WO2016182600A1 - Systèmes de génération d'énergie électrique ultraviolette et procédés associés - Google Patents

Systèmes de génération d'énergie électrique ultraviolette et procédés associés Download PDF

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Publication number
WO2016182600A1
WO2016182600A1 PCT/US2015/065826 US2015065826W WO2016182600A1 WO 2016182600 A1 WO2016182600 A1 WO 2016182600A1 US 2015065826 W US2015065826 W US 2015065826W WO 2016182600 A1 WO2016182600 A1 WO 2016182600A1
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WIPO (PCT)
Prior art keywords
power
molten metal
ignition
source
reactants
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Application number
PCT/US2015/065826
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English (en)
Inventor
Randell Lee Mills
Original Assignee
Brilliant Light Power, Inc.
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Application filed by Brilliant Light Power, Inc. filed Critical Brilliant Light Power, Inc.
Publication of WO2016182600A1 publication Critical patent/WO2016182600A1/fr

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Classifications

    • G—PHYSICS
    • G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
    • G21B—FUSION REACTORS
    • G21B3/00—Low temperature nuclear fusion reactors, e.g. alleged cold fusion reactors
    • H—ELECTRICITY
    • H02—GENERATION; CONVERSION OR DISTRIBUTION OF ELECTRIC POWER
    • H02S—GENERATION OF ELECTRIC POWER BY CONVERSION OF INFRARED RADIATION, VISIBLE LIGHT OR ULTRAVIOLET LIGHT, e.g. USING PHOTOVOLTAIC [PV] MODULES
    • H02S10/00—PV power plants; Combinations of PV energy systems with other systems for the generation of electric power
    • H02S10/30—Thermophotovoltaic systems
    • H—ELECTRICITY
    • H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05H—PLASMA TECHNIQUE; PRODUCTION OF ACCELERATED ELECTRICALLY-CHARGED PARTICLES OR OF NEUTRONS; PRODUCTION OR ACCELERATION OF NEUTRAL MOLECULAR OR ATOMIC BEAMS
    • H05H2240/00—Testing
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00—Energy generation through renewable energy sources
    • Y02E10/50—Photovoltaic [PV] energy
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E30/00—Energy generation of nuclear origin
    • Y02E30/10—Nuclear fusion reactors

Definitions

  • the present disclosure relates to the field of power generation and, in particular, to systems, devices, and methods for the generation of power. More specifically, embodiments of the present disclosure are directed to power generation devices and systems, as well as related methods, which produce optical power, plasma, and thermal power and produces electrical power via an optical to electric power converter, plasma to electric power converter, photon to electric power converter, or a thermal to electric power converter. n addition, embodiments of the present disclosure describe systems, devices, and methods that use the ignition of a water or water-based fuel source to generate optical power, mechanical power, electrical power, and/or thermal power using photovoltaic power converters. These and other related embodiments are described in detail in the present disclosure.
  • Power generation can take many forms, harnessing the power from plasma.
  • Successful commercialization of plasma may depend on power generation systems capable of efficiently forming plasma and then capturing the power of the plasma produced.
  • Plasma may be formed during ignition of certain fuels. These fuels can include water or water-based fuel source. During ignition, a plasma cloud of electron-stripped atoms is formed, and high optical power may be released. The high optical power of the plasma can be harnessed by an electric converter of the present disclosure. The ions and excited state atoms can recombine and undergo electronic relaxation to emit optical power. The optical power can be converted to electricity with photovoltaics.
  • Certain embodiments of the present disclosure are directed to a power generation system comprising; a plurality of electrodes configured to deliver power to a fuel to ignite the fuel and produce a plasma; a source of electrical power configured to deliver electrical energy to the plurality' of electrodes; and at least one photovoltaic power converter positioned to receive at least a plurality of plasma photons.
  • the present disclosure is directed to a power system that generates at least one of electrical energy and thermal energy comprising: at least one vessel capable of a maintaining a pressure of below, at, or above atmospheric;
  • the reaciants comprising:
  • At least one molten metal injection system comprising a molten metal reservoir and an electromagnetic pump
  • the additional reaciants comprise:
  • At least one reactants ignition system comprising a source of electrical power to cause the reactants to form at least one of light-emitting plasma and thermal- emitting plasma wherein the source of electrical power receives electrical power from the power converter;
  • molten metal ignition system comprises:
  • the electrodes comprise a refractory metal
  • the source of electrical power to deliver a short, burst of high-current electrical energy sufficient to cause the reactants to react to form plasma comprises at least one supercapacitor
  • the molten metal injection system comprises an electromagnetic pump comprising at least one magnet providing a magnetic field and current source to provide a vector-crossed current component;
  • the molten metal reservoir comprises an inductively coupled heater to at least initially heat a metal that forms the molten metal
  • the molten metal ignition system comprises at least one set of electrodes that are separated to form an open circuit, wherein the open circuit is closed by the injection of the molten metal to cause the high current to flow to achieve ignition; wherein the molten metal ignition system current is in the range of 500 A to 50,000 A;
  • molten metal ignition system wherein the circuit is closed to cause an ignition frequency in the range of 1 Hz to 10,000 Hz;
  • the molten metal comprises at least one of silver, silver-copper alloy, and copper;
  • the addition reactants comprise at least one 0F H 2 O vapor and hydrogen gas
  • the additional reactants injection system comprises at least one of a computer, 3 ⁇ 40 and 3 ⁇ 4 pressure sensors, and flow controllers comprising at least one or more of the group of a mass flow controller, a pump, a syringe pump, and a high precision electronically controllable valve; the valve comprising at least one of a needle valve, proportional electronic valve, and stepper motor valve wherein the valve is controlled by the pressure sensor and the computer to maintai at least one of the H 2 0 and 3 ⁇ 4 pressure at a desired value;
  • system to recover the products of the reactants comprises at least one of the vessel comprising walls capable of providing flow to the melt under gravity, an electrode electromagnetic pump, and the reservoir in communication with the vessel and further comprising a cooling system to maintain the reservoir at a lower temperature than another portion of the vessel to cause metal vapor of the molten metal to condense in the reservoir;
  • the recovery system comprising an electrode electromagnetic pump comprises at least one magnet providing a magnetic field and a vector-crossed ignition current component
  • the vessel capable of a maintaining a pressure of below, at, or above atmospheric comprises an inner reaction ceil, a top cover comprising a blackbody radiator, and an outer chamber capable of maintaining the a pressure of below, at, or above atmospheric;
  • top cover comprising a blackbody radiator is maintained at a temperature in the range of 1000 K to 3700 K;
  • At least one of the inner reaction cell and top cover comprising a biackbody radiator comprises a refractory metal having a high emissivity
  • the blackbody radiator further comprises a blackbody temperature sensor and controller
  • the at least one power converter of the reaction power output comprises at least one of the group of a thermophotovoltaic converter and a photovoltaic converter; wherein the light emitted by the ceil is predominantly blackbody radiation comprising visible and near infrared light, and the photovoltaic cells are concentrator cells that comprise at least one compound chosen from crystalline silicon, germanium, gal Hum arsenide (GaAs), gallium antimonide (GaSb), indium gallium arsenide (InGaAs), indium gallium arsenide antimonide (InGaAsSb), and indium phosphide arsenide antimonide (InPAsSb), Group III/V semiconductors, InGaP/InGaAs/Ge;
  • GalnP/GaAsP/Ge GainP/GaAsP/Si/SiGe; GalnP/GaAs InGaAs;
  • GalnP/GaAs/GalnNAs GalnP/GaAs/GalnNAs; GalnP/GaAs/InGaAs InGaAs; GaInP/Ga(in)As/lnGaAs; GainP-GaAs-wafer-InGaAs; GamP-Ga(Tn)As-Ge; and GainP-GainAs-Ge
  • the power system further comprises a vacuum pump and at least one chiller.
  • the present disclosure is directed to a power system that enerates at least one of electrical energy and thermal energy comprising:
  • At least one vessel capable of a pressure of below atmospheric
  • At least one shot injection system comprising at least one augmented railgun, wherein the augmented railgun comprises separated electrified rails and magnets that produce a magnetic field perpendicular to the plane of the rails, and the circuit between the rails is open until closed by the contact of the shot with the rails;
  • At least one ignition system to cause the shot to form at least one of light-emitting plasma and thermal-emitting plasma, at least one ignition system comprising:
  • the at least one set of electrodes form an open circuit, wherein the open circuit is closed by the injection of the shot to cause the high current to flow to achieve ignition, and the source of electrical power to deliver a short burst of high- current electrical energy comprises at least one of the following:
  • a voltage selected to cause a high AC, DC, or an AC-DC mixture of current that is in the range of at least one of 100 A to 1 ,000,000 A, 1 kA to 100,000 A, 10 kA to 50 kA;
  • a DC or peak AC current density in the range of at least one of 100 A/cm 2 to 1,000,000 A/cm 2 , 1000 A/cm 2 to 100,000 A/em 2 , and 2000 A/cm 1 to 50,000 A/cm 2 ;
  • the voltage is determined by the conductivity of the solid fuel or energetic material wherein the voltage Is given by the desired current times the resistance of the solid fuel or energetic material sample;
  • ihe DC or peak AC voltage is in the range of at least one of 0. 1 V to 500 kV, 0.1 V to 100 kV, and 1 V to 50 kV, and
  • the AC frequency is in range of at least one of 0.1 Hz to 10 GHz, 1 Hz to 1 MHz, 10 Hz to 100 kHz, and 100 Hz to 10 kHz.
  • a system to recover reaction products of the reactants comprising at least one of gravity and an augmented plasma railgun recovery sysiem comprising at least one magnet providing a magnetic field and a vector-crossed current component of the ignition electrodes;
  • At least one regeneration system to regenerate additional reactants from the reaction
  • products and form additional shot comprising a pelletizer comprising a smelter to form molten reactants, a sysiem to add 3 ⁇ 4 and 13 ⁇ 40 to the molten reactants, a melt dripper, and a water reservoir to form shot,
  • At least one power converter or output system of at least one of the light and thermal output to electrical power and/or thermal power comprising at least one or more of the group of a photovoltaic converter, a photoekctronic converter, a p!asmadynamie converter, a thermionic converter, a thermoelectric converter, a Sterling engine, a Brayion cycle engine, a Rankine cycle engine, and a heat engine, and a heater.
  • the present disclosure is directed to a power system that generates at least one of electrical energy and thermal energy comprising:
  • At least one vessel capable of a pressure of below atmospheric
  • the shot comprising reactants, the reactants comprising at least one of silver, copper,
  • At least one shot injection system comprising at least one augmented railgun wherein the augmented railgun comprises separated electrified rails and magnets that produce a magnetic field perpendicular to the plane of the rails, and the circuit between the rails is open until closed by the contact of the shot with the rails;
  • At least one ignition system to cause the shot to form at least one of light-emitting plasma and thermal -e itting plasma, at least one ignition system comprising:
  • the at least one set of electrodes that are separated to form an open circuit wherein the open circuit is closed by the injection of the shot to cause the high current ⁇ flow to achieve ignition, and he source of eiectricai power to deliver a short burst of high-current electrical energy comprises at least one of the following:
  • a voltage selected to cause a high AC, DC, or an AC-DC mixture of current that is in the range of at least one of 100 A to 1 ,000,000 A, 1 kA to 100,000 A, 10 kA to 50 kA;
  • a DC or peak AC current density in the range of at least one of 100 A/cm 2 to 1,000,000 A/cm 2 , 1000 A/cm 2 to 100,000 A/cm 2 , and 2000 A/cm 2 to 50,000 A/cm 2 ; the voltage is determined by the conductivity of the solid fuel or energetic material wherein the voltage is given by the desired current times the resistance of the solid fuel or energetic material sample;
  • the DC or peak AC voltage is in the range of at least one of 0.1 V to 500 kV, 0.1 V to 100 kV, and 1 V to 50 kV, aad
  • the AC frequency is in range of at least one of 0.1 Hz to 10 GHz, i Hz to 1 MHz, 10 Hz to 100 kHz, and 100 Hz to 10 kHz.
  • a system to recover reaction products of the reacianis comprising at least one of gravity and a augmented plasma rail gun recovery system comprising at least one magnet providing a magnetic field and a vector-crossed current component of the ignition electrodes;
  • At least one regeneration system to regenerate additional reactants from the reaction products and form additional shot comprising a peiletizer comprising a smelter to form molten reacianis, a system to add 3 ⁇ 4 and 3 ⁇ 40 to the molten reactants, a melt dripper, and a water reservoir to form shot,
  • the additional reactants comprise at least one of silver, copper, absorbed hydrogen, and water;
  • At least one power converter or output system comprising a concentrator ultraviolet photovoltaic converter wherein the photovoltaic cells comprise at least one compound chosen from a Group Hi nitride, GaAIN, GaN, and InGaN.
  • the present disclosure is directed to a power system that enerates at least one of eiectricai energy and thermal energy comprising:
  • reactants comprising:
  • At least one shot injection system At least one shot injection system
  • At least one shot ignition system to cause the shot to form at least one of light-emitting plasma and tnennal-emirtiag plasma; a system to recover reaction products of the reactants;
  • At least one regeneration system to regenerate additional reactants from the reaction
  • Certain embodiments of the present disclosure are directed to a power generation system comprising: a plurality of electrodes configured to deliver power to a fuel to ignite the fuel and produce a plasma; a source of electrical power configured to deliver electrical energy to the plurality of electrodes; and at least one photovoltaic power converter positioned to receive at ieast a plurality of plasma photons.
  • the present disclosure is directed to a power system that generates at least one of direct electrical energy and thermal energy comprising:
  • reactants comprising:
  • At least one set of electrodes to confine the hydrino reactants
  • At ieast one system to regenerate the initial reactants from the reaction products and ai ieast one plasma dynamic converter or at least one photovoltaic converter.
  • a method of producing electrical power may comprise supplying a fuel to a region between a plurality of electrodes; energizing the plurality of electrodes to ignite the fuel to form a plasma; converting a plurality of plasma photons into electrical power with a photovoltaic power converter; and outputting at least a portion of the electrical power.
  • a method of producing electrical power may comprise supplying a fuel to a region between a plurality of electrodes; energizing the plurality of electrodes to ignite the fuel to form a plasma; converting a plurality of plasma photons into thermal power with a photovoltaic power converter; and outputting at least a portion of the electrical power.
  • a method of generating power may comprise delivering an amount of fuel to a fuel loading region, wherein the fuel loading region is located among a plurality of electrodes; igniting the fuel by flowing a current of at least about 2,000 A/cm 2 through the fuel by applying the current to the plurality of electrodes to produce at least one of plasma, light, and heat; receiving at least a portion of the light in a photovoltaic power converter; converting the light to a different form of power using the photovoltaic power converter; and outputting the different form of power.
  • the present disclosure is directed to a water arc plasma power system comprising: at least one closed reaction vessel; reactants comprising at least one of source of 3 ⁇ 40 and 3 ⁇ 40; at least one set of electrodes; a source of electrical power to deliver an initial high breakdown voltage of the 3 ⁇ 40 and provide a subsequent high current, and a heat exchanger system, wherein the power system generates arc plasma, light, aod thermal energy, and at least one photovoltaic power converter.
  • the water may be supplied as vapor on or across the electrodes.
  • the plasma may be permitted to expand into a low- pressure region of the plasma cell to prevent inhibition of the hydrino reaction due to confinement.
  • the arc electrodes may comprise a spark plug design.
  • the electrodes may comprise at least one of copper, nickel, nickel with silver chromate and zinc plating for corrosion resistance, iron, nickel-iron, chromium, noble metals, tungsten, molybdenum, yttrium, iridium, and palladium.
  • the water arc is maintained at low water pressure such as in at least one range of about 0.01 Torr to 10 Torr and 0.1 Torr to I Torr.
  • the pressure range may be maintained in one range of the disclosure by means of the disclosure for the SF-CIHT cell
  • Exemplary means to supply the water vapor are at least one of a mass flow controller and a reservoir comprising 3 ⁇ 4G such as a hydrated zeolite or a salt bath such as a KOH solution that off gases 3 ⁇ 40 at the desired pressure range.
  • the water may be supplied by a syringe pump wherein the delivery into vacuum results in the vaporization of the water.
  • Certain embodiments of the present disclosure are directed to a power generation system comprising: an electrical power source of at least about 2,000 A/cm 2 or of at least about 5,000 kW; a plurality of electrodes electrically coupled to the electrical power source; a fuel loading region configured to receive a solid fuel, wherein the plurality of electrodes is configured to deliver electrical power to the solid fuel to produce a plasma; and at least one of a plasma power converter, a photovoltaic power converter, and thermal to electric power converter positioned to receive at least a portion of the plasma, photons, and/or heat generated by the reaction.
  • a power generation system comprising: a plurality of electrodes; a fuel loading region located between the plurality of electrodes and configured to receive a conductive fuel, wherein the plurality of electrodes are configured to apply a current to the conductive fuel sufficient to ignite the conductive fuel and generate at least one of plasma and thermal power; a delivery mechanism for moving the conductive foe! into the fuel loading region; and at !easi one of a photovoltaic power converter to convert the plasma photons into a form of power, or a thermal to electric converter to convert the thermal power into a nonthermal Form of power comprising electricity or mechanical power.
  • Additional embodiments are directed to a power generation system, comprising: an electrical power source of at least about 5,000 kW; a plurality of spaced apart electrodes, wherein the plurality of electrodes at least partially surround a fuel, are electrically connected to the electrical power source, are configured to receive a current to ignite the fuel, and at least one of the plurality of electrodes is moveable; a delivery mechanism for moving the fuel; and a photovoltaic power converter configured to convert plasma generated from the ignition of the fuel into a non-plasma form of power.
  • a power generation system comprising: an electrical power source of at least about 2,000 A cm 2 ; a plurality of spaced apart electrodes, wherein the plurality of electrodes at least partially surround a fuel, are electrically connected to the electrical power source, are configured to receive a current to ignite the fuel, and at least one of the plurality of electrodes is moveable; a delivery mechanism for moving the fuel; and a photovoltaic power converter configured to convert plasma generated from the ignition of the fuel into a non-plasma form of power.
  • Another embodiments is directed to a power generation system, comprising: an electrical power source of at least about 5,000 kW or of at least about 2,000 A/cm 2 ; a plurality of spaced apart electrodes, wherein at least one of the plurality of electrodes includes a compression mechanism; a fuel loading region configured to receive a fuel, wherein the fuel loading region is surrounded by the plurality of electrodes so that the compression mechanism of the at least one electrode is oriented towards the fuel loading region, and wherein the plurality of electrodes are electrically connected to the electrical power source and configured to supply power to the fuel received in the fuel loading region to ignite the fuel; a delivery mechanism for ?moving the fuel into the fuel loading region; and a photovoltaic power converter configured to convert photons generated from the ignition of the fuel into a non-photon form of power.
  • a power generation system comprising: an electrical power source of at least about 2,000 A/cm 2 ; a plurality of spaced apart electrodes, wherein at least one of the plurality of electrodes includes a compression mechanism; a fuel loading region configured to receive a fuel, wherein the fuel loading region is surrounded by the plurality of electrodes so thai the compression mechanism of the at least one electrode is oriented towards the fuel loading region, and wherein the plurality of electrodes are electrically connected to the electrical power source and configured to supply power to the fuel received in the fuel loading region to ignite the fuel; a delivery mechanism for moving the fuel into the fuel loading region; and a plasma power converter configured to convert plasma generated from the ignition of the fuel into a non-plasma form of power.
  • Embodiments of the present disclosure are also directed to power generation system, comprising: a plurality of electrodes; a fuel loading region surrounded by the plurality of electrodes and configured to receive a fuel, wherein the plurality of electrodes is configured to ignite the fuel located in the fuel loading region; a delivery mechanism for moving the fuel into the fuel loading region; a photovoltaic power converter configured to convert photons generated from the ignition of the fuel into a non-photon form of power, a removal system for removing a byproduct of the ignited fuel; and a regeneration system operabiy coupled to the removal system for recycling the removed byproduct of the ignited fuel into recycled fuel.
  • Certain embodiments of the present disclosure are also directed to a power generation system, comprising: an electrical power source configured to output a current of at least about 2,000 A/cm 2 or of at least about 5,000 kW; a plurality of spaced apart electrodes electrically connected to the electrical power source; a fuel loading region configured to receive a fuel, wherein the fuel loading region is surrounded by the plurality of electrodes, and wherein the plurality of electrodes is configured to supply power to the fuel to ignite the fuel when received in the fuel loading region; a delivery mechanism for moving the fuel into the fuel loading region; and a photovoltaic power converter configured to convert a plurality of photons generated from the ignition of the fuel into a non-phoion form of power.
  • Certain embodiments may further include one or more of output power terminals operabiy coupled to the photovoltaic power converter; a power storage device; a sensor configured to measure at least one parameter associated with the power generation system; and a controller configured to control at least a process associated with the power generation system.
  • embodiments of the present disclosure are also directed to a power generation system, comprising: an electrical power source configured to output a current of a t least about 2,000 A/cm 2 or of at least about 5,000 kW; a plurality of spaced apart electrodes, wherein the plurality of electrodes at least partially surround a fuel, are electrically connected to the electrical power source, are configured to receive a current to ignite the fuel, and at least one of the plurality of electrodes is moveable; a delivery mechanism for moving the fuel; and a photovoltaic power converter configured to convert photons generated from the ignition of the fuel into a different form of power.
  • Additional embodiments of the presest disclosure are directed to a power generation system, comprising: an electrical power source of at least about 5,000 kW or of at least about 2,000 A/em 2 ; a plurality of spaced apart electrodes electrically connected to the electrical power source; a fuel loading region configured to receive a fuel, wherein the fuel loading region is surrounded by the plurality of electrodes, and wherein the plurality of electrodes is configured to supply power to the Fuel to ignite the Fuel when received in the fuel loading region; a delivery mechanism for moving the fuel into the fuel loading region; a photovoltaic power converter configured to convert a plurality of photons generated from the ignition of the fuel into a non-photon form of power; a sensor configured to measure at least one parameter associated with the power generation system; and a controller configured to control at least a process associated with the power generation system.
  • Certain embodiments of the present disclosure are directed to a power generation system, comprising: an electrical power source of at least about 5,000 kW or of at least about 2,000 A/cm 2 ; a plurality of spaced apart electrodes electrically connected to the electrical power source; a fuel loading region configured to receive a fuel, wherein the fuel loading region is surrounded by the plurality of electrodes, and wherein the plurality of electrodes is configured to supply power to the fuel to ignite the Fuel when received in the fuel loading region, and wherein a pressure in the fuel loading region is a partial vacuum; a delivery mechanism for moving the fuel into the fuel loading region; and a photovoltaic power converter configured to convert plasma generated from the ignition of the fuel into a non- plasma form of power.
  • the photovoltaic power converter may be located within a vacuum ceil; the photovoltaic power converter may include at least one of an antireflection coating, an optical impedance matching coating, or a protective coating; the photovoltaic power converter may be operabiy coupled to a cleaning system configured to clean at least a portion of the photovoltaic power converter; the power generation system may include an optical filter; the photovoltaic power converter may comprise at least one of a moaocrystalline cell, a poiycrystalline cell, an amorphous cell, a string ribbon silicon cell, a multi-junction cell, a homojunctioa cell, a heterojunction cell, a p-i-n device, a thin-film ceil, a dye-seositized cell, and an organic photovoltaic cell; and the photovoltaic power converter may comprise at multi-junction cell, wherein the muiti-junctioa ceil comprises at least one
  • Additional exemplary embodiments are directed to a system configured to produce power, comprising: a fuel supply configured io supply a fuel; a power supply configured to supply an electrical power; and at least one gear configured to receive the fuel and the electrical power, wherein the at least one gear selectively directs the electrical power to a local region about the gear to ignite the fuel within the local region.
  • the system may further have one or more of the following features: the fuel may include a powder; the at least one gear may include two gears; the at least one gear may include a first material and a second material having a lower conductivity than the first material, the first material being electrically coupled to the local region; and the local region may be adjacent to at least one of a tooth and a gap of the at least one gear.
  • Some embodiments are directed to a method of producing electrical power, comprising: supplying a fuel to rollers or a gear; rotating the rollers or gear to localize at least some of the fuel at a region of the rollers or gear; supplying a current to the roller or gear to ignite the localized fuel to produce energy; and converting at least some of the energy produced by the ignition into electrical, power, in some embodiments, rotating the rollers or gear may include rotating a first roller or gear and a roller or second gear, and supplying a current may include supplying a current to the first roller or gear and the roller or second gear.
  • a power generation system comprising: an electrical power source o f at least about 2,000 A/cm 2 ; a plurality of spaced apart electrodes electrically connected to the electrical power source; a fuel loading region configured to receive a fuel, wherem the fuel loading region is surrounded by the plurality of electrodes, and wherein the plurality of electrodes is configured to supply power to the fuel to ignite the fuel when received in the fuel loading region, and wherein a pressure in the fuel loading region is a partial vacuum; a delivery mechanism for moving the fuel into the fuel loading region; and a photovoltaic power converter configured to convert plasma generated from the ignition of the fuel into a non-plasma form of power.
  • a power generation system comprising: an electrical power source of at least about 5,000 A/cnr; a plurality of electrodes electrically coupled to the electrical power source; a fuel loading region configured to receive a water-based fuel comprising a majority 3 ⁇ 40, wherein the plurality of electrodes is configured to deliver power to the water-based fuel to produce at least one of an arc plasma and thermal power; and a power converter configured to convert at least a portion of at least one of the arc plasma and the thermal power into electrical power.
  • the power converter comprises a photovoltaic converter of optical power into electricity.
  • Additional embodiments are directed to a method of generating power, comprising: loading a fuel into a fuel loading region, wherein the fuel loading region includes a plurality of electrodes; applying a current of at least about 2,000 A/cm to the plurality of electrodes to ignite the fuel to produce at least one of an arc plasma and thermal power; perforating at least one of passing the arc plasma through a photovoltaic converter to generate electrical power; and passing the thermal power through a thermai-to-electric converter to generate electrical power; and outpurting at least a portion of the generated electrical power.
  • a power generation system comprising: an electrical power source of at least about 5,000 kW; a plurality of electrodes electrically coupled to the power source, wherein the plurality of electrodes is configured to deliver electrical power to a water-based fuel comprising a majority 3 ⁇ 40 to produce a thermal power; and a heat exchanger configured to convert at least a portion of the thermal power into electrical power; and a photovoltaic power converter configured to convert at least a portion of the light into electrical power.
  • another embodiment is directed to a power generation system, comprising: an electrical power source of at least about 5,000 kW; a plurality of spaced apart electrodes, wherein at least one of the plurality of electrodes includes a compression mechanism; a fuel loading region configured to receive a water-based fuel comprising a majority 3 ⁇ 4(), wherein the fuel loading region is surrounded by the plurality of electrodes so thai the compression mechanism of the at least one electrode is oriented towards the fuel loading region, and wherein the plurality of electrodes are electrically connected to the electrical power source and configured to supply power to the water-based fuel received in the fuel loading region to ignite the fuel; a delivery mechanism for moving the water-based fuel into the fuel loading region; and a photovoltaic power converter configured to convert plasma generated from the ignition of the fuel into a non-plasma form of power.
  • FIGURE 2G le4 is a schematic drawing of a phoioelectronic ceil of the transmission or senutransparent type in accordance with an embodiment of the present disclosure.
  • FIGURE 2GI e5 is a schematic drawing of a photoeleetronic eel! of the reflective or opaque type in accordance with an embodiment of the present disclosure.
  • FIGURE 2Gle6 is a schematic drawing of a photoelectronic cell of the reflective or opaque type comprising a grid anode or collector in accordance with an embodiment of the present disclosure.
  • FIGURE 2H1 is a schematic drawing of a SF-CIHT cell po was generator showing a eel! capable of maintaining a vacuum, an ignition system having a rai!gun shot injection system fed by two transporters, augmented plasma railgun and gravity recovery systems, a pelletizer, and a photovol taic converter system in accordance with an embodiment of the present disclosure.
  • FIGURE 2H2 is a schematic drawing of a SF-CIHT cell power generator showing the details of the ignition system and it power supply in accordance with an embodiment of the present disclosure.
  • FIGURE 2H3 is a schematic drawing of a SF-CiHT cell power generator showing a cell capable of maintaining a vacuum, an ignition system having a railgun shot injection system fed by two transporters, augmented plasma railgun and gravity a-ecovery systems, a pel letizer, and a photovoltaic converter system showing the details of the ignition system and the photovoltaic converter system in accordance with an embodiment of the present disclosure.
  • FIGURE 2H4 is a schematic drawing of a SF-CiHT cell power generator showing a ceil capable of maintaining a vacuum, an ignition system having a railgun shot injection system fed by two transporters, augmented plasma railgun and gravity recovery systems, a pelletizer, and a photovoltaic converter system showing the details of the ignition and injection systems, the ignition product recovery systems, and the pelletizer to form shot fuel in accordance with an embodiment of the present disclosure.
  • FIGURE 211 is a schematic drawing of a SF-CIHT cell power generator showing two views of a ceil capable of maintaining a vacuum, an ignition system having a railgun shot injection system fed directly from a pelletizer, augmented plasma railgun and gravity recovery systems, the pelletizer, and a photovoltaic converter system in accordance with an embodiment of the present disclosure.
  • FIGURE 212 is a schematic dra wing of a SF-CiHT cell power genera tor showing a cell capable of maintainmg a vacuum, an ignition system having a railgua shot Injection system fed directly from a pelletizer, augmented plasma railgun and gravity recovery systems, the pelletizer, and a photovoltaic converter system in accordance with an embodiment of the present disclosure.
  • FIGURE 2 ⁇ 3 is a schematic drawing of a SF-CIHT cell power generator showing a cell capable of maintaining a vacuum, an ignition system having a railgun shot injection system fed directly from a peiletizer, augmented plasma railgun and gravity recovery systems, the peiletizer, and a photovoltaic converter system showing the details of the railgun injector and ignition system and the photovoltaic converter system in accordance with an embodiment of the present disclosure.
  • FIGURE 2 ⁇ 4 is a schematic drawing of a SF-CIHT cell power generator showing a cell capable of maintaining a vacuum, an ignition system having a railgun shot injection system fed directly from a peiletizer, augmented plasma railgun and gravity recovery systems, the peiletizer, and a photovoltaic converter system showing the details of the injection system having a mechanical agitator, the ignition system, the ignition product recovery systems, and the peiletizer to form shot fuel in accordance with an embodiment of the present disclosure.
