the foam pipe cleaning agent may include 0.3 to 10 wt% of the pH adjusting agent in one agent, based on the total weight of the one agent composition. In such a case, generation of chlorine gas is remarkably suppressed in the use of the foam cleaning drain pipe cleaner, which is safe for the human body.
  • the foam pipe cleaning pipe cleaner may include the hypochlorite and hydrogen peroxide in an equivalent ratio (hypochlorite: hydrogen peroxide) of 1: 1 to 10: 1.
  • the foaming pipe cleaning composition for foam cleaning is significantly improved foaming amount, and excellent sterilization and disinfection of the strainer, drain and drain pipe.
  • the present invention also provides a foam cleaning drain pipe cleaning kit comprising the foam cleaning drain pipe cleaning container and the foam cleaning drain pipe cleaning agent.
  • the kit can be used by ordinary users to easily and effectively clean the strainer, drains and drains of the kitchen sink.
  • the present invention is a drainage pipe cleaner for foam cleaning comprising a first agent containing hypochlorite and a second agent containing hydrogen peroxide; And a container main body having an accommodating space formed therein, and an inlet for introducing a foaming washing drain pipe cleaner into the accommodating space, wherein the volume of the accommodating space is the foaming washing drain pipe cleaner. It provides a foam pipe cleaning kit for cleaning the foam, characterized in that less than the total volume of.
  • the cleaning kit includes the cleaning container included with the cleaning agent
  • the receiving space of the cleaning container is smaller than the total volume of the cleaning agent
  • the foam-rich cleaning agent overflows through the inlet to effectively clean the screen and the drain. Can be.
  • the volume of the receiving space may be smaller than the volume of the mixture of the first agent and the second agent in the foamed state and the bubbles generated therefrom.
  • the mixture of the first agent and the second agent of the foam cleaning drain pipe cleaner or bubbles thereof can overflow through the inlet of the receiving space, so that the cleaning power for the strainer and the drain is very excellent.
  • the volume of the accommodation space is larger than the sum of the mixture of the first agent and the second agent and the bubble volume, the cleaning effect is not sufficiently exerted on the strainer located above the cleaning container because the cleaning agent does not overflow through the inlet.
  • the volume of the receiving space and the volume of the foamed detergent is 1: 1.01-5, preferably 1: 1.05-3, more preferably 1: 1.1-2 (volume of the storage space: of the foamed detergent Volume). If the volume of the foamed detergent to the volume of the containing space is less than 1: 1.01 (volume of the receiving space: volume of the foamed detergent), the foamed detergent does not overflow the container or flows in a small amount, the cleaning effect is weak can do. If the volume of the foamed detergent to the volume of the containing space exceeds 1: 5 (volume of the receiving space: volume of the foamed detergent), there is a problem that the foamed detergent flows excessively to the bottom of the sink around the drain. .
  • the present invention provides a method for foam cleaning of the strainer and the drain pipe of the kitchen sink using the foam pipe for cleaning the drain pipe.
  • 2 shows a cleaning method of the present invention using the above-mentioned foamed cleaning drain pipe cleaner and a cleaning container.
  • the cleaning method includes the steps of: (s1) installing the foam cleaning drain pipe cleaning container in a drain; And (s2) simultaneously or sequentially pouring the first composition and the second composition of the cleaning agent into the accommodation space of the cleaning container.
  • the pouring order is irrelevant.
  • the method of foam cleaning the sieve and drain pipe of the kitchen sink is foamed by the mixing of the first agent composition and second agent composition after the step (s2) and the foam overflowed from the inlet of the cleaning vessel to wash the sieve, liquid foaming detergent Is gradually flowed through the discharge port to exert a continuous cleaning effect on the drain pipe, the cleaning method of the present invention can effectively clean the strainer and the drain pipe at the same time.
  • the foam cleaning drain pipe cleaning container of the present invention can effectively wash the foam of the foaming detergent by flowing into the strainer and the drain of the kitchen sink, and slowly flows the foaming cleaning drain pipe cleaner into the drain pipe to exert a continuous cleaning effect on the drain pipe. do.
  • the drain pipe cleaner composition of the present invention generates abundant bubbles when the chlorine-based cleaner component and the blowing agent are included in a specific weight ratio, so that the disinfection and cleaning effects on the strainer, drain and drain pipe of the sink are remarkably excellent.
  • the drain pipe cleaner composition of the present invention additionally includes a pH adjusting agent
  • the pH of the first agent and the second agent is maintained at 9 or higher when mixing, thereby significantly suppressing the generation of chlorine gas due to the reaction of the chlorine-based detergent component and the blowing agent. Safe and excellent cleaning effect can be achieved.
  • the foam cleaning drain pipe cleaning kit of the present invention can be caused to overflow the foam of the foaming detergent in the cleaning container, it is possible to effectively clean the strainer and drain holes of the kitchen sink.
  • Figure 1 shows an embodiment of the foam pipe washing vessel cleaning vessel of the present invention.
  • Figure 2 shows a method of foam cleaning of the strainer and the drain pipe of the kitchen sink using the foam cleaning drain pipe cleaner and the cleaning vessel of the present invention.
  • 3 and 4 show photographs before (left) and after (right) cleaning of the strainer and drain pipe using the foam cleaning drain pipe cleaner and cleaning container of the present invention.
  • FIG 5 is a view corresponding to one embodiment of the reaction cup of the present invention.
  • FIG. 10 is a graph showing the results of GC / MS analysis on the concentration of chlorine gas after mixing the first agent and the second agent of Example 13 in Experimental Example 4.
  • FIG. 10 is a graph showing the results of GC / MS analysis on the concentration of chlorine gas after mixing the first agent and the second agent of Example 13 in Experimental Example 4.
  • FIG. 11 is a graph showing the results of GC / MS analysis on the concentration of chlorine gas after mixing the first agent and the second agent of Comparative Example 4 in Experimental Example 4.
  • FIG. 11 is a graph showing the results of GC / MS analysis on the concentration of chlorine gas after mixing the first agent and the second agent of Comparative Example 4 in Experimental Example 4.
  • FIG. 12 illustrates an embodiment of a foam cleaning drain pipe cleaning container including a mesh member.
  • the cleaning container was manufactured as a cup-shaped container as in the example of FIG. 5.
  • the foamable mixture of the first agent and the second agent can overflow through the inlet to clean the sieve, and the foamable liquid composition is continuously discharged through the discharge hole opened in the cup. Confirmed.
  • FIG. 3 and 4 show photographs before (left) and after (right) cleaning.
  • the foaming detergent composition and the cleaning container of the present invention are used, the cleaning effect on the strainer and the drain is remarkably excellent. Confirmed.
  • the reaction cup was placed in the sink, 500 ml of the first agent was poured, and 250 ml of the second agent was poured and left for 1.5 hours.
  • 500 ml of the first agent and 250 ml of the second agent were poured simultaneously into the sink and left for 1.5 hours. Thereafter, a sample of about 10 cm from the pipe inlet of the sink drain pipe was taken and measured.
  • Example 1 4.20E + 07 1.20E + 04 99.97 99.95%
  • Example 2 1.40E + 07 1.20E + 05 99.91
  • Example 3 7.20E + 07 1.00E + 04 99.99
  • Example 4 4.90E + 07 2.60E + 04 99.95 Comparative Example 1 5.60E + 07 2.40E + 07 57.14 57.10% Comparative Example 2 5.20E + 07 2.00E + 07 61.54 Comparative Example 3 3.80E + 07 1.80E + 07 52.63
  • FIGS. 8 and 9 show photographs of the comparative example before washing (FIG. 6) and after washing (FIG. 7), and in FIGS. 8 and 9 before washing (FIG. 8) and after washing (FIG. 9) of the example. Showed a photo of. From these results, it was confirmed that the cleaning effect on the drain pipe is remarkably excellent when the foaming detergent composition and the drain pipe cleaning container of the present invention are used.
  • the first agent and the second agent were prepared in the composition ratios of Tables 1 and 2. Thereafter, 500 ml of the first agent and 250 ml of the second agent were poured into a cup-type cleaning container having each discharge port size and number disclosed in Table 5, and the time for discharging all the contents was measured.
  • Discharge port diameter length (mm) Number of outlets Discharge time Microbial killing rate (%)
  • Example 5 0.5 2 7h 30m 99.99%
  • Example 6 0.5 4 4h 10m 99.99%
  • Example 7 One 2 2h40m 99.99%
  • Example 8 3 4 23m 89.51%
  • Example 9 5 2 11m 71.33%
  • Example 10 1.5 4 1h 52m 99.99%
  • Example 11 2.0 2 1h 12m 99.95%
  • Example 12 2.0 4 35m 99.91%
  • the foamed detergent is discharged for about 30 minutes to 2 hours under the conditions of the discharge port consisting of a diameter of 1 ⁇ 2.5 mm and the number of 2 ⁇ 5 (Examples 10 to 12) .
  • the ejection time of the foam composition is more than 30 minutes, it showed a 99.9% or more microbial killing rate, it was found that it is difficult to expect the effect of increasing the sterilization power more than 2 hours.
  • the ingredients of the raw materials were mixed and stirred in the composition ratios shown in Table 6 below to prepare the first and second compositions of the comparative examples and examples of the present invention.
  • compositions of the first and second compositions of Comparative Examples and Examples prepared by varying the NaOH content of the first agent were mixed at a ratio of 1: 1, and the pH and the amount of chlorine gas generated were analyzed by gas chromatography.
  • Example 14 Example 15 1st Purified water To 100 To 100 To 100 To 100 Sodium hypochlorite (12%) 30% 30% 30% 30% 30% SLES (3 mol, 27%) 5% 5% 5% 5% 5% 5% 5% 5% 5% 5% 5% 5% 5% 5% 5% 5% 5% 5% 5% 5% 5% 5% 5% 5% 5% 5% 5% 5% 5% 5% Salicylic acid One % One % One % One % One % % Sodium sulfate 0.5% 0.5% 0.5% 0.5% 0.5% incense 0.1% 0.1% 0.1% 0.1% PH after mixing 6.2 6.8 9.8 12.1 13.5 Chlorine gas concentration 1808 ppm 1250 ppm 15.3 ppm 1.8 ppm 0.5 ppm
  • Example 13 confirms that the concentration of chlorine gas is 15.3 ppm significantly lower generation of chlorine gas than the comparative example could.
  • the chlorine gas concentration of Example 13 is significantly lower than the toxic concentration (LC50) 293 ppm.
  • Example 18 Purified water To 100 To 100 To 100 To 100 To 100 To 100 Sodium hypochlorite (12%) 5% 67% 8% 20% 35% SLES (3 mol, 27%) 5% 5% 5% 5% 5% 5% Lauryl amine oxide One% One% One% One% One% Incense 0.1% 0.1% 0.1% 0.1% 0.1% 0.1%
  • Example 16 Example 17
  • Example 18 Initial bubble 2500 ml 1300ml 2400 ml 2200ml 1900ml Break time 150 minutes 40 minutes 140 minutes 120 minutes 70 minutes
  • Comparative Example 7 in which sodium hypochlorite exceeds the equivalent ratio of 10: 1 (hypochlorite: hydrogen peroxide) has a relatively small amount of bubbles initially generated. In addition, Comparative Example 7 also had a short break time, which was not suitable for the detergent composition to remain in the drainage pipe for a long time to exhibit sufficient cleaning power.
  • Bactericidal power and detergency were evaluated for the solution in which 500 ml of the first agent and 250 ml of the second agent of Comparative Example and Example of Experimental Example 6 were mixed. Five homes were visited and the sink drain pipe was washed for 1.5 hours using the cleaning composition of the first and second agents and the cleaning container of the present invention. Then, the number of microorganisms in the drain was evaluated and the degree of decontamination was checked.
  • Example 18 Sink sieve ⁇ ⁇ ⁇ ⁇ ⁇ drain X ⁇ ⁇ ⁇ ⁇
  • Example 19 Comparative evaluation of cleaning power before and after treatment Comparative Example 8 Comparative Example 9 Example 19
  • Example 20 Example 21
  • Example 22 Example 23
  • Example 24 Cleaning power ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇

Abstract

The present invention relates to a cleaning agent, having an excellent cleaning effect, for foaming and cleaning drain pipes, a cleaning container continuously supplying the cleaning agent to drain pipes, thereby maximizing the cleaning effect, and a method for cleaning drain pipes by using the cleaning agent and the container. A cleaning container for foaming and cleaning drain pipes according to the present invention can effectively clean mesh filters and drain holes in kitchen sinks by causing the foam of a foaming cleaning agent to overflow through the mesh filters and the drain holes, and ensures a continuous cleaning effect on drain pipes by gradually discharging a cleaning agent for foaming and cleaning drain pipes through a small discharge hole. Moreover, a drain pipe cleaning agent composition according to the present invention creates an abundance of foam, thereby having a significantly excellent sterilizing and cleaning effect on drain holes and drain pipes, and is safe to the human body as a result of the generation of chlorine gas inhibited.

Description

배수관 세정 키트 및 이를 이용한 세정 방법Drain pipe cleaning kit and cleaning method using the same
본 발명은 발포 세정용 배수관 세정제, 이를 지속적으로 배수관에 공급할 수 있는 세정 용기 및 이를 이용한 세정 방법에 관한 것으로, 보다 구체적으로 발포 세정용 배수관 세정제를 배수관에 지속적으로 공급하여 세정 효과를 극대화할 수 있는 세정 용기, 세정 키트 및 이를 이용한 세정 방법에 관한 것이다.The present invention relates to a foam cleaning drain pipe cleaner, a cleaning container capable of continuously supplying the same to the drain pipe, and a cleaning method using the same, and more specifically, to continuously supply the foam cleaning drain pipe cleaner to the drain pipe to maximize the cleaning effect. A cleaning container, a cleaning kit and a cleaning method using the same.
본 출원은 2015년 7월 31일에 출원된 한국특허출원 제10-2015-0108579호, 2016년 3월 11일에 출원된 한국특허출원 제10-2016-0029739호, 2016년 3월 2일에 출원된 한국특허출원 제10-2016-0025287호, 2016년 4월 5일에 출원된 한국특허출원 제10-2016-0041660호, 2016년 2월 26일에 출원된 한국특허출원 제10-2016-0023278호, 2016년 7월 8일에 출원된 한국특허출원 제10-2016-0086875호, 2016년 2월 26일에 출원된 한국특허출원 제10-2016-0023334호, 2016년 7월 8일에 출원된 한국특허출원 제10-2016-0086883호, 및 2016년 7월 15일에 출원된 한국특허출원 제10-2016-0089926호에 기초한 우선권을 주장하며, 해당 출원의 명세서 및 도면에 개시된 모든 내용은 본 출원에 원용된다.This application is filed with the Korean Patent Application No. 10-2015-0108579 filed on July 31, 2015, the Korean Patent Application No. 10-2016-0029739 filed March 11, 2016, and March 2, 2016. Korean Patent Application No. 10-2016-0025287, filed April 5, 2016 Korean Patent Application No. 10-2016-0041660, filed February 26, 2016 Korean Patent Application No. 10-2016- 0023278, Korean Patent Application No. 10-2016-0086875, filed July 8, 2016, Korean Patent Application No. 10-2016-0023334, filed February 26, 2016, on July 8, 2016 Claims priority based on Korean Patent Application No. 10-2016-0086883, and Korean Patent Application No. 10-2016-0089926, filed July 15, 2016, all the contents disclosed in the specification and drawings of the application. Is incorporated in this application.
싱크대의 거름망과 배수관은 음식을 조리하거나 버리는 과정에서 음식물이 잔류하며, 물에 항상 젖어 있어 미생물이 자라기 쉬운 환경이므로 쉽게 지저분해지고 심한 냄새를 유발하는 원인이 된다. 거름망이나 배수관을 청결하게 유지하기 위하여 이들을 청소하는 것은 불편하고 시간 및 노동력이 많이 소요된다. 그러나, 거름망이나 배수관을 교체하는 방법 이외에 특별한 대안이 없어 문제가 되고 있다.The strainer and drain pipe of the sink remain in the process of cooking or discarding food, and it is always wet with water, so it is easy to grow microorganisms, causing dirty and bad smell. Cleaning them to keep the strainer or drainpipe clean is inconvenient and time consuming and labor intensive. However, there is a problem because there is no special alternative to replacing the strainer or the drain pipe.
이를 해결하기 위해 미국특허출원 14/529388에는 과산화수소를 아밀라아제 등의 가수분해효소로 발포하여 배관을 세정하는 이액형 시스템이 개시되어 있다. 그러나, 이러한 시스템은 과산화수소의 살균 표백력이 차아염소산나트륨에 비하여 현저히 낮아 살균 표백 효과가 충분히 발휘되지 못하는 단점이 있다.In order to solve this problem, US patent application 14/529388 discloses a two-part system for foaming hydrogen peroxide with a hydrolase such as amylase to clean a pipe. However, such a system has a disadvantage that the sterilizing bleaching power of hydrogen peroxide is significantly lower than that of sodium hypochlorite, so that the sterilizing bleaching effect is not sufficiently exhibited.