  • FIGURE 215 is a schematic drawing of a SF-CIHT cell power generator showing a cell capable of maintaining a vacuum, an ignition system having a railgun shot injection system fed directly from a peiletizer, augmented plasma railgun and gravity recovery systems, the peiletizer, and a photovoltaic converter system showing the detai ls of the injection system having a water jet agitator, the ignition system, the ignition product recovery systems, and the peiletizer to form shot fuel in accordance with an embodiment of the present disclosure.
  • FIGURE 2 ⁇ 6 is a schematic drawing of a SF-CIHT ceil power genera tor showing a cell capable of maintaining a vacuum, an ignition system having a railgun shot injection system fed directly from a peiletizer, augmented plasma railgun and gravity recovery systems, the peiletizer, and a photovoltaic converter system showing details of the injection system having a water slide single-file feed, the ignition system, the ignition product recovery systems, and the peiletizer to form shot fuel having an electromagnetic pump between vessels in accordance with an embodiment of the present disclosure.
  • FIGURE 2 ⁇ 7 is a schematic drawing of a SF-CIHT cell power generator showing the cross section of the peiletizer shown in FIGURE 216 in accordance with an embodiment of the present disclosure.
  • FIGURE 218 is a schematic drawing of a SF-CIHT cell power generator showing a ceil capable of maintaining a vacuum, an ignition system having an electromagnetic injection system fed directly from a peiletizer, augmented plasma railgun and gravity recovery systems, the peiletizer, and a photovoltaic converter system showing details of the injection system having a electromagnetic pump and nozzle, the ignition system, the ignition product recovery systems, and the peiletizer to form shot fuel in accordance with an embodiment of the present disclosure.
  • FIGURE 219 is a schematic drawing of a SF-CIHT cell power generator showing the cross section of the pelietizer shown in FIGURE 218 in accordance with an embodiment of the present disclosure.
  • FIGURE 2 ⁇ 0 is a schematic drawing of a SF-CIHT cell power generator showing a cell capable of maintaining a vacuum, an ignition system having stationary electrodes and an electromagnetic injection system fed directly from a pelietizer, augmented plasma railgun and gravity recovery systems, the pelietizer, and a photovoltaic converter system showing details of the injection system having a electromagnetic pump and nozzle, the stationary electrode ignition system, the ignition product recovery systems, and the pelietizer to form shot fuel in accordance with an embodiment of the present disclosure.
  • FIGURE 211 1 is a schematic drawing of a SF-CIHT cel l power generator showing the cross section of the pelietizer shown in FIGURE 2110 in accordance with an embodiment of the present disclosure.
  • FIGURE 2112 is a schematic drawing of a SF-CIHT cell power generator showing the electrodes and two cross sectional views of the electrodes shown in FIGURES 2110 aod 21 I I in accordance with an embodiment of the present disclosure.
  • FIGURE 2113 is a schematic drawing of a SF-CIHT cell power generator showing the cross section of the pelietizer shown in FIGURE 2110 having a pipe bubbler to introduce the gasses such as 3 ⁇ 4 and steam to the melt in accordance with an embodiment of the present disclosure.
  • FIGURE 2114 is a schematic drawing of a SF-CIHT eel! power generator showing the cross section of the pelietizer having a pipe bubbler in the second vessel to introduce the gasses such as H 2 and steam to the melt, two electromagnetic pumps, and a nozzle to inject shot into the bottom of the electrodes in accordance with an embodiment of the present disclosure.
  • FIGURE 2115 is a schematic drawing of a SF-CIHT cell power generator showing the electrodes with shot injection from the bottom in accordance with an embodiment of the present disclosure.
  • FIGURE 2116 is a schematic drawing of a SF-CIHT cell power generator showing the details of an electromagnetic pump in accordance with an embodiment of the present disclosure.
  • FIGURE 2117 is a schematic drawing of a SF-CIHT cell power generator showing the cross section of the pelietizer having a pipe bubbler in the second vessel to introduce the gasses such as H? and steam to the melt, two electromagnetic pumps, and a nozzle to inject shot into the top of the electrodes in accordance with an embodiment of the present disclosure.
  • FIGURE 211 8 is a schematic drawing of a SF-CIHT cell power generator showing the electrodes with shot injection from the top in accordance with an embodiment of the present disclosure.
  • FIGURE 2119 is a schematic drawing of a SF-CIHT cell power generator showing the cross section of the pelletizer having both a pipe bubbler in the cone reservoir and a direct injector to introduce the gasses such as 3 ⁇ 4 and steam to the melt, one electromagnetic pump, and a nozzle to inject shot into the bottom of the electrodes in accordance with an embodiment of the present disclosure.
  • FIGURE 2120 is a schematic drawing of a SF-CIHT cell power generator showing the electrodes with shot injection and gas injection such as 3 ⁇ 4 and steam injection from the bottom in accordance with an embodiment of the present disclosure.
  • FIGURE 212 is a schematic drawing of two foil views of the SF-CIHT cell power generator shown m FIGURE 2119 in accordance with an embodiment of the present disclosure.
  • FIGURE 2122 is a schematic drawing of a SF-CIHT cell power generator showing an electrode cooling system irs accordance with an embodiment of the present disclosure.
  • FIGURE 2123 is a schematic drawing of a SF-CIHT cell power generator showing two views of cells with passive photovoltaic converter cooling systems, active and passive electrode cooling systems, and gas getter systems in accordance with an embodi ment of the present disclosure.
  • FIGURE 2124 is a schematic drawing of at least one of a thermophotovoltaic, photovoltaic, photoelectric, thermionic, and thermoelectric SF-CIHT cell power generator showing a capacitor bank ignition system in accordance with an embodiment of the present disclosure.
  • FIGURE 2125 is a schematic drawing of an internal view of the SF-CIHT cell power generator shown in FIGURE 2124 in accordance with an embodiment of the present disclosure.
  • FIGURE 2126 is a schematic drawing of an internal view of the further details of the injection and ignition systems of the SF-CIHT cell power generator shown in FIGURE 2125 in accordance with an embodiment of the present disclosure.
  • FIGURE 2127 is a schematic drawing of an internal view of additional details of the injection and ignition systems of the SF-CIHT cell power generator shown in FIGURE 2126 in accordance with an embodiment of the present disclosure
  • FIGURE 2128 is a schematic drawing of magnetic yoke assembly of the
  • FIGURE 2127 is a schematic drawing of blade electrodes with end Fasteners and an electrode electromagnetic pump comprising a magnetic circuit in accordance with an embodiment of the present disclosure.
  • FIGURE 2 ⁇ 30 is a schematic drawing of a SF-CIHT cell power generator showing an optical distribution and the photovoltaic converter system in accordance with an embodiment of the present disclosure
  • FIGURE 213 1 is a schematic drawing of a SF-CIHT cell power generator showing details of an optical distribution and the photovoltaic converter system in accordance with an embodiment of the present disclosure.
  • FIGURE 2J is a schematic of a thermal power system in accordance with an embodiment of the present disclosure.
  • FIGURE 3 is the absolute spectrum in the 120 nm to 450 nm region of the ignition of a 80 mg shot of silver comprising absorbed 3 ⁇ 4 and 3 ⁇ 40 from gas treatment of silver melt before dripping into a water reservoir showing an average optical power of 527 kW, essentially all in the ultraviolet and extreme ultraviolet spectral region according to a fuel embodiment.
  • catalyst systems to release energy from atomic hydrogen to form lower energy states wherein the electron shell is at a closer position relative to the nucleus.
  • the released power is harnessed for power generation and additionally new hydrogen species and compounds are desired products.
  • These energy states are predicted by classical physical laws and require a catalyst to accept energy from the hydrogen in order to undergo the corresponding energy-releasing transition.
  • Atomic hydrogen may undergo a catalytic reaction with certain species, including itself, that can accept energy in integer multiples of the potential energy of atomic hydrogen, m - 27.2 eV, wherein m is an integer.
  • the predicted reaction involves a resonant, nonradiative energy transfer from otherwise stable atomic hydrogen to the catalyst capable of accepting the energy.
  • H(l/p) fractional Rydberg states of atomic hydrogen
  • Each hydrino state also comprises an electron, a proton, and a photon, but the field contribution from the photon increases the binding energy rather than decreasing it corresponding to energy desorpiion rather than absorption. Since the potential energy of atomic hydrogen is 27.2 eV, m H atoms serve as a catalyst of m ⁇ 27.2 eV for another ( m + l )th H atom [1].
  • a H atom can act as a catalyst for another H by accepting 27.2 eV from it via through-space energy transfer such as by magnetic or induced electric dipoie-dipole coupling to form an intermediate thai decays with the emission of
  • a molecule that accepts m ⁇ 27.2 eV from atomic H with a decrease in the magnitude of the potential energy of the molecule by the same energy may also serve as a catalyst.
  • the potential energy of H2O is 81 .6 eV. Then, by the same mechanism, the nascent
  • H 2 O molecule (not hydrogen bonded In solid, liquid, or gaseous state) formed by a
  • thermodynarnical ly favorable reduction of a metal oxide is predicted to serve as a catalyst to form ( ⁇ / 4 ) with an energy release of 204 eV, comprising an 81.6 eV transfer to HOH and a j-elease of continuum radiation with a cutoff at 10.1 run (122.4 eV).
  • H atoms serve as a catalyst of m ⁇ 27.2 eV for another ( in + 1 )th H atom. Then, the reaction between m + l hydrogen atoms whereby m atoms resonantly and nonradiatively accept m ⁇ 27,2 eV from the (m + 1 )th hydrogen atom such that mH serves as the catalyst is given in ⁇ 27.2 e V + mH ⁇ II— mi + me + H + m - 27.2 eV 0)
  • H * is formed having the radius of the H atom and a centra! field of m + 1 times the m + 1 central field of a proton.
  • the radius is predicted to decrease as the electron undergoes acceleration to a stable state having a radius of i/(m + 1) the radius of the o catalyzed hydrogen atom, with the release of m 2 ⁇ ] 3.6 eV of energy.
  • the extreme-ultraviolet continuum radiation band due to the H * intermediate (e.g. Eq. (2) and Eq. (6)) is
  • n integer in the ydberg equation for hydrogen excited states and represent lower-energy-state hydrogen atoms called "hydrinos.”
  • n integer in the ydberg equation for hydrogen excited states and represent lower-energy-state hydrogen atoms called "hydrinos.”
  • the n - 1 state of hydrogen and the n ⁇ ⁇ states of hydrogen are nonradiative, but a transition between
  • the catalyst reactions involve two steps of energy release: a nonradiative energy traosfer to the catalyst followed by additional energy release as the radius decreases to the corresponding stable final state.
  • a nonradiative energy traosfer to the catalyst followed by additional energy release as the radius decreases to the corresponding stable final state.
  • H has the radius of the hydrogen atom
  • the catalyst product, ⁇ I p) may also react with an electron to form a hydrino hydride ion H ⁇ [l i ?) , or two Hi .
  • I p ⁇ may react to form the corresponding molecular hydrino H, L ⁇ I p) ,
  • the catalyst product, H ⁇ I p ⁇ may also react with an electro
  • hydride ion is 0.7541 8 eV , and the experimental value is 6082.99 ⁇ 0.15 cnf (0.75418 eV).
  • the binding energies of hydrino hydride ions may be measured by X-ray photoelectron spectroscopy (XPS).
  • Upfie Id- shifted NMR peaks are direct evidence of the existence of lower-energy state hydrogen with a reduced radius relative to ordinary hydride ion and having an increase in diamagnetic shielding of the proton.
  • the shift is given by the sum of the contributions of the diamagnetism of the two electrons and the photon field of magnitude p (Mills GUTCP Eq.
  • the predicted hydrino hydride peaks are extraordinarily upfieid shifted relative to ordinary hydride ion. In an embodiment, the peaks are upfieid of TMS.
  • the NMR shift relative to TMS may be greater than thai known for at least one of ordinary ⁇ " , ⁇ , 3 ⁇ 4, or ⁇ " alone or comprising a compound.
  • the shift may be greater than at least one of 0, - 1 , -2, -3, -4, -5, -6, -7, -8, -9, - 10, - 1 1 , -12, -13, -14, -15, - 16, -17, -18, -19, -20, -21 , - 22, -23, -24, -25, -26, -27, -28, -29, -30, -31, -32, -33, -34, -35, -36, -37, -38, -39, and -40 ppm.
  • the range of the absolute shift relative to a bare proton, wherein the shift of TMS is about -31.5 relative to a bare proton, may be -(p29.9 + p 2 2.74) ppm (Eq, (20)) within a range of about at least one of ⁇ 5 ppm, ⁇ 10 ppm, ⁇ 20 ppm, ⁇ 30 ppm, ⁇ 40 ppm, ⁇ 50 ppm, ⁇ 60 ppm, ⁇ 70 ppm, ⁇ 80 ppm, ⁇ 90 ppm, and ⁇ 00 ppm.
  • the range of the absolute shift relative to a bare proton may be -(p29.9 + p 2 1.59 X 30 "3 ) ppm (Eq. (20)) within a range of about at least one of about 0,1% to 99%, 1% to 50%, and 1% to 10%.
  • ppm Eq. (20)
  • the presence of a hydrino species such as a hydrino atom, hydride ion, or molecule in a solid matrix such as a matrix of a hydroxide such as NaOH or KOH causes the matrix protons to shift upfield.
  • the matrix protons such as those of NaOH or KOH may exchange, in an embodiment, the shift may cause the matrix peak to be in the range of about -0.1 ppm to -5 ppm relative to TMS.
  • the N R determination may comprise magic angle spinning ⁇ nuclear magnetic resonance spectroscopy (MAS 'H R).
  • H(l / p) may react with a proton and two H(l / >) may react to form H, (l / p) and H ⁇ ⁇ I j , respectively.
  • the hydrogen molecular ion and molecular charge and current density functions, bond distances, and energies were solved from the Laplacian in ellipsoidal coordinates with the constraint of nonradiation.
  • the total energy E T of the hydrogen molecular ion having a central field of +pe at each focus of the prolate spheroid molecular orbital is
  • the bond dissociation energy, ⁇ ⁇ , of the hydrogen molecule H 2 (l / p) is the difference between the iota! energy of the corresponding hydrogen atoms and E T
  • H 2 (l / p) may be identified by X-ray photoelectron spectroscopy (XPS) wherein the ionization produci in addition to the ionized electron may be at least one of the possibilities such as those comprising two protons and an electron, a hydrogen ( ⁇ ) atom, a hydrino atom, a molecular ion, hydrogen molecular ion, and H 2 (l / p) wherein the energies may be shifted by the matrix.
  • XPS X-ray photoelectron spectroscopy
  • the experimental absolute H 2 gas-phase resonance shift of -28.0 ppm is in excellent agreement with the predicted absolute gas-phase shift of -28.01 ppm (Eq. (28)).
  • molecular hydrino peaks are extraordinarily iipfield shifted relative to ordinary 3 ⁇ 4.
  • the peaks are upfield of TMS.
  • the NMR shift relative to TMS may be greater than thai known for at least one of ordinary FT. ⁇ , 3 ⁇ 4, or FT alone or comprising a
  • the shift may be greater than at least one of 0, -1, -2, -3, -4, -5, -6, -7, -8, -9, -10, - 1 1 , -12, -13, - 14, -15, -16, - 17, - 18, - 19, -20, -21, -22, -23, -24, -25, -26, -27, -28, -29, -30, - 3 1 , -32, -33, -34, -35, -36, -37, -38, -39, and -40 ppm.
  • the range of the absolute shift relative to a bare proton may be -(p28.01 + p " 2.56) ppm (Eq. (28)) within a range of about at least one of ⁇ 5 ppm, ⁇ 10 ppm, ⁇ 20 ppm, ⁇ 30 ppm, ⁇ 40 ppm, ⁇ 50 ppm, ⁇ 60 ppm, ⁇ 70 ppm, ⁇ 80 ppm, ⁇ 90 ppm, and ⁇ 100 ppm.
  • the range of the absolute shift relative to a bare proton may be - (p28.01 + p l .49 X 10 "3 ) ppm (Eq. (28)) within a range of about at least one of about 0.1% to 99%, 1 % to 50%, and 1 % to 10%.
  • At least one of the rotational and vibration energies of 3 ⁇ 4( l /p) may be measured by at least one of electron-beam excitation emission spectroscopy, Raman spectroscopy, and
  • FTIR Fourier transform infrared
  • the molecular hydrino product is observed as an inverse Raman effect (IRE) peak at about 1950 cm "1 .
  • the peak is enhanced by using a conductive material comprising roughness features or particle size comparable to that of the Raman laser wavelength that supports a Surface Enhanced Raman Scattering (SERS) to show the IRE peak.
  • SERS Surface Enhanced Raman Scattering
  • hydrino reaction H catalysis, H catalysis reaction, catalysis when referring to hydrogen, the reaction of hydrogen to form hydrinos, and hydrino formation reaction all refer to the reaction such as that of Eqs. ( 15-18)) of a catalyst defined by Eq. (14) with atomic H to form states of hydrogen having energy levels given by Eqs. (10) and (12).
  • hydrino reaetants such as hydrino reaetants, hydrino reaction mixture, catalyst mixture, reactanis for hydrino formaiion, reaetants that produce or form lower-energy state hydrogen or hydrinos are also used interchangeably when referring to the reaction mixture that performs the catalysis of H to H states or hydrino states having energy levels given by Eqs. (10) and (12).
  • the catalytic lower-energy hydrogen transitions of the present disclosure require a catalyst that may be in the form of an endothermic chemical reaction of an integer in of the potential energy of uncatalyzed atomic hydrogen, 27.2 eV , that accepts the energy from atomic H to cause the transition.
  • He' fulfills the catalyst criterion— a chemical or physical process with an enthalpy change equal to an integer multiple of 27.2 eV since it ionizes at 54.417 eV , which is 2 ⁇ 27,2 eV .
  • An integer number of hydrogen atoms may also serve as the catalyst of an integer multiple of 27.2 eV enthalpy, catalyst is capable of accepting energy from atomic
  • the catalyst comprises an atom or ion M wherein the ionization of t electrons from the atom or ion M each to a continuum energy level is such that the sum of ionization energies of the t electrons is approximately one of m » 27.2 eV and
  • the catalyst comprises a diatomic molecule MB wherein the breakage of the M-H bond plus the ionization of ( electrons from the atom M each to a continuum energy level is such thai the sum of the bond energy and ionization energies of the
  • / electrons is approximately one of #2 - 27.2 eV and m ⁇ eV where m is an integer.
  • the catalyst comprises atoms, ions, and/or molecules chosen from molecules of A1H, AsH, BaH, Bill, CdH, C1H, CoH, GeH, InH, NaH, bH, OH, RhH, RuH, SH, SbH, SeH, SiH, SnH, SrH, T1H, C, , N 2 , 0 2 , C0 2 , N0 2 , and NO i and atoms or ions of
  • ⁇ " type hydrogen catalysts to produce hydrinos provided by the transfer of an electron to an acceptor A, the breakage of the ⁇ - ⁇ bond plus the ionization of t electrons from the atom M each to a continuum energy level such that the sum of the electron transfer energy comprising the difference of electron affinity (EA) of ⁇ and A, M- ⁇ bond energy, and ionization energies of the / electrons from M is approximately
  • MH " type hydrogen catalysts to produce hydrinos are provided by the transfer of an electron from an donor A which may be negatively charged, the breakage of the M-H bond, and the ionization of / electrons from the atom M each to a continuum energy level such that the sum of the electron transfer energy comprising the difference of ionization energies of MH and A, bond M-H energy, and ionization energies of the / electrons from M is approximately m - 27,2 e ⁇ where m is an integer.
  • At least one of a molecule or positively or negatively charged molecular ion serves as a catalyst that accepts about m27.2 eV from atomic H with a decrease in the magnitude of the potential energy of the molecule or positively or negatively charged molecular ion by about m27.2 eV.
  • exemplary catalysts are 3 ⁇ 40, OH, amide group NH 2 , and H 2 S.
  • O2 may serve as a catalyst or a source of a catalyst.
  • the bond energy of the oxygen molecule is 5.165 eV
  • the fust, second, and third ionization energies of an oxygen atom are 13.61806 eV , 35.1 1730 eV , and 54.9355 eV , respectively.
  • the binding energy of an atom, ion, or molecule also known as the ionijzation energy, is the energy required to remove one electron from the atom, ion or molecule.
  • a hydrogen atom having the binding energy given in Eqs. (10) and (12) is hereafter referred to as a "hydrino atom" or "hydrino.”
  • a hydrogen atom with a radius a H is hereinafter referred to as "ordinary hydrogen
  • Ordinary atomic hydrogen is characterized by its binding energy of 13.6 eV.
  • the hydride ion binding energies are respectively 3, 6.6, 1 1 .2, 16.7, 22,8, 29.3, 36.1 , 42.8, 49.4, 55.5, 61 .0, 65.6, 69.2, 71.6, 72.4, 71.6, 68.8, 64.0, 56.8, 47. 1 , 34,7, 19.3, and 0.69 eV.
  • Exemplary compositions comprising the novel hydride ion are also provided herein.
  • Exemplary compounds are also provided comprising one or more hydrino hydride ions and one or more other elements. Such a compound is referred to as a "hydrino hydride compound.”
  • Ordinary hydrogen species are characterized by the following binding energies (a) hydride ion, 0.754 eV ("ordinary hydride ion”); (b) hydrogen atom ("ordinary hydrogen atom"), 13,6 eV; (c) diatomic hydrogen molecule, 15.3 eV ("ordinary hydrogen molecule”); (d) hydrogen molecular ion, 16.3 eV ("ordinary hydrogen molecular ion”); and (e) , 22.6 eV ("ordinary trihydrogen molecular ion”)-
  • binding energies (a) hydride ion, 0.754 eV (“ordinary hydride ion”); (b) hydrogen atom ("ordinary hydrogen atom"), 13,6 eV; (c) diatomic hydrogen molecule, 15.3 eV (“ordinary hydrogen molecule”); (d) hydrogen molecular ion, 16.3 eV (“ordinary hydrogen molecular ion”); and (e) , 22.6 eV ("ordinary trihydrogen molecular ion”)-
  • a compound comprising at least one increased binding energy hydrogen species such as (a) a hydrogen
  • Binding Energy -- such as
  • eV such as within a range of about 0.9 to ! . 1 times——— - eV where p is an integer
  • a compound comprising at least one increased binding energy hydrogen species such as (a) a dihydrino molecular ion having a total energy of about
  • cr ⁇ is the Bohr radius
  • the compound comprises a negatively charged increased binding energy hydrogen species
  • the compound further comprises one or more cations, such as a proton, ordinary H* , or ordinary H* .
  • a method for preparing compounds comprising at least one hydrino hydride ion. Such compounds are hereinafter referred to as "hydrino hydride compounds.”
  • the method comprises reacting atomic hydrogen with a catalyst having a net m
  • enthalpy of reaction of about y 27 eV , where m is an integer greater than 1 , preferably an integer less than 400, to produce an increased binding energy hydrogen atom having a
  • binding energy of about - where p is an integer, preferably an integer from 2 to 137.
  • a further product of the catalysis is energy.
  • the increased bindiag energy hydrogen atom can be reacted with an electron source, to produce an increased binding energy hydride ion.
  • the increased bindiag energy hydride ion caa be reacted with one or more cations to produce a compound comprising at least one increased binding energy hydride ion.
  • novel hydrogen compositions of matter can comprise:
  • other element in this context is meant an element other than an increased binding energy hydrogen species.
  • the other element can be an ordinary hydrogen species, or any element other than hydrogen.
  • the other element and the increased binding energy hydrogen species are neutral.
  • the other element and increased binding energy hydrogen species are charged such that the other element provides the balancing charge to form a neutral compound.
  • the former group of compounds is characterized by molecular and coordinate bonding; the latter group is characterized by ionic bonding.
  • novel compounds and molecular ions comprising
  • the total energy of the hydrogen species is the sum of the energies to remove ail of the electrons from the hydrogen species.
  • the hydrogen species according to the present disclosure has a total energy greater than the total energy of the corresponding ordinary hydrogen species.
  • the hydrogen species having an increased iota! energy according to the present disclosure is also referred to as an "increased binding energy hydrogen species" even though some embodiments of the hydrogen species having an increased total energy may have a first electron binding energy less that she first electron binding energy of the corresponding ordinary hydrogen species.
  • the compounds of the present disclosure are hereinafter referred to as "increased binding energy hydrogen compounds.”
  • the increased binding energy hydrogen species can be formed by reacting one or more hydrino atoms with one or more of an electron, hydrino atom, a compound containing ai least one of said increased binding energy hydrogen species, and at least one other atom, molecule, or ion other than an increased binding energy hydrogen species.
  • novel compounds and molecular ions comprising
  • increased binding energy hydrogen species chosen from (a)
  • the present disclosure is also directed to other reactors for producing increased binding energy hydrogen species and compounds of the present disclosure, such as dihydri o molecules and hydrino hydride compounds. Further products of the catalysis are power aod optionally plasma and light depending on the cell type.
  • a reactor is hereinafter referred to as a "hydrogen reactor” or "hydrogen cell/'
  • the hydrogen reactor comprises a cell for making hydrinos.
  • the cell for making hydrinos may take the form of a chemical reactor or gas fuel cell such as a gas discharge cell, a plasma torch cell, or microwave power ceil, and an electrochemical cell.
  • the catalyst is HOH and the source of at least one of the HOH aod H is ice.
  • the cell comprises an arc discharge cell and that comprises ice at least one electrode such thai the discharge involves at least a portion of the ice.
  • the arc discharge cell comprises a vessel, two electrodes, a high voltage power source such as one capable of a voltage in the range of about 100 V to I MV and a current in the range of about J A to 1 00 kA, and a source of water such as a reservoir and a means to form and supply H 2 0 droplets.
  • the droplets may travel between the electrodes, in an embodiment, the droplets initiate the ignition of the arc plasma.
  • the water arc plasma comprises H and HOH thai may react to form hydrinos.
  • the ignition rate and the corresponding power rate may be controlled by controlling the size of the droplets and the rate at which they are supplied to the electrodes.
  • the source of high voltage may comprise at Least one high voltage capacitor that may be charged by a high voltage power source.
  • the arc discharge ceil further comprises a means such as a power converter such as one of the present invention such as at least one of a PV converter and a heat engine to convert the power from the hydrino process such as light and heat to electricity.
  • Exemplary embodiments of the cell for making hydrinos may take the form of a liquid-fuel cell, a solid-fuel cell, a heterogeneous-fuel cell, a CIHT cell, and an SF-CIHT cell.
  • Each of these cells comprises: (i) a source of atomic hydrogen; (ii) at least one catalyst chosen from a solid catalyst, a molten catalyst, a liquid catalyst, a gaseous catalyst, or mixtures thereof for making hydrinos; and (in) a vessel for reacting hydrogen and the catalyst for making hydrinos.
  • the term "hydrogen.” unless specified otherwise, includes not only proteurn ( !
  • Exemplary chemical reaction mixtures and reactors may comprise SF-CIHT, CIHT, or thermal ceil embodiments of the present disclosure. Additional exemplary embodiments are given in this Chemical Reactor section. Examples of reaction mixtures having HjO as catalyst formed during the reaction of the mixture are given in the present disclosure. Other catalysis may serve to form increased binding energy hydrogen species and compounds.
  • the reactions and conditions may be adjusted from these exemplary cases in the parameters such as the reactants, reactant wt% ! s, 3 ⁇ 4 pressure, and reaction temperature. Suitable reactants, conditions, and parameter ranges are those of the present disclosure.
  • Hydrinos and molecular hydrino are shown to be products of the reactors of the present disclosure by predicted continuum radiation bands of an integer times 13.6 eV, otherwise unexplainable extraordinarily high H kinetic energies measured by Doppler line broadening of H lines, inversion of H lines, formation of plasma without a breakdown fields, and anomalously plasma afterglow duration as reported in Mills Prior Publications.
  • the data such as that regarding the CIHT cell and solid fuels has been validated independently, off site by other researchers.
  • the formation of hydrinos by cells of the present disclosure was also confirmed by electrical energies that were continuously output over long-duration, that were multiples of the electrical input that in most cases exceed the input by a factor of greater than 10 with no alternative source.
  • Embodiments of solid fuels comprise energetic solid fuels such as those comprising reactants capable of high exothermic power such pyrotechnics, explosives, and propeilants such as those comprising the CHNO system that produce H and HOH.
  • the energetic solid fuels may comprise at least one of (i) a source of powerful exothermic reaction such a pyrotechnics, explosives, and propeilants, (ii) a source of atomic H such as a decomposition reaction such as a hydride decomposition, a CHNO compound decomposition, or a reaction of H 2 0 with a metal and (iii) a source of nascent HOH such as a source of low pressure HOH or HOH formed as a reaction product.
  • the source of low pressure HOH may comprise at least one of a low temperature source of HOH such as chilled water or ice.
  • the solid fuel such as a conventional explosive or pyrotechnic compound may be confined in ice.
  • the contact area may be maximized.
  • the contact area may be increased by filling the solid fuel into holes in the ice.
  • the ice may a!so provide confinement
  • Other exemplary low temperature source of HOH such as chilled water or ice.
  • temperature sources of HOH comprise a hydrate that dehydrates upon heating or reaction, a source of bound or absorbed water such as a hydrated zeolite, and a chemical that decomposes to HOH such as ammonium nitrate or other CHNO explosive.
  • the source of HOH may comprise a hydroscopic compound, Suitable hydroscopic salts are lithium bromide, calcium chloride, magnesium chloride, zinc chloride, potassium carbonate, potassium phosphate, carnallite such as KMgCl.r6(H20), ferric ammonium citrate, potassium hydroxide and sodium hydroxide.
  • Exemplar ' energetic materials comprise the reaction mixture of Al power + CuO powder impregnated in pores in crystalline ice with a large contact surface area with the ice, the reaction mixture of Al power + CuO powder + KOH and C1, and the reaction mixture of Al power + CuO powder + FrBr 2 + Cu(OH) 2 .
  • the source of HOH may comprise a compound that decomposes to release at least one of H and 3 ⁇ 40 such as a carbohydrate such as a sugar or hydrocarbon such as diesei fuel.
  • the source of HOH may comprise a material comprising absorbed water such as wetted zeolite that may serve as a source of low pressure 3 ⁇ 40 in the thermite reaction.
  • hydroscopic electrolytes comprise concentrated sulfuric and phosphoric acids.
  • a specific exemplary energetic solid fuel to farm hydrinos comprises a mixture of thermite and ice wherein atomic H and low pressure HOH are formed to produce hydrinos with rapid kinetics that forms a shock wave.
  • An exemplary thermite reaction mixture comprises a mixture of metal powder and an oxidant metal ox ide such as a mixture of Al or Mg powder and Fe 2 03 or CuO powder. The metal powder may be in excess.
  • the solid fuel reaction mixture may comprise excess reductant such as excess Al of the thermite reaction mixture to react with ice to form H and HOH catalyst with intense heat for the hydrino reaction initiation and propagation from the oxidation-reduction reaction between the metal and the metal oxide.
  • the mole percentage of metal of the metal-metal oxide reaction mixture may be in at least one range of about 51% to 99%, 55% to 80%, and 60% to 75%.
  • the reaction may be initiated by heating with a heat source such as an electrical or chemical heat source.
  • a fuse may comprise the initiator heat source.
  • low temperature may limit the H 2 G vapor pressure to favor HOH formation.
  • the Type I ice structure may also enhance the hydrino reaction rate, ice may sublime directly to HOH catalyst rather than water dimers that will increase the hydrino rate.
  • the mechanism may comprise energetic bombardment of the solid surface.
  • the solid fuel reaction mixture to form hydrinos comprises ice as a source of at least one of H and HOH.
  • the ice may be in a physical form to provide a high surface area such as ice crystals that may be injected Into a propagating highly exothermic reaction, in addition to high power release, the reaction mixture may comprise reactants that react with water such as that from the ice to form some hydrogen.
  • Suitable react mixtures comprise a pyrotechnic such as one comprising an oxidant and a reductaot such as a mixture of metal oxide and metal powders such as a thermite reaction mixture.
  • the ice may a!so be supplied as pressurized capsules containing water under the conditions that maintain the Type ⁇ ice structure until the walls are breached by the highly exothermic reaction.
  • ice is impacted and impregnated into the exothermic reaction mixture while it is propagating. The impacting and impregnation may be performed morjarcbically or pneumatically.
  • the mechanical means may comprise an electromagnetic, spring loaded, piezoelectric, or other mechanical drive comprising a primary mover such as a cam, piston, or other such means of the disclosure or known in the art.
  • the pneumatic drive may comprise a gas driven piston or other such means known in the art.
  • the impregnation may be performed extremely rapidly such as explosively.
  • the surface area of the ice may be very large.
  • the ice may comprise ice crystals.
  • the ice crystals may be accelerated with an explosive charge.
  • the ice crystals may be formed by an explosive charge into ice.
  • the solid fuel is encased to cause confinement of the hydrino reaction. The confinement may be achieved using ice. ice may encase the reaction mixture.
  • the mechanism of shock wave formation involves one di fferent than that of energetic materials wherein the latter produce a large volume of gaseous products.
  • the reaction of metals with ice to produce ⁇ and H does not yield a substantial gaseous fraction.
  • the product of metal oxidation is not a gas, and metal vaporization to produce a substantial partial pressure is highly unfavorable energetically.
  • the hydrino-reaciion shock wave mechanism may be the rapid local superheating of air by the short-wavelength IJV and EIJV light emitted by the hydrino reaction.
  • a nuclear reaction has a similar mechanism involving efficient coupling of emitted X-rays with air to form a shock wave.
  • An exemplary embodiment comprises t errnite, comprising Fe 2 OrA! powder with 2 to 3 relative weights and the reaction mixture in a metal container embedded in ice.
  • thermite melts through the metal container to interface the ice wherein the excess A! reacts to form HOH and H in the absence of an inhibiting about of water vapor.
  • the violent explosion that ensues is due to hydrino formation thai releases brilliant light. The light superheats the air, and a shock wave capable of braking concrete is released.
  • the energetic reactants, H sources, and HOH sources and systems may comprise those of the present disclosure or in prior US Patent Applications such as Hydrogen Catalyst Reactor, PCT/US08/61455, filed PCT 4/24/2008; Heterogeneous Hydrogen Catalyst Reactor, PCT/US09/G52Q72, filed PCT 7/29/2009; Heterogeneous Hydrogen Catalyst Power System, PCT/US 10/27828, PCT filed 3/18/2010; Electrochemical Hydrogen Catalyst Power System, PCT/US 1 1/28889, filed PCT 3/17/201 1 ; H 2 0-Based Electrochemical Hydrogen-Catalyst Power System, PCT/US 12/3 1369 filed 3/30/2012; CIHT Power System, PCT/ US 13/041938 filed 5/21/13; Power Generation Systems and Methods Regarding Same,
  • the energetic reaction mixture comprises a source of H and a source of catalyst such as at least one of nH (n is an integer) and HOH.
  • nH and HOH may be formed by the thermolysis or thermal decomposition of at least one physical phase of water such as at least one of solid, liquid, and gaseous water.
  • the thermolysis may occur at high temperature such as a temperature in at least one range of about 500K to ⁇ , ⁇ , 1QQ0K to 700GK, and !OOOK to 5000 .
  • the reaction temperature is about 3500 to 4000K such that the mole fraction of atomic H is high as shown by I. Lede, F. Lapicque, arid J Viiiermaux [J, Lede, F, Lapicque, J, Viiiermaux, "Production of hydrogen by direct thermal decomposition of water", International Journal of Hydrogen Energy, 1 83, Vf,. 1983, pp. 675-679; H. H. G. Jel linek, H.
  • thermolysis gases may be cooled to prevent recombination or the back reaction of the products into the starting water.
  • the reaction mixture may comprise a cooling agent such as at least one of a solid, liquid, or gaseous phase that is at a lower temperature than the temperature of the product gases.
  • the cooling of the thermolysis reaction product gases may be achieved by contacting the products with the cooling agent.
  • the cooling agent may comprise at least one of lower temperature sieara, water, and ice,
  • the thermolysis temperature may be created and maintained by an exothermic reaction of the reaction mixture such as the exothermic reaction of at least one of an explosive, propellant, or pyrotechnic such as at least one of those known in the art and disclosed in Mills Prior Applications.
  • An exemplary reaction to produce a temperature to cause thermolysis of water is the oxidation of metal to form multiple highly stable products such as the reaction of CaS0 4 with Al to form CaS and AI2O3.
  • Other exemplary exothermic reactions to cause the energetic material to explode are given by S. H. Fischer and M. C, GrubeSich [S, H. Fischer and M. C.
  • a power system that generates at least one of direct electrical energy and thermal energy comprises at least one vessel, reactants comprising: (a) at least one source of catalyst or a catalyst comprising nascent 3 ⁇ 40; (b) at least one source of atomic hydrogen or atomic hydrogen; and (c) at least one of a conductor and a conductive matrix, and at least one set of electrodes to confine the hydrino reactants, a source of electrical power to deliver a short burst of high-current electnca!
  • the vessel is capable of a pressure of at least one of atmospheric, above atmospheric, and below atmospheric.
  • the regeneration system can comprise at least one of a hydration, thermal, chemical, and electrochemical system.
  • the at least one direct plasma to electricity converter can comprise at least one of the group of plasmadynamic power converter, E x B direct converter, magnetohydrodyoarmc power converter, magnetic mirror magnetohydrodynamic power converter, charge drift converter, Post or Venetian Blind power converter, gyrotron, photon bunching microwave power converter, and photoelectric converter.
  • the at least one thermal to electricity converter can comprise at least one of the group of a heat engine, a steam engine, a steam turbine and generator, a gas turbine and generator, a Rankine- cycle engine, a Brayton- cycle engine, a Stirling engine, a thermionic power converter, and a thermoelectric power converter.
  • the converter may be one given in Mills Prior Publications and Mills Prior Applications,
  • HjO is ignited to form hydrinos with a high release of energy in the form of at least one of thermal, plasma, and electromagnetic (light) power.
  • ition in the present disclosure denotes a very high reaction rate of H to hydrinos that may be manifest as a burst, pulse or other form of high power release.
  • 3 ⁇ 40 may comprise the fuel that may be ignited with the application a high current such as one in the range of about 2000 A to 100,000 A. This may be achieved by the application of a high voltage such as about 5,000 to 100.000 V to first form highly conducive plasma such as an arc.
  • a high current may be passed through a compound or mixture comprising 3 ⁇ 40 wherein the conductivity of the resulting fuel such as a solid fuel is high.
  • a solid fuel is used to denote a reaction mixture that forms a catalyst such as HOH and H that further reacts to form hydrinos.
  • the reaction mixture may comprise other physical states than solid.
  • the reaction mixture may be at least one state of gaseous, liquid, molten matrix such as molten conductive matrix such a molten metal such as at least one of molten silver, silver-copper alloy, and copper, solid, slurry, sol gel, solution, mixture, gaseous suspension, pneumatic flow, and other states known to those skilled in the art.
  • the solid fuel having a very low resistance comprises a reaction mixture comprising H 2 0. The low resistance may be due to a conductor component of the reaction mixture.
  • the resistance of the solid fuel is at least one of in the range of about 10 "3 ⁇ 4 ohm to 100 ohms, 10 "8 ohm to 10 ohms, 10 ' * ohm to 1 ohm, 30 "4 ohm to 10 "! ohm, and 10 "4 ohm to 10 " 2 ohro.
  • the fuel having a high resistance comprises 3 ⁇ 40 comprising a trace or mirsor mole percentage of an added compound or material. In the latter case, high current may be flowed through the fuel to achieve ignition by causing breakdown to form a highly conducting state such as an arc or arc plasma.
  • the reactants can comprise a source of H 2 0 and a conductive matrix to form at least one of the source of catalyst, the catal st, the source of atomic hydrogen, and the atomic hydrogen
  • the reactants comprising a source of 3 ⁇ 40 can comprise at least one of bulk H2O, a state other than bulk H2O, a compound or compounds that undergo at least one of react to form H 2 O and release bound H 2 O.
  • the bound 3 ⁇ 40 can comprise a compound thai interacts with H 3 ⁇ 4 0 wherein the H 2 O is In a state of at least one of absorbed bound 3 ⁇ 4Q, physisorbed H 2 O, and waters of hydration
  • the reactants can comprise a conductor and one or more compounds or materials that undergo at least one of release of bulk 3 ⁇ 40, absorbed 3 ⁇ 40, bound H 2 O, physisorbed 3 ⁇ 4G, and waters of hydration, and have H 2 O as a reaction product
  • the at least one of the source of nascent H2O catalyst and the source of atomic hydrogen can comprise at least one of: (a) at least one source of 3 ⁇ 40; (b) at least one source of oxygen, and (c) at least one source of hydrogen.
  • the hydrino reaction rate is dependent on the application or development of a high current.
  • the reactants to form hyd inos are subject to a low voltage, high current, high power pulse that causes a very rapid reaction rate and energy release.
  • a 60 Hz voltage is less than 15 V peak
  • the current ranges from 10,000 A/cm 2 and 50,000 A/cm 2 peak
  • the power ranges from 150,000 W/cm 2 and 750,000 W/cm z .
  • Other frequencies, voltages, currents, and powers in ranges of about 1/100 times to 100 times these parameters are suitable.
  • the hydrino reaction rate is dependent on the application or development of a high current.
  • the voltage is selected to cause a high AC, DC, or an AC- DC mixture of current that is in the range of at least one of 100 A to 1 ,000,000 A, 1 kA to 100,000 A, 10 kA to 50 kA
  • the DC or peak AC current density may be in the range of at least one of 100 A/cm 2 to 1,000,000 A/cm 2 , 1000 A/cm 2 to 100,000 A cm 2 , and 2000 A7cm 2 to 50,000 A/cm 2 .
  • the DC or peak AC voltage may be in at least one range chosen from about 0. 1 V to 1000 V, 0.1 V to 100 V, 0.1 V to 15 V, and 1 V to 15 V.
  • the AC frequency may be in the range of about 0.1 Hz to 10 GHz, I Hz to 1 MHz, 10 Hz to 100 kHz, and 100 Hz to 10 kHz.
  • the pulse time may be in at least one range chosen from about 10 "6 s to 10 s, 10 '5 s to 1 s, 10 "4 s to 0.1 s, and 1Q "3 s to 0.01 s.
  • the transfer of energy from atomic hydrogen catalyzed to a hydrino state results in the ionization of the catalyst.
  • the electrons ionized from the catalyst may accumulate in the reaction mixture and vessel and result in space charge build up.
  • the space charge may change the energy levels for subsequent energy transfer from the atomic hydrogen to the catalyst with a reduction in reaction rate, in an embodiment, the application of the high current removes the space charge to cause an increase in hydrino reaction rate.
  • the high current such as an arc current causes the reactant such as water that may serve as a source of H and HOH catalyst to be extremely elevated in temperature. The high temperature may give rise to the thermolysis of the water to at least one of H and HOH catalyst.
  • the reaction mixture of the SF-CIHT eel! comprises a source of H and a source of catalyst such as at least one of «H (n is an integer) and ⁇ .
  • the at least one of nH and ⁇ may be formed by the thermolysis or thermal
  • thermolysis may occur at high temperature such as a temperature in at least one range of about 500K to ⁇ , ⁇ , 1GG0 to 7000K, and 1000K to 5000 .
  • the reaction temperature is about 3500 to 4000K such that the mole fraction of atomic ⁇ is high as shown by J. Lede, F. Lapicque, and J Villermaux [J. Lede, F. Lapicque, J. Villermaux, "Production of hydrogen by direct thermal decomposition of water", international Journal of Hydrogen Energy, 1 83, V8, 1983, pp. 675-679; H, H. G. Jellinek, H.
  • thermolysis may be assisted by a solid surface such as that of at least one of the nozzle 5q, the injector 5zl , and the electrodes 8 of FIGURES 2110-2123.
  • the solid surface may be heated to an elevated temperature by the input power and by the plasma maintained by the hydrino reaction.
  • the thermolysis gases such as those down stream of the ignition region may be cooled to prevent recombination or the back reaction of the products into the starting water.
  • the reaction mixture may comprise a cooling agent such as at least one of a solid, liquid, or gaseous phase that is at a lower temperature than the temperature of the product gases.
  • the cooling of the thermolysis reaction product gases may be achieved by contacting the products with the cooling agent.
  • the cooling agent may comprise at least one of lower temperature steam, water, and ice.
  • the SF-CIHT generator comprises a power system that generates at least one of electrical energy and thermal energy comprising:
  • reactants comprising:
  • At least one shot injection system At least one shot injection system
  • At least one shot ignition system to cause the shot to form at least one of light-emitting plasma and thermal-emitting plasma
  • At least one regeneration system to regenerate additional reactants from the reaction
  • At least one power converter or output system of at least one of the light and thermal output to electrical power and/or thermal power such as at least, one of the group of a photovoltaic converter, a photoeiectronic converter, a plasmadynamic converter, a thermionic converter, a thermoelectric converter, a Sterling engine, a Brayton cycle engine, a Raakine cycle engine, and a heat engine, and a heater.
  • the shot fuel may comprise at least one of a source of H, H 2 , a source of catalyst, a source of H 2 0, and 3 ⁇ 40.
  • Suitable shot comprises a conductive rnetaJ matrix and a hydrate such as at least one of an alkali hydraie, an alkaline earth hydrate, and a transition metal hydrate.
  • the hydrate may comprise at least one of MgCi 2 '63 ⁇ 40, Bai 2 -23 ⁇ 4Q, and ZnC3 ⁇ 4-4H20.
  • the shot may comprise at least one of silver, copper, absorbed hydrogen, and water.
  • the ignition system may comprise:
  • the shot ignition system comprises at least one set of electrodes that are separated to form an open circuit, wherein the open circuit is closed by the injection of the shot to cause the high current to flow to achieve ignition.
  • the ignition system comprises a switch to at least one of initiate the current and interrupt the current once ignition is achieved. The flow of current may be initiated by a shot that completes the gap between the electrodes.
  • the switching may be performed electronically by means such as at least one of an insulated gate bipolar transistor (IGBT), a silicon controlled rectifier (SCR), and at least one metal oxide semiconductor field effect transistor (K 0SFET).
  • IGBT insulated gate bipolar transistor
  • SCR silicon controlled rectifier
  • K 0SFET metal oxide semiconductor field effect transistor
  • ignition may be switched mechanically.
  • the current may be interrupted following ignition in order to optimize the output hydrino generated energy relative to the input ignition energy.
  • the ignition system may comprise a switch to allow controllable amounts of energy to flow into the fuel to cause detonation and turn off the power during the phase wherein plasma is generated.
  • the source of electrical power to deliver a short burst of high-current electrical energy comprises at least one of the following:
  • a voltage selected to cause a high AC, DC, or an AC-DC mixture of current that is in the range of at least one of 100 A to 1 ,000,000 A, 1 kA to 100,000 A, 10 kA to 50 kA;
  • a DC or peak AC current density in the range of at least one of 100 A/cm " to 1 ,000,000 A/cm 2 , 1000 A/cm 2 to 100,000 A-'cm 2 , and 2000 A/cm 2 to 50,000 A-'cm 2 ;
  • the voltage is determined by the conductivity of the solid fuel or energetic material wherein the voltage is given by the desired current times the resistance of the solid fuel or energetic material sample;
  • the DC or peak AC voltage is in the range of at least one of 0.1 V to 500 kV, 0.1 V to 100 kV, and l V to 50 kV, and
  • the AC frequency is In range of at least one of 0.1 Hz to 10 GHz, 1 Hz to 1 MHz, 10 Hz to 100 kHz, and 100 Hz to 1 0 kHz,
  • the output power of the SF-CIHT ceil may comprise thermal and photovoltaic- convertible light power.
  • the light to electricity converter may comprise one that exploits at least one of the photovoltaic effect, the ihermionic effect, and the photoelectron effect.
  • the power converter may be a direct power converter that converts the kinetic energy of energetic electrons into electricity.
  • the power of the SF- CIHT cell may be at least partially in the form of thermal energy or may be at least partially converted into thermal energy.
  • the electricity power converter may comprise a thermionic power converter.
  • An exemplary thermionic cathode may comprise scandium-doped tungsten.
  • the ceil may exploit the photon-enhanced thermionic emission (PETE) wherein the photo- effect enhances electron emission by lifting the electron energy in a semiconductor emitter across the bandgap into the conduction band from which the electrons are thermally emitted.
  • the SF-CIHT ceil may comprise an absorber of light such as at least one of extreme ultraviolet (EUV), ultraviolet (UV), visible, and near infrared light.
  • EUV extreme ultraviolet
  • UV ultraviolet
  • visible visible
  • near infrared light The absorber may be outside if the cell. For example, it may be outside of the window 20.
  • the absorber may become elevated in temperature as a result of the absorption.
  • the absorber temperature may be in the rauge of about 500 °C to 4000 S C.
  • the heat may be input to a
  • thermophotovoltaic or thermionic cell thermophotovoltaic or thermionic cell.
  • Thermoelectric and heat engines such as Stirling, Rankine, Brayton, and other heat engines known in the art are within the scope of the disclosure.
  • At least one first light to electricity converter such as one thai exploits at least one of the photovoltaic effect, the thermionic effect, and the phoioeiectron effect of a plurality of converters may be selective for a First portion of the electromagnetic spectrum and transparent to at least a second portion of the electromagnetic spectrum. The first portion may be converted to electricity in the corresponding first converter, and the second portion for which the first converter is non-selective may propagate to another, second converter that is selective for at least a portion of the propagated second portion of electromagnetic spectrum.
  • the plasma emits a significant portion of the optical power and energy as EUV and UV light.
  • the pressure may be reduced by maintaining a vacuum in the reaction chamber, ceil i , to maintain the plasma at condition of being less optical ly thick to decease the attenuation of the short wavelength light.
  • the light to electricity converter comprises the photovoltaic converter of the disclosure comprising photovoltaic (PV) cells that are responsive to a substantial wavelength region of the light emitted from the cell such as that corresponding to at least 10% of the optical power output.
  • the fuel may comprise silver shot having at least one of trapped hydrogen and trapped 3 ⁇ 4£).
  • the light emission may comprise predominantly ultraviolet light such as light in the wavelength region of about 120 mn to 300 run.
  • the PV cell may be response to at least a portion of the wavelength region of about 120 am to 300 am.
  • the PV ceil may comprise a group III nitride such as at least one of InGaN, GaN, and AlGaN.
  • the PV ceil comprises SiC.
  • the PV cell may comprise a plurality of junctions. The junctions may be layered in series. In another embodiment, the junctions are independent or electrically parallel The independent junctions may be mechanically stacked or wafer bonded.
  • An exemplary muki -junction PV cell comprises at least two junctions comprising n-p doped semiconductor such as a plurality from the group of InGaN, GaN, and AlGaN.
  • the n dopant of GaN may comprise oxygen, and the ⁇ dopant may comprise g.
  • An exemplary triple junction ceil may comprise InGaN/'/GaN/'/AiGaN wherein // may refer to an isolating transparent wafer bond layer or mechanical stacking.
  • the PV may be inn at high light intensity equivalent to thai of concentrator photovoltaic (CPV).
  • the substrate may be at least one of sapphire. Si, SiC, and GaN wherein the latter two provide the beast lattice matching for CPV applications. Layers may be deposited using metalorga ic vapor phase epitaxy (MOVPE) methods known in the art.
  • MOVPE metalorga ic vapor phase epitaxy
  • the cells may be cooled by cold plates such as those used in CPV or diode lasers such as commercial GaN diode lasers.
  • the grid contact may be mounted on the front and back surfaces of the cell as in the case of CPV ceils.
  • the PV converter may have a protective window that is substantially transparent to the light to which it is responsive, The window may be at least 10% transparent to the responsive light.
  • the window may be transparent to UV light.
  • the window may comprise a coating such as a UV transparent coating on the PV cells.
  • the coating may comprise may comprise the material of UV windows of the disclosure such as a sapphire or Mg?2 window. Other suitable windows comprise LiF and CaF
  • the coating may be applied by deposition such as vapor deposition.
  • the SF-CIHT ceil power converter may comprise a photoeiectron (PE) converter.
  • the photoeiectron effect comprises the absorption of a photon by a material such as a metal having a work function ⁇ with the ejection of an electron when the photon energy given by Planck's equation exceeds the work function.
  • a material such as a metal having a work function ⁇
  • the total energ ' of the excited electron is hv , with the excess over the work function ⁇ required to escape from
  • a light to electricity converter of the present disclosure such as an ultraviolet light to electricity converter exploits the photoeiectron effect to convert the photon energy into electrical energy. Heat may also assist in the ejection of electrons that, may contribute to the current of the device.
  • the light to electricity converter may compris a photoelectric power converter comprising at Least one cell shown in FIGURE 2G le4, each capable of receiving incident light such as ultraviolet light 205 comprising a transparent casing 201 , a
  • the photocathode or electron emitter 204 When exposed to at least one of light and heat, the cathode 204 emits electrons that are collected by the anode 202 that is separated from the cathode by a gap or space 203.
  • the photocathode 204 has a higher work function than the anode 202 wherein the former serves and an electron emitter and the latter serves as an electron collector when the cell is exposed to light such as ultraviolet light.
  • the difference in work functions between the different materials of the two electrodes serves to accelerate electrons from the higher work function photocathode to the lower work function anode to provide a voltage to perform useful work in an external circuit.
  • the work function of the anode may be low to enhance the cell power output to the load.
  • the photoeiectron cell further comprises an electrical connection 207 for conducting electrons to the photocathode and an electrical connection for removing electrons from the anode.
  • the electrical connections may comprise a circuit, by attaching across a load 206 through which the curtent flows.
  • the ceil may be sealed.
  • the gap 203 may be under vacuum.
  • phoiocathodes can be divided into two groups transmission or semitransparent shown in FIGURE 2G Ie4, and reflective or opaque shown in FIGURES 2Gle5 and 2G le6.
  • a semi transparent photoeiectronic eel! embodiment typically comprises a coating upon a transparent window 201 such as sapphire, LiF, Mgp , and CaF2, other alkaline earth halides such as fluorides such as BaF 2 , CdFj, quartz, fused quartz, UV glass, borosilicate, and Infrasil (ThorLabs) where the light strikes one surface of the phoiocathode 204 and electrons exit from the opposite surface of 204.
  • the cell comprises a photocathode 204, an anode 202, and a separating gap between the electrodes 203, and radiation 205 enters the cell through a window 201 onto which the phoiocathode 204 is deposited on the interior of the cell.
  • Eiecirons are emitted from the inner face of the photocathode 204 such as the gap or vacuum interface 203.
  • An opaque or reflective photoeiectronic ceil embodiment shown in FIGURES 2G l e5 and 2GIe6 typically comprises a photocathode material formed on an opaque metal electrode base, where the light enters and the electrons exit from the same side.
  • a variation is the double reflection type, where the metal base is mirror-like, causing light that passed through the phoiocathode without causing emission to be bounced back for a second pass at absorption and photoemission.
  • the cell shown in an "opaque" mode embodiment the cell shown in
  • FIGURE 2GIe5 comprises a transparent casing 201, a photocathode 204, a transparent anode 208, a separating space such as an evacuated inter-electrode space 203, and external electrical connections 207 between the cathode and anode through a load 206 wherein radiation such as UV radiation 205 enters the cell and is directly incident on the photocathode 204, Radiation enters the cathode 204 at the gap 203 such as vacuum gap interface, and eiecirons are emitted from the same interface.
  • the light 205 may enter the ceil through a transparent window 201 having the anode such as a grid anode 209 on the interior side of the window 201 .
  • the opaque mode may be considered to comprise a directly illuminated cathode wherein the incident radiation first traverses the window 201 , anode 208 or 209, and gap 203.
  • the cell of the SF-CIHT generator may be maintained under vacuum.
  • the photoelectric (PE) converter may comprise a photocathode, a grid anode, and a vacuum space between the electrodes wherein the vacuum is in continuity with the vacuum of the cell.
  • the PE converter may be absent a window in an embodiment.
  • the electrical connection grid of an electrode may comprise that of a photovoltaic cell such as a grid of fine wires wherein light may pass between the grid wires. Such grids are known to those skilled in the art.
  • a plurality of photoelectron effect cells may be connected in at least one of series and parallel to achieve a desired voltage and current.
  • the col lections may achieve at least one of higher current and higher voltage.
  • the cells may be connected in series to increase the voltage, and the cells may be connected in parallel to increase the ceil current.
  • the grid and interconnections may be connected to at least one bus bar 26b to carry the higher power to a load such as to power conditioning equipment and parasitic loads and power output 6 of the SF-CiHT cell (FIGURE 2D0).
  • high initiation or startup up current may be provided by a startup circuit that may comprise at least one of a power storage element such as one comprising at least one capacitor and battery, and a power source wherein the storage elements may be recharged with output from the power converter 26a.
  • the DC PV output may be power conditioned with at least one of a DC/DC, AC/DC, and DC/AC converter and other condition equipment know to those skilled in the art and output at terminals 6.
  • the voltage of the photoelectric cell V PK is given by the difference In the work functions of the photocathode ⁇ ⁇ and anode , coo'ected by the opposing negative space charge voltage V
  • the photoeiectron ceil power density P PE may be given by the product of the photoelectric ceil voltage V PE and the current density J
  • the gap or electrode separation d is in at least one range of about 0. 1 um to 1000 um, 1 um to 100 urn, about ⁇ urn to 10 urn, and about 1 to 5 um.
  • the gap spacing may be achieved with insulating spacers such as alumina or beryllium oxide.
  • a photoelectron effect ceil further comprises a voltage source to apply an electron collection voltage to ameliorate the space charge and its voltage at given current and power densities. Exemplary applied voltages are the opposite of those given by Eq. (33) within about ⁇ 50%.
  • the temperature may be maintained low such as less than 500 °C to avoid thermal distortion effects that may result in shorting across the gap.
  • the gap may be greater than 3 to 5 um to avoid near infrared losses.
  • Thermionic as well as photoelectron emission may be exploited at elevated temperature such as in the range of 500 °C to 3500 °C.
  • individual photoelsctronic ceils each comprising the two electrodes separated by a gap may be individually sealed.
  • the gap may be maintained at a pressure of less than atmospheric, atmospheric, or above atmospheric.
  • the gap may be maintained under vacuum.
  • die gap pressure may be maintained in at least one range of about 0 Torr to 10,000 Torr, 10 "9 Torr to 760 Torr, 10 '6 Torr to 10 Torr, and 10° Torr to 1 Torr.
  • individual photoelectronic cells each comprising the two electrodes separated by a gap may be individually unsealed and contained in a vessel capable of maintaining the pressure of the sealed cells.
  • the vessel may be a vessel containing just the photoelectronic cells.
  • the vessel may comprise the SF-CIHT cell.
  • the gap may contain a material to reduce the space charge from the electrons emitted from the cathode.
  • Exemplary materials are alkali metals such as cesium vapor.
  • the space charge may be reduced with an alkali metal vapor such as cesium vapor and oxygen.
  • the material may produce plasma in an ignited mode and not produce plasma in an un-ignited mode.
  • the cesium may ionize at the cathode other than being ionized by plasma. The ionization may be by at least one of thermal and electrical energy from the cathode.
  • the eel! may comprise a gate electrode in the gap and a longitudinal magnetic field to cause the electrons to avoid being collected at the gate electrode.
  • the gate electrode may be perforated to allow the electrons trapped on the magnetic field lines to pass through it without being collected.
  • the density of cesium atoms may be about 10 !6 /cm 3 (1 Torr), and the plasma density may be about l O' em 3 to iO i4 /em in the inter-electrode space.
  • the material may be present irs a larger enclosure beyond the inter-electrode space and may receive at least one of electrical and thermal energy to form plasma from at least one of the electrodes and contact surfaces other than the electrodes.
  • an arc drop of less than about 0.5 eV is required to mai tain the plasma.
  • the arc voltage drop is in the range of about 0.01 V to 5 V.
  • Ions may be formed by emission from the cathode surface that may be hot especially in the case of low material pressure and close inter-electrode spacing that minimize electron scattering.
  • the ionization may be due to at least one of thermal and electrical energy from the cathode.
  • Knudsen discharge the pressure between the electrodes is maintained low enough so that the electron mean free path is greater than the inter-electrode gap such that electron transport occurs essentially without scattering. In the limit, no voltage drop due to space charge occurs.
  • the material such as a gaseous materia!
  • the photocathode may have a surface that is angled relative to the direction of incidence of light such that the radiation pressure may reduce the space charge.
  • the photocathode comprises a photoelectron effect active material.
  • the photocathode may comprise a materia! with a work function that matches that of the ioniza tion spectrum of the incident radiation.
  • the photocathode work function may be greater than that of the anode.
  • the magnitude of the photocathode work function may be greater than the sum of the magnitudes of the opposing voltage energy of the space charge and the work function of the collector or anode. Representative energy magnitudes are 0.8 eV and 1 eV, respectively.
  • the radiation from the SF-CIHT cell comprises short wavelength radiation such as extreme ultraviolet (EUV) and ultraviolet (UV).