또한, 미국공개특허 US2003/0171234 A1에는 점도가 있는 차아염소산나트륨 조성물과 발포제를 동시에 부어 발포시켜 배관을 세정하는 방법이 개시되어 있다. 그러나, 이러한 세정 방법에서 차아염소산나트륨과 발포제는 균일하게 혼합되기 어렵고, 수직으로 설치된 싱크대의 배관에 거품이 장시간 머무르지 않고 금방 배출되어 세정력을 유지하는데 한계가 있다. 또한, 발포 효과를 얻기 위해 차아염소산나트륨 조성물을 산성인 과산화수소와 혼합하는 경우, 인체에 유해한 다량의 염소 가스가 발생되는 문제점이 있다.In addition, US Patent Publication No. US2003 / 0171234 A1 discloses a method of cleaning a pipe by pouring and foaming a sodium hypochlorite composition having a viscosity and a blowing agent at the same time. However, in such a cleaning method, sodium hypochlorite and the blowing agent are difficult to be uniformly mixed, and there is a limit in maintaining the cleaning power by quickly discharging bubbles in the pipe of the sink installed vertically for a long time. In addition, when the sodium hypochlorite composition is mixed with acidic hydrogen peroxide to obtain a foaming effect, there is a problem that a large amount of chlorine gas harmful to the human body is generated.
따라서, 발포 세정제 조성물의 세정 효과의 지속 시간을 늘림으로써, 싱크대 배수관을 보다 효과적으로 세정할 수 있는 도구 또는 방법의 개발이 필요한 실정이다. 또한, 발포 세정제 조성물에서 세정력 향상을 위해 발포 반응을 충분히 일으키도록 구성 성분들의 배합 비율을 조절하는 것과, 염소 가스의 발생을 억제하는 것이 매우 중요하다.Therefore, there is a need to develop a tool or method for more effectively cleaning the sink drain pipe by increasing the duration of the cleaning effect of the foamed detergent composition. In addition, it is very important to adjust the blending ratio of the constituents so as to sufficiently cause the foaming reaction to improve the cleaning power in the foaming detergent composition, and to suppress the generation of chlorine gas.
이에, 본 발명이 해결하고자 하는 과제는 발포 세정용 배수관 세정제를 이용하여 발생된 거품으로 거름망을 세정하고, 상기 세정제를 배수관으로 서서히 흘려보냄으로써 배수관에 대한 세정 효과를 지속적으로 발생시킬 수 있는 세정 용기를 제공하는 것이다.Therefore, the problem to be solved by the present invention is a cleaning container that can continuously generate the cleaning effect on the drain pipe by washing the strainer with foam generated by using the foam pipe for cleaning the drain pipe, and flowing the cleaner to the drain pipe To provide.
또한, 본 발명이 해결하고자 하는 과제는 배수관에 대한 세정 효과가 극대화되고, 염소 가스의 발생이 억제된 배수관 세정제 조성물을 제공하는 것이다.In addition, the problem to be solved by the present invention is to provide a drain pipe cleaning composition in which the cleaning effect on the drain pipe is maximized and the generation of chlorine gas is suppressed.
또한, 본 발명이 해결하고자 하는 과제는 발포 세정용 배수관 세정제 및 발포 세정용 배수관 세정 용기를 포함하는 키트를 제공하는 것이다.In addition, the problem to be solved by the present invention is to provide a kit comprising a foam pipe cleaning drain pipe cleaning agent and foam cleaning pipe cleaning pipe.
또한, 본 발명이 해결하고자 하는 과제는 상기 세정 용기를 이용하여 주방 싱크대 거름망 및 배수관을 동시에 효과적으로 세정하는 방법을 제공하는 것이다.In addition, the problem to be solved by the present invention is to provide a method for effectively cleaning the kitchen sink sieve and drain pipe at the same time using the cleaning container.
본 발명은 상기 과제를 해결하기 위해 발포 세정용 배수관 세정제를 배수관에 서서히 흘려 보낼 수 있는 세정 용기 및 이를 이용하여 주방 싱크대의 거름망 및 배수관을 효과적으로 발포 세정하는 방법을 제공한다.The present invention provides a cleaning container capable of slowly flowing the foaming pipe for cleaning the drain pipe to the drain to solve the above problems, and a method for effectively foam cleaning the strainer and drain pipe of the kitchen sink using the same.
본 발명의 발명자들은 상기 종래기술들의 문제점을 극복하기 위하여 예의 연구 노력한 결과, 발포 세정용 세정제를 거름망, 배수구 및 배수관으로 서서히 흘려 보낼 수 있는 유입부 및 토출구를 포함하는 세정 용기를 개발하였다. 발포 세정용 세정제를 상기 세정 용기와 함께 사용하게 되면 거품이 풍부하게 발생된 세정제가 유입부를 통해 배출되어 거름망 및 배수구를 효과적으로 세정할 수 있고, 발포 세정제를 토출구를 통해 서서히 배출시킴으로써 배수관을 장시간 발포 세정할 수 있어, 주방 싱크대의 거름망, 배수구 및 배수관에 대한 세정 효과가 현저하게 향상되는 놀라운 발견을 하여 본 발명을 완성하게 되었다.The inventors of the present invention, as a result of earnest research efforts to overcome the problems of the prior art, has developed a cleaning container including an inlet and a discharge port that can slowly flow the foam cleaning cleaner to the strainer, drain and drain pipe. When the foam cleaning cleaner is used together with the cleaning container, the foam-rich cleaner is discharged through the inlet to effectively clean the strainer and the drain, and the foam pipe is gradually discharged through the discharge port, thereby foaming the drain pipe for a long time. It is possible to complete the present invention by making a surprising discovery that the cleaning effect on the strainer, drain and drain pipe of the kitchen sink is remarkably improved.
본 발명은 내부에 형성된 수용공간이 구비된 용기 본체; 상기 수용공간에 발포 세정용 배수관 세정제를 유입시키는 유입구; 및 상기 용기 본체에 수용된 상기 수용공간과 배수관이 연통되도록 상기 용기 본체에 형성되며, 상기 수용공간에 수용된 세정제를 상기 배수관으로 토출시키는 적어도 하나의 토출구를 포함하며, 세정제를 배수관에 바로 처리하는 경우에 비해 느린 속도로 토출시키는 발포 세정용 배수관 세정 용기를 제공한다. 상기 세정제를 배수관에 바로 처리하는 경우는 상기 세정 용기를 사용하지 않고 세정제를 배수구 또는 배수관에 직접 처리하는 것을 의미한다. 상기 세정 용기는 배수관과 연결되도록 마련된 배수구에 설치될 수 있다.The present invention provides a container body having a receiving space formed therein; An inlet for introducing a foamed washing drain pipe cleaner into the accommodation space; And at least one discharge port formed in the container body to communicate the receiving space accommodated in the container main body with the drain pipe, and discharging the detergent contained in the receiving space into the drain pipe. Provided is a drain pipe cleaning container for foaming cleaning which is discharged at a slower speed. In the case where the cleaning agent is directly treated on the drain pipe, it means that the cleaning agent is directly disposed on the drain port or the drain pipe without using the cleaning container. The cleaning container may be installed in a drain hole provided to be connected to the drain pipe.
상기 발포 세정용 배수관 세정 용기는 발포성 세정제 조성물로부터 발생된 거품이 유입부를 통해 배수구 및 거름망으로 넘쳐 머무르게 하여 배수구 또는 거름망을 효과적으로 세정할 수 있으며, 작은 토출구를 통해 세정제를 서서히 흘려줌으로써 배수관에 세정 효과를 지속적으로 유지하여 배수관 세정 효과가 현저하게 우수하다. 바람직하게는, 상기 발포 세정용 배수관 세정 용기는 발포된 거품으로 배수구 또는 거름망을 세정함과 동시에, 작은 토출구를 통한 세정제로 배수관을 세정할 수 있다.The foam pipe cleaning vessel for cleaning the foam can effectively wash the drain or the strainer by allowing the bubbles generated from the foaming detergent composition to overflow into the drain and the strainer through the inlet, and by slowly flowing the cleaner through a small discharge port to the cleaning effect to the drainage pipe It maintains continuously, and the drain pipe cleaning effect is remarkably excellent. Preferably, the foam cleaning drain pipe cleaning vessel may clean the drain pipe or the sieve with foamed foam and at the same time, clean the drain pipe with a cleaner through a small discharge port.
일 실시예로, 상기 발포 세정용 배수관 세정 용기는 발포성 세정제로부터 발생된 거품으로 배수구 및 거름망을 세정하고 세정제를 배수관으로 서서히 흘려주기 위하여 토출구를 포함하는 컵 형태일 수 있으며, 도 1에 상기 컵 형태의 발포 세정용 배수관 세정 용기의 일 실시예를 나타내었다.In one embodiment, the foam pipe washing vessel for cleaning the foam may be in the form of a cup including a discharge port for cleaning the drain and the sieve with foam generated from the foaming detergent and flowing the cleaning agent to the drain pipe slowly, Figure 1 the cup form One embodiment of the water pipe cleaning vessel for foaming cleaning is shown.
일 실시예로, 상기 발포 세정용 배수관 세정 용기는 상면에서 하면으로 갈수록 직경이 점진적으로 작아지는 형태의 용기가 사용될 수 있다. 도 5에 상기와 같은 특징을 갖는 발포 세정용 배수관 세정 용기의 도면을 나타내었다. 상기 상면의 직경은 배수구 또는 거름망과 동일하거나 다소 작은 직경일 수 있다. 또한, 상기 상면의 직경은 배수구 또는 거름망에 삽입되어 끼움 결합이 가능하도록 미리 정해진 직경을 가질 수 있다. 또한, 상기 상면은 상단부의 둘레를 따라 배수구에 걸림 가능한 걸림턱을 추가적으로 포함할 수 있다. 상기와 같이 용기의 형태가 상면에서 하면으로 갈수록 직경이 점진적으로 작아짐으로 인해, 용기의 상단은 배수구 또는 거름망에 걸쳐질 수 있으며 하단은 거름망 안쪽으로 들어갈 수 있다.In one embodiment, the foam cleaning drain pipe cleaning vessel may be a container of the type that gradually decreases in diameter from the upper surface to the lower surface. 5 is a view of a foam pipe washing vessel cleaning vessel having the characteristics as described above. The diameter of the upper surface may be the same or somewhat smaller diameter than the drain or the strainer. In addition, the diameter of the upper surface may have a predetermined diameter to be inserted into the drain hole or the strainer to be fitted. In addition, the upper surface may further include a locking step that can be caught in the drain hole along the circumference of the upper end. Since the diameter of the container gradually decreases from the upper surface to the lower surface as described above, the upper end of the container may be spread over the drain or the strainer, and the lower end may enter the strainer.
또한, 상기 발포 세정용 배수관 세정 용기는 유입부를 통해 배출된 세정제가 외면을 타고 흐를 수 있도록 요철홈이 미리 정해진 간격으로 마련된 요철 구조를 포함할 수 있다. 상기와 같은 요철 구조를 통해, 용기가 거름망 또는 배수구에 꽉 끼게 되더라도 배출된 세정제가 요철 구조를 타고 흘러내림으로써 거름망 또는 배수구에 대한 세정 효과를 향상시킬 수 있다.In addition, the foam pipe cleaning vessel may include a concave-convex structure in which the concave-convex grooves are provided at predetermined intervals so that the cleaning agent discharged through the inlet flows on the outer surface. Through the concave-convex structure as described above, even if the container is tightly fitted into the strainer or the drain, the discharged detergent flows down the concave-convex structure to improve the cleaning effect on the strainer or the drain.
상기 발포 세정용 배수관 세정 용기에 있어서, 상기 수용공간에 수용된 세정제는 세정제를 배수관에 바로 처리하는 경우에 비해 느린 속도로 토출될 수 있으며, 상기 속도는 특별히 제한되는 것은 아니나, 수용공간에 수용된 세정제가 10~180분, 바람직하게 20~150분, 더욱 바람직하게 30~120분 동안 토출되는 속도일 수 있다. 이렇게 세정제가 장시간 서서히 토출되도록 토출 속도를 조절함으로써 배수관에 세정 효과를 지속적으로 발생시킬 수 있으며, 이를 통해 단순히 배수구에 세정제를 부어서 배수관을 세정하는 방법에 비해 세정 효과를 현저하게 향상시킬 수 있다.In the foam cleaning drain pipe cleaning container, the cleaning agent contained in the accommodation space may be discharged at a slower speed than when the cleaning agent is directly treated in the drain pipe, and the speed is not particularly limited, but the cleaning agent contained in the accommodation space is The discharge rate may be 10 to 180 minutes, preferably 20 to 150 minutes, more preferably 30 to 120 minutes. Thus, by adjusting the discharge rate so that the cleaning agent is gradually discharged for a long time, the cleaning effect can be continuously generated in the drain pipe, and through this, the cleaning effect can be remarkably improved as compared to the method of simply cleaning the drain pipe by pouring the cleaner into the drain.
본 발명에 있어서, 상기 세정 용기의 토출구는 상기 세정제가 상기 토출구를 통해 1~100 ml/min, 바람직하게는 5~50 ml/min, 더욱 바람직하게는 7~20 ml/min으로 배출되도록 미리 정해진 직경을 가질 수 있다.In the present invention, the discharge port of the cleaning container is predetermined so that the cleaning agent is discharged through the discharge port at 1 to 100 ml / min, preferably 5 to 50 ml / min, more preferably 7 to 20 ml / min It may have a diameter.
상기 배수관 세정 용기에 있어서, 상기 토출구의 미리 정해진 직경은 0.1~10 mm, 바람직하게 0.3~5 mm, 더욱 바람직하게 0.5~3 mm일 수 있다. 상기 토출구의 직경이 0.1 mm 미만인 경우 세정제가 너무 서서히 흘러나와 세정시간이 필요 이상으로 길어지는 문제점이 있으며, 10 mm 초과인 경우 너무 빠르게 흘러나와 본 발명에서 기대되는 세정력 상승효과가 미미할 수 있다.In the drain pipe cleaning container, the predetermined diameter of the discharge port may be 0.1 to 10 mm, preferably 0.3 to 5 mm, more preferably 0.5 to 3 mm. If the diameter of the discharge port is less than 0.1 mm there is a problem that the cleaning agent flows out too slowly and the cleaning time is longer than necessary, if more than 10 mm flows out too quickly, the cleaning force increase effect expected in the present invention may be insignificant.
또한, 본 발명의 바람직한 일 실시예에 따르면, 상기 세정 용기는 세정제가 토출구를 통해 10분 내지 180분, 바람직하게 20분 내지 150분, 더욱 바람직하게 30분 내지 120분 동안 배출되도록 미리 정해진 직경 및 개수의 토출구를 가질 수 있다. 특히, 발포 세정용 세정제가 30분 이내로 배출되는 경우 미생물의 평균 사멸율이 낮고 120분 초과의 경우 살균력 증가 효과가 미미하여 30분 내지 120분 사이로 배출되는 것이 적절하다. In addition, according to a preferred embodiment of the present invention, the cleaning vessel has a predetermined diameter such that the cleaning agent is discharged through the discharge port for 10 minutes to 180 minutes, preferably 20 minutes to 150 minutes, more preferably 30 minutes to 120 minutes and It may have a number of discharge ports. In particular, when the foaming cleaning agent is discharged within 30 minutes, the average killing rate of microorganisms is low, and if more than 120 minutes, it is appropriate to discharge between 30 minutes to 120 minutes because the effect of increasing the sterilization power is insignificant.
상기 배수관 세정 용기에 있어서 있어서, 상기 토출구의 미리 정해진 직경은 0.1~10 mm, 바람직하게 0.3~5 mm, 더욱 바람직하게 0.5~3 mm, 가장 바람직하게 1~2.5 mm일 수 있다. 또한, 상기 토출구의 개수는 1~8개, 바람직하게 1~6개, 더욱 바람직하게 2~5개일 수 있다. 바람직하게, 본 발명의 배수관 세정 용기에 토출구가 1~2.5 mm의 직경으로 2~5개로 형성되어 있는 경우, 토출구를 통해 세정제를 30분 내지 120분 동안 배출시킬 수 있어, 배수관 세정 효과가 가장 우수하게 발휘될 수 있다. 더욱 바람직하게, 본 발명의 세정제는 50분 이상 배수관을 세정하게 되면 세정 효과가 충분하게 발휘되어, 그 이상으로 세정하더라도 효과에 별다른 차이가 없으며 사용 시간만 불필요하게 늘어날 수 있다.In the drain pipe cleaning vessel, the predetermined diameter of the discharge port may be 0.1 to 10 mm, preferably 0.3 to 5 mm, more preferably 0.5 to 3 mm, most preferably 1 to 2.5 mm. In addition, the number of the discharge openings may be 1 to 8, preferably 1 to 6, more preferably 2 to 5. Preferably, when the discharge pipe cleaning container of the present invention is formed with 2 to 5 discharge ports having a diameter of 1 to 2.5 mm, the cleaning agent can be discharged for 30 to 120 minutes through the discharge port, the drain pipe cleaning effect is the best Can be exercised. More preferably, the cleaning agent of the present invention exhibits a sufficient cleaning effect when the drainage pipe is cleaned for 50 minutes or more, and there is no difference in the effect even if the cleaning of the drain pipe is performed for more than 50 minutes.