  • EUV extreme ultraviolet
  • UV ultraviolet
  • the cell gas such as helium or the operating pressure such as about vacuum may favor the emission of short wavelength light.
  • the photocathode is responsive to ultraviolet radiation from the SF-CIHT cell. Since radiation of higher energy than the work function may be lost to kinetic energy and potentially heat, the work function of the photocathode may be matched to be close to the energy of the light such as ultraviolet radiation.
  • the photocathode work function may be greater than 1.8 eV for radiation of shorter wavelength than 690 nm, and the photocaihode work function may be greater than 3.5 eV for radiation of shorter wavelength than 350 nm.
  • the photocaihode work function may be within at least one range of about 0.1 V to 100 V, 0,5 V to 10 V, 1 V to 6 V, and 1.85 eV to 6 V.
  • the photocathode may be at least one of GaN having a bandgap of about 3,5 eV that is responsive to light in the wavelength region 150-400 nm and its alloys such as Al ⁇ Oa ⁇ N, In x Ga!, x N, alkali haiide such as ⁇ , Br, and Csi having a bandgap of about 5.4 eV that is responsive to light in the wavelength region less than 200 nm, multi-alkali such as S20 Harnamatsu comprising Na-K-Sb-Cs that is responsive to light in the wavelength region greater than 150 nm, GaAs that is responsive to light in the wavelength region greater than 300 nm, CsTe that is responsive to light in the wavelength region 150-300 nm, diamond having a bandgap of about 5.47 eV that is responsive to light in the wavelength region less than 200 nm, Sb-Cs that is responsive to light in the wavelength region greater than 1 0 nm, Au that is responsive to light with a peak
  • semitransparent photocathode may comprise CsTe.
  • Type ⁇ -V material UV photocathodes have suitable large bandgaps such as 3.5 eV for GaN and 6.2 eV for A1N.
  • the energy or wavelength responsive region may be fine tuned by means such as by changing the material composition of the photocathode such as by changing the ratio of GaN to A1N in Al x Gai -x N.
  • Thin films of p-doped material can be activated into negative electron affinity by proper surface treatments with cesium or Mg and oxygen, for example.
  • Additional exemplary photocathodes comprise MgO thin-Film on Ag, MgF 2 , MgO, and Cul ⁇ .
  • Exemplary metal photocathodes comprise Cu, Mg, Pb, Y, and Nb.
  • Exemplary coated metal photocathodes comprise Cu-CsBr, Cu-MgF 2 , Cu-Cs, and Cu-CsL
  • Exemplary metal alloy photocathodes comprise CsAu arid alloys of pure metals such as A!, Mg, and Cu, with small amounts of Li, Ba, and BaO, respectively.
  • Exemplary semiconductor photocathodes comprise CsTe, RbTe, alkali antimonides, Cs 3 Sb, & 2 CsSb, Na 2 KSb, NaKjSb, CsK 2 Sb, Cs 2 Te, superalkalies, positive election affinity (PEA) type; Cs;GaAs, Cs:GaN, CsJnGaN, Cs:GaAsP, graded doping, tertiary structures, negative electron affinity (NEA) type.
  • Semiconductor photocathodes may be maintained in high vacuum such as less than about !0 "7 Pa. The size of the PE ceil may that desired and capable of being fabricated.
  • the photoelectric cell may comprise a cathode comprising a metal contact with a work function about matched to the photocathode such as Pi, a photocathode comprising at least one of GaN, A1 , and Al x Ga !-x N, a spacer such as vacuum or one comprised of posts such as posts of an etched AiN layer, and an anode such as a metal thin film or grid.
  • the anode metal may have a work function that may be about matched to the contact material
  • the photoelectric cell may comprise a cathode comprising a metal contact with a work function about matched to the photocathode such as Pi, a photocathode comprising at least one of p-doped GaN, AIN, and Ai x Gai. x N such as one comprising about 50% AIN, an rfGaN layer such as Si ⁇ -doped GaN, and an anode such as a metal thin film or grid wherein the work function may about match that of the contact layer.
  • the photoelectric cell may comprise a cathode comprising a metal contact with a work function about matched to the photocathode such as Pt, a photocathode comprising p-GaN, an n + GaN layer such as Si ⁇ -doped GaN, and an anode such as a metal thin film or grid wherein the work function may about match that of the contact layer.
  • the photoelectric cell may comprise a cathode comprising a metal contact with a work function about matched to the photocathode such as Pt, a photocathode comprising p-Al x Ga 5 .
  • the photoelectric cell may comprise a cathode comprising a metal contact with a work function about matched to the photocathode such as Pt, a photocathode comprising p-Al x Gaj. x N such as about 50% o AIN, an n InGaN layer, and an anode such as a metal thin film or grid wherein the work function may about match that of the contact layer.
  • the n'GaN layer such as Si ⁇ -doped GaN may be formed substantially precisely.
  • the layer may comprise a monolayer.
  • Molecular beam epitaxy may be used to form the monolayer.
  • Molecular beam epitaxy (MBE) or metal- organic chemical vapor deposition (MOCVD) may be used to form the n T doped InGaN layer.
  • At least one of the cathode and anode contacts may comprise a grid or a thin film.
  • the film may be transparent to at least one of ultraviolet (UV) and extreme ultraviolet (EUV) radiation.
  • UV ultraviolet
  • EUV extreme ultraviolet
  • the film may have a thickness in at least one range of about 1 A to 1 urn, 1 A to 1 00 A, and 1 A to 50 A.
  • the photoelectric cell may comprise a solid-state device such as one having a solid spacer through which the photoelectrons may tunnel.
  • the solid spacer may have a thickness in at least one range of about 1 A to 10 urn, 1 A to 1 um, 1 A to 100 A, and 1 A to 50 A.
  • An exemplary cell comprises a cathode comprising at least one of GaN, AIN, Al x Gai -x N, and SiC, a solid spacer such as one comprised of a thin AIN, sapphire, Mgfi, or UV window layer, and a metal grid anode.
  • Exemplary metal grid anodes that are transparent to UV and EUV light are thin films of at least one of Yb, Eu, and Al.
  • the anode may be selected to be transparent to ceil radiation such as UV and EUV radiation and have a low work function such as at least one of Yb, Eu, and cessiated Al thin films,
  • Other PV and PE cell contacts comprise at least one of Au, Ni, NiAu alloy, and Pt.
  • the metal contact to the photocathode may be on the front or top rather than the bottom or backside of the layer.
  • An exemplary cell comprises metal/spacer or
  • the metal may be a thin film of the disclosure and the spacer or insulator and photocathode are ones of the disclosure.
  • the effectiveness of a phoiocathode is expressed as quantum efficiency defined as the ratio of the emitted electrons and the impinging photons or quanta of light
  • the quantum efficiency is optimized by at least one of providing a strong electric field and optimizing the geometry, temperature, and material composition by means such as adding additives such as alkali metals
  • the photocathode is selected to optimize the photon absorption parameters, electron transport properties, and surface energy states to achieve maximum photoelectron efficiency.
  • the surface may be treated or activated to negative electron affinity such thai conduction electrons reaching the surface have a higher energy than vacuum electrons and consequently optimally form photoelectrons.
  • the surface of diamond for example, can be treated or activated to negative electron affinity by cesiation, hydrogenation, coating with monolayers of LiF and RbF, and phosphorous doping using P3 ⁇ 4 chemical vapor deposition.
  • the surface of GaN photocaihodes may be activated with Cs and oxygen.
  • Other exemplary dopants comprise silicon and germanium.
  • the film thickness on the back on the window is selected to optimize the quantum efficiency wherein a wavelength dependent manner, the absorption of incident photons increases with film thickness while the probability of electron transport to the surface deceases.
  • the phoiocathode film thickness may be in at least one range of about 0. 1 nm to 100 um, 1 nm to 10 um, 10 run to 5 um, and 100 nm to 1 urn.
  • the electrode, cathode or anode, thickness such as the electrode film thickness may be in at least one range of about 0, 1 nm to 100 um, 1 nm to 10 um, 10 nm to 5 um, and 100 nm to 1 um.
  • the photocathode comprises multiple layers to convert a wider range of photon wavelengths.
  • the multi-layer photocathode may comprise thin layers that are transparent for photons for successive layers along the propagation path.
  • the top layer may be selective to the least penetrating light, and the successive layers are arranged to be selective based on the rate of attenuation or the penetration depth in the layered structure, in an exemplary three layer photocathode, the top layer may be selective for the least penetrating wavelengths and have the corresponding highest work function, the middle layer may be selective for the intermediate penetrating wavelengths and have the corresponding intermediate work function, and the bottom or farthest layer along the light propagation path may be selective for the most penetrating wavelengths and have the corresponding lowest work function.
  • Other combinations of penetration depth, relative layer position, and work function are within the scope of the disclosure.
  • the anode comprises a material capable of collecting electrons.
  • the anode work function may be as low as possible to increase the cell voltage according to Eq. (34).
  • the anode work function may be lower than at least one of about 2 V, 1 .5 V, 1 V, 0,9 V, 0,8 V, 0.7 V, 0.6 V, 0.5 V, 0.4 V, and 0.3 V.
  • the anode may comprise at least one of an alkali metal such as cesium, calcium aluminaie electride (C12A7:e) having a work function of about 0,76 eV, phosphorus doped diamond nanofilm having a work function of about 0.9 eV, and scandium-doped tungsten.
  • At least one electrode of the cathode and anode may have at least a portion of its surface structured or non-planar such that a portion of the incident light may reflect to at least one of another photocathode, a portion of the photocaihode, and an optical element such as a mirror that is reflective of the light and reflects it onto another portion of the photocaihode or at least one other photocathode.
  • the photocathodes received multiple bounces (reflections) of the incident light to increase the absorption cross section of the photocathode for producing photoelectrons.
  • the photocathode comprises a structured substrate to increase the efficiency wherein the photon absorption path in the photocathode is increased while the electron escape path remains the same or less than as for a planar substrate.
  • An exemplary structured surface has zigzags with alternate interior angles of 45°. In another embodiment, the zigzag angles can alternate between 45° and 90°. Other angles are within the scope of the disclosure.
  • increased photon absorption within the material while decreasing the distance the photoelectrons have to travel to the surface can be achieved by at least one of changing the angle of incoming radiation and using multiple total internal reflections within the photocathode.
  • reflection of photoelectrons from the back surface of the photocathode facilitates the attainment of greater than 50% conversion efficiency for some materials when each photon produces at most a single photoelectron.
  • some GaN photocathodes are grown on a thin buffer layer of A1N, which has large bandgap energ ' and serves as a reflection layer. The efficiency of the photo-conversion as a function of incoming radiation angle increases with angle relative to normal incidence until reaching the point of total reflection.
  • the photocathode that is operated in a semi transparent mode can be grown on a transparent substrate such that it has a zigzag photoactive layer, the conduction electrons are produced closer to the escape surface than in the case of a flat substrate, and therefore should have higher probability to escape into vacuum.
  • the photocathode is grown on a planar surface to avoid substantial degradation from lattice mismatch.
  • GaN is typically grown on a matching crystal lattice of sapphire or silicon carbide substrates with C-piane at the surface.
  • similar reflective systems and methods may be applied to the anode.
  • the anode may comprise a double reflection type where the metal base is mirrorlike, causing Sight that passed through the photocathode without causing emission to be bounced back to the photocathode for a second illumination.
  • the window for the passage of light into the ceil may be transparent to the light such as short wavelength light such as ultraviolet light.
  • Exemplary ultraviolet light has energy greater than about 1.8 eV corresponding to a wavelength of about less than 690 run.
  • the window may comprise at least one of sapphire, LiF, MgF 2 , and CaF , other alkaline earth halides such as fluorides such as BaF 2 , CdF 2 , quartz, fused quartz, UV glass, borosilicate, and Infrasil (ThorLabs),
  • At least one of the photoelectric (PE) and photovoltaic (PV) converter may be mounted behind the baffle Sd (FIGURE 2 ⁇ 0) of the recirculation system of the disclosure,
  • PE or PV converter replaces the baffle 8d.
  • the windows of the PE or PV converter may serve the functions of the baffle as a means to impede the upward trajectory of the ignition product flow and provide transparency for the light into the light to electricity converter, the PE or PV converter in this embodiment.
  • at least on of the baffle 8d and the window may be very thin such as about 1 A to 100 A thick such that it is transparent to the UV and EUV emission from the cell.
  • Exemplary thin transparent thin films are Al, Yb, and Eu thin films.
  • the expanding plasma is comprised of positively charged particles and elections.
  • the electrons have a higher mobility than the positive ions, A space charge effect may develop.
  • the space charge is eliminated by grounding at least one conductive component of the cell such as the cell wail.
  • both electrodes are electrical ly connected to the cell wherein essentially all of the current from the source of electrical power 2 (FIGURE 212) to the roller electrodes flows through the fuel to cause ignition due to the much lower electrical resistance of the fuel such as that of a fuel shot or pellet.
  • the elimination of the space charge and it corresponding voltage may increase the hydrino reaction rate.
  • the cell is run under vacuum.
  • the vacuum condition may facilitate the elimination of at least one of space charge and confinement that may decrease the hydrino reaction rate.
  • the vacuum condition may also prevent the attenuation of UV light that may be desired for PE conversion to electricity.
  • S.F- CIHT cell generator may comprise a vacuum pump to maintain the evacuation at a desired pressure controlled by a pressure gauge and controller.
  • the product gases such as oxygen may be removed by at least one of pumping and a getter such as an oxygen getter that may be at least one of continuously and periodically regenerated. The latter may be achieved by removing the getter and regenerating it by applying hydrogen to reduce the getter to form a product such as water,
  • the cell may be operated under evacuated conditions.
  • the cell may comprise a vacuum chamber such as a cylindrical chamber or conical cylindrical chamber that may have domed end caps.
  • the recovery of the upward expanding ignition plasma is achieved by gravity which works against the upward velocity to slow, stop, and then accelerate the ignition product downwards to be collected ultimately in the regeneration system to be reformed into fuel.
  • the collection may be by means of the disclosure.
  • the fuel recirculation is achieved by using the Lorentz force, exploiting the principles of the railgim such as a plasma armature type that may further comprise an augmented railgun type.
  • the Lorentz force causes the ignition plasma to be directed and flow into a collection region such as a plate or a collection bin that may feed the product material into the regeneration system.
  • the current and the magnetic field may be in the horizontal or xy-plane such that the Lorentz force according to Eq. (37) is directed downward along the negative z-axis to the collection system components such as a plate or bin.
  • the current may be in the xy-pkne and the B-field directed along the z-axis such that the Lorentz force according to Eq.
  • the ignition plasma may carry current from the source of electrical power 2 (FIGURE 212) to the electrodes 8 or from an external power source to serve as the current in Eq. (37).
  • the electrodes and bus bar and the corresponding circuits may be designed to provide at least one of the plasma current and magnetic field during ignition to produce the desired Lorentz force to move the plasma in a desired manner such as out of the zone wherein the plasma is formed during ignition.
  • the ignition current that powers at least one of plasma current and magnetic flux to provide the Lorentz force may be delayed by a delay circuit element such as a delay line to provide the current and magnetic flux at a later rime than the ignition event.
  • the delay may permit the plasma to emit light before it is removed by the Lorentz force.
  • the delay may be controlled by circuit or control means known in ihe art.
  • the current such as high DC current may also be applied by a power source in a desired direction by parallel plate electrodes with the current direction along the inter-plate axis.
  • the current source power may be derived from the power converter such as the PE or PV converter wherein power may be stored in a capacitor bank.
  • the sources of ihe augmented magnetic fields may comprise at least one of electromagnets and permanent magnets.
  • the magnetic field of the augmented plasma railgun may be applied by Hekaholtz coils such as a pair of separated, axial-aligned coils with the field in the desired direction along the inter-coil axis.
  • the strength of the magnetic field may be controlled by a current controller to control the strength of the Lorentz force and consequently, the rate of recovery of the ignition products.
  • a plurality of electromagnets may have different controlled magnetic fields to direct the plasma and the ignition products to a desired location for collection.
  • At least one of the augmented electric and magnetic field may be produced inductively by at least one induction coil and an alternating voltage or current driver.
  • the magnetic field may be provided by a pair of separated, axial-aligned permanent magnets with the field in the desired direction along the inter-pole-face axis.
  • the permanent magnets may comprise AlNiCo, neodymium, rare earths, or other high field magnet known in the art.
  • the magnetic flux may he any desired such as in at least one range of about 0.001 T to 10 T, 0.01 T to I T and 0.1 T to 0.5 T.
  • the electromagnets may be powered by a power supply wherein the electromagnetic power may be derived from the power converter such the PE or PV converter wherein power may be stored in a capacitor bank.
  • the magnetic field from at least one of the source of electrical power 2 (FIGUKE 212) to the electrodes and the sources of the augmented magnetic fields is configured to cause the desired flow of the ignition product plasma into the collection system according to the Lorentz force.
  • the collection system may comprise that of the disclosure such as at least one of a collection plate and a bin that may feed into the regeneration system.
  • the bin may comprise a vessel of the
  • the augmented plasma railgun may achieve the effect of focusing or co!iimattng the plasma light onto the power converter by at least one of spatially and temporally directing the plasma.
  • the plasma may be confined magnetically using a magnetic bottle and other means of plasma confinement that are well known in the art.
  • the recirculation of the ignition product may be achieved using other means of the disclosure such as electrostatic precipitation (ESP).
  • ESP electrostatic precipitation
  • the ESP collection electrodes may be out of sight of the ray paths of the light created by the hydrino reaction.
  • the ESP may be operated in the ignition plasma region.
  • the plasma operation may be supported by the low cell gas pressure such as vacuum.
  • the ESP may operate with the ignition plasma in a region that does not substantially contact at least one type of the ESP electrodes such as the collection electrodes, being the cathode or anode.
  • the ESP collection electrodes may be circumferential to the ignition plasma with at least one of a vacuum and a low-pressure region having a high resistance in the electrical path from the counter to the collection electrodes.
  • At least one of the ESP electrodes of a pair may comprise a barrier electrode.
  • the barrier electrode may limit the current and maintain a high field to collect the ignition product electrostatically.
  • One electrode type may be covered with a highly resistive layer to be permissive of DC operation called resistive barrier
  • the electrode barrier may comprise a semiconductor such as a layer of gallium arsenide to replace a dielectric barrier layer to enable the use of high voltage DC.
  • the voltage may be in the range of 580 V to 740 V, for example.
  • the high voltage may be pulsed.
  • the ignition product may be transported from the collection electrodes to the regeneration system.
  • the transport may be at least one of gravity-assisted transport and achieved by other methods of the disclosure such as electrostatic and electromagnetic methods.
  • the regeneration system to regenerate the initial reactants from the reaction products and form shot comprises a peiietizer comprising a smelter to form molten reactants, a system to add 3 ⁇ 4 and 33 ⁇ 40 to the molten reactants, a melt dripper, and a coolant to form shot.
  • the peiietizer may comprise first and second vessels that may comprise heaters or furnaces to serve as meiters of the ignition product that may comprise a metal such as a pure metal or alloy such as Ag, Cu, or Ag-Cu alloy.
  • the heater to form the melt may comprise one of the disclosure such as a resistive, arc, or inductively coupled heater.
  • the light output from the SF-CIHT cell may be used to heat the fuel sample to form the pellet.
  • Heat from a heat exchanger may deliver heat to the melt from another component of the SF-CIHT cell.
  • the heater may comprise a resistive heater with heating elements capable of high temperature such as ones comprising at least one of Nichrome, tungsten, tantalum, molybdenum, SiC, MoS3 ⁇ 4, precious metals, and refractory metals.
  • the elements may be hermetically sealed.
  • the heater may comprise a .non-filament type such as an electric arc heater.
  • the ignition product is collected by a means such as gravity and an augmented plasma railgun recovery system. The collected product may be flowed into the first vessel, crucible, or hopper that further comprises a heater.
  • the product may be melted by the heater, and the melt may flow into the second vessel through a connecting passage.
  • the passage outlet into the second vessel may be submerged below the surface of the melt such as the molten ignition product in the second vessel
  • the first vessel may discharge the melt under the surface of the second.
  • the melt level in either vessel may be sensed by electrical resistance probes such as a refractor wire such as a W or Mo wire that is electrically isolated from the vessel wall to sense an open circuit in the absence of contact with the melt and a low resistance when in contact with the melt.
  • the flow from the first to the second may be controlled by the pressure di fferential between the first and second based on the level of melt in the first and second vessel and any gas pressures in the first and second vessels.
  • the melt levels may be changed to control the flow between the vessels, in an embodiment, the column height of molten ignition product in at least one of the passage and the first vessel is such that the corresponding pressure given by the product of the melt density, gravitational acceleration, and the column height plus the gas pressure in the first vessel is greater than or equal to the pressure in the second vessel.
  • the gas pressure in the first vessel may comprise that of the SF-CIHT ceil.
  • the pressure in at least one of the first and second vessel is controlled with at least one pressure sensor, at least one valve, at least on gas pressure controller, at !easi one pump, and a computer.
  • the flow through the passage may a!so or further be controlled by a valve, petcock, or sluice valve.
  • the second vessel or crucible further comprises at least one nozzle or dipper to form shot.
  • the melt may flow out an orifice or nozzle of the second vessel to a water reservoir to form shot, and the resulting level and pressure change may cause melt to flow from the first vessel to the second.
  • the orifice or nozzle opening size may be controlled to control at least one of the shot size and metal flow rate.
  • Exemplary orifices of adjustable size may comprise a solenoid valve, a shutter valve, or a sluice valve.
  • the high temperature nozzle valve may comprise a refractory lined butterfly valve.
  • the opening size may be controlled with a solenoid or other mechanical, electronic, or electromechanical actuator.
  • the orifice may have a fixed size such as 1 mm diameter for an alloy such as Ag-Cu (72 wt%/28 wt%).
  • the orifice may have a diameter in the range of about 0.01 mm to 10 mm.
  • the size of the shot may be controlled by contro!iably adjusting at least one of the orifice size, the fuel melt temperature, the diameter of the connecting passage between vessels, the pressure in the first vessel, the pressure in the second vessel, the pressure difference between the first and second vessel, the fuel composition such as the composition of at least one of the conductive matrix such as the weight percen tages of pure metal components of a metal alloy such as a Ag-Cu alloy, and at least one of the percentage composition of a water binding compound, the water content, and the hydrogen content.
  • the ignition product is melted in a first region or vessel having intense heating such as that provided by an electrical arc such as at least one of an arc having the ignition product directly carrying at least some of the arc current and an arc on in proximity to the first vessel such as a refractory metal tube through which the ignition product powder flows.
  • the melt may flow into another region or vessel having a temperature above the ignition product melting point that may be maintained by a second vessel heater such as a resistive heater such as one comprising at least one of Nichrome, SiC, and MoSi.
  • the heater to heat the ignition products such as the first vessel heater may comprise an inductive heating element such as an electromagnetic heater such as an alternating frequency (AC) inductively coupled heater.
  • the second vessel heater may comprise and inductively coupled heater.
  • the frequency may be in at least one range of about I Hz to 10 GHz, 10 Hz to 100 MHz, 10 Hz to 20 MHz, 100 Hz to 20 MHz, 100 kHz to 1 MHz, 500 H2 to 500 kHz, I kHz to 500 kHz, and 1 kHz to 400 kHz.
  • the vessel may comprise a heat resistant AC or RF-transparent material such as a ceramic such as silicon nitride such as SiiN , AI2Q3, alumina, sapphire, or zirconia, zirconium oxide.
  • the heater may comprise high insulation between the vessel and the inductively coupled coil that may be cooled by means such as water-cooling, in another embodiment, the second vessel may be at least one of partially and solely heated by the melt that is formed and elevated la temperature in the fust vessel.
  • the first vessel heater such as an inductively coupled heater may heat the melt to a higher temperature than thai desired in the second vessel to provide heat to the second vessel The temperature and flow rate of the metal flowing from the firet vesse!
  • the heater of at least one of the first and second vessels comprises at least one of an inductively coupled heater, a heat exchanger to transfer thermal power sourced from the reaction of the reactanis, and at least one optical element to transfer optical power sourced from the reaction of the reactants.
  • the heater may comprise a microwave heater such as one that operates at about 2.4 GHz. in other embodiments, the microwave frequency may be the range of about 300 MHz to 300 GHz.
  • the microwave heater may comprise at least one microwave generator such as at least one magnetron.
  • the microwave heater may comprise a cavity that surrounds the vessels such as 5b and 5c containing the solid fuel such as the solid fuel comprising molten silver. The cavity may be pumped with microwaves by an antenna output of the microwave generator.
  • the vessel walls may comprise a material such as a metal that absorbs microwaves and heats the solid fuel indirectly.
  • the vessel walls may comprise a material such as quartz, alumina, sapphire, zirconia, or silica that may be transparent to microwaves such that the microwaves directly heat the solid fuel to melt it.
  • An exemplary solid fuel comprises silver that is injected with at least one of 3 ⁇ 40 and 3 ⁇ 4,
  • an inert microwave absorbing material is added to the solid fuel to absorb microwaves.
  • the microwave absorber may be at least one of H 2 0 and H 2 .
  • the pelletizer may also comprise one or more electromagnetic pumps to control the flow of at least one of the powder and melt through the pelletizer.
  • the pelletizer further comprises a heat recuperator to recovery or reclaim at least some heat from the cooling shot and transfer it to incoming ignition product, to preheat it as it enters the smelter or Grst vessel comprising a heater.
  • the melt may drip from the dripper into the water reservoir and form hot shot that is recovered while hoi.
  • the heat from the cooling shot may be at least partially recovered or reclaimed by the recuperator.
  • the recovered or reclaimed heat may be used to at least one of preheat the recovered ignition product powder, melt the powder, heat the melt, and maintain the temperature of at least a portion of the pelletizer.
  • the pelletizer may further comprise a heat pump to increase the temperature of the recovered heat.
  • the second vessel may be capable of maintaining a gas at a pressure less than, equal to, or greater than atmospheric.
  • the second vessel may be sealed.
  • the second vessel may be capable of mamtaixsing a desired controlled atmosphere under gas flow conditions.
  • a gas such as at least one of a source of H, 3 ⁇ 4, a source of catalyst, a source of H2O, and H2O may be supplied to the second vessel under static or flow conditions.
  • the gas such as hydrogen and water vapor and mixtures may be recirculated.
  • the recirculation system may comprise one or more of the group of at least one valve, one pump, one flow and pressure regulator, and one gas line.
  • a plurality of gases such as 3 ⁇ 4 and 3 ⁇ 4G may be at least one of flowed into or out of the vessel using a common l ine or separate lines.
  • inlet gas ports may be submerged in the melt, and the gas outlet may be above the melt.
  • Both H 2 and H 2 0 may be supplied by flowing at least one of Hi, 3 ⁇ 40, and a mixture of H 2 and 3 ⁇ 40.
  • a carrier gas may flow through a H 0 bubbler to entrain H 2 0 in a gas stream such as one comprising a 3 ⁇ 4 gas stream, and then mixture may flow into the melt.
  • Hydrogen may comprise the carrier gas bubbled through H 2 0 to also serve as a reaetant in the hydrino reaction.
  • the carrier gas may comprise an inert gas such as a noble gas such as argon.
  • the gas-treated melt may be dripped Into 3 ⁇ 4Q to form the shot with incorporation of the gases such as at least one of H 2 0 and H 2 .
  • the added or flowing gas may comprise H 2 alone and H 2 0 alone.
  • the meii may comprise an oxide to further increase the shot content of at least one of a source of H, a source of catalyst, H_, and H 2 0.
  • the oxide may be formed by the addition of a source of 0 or 0 2 gas that may be flowed in to the melt.
  • the oxide may comprise those of the disclosure such as a transition metal oxide.
  • the oxide such as CuO may be reducible with 3 ⁇ 4 (CuO + 3 ⁇ 4 to Cu + H 2 0), or it may comprise an oxide thai is resistant to 3 ⁇ 4 reduction such as an alkaline, alkaline earth, or rare earth oxide.
  • the oxide may be capable of being reverslbiy hydrated.
  • the bydration/dehydraiioa may be achieved by 3 ⁇ 40 addition and heating or ignition, respectively.
  • a fluxing agent such as borax may be added to the melt to enhance the incorporation of at least one of H and H 2 0 into the shot.
  • the cell may be operated under evacuated conditions,
  • the cell may comprise a vacuum chamber such as a cylindrical chamber or conical cylindrical chamber that may have domed end caps.
  • the conical cylindrical chamber may be beneficial for optimizing the propagation of the light from the cone emitted from the electrodes at a minimum cell volume, in another embodiment, the ceil has sufficient diameter such that the ignition plasma light does not contact the wails substantially before exiting to at least one of a window of the PV or PE converter and being directly incident 00 the PV or PE converter.
  • the ignition product may collect on the cell walls and be dislodged mechanically such as by vibration.
  • the ignition electrodes 8 may be at least partially rigidly connected to the walls to transfer vibrations from the ignition of shot fuel to the walls to dislodge ignition products from the wails.
  • connection may electrically isolaie the electrodes from the ceil wail.
  • the ignition product may be collected in a vessel such as the first chamber of the pe!letizer by gravity or by other means of the disclosure such as electromagnetically or electrostatically.
  • the ceil may be operated at a low pressure such as vacuum.
  • the ignition product may be removed by at least one of (i) gravity wherein the ceil may be operated under reduced pressure such as a vacuum in the range of 0 to 100 Torr, (ii) an augmented railgun with the ignition plasma as the armature referred to herein as an augmented plasma railgim recovery system, and (iii) an electrostatic precipitator.
  • the larger particles may be charged by a means such as corona discharge and repelled from the light to electricity converter by an electric field such as an electrostatic field that may be applied to a repelling grid by a power supply.
  • the augmented plasma railgun recovery system removes or recovers essentially all of the fine particles such that the ceil is transparent to the light produced by the ignition.
  • Gravity may remove or recover the remainder, in an embodiment, the cell height is sufficient such that particles not removed or recovered by the augmented plasma railgun recovery system or stopped in an upward trajectory by gravity are cooled to a temperature thai causes the particles to be non-adherent to either of the window of the converter or the converter such as the PV or PE converter.
  • the SF-CIHT generator may comprise a means to remove ignition product from the surface of the window or the converter such as an ion-sputtering beam that may be swept or rastered over the surface.
  • the cleaning means to remove ignition product from the surface of the window or the converter may comprise a mecha ical scraper such as a knife such as a razor blade that is periodically moved across the surface.
  • the motion may be a sweep for a blade of the width of the window or a raster motion in the case of a smaller blade.
  • the baffle of the disclosure may further comprise the mechanical scraper such as a knife or the ion beam cleaner to remove ignition product from the baffle in the same manner.
  • the symmetrical wiper may travels around the inside of the cell such as on the conical surface.
  • the surface clearing system may comprise a cell iper and wiper on PV converter.
  • the wiper or blade may be moved by an electric motor controlled by a controller.
  • the scraper may comprise carbon that is not wetted by silver and also is non-abrasive.
  • the carbon wiper may maintain a thin coating of graphite on the window to prevent melt adliesion such as silver or copper adhesion.
  • the injector is at least one of electrostatic, electric, eiectrodynamic, magnetic, magnetodynamic, and electromagnetic.
  • the trajectory of the path is in the inter- electrode region such as in the center point of closest contact of the opposed roller electrodes.
  • the aimed transport may comprise an injection of the fuel shot or pellet. The injection may result in the completion of the electrical contact between the rollers that may result in high current flow to cause the shot or pellet to be ignited.
  • the injector comprises and electrostatic injector such as one of the disclosure.
  • the shot or pellet may be electrostatically charged, the roller electrodes may be oppositely charged, and the shot or pellet may be propelled by the electric field to be injected into the inter-electrode region to be ignited.
  • the high conductivity of the fuel shot or pellet is permissive of the induction of a surface current due to a time dependent application of at least one of a magnetic field and an electric field wherein the induced current gives rise to a magnetic field produced by the shot or pellet.
  • the correspondingly magnetized shot or pellet may be accelerated along a path such as that provided by guiding magnetic fields such as those provided by current carrying rails.
  • a gradient of magnetic field may be caused over time to accelerate the shot or pellet along the path.
  • the shot or pellet injector comprises a railgun.
  • the railgun comprises a high current source, at least one pair of rails comprising a high conductor, and an armature that comprises the shot or pellet that also serves as the projectile.
  • the railgun injector may comprise a sabot that may be reusable.
  • the railgun may use a plasma armature that may comprise metal that may be at least one of ignition product and fuel that vaporizes and becomes plasma behind the shot or pellet as it carries the high current and causes the shot or pellet to be accelerated along the rails of the railgun injector.
  • the source of current may provide a pulse of current in at least one range of about 1 A to 100 MA, 10 A to 10 MA, 100 A to 1 MA, 1000 A to 100 KA, and 1 kA to 10 kA.
  • the source of current may comprise the source of electrical power 2 (FIGURE 212) to the rol ler electrodes that causes ignition such as one comprising a bank of capacitors charged by the light to electricity converter such as the PV or PE converter.
  • the rails may comprise a positive rail and a negative rail comprising a high conductor such as at. least one of copper and silver.
  • the railgun injector may be activated at a desired frequency such as 1000 Hz to provide sufficient fuel to maintain the desired fuel ignition rate wherein the conductive arriving shot or pellet may complete the electrical circuit between the roller electrodes to cause the shot or pellet ignition.
  • the injection activation frequency may be controlled to be within at least one range of about 0.01 Hz to 1 MHz, i Hz to 10 kHz, and 10 Hz to 1 kHz.
  • the injection activation frequency may be controlled to control the power output of the SF-CIHT cell.
  • the injection activation control may comprise a switch.
  • the switch may comprise one of the switches of the disclosure for the source of electrical power 2 (FIGURE 212) to the roller electrodes such as mechanical or electronic switch such as one comprising at least of a IGBT, SCR, and a MOSFET transistor.
  • the rails are continuously energi zed as an open circuit that is closed to allow high current to flow with the completion of the circuit by a fuel shot or pellet.
  • each time that a shot or pellet contacts the rails to complete the circuit it is accelerated and injected into the electrodes to be ignited.
  • the power source may be capable of maintaining the desired current to each shot or pellet of a plurality of shots or pellets accelerated along the rails at any given time.
  • the current may be controlled by at least one of circuit elements and a controller.
  • the railgun current is divided amongst an integer n number of shots or pellets that are accelerating on the rails at a given instance such that the decrease in speed of injection of a single shot or pellets according to Eq. (37) is compensated by the simultaneous acceleration and sequential injection of the n shots or pellets.
  • This compensation mechanism may maintai about a constant injection rate dependent on the railgun current.
  • the voltage across the rails is maintained about constant independent of the number of shots or pellets such that the current per shot or pellet is about the same due to the similar resistances of the shots or pellets.
  • the about constant voltage may be supplied by a power source comprising a large capacitance such as one comprising a bank of capacitors.
  • the rails may provide a continuous guide path, but comprise segmented sections for electrical current such that the current may be variable and controlled as the shot propagates along the different sections.
  • the current in each section may be controlled by a computer, sensors, and a plurality of current sources to control the speed and energy of the shot in any given section to control the timing of injection or injections wherein multiple shots may be on the rails comprising the variable current sections.
  • the constant voltage may be kept below a voltage that causes arcing and consequent shot-to-rail welding or rail arc damage.
  • the voltage may be at least one of less than about 100 V, less than about 50 V, less than about 20 V, less than about 10 V, less than about 5 V, less than about I V, less than about 0.5 V, and less than about 0.25 V.
  • the power may be supplied by at least one of a capacitor bank such a one comprising super- capacitors, the PV converter, and a battery with a high shorting current.
  • the rails may be heat sunk to avoid shot-to-rail welding.
  • the heat sink may be electrically isolated from the circuit comprising the rails and shot.
  • An electrical insulator that may also be a good heat conductor may provide the electrical isolation.
  • An exemplary heat sink comprises a high mass of a high heat conductive material such s a block of AI, Cu, or Ag that may be electrically insulated with a top layer of diamond film that is also a good thermal conductor as well being an electrical insulator.
  • the rails may comprise a conductor such as graphite that is resistant to welding.
  • the rails may comprise a refractory metal conductor such as tungsten or molybdenum that is resistant to welding.
  • the rails may be cooled by means such as air or water cooling to prevent welding. In an embodiment, the rails are at least partially submerged in water that cools the rails and shot and prevents welding.
  • the water may also prevent electrical arcing between the shot and rails,
  • a conducting lubricant and electrical contact agent that may have a higher breakdown voltage than the cell gas such as graphite or MoS 2 may be coated on the rails to decrease arcing.
  • the current may be less than that which causes shot-to-rail welding.
  • the rails may be long cylinders thai are rotated about their longitudinal axes (z-axis in cylindrical coordinates) to make better contact with the shot.
  • the relative rail rotation may be counier-rotating towards the center of the pair to push the shot tighter against the rails.
  • the tighter connection may abate welding of the shot to the rails.
  • one roller driven by a pulley drive in turn drives the other in counter rotation by a pulley or chain linkage for example.
  • the rollers run in the same direction with one driving the other with the shot as the l inkage. This configuration may apply downward pressure on the shot to rnake better electrical contact, and the rolling of the shot may further decrease the arc damage.
  • the Lorentz force may be high with a low magnetic field contribution from the rail current by augmenting the magnetic field with an applied magnetic field by a magnet such as an electromagnet or a permanent magnet
  • the applied magnetic field may be provided by a pair of Helrnholiz coils with one above and one below the plane of the rails (xy-plane); each parallel to the xy-plane to provide a magnetic field perpendicular to the xy-plane.
  • a similar z-axis oriented magnetic field may be generated by two permanent magnet such as discs replacing the Helmhoitz coils in the xy- plane.
  • the permanent magnets may comprise rectangular bars thai run above and below and parallel to the rails having the field oriented along the z-axis.
  • the permanent magnets may comprise AI iCo, rare earths, or other high field magnet known in the art.
  • the magnetic flux may be any desired such as in at least one range of about 0.001 T to 10 T, 0.01 T to I T and 0.1 T to 0.5 T.
  • multiple shots may be present on the rails to divide the applied power to prevent arcing and corresponding welding of the shot to the rails or arc damage ⁇ the rails.
  • a current surge that causes welding or rail damage may be ameliorated by a damping circuit element such as at least one of a shunt diode, a delay line, and circuit inductor.
  • the raiigun injectors may have redundancy such that if one fails another may serve in its place until the failed raiigun is repaired. In the case that the failure is due to a pellet welding on the rails, it may be removed mechanically by grinding or lathing for example or electrically such as by vaporization at high current.
  • the raiigun injector may comprise a low-friction, low-pressure spring-loaded top guide to facilitate the electrical contact between the shot and rails.
  • the shot-to-rail electrical contact is assisted by vibration applied to the injector. Vibration may be applied to cause a low-resistance electrical contact between the rails and the shot. The contact may also be facilitated by an agitator such as the mechanical and water jet agitators shown in FIGURE 214 and 215.
  • the applied magnetic field of the augmented raiigun injector may comprise a component parallel to the direction of pellet motion and trarssverse to the current through the shot such that the shot is forced down on the rails according to the Lorentz force given by Eq.
  • the motion-parallel magnetic field may be provided by at least one of permanent magnets and electromagnets. In the latter case, the magnetic field may be varied to control the downward force on the shot to optimize the contact while avoiding excess friction.
  • the control of the magnetic field may be provided by a computer, sensors, and a variable current power supply.
  • the rails may comprise an oxidation resistant material such as silver rails to limit rail oxidation and corresponding resistance increase.
  • the raiigun injector may comprise a plurality of raiigun injectors that may have synchronous injection activation that may be controlled with a controller such as a microprocessor or computer.
  • the plurality of injectors may increase the injection rate.
  • the plurality of railgun injectors may comprise as array of injectors to increase the injection rate.
  • the rails of the railgun may be straight or curved to achieve a desired injection path from the shot or pellet supply to the inter-electrode region where ignition occurs.
  • the rotational velocity of the roller electrodes may be increased to accommodate more fuel and increase the power output of the SF-CIHT cell.
  • the roller diameter may be scaled to achieve the increased rotational speed.
  • the maximum rotational speed for steel for example is approximately 1 100 m/s [J. W, Beams, "Uiirahigh-Speed Rotation", pp. 135- 147].
  • the maximum fuel flow rate supplied by the railgun or plurality of railguns is 367,000 per second.
  • the corresponding total power to be converted into electricity may be 1 80 MW. Additional power can be achieved by adding a plurality of roller electrode pairs with injectors wherein the electrodes may be on the same or di fferent shafts.
  • the injector comprises a Gauss gun or coilgun wherein the pellet or shot comprises the projectile.
  • the pellet or shot may comprise a ferromagnetic material such as at least one of Ni, Co, or Fe.
  • An exemplary shot comprises Ag with trapped 3 ⁇ 4 and H O and a ferromagnetic material.
  • the coiigun may comprise at least one current coil along a barrel comprising a guide for the pellet or shot, a power supply to provide a high current and a magnetic field in the at least one coil, and a switch to cause the current to flow to pull the shot or pellet towards the center of the coil wherein the current is switched off before the shot or pellet experiences a reverse force by passing the coil center.
  • the switch may be one of the disclosure such as one comprising an IGBT.
  • the power supply may comprise at least one capacitor.
  • current is flowed through the shot or pellet to create a shot or pellet magnetic field by the application of external power or by an external time dependent field such as a time dependent magnetic field.
  • the shot or pellet current flow may be achieved by magnetic induction.
  • the magnetic induction may be caused by the time-varying magnetic field of the current coils.
  • the temporal current flow to the at least one current coil is controlled to propel the shot or pellet along the barrel.
  • the speed and location of the delivery of a shot or pel let on the roller electrode surface can be controlled to controllably repair any ignition damage to the surface.
  • the control can be achieved by controlling the timing of the shot or pellet accelerating current pulse, as well as the current position, and steering capability of the railgun injector, for example.
  • the controiled-position delivery with the control of the roller speed and ignition current can facilitate the bonding of the shot or pellet to the electrode.
  • the bonding may be by at least one of sintering, fusing, and welding of the shot or pellet to the electrode surface at the desired position, in an embodiment, a specific percentage of shot or pellets may be made to have less to none of the hydrino reactants such as at least one of hydrogen and HOH, In an embodiment, this can be achieved by forming the shot without the addition of at least one of steam and 3 ⁇ 4 in the peiietizer.
  • the reduction or elimination of 3 ⁇ 4G and 3 ⁇ 4 may be achieved by eliminating the supply or reducing the solubility in the melt by lowering the melt temperature during shot formation.
  • pellets may be made absent or with diminished amounts of at least one of 3 ⁇ 4 and 3 ⁇ 40.
  • the corresponding "dud" shots or pellets may be applied separately or mixed with ordinary ones at a desired percentage.
  • one shot or pellet out of integer n is a dud that becomes bonded to the electrodes when injected.
  • the integer n can be controlled to be larger or smaller depending on the amount of damage there is to be repaired.
  • ignition powder is recovered, forgoes the shot forming process, and is injected into the electrodes by a plasma railgun injector or augmented plasma railgun wherein some of the powder supports the plasma to cause it to be propelled. At least one of the ignition current and ignition plasma supported by ignition of other shots may cause the powder to bond to the electrodes. Excess material may be machined off by means such as by use of a precision grinder or lathe.
  • the excess material may be removed by electrical discharge maeluning (EDM) wherein the EDM system may comprise the electrodes and power supply.
  • EDM electrical discharge maeluning
  • the electric current runs from the positive terminal of the power supply, up the positive rail, across the armature comprising the fuel shot or pellet, and down the negative rail back to the power supply.
  • the current flowing in the rails creates an azimuthal or circular magnetic field about each rail axis.
  • the magnetic field Sines run in a counterclockwise circle around the positive rail and in a clockwise circle around the negative rail with the net magnetic field between the rails directed vertically.
  • current is channeled through additional pairs of parallel conductors, arranged to increase the magnetic field applied to the shot or pellet.
  • externa) magnetic fields may be applied mat act on the shot or pellet when current is flowed through it.
  • the shot or pellet projectile experiences a Lorentz force directed perpendicularly to the magnetic Field and to ihe direction of the current flowing across the armature comprising the shot or pellet.
  • the Lorentz force F that is parallel to the rails is given by
  • F ii x B (37) where is the current, L is the path length of the current through the shot or pellet between the rails, and B is the magnetic flux.
  • the force may be boosted by increasing either the diameter of the fuel shot or pellet or the amount of current.
  • the kinetic energy of the shot or pellet may be increased by increasing the length of the rails.
  • the projectile under the influence of the Lorentz force, accelerates to the end of the rails and exits to fly to the inter- electrode region. The exit may be through an aperture. With the exit, the circuit is broken, which ends the flow of current.
  • the force is 0.03 N.
  • the corresponding kinetic energy for 5 cm length rails is 0 0015 J. From the kinetic energy, the fma! velocity of an 80 mg shot is 6 m/'s.
  • the shots or pellets may be fed into the injector.
  • the feed may be from a hopper.
  • the feeder may comprise one of the disclosure such as a mechanical feeder.
  • the feeder may comprise a vibrator.
  • the feeder may comprise at least one of a piezoelectric vibrator and an actuator.
  • the feeder may comprise at least one of an auger and a trough. The latter may have a slot along the bottom to feed along the railgun.
  • the shot or pellets may be fed from a plurality of positions along the railgun injector.
  • the feeding may be achieved by at least one method of mechanically and hydraulically.
  • the shots recovered from the quenching water bath are dried in a dryer such as an oven such as a vacuum oven before entering the evacuated region of the injector system such as the feed to the injector such as a railgun injector, in an embodiment, at least one of the pelletizer, the water reservoir or bath for cooling and forming of the shots, and the transporter to remove the shots from the water reservoir are connected to the cell under vacuum conditions.
  • the transporter may dram excess water from the shot.
  • An exemplar ⁇ ' transporter comprises a conveyor that is permeable to water. The shot may be removed when sufficiently hot that surface absorbed water is evaporated.
  • the water evaporated from at least one of the shot and the water reservoir may be removed from the cell atmosphere to maintain a desired low pressure by a pump such as a vacuum pump or a cryopump.
  • the cryopump may comprise a water condenser.
  • a condenser may be used in lieu of a vacuum pump to at least one of partially evacuate the cell and maintain the cell under reduced pressure,
  • a water condenser may decrease the pressure due to the water vapor by condensing the water.
  • the water may be recycled to the reservoir or bath.
  • the water from the condenser may be recirculated to the reservoir or bath by a return water line such as a return water drip line.
  • the water condenser may be chilled with chiller such as at least one of an air-cooled radiator, refrigerator chiller, and Peltier chiller.
  • chiller such as at least one of an air-cooled radiator, refrigerator chiller, and Peltier chiller.
  • Other chillers known in the art may be used to chili the condenser to a desired temperature
  • the water vapor pressure in the cell is determined by the temperature of the condenser that may be in the range of about 0 0 C to 100 °C.
  • a typical industrial water chiller operates at about 17 °C con-espo ding to a water vapor pressure of about 13 Torr
  • the chiller may directly chill the reservoir or bath so that the water vapor is condensed directly into the reservoir or bath and the water return line is eliminated.
  • the dry shot may be transported to the injector by a second transporter such as an auger to the shot injector.
  • the shot injector may comprise a railgun injection system wherein the highly conductive shot may serve as the armature and its contact with the electrified rails may trigger the current across the rails to cause the Lorentz force propulsion of the shot into the electrodes such as the roller electrodes.
  • Exemplary shot comprises silver spheres having entrapped gases such as at least one of 3 ⁇ 4 and 3 ⁇ 40.
  • the shot may be formed by dripping and quenching the corresponding melted material in a bath or reservoir such as a water bath or reservoir.
  • the shot transporter auger and shot injector feed auger are replaced.
  • water jets make a water fluidized bed feed to the raiigun injector wherein the inlet to the rail gun is in the water bath and travels outside of bath to the injection site.
  • the fluidized water bath may serve a purpose of preventing adhesion of hoi/cooling shots and transporting and loading shot.
  • the water bath or reservoir to coo! the meit and form shot further comprises an agitator to stir the shot.
  • the agitator may comprise water jets that may be driven by at least one water pump. The actioa of the water jets may foam a fluidized bed.
  • the agitator may further comprise a mechanical agitator such as an auger, a stirrer, or a vibrator such as ao electromagnetic or piezoelectric vibrator and other agitators k own in the art.
  • the bath comprises a raiigun in a position to receive shot and propel it into the electrodes for ignition.
  • a shot input section of the raiigun may be positioned in the bottom of the bath and may comprise a trough or hopper to receive shot agitated in the water bath by the agitator,
  • the rai igun injector may penetrate the wall of the bath to be directed at the ignition region of the electrodes.
  • the raiigun may have a guide path shape the transports the shot form the bottom of the bath to the ignition region of the electrodes such as roller electrodes.
  • the raiigun may comprise a means to drain any water moved with the shot back into the bath as ⁇ he shot travels with at least some vertical travel above the water level of the bath. Water thai does not flow back into the bath such as water that is ejected with the shot may fall to a receiving hopper at the bottom of the cell and be pumped back into the bath with a drainage water pump. Water that is vaporized by the hot shot may be condensed into the bath by the bath chiller. The shot may be hoi to provide drying. The elevated temperature of the shot may be from the residua!
  • the ceil, the pelletizer such as the one comprising to chambers, the water bath, and the injection raiigun may be maintained in continuity regarding the gas pressure and evacuated cell atmosphere.
  • the SF-CIBT cell may operate according to at least one of independent of its orientation relative to Earth and independent of gravity.
  • the shot water bath may be sealed, expandable, and capable of maintaining a pressure in the range of about
  • the pressure P may about match or exceed that of the water pressure column of the bath of height h given by Eq. (38) wherein the density p is the density of water and g is the gravitational acceleration (9.8 m/s 2 ).
  • the shot dripper may be very highly thermally insulated to prevent excessive cooling of the meit in the dripper by contact with the bath water.
  • the systems that transport fuel and the ignition product may operate using the Lorentz force applied by intrinsic or augmented magnetic fields and currents.
  • the shot injection system may comprise an augmented railgun of the disclosure.
  • the ignition product recovery system may comprise an augment plasma railgun of the disclosure.
  • the pelieiizer may transport at least one of the powder ignition product and the melt using an augmented railgun comprising applied magnetic fields and applied current flowed through at least one of the powder and melt.
  • the current and magnetic field are transverse to the desired direction of flow and are mutually perpendicular according to Eq. (37).
  • the system may comprise the appropriate current electrodes and magnets to achieve the transport.
  • the railgun transporters may have sensors and controllers to monitor the Lorentz forces, the flow rates, and apply current to achieve the desired forces and flow rates.
  • the means to transport at least one of the powder and melt through the pelletizer may comprise a pump such as an electromagnetic pump such as those known in the literature.
  • the agitator such as water jets may agitate shot in the bath to be input to the railgun.
  • a mechanical agitator may also feed shot into the augmented railgun injector.
  • the mechanical agitator may be large relative to the water bath such that the agitator may function irrespective of the cell's orientation relative to gravity.
  • a large diameter auger with an equal gap with the top and bottom of the water reservoir may push shot to the railgun independent of the cell's orientation.
  • the water pump may return any water lost from the shot water bath through the railgun injector by pumping it at a rate that matches any loss.
  • the SF-CIHT cell such as embodiments shown in FIGURES 2110- 21120 may operate according to at least one of independent of its orientation relative to Earth and independent of gravity.
  • the cell may be secured on a gimbal such that it is always maintained with the z-axis away from the center of gravity of the Earth. Then, the ceil will operate independent of the orientation of a craft to which the gimbal is mounted.
  • the SF-CIHT cell may comprise a centrifugal platform that spins or permits t least one of the SF-CIHT cell, at least one component, and at least one system to spin or rotate wherein the components or systems such as the injection system and pelletizer system are positioned in a location in the ceil that permits the development of a centrifugal force that replaces the force of gravity in gravity's role in the operation of the cell such as in returning the shot or ignition product to the pelletizer.
  • the spinning or rotation may force the ignition particles to the perimeter.
  • the particles forced to the perimeter may be transported to the pelletizer inlet.
  • the transporting may be by means and methods of the disclosure such as mechanical transport or pumping.
  • An electromagnetic pump may achieve the pumping.
  • At least one component or system such as the cell wall, electrodes, injection system, ignition product recovery system, and pelleiizer may comprise a mechanism that causes it to spin to develop a centrifugal force to replace the action of gravity.
  • the spinning mechanism may be one known to those skilled in the art such as a platform or structural support holding the component or system mounted on bearings and driven by an electric motor.
  • the system may comprise (i) a cell such as a vacuum cell, (ii) an ignition system comprising the roller electrodes and bus bars, (iii) an injector such as a railgun injector, (iv) a ignition product recovery system that may comprise at least one of an augmented plasma railgun recovery system and gravity flow into (v) a hopper connected to the bottom of the cell, (vi) a pelleiizer comprising a first vessel to receive ignition product from the hopper, a heater to melt the ignition product, and a second vessel to apply at least one of hydrogen and steam to the melt, (vii) a bath such as an 3 ⁇ 40 bath to receive dripping melt from a dripper of the second vessel to form shot, (viii) a shot conveyor, (ix) a drier such as a vacuum oven to receive the shot, (x) a means to transport the shot to the injector such as a chute with controllable vacuum lock passage, (xi) a conveyor such as an auger to transport the shot to the injector such
  • FIGURE 2H1 An embodiment of a SF-CIHT cell power generator showing a cell capable of maintaining a vacuum, an ignition system having a railgun shot injection system fed by two transporters, augmented plasma railgun and gravity recovery systems, a pelleiizer, and a photovoltaic converter system is shown in FIGURE 2H1.
  • the SF- CIHT cell power generator may comprise i.) a cell 26 such as a vacuum ceil that may comprise a co ical cylinder having a vacuum pump 13a; ii.) an ignition system 8a with a power supply 2; iii) a photovoltaic converter system 26a comprising photovoltaic cells or panels 15 to receive the light from the ignited fuel and convert it into electricity, the converter having a heat exchanger 87 for cooling wherein the hoi coolant flows into the photovoltaic converter cooling system 31 through inlet 31 b and chilled coolant exits through outlet 31 c; and iv) a fuel formation and delivery system 8b having a water reservoir for quenching dripped melt to form shot, the reservoir having a cooling system 31 a wherein the hot coolant flows into the water reservoir cooling system 3 l a through inlet 3 Id and chilled coolant exits through outlet 31e, Details of the ignition system 8a and its power supply 2 are shown in FIGURE 2H2.
  • a cell 26 such as
  • the ignition system 8a comprises a source of electrical power 2 to flow a high current through bus bars 9 and 10, slip rings 73a, shafts 7, and the roller electrodes 8 that are mounted on the shafts 7 suspended by bearings 4a attached to structural support 4 being mounted on base support 61.
  • the shafts and attached electrodes 8 are ruined by roiier drive pulleys 71 a that are driven by belts 72 each having a belt tensioner 72a, motor shafts and pulleys 71 suspended on bearings 73, and motors 12 and 1 3.
  • FIGURE 2H3 Details of the ignition system 8a and the photovoltaic converter system 26a are shown in FIGURE 2H3.
  • the fuel may be injected by augmented railgun injector 8f.
  • the power supply 2 may receive power from the photovoltaic converter 26a and supply a high current to roller electrodes 8 to cause ignition of fuel to form plasma in ignition location 8e,
  • the upward trajectory of the ignition products may be interrupted by the light transparent baffle 8d that may be concave.
  • the ignition products may be recovered by at least one of gravity in the evacuated ceil .26 and by the augmented plasma rai!gun recovery system comprising Heimholtz coil magnets 8c and the current flowing between electrodes 8 through the plasma. Details of the ignition 8a and the fuel formation and delivery system 8b comprising the ignition product recovery system 8c, and the pelletizer to form shot fuel 5a, and the injection system 8f are shown in FIGURE 2H4.
  • shot fuel may be injected into the roller electrodes 8 by the augmented railgun injector Sf that is fed pellets from water reservoir 1 1 of pelletizer 5a, conveyed by shot transport auger 66a into injector auger hopper 66b and then injection auger 66 driven by Injector auger motor and drive shaft 67.
  • the roller electrodes 8 may receive high current from power supply 2 that flows through each sequentially injected shot to cause ignition of the fuel to form a brilliant light emitting plasma that is converted into electricity by photovoltaic convener 26a (FIGURES 2HI and 2H3).
  • the upward trajectory of the ignition products may be interrupted by the light transparent baffle 8d, and the ignition products may be recovered by at least one of gravity in the evacuated cell 26 and by the augmented plasma railgun recovery system comprising
  • the ignition products may flow into a First vessel 5b of the pelletizer 5a that may comprise a crucible 5d that may be insulated with insulation 5e.
  • the products may heated by inductively coupled heater 5f to a melt. Shot that does not ignite may flow to the first vessel 5b of the pelletizer 5a along with the recovered ignition products.
  • the melt may flow into the second vessel 5c of the pelletizer 5a wherein the melt may be exposed to at least one of steam and hydrogen gas supplied by inlet lines 5g and 5h.
  • the gases may be recirculated to incorporate the gases into the melt that drips out the shot dripper 5s and quenched in the water reservoir 1 1 to form shot.
  • the hydrogen may be supplied from a tank refilled by the electrolysis of water, and the water may be supplied for a water tank wherein the water in both cases is periodically refilled as water is consumed.
  • the water may be absorbed from the atmosphere by a water absorbing material such as a hydroscopic material.
  • the water may be condensed from the atmosphere using a condenser powered by the SF-CIHT cell. Excess potable water may be generated in the same manner.
  • the reservoir may have a cooling system 31 a wherein the hot coolant flows into the water reservoir cooling system 31a through inlet 3 Id, and chilled coolant exits through outlet 31e.
  • the temperature of the bath in connection with the evacuated cell 26 may be controlled to control the vapor pressure of water vapor in the cell.
  • the cell pressure may also be controlled using vacuum pump 1 3a shown in FIGURE 2HI .
  • An embodiment of a SF-CIHT cell power generator showing a cell capable of maintaining a vacuum, an ignition system having a railgun shot injection system fed directly from a pelletizer, augmented plasma railgun and gravity recovery systems, the pelletizer, and a photovoltaic converter system is shown from two perspectives in FIGURE 211.
  • the SF-CIHT ceil power generator may comprise i.) a ceil 26 such as a vacuum cell that may comprise a co ical cylinder having a vacuum pump 13a; ii.) an ignition system 8a with a power supply 2; iii) a photovoltaic converter system 26a comprising photovoltaic cells or panels 15 to receive the light from the ignited fuel and convert it into electricity, the converter having a heat exchanger 87 for cooling wherein the hot coolant flows into the photovoltaic converter cooling system 31 through inlet 3 1 b and chilled coolant exits through outlet 31c; and iv) a fuel formation and delivery system 8b having a water reservoir for quenching dripped melt to form shot, the reservoir having a cooling system 31 a wherein the hoi.
  • a ceil 26 such as a vacuum cell that may comprise a co ical cylinder having a vacuum pump 13a
  • an ignition system 8a with a power supply 2 iii)
  • the coolant flows into the water reservoir cooling system 31 a through inlet 3 id and chilled coolant exits through outlet 3 le.
  • Details of the ignition system 8a and its power supply 2 are shown in FIGURE 2H2.
  • Details of the ignition system 8a and the photovoltaic converter system 26a are shown in FIGURE 213.
  • the fuel may be injected by augmented railgun injector 8f.
  • the power supply 2 may receive power from the photovoltaic converter 26a and supply a high current to roller electrodes 8 to cause ignition of fuel to form plasma in ignition location 8e.
  • the upward trajectory of the ignition products may be interrupted by the light transparent baffle 8d that may be concave.
  • the ignition products may be recovered by at least one of gravity in the evacuated ceil 26 and by the augmented plasma railgun recovery system comprising Heimholtz coil magnets 8c and the current flowing between electrodes 8 through the plasma.
  • the augmented plasma railgun recovery system may comprise permanent magnets with electromagnets such as Heimholtz coils as adjustable or shimming magnets to refine the magnetic field to give fine control over the fuel recovery process. Details of the ignition 8a and the fuel formation and delivery system 8b comprising the ignition product recovery system 8c, and the pelletizer to form shot fuel 5a, and the injection system 8 f are shown in FIGURE 2H4.
  • the magnets such as 8c may be located outside of the cell 26 wherein the cell material is permeable to the magnetic field of the magnets.
  • shot fuel may be injected into the roller electrodes 8 by the augmented railgun injector 8f that is fed pellets from water reservoir 1 1 of pelletizer 5a, conveyed by auger agitator 16a or a water jet agitator fed by agitator water jet line 15 (FIGURE 215).
  • the roller electrodes 8 may receive high current from power supply 2 that flows through each sequentially injected shot to cause ignition of the fuel to form a brilliant light emitting plasma that is converted into electricity by photovoltaic converter 26a (FIGURES 21 ! , 212, and 213).