또한, 본 발명은 내부에 형성된 수용공간이 구비된 용기 본체; 상기 수용공간에 발포 세정용 배수관 세정제를 유입시키는 유입구; 상기 용기 본체에 수용된 상기 수용공간과 배수관이 연통되도록 상기 용기 본체에 형성되며, 상기 수용공간에 수용된 세정제를 상기 배수관으로 토출시키는 적어도 하나의 토출구; 및 상기 발포 세정용 배수관 세정제가 통과되는 메시 부재를 포함하며, 세정제를 배수관에 바로 처리하는 경우에 비해 느린 속도로 토출시키는 발포 세정용 배수관 세정 용기를 제공한다.In addition, the present invention is a container body having a receiving space formed therein; An inlet for introducing a foamed washing drain pipe cleaner into the accommodation space; At least one discharge port formed in the container body such that the accommodation space accommodated in the container body communicates with the drain pipe, and discharge the cleaning agent contained in the accommodation space to the drain pipe; And a mesh member through which the foam cleaning drain pipe cleaner passes, and provides a foam cleaning drain pipe cleaning container for discharging the cleaning agent at a slower speed than when the cleaning agent is directly processed into the drain pipe.
상기 발포 세정용 배수관 세정 용기는 배수관 세정제가 통과되는 메시 부재가 상기 유입구에 형성될 수 있다. 이를 통해 유입구의 메시 부재를 통해 유입된 세정제의 1제 및 2제가 세정 용기 내부에서 고르게 퍼져 내려가고 균일하게 혼합될 수 있다. 또한, 발포된 세정제의 거품이 상기 유입구에 형성된 메시 부재를 통해 외부로 배출됨으로써, 보다 조밀한 거품이 형성되어 세정 효과가 매우 향상될 수 있다.The foam cleaning drain pipe cleaning container may have a mesh member through which the drain pipe cleaner passes, at the inlet. This allows the first and second agents of the cleaning agent introduced through the mesh member of the inlet to be spread evenly inside the cleaning container and mixed uniformly. In addition, the foam of the foamed detergent is discharged to the outside through the mesh member formed in the inlet, the denser foam is formed can be greatly improved cleaning effect.
본 발명에 있어서, 상기 메시 부재의 형태는 그물망인 것이 사용될 수 있다. 또는 간격이 일정한 그물망 형태의 메시 부재 대신 간격이 불균일한 부직포 재질로 이루어진 부재가 사용될 수 있으나, 이에 한정되는 것은 아니다.In the present invention, the mesh member may be a mesh. Alternatively, a member made of a non-woven fabric having a nonuniform spacing may be used instead of a mesh member having a uniform spacing, but is not limited thereto.
바람직하게 상기 메시 부재의 공극 크기(pore size)는 100 내지 10000 마이크론(micron), 바람직하게 300 내지 4000 마이크론, 더욱 바람직하게 400 내지 2000 마이크론, 가장 바람직하게 400 내지 900 마이크론인 것이 사용될 수 있다. 상기 메시 부재가 100 마이크론 미만일 경우에는 세정제 조성물이 잘 통과되지 않아 부적절하며, 10000 마이크론 초과일 경우에는 세정제 혼합물의 균일화 및 배출된 거품의 조밀화 효과가 떨어진다.Preferably the pore size of the mesh member can be used in the range of 100 to 10000 microns, preferably 300 to 4000 microns, more preferably 400 to 2000 microns, and most preferably 400 to 900 microns. If the mesh member is less than 100 microns, the cleaning composition does not pass well and is inappropriate. If the mesh member is more than 10000 microns, the uniformity of the cleaning mixture and the density of the discharged bubbles are inferior.
본 발명에 있어서, 상기 메시 부재는 스테인리스, 화이버 글라스 및 폴리에틸렌(PE) 등으로 이루어진 군에서 선택된 어느 하나 이상의 재질을 포함하는 와이어로 이루어질 수 있다. 또한, 상기 메시 부재는 와이어의 종선 및 횡선이 수직으로 교차된 정방형의 망목을 형성하는 것이 사용될 수 있다. 본 발명의 목적상 상기와 같은 메시 부재를 통해 세정제 조성물이 유입되는 경우, 유입된 세정제의 균일화 효과와 유입구를 통해 배출된 발포 거품의 조밀화 효과가 가장 우수하다.In the present invention, the mesh member may be made of a wire including any one or more materials selected from the group consisting of stainless steel, fiber glass, polyethylene (PE) and the like. In addition, the mesh member may be used to form a square mesh of the vertical cross and vertical lines of the wire. For the purpose of the present invention, when the cleaning composition is introduced through the mesh member as described above, the homogenizing effect of the introduced cleaning agent and the densifying effect of the foam bubbles discharged through the inlet are the best.
일 실시예로, 상기 발포 세정용 배수관 세정 용기는 발포성 세정제로부터 발생된 거품으로 배수구 및 거름망을 세정하고 세정제를 배수관으로 서서히 흘려주기 위하여 토출구를 포함하며, 유입구에 메시 부재가 형성된 컵 형태일 수 있으며, 도 12에 상기 컵 형태의 발포 세정용 배수관 세정 용기의 일 실시예를 나타내었다.In one embodiment, the foam cleaning drain pipe cleaning container includes a discharge port for cleaning the drain and the sieve with foam generated from the foaming detergent and flowing the cleaning agent to the drain pipe slowly, and may be in the form of a cup with a mesh member formed in the inlet 12 shows an embodiment of the cup washing container for foam cleaning in the form of a cup.
본 발명에 있어서, 상기 발포 세정용 배수관 세정 용기의 재질은 HDPE(high density polyethylene), LDPE(low density polyethylene), PET(polyethylene terephthalate), PP(polypropylene), PE(polyethylene), PC(polycarbonate), PS(polystyrene), 또는 ABS(acrylonitrile butadiene styrene) 등의 통상적으로 사용되는 플라스틱 재질, 종이, 유리, 또는 금속 등의 재질이 사용될 수 있다.In the present invention, the material for the foam cleaning drain pipe cleaning container is HDPE (high density polyethylene), LDPE (low density polyethylene), PET (polyethylene terephthalate), PP (polypropylene), PE (polyethylene), PC (polycarbonate), Commonly used plastic materials such as PS (polystyrene) or ABS (acrylonitrile butadiene styrene), paper, glass, or metal may be used.
본 발명에 있어서, 발포 세정용 배수관 세정제 조성물은 거름망, 배수구 또는 배수관을 세정하기 위해 락스를 포함하는 조성물 등과 같이 통상적으로 사용되는 세정용 조성물이면 특별한 제한 없이 모두 사용될 수 있다.In the present invention, any foaming cleaning drain pipe cleaning composition may be used without any particular limitation as long as it is a cleaning composition that is commonly used, such as a composition including lacx for cleaning a strainer, a drain or a drain pipe.
바람직하게, 본 발명은 염소계 세정제 성분, 바람직하게 차아염소산염을 포함하는 1제 조성물 및 발포제, 바람직하게 과산화수소를 포함하는 2제 조성물을 분리하여 포함하는 발포 세정용 배수관 세정제를 제공한다. 보다 구체적으로, 상기 발포 세정용 배수관 세정제는 염소계 세정제 성분을 포함하는 1제 조성물 및 발포제를 포함하는 2제 조성물을 분리하여 포함할 수 있다. 상기 1제 조성물 또는 2제 조성물은 음이온 계면활성제, 비이온 계면활성제, 또는 이들의 혼합물 등을 포함할 수 있다.Preferably, the present invention provides a drainage cleaning agent for foam cleaning comprising separately separating a first composition comprising a chlorine-based cleaning agent component, preferably hypochlorite and a second composition comprising a blowing agent, preferably hydrogen peroxide. More specifically, the foam pipe for cleaning the drainage pipe may be separately contained a one-component composition comprising a chlorine-based cleaner component and a two-component composition comprising a blowing agent. The first agent composition or second agent composition may include anionic surfactants, nonionic surfactants, or mixtures thereof.
본 발명에 있어서, 상기 1제 조성물 및 2제 조성물은 사용시 하기 본 발명의 발포 세정용 배수관 세정 용기의 수용공간에서 혼합하여 사용될 수 있다. 또한, 상기 1제 조성물 및 2제 조성물은 10:1 내지 1:10, 바람직하게 5:1 내지 1:5, 더욱 바람직하게 3:1 내지 1:3(1제 조성물:2제 조성물)의 중량비로 사용될 수 있으며, 이러한 중량비 범위 내에서 발포력 및 세정력이 가장 우수하다.In the present invention, the first agent composition and the second agent composition can be used by mixing in the receiving space of the foam pipe washing vessel cleaning vessel of the present invention in use. Further, the first agent composition and the second agent composition are 10: 1 to 1:10, preferably 5: 1 to 1: 5, more preferably 3: 1 to 1: 3 (one agent composition: second agent composition). It can be used as, the foaming force and the cleaning power is the best within this weight ratio range.
본 발명에 있어서, 염소계 세정제 성분 및 발포제, 바람직하게 차아염소산염 및 과산화수소의 반응은 하기 반응식 1과 같이 산소를 발생시켜 발포를 일으키는 반응이 사용될 수 있다. 이외에도 발포 반응은 다양한 방법으로 발생시킬 수 있으며, 예를 들어 탄산나트륨 또는 탄산수소나트륨 등과 유기산(구연산 또는 젖산 등) 또는 무기산(설파민산 등)의 반응이 있고, 계면활성제 또는 살균제 등을 배합하여 유사한 효과를 얻을 수 있다. 그러나, 본 발명에서는 주성분으로 차아염소산염과 과산화수소를 반응시켜 발포 세정 효과를 발생시킬 수 있으며, 이러한 경우 다른 발포 세정 방법에 비해 효과가 가장 우수하다.In the present invention, the reaction of the chlorine-based detergent component and the blowing agent, preferably hypochlorite and hydrogen peroxide, may be used to generate oxygen by foaming as shown in Scheme 1 below. In addition, the foaming reaction can be generated in various ways. For example, there is a reaction between sodium carbonate or sodium bicarbonate and an organic acid (citric acid or lactic acid) or an inorganic acid (sulfamic acid, etc.) and a similar effect by combining a surfactant or a bactericide. Can be obtained. In the present invention, however, hypochlorite and hydrogen peroxide may be reacted as a main component to generate a foaming cleaning effect. In this case, the effect is the most excellent compared to other foaming cleaning methods.
[반응식 1]Scheme 1
NaOCl + H2O2 NaCl + H2O + 1/2 O2 NaOCl + H 2 O 2 NaCl + H 2 O + 1/2 O 2
본 발명에 있어서, 1제는 주성분으로 염소계 세정제 성분, 바람직하게 차아염소산염을 포함할 수 있으며, 이는 살균 및 표백 효과가 우수하며 희석되면 분해속도가 빨라 잔류성이 적고 경구독성도 낮아 식품 및 식기의 살균 소독에 효과적으로 사용될 수 있다.In the present invention, the first agent may include a chlorine-based detergent component, preferably hypochlorite as a main component, which is excellent in sterilization and bleaching effect, and when diluted, has a fast decomposition rate, low persistence, and low oral toxicity. It can be effectively used for disinfection.
상기 살균 또는 소독의 유효성분으로 사용되는 차아염소산염은 차아염소산나트륨(sodiumhypochlorite ion, NaOCl), 차아염소산칼륨, 차아염소산칼슘 및 차아염소산마그네슘 등으로 이루어진 군에서 선택된 1종 또는 그 이상이 사용될 수 있다. 바람직하게는 차아염소산염으로 차아염소산나트륨이 사용될 수 있다.The hypochlorite used as the active ingredient of the sterilization or disinfection may be used one or more selected from the group consisting of sodium hypochlorite ion (NaOCl), potassium hypochlorite, calcium hypochlorite and magnesium hypochlorite. Preferably sodium hypochlorite can be used as hypochlorite.
상기 염소계 세정제 성분, 바람직하게 차아염소산염은 1제 조성물 총 중량 대비 0.1~30 중량%, 바람직하게는 5~27 중량%, 더욱 바람직하게는 15~25 중량%로 사용될 수 있다. 상기 염소계 세정제 성분을 0.1 중량% 미만으로 사용하면 살균 또는 소독제로서의 기능이 미약하며, 30 중량% 초과로 사용하면 계면활성제와의 상용성이 좋지 않으며, 염소산 이온 자체의 안정성 측면에서도 불리하다.The chlorine cleaner component, preferably hypochlorite may be used in an amount of 0.1 to 30% by weight, preferably 5 to 27% by weight, and more preferably 15 to 25% by weight, based on the total weight of the first composition. When the chlorine-based cleaner component is used in less than 0.1% by weight, the function as a disinfectant or disinfectant is weak, and when used in excess of 30% by weight, the compatibility with the surfactant is not good, and the stability of the chlorate ion itself is disadvantageous.
본 발명에 있어서, 세정제 조성물의 발포 세정 효과를 향상시키기 위해 상기 차아염소산염 및 과산화수소는 1:1 내지 10:1, 바람직하게 1.25:1 내지 9:1, 더욱 바람직하게 2:1 내지 7:1, 가장 바람직하게 3:1 내지 5:1의 당량비(차아염소산염:과산화수소)로 포함될 수 있다. 이러한 당량비 범위를 포함하는 세정제 조성물은 발포력 및 세정력이 가장 우수하다.In the present invention, the hypochlorite and hydrogen peroxide are 1: 1 to 10: 1, preferably 1.25: 1 to 9: 1, more preferably 2: 1 to 7: 1, in order to improve the foam cleaning effect of the cleaning composition. Most preferably, it may be included in the equivalent ratio (hypochlorite: hydrogen peroxide) of 3: 1 to 5: 1. The cleaning composition containing such an equivalent ratio range has the best foaming power and the cleaning power.
또한, 본 발명은 염소계 세정제 성분을 포함하는 1제, 발포제를 포함하는 2제 및 pH 조절제를 포함하는 배수관 세정제 조성물, 바람직하게 배수관 세정용 이액형 발포 세정제 조성물을 제공한다. 바람직하게 상기 염소계 세정제는 차아염소산염 등이 사용될 수 있으며, 상기 발포제는 과산화수소 등이 사용될 수 있다. 상기 염소계 세정제 성분이 발포제와 혼합될 때 pH가 9 이상으로 유지되도록 pH 조절제가 추가적으로 포함되는 경우, 인체에 유해한 염소 가스의 발생이 현저하게 억제된다.The present invention also provides a drain pipe cleaner composition comprising a chlorine-based cleaner component, a two agent comprising a blowing agent, and a pH adjusting agent, preferably a two-component foam cleaner for drain pipe cleaning. Preferably the chlorine-based cleaner may be used hypochlorite, etc., the blowing agent may be used hydrogen peroxide and the like. When the pH adjusting agent is additionally included so that the pH of the chlorine-based cleaner component is mixed with the blowing agent, the generation of chlorine gas harmful to the human body is significantly suppressed.
보다 구체적으로, 본 발명의 배수관 세정제 조성물은 pH 조절제를 포함함으로써 1제의 염소계 세정제 성분, 바람직하게 차아염소산나트륨을 포함하는 조성물의 pH를 12 이상으로 유지할 수 있다. 또한, 본 발명의 2제의 산성의 발포제 조성물을 1제와 혼합한 후에도 혼합물의 pH가 9 이상으로 유지될 수 있어, 염소 가스가 다량으로 생성되지 않기 때문에, 인체에 안전하게 주방 싱크대의 거름망 및 배수관을 발포 세정할 수 있다.More specifically, the drain pipe cleaner composition of the present invention can maintain the pH of the composition containing one chlorine cleaner component, preferably sodium hypochlorite by 12 or more by including a pH adjuster. In addition, even after mixing the acidic blowing agent composition of the second agent of the present invention with the first agent, the pH of the mixture can be maintained at 9 or more, so that a large amount of chlorine gas is not generated, so that the human body is safe for the kitchen sink and drain pipe Can be foamed and washed.
본 발명에 있어서, 차아염소산나트륨이 주성분인 1제와 산성의 과산화수소가 주성분인 2제를 혼합하는 과정에서 유해한 염소 가스가 다량 발생할 수 있으며, 이는 인체에 매우 위험할 수 있으므로 염소 가스 발생이 최소로 될 수 있도록 1제와 2제의 처방은 신중하게 설계되어야 한다. 특히, 1제 및 2제를 혼합 시에도 염소 가스의 발생량을 최소한으로 감소시키는 것이 바람직하다. 차아염소산나트륨은 pH 9 미만의 조건에서는 염소 가스를 다량으로 발생시켜 인체에 매우 위험할 수 있으며, 1제 및 2제를 혼합할 경우에도 염소 가스가 일시에 급격하게 발생할 수 있어, 이를 방지하기 위해 혼합액의 pH를 조절하는 것이 매우 중요하다.In the present invention, a large amount of harmful chlorine gas may be generated in the process of mixing the first agent comprising sodium hypochlorite as the main ingredient and the second agent containing acidic hydrogen peroxide as the main ingredient, which may be very dangerous to the human body, thereby minimizing the generation of chlorine gas. Prescriptions for drugs 1 and 2 should be designed carefully. In particular, it is preferable to reduce the amount of generation of chlorine gas to a minimum even when mixing the first agent and the second agent. Sodium hypochlorite generates a large amount of chlorine gas under the condition below pH 9 can be very dangerous to the human body, chlorine gas may suddenly occur even at the time of mixing the first and second agents, to prevent It is very important to adjust the pH of the mixed solution.