  • the upward trajectory of the ignition products may be interrupted by the light transparent baffle 8d, and the ignition products may be recovered by at least one of gravity in the evacuated cell 26 and by the augmented plasma raiiguo recovery system comprising
  • the ignition products may flow into a firsi vessel 5b of the pelletizer 5a that may comprise a crucible 5d that may be insulated with insulation 5e.
  • the products may be heated by inductively coupled heater 5f to a melt. Shot that does not ignite may flow to the first vessel 5b of the pelletizer 5a along with the recovered ignition products.
  • the melt may flow into the second vessel 5c of the pelletizer 5a wherein the melt may be exposed to at least one of steam and hydrogen gas supplied by inlet lines 5g and Sh.
  • the gases may be recirculated to incorporate the gases into the melt that drips out the shot dripper 5i and quenched in the water reservoir 1 1 to form shot.
  • the reservoir may have a cooling system 3 la wherein the hot coolant flows into the water reservoir cooling system 31a through inlet 3. Id, and chilled coolant exits through outlet 31e.
  • the temperature of the bath in connection with the evacuated cell 26 may be controlled to control the vapor pressure of water vapor in the cell.
  • the ceil pressure may also be controlled using vacuum pump 13a shown in FIGURES 211, 212, and 213.
  • the pressure in the first vessel 5b and the second vessel 5c of the pelletizer 5a are the same such that the metal head pressures are equilibrated wherein the metal head pressure in the second vessel 5c may be determined by the height from the exit of the metal passage 5j to the metal level in the second vessel 5c and the metal head pressure in the first vessel 5b may be determined by the height from the exit of the metal passage 5j to the metal level in the first vessel.
  • the metal level in the second vessel may automatically adjust due to this principle to be maintained nearly constant on average.
  • the pressure in the two vessels is different such as in the case that elevated pressure gas such as at least one of hydrogen and steam is added to the second vessel to be incorporated into the shot.
  • a pump such as an
  • electromagnetic pump 5k may control the metal level in the second vessel 5c.
  • the level may be sensed with a sensor such as a conductivity sensor or an optical one such as an infrared sensor and the level controlled by the electromagnetic pump power supply and a computer.
  • the pelletizer may comprise at least one sensor for the flow of metal into the input of the pump 5k with a safety shut off valve to turn off the current to the pump when there is at least one of reduced volume or flow of metal into the pump.
  • flow sensors may be located in d e vessels such as 5b and 5c. that serve to provide input data such as at least one of melt flow and melt volume to a controller to shut off the heaters such as 5f and 5o when there is inadequate melt volume or flow in these sections of the pelletizer.
  • each shot dripper produces shot in single file at a rate that matches the injection rate and the ignition rate to achieve a steady state power output and continuity of mass flow.
  • This matching rate and single file aspect of the shot stream from the dripper may be used to load the injector such as the railgun injector at the matching rate.
  • Each shot discharged from the dripper is initially in a molten state. The shot may be cooled in route to the input to the injector. The shot may be flowed single file along a water slide 51.
  • the water slide 51 may comprise a conduit such as a channel, chute, or trough having streaming water such as that provided by water jet 16 or a water bath i i that cools the shot as it flows from the dripper to the input to the injector such as the raiigun.
  • the channel may direct shot directly to the raiigun injector without discharging them into the water bath 1 1.
  • the water may flow around the rails in a manner to load the shot onto the rails to be injected.
  • the channel may discharge the shot into a water bath 1 1 that may be shallow enough to maintain a single file shot stream that flows to the injector input.
  • the water may be recirculated through a chiller 3 la to maintain a low temperature and remove the heat released in the partial cooling of the shot.
  • the shots may arrive in single file to the raiigun injector 8f such that at least one of the slide and shallow bath may replace the agitator such as the auger 16 or water jet 16a (FIGURE 2 ⁇ 5) to facilitate loading the raiigun injector 8f.
  • the agitator such as the auger 16 or water jet 16a (FIGURE 2 ⁇ 5) to facilitate loading the raiigun injector 8f.
  • the shot may be cooled just sufficiently to form a thin solid shell on the outer surface such as a shell having a thickness in at least one range of about 1 nm to 100 urn, 10 nra to 10 urn, and 100 nm to 1 um.
  • the hot shots will require at least one of less energy', lower ignition current, and less time under ignition power to ignite by arriving preheated; thus, some of the heat from the pelletizer is recovered.
  • the ignition may be more complete such that the fuel formation and power release is more efficient with higher gain.
  • the only partial cooling with the injection of preheated shot may serve as the heat recuperator.
  • the preheated temperature may be in at least one range of about 100 °C to 950 °C, 300 °C to 900 °C, and 400 °C to 900 °C.
  • the ignition energy per shot may be essentially that to melt the thin shell.
  • the ignition product may comprise at least one of plasma, molten metal, and elevated temperature molten metal.
  • the products may be recovered to the input to the pelleh ' zer while still at an elevated temperature such as at least one temperature range of about 100 °C to 950 °C, 300 °C to 850 °C, and 400 °C to 900 °C.
  • the hot powder may be further elevated in temperature by the heater such as the inductively coupled heater.
  • the elevated temperature may be in at least one range of about 965 °C to 3000 °C, 965 °C to 2000 °C, and 965 °C to 1500 S C.
  • the pelletizer input heat energy may be a small fraction of that to melt room temperature ignition product.
  • the round trip energy consumption comprising the contributions from melting the preheated thin-shelled shot and melting the hoi recovered products to an elevated melt temperature may be minimized.
  • the injector comprises a pump such as an electromagnetic pump 5k that pumps molten fuel such as molten silver metal treated with a source of hydrogen and a source of catalyst such as 3 ⁇ 4 and steam into the gap between the electrodes such as roller electrodes 8.
  • the pump 5k may operate by the same principle as thai of the raiigun wherein a current is passed through the melt and a
  • the pump may also comprise a mechanical pump.
  • mechanical molten metal pumps incorporate graphite or ceramic impellers.
  • the pump 5k may comprise and electromagnetic pump that comprise powerful, permanent magnets and DC current to propel the molten metal, eliminating a mechanical pump impeller.
  • a motive force is directly applied to the liquid metal by supplying an electrical current through the metal within a strong magnetic field according to the Lorentz Force Law.
  • the strength of the current directly controls the force on the metal, and hence the volume of flow, in an embodiment, ihe magnetic field is supplied by high-strength, permanent magnets, and the current is direct, or DC current, supplied by industry standard rectifier power supplies.
  • the result is an electromagnetic pump with higher flow rates at reduced energy consumption compared to AC
  • electromagnetic pumps Exemplary manufacturers and vendors of suitable electromagnetic pumps and flow meters for liquid metal are Hazelett, CMI Novacast, Suzhou Debra
  • the metal flows through a straight pipe that is partially flattened over part of its length, where the races of an electromagnet are positioned (keeping the gap between the pole faces small).
  • the tube of the electromagnetic pump may comprise a high-temperature metal such as a refractory metal such as molybdenum, tantalum, niobium, or tungsten pump tube.
  • a refractory metal such as molybdenum, tantalum, niobium, or tungsten pump tube.
  • the pump tube is difficult to machine, it may be fabricated by other methods known in ihe art such as casting, electrical discharge machining, and metal printing.
  • the melt may comprise one having a lower melting point than at least one of stainless steel and a non-refractory metal.
  • the melt may comprise an alloy such as a silver-copper alloy such as Ag-Cu (72 wt%/28 wt%) that has a melting point of 779 °C.
  • Exemplary pump tubes that have a higher melting point are high-temperature stainless steel such as Haynes 188, Haynes 230, Haynes HR-16Q, Hastelloy X, nickel, and titanium.
  • the pump tube has at least one property of wettability by silver such that it is protected from reaction with H 2 0 and is non-reactive with water.
  • Suitable exemplary materials for the tube that lack 3 ⁇ 40 reactivity with sufficient meltiiig points axe at least one of the metals and alloys from the group oFCu, Ni, CuNi, Haynes 188, Haynes 230, Haynes HR-160, Hastelloy C, Hastelloy X, inconel, Incoloy, carbon steel, stainless steel, chromium- molybdenum
  • any oxide coat on the inner wall of the pump tube that may decrease the current through the pump tube walls and the connection with the melt such as silver melt inside of the tube may be removed by methods known by those skilled in the art such as at least one of chemical, mechanical, and plasma etching and electroplating.
  • the chemical method of removing the inner wall oxide may comprise etching with acid and neutralization.
  • the plasma method of removing the inner wall oxide may comprise at least one of electrical discharge machining and vapor deposition, in an embodiment, any oxide coat is removed for the inside of the pump tube by means known in the art such as acid or plasma etching.
  • the inside of the tube may be coated with the metal of the fuel melt such as silver or silver-copper alloy to protect the inside wall from oxidation until put into use.
  • the coating may be achieved by at least one method comprising application of the molten metal, electroplating, eiectroless plating, vapor deposition, chemical deposition, and other methods known by those ski lled in the art.
  • the pump further comprises bus bas or metal tabs having electrical connections to the side of the tube in this same area that introduce an electrical current flow into the molten metal.
  • the bus bars may be attached with high resistance welds, or ceramic feed-throughs may be used for the bus bars of the EM pump tube thai supply current to the pumped molten metal such as the Ag metal Ceramic feed-throughs may be cooled by means such as gas or wafer cooling.
  • Each EM pump bus bar or tab may be contacted directly to the molten metal such as molten silver by the steps of (i) machining penetrations such as rectangular penetrations in the sides of the tube wall on opposite wails that are each a tight fit with the bus bar when the tube is at an elevated temperature, (ii) heating the tube to expand the penetrations to accommodate the bus bars, (iii) inserting the bus bars through the molten metal such as molten silver by the steps of (i) machining penetrations such as rectangular penetrations in the sides of the tube wall on opposite wails that are each a tight fit with the bus bar when the tube is at an elevated temperature, (ii) heating the tube to expand the penetrations to accommodate the bus bars, (iii) inserting the bus bars through the molten metal such as molten silver by the steps of (i) machining penetrations such as rectangular penetrations in the sides of the tube wall on opposite wails that are each a tight fit with the bus bar when the tube is at an elevated temperature, (ii) heating the tube to
  • each EM pump bus bar or tab may be contacted directly to the molten metal such as molten silver by the steps of (i) machining flaps in the sides of the tube wall on opposite walls that are each a tight fit with the bus bar, (ii) inserting the bus bars throug the slits of the flaps, and (iii) mechanically squeezing the flaps onto the bus bars to form a compression bond of the bus bare to the pump tube, in another embodiment, the tabs may be welded to inwardly projecting dimples made in the opposite side wails of the flattened tube.
  • the current may be selectively supplied to the melt inside of the tube by increasing the contact area of the pump bus bar with the metal relative to the area in contact with the pump tube wall.
  • the contact area with the melt may be increased by inserting die bus bar into the melt by having it protrude through the pump tube wall inside of the tube.
  • the inner protrusion may comprise a shape or structure such as a curved plate to increase the surface area of contact with the melt.
  • the bus bar may be fastened to the pump tube wall by at least one of we!ds and compression bonding.
  • Exemplary pump tubes and bus bars comprise at least one from the group of zirconium, niobium, titanium, and tantalum.
  • the bus bars may each comprise a coating of low conduetiveiy such as an oxide coat at the region of contact of the bus bar with the tube wall at the penetration.
  • Exemplary bus bars and the corresponding low conductivity coatings are zirconium and zirconium oxide, niobium and niobium oxide, titanium and titanium oxide, nickel and nickel oxide, and tantalum and tantalum oxide, respectively.
  • the oxide may be formed by heating in oxygen or by anodizing.
  • the sections that are desired to be conductive that contact the melt may be masked during oxidation, or the oxide may be removed from the melt contact regions after the bus bar is coated with oxide by means such as mechanical abrasion, chemical etching, or chemical reduction.
  • the high resistance between the bus bar and the ceil wall causes the low resistance electrical path to be through the metal melt inside the pump tube.
  • the electrical current may flow across the flattened section while the magnetic flux may pass through the flattened section at right angles to the current flow, and this may produce a force on the metal that is at right angles to the current and magnetic flux.
  • the electromagnetic pumps may operate on direct current or alternating current.
  • the magnets may comprise permanent magnets or DC electromagnets.
  • the magnets When operated with alternating current, the magnets comprise AC electromagnets.
  • the direction of the flow of electricity in the metal may change every half-cycle, and the electromagnets may also be powered by the same alternating current such that the magnetic field may also change direction eveiy half-cycle, so the force on the metal may pulsate but may always be in the same direction.
  • the pump may be convection cooled. Although, if the pumped metal temperature such as silver is high such as 1000 °C and higher, the pump may be cooled with supplemental cooling such as forced convection and water-cooling.
  • energy is dissipated as ohmic heating of the metal by the flow of current through the metal to cause pumping by electromagnetic pump 5k, and this energy supplements the heating by the heater 5o of the second vessel 5c.
  • the metal may be directly resistiveiy heated by flowing current through it using electrodes in contact with the metal.
  • the pump 5k may comprise a 3-phase linear annular induction pump.
  • the pump may comprise two annular tubes separated by a space.
  • the metal may flow through the annular" space between two concentric tubes wherein the inner of ihe two tubes may contain a magnetic core, through which the lines of a moving radial magnetic field are looped.
  • a 3- phase stator around the tube may develop the field.
  • the flow of induced currents may be circular, within the annular space, cutting the lines of the field.
  • An axialiy exerted force may result that may move the liquid metal through the pump.
  • the pelletizer may comprise a flow meter such as one known by those skilled in the art.
  • the flow meter may comprise a Lorentz force velocimeter or Lorentz flow meter that measures the integrated or bulk Lorentz force resulting from the interaction between the liquid metal in motion and an applied magnetic field.
  • the flow meter may comprise one based on Faraday's law of induction wherein a magnetic, field is applied along the transverse x-axis, a set electrodes are applied along the transverse y-axis, and the flow of the conducting molten metal along the z-axis produces a voltage across the electrodes that is linearly proportional to the velocity of the flow according to Faraday's law of electromagnetic induction.
  • the flow meter may comprise a coniactless electromagnetic flow meter that operates by measuring the amount of distortion in a magnetic field that is caused by movement of a conductor within that magnetic field.
  • permanent magnets may be set near the moving material.
  • the moving material may or may not be contained within a pipe or conduit.
  • the amount of shift of the magnetic field may be measured in the direction of melt flow corresponding to the velocity of the melt that is read out by a calibrated indicator as a flow rate.
  • the pressure of the molten fuel may be sufficient to form shot 5t. as it ejects out of a nozzle 5q
  • the gas pressure may be elevated relative to the cell pressure such as in at least one range of about 0,01 Torr to 100 aim, 1 Torr to 30 aim, 10 Torr to 5 atm, and 100 Torr to 1 atm
  • the electromagnetic pump 5k may develop a pressure greater than that of the gas pressure to cause melt flow and ejection from the vessel and nozzle.
  • the shot 5t may comprise projectiles that enter the inter-electrode region to cause contract between the otherwise non-contacting electrodes 8. The consequential high current flow results in ignition of the fuel such as the formation of plasma.
  • the fuel may- comprise a continuous stream rather than shot or a combination of intervals of continuous stream mixed with shots.
  • the pressure in the pelletizer 5a developed by the pump 5k is greater than at least one of the pressure of any gases applied to the melt such as 3 ⁇ 4 and steam and the pressure corresponding to gravity at a height of the electrodes over the nozzle 5q. In the latter case, after leaving the nozzle 5q, the ejected fuel has sufficient kinetic energy to transport it to the ignition site between the electrodes against gravity.
  • the ignition products are recovered and collected in the first vessel of the pelletizer 5b and are melted.
  • the melt may be pumped by at least one electromagnetic pump 5k.
  • the inlet of the first vessel 5b may be aligned along the vertical axis (z-axis) of the cell 26.
  • the melt may flow from the first vessel 5h into the pump 5k that pumps the melt into the second vessel 5c.
  • the second vessel 5c may have a section that bends such that the rae!t flow direction gradually changes from along the negative z-axis to along the positive z-axis towards the injection or ignition site comprising the region of closest proximity of the opposing separated electrodes 8.
  • At least one of the first vessel 5b and the second vessel 5c may be pipe-like.
  • the vessels comprise an arc, semicircle, U-shape, or other such shape to permit the receipt of ignition product from the cell at the inlet and ejection of regenerated fuel into the electrodes of the cell at the outlet or nozzle.
  • the EM pump height from the pump in be to the top of the EM pump is reduced.
  • the height of the permanent magnet such as a neodyniium magnet and a shallow magnetic pole piece of the magnetic circuit may give the desired overall height.
  • This EM pump section distal to the pump tube may be cooled.
  • the distal section may comprise a thermally insulating spacer and a cold plate in the magnetic circuit to thermally isolate and cool the distal magnet.
  • the cool or cold plate may comprise a micro-channel plate such as one of a concentrator photovoltaic cell such as one made by Masimo or a diode laser cold plate that are known in the art.
  • the second vessel 5c may comprise at least one manifold that supplies at least one of 3 ⁇ 4 and gaseous 3 ⁇ 40 to the melt such as hydrogen manifold and input lines 5w and steam manifold and input lines 5x as the melt flows towards a nozzle 5q at the end of the pipe-like second vessel 5c directed at the injection site
  • the H 2 and 3 ⁇ 40 injection system comprises gas lines, manifolds, pressure gauges, regulators, flow meters, and injectors and may further comprise a H 2 -sieam mixer and regulator in case that both gas are injected with a common manifold.
  • liquid water may be injected into the melt.
  • the injection may be achieved by at least one of a pump such as a peristaltic pump and gravity feed.
  • the metal of the fuel may comprise a copper-silver alloy. 3 ⁇ 4 gas injected into the melt through hydrogen manifold and input lines 5w may be used to reduce any oxide of the alloy such as CuO formed during the operation of the cell.
  • oxide of the alloy may be reduced in situ in the cell by addition of hydrogen gas that may be intermittent. Oxide of the alloy may also be reduced by hydrogen treatment outside of the cell.
  • the pe!!etizer 5a may be heated with at least one heater such as at least one inductively coupled heater.
  • the inductively couple heater may comprise and inductively coupled heater power supply 5m.
  • the pelleiizer 5a may be heated with a first inductively coupled heater coil 5f that may extend along the first vessel 5b from its inlet to the inlet of the electromagnetic pump 5k.
  • the first inductively couple heater comprising coil 5f may be circumferential to the first vessel 5b having crucible 5d and insulation 5e.
  • the heater may further comprise a second inductively coupled heater coil 5o that may extend along the second vessel 5c from the outlet of the electromagnetic pump 5k to the nozzle 5q of the second vessel 5c.
  • the second inductively couple heater comprising coil 5o may be circumferential to the second vessel 5c having crucible 5d and insulation 5e.
  • the corresponding first and second heating coils define a first and second heating section or zone.
  • the fust section may be heated to a temperature that is at least above the melting point of silver (962 °C) to form the melt that is pumped.
  • the vessel and coil may comprise a high Q cavity further comprising the recovered product melt.
  • a gas such as at least one of H 2 0 and 3 ⁇ 4 may be injected to increase the resistivity of the melt to improve the coupling of the radiation from the inductively coupled heater with the melt.
  • the second section may be superheated relative to the first.
  • the temperature of the melt in the second section may be maintained in at least one range of about 965 °C io 3000 °C, 965 °C to 2000 ⁇ ⁇ , and 965 a C to 1300 "C.
  • An optical pyrometer, thermistor, or thermocouple may be used to monitor the temperature of the melt.
  • power dissipated in the pump 5k due to mechanisms such as resistive heating may contribute to heating the melt.
  • the superheating may increase the absorption of at least one treatment gas such as at least one of 3 ⁇ 4 and steam in the melt.
  • the pelletizer may comprise a plurality of heaters such as inductively coupled heaters each comprising an antenna such as a coil antenna and an inductively coupled heater power supply 5m to supply electromagnetic power to heater coils 5f and 5o through inductively coupled heater leads 5p.
  • the inductively coupled heater power supply 5m may comprise a shared power supply to the plurality of antennas wherein the power to each antenna may be adjusted by a circuit such as a matching or tuning circuit.
  • each antenna may be driven by its independent power supply.
  • each heater may further comprise a controller of the power delivered by each coil
  • the inductively coupled heater comprises one antenna driven by one power supply wherein the antenna is designed to selectively deliver a desired proportion of the power to each of the first heating section and second heating section.
  • the heating power may be divided between the two sections according partition means such as fixed differences in (i) antenna gain achieved by different numbers coil turns for example, (ii) variable, controllable antenna gain, (iii) switches, and (iv) matching or tuning networks.
  • the two coil sections may be connected by additional inductively coupled heater leads 5p between the sections that may bridge the electromagnetic pump 5k.
  • the leads may be designed to transmit rather than dissipate power such that the heating power is selectively delivered and dissipated into the fuel melt by the coils 5f and So.
  • the sections heated by inductively coupled heaters may each comprise a crucible comprising material transparent to the radiation such as Rp radiation of the inductively coupled heater.
  • Exemplary materials are silicon dioxide such as quartz or silica, zirconia, and sapphire, alumina, gF 2> silicon nitride, and graphite.
  • Each crucible may be insulated with high temperature insulation 5e that is also transparent to the radiation of the inductively coupled heater.
  • the portion of the second vessel 5c that is in contact with the electromagnetic pump 5k may comprise a conductor and a magnetie-field-permeable material such that the applied current and magnetic field of the pump 5k may pass through the melt.
  • the RF transparent sections may be connected to the conductive and magnetic- ield- permeabie section by joints such as ones comprising a flange and a gasket.
  • the joint may- comprise a clamp such as a C-clamp, clamshell type, bolted fittings, or tightened wires.
  • the joints may operate at high temperature and may be stable to molten fuel.
  • An exemplary gasket is a graphite gasket.
  • the gaskets may comprise a wet seal type common in molten fuel ceils wherein the fuel is liquid in the vessel and is solid at the perimeter of the joints or unions of the vessel with the pump wherein the temperature is below the melting point.
  • the union may comprise at least one of the penetration for the pipe bubbler and the valve.
  • the pump tube through the electromagnetic pump 5k may comprise a material that is transparent to the radiation of the inductively coupled heater.
  • the material of the pump tube may be the same material as that of at least one of the first vessel and the second vessel.
  • the joint may comprise a ceramic-to-ceramic joint wherein ceramic comprises a material that is transparent to the radiation of the inductively coupled heater such as at least one of silica, quartz, alumina, sapphire, zirconia, MgF 2 , and silicon nitride.
  • the joint may be eliminated such thai there is continuity of the vessel through the pump.
  • An exemplary material of at least one of the vessels and the pump tube of an exemplary induction-type or mechanical pump is silicon nitride.
  • at least one component from the group of the first vessel, the second vessel, the manifold section of the second vessel, and the pump tube may be comprise a material that absorbs the radiation of the inductively coupled heater such as a metal or graphite such that the fuel metal contained in the component is heated indirectly. The heater may heat the component, and heat transfer from the heated component may secondarily heat the fuel metal inside of the component
  • the first vessel 5b comprises an RF transparent material such as quartz.
  • the quartz section of the first vessel is connected to a metal elbow such as a high -tempera hire stainless steel (SS) elbow thai connects to a metal pipe rube such as a high-temperature stainless steel (SS) pipe tube of the electromagnetic pump 5k.
  • the tube connects to the second vessel 5c that comprises a metal elbow such as a high- temperature stainless steel (SS) elbow that further connects to an RF transparent material such as quartz.
  • the quartz rube ends in the nozzle 5q.
  • the second vessel may further comprise an S or C-shaped section that may penetrate the cell and align the nozzle 5q with the gap Sg of the electrodes 8.
  • the each joint between sections that connect may comprise a clamp and a gasket such as a graphite gasket.
  • the peiletizer comprises a short heating section 5b such as an RF transparent section, a metal joint transition to the pump tube, the electromagnetic pump 5k that may be in a vertical section of the vessel 5b, a transition to an elbow such as a metal elbow having a metal fitting or penetration for a pipe bubbler 5z that runs through a second longer RF transparent heating section 5c that ends in the nozzle 5q.
  • the RF transparent sections comprising the first and second vessels may comprise quartz
  • the quartz to metal joints may comprise quartz and metal lips on the joined sections held together with clamps.
  • An exemplary pipe tube size and vessel size are .1 cm ID and 2 cm ID, respectively.
  • the pipe tube may comprise a high temperature stainless steel, and the RF transparent vessel may comprise quartz.
  • At least one of the peiletizer components such as the melt conduit components and gas delivery component comprising at least one of the first vessel 5b, second vessel 5c, pump tube, manifold section of the second vessel 5c (FIGURE 211 1), and pipe bubbler 5z (FIGURE 2113) may comprise a material that absorbs at least some power from the inductively coupled heater(s) and indirectly heats the fuel melt such as silver or Ag-Cu alloy melt,
  • the vessel walls such as quartz, silica, sapphire, zireonia, alumina, or ceramic wal ls may be transparent to the RF power of the inductively coupled heater.
  • the peiletizer components may comprise high, temperature stainless steel, niobium, nickel, chromium-molybdenum steel such as modified 9 Cr-lMo-V (P91), 21 Cr- 1 Mo steel (P22), molybdenum, tungsten, H242, TZM, titanium, chromium, cobalt, tungsten carbide, and other metals and alloys that have a melting point higher than that of the fuel melt.
  • the metal may have a high efficiency for absorbing the radiation from the heater.
  • the components such as the vessels may be narrow to effectively heat the fuel melt indirectly. Exemplary vessels are tubes having tube sizes of the 1/4 inch to 3/8 inch ID.
  • the melt contact surfaces of the components such as the vessels, pump tube, and pipe bubbler may be pre-oxidized by means such as heating in an oxygen atmosphere in order to form a passivation layer to prevent reaction with injected steam or water that becomes steam.
  • the wails of the component may be wetted with the melt such as silver melt that protects the walls form reaction with water.
  • water reactive metals may be used for the peiletizer component.
  • the joints may be welds, Swagelok, and others known in the art for connecting metal parts.
  • the parts may be made of the same materials as the pump rube such as at least one of zirconium, niobium, titanium, tantalum, other refractory metal, and high temperature stainless steel such as at least one of Haynes 188, Haynes 230 and Haynes HR-160.
  • At least one vessel of the peiletizer that is heated by at least one of the inductively coupled heaters such as 5f and So comprises a material such as a metal that absorbs the radiated power of the inductively coupled heater and indirectly heats the metal such as silver that is contained in the vessel.
  • Exemplary metals that are veiy efficiency at absorbing the RF radiation of the inductively coupied heater are tantalum, niobium, ferrous metals, and chromoly metal
  • at least one vessel of the peiletizer comprises tubing comprising a material that efficiently absorbs the radiation from the inductively coupied heater such as tantalum, niobium, or a ferrous metal such as chromoly.
  • the tubing may be coiled to be permissive of heating a longer length section within a coil of an inductively coupled heater.
  • the tubing may have a small diameter such as in the range of about 1 mm to 10 mm to effectively indirectly heat the metal inside of the tubing.
  • the tubing such as polished or electro-polished tubing may have a low emissivity.
  • the tubing may be wrapped with insulation such as insulation substantially transparent to the radiation of the inductively coupied heater. The insulation may be effective at mini niziag the conductive and convective heat losses and may further at least partially reflect infrared radiation from the tubing to decrease radiative power losses.
  • the peiletizer may further comprise a vacuum chamber or a cell extension that provides a vacuum chamber around at least of portion of the peiletizer.
  • the vacuum about the vessels may decrease conductive and convective heat losses and lower the required heater power to maintain the melt at the desired temperatures.
  • the vacuum may further decrease oxidation of the tubing that maintains its desired low emissivity.
  • the vessel wail may be comprised of a material that has a diminished to low permeability to hydrogen and is capable of a high temperature. Suitable materials are refractory metals such as tungsten and molybdenum and nitride bonded silicon nitride tube.
  • the vessel may be lined with insulation in the absence of the inductively couple heater in the manifold section.
  • T is section may be insulated and heated by the contiguous section of the second vessel from which the melt flows into this section, if necessary, in addition to insulation, the temperature may be maintained by an inductively coupled heater that heats the metal wall and indirectly heats the melt. Alternatively, another type of heater such as a resistive heater may be used.
  • the manifold section further comprises a mixer to increase the rate of incorporation H 2 and gaseous 3 ⁇ 40 into the melt.
  • the mixer may comprise an
  • the peiletizer 5a further comprises a source of 3 ⁇ 4 and H2O such as gas tanks and lines 5u and 5v thai connect to the manifolds 5w and 5x, respectively.
  • 3 ⁇ 4G is provided as steam by 3 ⁇ 40 tank, steam generator, and steam line 5v.
  • the hydrogen gas may be provided by the electrolysis of water using electricity generated by the generator.
  • the ejection of elevated pressure meli from the nozzle 5q achieves injection of fuel into the electrodes wherein the elevated pressure is produced by the at least one electromagnetic pump 5k,
  • the pressure may be increased by controlling the cross sectional area of the ejection nozzle 5q relative to that of the melt vessel 5c.
  • the nozzle orifice may be adjustable and controllable. Sensors such as conductivity or optical sensors such as infrared sensors and a computer may control the pressure of pump 5k and the injection rate.
  • the nozzle 5q may further comprise a valve such as one of the disclosure that may provide additional injection control.
  • the valve may comprise a needle type with the nozzle opening as the valve seat.
  • a fast controller such as a fast current controller of the electromagnetic pump serves as a valve since the pressure produced by the pump is eliminated at essentially the same time scale as the current according to the Loreniz force (Eq. (37)) that depends on the current.
  • the shot size may be controlled by controlling at least one of the nozzle size, the pressure across the nozzle orifice, vibration applied io the nozzle with a vibrator such as an electromagnetic or piezoelectric vibrator, and the temperature, viscosity and surface tension of the melt.
  • the movement of the shots may be sensed with a sensor such as an optical sensor such as an infrared sensor.
  • the position data may be feedback into at least one of the controller of the injection and the ignition to synchronize the flow of fuel into the ignition process.
  • the nozzle 5q may be surrounded by a Faraday cage to prevent the RF field from inducing eddy currents in the shot and causing the shot to deviate from a straight course into the electrode gap where ignition occurs.
  • the shot formed by surface tension following ejection from the nozzle 5q may radiate heat and cool.
  • the flight distance from the nozzle 5q to the point of ignition between the electrodes 8 may be sufficient such that the metal forms spheres, and each sphere may cool sufficiently for a shell to form on the outside.