본 발명에 있어서, 1제와 2제를 혼합하는 과정에서 1제에 포함된 차아염소산나트륨의 일부는 과산화수소와 반응하여 염화나트륨, 물 및 산소로 변환될 수 있다. 반응 후 남아 있는 차아염소산나트륨이 급속도로 분해되어 염소 가스가 다량으로 발생하는 것을 억제하기 위해, 1제 및 2제의 혼합물의 pH는 9~14인 것이 바람직하며, 더욱 바람직하게 pH는 11~14인 것이 보다 안전하다.In the present invention, in the process of mixing the first agent and the second agent, part of the sodium hypochlorite contained in the first agent may be converted into sodium chloride, water and oxygen by reacting with hydrogen peroxide. In order to suppress the rapid decomposition of sodium hypochlorite remaining after the reaction to generate a large amount of chlorine gas, the pH of the mixture of the first agent and the second agent is preferably 9-14, more preferably pH 11-14. It is safer to be.
본 발명의 배수관 세정제 조성물은 pH 조절제를 포함함으로써 1제 및 2제를 혼합 시 염소 가스의 발생을 현저하게 억제시킬 수 있다. 상기 배수관 세정제 조성물의 사용 시 발생되는 염소 가스의 양은 300 ppm 미만, 바람직하게 100 ppm 미만, 더욱 바람직하게 50 ppm 미만일 수 있다. 참고적으로, 안전보건공단에서 제공하는 물질안전자료(MSDS) 기준에 따를 때, 염소 가스의 독성 농도(LC50)는 293 ppm이다. 본 발명의 배수관 세정제 조성물은 사용 시 염소 가스의 발생량을 상기 독성 농도(LC50)에 비해 현저하게 억제시킴으로써, 인체에 대한 안전성이 매우 우수하다.The drain pipe cleaning composition of the present invention can suppress the generation of chlorine gas when mixing the first agent and the second agent by including a pH adjuster. The amount of chlorine gas generated in the use of the drain pipe cleaner composition may be less than 300 ppm, preferably less than 100 ppm, more preferably less than 50 ppm. For reference, according to MSDS standards provided by the Safety and Health Agency, the toxic concentration (LC50) of chlorine gas is 293 ppm. The drain pipe cleaning composition of the present invention significantly suppresses the amount of chlorine gas generated when used compared to the toxic concentration (LC50), thereby providing excellent safety for the human body.
본 발명에 있어서, 상기 배수관 세정제 조성물은 1제 및 2제를 혼합한 후 pH가 9 이상으로 유지되어 염소 가스의 발생을 최소로 하기 위하여 pH 조절제를 사용할 수 있다. 상기 pH 조절제로는 수산화나트륨(NaOH), 수산화칼륨(KOH), 규산나트륨(Na3SiO3, Na4SiO4) 및 탄산나트륨(Na2CO3) 등으로 이루어진 군에서 선택된 어느 하나 이상이 사용될 수 있으며, 바람직하게는 수산화나트륨이 사용될 수 있다.In the present invention, the drainage pipe cleaning composition may be a pH adjusting agent to minimize the generation of chlorine gas by maintaining a pH of 9 or more after mixing the first agent and the second agent. As the pH adjusting agent, any one or more selected from the group consisting of sodium hydroxide (NaOH), potassium hydroxide (KOH), sodium silicate (Na 3 SiO 3 , Na 4 SiO 4 ), sodium carbonate (Na 2 CO 3 ), and the like may be used. And preferably sodium hydroxide may be used.
본 발명의 배수관 세정제 조성물은 pH 조절제를 포함함으로써 1제 및 2제의 혼합 시 pH가 9~14로 유지될 수 있다. 바람직하게, 상기 pH 조절제는 상기 1제에 포함될 수 있으며, 이러한 경우 상기 1제는 pH가 12~14로 유지될 수 있다.The drainage pipe cleaning composition of the present invention may be maintained at a pH of 9 to 14 when mixing the first agent and the second agent by including a pH adjuster. Preferably, the pH adjusting agent may be included in the first agent, in which case the first agent may be maintained at a pH of 12 to 14.
본 발명에 있어서, 상기 pH 조절제는 2제에 포함된 산성 물질의 총 수소 이온과 1.1~10:1, 바람직하게 1.1~5:1, 더욱 바람직하게 1.1~3:1의 당량비(pH 조절제: 2제에 포함된 산성 물질의 총 수소 이온 당량)로 포함될 수 있다. 상기 pH 조절제가 1.1:1의 당량비(pH 조절제: 2제에 포함된 산성 물질의 총 수소 이온 당량) 미만으로 포함될 경우에는 혼합 후의 pH가 9 미만이 되어 염소 가스의 발생량이 급격하게 증가할 수 있다. 상기 pH 조절제가 10:1의 당량비(pH 조절제: 2제에 포함된 산성 물질의 총 수소 이온 당량)를 초과하여 포함될 경우에는 염소계 세정제 성분과 발포제의 반응성이 감소할 수 있다.In the present invention, the pH adjusting agent is equivalent to the ratio of the total hydrogen ions of the acidic material contained in the second agent to 1.1 to 10: 1, preferably 1.1 to 5: 1, more preferably 1.1 to 3: 1 (pH regulator: 2 Total hydrogen ion equivalent weight of the acidic material included in the agent). When the pH adjuster is included in an equivalent ratio of 1.1: 1 (pH adjuster: total hydrogen ion equivalents of the acidic substances included in the second agent), the pH after mixing may be less than 9, thereby rapidly increasing the amount of chlorine gas generated. . When the pH adjusting agent is included in an amount of more than 10: 1 equivalent ratio (pH adjusting agent: total hydrogen ion equivalents of the acidic substances included in the second agent), the reactivity of the chlorine-based cleaner component and the blowing agent may decrease.
본 발명에 있어서, 상기 1제 조성물은 차아염소산 이온의 살균 또는 소독력을 증대시키고 세정 효과 및 점도 향상을 위해 음이온 계면활성제, 비이온 계면활성제 또는 이들의 혼합물을 포함할 수 있다. 바람직하게 상기 음이온 계면활성제는 하기 화학식 1의 알킬 에테르 설페이트, 바람직하게 SLES(sodium lauryl ether sulfate)를 포함할 수 있다.In the present invention, the single-agent composition may include anionic surfactants, nonionic surfactants or mixtures thereof to increase the sterilization or disinfection power of hypochlorite ions and to improve the cleaning effect and viscosity. Preferably the anionic surfactant may include an alkyl ether sulfate of Formula 1, preferably SLES (sodium lauryl ether sulfate).
[화학식 1][Formula 1]
R(CH2CH2O)nSO3MR (CH 2 CH 2 O) n SO 3 M
(상기 R은 C10~C16의 알킬기, n은 1~5의 정수, M은 나트륨 또는 칼륨을 나타냄)(Wherein R is an alkyl group of C10 to C16, n is an integer of 1 to 5, M represents sodium or potassium)
바람직하게, 상기 음이온 계면활성제는 상기 화학식 1의 알킬 에테르 설페이트와 하기 화학식 2의 알킬 아민산화물의 혼합물을 포함할 수 있다. 바람직하게 하기 화학식 2의 알킬 아민산화물은 라우라민 옥사이드(lauramine oxide)가 사용될 수 있다.Preferably, the anionic surfactant may include a mixture of the alkyl ether sulfate of Formula 1 and the alkyl amine oxide of Formula 2 below. Preferably, the alkyl amine oxide of Formula 2 may be used lauramine oxide (lauramine oxide).
[화학식 2][Formula 2]
Figure PCTKR2016008407-appb-I000001
Figure PCTKR2016008407-appb-I000001
(상기 R'은 C10~C16의 알킬기를 나타냄)(The R 'represents an alkyl group of C10 ~ C16)
본 발명에 있어서, 음이온 계면활성제로 상기 알킬 에테르 설페이트와 알킬 아민산화물의 혼합물을 사용함으로써, 계면활성제 상호간의 상승효과와 계면활성제 및 차아염소산염과의 상호작용에 의해 각각을 단독으로 사용하는 경우에 비해 우수한 세정력 및 점도를 형성할 수 있다.In the present invention, by using the mixture of the alkyl ether sulfate and alkyl amine oxide as the anionic surfactant, the synergistic effect between the surfactants and the interaction with the surfactant and hypochlorite compared with the case of using each alone Excellent detergency and viscosity can be formed.
바람직하게, 상기 알킬 에테르 설페이트 및 알킬 아민산화물의 중량비는 1:20 내지 20:1, 바람직하게 1:10 내지 10:1, 더욱 바람직하게 1:1 내지 10:1, 가장 바람직하게 3:1 내지 7:1(알킬 에테르 설페이트:알킬 아민산화물)일 수 있다. 상기 알킬 에테르 설페이트 및 알킬 아민산화물이 상기 중량비 범위로 사용될 경우, 본 발명의 1제 조성물의 점도가 가장 우수하게 형성될 수 있다.Preferably, the weight ratio of the alkyl ether sulfate and alkyl amine oxide is 1:20 to 20: 1, preferably 1:10 to 10: 1, more preferably 1: 1 to 10: 1, most preferably 3: 1 to 7: 1 (alkyl ether sulfate: alkyl amineoxide). When the alkyl ether sulfate and alkyl amine oxide are used in the weight ratio range, the viscosity of the first composition of the present invention may be best formed.
본 발명에 있어서, 상기 1제 조성물은 알칼리성을 유지시키면서 계면활성제와 차아염소산 이온과의 상호작용에 의한 점도 형성을 촉진하기 위해 추가적으로 무기알칼리염을 더 포함할 수 있다. 상기 무가알칼리염은 탄산나트륨(Na2CO3), 중탄산나트륨(NaHCO3), 규산나트륨(Na3SiO3, Na4SiO4) 및 수산화나트륨(NaOH) 등으로 이루어진 군에서 선택된 어느 하나 이상이 사용될 수 있으며, 바람직하게는 수산화나트륨이 사용될 수 있다.In the present invention, the one-component composition may further include an inorganic alkali salt in order to promote viscosity formation by the interaction between the surfactant and the hypochlorite ion while maintaining alkalinity. The alkali free salt is at least one selected from the group consisting of sodium carbonate (Na 2 CO 3 ), sodium bicarbonate (NaHCO 3 ), sodium silicate (Na 3 SiO 3 , Na 4 SiO 4 ) and sodium hydroxide (NaOH) and the like. And preferably sodium hydroxide may be used.
상기 무기알칼리염은 1제 조성물 총 중량 대비 0.1~10 중량%, 바람직하게 0.5~7 중량%로 사용될 수 있다. 상기 무기알칼리염이 0.1 중량% 미만으로 사용되는 경우 알칼리성 유지 및 점도 형성 촉진 효과가 미약하며, 10 중량% 초과할 경우에는 차아염소산염과 과산화수소의 반응성이 감소할 수 있다.The inorganic alkali salt may be used in 0.1 to 10% by weight, preferably 0.5 to 7% by weight relative to the total weight of the first composition. When the inorganic alkali salt is used at less than 0.1% by weight, the effect of promoting alkaline retention and viscosity formation is weak, and when it exceeds 10% by weight, the reactivity of hypochlorite and hydrogen peroxide may be reduced.
상기 무기알칼리염의 종류 및 사용량은 1제 조성물의 pH를 10~14로 유지시킬 수 있도록 선택될 수 있는데, 여기서 pH를 10 이상으로 유지시키는 것은 1제 조성물의 화학적 안정성을 극대화하는데 중요한 요소일 뿐만 아니라, 계면활성제의 오염 제거 능력을 향상시키는 요인이다. 또한, 1제 조성물의 pH를 10~14로 유지하는 것은 수용액 상에서 차아염소산염 화합물의 화학적 분해를 최소화하고, 차아염소산염 화합물과 계면활성제 간의 화학적 상호작용을 최소화 하는데 도움을 준다.The type and amount of the inorganic alkali salt may be selected to maintain the pH of the formulation of 1 to 10, wherein maintaining the pH above 10 is not only an important factor in maximizing the chemical stability of the formulation This is a factor to improve the decontamination ability of the surfactant. In addition, maintaining the pH of the first composition at 10-14 helps to minimize chemical degradation of the hypochlorite compound in aqueous solution and to minimize chemical interaction between the hypochlorite compound and the surfactant.
본 발명에 있어서, 발포 세정용 배수관 세정제의 사용 시, 차아염소산 이온의 강한 냄새를 줄이고 심미적인 요구를 만족시키기 위하여 추가적으로 향료를 더 포함할 수 있다. 상기 향료는 차아염소산 이온에 안정한 것이 사용될 수 있으며, 1제 조성물 총 중량 대비 0.01~2 중량%로 사용될 수 있다.In the present invention, in the use of the foam pipe for cleaning the drainage pipe, it may further include a fragrance in order to reduce the strong odor of hypochlorite ions and satisfy the aesthetic requirements. The fragrance may be used that is stable to hypochlorite ions, it may be used in 0.01 to 2% by weight relative to the total weight of the first composition.
또한 상기 언급한 바와 같이 본 발명에 따른 1제 조성물의 pH는 10~14로 유지되는 것이 바람직하므로, 제조된 1제 조성물의 pH가 이 범위 내에 있지 않을 경우 추가로 pH 조절제를 사용함으로써 pH 10~14로 조절할 수 있다. 상기 pH 조절제로는 구연산, 수산화나트륨, 수산화칼슘, 또는 트리에탄올아민 등이 사용될 수 있다.In addition, as mentioned above, since the pH of the single-agent composition according to the present invention is preferably maintained at 10 to 14, when the pH of the prepared single-agent composition is not within this range, additionally, a pH adjusting agent may be used. 14 can be adjusted. Citric acid, sodium hydroxide, calcium hydroxide, or triethanolamine may be used as the pH adjusting agent.
본 발명에 있어서, 상기 발포 세정용 배수관 세정제는 거품을 발생시키기 위한 목적으로 산소계 발포성 조성물인 2제 조성물을 사용하며, 1제 조성물의 차아염소산염과 반응하여 산소를 발생시키는 과산화수소를 2제 조성물의 주성분으로 포함할 수 있다. 또한, 상기 2제 조성물은 100 cps 이상의 점도를 유지하면서 세정 효과를 향상시키기 위해, 음이온 계면활성제, 비이온 계면활성제, 또는 이들의 혼합물을 포함할 수 있으며, 과산화수소를 안정하게 유통시키기 위해 라디칼 안정화제를 포함할 수 있다.In the present invention, the foam pipe for cleaning the drain pipe uses a two-component composition, which is an oxygen-based foamable composition, for the purpose of generating bubbles, and hydrogen peroxide that reacts with hypochlorite of the one-component composition to generate oxygen. It can be included as. In addition, the two-component composition may include anionic surfactants, nonionic surfactants, or mixtures thereof to improve the cleaning effect while maintaining a viscosity of 100 cps or more, and a radical stabilizer to stably distribute hydrogen peroxide. It may include.
상기 과산화수소는 2제 조성물 총 중량 대비 0.1~30 중량%, 바람직하게 5~27 중량%, 더욱 바람직하게 15~25 중량%로 포함될 수 있다. 상기 과산화수소가 0.1 중량% 미만일 경우에는 발포 효과 및 이에 의한 세정 효과의 상승이 미미하며, 30 중량%를 초과할 경우에는 2제 조성물의 안정성이 저하되어 유통이 어려운 단점이 있다.The hydrogen peroxide may be included in 0.1 to 30% by weight, preferably 5 to 27% by weight, more preferably 15 to 25% by weight relative to the total weight of the second composition. When the hydrogen peroxide is less than 0.1% by weight, the foaming effect and the increase in the cleaning effect thereof are insignificant. When the hydrogen peroxide is more than 30% by weight, the stability of the second agent composition is lowered, making it difficult to distribute.
본 발명에 있어서, 상기 2제 조성물은 주성분인 과산화수소를 안정화시키는 것이 매우 중요하며, 이를 위해 2제 조성물은 추가적으로 라디칼 안정화제를 더 포함할 수 있다. 상기 라디칼 안정화제는 하기 화학식 3으로 표시되는 살리실산 등이 사용될 수 있으나, 이에 한정되는 것은 아니다.In the present invention, it is very important that the second composition stabilizes hydrogen peroxide, which is a main component, and for this purpose, the second composition may further include a radical stabilizer. The radical stabilizer may be used salicylic acid represented by the following formula (3), but is not limited thereto.
[화학식 3][Formula 3]
Figure PCTKR2016008407-appb-I000002
Figure PCTKR2016008407-appb-I000002
상기 라디칼 안정화제는 2제 조성물 총 중량 대비 0.01~15 중량%, 바람직하게 0.1~5 중량%, 더욱 바람직하게 0.5~3 중량%로 포함될 수 있다. 상기 라디칼 안정화제가 0.01 중량% 미만일 경우에는 과산화수소 안정화 효과가 충분하지 않으며, 15 중량% 초과일 경우에는 2제 조성물의 안정성을 저하시키는 문제점이 있다.The radical stabilizer may be included in 0.01 to 15% by weight, preferably 0.1 to 5% by weight, more preferably 0.5 to 3% by weight relative to the total weight of the second composition. When the radical stabilizer is less than 0.01% by weight, the hydrogen peroxide stabilization effect is not sufficient, and when the radical stabilizer is more than 15% by weight, there is a problem of lowering the stability of the second composition.
본 발명에 있어서, 상기 2제 조성물은 상기 언급한 구성성분 외에도 세정제 조성물에 통상적으로 사용되는 탄산나트륨, 황산나트륨 등의 무기염, 고분자, 또는 향료 등을 추가로 포함할 수 있다.In the present invention, the two-component composition may further include inorganic salts such as sodium carbonate and sodium sulfate, polymers, or fragrances, which are commonly used in detergent compositions, in addition to the aforementioned components.
본 발명에 있어서, 차아염소산 이온의 살균 또는 소독력을 증대시키고 세정 효과 및 점도 향상을 위해, 상기 1제 조성물 및 2제 조성물은 각각 음이온 계면활성제, 비이온 계면활성제, 또는 이들의 혼합물을 포함할 수 있다.In the present invention, in order to increase the sterilizing or disinfecting power of hypochlorite ions and to improve the cleaning effect and viscosity, the first composition and the second composition may each include an anionic surfactant, a nonionic surfactant, or a mixture thereof. have.
상기 음이온 계면활성제는 1제 조성물 또는 2제 조성물 각각의 총 중량 대비 0.1~10 중량%, 바람직하게 0.5~7 중량%로 포함될 수 있다. 상기 비이온 계면활성제는 1제 조성물 또는 2제 조성물 각각의 총 중량 대비 0.1~10 중량%, 바람직하게 0.5~7 중량%로 포함될 수 있다. 상기 음이온 계면활성제 또는 비이온 계면활성제가 0.1 중량% 미만일 경우에는 세정력이 충분히 발휘되지 않으며 1제 또는 2제 조성물의 점도 형성이 곤란하고, 10 중량% 초과일 경우에는 차아염소산 이온 또는 과산화수소의 안정성을 저해시킬 수 있다.The anionic surfactant may be included in 0.1 to 10% by weight, preferably 0.5 to 7% by weight relative to the total weight of each of the first agent composition or second agent composition. The nonionic surfactant may be included in an amount of 0.1 to 10% by weight, preferably 0.5 to 7% by weight, based on the total weight of each of the first agent composition or the second agent composition. When the anionic surfactant or the nonionic surfactant is less than 0.1% by weight, the cleaning power is not sufficiently exhibited, and it is difficult to form the viscosity of the one or two-component composition, and when it is more than 10% by weight, the stability of hypochlorite ions or hydrogen peroxide is improved. Can be inhibited.
바람직하게 상기 1제 조성물 및 2제 조성물은 음이온 계면활성제 및 비이온 계면활성제의 혼합물을 각각 포함할 수 있다. 더욱 바람직하게, 상기 혼합물에서 음이온 계면활성제 및 비이온 계면활성제의 중량비는 1:10 내지 10:1, 바람직하게 1:5 내지 5:1, 더욱 바람직하게 1:3 내지 3:1(음이온 계면활성제:비이온 계면활성제)일 수 있고, 이러한 중량비 범위 내에서 점도 형성 및 세정력 향상 효과가 가장 우수하다.Preferably, the first agent composition and the second agent composition may each include a mixture of anionic surfactant and nonionic surfactant. More preferably, the weight ratio of the anionic surfactant and nonionic surfactant in the mixture is 1:10 to 10: 1, preferably 1: 5 to 5: 1, more preferably 1: 3 to 3: 1 (anionic surfactant : Nonionic surfactant), and the effect of improving viscosity and cleaning power is most excellent within this weight ratio range.
본 발명에 있어서, 상기 음이온 계면활성제, 비이온 계면활성제, 또는 이들의 혼합물은 세정제 총 중량 대비 1~40 중량%, 바람직하게 3~30 중량%, 더욱 바람직하게 5~20 중량%로 포함될 수 있다. 상기 계면활성제의 함량이 1 중량% 미만일 경우에는 세제 성능이 미미하며, 40 중량%를 초과할 경우에는 세정제의 용해성이 저하되는 문제점이 있다.In the present invention, the anionic surfactant, nonionic surfactant, or a mixture thereof may be included in an amount of 1 to 40% by weight, preferably 3 to 30% by weight, and more preferably 5 to 20% by weight, based on the total weight of the detergent. . When the content of the surfactant is less than 1% by weight, the detergent performance is insignificant, and when the content of the surfactant is more than 40% by weight, the solubility of the detergent is reduced.
상기 음이온 계면활성제는 예를 들어, 직쇄형알킬벤젠술폰산염(R1-CH2-SO3Na, 여기에서 R1 은 C9∼C15의 알킬), 지방산염(R2-CH2 -COONa, 여기에서 R2 는 C11∼C16의 알킬), 알칼술폰산염(R3=CH-SO3Na, 여기에서 R3 는 C11∼C18의 알킬), 및 알파올레핀술폰산염(R4-CH=CH-CH2SO3 Na, 여기에서 R4는 C12∼C18의 알킬) 등으로 이루어진 군에서 선택된 어느 하나 이상이 포함될 수 있으나, 이에 한정되는 것은 아니다.The anionic surfactants include, for example, straight-chain alkylbenzene sulfonate (R1-CH 2 -SO 3 Na , where R1 is a C9~C15 alkyl), fatty acid salts (R2-CH 2 -COONa, where R2 is C11-C16 alkyl), alkalsulfonate (R3 = CH-SO 3 Na, wherein R3 is C11-C18 alkyl), and alphaolefinsulfonate (R4-CH = CH-CH 2 SO 3 Na, wherein R4 may include any one or more selected from the group consisting of C12 to C18 alkyl), but is not limited thereto.
상기 비이온 계면활성제는 예를 들어, 지방알콕폴리옥시에틸렌글리콜(R5-CH-(O-CH2-CH2)l-OH, 여기에서 R5 는 C11∼C18의 알킬, l 은 5~25의 정수), 지방산폴리옥시에틸렌글리콜(R6-CO-(O-CH2-CH2)m-OH, 여기에서 R6 는 C11∼C18의 알킬, m은 5~25의 정수), 알킬페닐폴리옥시에틸렌글리콜(R7-Ar-O-(CH20CH2-O)n-H, 여기에서 R7 은 C11∼C18의 알킬, Ar은 벤젠 고리, n은 5~25의 정수), 또는 폴리옥시에틸렌글리콜(H-(O-CH2-CH2)i-OH, 여기에서 i는 전체 분자량이 1,000∼30,000인 정수) 등으로 이루어진 군에서 선택된 어느 하나 이상이 포함될 수 있으나, 이에 한정되는 것은 아니다.The nonionic surfactant is, for example, fatty alkoxypolyoxyethylene glycol (R5-CH- (O-CH 2 -CH 2 ) 1 -OH, wherein R5 is C11-C18 alkyl, l is 5-25 Integer), fatty acid polyoxyethylene glycol (R6-CO- (O-CH 2 -CH 2 ) m-OH, where R6 is C11-C18 alkyl, m is an integer of 5-25), alkylphenylpolyoxyethylene Glycol (R7-Ar-O- (CH 2 0CH 2 -O) nH, wherein R7 is C11-C18 alkyl, Ar is a benzene ring, n is an integer of 5-25), or polyoxyethylene glycol (H- (O-CH 2 -CH 2 ) i-OH, where i is an integer having a total molecular weight of 1,000 to 30,000) and the like may include any one or more selected from, but is not limited thereto.
본 발명은 본 발명의 목적을 해치지 않는 범위에서 임의의 성분들을 더 포함할 수 있으며, 세정제 조성물로서의 기본적인 물성 및 품질을 유지하기 위해 세정제 조성물에 유용하게 통상 사용되는 방부제, 점증제 및 점도 조정제, 향료, 또는 염료 등을 더 포함할 수 있다. The present invention may further include any ingredients within the scope of not impairing the object of the present invention, preservatives, thickeners and viscosity modifiers, fragrances commonly used in detergent compositions to maintain basic physical properties and quality as a detergent composition. Or a dye may be further included.
예를 들어, 방부제는 파라옥시안식향산메틸, 메틸클로로이소티아졸리논 및 메틸이소티아졸리논의 혼합물(상품명: Kathon CG, 제조회사: 미국 롬앤하스사) 등이 사용될 수 있다. 점증제 및 점도 조정제로는 하이드록시프로필메틸셀룰로오스, 하이드록시메틸셀룰로오스, 염화나트륨, 염화암모늄, 프로필렌글리콜, 또는 헥실렌글리콜 등이 사용될 수 있다. 염료로는 수용성 타르색소 등이 사용될 수 있다.For example, a preservative may be a mixture of methyl paraoxybenzoate, methylchloroisothiazolinone and methylisothiazolinone (trade name: Kathon CG, manufactured by Rohm & Haas, USA). As the thickener and the viscosity modifier, hydroxypropyl methyl cellulose, hydroxymethyl cellulose, sodium chloride, ammonium chloride, propylene glycol, hexylene glycol and the like can be used. As the dye, a water-soluble tar dye may be used.
본 발명에 있어서, 상기 발포 세정용 배수관 세정제는 방출 속도를 느리게 하기 위해 점증제를 추가적으로 포함할 수 있다. 상기 점증제가 포함된 세정제 조성물의 점도는 100~10,000 cps일 수 있다. 상기 점증제는 예를 들어, 잔탄검, 로커스트빈검, 카라기난, 펙틴 및 젤라틴 등으로 이루어진 군에서 선택된 1종 이상이 사용될 수 있으나, 이에 한정되는 것은 아니다.In the present invention, the foam cleaning drain pipe cleaner may further include a thickener to slow the release rate. The viscosity of the detergent composition containing the thickener may be 100 ~ 10,000 cps. The thickener may be, for example, one or more selected from the group consisting of xanthan gum, locust bean gum, carrageenan, pectin, gelatin, and the like, but is not limited thereto.
또한, 본 발명은 1제 조성물 총 중량 대비 차아염소산염 0.1~30 중량%, 음이온 계면활성제 0.1~10 중량%, 비이온 계면활성제 0.1~10 중량%, 및 무기알칼리염 0.05~10 중량%를 포함하는 1제 조성물; 및 2제 조성물 총 중량 대비 과산화수소 0.1~30 중량%, 음이온 계면활성제 0.1~10 중량%, 비이온 계면활성제 0.1~10 중량%, 및 라디칼 안정화제 0.05~10 중량%를 포함하는 2제 조성물을 분리하여 포함하는 발포 세정용 배수관 세정제를 제공한다. 상기 발포 세정용 배수관 세정제는 주방 싱크대의 거름망 및 배수관에 대한 살균 및 소독력이 매우 우수하며 100 cps 이상의 우수한 점도를 가진다.In addition, the present invention comprises 0.1 to 30% by weight of hypochlorite, 0.1 to 10% by weight of anionic surfactant, 0.1 to 10% by weight of nonionic surfactant, and 0.05 to 10% by weight of inorganic alkali salts relative to the total weight of the first composition Agent composition; And separating the two-component composition comprising 0.1-30 wt% of hydrogen peroxide, 0.1-10 wt% of anionic surfactant, 0.1-10 wt% of nonionic surfactant, and 0.05-10 wt% of radical stabilizer, based on the total weight of the second composition. It provides a drainage pipe cleaning agent for foam cleaning. The foam pipe drainage cleaning agent is very good sterilization and disinfection of the strainer and drain pipe of the kitchen sink and has an excellent viscosity of more than 100 cps.
또한, 상기 발포 세정용 배수관 세정제는 1제에 pH 조절제를 상기 2제에 포함된 산성 물질의 총 수소 이온과 1.1~10:1의 당량비(pH 조절제: 2제에 포함된 산성 물질의 총 수소 이온 당량)로 포함할 수 있다. 또는 상기 발포 세정용 배수관 세정제는 1제에 pH 조절제를 1제 조성물 총 중량 대비 0.3~10 중량%로 포함할 수 있다. 이러한 경우, 발포 세정용 배수관 세정제의 사용 시 염소 가스의 발생이 현저하게 억제되어 인체에 안전하다.In addition, the foam cleaning drain pipe cleaner has a pH adjusting agent in one agent and a total ratio of hydrogen ions of the acidic substance contained in the second agent and an equivalent ratio of 1.1 to 10: 1 (pH regulator: total hydrogen ions of the acidic substance contained in the second agent). Equivalent weight). Alternatively, the foam pipe cleaning agent may include 0.3 to 10 wt% of the pH adjusting agent in one agent, based on the total weight of the one agent composition. In such a case, generation of chlorine gas is remarkably suppressed in the use of the foam cleaning drain pipe cleaner, which is safe for the human body.
또한, 상기 발포 세정용 배수관 세정제는 상기 차아염소산염 및 과산화수소를 1:1 내지 10:1의 당량비(차아염소산염:과산화수소)로 포함할 수 있다. 이러한 경우, 상기 발포 세정용 배수관 세정제 조성물은 거품 발생량이 현저하게 향상되며, 거름망, 배수구 및 배수관에 대한 살균 및 소독력이 매우 우수하다.In addition, the foam pipe cleaning pipe cleaner may include the hypochlorite and hydrogen peroxide in an equivalent ratio (hypochlorite: hydrogen peroxide) of 1: 1 to 10: 1. In this case, the foaming pipe cleaning composition for foam cleaning is significantly improved foaming amount, and excellent sterilization and disinfection of the strainer, drain and drain pipe.
또한, 본 발명은 상기 발포 세정용 배수관 세정 용기 및 상기 발포 세정용 배수관 세정제를 포함하는 발포 세정용 배수관 세정 키트를 제공한다. 상기 키트는 일반 사용자들이 주방 싱크대의 거름망, 배수구 및 배수관을 용이하고 효과적으로 세정하는데 사용될 수 있다.The present invention also provides a foam cleaning drain pipe cleaning kit comprising the foam cleaning drain pipe cleaning container and the foam cleaning drain pipe cleaning agent. The kit can be used by ordinary users to easily and effectively clean the strainer, drains and drains of the kitchen sink.
바람직하게, 본 발명은 차아염소산염을 포함하는 1제 및 과산화수소를 포함하는 2제를 포함하는 발포 세정용 배수관 세정제; 및 내부에 형성된 수용공간이 구비된 용기 본체 및 상기 수용공간에 발포 세정용 배수관 세정제를 유입시키는 유입구를 포함하는 발포 세정용 배수관 세정 용기를 포함하며, 상기 수용공간의 부피는 상기 발포 세정용 배수관 세정제의 총 부피보다 작은 것을 특징으로 하는 발포 세정용 배수관 세정 키트를 제공한다.Preferably, the present invention is a drainage pipe cleaner for foam cleaning comprising a first agent containing hypochlorite and a second agent containing hydrogen peroxide; And a container main body having an accommodating space formed therein, and an inlet for introducing a foaming washing drain pipe cleaner into the accommodating space, wherein the volume of the accommodating space is the foaming washing drain pipe cleaner. It provides a foam pipe cleaning kit for cleaning the foam, characterized in that less than the total volume of.
상기 세정 키트는 이에 포함된 세정 용기를 세정제와 함께 사용할 때, 세정 용기의 수용공간이 세정제의 총 부피보다 작기 때문에, 거품이 풍부하게 발생된 세정제가 유입부를 통해 넘쳐 흘러 거름망 및 배수구를 효과적으로 세정할 수 있다.When the cleaning kit includes the cleaning container included with the cleaning agent, since the receiving space of the cleaning container is smaller than the total volume of the cleaning agent, the foam-rich cleaning agent overflows through the inlet to effectively clean the screen and the drain. Can be.
보다 구체적으로, 상기 수용공간의 부피는 발포된 상태의 배수관 세정제의 1제 및 2제의 혼합물 및 이로부터 발생하는 기포의 부피보다 작을 수 있다. 이를 통해, 발포 세정용 배수관 세정제의 1제 및 2제의 혼합물 또는 이의 기포가 상기 수용공간의 유입구를 통해 넘쳐 흐를 수 있어, 거름망 및 배수구에 대한 세정력이 매우 우수하다. 상기 수용공간의 부피가 1제와 2제의 혼합물 및 기포 부피의 합보다 큰 경우에는 유입구를 통해 세정제가 넘치지 않기 때문에 세정 용기 상부에 위치한 거름망에 대해서 세정 효과가 충분히 발휘되지 않는다.More specifically, the volume of the receiving space may be smaller than the volume of the mixture of the first agent and the second agent in the foamed state and the bubbles generated therefrom. Through this, the mixture of the first agent and the second agent of the foam cleaning drain pipe cleaner or bubbles thereof can overflow through the inlet of the receiving space, so that the cleaning power for the strainer and the drain is very excellent. If the volume of the accommodation space is larger than the sum of the mixture of the first agent and the second agent and the bubble volume, the cleaning effect is not sufficiently exerted on the strainer located above the cleaning container because the cleaning agent does not overflow through the inlet.