  • the ejected molten fuel stream may he sprayed with water such as water droplets with a sprayer such as one of the disclosure.
  • An exemplary water sprayer is Fog Buster Model # 101 10, U.S. Patent No. 5,390,854.
  • Excess water may be condensed with a duller to maintain a rough vacuum in the cell
  • the sprayer and water condenser or chiller may be replaced with a nozzle cooler 5s that may cool the shot 5t just as it is ejected.
  • the cooling may comprise at least one of a heat sink such as one comprising a thennal mass that radiates heat, a heat exchanger on the nozzle with lines 3 Id and 31e to a chiller, and a chiller 3 l a, and a Peltier chiller on the nozzle 5s.
  • the melt flowing into the nozzle section of the peiietizer 5a may have a substantially elevated temperature in order to absorb applied gases such as 3 ⁇ 4 and HiO in the upstream, gas application section.
  • the melt temperature may be quenched with the nozzle cooling.
  • the temperature may be lowered to just above the melting point just as the melt is ejected.
  • the lower-temperature melt may form spheres, and each may
  • the temperature at ejection may be established to within a rough temperature rarige such as to within about 50 °C of the melting point of the melt, A more precise temperature near the desired temperature such as to within about 1 to 5 °C of the melting point of the melt may be achieved with a highly controllable, low capacity cooler such as the Peltier duller.
  • the pelletizer 5a may further comprise a chiller to cool the inductively coupled heater which may comprise a separate chiller or the same chiller as at least one of the nozzle chiller 3 1a and power converter chiller such as the PV converter chiller 3 1.
  • the ignition system 8a (FIGURE 2H2) may also be cooled with a heat exchanger that rejects the heat to a chiller that may comprise one such as 31 that also cools another system such as the PV converter.
  • the ignition system cooler may cool at least one of the electrical connecting bearing such as the plain bearing or slip ring, the roller shafts, and the roller electrodes.
  • the ignition system cooler may comprise a heat exchanger such as a water jacket about the slip ring.
  • the water jacket water may also flow through the shafts 7 and roller electrodes 8.
  • the water flow may be connected with the shafts 7 through water tight, shaft sealing bearings or watertight slip rings at the ends of the shafts that are well known in the art.
  • the ignition of the fuel forms hydrinos and oxygen that may be pumped off with a vacuum pump 13a (FIGURE 212) such as a root pump, a scroll pump, a eryopump, a diaphragm pump, a dry vacuum root pump, and others known to those skilled in the art.
  • a vacuum pump 13a such as a root pump, a scroll pump, a eryopump, a diaphragm pump, a dry vacuum root pump, and others known to those skilled in the art.
  • Excess water and hydrogen may be recovered and recirculated.
  • the water may be removed by differential pumping.
  • hydrogen and oxygen formed in the plasma may be removed by pumping and other means of the disclosure such as by the separatory means,
  • the removal of the hydrogen and oxygen may be used as a means to remove excess water. In the case that an atmosphere comprising water is maintained at the electrodes, excess water may be removed by pumping.
  • the water may be condensed af a chiller in the cell 26 or connected with the inside of the cell 26 and reused. Hydrogen may be recovered with a scrubber such as a hydrogen storage material. Alternatively, it may be pumped off as well using pump 13a, for example.
  • the pressure may be maintained in a pressure range that prevents at least one of excessive attenuation of the light emitted by the cell and allows the ignition particles to fall substantially unimpeded under the influence of gravity.
  • the pressure may be maintained in at least one pressure range of about 1 nanoTorr to 100 atm, 0.1 miliiTorr to 1 atm and 10 miiliTorr to 2 Torr.
  • the ignition of hot fuel may require less energy than thai of cold fuel; so, the timing of the ignition may be earlier in the hoi-fuel case.
  • the timing of the ignition may be controlled to achieve the formation of light in a desired region such as one that provided light directed towards the power converter such as the photovoltaic converter 26a (FIGURE 212).
  • the roller speed may be increased to transport the fuel upward to cause the light to be emitted in the desired region.
  • the system may comprise an ignition current delay element such as a delay line to delay the ignition as the fuel is transported by the rollers such that the light is produced in the desired region.
  • the power may be controlled by controlling the injection rate and size of the shot.
  • the flow rate may be controlled by controlling the pumping rate.
  • the H 2 and 3 ⁇ 40 content may also be controlled by controlling the gas absorption conditions such as gas pressures, exposure time, and melt temperature to control the power output of the SF-CIHT ceil.
  • the melt such as molten silver may be injected absent at least one of gas treatmen t and cooling such as with the water spray, the heat exchanger and chiller, or the Peltier chiller.
  • the untreated metal serves as "dud" material in that the ignition to form hydrinos is absent such that the materia! may bond to the electrode surface.
  • the bonding may be more dispersed and uniform in the case that the melt is not cooled into shot having an external shell.
  • Molten droplets may impact the electrode surface with injection to cover the surface over time with new metal.
  • the excess metal may be machined by means of the disclosure such as by use of at least one of a dressing wheel, precision grinder, and lathe.
  • the milling may be achieved with a fixed abrasive blade that mills the surface as the roller electrode rotates.
  • the height of the blade may be adjustable.
  • the excess material may be removed by electrical discharge machining (EDM) wherein the EDM system may comprise the electrodes and power supply.
  • EDM electrical discharge machining
  • Each electrode may have a dressing wheel to condition the surface.
  • the rollers may be smoothed and formed to a desired radius by at least one of milling, grinding, lapping, super finishing and heat-treating.
  • the electrode mending or repair system comprises a sensor such as an optical sensor such as a laser to detect roller damage.
  • a controller may control the deposition, removal of excess material, and dressing to repair blast damage to maintain the electrodes within certain desired size tolerances.
  • the ignition products may be recovered by at least one of an electrostatic and an electromagnetic recovery system.
  • the electrostatic recovery system comprises at least one set of electrodes thai may be maintained at high voltage that causes the ignition product powder to become charged by one electrode such as the positive (negative) electrode and the charged particles are collected by the oppositely charged electrode such as the Negative (positive) electrode.
  • the particles may be charged by electrons produced by a discharge at the negative electrode such as a coronal discharge. Aliemaiiveiy, particles such as ones comprising silver may become positively charged in a high field between the ESP electrodes.
  • the direction of the electric fields created by the electrodes may be such that the particles travel in a trajectory that is along at least two directions of a Cartesian coordinate system.
  • the particles may travel directly to a collector thai may be the input of the pei!etizer.
  • the powder may be melted In the pelleiizer, and an electromagnetic pump may pump the meii to transport it.
  • the melt may be treated with gases to become fuel and injected into the electrodes.
  • the ignition product powder may be transported
  • the powder may then be transported to the pelletizer by at least one transporter such as a mechanical and electrostatic transporter.
  • the electrodes may comprise barrier eiectrodes wherein a charge is maintained on the surface of the collection electrodes.
  • the collected charged powder may be maintained in a charged state.
  • the power may be transported by a series of electrically isolated collection electrodes wherein electrode n + 1 of the series of integer n electrodes is electrically charged by the application of a voltage while electrode n is discharged or oppositely charged such that ihe powder is attracted to electrode n + I and no longer attached or is repelled by electrode n.
  • the series of electrodes may be sequentially activated and deactivated electrically to move ihe powered to a desired location such as to the pelletizer. The n series of electrodes may move the powder in any desired direction such as vertically in the case that the standard design with the light directed vertically is operated in an upside-down orientation. In an embodiment, the series of electrodes may move the powder to a plasma-containing region of the cell wherein the augmented plasma railgun recovery system of the disclosure may complete the recovery of the powder. In the case that the plasma conductivity is low.
  • an electrostatic precipitator may be used to collect the ignition products or direct them to a region that has a high conductivity. In a region of high plasma conductivity, the ignition product may be recovered by at least one of a barrier electrode electrostatic precipitator and an augmented plasma railgun recovery system.
  • the electrostatic precipitator may comprise a high voltage power supply that may be run off of at least one of the photovoltaic (PV) converter and the power conditioner of the PV converter power.
  • the power supply may supply power between the ESP electrodes to cause the electrostatic precipitation.
  • the ESP precipitator further comprises a set of electrodes such as a central electrode such as a wire electrode 88 (FIGURE 2123) of a polarity and at least one counter electrode 89 of opposite polarity.
  • the wire electrode may create a coronal discharge with the counter electrode(s).
  • the wire may comprise objects such as sharp needles to intensify the electric field
  • the counter electrodes such as the collection or precipitator electrodes may comprise at least one of the cell wails and the inlet or region around the inlet to the pelletizer.
  • the ESP power supply such as a high voltage power supply may apply a high negative voltage to the central electrode such as the wire electrode, and the collection electrodes such as at least one of the cell walls and inlet may be grounded.
  • the particles such as ones comprising silver become positively charged and are collected on the negative wire or rod.
  • the high voltage power supply may apply a high positive voltage to the central electrode such as the wire or rod electrode, and the collection electrodes such as at least one of the cell walls and inlet may be grounded such that the positively charged silver particles collect on the ceil wails and inlet. (The opposite occurs for the two cases, when the particles are negatively charged.)
  • the collected particles may be transported to the inlet to the pelletizer.
  • the transport may by at least one of gravity, electrostatic fields, electromagnetic fields, and mechanically.
  • At least one electrode may comprise at least one wire (88 of FIGURE 2123), wire gauze (89 of FIGURE 2123), or a wire mesh that is substantially non-blocking of the emission of the cell to the PV converter.
  • the electrodes may comprise a refractory conductor such as a refractory metal such as Mo or W such that cooling may be achieved predominantly by radiation.
  • a central wke was charged negatively to between 500 V and 1500 V while two counter electrode plates at a radius of 10 cm were grounded. The ceil pressure was about 30 to 50 mTorr. Positively charged silver particles were electrostatically collected at 50 mA on the negative central electrode.
  • the particles were neutralized upon contacting the central wire, and the neutralized sliver particles fell by gravity to a collector.
  • the electric field strength may be increased to provide a higher ESP force and ESP effect by decreasing the spacing of the electrodes, and by increasing the applied ESP electrode voltage.
  • the time of action and the ESP effect may be increase by increasing the vertical length of the electrodes along the trajectory of the ignition products.
  • the ceil 26 may comprise a transmission line or waveguide designed to have impedance that reflects the plasma and particles at a desired distance from the blast region based on the impedance matching of the plasma medium for propagating alternating frequency power along the ceil.
  • the alternating frequency may be characteristic of the ignition waveform that may be controlled.
  • the dimensions of the cell may be controlled.
  • the controls may facilitate plasma power propagation into a region of the cell until the impedance for the plasma power propagation is no longer matched to the cell impedance.
  • the plasma impedance may be control ably changed through the conductivity of the plasma that may drop along the propagation path due to ion-electron recombination.
  • the plasma propagation may be halted or reflected.
  • the recovery of the ignition products may be at least partially facilitated by the halting or the reflection of the plasma.
  • At least one polarity of electrode may comprise a UV mirror surface such as those of the disclosure such as MgFi coated Al to at least one of reflect the emission of the cell and prevent the ignition product from adhering.
  • another anti-adhering coating comprises sapphire.
  • the wails may comprise aluminum foil such as Al foil that may comprise a thin protective oxide coat as an anti-adhering surface.
  • the walls may comprise at least one of molybdenum such as Mo foil with an oxide coat, tungsten carbide (WC), WC coated metal such as WC-coated Mo or W, tungsten, Ta, Nh, TaW, carburized metal such as steel or related alloys, anodized aluminum, alumina such as alpha alumina that may be sputter coated on a substrate such as stainless steel, graphite, Grafoil, graphene, and graphite coated conductor such as graphite coated Cu, Mo, or W as an anti- adhesion material in an embodiment, the waJis may comprise carbon-coated support such as a ceramic or metal support. The carbon may comprise graphite.
  • the graphite may be applied by means known in the art such as a liquid spray that is cured on the support. Other means comprise vapor deposition, sputtering, chemical deposition, and others known in the art.
  • the walls may comprise a support such as a metal coaied with graphite that may be pyrolytic graphite.
  • the coating may be with pyrolytic graphite tiles.
  • the coating may be boron carbide (e.g. 4C), fiuoroearbon polymer such as Teflon (PTFE), zirconia + 8% yttria, Mullite, Mullite-zirconia, or Mullite-yttria stabilized zirconia (YSZ) that may operate at high temperature.
  • the coating such as one on high-temperature stainless steel or copper may comprise anodized aluminum.
  • the aluminum may be applied by coating methods known in the art such as thermal spray or arc spraying and electroplating.
  • the aluminum coating may be anodized.
  • the anodization may be performed in an electrolysis ceil such as one comprising a sulfuric acid electrolyte.
  • the cell walls such as ones comprising surfaces that resist wetting or adhesion of the ignition product may be angled or tilted from the direction of the propagation trajectory of the ignition product particles to facilitate the ignition product particles deflection from the walls without adhesion.
  • At least one of the cell wails and cell top may comprise a corrugated surface of a material such a anodized aluminum or graphite that resists ignition product adhesion so that the ignition product particles such as molten Ag particles do not impact perpendicularly and adhere.
  • the walls may comprise a foil that may be stretched to absorb impact from particles from the blast to prevent them from embedding.
  • the foil may be angled relative to the blast direction to deflect the particles to avoid adhesion.
  • the wails may comprise different materials in order to provide desired selective capabilities such as heat resistance and reflection of UV light in desired cell regions.
  • the top portion of the ceil walls nearer the PV converter may comprise MgFj coated AS to reflected UV light
  • the bottom portion of the cell walls at the electrodes and ignition product inlet may comprise graphite, Mo, or tungsten carbide to operate at high temperature.
  • the high temperature of the bottom section of the walls may facilitate returning the ignition product close to or above its melting temperature to reduce the input energy to regenerate the fuel shot by the pelletizer.
  • a hydrogen atmosphere, low oxygen partial pressure due to pumping, or an oxygen getter may protect the oxidizable components such as graphite and aluminum from oxidation. The same applies to oxidizable electrode components.
  • the ESP system may further comprise a barrier electrode section to charge the particles.
  • at least one of the walls and surface to the photovoltaic (PV) converter may be positively charged to repel positively charged silver particles to prevent them from adhering to the cell wall or PV coaverter.
  • the particles may be positively charged by a high voltage coronal discharge.
  • at least one of the walls and the surface of the photovoltaic (PV) converter may comprise a barrier electrode or may have a barrier electrode between the region of ignition and the wall or PV converter.
  • the barrier electrode may be charged to the same polarity as the ignition product particles to repel them and prevent adhesion to the wall or converter surface, in an exemplary embodiment, the particles such as silver particles are positively charged, and the barrier electrode is positively polarized to repel the particles.
  • eddy currents are induced in the particles by time-varying fields such as radio frequency fields that comprise excitation fields.
  • the eddy currents may induce a field to be produced by the particles,
  • the induced field may interact with the excitation field to cause the particles to undergo at least one of trapping and translation.
  • the excitation field may be controlled to achieve a translation away from at least one of the cell walls and the PV converter to prevent adhesion.
  • At least one antenna and RF generator may apply the R.F field.
  • the at least one antenna may comprise a set of electrodes.
  • the antenna may comprise an RF coil.
  • the coil and RF generator or power source may comprise an inductively coupled heater.
  • the coil may surround the region where the ignition product is desired to be confined.
  • a standing electromagnetic wave is maintained in an inductively coupled cavity formed by opposing antennae orientations that induces eddy currents in the metallic particles and traps them in the cavity.
  • the trapping action of the rad o frequency field on the particles reduces their velocities acquired from the ignition blast so that gravity may eventually make them drop to the bottom of the cell to be collected into the inlet of the pelietizer.
  • the system to prevent particle adhesion may comprise an RF source and at least one antenna to induce eddy currents in the particles and may further comprise an applied field such as at least one of a static magnetic field and a static electric field.
  • the static magnetic field may be applied by at least one of a permanent and an electromagnet
  • the static electric field may be applied by a set of electrodes and a power supply.
  • the frequency of the antennae-excited electromagnetic trapping system may be in at least one frequency range of about 1 Hz to 100 GHz, 1 kHz to 10 GHz, and 100 kHz to 100 MHz, The frequency may be selected based on the particle size, A higher frequency may be applied for smaller particles.
  • One skilled in the art may test di ferent coil geometries, power, and frequency to achieve a force such as levitaiion of the metal powder ignition product or its expulsion from the top ceil region.
  • ionized particles of the plasma formed by ignition of the solid fuel are pa-evented from electrostatically adheri g to surfaces of the cell such as the window of the PV converter, the PV converter, and the cell walls.
  • magnets such as 8c (FIGURE 2110) thai produce a magnetic field perpendicular to the direction of the ignition and plasma current across the electrodes, at least a portion of the ionized particles are swept away from the window of the PV converter and the PV converter by the Lorentz force, and at least a portion of the remaining unionized particles do not electrostatically adhere to the surfaces due to their electrical neutrality.
  • the neutral particles may elastically scatter from the surfaces.
  • the particles are further prevented from
  • the grounding may be achieved by using a conductor in contact with the un- neutraiized particles.
  • the material may have at least one of the characteristics of a low work function, high surface area, high thermionic activity, and high photoelectric activity.
  • the material may comprise a metal that is cessiated.
  • a means to neutralize the charged particles such as positively charged particles comprises a source of neutralizing electrons such as at least one an electrical ground path and free electron injector.
  • the injection of free electrons may be by means such as an electron beam and a photocathode.
  • the photocathode may emit photoeiectrons due to the illumination with the appropriate high- energy light from the plasma.
  • the photocathode may be one of the disclosure such as GaN.
  • Neutralization may also be achieved by using a heated filament that emits electrons when heated such as a or thoriated VV filament.
  • a positive bias may be applied between an accelerating grid and the filament to improve the amount of current injected into the plasma to neutralize it.
  • At least one of the photovoltaic (PV) cells and panels are tilted away from being in the transverse plane to the propagation direction of the particles from the ignition of the solid fuel shots.
  • the array of at least one of the PV ceils and panels may be arranged as a Venetian blind such that the moving particles from the ignition graze them at an angle.
  • the grazing incidence prevents the particles from adhering to the at least one of the PV cells and panels.
  • the particles may elastically scatter. Small particles have a high surface tension to form spheres that may facilitate the elastic scattering and non- adherence.
  • the tilted PV cells and panels may elastically deflect or scatter the particles to a non-adhering surface such as a graphite, aluminum, zirconium, or WC surface.
  • the non- adhering surface may comprise vertical slats connecting the upper edge of one member and the lower edge of a contiguous member of the array arranged as a Venetian blind
  • the particles may drop or be transported from the non-adhering surface to the inlet of the pelletizer.
  • the grazing incidence feature of the PV converter may be applied in combination with other methods of the disclosure to prevent adhesion of the particles such as the use of crossed current such as ignition current and magnetic fields applied by magnets to cause a Loreritz force deflection of the particles, aad the PV cells may be each coated with an non-adhering surface such as aluminum, in an embodiment, the tiled or Venetian blind PV configuration may increase the surface area of the PV converter to permit higher power output.
  • the plasma and plasma emission are incident each of a series of mirrors such as UV mirrors of the disclosure at shallow incidence angle.
  • the shallow or grazing angle results in a much higher reflection coefficient than that of a more normal incidence angle.
  • the series of mirrors selectively separates the light from the particles.
  • the particles may undergo inelastic collisions with the mirrors to be removed from the plasma while the light is reflected through the series of mirrors to he directed onto the PV converter.
  • the particles comprising the solid Fuel ignition product are collected at the inlet to the pelletizer. The collection may be by gravity flow or other means of the disclosure.
  • the collection electrode may comprise a mechanical transporter such as a bucket elevator.
  • the transporter may comprise a conveyor belt wherein the powder may adhere electrostatically and be transported mechanically to the pelletizer.
  • Charged electrodes may generate an electrostatic field that induces a mirror dipole in the conducting particles and holds the particles on the belt electrostatically by the charge and induced charge interaction.
  • the belt may be charged by the mechanism of a van de Graaf generator.
  • the conveyor may comprise a van de Graaf generator.
  • the fields may be created with current carrying wires that alternate in current direction and are embedded in an insulator.
  • Such a transporter is well known in the art of photocopying wherein an electrostatic binding plate binds and transports paper that has an oppositely induced polarization charging.
  • the powder may be released where desired such as into the pelletizer by discharging the fields.
  • the discharge may be achieved with illumination as in the case of the selenium plate of photocopy ing technology.
  • particles may adhere to a magnetized conveyor such as one comprising a belt that comprises surface electrodes that supply current through the pa ticles when in contact with the conveyor surface.
  • the particle current gives rise to a particle magnetic field thai interacts with the magnetization of the conveyor belt to cause the particles to adhere.
  • the particles may be released by terminating the current through the conducting particles.
  • the particle may fly off of the belt due to the centrifugal force at top belt rollers. They may also be mechanically removed with a scraper for example.
  • the mechanical transporter such as the conveyor belt may replace the raiigun injector shown in FIGURE 216 wherein fuel shot replaces the particles of the present disclosure.
  • the shot or pellets may drop directly into the roller electrodes from the pelletizer or shot dripper of the pelletizer from above the rollers (FIGURES 2H1-2H4 and 211-219).
  • the ignition products may flow into the pelletizer that may be above or below the rollers. Shot may be formed below and transported above the rollers. Metal may be pumped above the rollers where shot may be made, and the shot may be dropped or injected into the rollers, in another embodiment, the ignition product may be transported to the peiietizer that may be above the rollers.
  • the PV panels may be oriented to maximize the capture of the light wherein other positions than that shown for the
  • photovoltaic converter 26a FIGURES 2HI, 211, and 212 are anticipated and can be determined by one skilled in the art with routine knowledge. The same applies to the relative orientation of other systems and combinations of systems of the disclosure.
  • the ignition system comprises a pair of stationary electrodes 8 having a gap 8g between ihem that establishes an open circuit, a source of electrical power to cause ignition of the fuel 2, and a set of bus bars 9 and ] 0 connecting the source of electrical power 2 to the pair of electrodes 8.
  • At least one of the electrodes and bus bar may be cooled by a cooling system of the ignition system.
  • the gap 8g may be filled with conductive fuel with the concomitant closing of the circuit by the injection of molten fuel from the Injection system such as that comprising an electromagnetic pump 5k and a nozzle 5q.
  • the injected molten fuel may comprise spherical shots 5t that may be at least one of molten, partially molten, and molten with a solidified shell.
  • the solid fuel may be delivered as a stream of shots, a continuous stream, or a combination of shot and a stream.
  • the molten fuel feed to the electrodes may further comprise a continuous steam or intermittent periods of shots and continuous steam.
  • the source of electricity 2 may comprise at least one capacitor such as a bank of capacitors charged by the light to electricity converter such as the PV or PE converter.
  • the charge circuit may be in parallel with the source of electricity 2 and the electrodes 8.
  • the charging circuit may be in series with the source of electricity 2 and the rollers 2 wherein a switch connects the charging circuit to the source of electricity when the electrodes are in an open circuit state.
  • the voltage may be in the range of about 0.1 V to 10 V.
  • the desired maximum voltage may be achieved by connecting capacitors in series.
  • a voltage regulator may control the maximum charging voltage.
  • the peak current may be in the range of abou! 100 A to 40 kA.
  • the desired maximum current may be achieved by connecting capacitors in parallel with a desired voltage achieved by parallel sets connected in series.
  • the ignition circuit may comprise a surge protector to protect the ignition system against voltage surges created during ignition.
  • An exemplary surge protector may comprise at least one capacitor and one diode such as Vishay diode (VS-UFB 130FA20).
  • An exemplary source of electrical power comprises two capacitors in series (Maxwell Technologies 2 Ultracapacitor 2.85 V/3400F) to provide about 5 to 6 V and 2500 A to 10,000 A.
  • An exemplary source of electrical power comprises two capacitors in series (Maxwell Technologies 2 Ultracapacitor 2.85V/3400F) to provide about 5 to 6 V and 2500 A to 10,000 A.
  • Another exemplary source of electrical power comprises four capacitors in series (Maxwell Technologies 2 Ultracapacitor 2.85 73400F) to provide about 9.5 V and about 4 kA.
  • the manifold and injectors comprise a pipe bubbler 5z running longitudinally inside of at least one of the first vessel 5b and the second vessel 5c
  • the pipe bubbler 5z comprises a closed channel or conduit for gas and at least one perforation along its length to delivery gas into the fuel smelt surrounding it.
  • the pipe bubbler has perforations or ports distributed over its surface along its length to deliver gas over its surface along its length.
  • the pipe bubbler may be centerline inside at least one vessel. The centerline position may be maintained by spoke supports along the pipe bubbler.
  • the pipe bubbler may enter the inside of the first vessel 5b at the first vessel's open inlet and may run through at least one of the fust vessel 5b and the second vessel 5c such that it ends before the nozzle 5q (FIGURE 2113),
  • the pipe bubbler runs in at least one of the first or second vessel without running through the pump 5k.
  • the pipe bubbler 5z may make a penetration into the vessel at a wall region such as at a joint or elbow such that of the second vessel 5 c (FIGURE 2116) and may terminate before entering a pump 5 k (FIGURE 2114),
  • the pipe bubbler may be supplied with at least one hydrogen gas line, liquid or gaseous water line, and a common hydrogen and liquid or gaseous water line such as a line 5y from a manifold connected to a source of at least one of j3 ⁇ 4 and 3 ⁇ 4Q and 5v and 5u.
  • At least one of the first vessel 5b and the second vessel 5c may comprise a coil having a coiled pipe bubbler 5z that may increase the residence time to inject at least one of 3 ⁇ 40 and H 2 into the fuel melt.
  • At least one of the pelletizer components such as the vessels 5b and 5c, the pump tube, and the pipe bubbler 5z may be comprised of a metal wherem the fuel melt may be heated indirectly.
  • the pipe bubbler may be positioned inside of the vessels with setscrews through the walls of the vessels. For example, the pipe bubbler centering may be achieved by the adjusting the relative protrusion length of each of three screws set 120 ° apart around the circumference of the vessel.
  • the pelletizer may further comprise a chamber that receives melt from a vessel such as the first vessel.
  • the chamber may comprise at least one bubbler tube such as a plurality of bubbler tubes in the chamber and may further comprise a manifold to feed the bubbler tubes.
  • the water may be supplied to the chamber as steam to be incorporated into the melt such as molten silver.
  • the steam may be preheated to at least the temperature of the chamber to avoid heat loss.
  • the steam may be preheated by heat exchange from a heated section of the pelletizer such as the first vessel.
  • the steam may be heated with a heater such as an
  • the at least one of steam and hydrogen treated melt such a molten silver may flow out of the chamber to the second vessel that may comprise tubing that may be heated with a heater such as an inductively coupled heater.
  • the tubing may penetrate the cell wall aod terminate In a nozzle 5q that injects the melt into the electrodes.
  • the chamber may comprise a pump such as an electromagnetic pump in at least one of the chamber irs!ei aad outlet.
  • the pipe bubbler attaches to both of the 3 ⁇ 4 and 3 ⁇ 40 gas tajiks, lines 5u and 5v, respectively, may attach to a gas mixer such as a manifold that then attaches to the pipe bubbler through a connecting pipe 5y (FIGURE 2114).
  • the pipe bubbler may comprise a plurality of pipe bubbl may be independently connected to a separate gas supply such as the H 2 and H 2 0 gas tanks by lines 5u and 5 v, respectively.
  • the pipe bubbler may be comprise multiple sections that can be at least one of connected and disconnected during assembly and disassembly such as during fabrication and maintenance.
  • the pipe bubbler may comprise suitable joints to achieve the connections.
  • One first pipe bubbler section may serve to deliver gas into the melt up to the electromagnetic (EM) pump.
  • a second pipe bubbler section may perform at least one of channel and del iver the gases along the EM pump section, and a third pipe bubbler section may deliver gases along the second vessel 5c,
  • the multi-section pipe bubbler comprises a first section inside the first vessel running though its inlet and along its length and a second pipe bubbler section inside of the second vessel 5c that terminates before the nozzle 5q.
  • the pipe bubbler may enter the vessel after the pump 5k such that the pressure from the injected gases does not cause the melt to reverse flow.
  • the bubbler 5z may enter the vessel through a joining section such as an elbow that may connect dissimilar vessel materials such as metal and quartz (FIGURES 2114 and 2116) that are connected by joi nts 5b 1 of the disclosure.
  • the inductively coupled heater may comprise two full coils.
  • the first inductively coupled heater coil 5f heats the first vessel and the second inductively coupled heater coil 5o heats the second vessel 5c.
  • the pipe bubbler may comprise a metal or alloy resistant to reaction with H 2 0 at the operating temperature, capable to maintaining its integrity and avoiding silver alloy formation at the melt temperature.
  • Suitable exemplary materials that lack 3 ⁇ 40 reactivity with sufficient melting points are at least one of the metals and alloys from the group of Cu, Ni, CuNi, Hastelloy C, Hastelloy X, Inconel, Incoloy, carbon steel, stainless steel, chromium-molybdenum steel such as modified 9Cr-l Mo-V (P91 ), 21/4Cr-lMo steel (P22), Co, Ir, Fe, Mo, Os, Pd, Pt, Re, R , Ru, Tc, and W,
  • the pipe bubbler may be attached at the input end to at least one of the H 2 and H 2 0 gas tanks by lines 5u and 5v, respectively.
  • H 2 0 is provided as steam by H 2 0 tank, steam generator, and steam line 5v.
  • the pelletizer comprises a steam generator 5v for adding the 3 ⁇ 40 to the melt such as silver melt in the vessel such as at least one of 5b and 5c that may comprise quartz vessels, in an embodiment, the steam generator comprises a capillary wick system that has a heat gradient to create steam at one end, and wick water out of a reservoir from the opposite end.
  • the steam generator comprises a high surface area heated material such as a metal foam or mat such as ones comprising nickel or copper to provide boiling sites for the conversion of water from a H 2 0 reservoir into steam for hydrating the shot.
  • a high surface area heated material such as a metal foam or mat such as ones comprising nickel or copper to provide boiling sites for the conversion of water from a H 2 0 reservoir into steam for hydrating the shot.
  • Other exemplary high surface area materials comprise ceramics such as zeolite, silica, and alumina.
  • the steam generator may be run under pressure to increase the steam temperature and heat content. The pressure may be obtained by controlling the size of the sieam-flow outlet to control a restriction to flow such that steam is generated at a rate relative to the restricted output flow to cause a desired steam pressure.
  • the line may comprise a pressure reducer.
  • the steam generator may comprise a condenser to condense water droplets and low -temperature steam.
  • the condensed water may reflux back into the cell.