본 발명에 있어서, 상기 수용공간의 부피 및 상기 발포된 세정제의 부피는 1:1.01~5, 바람직하게 1:1.05~3, 더욱 바람직하게 1:1.1~2(수용공간의 부피:발포된 세정제의 부피)의 부피비일 수 있다. 상기 수용공간의 부피 대비 발포된 세정제의 부피가 1:1.01(수용공간의 부피:발포된 세정제의 부피) 미만일 경우에는, 발포된 세정제가 용기를 흘러 넘치지 않거나 소량으로 흘러 넘치므로, 세정 효과가 미약할 수 있다. 상기 수용공간의 부피 대비 발포된 세정제의 부피가 1:5(수용공간의 부피:발포된 세정제의 부피)를 초과하는 경우에는, 발포된 세정제가 배수구 주변의 싱크대 바닥까지 과도하게 흘러 넘치는 문제점이 있다.In the present invention, the volume of the receiving space and the volume of the foamed detergent is 1: 1.01-5, preferably 1: 1.05-3, more preferably 1: 1.1-2 (volume of the storage space: of the foamed detergent Volume). If the volume of the foamed detergent to the volume of the containing space is less than 1: 1.01 (volume of the receiving space: volume of the foamed detergent), the foamed detergent does not overflow the container or flows in a small amount, the cleaning effect is weak can do. If the volume of the foamed detergent to the volume of the containing space exceeds 1: 5 (volume of the receiving space: volume of the foamed detergent), there is a problem that the foamed detergent flows excessively to the bottom of the sink around the drain. .
또한, 본 발명은 상기 발포 세정용 배수관 세정 용기를 사용하여 주방 싱크대의 거름망 및 배수관을 발포 세정하는 방법을 제공한다. 상기 발포 세정용 배수관 세정제 및 세정 용기를 사용하는 본 발명의 세정 방법을 도 2에 나타내었다.In addition, the present invention provides a method for foam cleaning of the strainer and the drain pipe of the kitchen sink using the foam pipe for cleaning the drain pipe. 2 shows a cleaning method of the present invention using the above-mentioned foamed cleaning drain pipe cleaner and a cleaning container.
상기 세정 방법은 (s1) 상기 발포 세정용 배수관 세정 용기를 배수구에 설치하는 단계; 및 (s2) 상기 세정제의 1제 조성물 및 2제 조성물을 상기 세정 용기의 수용공간에 동시에 또는 순차적으로 붓는 단계를 포함할 수 있다. 상기 (s2) 단계에서 1제 조성물 및 2제 조성물을 순차적으로 붓는 경우, 붓는 순서는 무관하다.The cleaning method includes the steps of: (s1) installing the foam cleaning drain pipe cleaning container in a drain; And (s2) simultaneously or sequentially pouring the first composition and the second composition of the cleaning agent into the accommodation space of the cleaning container. In the case of pouring the one-component composition and the two-component composition in the step (s2) sequentially, the pouring order is irrelevant.
상기 주방 싱크대의 거름망 및 배수관을 발포 세정하는 방법은 상기 (s2) 단계 이후 1제 조성물 및 2제 조성물의 혼합으로 발포가 일어나고 상기 세정 용기의 유입구로부터 넘친 거품은 거름망을 세정하며, 액체상의 발포 세정제는 토출구를 통해 서서히 흘러나와 배수관에 지속적인 세정 효과를 발휘하여, 본 발명의 세정 방법은 거름망 및 배수관을 동시에 효과적으로 세정할 수 있다.The method of foam cleaning the sieve and drain pipe of the kitchen sink is foamed by the mixing of the first agent composition and second agent composition after the step (s2) and the foam overflowed from the inlet of the cleaning vessel to wash the sieve, liquid foaming detergent Is gradually flowed through the discharge port to exert a continuous cleaning effect on the drain pipe, the cleaning method of the present invention can effectively clean the strainer and the drain pipe at the same time.
본 발명의 발포 세정용 배수관 세정 용기는 발포성 세정제의 거품을 주방 싱크대의 거름망 및 배수구로 흘러 넘치게 하여 이들을 효과적으로 세정할 수 있으며, 발포 세정용 배수관 세정제를 배수관으로 서서히 흘려보내 배수관에 지속적인 세정 효과를 발휘한다.The foam cleaning drain pipe cleaning container of the present invention can effectively wash the foam of the foaming detergent by flowing into the strainer and the drain of the kitchen sink, and slowly flows the foaming cleaning drain pipe cleaner into the drain pipe to exert a continuous cleaning effect on the drain pipe. do.
또한, 본 발명의 배수관 세정제 조성물은 염소계 세정제 성분 및 발포제를 특정한 중량비로 포함할 때 거품이 풍부하게 발생하여, 싱크대의 거름망, 배수구 및 배수관에 대한 살균 및 세정 효과가 현저하게 우수하다.In addition, the drain pipe cleaner composition of the present invention generates abundant bubbles when the chlorine-based cleaner component and the blowing agent are included in a specific weight ratio, so that the disinfection and cleaning effects on the strainer, drain and drain pipe of the sink are remarkably excellent.
또한, 본 발명의 배수관 세정제 조성물은 추가적으로 pH 조절제를 포함할 때, 1제 및 2제를 혼합 시 pH를 9 이상으로 유지하여 염소계 세정제 성분 및 발포제의 반응으로 인한 염소 가스의 발생을 현저하게 억제함으로써, 안전하고 우수한 세정 효과를 발휘할 수 있다.In addition, when the drain pipe cleaner composition of the present invention additionally includes a pH adjusting agent, the pH of the first agent and the second agent is maintained at 9 or higher when mixing, thereby significantly suppressing the generation of chlorine gas due to the reaction of the chlorine-based detergent component and the blowing agent. Safe and excellent cleaning effect can be achieved.
또한, 본 발명의 발포 세정용 배수관 세정 키트는 발포성 세정제의 거품을 세정 용기에서 흘러 넘치게 하여, 주방 싱크대의 거름망 및 배수구를 효과적으로 세정할 수 있다.In addition, the foam cleaning drain pipe cleaning kit of the present invention can be caused to overflow the foam of the foaming detergent in the cleaning container, it is possible to effectively clean the strainer and drain holes of the kitchen sink.
도 1은 본 발명의 발포 세정용 배수관 세정 용기의 일 실시예를 나타낸다.Figure 1 shows an embodiment of the foam pipe washing vessel cleaning vessel of the present invention.
도 2는 본 발명의 발포 세정용 배수관 세정제 및 세정 용기를 사용하여 주방 싱크대의 거름망 및 배수관을 발포 세정하는 방법을 나타낸다.Figure 2 shows a method of foam cleaning of the strainer and the drain pipe of the kitchen sink using the foam cleaning drain pipe cleaner and the cleaning vessel of the present invention.
도 3 및 도 4는 본 발명의 발포 세정용 배수관 세정제 및 세정 용기를 사용하여 거름망 및 배수관의 세정 전(왼쪽) 및 세정 후(오른쪽)의 사진을 나타낸다.3 and 4 show photographs before (left) and after (right) cleaning of the strainer and drain pipe using the foam cleaning drain pipe cleaner and cleaning container of the present invention.
도 5는 본 발명의 반응컵의 일 실시예에 해당하는 도면이다.5 is a view corresponding to one embodiment of the reaction cup of the present invention.
도 6 및 도 7은 실험예 2에서 배수관에 비교예의 처리 전, 후를 비교한 사진이다.6 and 7 are photographs comparing the before and after treatment of the comparative example to the drain pipe in Experimental Example 2.
도 8 및 도 9는 실험예 2에서 배수관에 실시예의 처리 전, 후를 비교한 사진이다.8 and 9 are photographs comparing the before and after treatment of the embodiment in the drain pipe in Experimental Example 2.
도 10은 실험예 4에서 실시예 13의 1제 및 2제의 혼합 후 염소 가스 농도에 대한 GC/MS 분석 결과를 나타낸 그래프이다.FIG. 10 is a graph showing the results of GC / MS analysis on the concentration of chlorine gas after mixing the first agent and the second agent of Example 13 in Experimental Example 4. FIG.
도 11은 실험예 4에서 비교예 4의 1제 및 2제의 혼합 후 염소 가스 농도에 대한 GC/MS 분석 결과를 나타낸 그래프이다.FIG. 11 is a graph showing the results of GC / MS analysis on the concentration of chlorine gas after mixing the first agent and the second agent of Comparative Example 4 in Experimental Example 4. FIG.
도 12는 메시 부재가 포함된 발포 세정용 배수관 세정 용기의 일 실시예를 나타낸다.12 illustrates an embodiment of a foam cleaning drain pipe cleaning container including a mesh member.
이하, 본 발명의 이해를 돕기 위하여 실시예 등을 들어 상세하게 설명하기로 한다. 그러나, 본 발명에 따른 실시예들은 여러 가지 다른 형태로 변형될 수 있으며, 본 발명의 범위가 하기 실시예들에 한정되는 것으로 해석되어서는 안 된다. 본 발명의 실시예들은 당업계에서 평균적인 지식을 가진 자에게 본 발명을 보다 완전하게 설명하기 위해 제공되는 것이다.Hereinafter, examples and the like will be described in detail to help understand the present invention. However, embodiments according to the present invention can be modified in many different forms, the scope of the invention should not be construed as limited to the following examples. Embodiments of the present invention are provided to more fully describe the present invention to those skilled in the art.
실시예Example : 발포 세정용 배수관 세정제의 제조: Manufacture of Drain Pipe Cleaner for Foam Cleaning
하기 표 1 및 표 2와 같은 조성 비율로 원료의 성분을 혼합하고 교반하여 1제 조성물 및 2제 조성물을 제조하였다.To prepare a one-component composition and a two-component composition by mixing and stirring the components of the raw material in the composition ratio as shown in Table 1 and Table 2.
1제 조성물1 agent composition
원료명Raw material name 중량비Weight ratio
1One 정제수Purified water To 100To 100
22 차아염소산 나트륨(12%)Sodium hypochlorite (12%) 20%20%
33 SLES(3 mol, 27%)SLES (3 mol, 27%) 5%5%
44 Lauramine oxideLauramine oxide 1%One%
55 incense 0.1%0.1%
2제 조성물2 agent composition
원료명Raw material name 중량비Weight ratio
1One 정제수Purified water To 100To 100
22 과산화수소(35%)Hydrogen peroxide (35%) 20%20%
33 SLESSLES 5%5%
44 살리실산Salicylic acid 1%One%
55 소듐설페이트Sodium sulfate 0.5%0.5%
66 incense 0.1%0.1%
세정 용기는 도 5의 일 실시예와 같은 컵 형태의 용기로 제작하였다. 상기 1제 및 2제 조성물을 세정 용기와 함께 사용할 때, 1제 및 2제의 발포성 혼합물은 유입부를 통해 넘쳐 거름망을 세정할 수 있고, 발포성 액상 조성물은 컵에 뚫린 토출구를 통해 지속적으로 배출되는 것을 확인하였다.The cleaning container was manufactured as a cup-shaped container as in the example of FIG. 5. When the first agent and second agent composition is used together with the cleaning vessel, the foamable mixture of the first agent and the second agent can overflow through the inlet to clean the sieve, and the foamable liquid composition is continuously discharged through the discharge hole opened in the cup. Confirmed.
실험예Experimental Example 1: 세정 용기 사용에 따른 배수구 살균력 및 세정력 평가 1: Evaluate drainage sterilization and cleaning power according to the use of cleaning container
가정집 6곳을 방문하여 본 발명의 1제와 2제 및 컵 형태의 세정 용기를 이용하여 싱크대 배수관을 1.5 시간 동안 세정 처리한 후 배수구에 있는 미생물의 개체수를 평가하였다. 하기 표 3에 나타난 실험 결과를 볼 때, 배수관에서 평균 99.93%의 미생물이 사멸되어 살균 효과가 우수한 것을 확인할 수 있었다. Six homes were visited and the sink drain pipe was cleaned for 1.5 hours using the first and second tablets of the present invention and the cup-type cleaning containers, and the number of microorganisms in the drains was evaluated. When the experimental results shown in Table 3 below, the average of 99.93% of the microorganisms in the drain pipe was confirmed that the excellent sterilization effect.
처리 전후의 미생물 사멸율Microbial killing rate before and after treatment
처리 전 (CFU/mL)Before treatment (CFU / mL) 처리 후 (CFU/mL)After Treatment (CFU / mL) 사멸율 (%)% Mortality
1One 4.2E+074.2E + 07 1.2E+041.2E + 04 99.9799.97
22 1.4E+081.4E + 08 1.2E+051.2E + 05 99.9199.91
33 7.2E+077.2E + 07 1.1E+051.1E + 05 99.8599.85
44 4.9E+074.9E + 07 2.6E+042.6E + 04 99.9599.95
55 5.6E+075.6E + 07 2.4E+042.4E + 04 99.9699.96
66 5.2E+075.2E + 07 4.0E+044.0E + 04 99.9299.92
전체 평균Overall average 99.9399.93
또한, 도 3 및 도 4에 세정 전(왼쪽) 및 세정 후(오른쪽)의 사진을 나타내었으며, 본 발명의 발포성 세정제 조성물 및 세정 용기를 사용하는 경우 거름망 및 배수구에 대한 세정 효과가 현저하게 우수한 것을 확인하였다.3 and 4 show photographs before (left) and after (right) cleaning. When the foaming detergent composition and the cleaning container of the present invention are used, the cleaning effect on the strainer and the drain is remarkably excellent. Confirmed.
실험예Experimental Example 2: 세정 용기 사용에 따른 배수관 살균력 및 세정력 평가 2: Evaluation of Sterilization and Cleaning Power of Drain Pipe by Using Cleaning Container
가정집 7곳을 방문하여 본 발명의 1제와 2제 및 컵 형태의 세정 용기를 이용하여 싱크대 배수관을 1.5 시간 동안 세정 처리한 후 배수관에 있는 미생물의 개체수를 평가하였다.Seven homes were visited and the sink drain pipe was cleaned for 1.5 hours using the first and second tablets of the present invention and a cup-type cleaning container, and then the number of microorganisms in the drain pipe was evaluated.
실시예는 싱크대에 반응컵을 넣고 1제 500 ml 를 부은 뒤 2제 250 ml 를 부은 후 1.5 시간 방치하였다. 비교예는 싱크대에 1제 500 ml 와 2제 250 ml 를 동시에 붓고 1.5 시간 방치하였다. 이후 싱크대 배수관의 파이프 입구로부터 약 10 cm 지점의 미생물 시료를 채취하여 측정하였다.In the Example, the reaction cup was placed in the sink, 500 ml of the first agent was poured, and 250 ml of the second agent was poured and left for 1.5 hours. In Comparative Example, 500 ml of the first agent and 250 ml of the second agent were poured simultaneously into the sink and left for 1.5 hours. Thereafter, a sample of about 10 cm from the pipe inlet of the sink drain pipe was taken and measured.
하기 표 4에 나타난 실험 결과를 볼 때, 반응컵을 사용하지 않은 비교예 1~3의 경우 57.10%의 평균 살균력을 나타내는 것에 비해, 배수관에서 반응컵을 이용한 실시예 1~4의 경우 99.95%의 평균 살균력을 나타내었다. 따라서, 본 발명의 반응컵을 사용하는 경우 살균 효과가 현저하게 우수한 것을 확인할 수 있었다.In the results of the experiment shown in Table 4, compared to the average sterilization of 57.10% for Comparative Examples 1 to 3 without using the reaction cup, 99.95% of Examples 1 to 4 using the reaction cup in the drain pipe Average bactericidal power was shown. Therefore, it was confirmed that the sterilization effect is remarkably excellent when using the reaction cup of the present invention.
처리 전(CFU/mL)Before treatment (CFU / mL) 처리 후(CFU/mL)After Treatment (CFU / mL) 사멸율(%)% Mortality 평균 사멸율Average mortality
실시예 1Example 1 4.20E+074.20E + 07 1.20E+041.20E + 04 99.9799.97 99.95%99.95%
실시예 2Example 2 1.40E+071.40E + 07 1.20E+051.20E + 05 99.9199.91
실시예 3Example 3 7.20E+077.20E + 07 1.00E+041.00E + 04 99.9999.99
실시예 4Example 4 4.90E+074.90E + 07 2.60E+042.60E + 04 99.9599.95
비교예 1Comparative Example 1 5.60E+075.60E + 07 2.40E+072.40E + 07 57.1457.14 57.10%57.10%
비교예 2Comparative Example 2 5.20E+075.20E + 07 2.00E+072.00E + 07 61.5461.54
비교예 3Comparative Example 3 3.80E+073.80E + 07 1.80E+071.80E + 07 52.6352.63
또한, 도 6 및 도 7에 비교예의 세정 전(도 6) 및 세정 후(도 7)의 사진을 나타내었으며, 도 8 및 도 9에 실시예의 세정 전(도 8) 및 세정 후(도 9)의 사진을 나타내었다. 이러한 결과를 볼 때, 본 발명의 발포성 세정제 조성물 및 배수관 세정 용기를 사용하는 경우 배수관에 대한 세정 효과가 현저하게 우수한 것을 확인하였다.6 and 7 show photographs of the comparative example before washing (FIG. 6) and after washing (FIG. 7), and in FIGS. 8 and 9 before washing (FIG. 8) and after washing (FIG. 9) of the example. Showed a photo of. From these results, it was confirmed that the cleaning effect on the drain pipe is remarkably excellent when the foaming detergent composition and the drain pipe cleaning container of the present invention are used.
실험예Experimental Example 3: 토출구  3: discharge port 직경diameter 및 개수에 따른 배출시간 및 살균력 평가 Evacuation time and sterilization according to the number and number
토출구의 크기 및 개수에 따른 발포 세정제의 배출 시간 및 살균력을 평가하기 위하여 상기 표 1 및 표 2의 조성비로 1제와 2제를 제조하였다. 이후, 하기 표 5에 개시된 각각의 토출구 크기와 개수를 가지는 컵 형태의 세정 용기에 상기 1제 500 ml와 2제 250 ml를 붓고 내용물이 모두 배출되는 시간을 측정하였다. In order to evaluate the discharging time and the sterilizing power of the foaming detergent according to the size and number of discharge ports, the first agent and the second agent were prepared in the composition ratios of Tables 1 and 2. Thereafter, 500 ml of the first agent and 250 ml of the second agent were poured into a cup-type cleaning container having each discharge port size and number disclosed in Table 5, and the time for discharging all the contents was measured.
토출구 직경 길이(mm)Discharge port diameter length (mm) 토출구 개수Number of outlets 배출 시간Discharge time 미생물 사멸율 (%)Microbial killing rate (%)
실시예5Example 5 0.50.5 22 7h 30m7h 30m 99.99%99.99%
실시예6Example 6 0.50.5 44 4h 10m4h 10m 99.99%99.99%
실시예7Example 7 1One 22 2h40m2h40m 99.99%99.99%
실시예8Example 8 33 44 23m23m 89.51%89.51%
실시예9Example 9 55 22 11m11m 71.33%71.33%
실시예10Example 10 1.51.5 44 1h 52m1h 52m 99.99%99.99%
실시예11Example 11 2.02.0 22 1h 12m1h 12m 99.95%99.95%
실시예12Example 12 2.02.0 44 35m35m 99.91%99.91%
상기 표 5에 나타난 결과를 볼 때, 1~2.5 mm의 직경 및 2~5의 개수로 이루어진 토출구의 조건에서(실시예 10~12) 발포 세정제가 약 30분 내지 2시간 동안 배출되는 것을 확인하였다. 또한 상기 발포 조성물의 토출 시간이 30분 이상인 경우 99.9% 이상의 미생물 사멸율을 나타내었으며, 2시간을 초과하게 되면 더 이상 살균력이 증가하는 효과를 기대하기 어려운 것을 발견하였다.When viewing the results shown in Table 5, it was confirmed that the foamed detergent is discharged for about 30 minutes to 2 hours under the conditions of the discharge port consisting of a diameter of 1 ~ 2.5 mm and the number of 2 ~ 5 (Examples 10 to 12) . In addition, when the ejection time of the foam composition is more than 30 minutes, it showed a 99.9% or more microbial killing rate, it was found that it is difficult to expect the effect of increasing the sterilization power more than 2 hours.
실험예Experimental Example 4: pH 조절제가 포함된 세정제 조성물의 혼합 후 염소 가스 농도 4: chlorine gas concentration after mixing of detergent composition with pH adjuster
하기 표 6 과 같은 조성 비율로 원료의 성분을 혼합하고 교반하여, 본 발명의 비교예 및 실시예의 1제 조성물 및 2제 조성물을 제조하였다.The ingredients of the raw materials were mixed and stirred in the composition ratios shown in Table 6 below to prepare the first and second compositions of the comparative examples and examples of the present invention.
1 제의 NaOH 함량을 달리하여 제조한 비교예와 실시예의 1제와 2제 조성물을 1:1 의 비율로 혼합하고 pH와 염소 가스 발생량을 가스 크로마토그래피를 이용하여 분석하였다. The compositions of the first and second compositions of Comparative Examples and Examples prepared by varying the NaOH content of the first agent were mixed at a ratio of 1: 1, and the pH and the amount of chlorine gas generated were analyzed by gas chromatography.
원료명Raw material name 비교예4Comparative Example 4 비교예5Comparative Example 5 실시예13Example 13 실시예14Example 14 실시예15Example 15
1제1st 정제수Purified water To 100To 100 To 100To 100 To 100To 100 To 100To 100 To 100To 100
차아염소산나트륨(12%)Sodium hypochlorite (12%) 30%30% 30%30% 30%30% 30%30% 30%30%
SLES(3 mol,27%)SLES (3 mol, 27%) 5%5% 5%5% 5%5% 5%5% 5%5%
Lauramine oxideLauramine oxide 1%One% 1%One% 1%One% 1%One% 1%One%
NaOH (50%)NaOH (50%) 0.1%0.1% 0.2%0.2% 0.5%0.5% 1.0%1.0% 2.0%2.0%
incense 0.1%0.1% 0.1%0.1% 0.1%0.1% 0.1%0.1% 0.1%0.1%
2제2nd 정제수Purified water To 100To 100 To 100To 100 To 100To 100 To 100To 100 To 100To 100
과산화수소(35%)Hydrogen peroxide (35%) 3 %3% 3 %3% 3 %3% 3 %3% 3 %3%
SLESSLES 5 %5% 5 %5% 5 %5% 5 %5% 5 %5%
살리실산Salicylic acid 1 %One % 1 %One % 1 %One % 1 %One % 1 %One %
소듐설페이트Sodium sulfate 0.5 %0.5% 0.5 %0.5% 0.5 %0.5% 0.5 %0.5% 0.5 %0.5%
incense 0.1 %0.1% 0.1 %0.1% 0.1 %0.1% 0.1 %0.1% 0.1 %0.1%
혼합 후의 pHPH after mixing 6.26.2 6.86.8 9.89.8 12.112.1 13.513.5
염소 가스 농도Chlorine gas concentration 1808 ppm1808 ppm 1250 ppm1250 ppm 15.3 ppm15.3 ppm 1.8 ppm1.8 ppm 0.5 ppm0.5 ppm
상기 표 6에 나타난 실험 결과를 볼 때, 비교예 4 및 비교예 5에서 1제의 NaOH 함량이 0.2% 이하일 경우에는 혼합 후 pH가 9 미만으로 낮으며, 염소 가스가 현저하게 다량으로 발생한 것을 확인할 수 있었다.When the results of the experiment shown in Table 6, when the NaOH content of the first agent is less than 0.2% in Comparative Example 4 and Comparative Example 5, the pH is lower than 9 after mixing, it was confirmed that a significant amount of chlorine gas occurred Could.
반면, 도 10 및 도 11에 나타난 실시예 13의 염소 가스 발생량에 대한 분석 결과를 볼 때, 실시예 13은 염소 가스의 농도가 15.3 ppm으로 비교예에 비해 염소 가스의 발생량이 현저하게 낮은 것을 확인할 수 있었다. 참고적으로, 실시예 13의 염소 가스 농도는 독성 농도(LC50) 293 ppm에 현저하게 미달되는 수치이다.On the other hand, when looking at the analysis results for the amount of chlorine gas generated in Example 13 shown in Figures 10 and 11, Example 13 confirms that the concentration of chlorine gas is 15.3 ppm significantly lower generation of chlorine gas than the comparative example Could. For reference, the chlorine gas concentration of Example 13 is significantly lower than the toxic concentration (LC50) 293 ppm.
실험예Experimental Example 5: pH 조절제가 포함된 세정제 조성물의 살균력 평가 5: Evaluation of the bactericidal power of the cleaning composition containing the pH adjuster
가정집 6곳을 방문하여 본 발명의 실시예 13의 조성물에 해당하는 1제 500 mL, 2제 500 mL 및 하단에 직경 1 mm 구멍이 4개 뚫린 컵 형태의 반응 용기를 이용하여 싱크대 배수관을 1.5 시간 동안 세정 처리한 후 배수구에 있는 미생물의 개체수를 평가하였다.6 hours of homes were visited and the sink drain pipe was used for 1.5 hours using 500 mL of the first agent, 500 mL of the second agent corresponding to the composition of Example 13 of the present invention, and a cup-type reaction vessel having four holes with a diameter of 1 mm at the bottom. The number of microorganisms in the drains was evaluated after washing.
처리 전후의 미생물 사멸율Microbial killing rate before and after treatment
처리 전 (CFU/mL)Before treatment (CFU / mL) 처리 후 (CFU/mL)After Treatment (CFU / mL) 사멸율 (%)% Mortality
1One 4.2E+074.2E + 07 1.2E+041.2E + 04 99.9799.97
22 1.4E+081.4E + 08 1.2E+051.2E + 05 99.9199.91
33 7.2E+077.2E + 07 1.1E+051.1E + 05 99.8599.85
44 4.9E+074.9E + 07 2.6E+042.6E + 04 99.9599.95
55 5.6E+075.6E + 07 2.4E+042.4E + 04 99.9699.96
66 5.2E+075.2E + 07 4.0E+044.0E + 04 99.9299.92
전체 평균Overall average 99.9399.93
상기 표 7에 나타난 실험 결과를 볼 때, 배수관에서 평균 99.93%의 미생물이 사멸되어 살균 효과가 우수한 것을 확인할 수 있었다.When the experimental results shown in Table 7 above, the average of 99.93% of the microorganisms in the drain pipe was confirmed that the sterilization effect is excellent.
실험예Experimental Example 6: 차아염소산염 및 과산화수소의  6: of hypochlorite and hydrogen peroxide 당량비에At equivalence ratio 따른 세정제의 거품 발생량 평가 Foaming amount of cleaning agents
1제 조성물1 agent composition
원료명Raw material name 비교예6Comparative Example 6 비교예7Comparative Example 7 실시예16Example 16 실시예17Example 17 실시예18Example 18
정제수Purified water To 100To 100 To 100To 100 To 100To 100 To 100To 100 To 100To 100
차아염소산나트륨(12%)Sodium hypochlorite (12%) 5%5% 67%67% 8%8% 20%20% 35%35%
SLES(3 mol, 27%)SLES (3 mol, 27%) 5%5% 5%5% 5%5% 5%5% 5%5%
Lauryl amine oxideLauryl amine oxide 1%One% 1%One% 1%One% 1%One% 1%One%
incense 0.1%0.1% 0.1%0.1% 0.1%0.1% 0.1%0.1% 0.1%0.1%
상기 표 8과 표 2에 나타난 조성으로 1제와 2제를 제조한 후, 하기 표 9에 나타난 당량비로 각각의 비교예 및 실시예를 제조하였다.After preparing the first agent and the second agent with the composition shown in Table 8 and Table 2, each of Comparative Examples and Examples were prepared in the equivalent ratio shown in Table 9.
1제 차아염소산나트륨(mol)Sodium hypochlorite (mol) 2제 과산화수소(mol)2nd hydrogen peroxide (mol)
비교예6Comparative Example 6 0.790.79 1One
비교예7Comparative Example 7 10.5910.59 1One
실시예16Example 16 1.261.26 1One
실시예17Example 17 3.163.16 1One
실시예18Example 18 5.535.53 1One
3500 mL 비커에 1제 500 ml를 부은 후 2제 250 ml를 붓고, 발생하는 거품의 양과 파포 시간을 측정한 결과를 하기 표 10에 나타내었다.500 ml of the first agent was poured into a 3500 mL beaker and 250 ml of the second agent was poured, and the results of measuring the amount of foam and the break time occurred are shown in Table 10 below.
거품양 및 파포 시간 평가 결과Foaming and Breaking Time Evaluation Results
비교예6Comparative Example 6 비교예7Comparative Example 7 실시예16Example 16 실시예17Example 17 실시예18Example 18
초기 거품양Initial bubble 2500ml2500 ml 1300ml1300ml 2400ml2400 ml 2200ml2200ml 1900ml1900ml
파포 시간Break time 150분150 minutes 40분40 minutes 140분140 minutes 120분120 minutes 70분70 minutes
상기 표 10에 나타난 결과를 볼 때, 차아염소산나트륨이 당량비 10:1(차아염소산염:과산화수소)을 초과하는 비교예 7은 초기 발생하는 거품의 양이 비교적 적었다. 또한, 비교예 7은 파포 시간도 짧아 세정제 조성물이 배수관에 오랫동안 머물러 충분한 세정력을 나타내기에는 적절하지 못하였다.From the results shown in Table 10, Comparative Example 7 in which sodium hypochlorite exceeds the equivalent ratio of 10: 1 (hypochlorite: hydrogen peroxide) has a relatively small amount of bubbles initially generated. In addition, Comparative Example 7 also had a short break time, which was not suitable for the detergent composition to remain in the drainage pipe for a long time to exhibit sufficient cleaning power.
실험예Experimental Example 7: 혼합용액의 배수관 살균력 및 세정력 평가 7: Evaluation of sterilization and cleaning power of mixed solution
실험예 6의 비교예 및 실시예의 1제 500 ml 및 2제 250 ml를 혼합한 용액에 대하여 살균력 및 세정력을 평가하였다. 가정집 5곳을 방문하여 상기 1제와 2제의 세정제 조성물 및 본 발명의 세정 용기를 이용하여, 싱크대 배수관을 1.5 시간 동안 세정 처리하였다. 이후 배수구에 있는 미생물의 개체수를 평가하고, 오염 제거 정도를 확인하였다.Bactericidal power and detergency were evaluated for the solution in which 500 ml of the first agent and 250 ml of the second agent of Comparative Example and Example of Experimental Example 6 were mixed. Five homes were visited and the sink drain pipe was washed for 1.5 hours using the cleaning composition of the first and second agents and the cleaning container of the present invention. Then, the number of microorganisms in the drain was evaluated and the degree of decontamination was checked.
처리 전후의 미생물 사멸율Microbial killing rate before and after treatment
처리 전 (CFU/mL)Before treatment (CFU / mL) 처리 후 (CFU/mL)After Treatment (CFU / mL) 사멸율 (%)% Mortality
비교예6Comparative Example 6 5.6E+075.6E + 07 5.9E+065.9E + 06 89.4689.46
비교예7Comparative Example 7 5.1E+075.1E + 07 4.8E+054.8E + 05 99.0699.06
실시예16Example 16 3.1E+083.1E + 08 1.6E+051.6E + 05 99.9599.95
실시예17Example 17 4.3E+074.3E + 07 1.9E+041.9E + 04 99.9699.96
실시예18Example 18 7.7E+077.7E + 07 3.4E+043.4E + 04 99.9699.96
상기 표 11에 나타난 실험 결과를 볼 때, 1제 차아염소산나트륨의 함량이 낮은 경우, 즉 비교예 6과 같이 2제 과산화수소 당량 대비 1제 차아염소산나트륨의 당량이 0.79배인 경우에는 1제와 2제가 반응한 후 남은 차아염소산나트륨의 양이 적어 살균력이 약하게 발휘된 것을 확인할 수 있었다. 또한, 비교예 7에서와 같이 과산화수소 대비 차아염소산나트륨의 당량이 10.59배로 많은 경우에도 배수관에 충분히 거품이 남지 못하여 살균력이 최대한 발휘되지 못하였다.According to the experimental results shown in Table 11, when the content of the first agent sodium hypochlorite is low, that is, when the equivalent of the first agent sodium perchlorate is 0.79 times compared to the second agent hydrogen peroxide equivalent as in Comparative Example 6, the first agent and the second agent are After the reaction, the amount of sodium hypochlorite remaining was confirmed to be weakly exhibited bactericidal power. In addition, even in the case where the equivalent amount of sodium hypochlorite compared to hydrogen peroxide was 10.59 times as in Comparative Example 7, the foam was not sufficiently foamed in the drainage tube and the sterilizing power was not exhibited to the maximum.
또한, 방문한 가정집의 싱크대 배수구에 1제와 2제를 혼합한 용액을 1.5 시간 동안 세정 처리한 후, 거름망과 배수관의 오염이 제거된 정도를 육안으로 확인하여 세정력을 평가한 결과를 하기 표 12에 나타내었다.In addition, after washing the solution mixed with the first agent and the second agent in the sink drain of the visited home for 1.5 hours, the degree of contamination of the strainer and the drain pipe was visually confirmed to evaluate the cleaning power. Indicated.
처리 후 오염 제거 평가Decontamination assessment after treatment
비교예6Comparative Example 6 비교예7Comparative Example 7 실시예16Example 16 실시예17Example 17 실시예18Example 18
싱크대 거름망Sink sieve
배수관drain XX
(◎:매우좋음, ○:좋음, △:보통, X:나쁨)(◎: Very good, ○: Good, △: Normal, X: Bad)
상기 표 12에서와 같이 1제 차아염소산나트륨의 함량이 낮은 경우, 즉 과산화수소 대비 차아염소산나트륨의 당량이 0.79배인 비교예 6의 경우에 세정력이 약하게 발휘됨을 확인할 수 있었다. 또한 비교예 7의 경우에는 과산화수소 대비 차아염소산나트륨의 당량이 10.59배로 높았음에도 불구하고 세정 거품이 배수관 내벽에 충분히 머무르지 못하여 세정력이 제대로 발휘되지 못하는 결과를 나타내었다.As shown in Table 12, when the content of monobasic sodium hypochlorite was low, that is, in the case of Comparative Example 6 in which the equivalent weight of sodium hypochlorite to hydrogen peroxide was 0.79 times, it was confirmed that the cleaning power was weakly exhibited. In addition, in Comparative Example 7, although the equivalent of sodium hypochlorite was 10.59 times higher than that of hydrogen peroxide, the cleaning foam did not sufficiently remain on the inner wall of the drain pipe, and thus the cleaning power was not properly exhibited.
실험예Experimental Example 8: 세정 용기의  8: washing vessel 메시Messi 부재에 따른 배수구 살균력 및 세정력 평가 Evaluation of Drainage Sterilization and Detergency
가정집 8곳을 방문하여 2곳에는 메시 부재가 없는 세정 용기, 6곳에는 메시 부재가 부착된 세정 용기를 싱크대 배수구에 설치하여 세정제 1제 및 2제를 처리하였다. 싱크대 배수관을 1.5 시간 동안 세정 처리한 후, 배수구에 있는 미생물의 개체수와 세정력을 평가하였다.8 homes were visited, and two cleaning containers without mesh members and two cleaning containers with mesh members were installed in the sink drain hole to treat the first and second cleaning agents. After washing the sink drain pipe for 1.5 hours, the population and the cleaning power of the microorganisms in the drain were evaluated.
하기 표 13에 나타난 실험 결과를 볼 때, 메시 부재가 부착된 세정 용기를 이용하여 세정제를 처리한 배수관에서는 평균 99.87%의 미생물이 사멸된 것을 확인할 수 있었다. 이러한 결과로부터, 메시 부재가 부착된 세정 용기로 처리한 실시예는 메시 부재가 없는 세정 용기로 처리한 비교예에 비하여 살균력이 현저하게 높은 것을 확인할 수 있었다.When the results of the experiment shown in Table 13 below, it was confirmed that the average of 99.87% of the microorganisms were killed in the drain pipe treated with the cleaning agent by using the cleaning container attached to the mesh member. From these results, it was confirmed that the Example treated with the cleaning container with the mesh member was significantly higher in sterilizing power than the Comparative Example treated with the cleaning container without the mesh member.
처리 전후의 미생물 사멸율Microbial killing rate before and after treatment
처리 전 (CFU/mL)Before treatment (CFU / mL) 처리 후 (CFU/mL)After Treatment (CFU / mL) 사멸율 (%)% Mortality
비교예8Comparative Example 8 2.6E+072.6E + 07 2.5E+062.5E + 06 90.3890.38
비교예9Comparative Example 9 1.1E+071.1E + 07 2.3E+052.3E + 05 97.9197.91
비교예 평균Comparative example mean 94.1594.15
실시예19Example 19 3.1E+063.1E + 06 1.9E+031.9E + 03 99.9499.94
실시예20Example 20 1.5E+071.5E + 07 2.3E+042.3E + 04 99.8599.85
실시예21Example 21 6.5E+076.5E + 07 3.9E+043.9E + 04 99.9499.94
실시예22Example 22 2.2E+072.2E + 07 5.0E+045.0E + 04 99.7799.77
실시예23Example 23 1.7E+071.7E + 07 3.8E+043.8E + 04 99.7899.78
실시예24Example 24 5.2E+065.2E + 06 1.6E+031.6E + 03 99.9799.97
실시예 평균Example Average 99.8799.87
또한, 오염이 제거된 정도를 육안으로 판정하여 세정력을 평가한 결과를 하기 표 14에 나타내었다. 하기 표 14에 나타난 결과를 볼 때, 실시예는 비교예에 비해 전반적으로 우수한 세정력을 보이는 것을 확인할 수 있었다. 이러한 결과로부터, 세정 용기에 처리된 1제와 2제 혼합액이 메시 부재를 통과하면서 조밀한 거품이 형성되었고, 이 세정 거품이 배수관 벽면에 밀착되면서 오염을 보다 효과적으로 제거한 것을 확인할 수 있었다.In addition, the results of evaluating the cleaning power by visually determining the degree of contamination removed are shown in Table 14 below. When the results shown in Table 14, the Example was confirmed to show an overall excellent cleaning power compared to the comparative example. From these results, it was confirmed that dense foam was formed while the mixed solution of the first agent and the second agent treated in the cleaning container passed through the mesh member, and the cleaning foam adhered to the wall of the drain pipe more effectively to remove the contamination.
처리 전후의 세정력 비교평가Comparative evaluation of cleaning power before and after treatment
비교예8Comparative Example 8 비교예9Comparative Example 9 실시예19Example 19 실시예20Example 20 실시예21Example 21 실시예22Example 22 실시예23Example 23 실시예24Example 24
세정력Cleaning power
(◎:매우좋음, ○:좋음, △:보통, X:나쁨)(◎: Very good, ○: Good, △: Normal, X: Bad)

Claims (29)

  1. 내부에 형성된 수용공간이 구비된 용기 본체;A container body having a receiving space formed therein;
    상기 수용공간에 발포 세정용 배수관 세정제를 유입시키는 유입구; 및An inlet for introducing a foamed washing drain pipe cleaner into the accommodation space; And
    상기 용기 본체에 수용된 상기 수용공간과 배수관이 연통되도록 상기 용기 본체에 형성되며, 상기 수용공간에 수용된 세정제를 상기 배수관으로 토출시키는 적어도 하나의 토출구를 포함하며, 세정제를 배수관에 바로 처리하는 경우에 비해 느린 속도로 토출시키는 발포 세정용 배수관 세정 용기.And at least one discharge port formed in the container body to communicate the receiving space accommodated in the container body with the drain pipe and discharging the detergent contained in the receiving space into the drain pipe, compared to a case where the cleaning agent is directly disposed in the drain pipe. Drain pipe cleaning container for foaming cleaning discharged at a slow speed.
  2. 제1항에 있어서, 상기 세정 용기는 배수관과 연결되도록 마련된 배수구에 설치되는 것을 특징으로 하는 발포 세정용 배수관 세정 용기.According to claim 1, wherein the cleaning vessel is a foam pipe cleaning drain pipe cleaning container, characterized in that installed in the drain provided to be connected to the drain pipe.
  3. 제1항에 있어서, 상기 세정 용기는 상면에서 하면으로 갈수록 직경이 점진적으로 작아지는 것을 특징으로 하는 발포 세정용 배수관 세정 용기.2. The foam pipe cleaning container according to claim 1, wherein the cleaning container gradually decreases in diameter from an upper surface to a lower surface.
  4. 제1항에 있어서, 상기 세정 용기는 유입부를 통해 배출된 세정제가 외면을 타고 흐를 수 있도록 요철홈이 미리 정해진 간격으로 마련된 요철 구조를 포함하는 것을 특징으로 하는 발포 세정용 배수관 세정 용기.The method of claim 1, wherein the cleaning container is a foam pipe washing container for cleaning the drainage, characterized in that the concave-convex groove is provided at predetermined intervals so that the cleaning agent discharged through the inlet flows on the outer surface.
  5. 제1항에 있어서, 상기 토출구는 상기 세정제가 상기 토출구를 통해 1~100 ml/min으로 배출되도록 미리 정해진 직경을 갖는 것을 특징으로 하는 발포 세정용 배수관 세정 용기.According to claim 1, wherein the discharge port has a predetermined diameter so that the cleaning agent is discharged through the discharge port at 1 ~ 100 ml / min, characterized in that the foam pipe for cleaning the drain pipe.
  6. 제5항에 있어서, 상기 미리 정해진 직경은 0.1~10 mm인 것을 특징으로 하는 발포 세정용 배수관 세정 용기.The foam pipe washing vessel cleaning vessel according to claim 5, wherein the predetermined diameter is 0.1 to 10 mm.
  7. 제1항에 있어서, 상기 토출구는 상기 세정제가 상기 토출구를 통해 10분 내지 180분 동안 배출되도록 미리 정해진 직경 및 개수를 갖는 것을 특징으로 하는 발포 세정용 배수관 세정 용기.According to claim 1, wherein the discharge port has a predetermined diameter and the number of the cleaning pipe for cleaning the drain pipe, characterized in that the cleaning agent is discharged through the discharge port for 10 minutes to 180 minutes.
  8. 제7항에 있어서, 상기 토출구의 미리 정해진 직경은 0.1~10 mm인 것을 특징으로 하는 발포 세정용 배수관 세정 용기.8. The foam pipe washing vessel cleaning container according to claim 7, wherein the discharge port has a predetermined diameter of 0.1 to 10 mm.
  9. 제7항에 있어서, 상기 토출구의 개수는 1~8개인 것을 특징으로 하는 발포 세정용 배수관 세정 용기.8. The drain pipe washing container for foam cleaning according to claim 7, wherein the number of the discharge holes is 1 to 8.
  10. 제1항에 있어서, 상기 용기는 발포 세정용 배수관 세정제가 통과되는 메시 부재를 포함하는 것을 특징으로 하는 발포 세정용 배수관 세정 용기.2. The foam pipe cleaning container according to claim 1, wherein the container includes a mesh member through which the foam pipe cleaning pipe passes.
  11. 제10항에 있어서, 상기 메시 부재는 상기 유입구에 형성되는 것을 특징으로 하는 발포 세정용 배수관 세정 용기.11. The foam pipe cleaning container according to claim 10, wherein the mesh member is formed at the inlet.
  12. 제10항에 있어서, 상기 메시 부재는 그물망의 형태인 것을 특징으로 하는 발포 세정용 배수관 세정 용기.11. The foam pipe cleaning container according to claim 10, wherein the mesh member is in the form of a mesh.
  13. 제10항에 있어서, 상기 메시 부재의 공극 크기는 100 내지 10000 마이크론(micron)인 것을 특징으로 하는 발포 세정용 배수관 세정 용기.11. The foam pipe cleaning vessel according to claim 10, wherein the pore size of the mesh member is 100 to 10000 microns.
  14. 차아염소산염 및 과산화수소를 1:1 내지 10:1의 당량비(차아염소산염:과산화수소)로 포함하는 발포 세정용 배수관 세정제 조성물.A foaming cleaning drainage pipe cleaning composition comprising hypochlorite and hydrogen peroxide in an equivalent ratio of 1: 1 to 10: 1 (hypochlorite: hydrogen peroxide).
  15. 제14항에 있어서, 상기 조성물은 차아염소산염을 포함하는 1제와 과산화수소를 포함하는 2제의 이액형으로 이루어진 것을 특징으로 하는 발포 세정용 배수관 세정제 조성물.15. The drainage pipe cleaning composition according to claim 14, wherein the composition is composed of a two-component type comprising a first agent containing hypochlorite and a second agent containing hydrogen peroxide.
  16. 염소계 세정제 성분을 포함하는 1제, 발포제를 포함하는 2제 및 pH 조절제를 포함하는 발포 세정용 배수관 세정제 조성물.A drainage pipe cleaning composition for foaming cleaning comprising a chlorine-based detergent component, a second agent including a blowing agent, and a pH adjuster.
  17. 제1항에 있어서, 상기 발포 세정용 배수관 세정제는 염소계 세정제 성분을 포함하는 1제, 발포제를 포함하는 2제 및 pH 조절제를 포함하는 것을 특징으로 하는 발포 세정용 배수관 세정 용기.2. The foam pipe washing container according to claim 1, wherein the foam pipe drain cleaning agent comprises a first agent containing a chlorine-based cleaner component, a second agent including a blowing agent, and a pH adjuster.
  18. 제16항에 있어서, 상기 조성물은 1제 및 2제의 혼합 시 pH가 9~14인 것을 특징으로 하는 발포 세정용 배수관 세정제 조성물.17. The method of claim 16, wherein the composition has a pH of 9 to 14 when mixing the first agent and the second agent, the drain pipe cleaning composition for foam cleaning.
  19. 제16항에 있어서, 상기 pH 조절제는 상기 1제에 포함되는 것을 특징으로 하는 발포 세정용 배수관 세정제 조성물.The drainage pipe cleaning composition according to claim 16, wherein the pH adjusting agent is contained in the first agent.
  20. 제19항에 있어서, 상기 1제는 pH가 12~14인 것을 특징으로 하는 발포 세정용 배수관 세정제 조성물.The drainage pipe cleaning composition according to claim 19, wherein the one agent has a pH of 12 to 14.
  21. 제16항에 있어서, 상기 pH 조절제는 상기 2제에 포함된 산성 물질의 총 수소 이온과 1.1~10:1의 당량비(pH 조절제: 2제에 포함된 산성 물질의 총 수소 이온 당량)로 포함되는 것을 특징으로 하는 발포 세정용 배수관 세정제 조성물. The pH adjusting agent of claim 16, wherein the pH adjusting agent is included in an equivalent ratio of 1.1 to 10: 1 total hydrogen ions of the acidic substances included in the agent (pH regulator: total hydrogen ion equivalents of the acidic substances included in the agent). Drainage cleaning agent composition for foam cleaning, characterized in that.
  22. 제16항에 있어서, 상기 조성물은 1제 및 2제를 혼합 시 발생되는 염소 가스가 300 ppm 미만인 것을 특징으로 하는 발포 세정용 배수관 세정제 조성물.17. The method of claim 16, wherein the composition is a foaming cleaning drain pipe cleaning composition, characterized in that the chlorine gas generated when mixing the first agent and the second agent is less than 300 ppm.
  23. 차아염소산염을 포함하는 1제 및 과산화수소를 포함하는 2제를 포함하는 발포 세정용 배수관 세정제; 및A foaming cleaning drainage pipe cleaning agent comprising a first agent containing hypochlorite and a second agent containing hydrogen peroxide; And
    내부에 형성된 수용공간이 구비된 용기 본체 및 상기 수용공간에 발포 세정용 배수관 세정제를 유입시키는 유입구를 포함하는 발포 세정용 배수관 세정 용기를 포함하며,It includes a container body having a receiving space formed therein and a foaming cleaning drain pipe cleaning container including an inlet for introducing a foaming cleaning drain pipe cleaner into the receiving space,
    상기 수용공간의 부피는 상기 발포 세정용 배수관 세정제의 총 부피보다 작은 것을 특징으로 하는 발포 세정용 배수관 세정 키트.And a volume of the accommodation space is smaller than a total volume of the foam cleaning drain pipe cleaner.
  24. 제23항에 있어서, 상기 수용공간의 부피는 발포된 상태의 상기 배수관 세정제의 차아염소산염을 포함하는 1제 및 과산화수소를 포함하는 2제의 혼합물 및 이로부터 발생하는 기포의 부피보다 작은 것을 특징으로 하는 발포 세정용 배수관 세정 키트.24. The method of claim 23, wherein the volume of the receiving space is characterized in that the volume of the mixture of the first agent containing hypochlorite of the drainage pipe cleaner in the foamed state and the second agent containing hydrogen peroxide and bubbles generated therefrom. Drain Cleaning Kit for Foam Cleaning.
  25. 제24항에 있어서, 상기 수용공간의 부피 및 상기 발포된 세정제의 부피는 1:1.01~5(수용공간의 부피:발포된 세정제의 부피)의 부피비인 것을 특징으로 하는 발포 세정용 배수관 세정 키트.25. The method of claim 24, wherein the volume of the accommodating space and the volume of the foamed detergent is a volume ratio of 1: 1.01 ~ 5 (volume of the accommodating space: the volume of the foamed detergent) foam cleaning kit for the foam cleaning.
  26. 제24항에 있어서, 상기 1제 및 2제의 혼합물 또는 이로부터 발생하는 기포는 발포 세정용 배수관 세정 용기의 유입구를 통해 넘쳐 흐르는 것을 특징으로 하는 발포 세정용 배수관 세정 키트.25. The foam pipe cleaning kit according to claim 24, wherein the mixture of the first agent and the second agent or bubbles generated therefrom flow through the inlet of the foam pipe washing container.
  27. 제1항의 발포 세정용 배수관 세정 용기 및 발포 세정용 배수관 세정제를 포함하는 발포 세정용 배수관 세정 키트.A foam cleaning drain pipe cleaning kit comprising the foam cleaning drain pipe cleaning container and the foam cleaning drain pipe cleaner.
  28. 제27항에 있어서, 상기 발포 세정용 배수관 세정제는 점증제를 추가적으로 포함하여, 점도가 100~10,000 cps인 것을 특징으로 하는 발포 세정용 배수관 세정 키트.28. The method of claim 27, wherein the foam pipe for cleaning the drainage pipe further comprises a thickener, viscosity of the foam pipe for cleaning the drainage pipe, characterized in that 100 ~ 10,000 cps.
  29. 제1항의 발포 세정용 배수관 세정 용기를 사용하여 주방 싱크대의 거름망 및 배수관을 발포 세정하는 방법.A method of foam cleaning of a strainer and drain pipe of a kitchen sink using the foam cleaning drain pipe cleaning container according to claim 1.
PCT/KR2016/008407 2015-07-31 2016-07-29 Drain pipe cleaning kit and cleaning method using same WO2017023051A1 (en)

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20010073063A (en) * 1998-08-31 2001-07-31 피프 카렌 에이. Foaming drain cleaner
JP2002356700A (en) * 2001-05-31 2002-12-13 Ue Ruko:Kk Foaming washing tool and method
JP2003164472A (en) * 2001-11-29 2003-06-10 Ue Ruko:Kk Bubble cleaning method
JP2008150461A (en) * 2006-12-15 2008-07-03 T Hasegawa Co Ltd Viscous detergent used for water-discharging port or pipe
JP2015062891A (en) * 2013-08-30 2015-04-09 情次 本多 Foam cleaning device and foam cleaning method

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20010073063A (en) * 1998-08-31 2001-07-31 피프 카렌 에이. Foaming drain cleaner
JP2002356700A (en) * 2001-05-31 2002-12-13 Ue Ruko:Kk Foaming washing tool and method
JP2003164472A (en) * 2001-11-29 2003-06-10 Ue Ruko:Kk Bubble cleaning method
JP2008150461A (en) * 2006-12-15 2008-07-03 T Hasegawa Co Ltd Viscous detergent used for water-discharging port or pipe
JP2015062891A (en) * 2013-08-30 2015-04-09 情次 本多 Foam cleaning device and foam cleaning method

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