  • the steam may be flowed through the pipe bubbler 5z and injected into the melt such as molten silver that is injected into the electrodes 8.
  • the pressure may be maintained low such as in at least one range of about 0.001 Torr to 760 Torr, 0.01 Tor to 400 Torr, and 0.1 Torr to 100 Torr.
  • At least one of low heat, chilling liquid water, maintaining ice, and cooling ice may be applied to the water in a reservoir or tank such as 5v operated under reduced pressure to form low-pressure gaseous water.
  • the chilling and ice may be maintained with a chiller such as 31 and 31a.
  • the reduced pressure may be provided by the vacuum pump 13a.
  • the wt% of water in the silver may be optimal for the hydrino reaction wherein the rate increases with 3 ⁇ 40 wt% starting from pure metal plasma, reaches a maximum rate and hydrino yield at the optimal wt%, and may decrease with further 3 ⁇ 40 plasma content due to competing processes such as hydrogen bonding of HOH to lower the nascent HOH concentration and recombination of atomic H to lower the atomic H concentration.
  • the 3 ⁇ 40 weight percentage (wt%) of the ignition plasma thai comprises the conductive matrix such as a metal such as silver, silver-copper alloy, and copper is in at least one wt% range of about 10 '10 to 25, 10 " i0 to 10, 10 '!0 to 5, 10 s0 to 1 , 1G "!0 to 30 "!
  • the cell atmosphere may comprise hydrogen to react with any copper oxide that may form by reaction with oxygen formed in the cell.
  • the hydrogen pressure may be in at least one range of about 1 mTorr to 1000 Torr, 10 mTorr to 100 Torr, and 100 mTorr to 10 Torr.
  • the hydrogen pressure may be one that reacts with copper oxide at a rate that it forms or higher and below a pressure that significantly attenuates the UV light from the fuel ignition.
  • the SF-CIHT generator may further comprise a hydrogen sensor and a controller to control the hydrogen pressure in the cell from a source such as 5u.
  • the stationary electrodes 8 of FIGURES 2110-2123 may be shaped to cause the plasma and consequently the light emitted for the plasma to be projected towards the PV converter 26a (FIGURE 212).
  • the electrodes may be shaped such the molten fuel initially flows through a first electrode section or region 8i (FIGURE 2112) comprising a neck or narrower gap to second electrode section or region 8j having a broader gap. Ignition preferentially occurs in the second section 8j such that plasma expands from the second electrode section 8j towards the PV converter 26a.
  • the necked section may create a Venturi effect to cause the rapid flow of the molten fuel to the second electrode section
  • the electrodes may comprise a shape to project the ignition event towards the PV converter, away from the direction of injection.
  • Suitable exemplary shapes are a minimum energy surface, a pseudosphere, a conical cylinder, an upper sheet parabola, an upper half sheet hyperbola, an upper half sheet catenoid, and an upper half sheet astro idal ellipsoid with the apex truncated as a suitable inlet comprising the first section.
  • the electrodes may comprise a surface in three dimensions with a split that may be filled with insulation 8h between half sections (FIGURE 2112) to comprise the two separated electrodes 8 having an open circuit gap 8g.
  • the open circuit is closed by injection of the melt shot causing contact across the conductive parts of the geometric form comprising the gap 8g.
  • the electrodes may comprise a rectangular section of the three- dimensional surface that is split.
  • the split Sh may be formed by machining away material such that the geometric form remains except for the missing material comprising the split 8h.
  • the velocity of the shot may be controlled to be sufficient to cause the plasma and emitted light to be in region 81 directed to the PV converter 26a.
  • the power of the electromagnetic pump 5k and nozzle orifice size may be control led to control the pressure at the nozzle 5q and the velocity of the shot.
  • Control of the site of ignition on the electrode surface may be used to control the region in the cell and direction of the plasma expansion and light emission.
  • the electrode 8 is shaped to moid the melt shot 5t to a geometric form having a focus region with reduced resistance to cause the current to concentrate in the focus region to selectively cause concentrated ignition in the focus region.
  • the selective concentrated ignition causes at least one of the plasma expansion and light emission into a region of the ceil 81 directed towards the PV converter 26a.
  • the electrodes 8 may be partially electrically conductive and partially electrically insulated.
  • the insulated section 8i may guide the fuel from the site of injection 8k into the conductive section 8j to be ignited such that the plasma preferentially expands into the region 81 towards the PV converter 26a,
  • the high current that causes ignition is delayed in time from the time that the melted shot initially completes the electrical connection between the electrodes.
  • the delay may allow the shot melt to travel to a part of the electrodes 8j on the opposite side of the injection site 8i.
  • the subsequent ignition on the opposite side 8j may direct the plasma and light towards the PV converter 26a.
  • the delay circuit may comprise at least one of an inductor and a delay line.
  • the electrodes may comprise a minimum energy surface such as a minimum energy surface, a pseudosphere, a conical cylinder, an upper sheet parabola, an upper half sheet hyperbola, an upper half sheet catenoid, and an upper half sheet astroidal ellipsoid with the apex truncated.
  • "Dud" melt being absent hydrogen and H 2 0 such that it is not capable of undergo ignition may be injected into the electrodes.
  • the melt may distribute over the electrode surface according to the minimum energy. The distribution may restore the original electrode surface to repair any ignition damage.
  • the system may further comprise a tool to reform the electrode surface to the original shape following the deposition of melt.
  • the tool may be one of the disclosure such as a mechanical tool such as a mill or a grinder or an electrical tool such as an electrical discharge machining (EDM) tool.
  • EDM electrical discharge machining
  • the fuel mete] may be removed with a mechanical tool such as a wiper, blade, or knife that may be moved by an electric motor controlled by a controller.
  • the electrodes may comprise a metal such as highly electrically conductive metal such as copper that is different from the conductive matrix of the fuel such as silver. Excess adherence of fuel metal such as silver to the electrodes may be removed by heating the electrode to a temperature thai exceeds the melting point of the fuel metal but is below the melting point of the electrode metal. Maintaining the temperature below the melting point of the electrode may also prevent alloy formation of the electrode and fuel metals such as Cu and Ag. in this case, the excess metal may flow off of the electrodes to restore the original form. The excess metal may flow into the peiietizer to be recycled.
  • the electrode heating may be achieved by using the heat from at least one of the ignition process using power from the source of electrical power 2 and the power from the formation of hydrinos. The heating may be achieved by reducing any cooling of the electrodes by the electrode cooling system.
  • the electrodes may comprise a conductive material that has a higher melting point than the melting point of the shot.
  • Exemplary materials are at least one of the metals and alloys from the group of WC, TaW, CuNi, Hastelloy C, Hastelloy X, inconel, Incoioy, carbon steel, stainless steel, chromium-molybdenum steel such as modified 9Cr- l Mo-V (P I ), 2 l/4Cr-l Mo steel (P22), Nd, Ac, Au, Sm, Cu, Pm, U, Mn, doped Be, Gd, Cm, Tb, doped Si, Dy, Ni, Ho, Co, Er, Y, Fe, Sc, Tm, Pd, Pa.
  • the electrodes may be operated at a temperature above the melting point of the shot such that the shot flows off the electrodes rather than solidifying and blocking the gap 8g.
  • the electrode operating temperature may be above 962 °C.
  • the electrodes may comprise a conductive material that has a higher melting point than the boiling point of the shot. Exemplary materials are WC, refractory metals, Tc, Ru, doped B, Ir, Nb, Mo, Ta, Os, Re, W, and C.
  • the electrodes may be operated at a temperature above the boiling point of the shot such thai the shot flows and boils off the electrodes rather than solidifying or wetting the electrodes and blocking the gap 8g.
  • the electrode operating temperature may be above 2162 °C.
  • the high operating temperature may provide heat removal from the electrodes by at least one of conduction and radiation.
  • the electrodes 8 may comprise a startup electrode heater to elevate the temperature of the electrodes.
  • the electrodes may comprise a plurality of regions, components, or layers, any of which may be selectively heated by at least one heater or may comprise a heater. The heating may reduce the adhesion of the shot.
  • the heater may comprise a resistive heater or other heater of the disclosure.
  • the electrodes comprise a startup heater that heats ihem to prevent the shot from adhering.
  • the electrode heater may comprise the source of electrical power 2 and a means to short the electrodes such as a movable conductive bridge between electrodes or a means to move the electrodes into contact to short them until the heating is achieved.
  • Any electrode cooling may be suspended until the electrodes are treadiog over the operating temperature such as in the range of 100 °C to 3000 °C for suitable materials of the disclosure.
  • the electrode temperature may be maintained below the melting point of the electrodes.
  • the cooling may be suspended dining the period of electrode warm-up during startup by pumping off the coolant.
  • the chiller pump may pump off the coolant.
  • the electrode may be operated at least one temperature range below the melting point of the shot, above the melting point of the shot, and above the boiling point of the shot wherein the electrodes comprise a material suitable for such temperature operation.
  • the electrodes may comprise a bilayer.
  • the bottom layer on the side 8k may comprise an insulator such as a ceramic such as an alkaline earth oxide, alumina, anodized aluminum, or zirconia, and the top layer on the side of 81 may comprise a conductor such as copper, silver, copper-silver alloy, molybdenum, tungsten carbide (WC), tungsten, Ta, TaW, Nb, and graphite coated conductor such as graphite coated Cu or W,
  • the graphite coated W may form a metai-carbide-carbon (W-WC-C) structure that may be very durable for wear.
  • the electrodes 8 comprise a meia! to which silver has low adhesion or does not substantially wet such as at least one of aluminum, molybdenum, tungsten, Ta, TaW, tungsten carbide (WC), and graphite coated conductor such as graphite coated Cu or W.
  • Low melting point electrodes such as aluminum electrodes may be cooled to prevent melting.
  • the nonconductive bottom layer may comprise an insulator such as an alkaline earth oxide, alumina, or anodized aluminum.
  • the bottom layer may comprise a conductor of much lower conductivity than the electrodes.
  • the bottom layer may be conductive but electrically isolated.
  • the bilayer electrodes may further comprise a thin insulating spacer between electrically conductive layers wherein only the highly conductive layer such as the top layer is connected to the source of electricity 2.
  • An exemplary bottom layer of low conductivity relative to the ignition portion of the electrode such as a silver, copper, Mo, tungsten, Ta, TaW, WC, or graphite coated conductor such as graphite coated Cu or W portion comprises graphite.
  • graphite serves as a layer to which the shot such as silver shot does not adhere.
  • the electrodes may be maintained at an elevated temperature to prevent the melt fi'oro rapidly cooling and adhering to the electrodes that may cause undesired electrical shorting.
  • any adhering melt may be removed by at least one of an ignition event and ignition current
  • the start-up power source may preheat the electrodes to prevent cooled melt 6'om adhering to the electrodes.
  • the electrode cooling system may be controlled to maintain an electrode temperature that achieves ignition in the desired location on the electrodes while preventing the melt from adhering in an undesired manner.
  • the electrode temperature may be maintained in a temperature range that avoids wetting or adherence of the molten shot such as silver shot to the electrodes.
  • the electrodes such as W electrodes may be operated at least one elevated temperature range such as about 300 °C to 3000 °C and 300 °C to 900 °C wherein a high Ag contract angle is favored.
  • the electrodes such as WC electrodes may be operated at. lower temperature such as about 25 °C to 300 °C wherein a high Ag contract angle is favored.
  • the lower temperature may be achieved by cooling with electrode cooling system inlet and outlet 3 If and 3 Ig (FIGURE 2113).
  • the bottom and top layers may each comprise a gap 8g that are connected, in an embodiment, the electrodes such as the W plate electrodes comprise gap between the W plates and the bus bars such as copper bus bars such that the W electrodes operate at a temperature to cause the silver to vaporize such as in the temperature range of about 1700 to 2500 °C.
  • the channel of electrode electromagnetic (EM) pump may be injected with molten solid fuel by EM pump 5k.
  • the solid fuel may comprise silver that may solidify.
  • Current from the source of electricity 2 may be flowed through the solid until its temperature is above the melting point, and the silver may pumped out of the channel by the electrode EM pump.
  • the heating of the material in the channel of the electrode EM pump heats the electrodes.
  • the channel of the electrode EM pump may serve as the startup heater.
  • the bilayer electrodes may serve to project the ignition event towards the PV converter, away from the direction of injection on the side 8k.
  • the open circuit is closed by injection of the melt shot causing contact across the conductive parts of the gap 8g only in the top layer.
  • the gap 8g of the bottom non-conductive layer may be sufficiently deep that the pressure resistance to the blast from the ignition of fuel may preferentially force the expanding light emitting plasma upward to emit in region 81.
  • one bilayer set electrodes comprises copper, Mo, tungsten, Ta, TaW, tungsten cai'bide (WC), or graphite coated conductor such as graphite coated Cu or W upper electrodes on a bottom ceramic layer such as alumina, zirconia, MgO, or firebrick having a hole to the gap 8g of the top layer.
  • the top and bottom layers may comprise opposing cones or conical sections with a neck at the interface of the two layers and a gap. Alternatively, the layers may form back-to- back V * s in cross section.
  • Such exemplary bilayer electrodes are a downward V-shaped graphite or zirconia bottom layer and an upward V-shaped W or WC upper layer.
  • the electrodes are constant along the transverse axis to Form V-shaped troughs with a gap that is filled with the shot to cause the circuit to be closed and ignition to occur.
  • the downward facing V-shaped layer may have low conductivity and may guide the shot to the second layer of high conductivity thai ignites the plasma.
  • the upward V-shape of the top layer may direct the plasma and light towards the PV converter.
  • the electrode may comprise a bilayer electrode such as one comprising a downward V-shaped layer such as graphite or zirconia bottom layer and a top layer having vertical walls or near vertical wails towards the gap 8g.
  • a bilayer electrode such as one comprising a downward V-shaped layer such as graphite or zirconia bottom layer and a top layer having vertical walls or near vertical wails towards the gap 8g.
  • Exemplary materials of the top layer are W, WC, and Mo.
  • the open circuit is closed by injection of the melt shot causing contact across the conductive parts of the gap 8g only in the top layer.
  • the electrode may comprise a trilayer electrode such as one comprising a bottom layer comprising a downward V-shape, a middle current delivery layer such as a fiat plate with the plate edge slightly extended into the gap 8g, and an upward V- shaped electrode lead layer that is recessed away from the gap 8g.
  • the bottom layer may comprise a material that resists adhesion of the shot melt such as silver shot melt. Suitable exemplary materials are graphite and zirconia.
  • the graphite may be highly oriented with the face that best resists adhesion oriented to contact the shot.
  • the graphite may be pyrolytic graphite.
  • the middle current delivery layer may comprise a conductor with a high melting point and high hardness such as flat W, WC, or Mo plate.
  • the top electrode lead layer may comprise a high conductor that may also be highly thermal conductive to aid in heat transfer. Suitable exemplary materials are copper, silver, copper-silver alloy, and aluminum. In an embodiment, the top lead electrode layer also comprises a material that resists adhesion of the shot melt such as silver or Ag-Cu alloy. Suitable exemplary non-adhering lead electrodes are WC and W. Alternatively, the lead electrode such as a copper electrode may be coated or clad with a surface that is resistant for the adherence of the shot melt. Suitable coatings or claddings are WC, W, carbon or graphite. The coating or cladding may be applied over the surface regions thai are exposed to the shot melt during ignition.
  • the open circuit may be closed by injection of the melt shot causing contact across the conductive parts of the gap 8g only in the middle layer.
  • the top lead layer may be cooled such as cooled through internal conduits.
  • the contact between the middle and top cooled layer may heat sink and cool the middle layer.
  • the contact between the bottom and middle cooled layer may heat sink and cool the bottom layer.
  • the shot injection rate was 1000 Hz
  • the voltage drop across the electrodes was less than 0.5 V
  • the ignition current was in the range of about 1 00 A to 1 0 kA.
  • the electrode may comprise a plurality of layers such as Mo, tungsten, Ta, TaW, WC, or graphite coated conductor such as graphite coated Cu or W on a lead portion such as a copper portion with ignition on the Mo, W, Ta, TaW, WC, or graphite coated conductor such as graphite coated Cu or W surface, and the e!ectrode may further comprise a non-conductive layer to direct the ignition in the direction of the PV converter.
  • the W or Mo may be welded to or electroplated on the lead portion.
  • the WC may be deposited by deposition techniques know in the art such as welding, thermospray, high velocity oxy fuel (HVOF) deposition, plasma vapor deposition, electro-spark deposition, and chemical vapor deposition
  • the graphite layer of a bilayer electrode comprising graphite on a lead portion may comprise the ignition electrode.
  • the graphite ignition electrode may thin and comprise a large area connection with a highly conductive lead such as copper or silver plate lead. Then the resistance may be low, and the graphite surface may prevent sticking.
  • the graphite electrode may comprise conductive elements such as copper posts in a graphite electrode to give the graphite more conductivity. The post may be added by drilling holes in the graphite and mechanically adding them or by pouring molten copper into the holes then machining a clean graphite-copper-post surface that faces the ignition.
  • FIGURES 2114 and 2117 A schematic drawing of a SF-CIHT cell power generator showing the cross section of the pelletizer having a pipe bubbler in the second vessel to introduce the gasses such as 3 ⁇ 4 and steam to the melt, two electromagnetic pumps, and a nozzle to injection shot on the bottom and top of the electrodes is shown in FIGURES 2114 and 2117, respectively. Details of the corresponding injection and ignition systems are shown in FIGURES 2115 and 2118, respectively. Details of the electromagnetic (EM) pump and pipe bubbler vessel penetration are shown in FIGURE 2116.
  • the electromagnetic pump 5k may comprise a plurality of stages and may be positioned at a plurality of locations along the pelletizer (FIGURE 2114).
  • the electromagnetic (EM) pump assembly Ska is shown in FIGURE 2 ⁇ 28.
  • the EM pump 5k may comprise an EM pump heat exchanger 5kl , an electromagnetic pump coolant lines feed-through assembly 5kb, magnets 5k4, magnetic yolks and optionally thermal barrier 5k5 that may comprise a gas or vacuum gap having optional radiation shielding, pump tube 5k6, bus bars 5k2, and bus bar current source connections 5k3 that may be supplied by current from the PV converter.
  • the pump tube 5k6 may be coated to reduce corrosion. Exemplary coatings are corrosion resistant metals with a higher melting point than the fuel metal such as nickel and a noble metal such as Pt or Ir in the case of Ag or Ag-Cu alloy melt.
  • At least one of the magnets and the magnetic circuit may comprise a polished surface such as the end surface facing the gap to serve as the radiation shield.
  • At least one of the magnets 5k4 and yoke 5k5 of the magnetic circuit may be cooled by EM pump heat exchanger 5kl such as one that is cooled with a coolant such as water having coolant inlet lines 3 Id and coolant outlet lines 3 le to a chiller 31 a.
  • the pump tube 5k6 of the EM pump 5k may he connected to the vessels such as the first vessel 5b, the second vessel 5 c, and the vessel section to the nozzle 5q by joints of the disclosure 5b 1.
  • the EM pump 5k may be position at the end of the first vessel 5b, and another may be position at the vessel wall at the end of the second vessel 5c.
  • An extension of the pump tube of the latter may be used as the line that penetrates the cell wall and is sealed at the cell wall.
  • the pump tube extension may comprise an S-shaped tube for injecting beiow the electrodes 8.
  • the pump tube extension may vertically enter the cell, transition horizontally at an elbow or bend, and the nozzle 5q may comprise a bend with an end outlet.
  • the nozzle may comprise a hole in ihe sidewall of the tube that is capped at the end so that the pressure in the tube ejects the melt out the sidewall hole and into the electrodes 8,
  • the section of the tube in the cell may be at least one of insulated and heated to maintain the melt at a desired temperature.
  • the heating may be with an inductively coupled heater coil that penetrates the cell wall and encloses at least a portion, of the tube.
  • the rube section inside of the cell and any other objects in the cell such as heater coils and bus bars may be coated with a material that resists adhesion by the ignition products.
  • Exemplary materials of the disclosure comprise graphite, tungsten, and timgsten carbide.
  • the plasma and adhering metal shot are ejected from the electrodes, and fuel recirculation is achieved by using the Lorentz force, exploiting the principles of the raiigun such as a shot and plasma armature type that may further comprise an augmented raiigun type herein also referred to as an electrode electromagnetic pump.
  • the Lorentz force may cause the flow of the adhering shot into the ignition section of the electrodes and causes the ignition plasma to be directed and flow into a collection region such as inlet of the fuel regeneration system such as the pelletizer.
  • the electrodes may comprise a downward (negative z-axis oriented) V-shape with a gap at the 8g at the top of the V.
  • the V may be formed by flat plate electrodes mounted on opposite faces of supports that form a V with a gap at the top.
  • Exemplary electrode materials comprising a conductor that operates a high temperature and resists adhesion of Ag are W, WC, and Mo.
  • the supports may be water-cooled.
  • the supports may be a least partially hollow.
  • the hollow portions may each comprise a conduit for coolant thai flows through the conduits and cools the electrodes.
  • the electrodes may further comprise an upper section having vertical walls or near vertical walls at the gap 8g. The walls may form a channel.
  • the open ignition circuit of the electrodes may be closed by injection of the melt shot causing contact across the conductive parts of the gap 8g at the top of the V.
  • the cell surfaces that may be exposed to ignition product may be coated with an adherence resistant material such as graphite or aluminum that may be anodized or another such material of the disclosure.
  • the surfaces may be coated with alumina such as alpha alumina that may be sputter coated on a substrate such as a high-temperature metal in another embodiment, the surfaces may be coated with a housing that comprises or is coated with a material that resists melt adherence such as one of the disclosure.
  • the bus bars may penetrate the cell through separate of a common flange wherein each bus bar is electrically isolated.
  • At least one of the bus bars, electrode mounts, aid electrodes may be shaped io at least one of minimize the surface for adherence of the ignition product and posses a low cross section for accumulation of returning melt such as Ag or Ag-Cu melt
  • the electrodes 8 may comprise straight rod bus bars 9 and 10 that are beveled at the ends to form the electrodes 8 or electrode mounts.
  • the surface of each beveled bus bar may be covered with a fastened electrode plate.
  • the bus bars may comprise flat copper bus bars having electrodes mounted to the inner surface.
  • Each bus bar may be covered with a plate electrode such as a tungsten plate or other durable conductor.
  • the plates may be curved to form a gap 8g.
  • the curved plate may comprise at least one of a tube or a semicircular cross section of a tube that is electrically connected to the bus bar.
  • the tube electrode may also connect to a bus bar of a different geometry such as a rod.
  • the tube may be concentric to the rod connection points.
  • An exemplary electrode separation across the gap 8g is in at least one range of about 0.05 to 10 mm, and I to 3 mm.
  • the electrodes such as ones comprising plates or tubes may be capable of high temperature.
  • the electrodes may comprise a refractory metal such as at least one of Tc, u, doped B, if, Nb, Mo, Ta, Os, Re, W, and C, and another such metal of the disclosure,
  • the high temperature electrodes may serve as a blackbody radiator for thermophotovoltaic power conversion.
  • the electrodes may comprise a heat embrittlemeat resistant composition.
  • the electrodes may comprise a sintered material such as a sintered refractory metal.
  • the electrodes may be at least one of segmented and thick to avoid breakage when heat embrittled.
  • the electrodes may comprise a thermally insulating layer or gap between the refractory metal plate and the bus bar to permit the electrode temperature to be elevated relative to thai of the bus bar.
  • the curved plate electrodes may form a thermally insulating layer or gap.
  • the thermally insulating material such as MgO or AI2O3 may comprise a ceramic thai may be molded or machined.
  • At least one of the bus bars and electrode mounts may be cooled such as water or air-cooled.
  • Other cool ante such as molten metals such as molten lithium are within the scope of the disclosure.
  • the electrodes further comprise a source of magnetic field such as a set of magnets at opposite ends of the channel of the electrodes such as 8c of FIGURES 2114 and 1115.
  • the magnets may be electrically isolated from the bus bars 9 and 10 when mounted across them by an electrical insulator such as a ceramic or high-temperature paint or coating such as a boron nitride coating that may be applied on the bus bar contact region by means such as spraying.
  • An insulator sleeve such as a ceramic tube may electrically isolate fasteners such as bolts or screws. Other such parts may be electrically isolated from another electrified system by the electrically insulating materials of the disclosure.
  • the magnets 8c and channel 8g supporting the ignition current may comprise an electromagnetic pump that performs the function of ejecting any shot adhering to at least one of the electrodes and the channel and ejecting ignition particles from the electrodes 8 and the channel 8g.
  • the ejection may be by the Lorentz force according to Eq. (37) formed by a crossed applied magnetic field such as thai from magnets 8c and ignition current through at least one of the plasma particles and shot such as silver shot adhering to the electrode surfaces such as those of the channel 8g,
  • the current carrying particles may be charged.
  • the plasma may additionally comprise electrons and ions.
  • the ignition current may be from the source of electrical power 2 (FIGURE 2110). Current may be carried through metal that adheres and shorts the electrodes of the bottom layer.
  • the current is crossed with the applied magnetic field such that a Lorentz force is created to push the adhering metal from the electrode surfaces.
  • the direction of the magnetic field and current may be selected to cause shot and plasma particles such as those from the shot ignition to be directed away from the channel 8g (FIGURE 2 ⁇ 15 and FIGURE 2117) in the positive or negative direction wherein the shot may be injected in the positive z-axis direction (FIGURES 2114 and 2115) or the negative z-axis direction
  • the magnets may produce a magnetic field along the y-axis parallel to the electrode or channel axis and perpendicular to the ignition current along the x- axis.
  • the channel with crossed current and magnetic field comprising an electromagnetic (EM) pump directed along the positive z-axis may perform at least one function of pumping injected shot upward into the electrodes to be ignited, pumping adhering shot upward to be ignited, pumping adhering shot upward out of the electrodes and channel, and pumping ignition particles upward out of the electrodes and channel.
  • EM electromagnetic
  • the Lorentz force due to the crossed ignition current and magnetic field may perform at least one function of pumping adhering shot downward to be ignited, pumping adhering shot downward out of the electrodes and channel, pumping ignition particles downward out of the electrodes and channel, pumping ignition particles downward away from the PV converter, and pumping ignition particles downward toward the inlet to the peSieiizer to recover the ignition product.
  • the strength of the crossed current and magnetic field and well as the dimensions of the channel provide the pump pressure through the channel comprising the electromagnetic pump tube.
  • the electrode EM pump may further comprise a switch that may reverse the direction of the current to reverse the direction of the EM pump.
  • the electrode EM pump switch may be activated to reverse the current and pump the shot downward to the inlet of the peileiizer.
  • the electrodes may further comprise a sensor and a controller.
  • the sensor may comprise a current sensor that may detect an electrode short.
  • the sensor may feed the shorting data into the controller that may inactivate the EM pump 5k to stop further injection of shot and activate the switch to reverse the current of the electrode EM pump until the short is cleared
  • the electrodes and magnets may be designed to direct the plasma in an upward arch to perform at least one function of (i) ejecting the shot and particles from the electrodes and channel such as 8g and (ii) recovering the ignition product and un-ignited shot to the pelletizer, while avoiding guiding ignition particles to the PV converter 26a,
  • the electrodes may comprise a downward (negative z-axis oriented) V-shape with a gap 8g at the top of the V,
  • the open circuit may be closed by injection of the melt shot causing contact across the conductive parts of the gap 8g at the top of the V.
  • the V may be formed by flat plate electrodes mounted on opposite faces of supports that form a V with a gap at the top.
  • Exemplary electrode materials comprising a conductor that operates a high temperature and resists adhesion of Ag are W, WC, and Mo.
  • the electrodes may further comprise a first electrode EM pump comprising a channel at the top of the electrodes above the gap 8g with the source of magnetic field 8c crossed to the ignition current.
  • the melted shot may be injected from below in the positive z-axis direction (FIGURES 2 ⁇ 4 and 2115), and the electrode EM pump may perform at least one function of facil itating the upward flow of the shot into the gap 8g to cause ignition, pumping adhering shot out of the electrodes and channel, and pumping ignition products out of the electrodes and channel 8g.
  • the electrodes comprises a second electrode EM pump comprising magnets 8cl and second electrode channel 8gl that produces a Lorentz force to at least one of force the particles away from the PV converter and facilitate recovery of the particles to the pelletizer.
  • the second electrode EM pump may be above the first electrode EM pump to receive plasma and particles from the ignition and pump the particles away from the PV converter 26a.
  • the polarity of the magnets of the second electrode EM pump may be opposite to those of the first while using a portion of the ignition current that is common to the electrodes and both electrode EM pumps.
  • the electrode EM pumps may be augmented types. At least one of the first EM pump and the second electrode EM pump may comprise an independent source of current that may be in the same or different direction as the ignition current.
  • the source of current may be from the PV converter.
  • the current may be in a direction different from that of the ignition current wherein the crossed magnetic field is oriented to at least one of produce a force on the ignition particles away from the PV converter and at least partially facilitate the transport of the particles to the inlet of the pelletizer.
  • the independent current may be in the opposite direction of the ignition current, and the magnetic field may be in the same direction as that of the first electrode EM pump.
  • at least one of the magnets and current of the second electrode EM pump may be less strong than those parameters of the fist electrode EM pump such that the velocity of the ignition particles is reduced.
  • the particle direction may not be completely reversed.
  • At least one of the Lorentz force and gravity may at least one of prevent the particles from impacting the PV converter and facilitate recovery of the particles.
  • each of the first and second set of magnets of the first and second electrode pumps are mounted to the bus bars 9 and 10, and the magnets are protected from overheating by at least one method of thermally isolating or cooling the magnets.
  • the magnets of each electrode electromagnetic pump may comprise at least one of a thermal barrier or thermal isolation means such as insulation or a thermally insulating spacer and a mean of cooling such as a cold plate or water cooling lines or coils and a chiller.
  • the cool or cold plate may comprise a micro-channel plate such as one of a concentrator photovoltaic cell such as one made by Masirao or a diode laser cold plate thai are known in the art.
  • the second electrode EM pump comprises a channel, a current source that may comprise a portion of the source of electricity to cause ignition, and magnets wherein the orientation of at l east one of the channel, the current, and magnetic field produces a Lorentz force that may be along the positive or negative z-axis and have a component in the xy-plane.
  • the Lorentz force of the second electrode EM pump may be oriented to at least one of produce a force on the ignition particles away from the PV converter and at least partially facilitate the transport of the particles to the inlet of the pelietizer.
  • the Lorentz force may be in the positive z-direction and have a component in the xy-plane.
  • the crossed current and magnetic fields of the embodiments of the electrode EM pumps of the disclosure may cause the ejection of adhering shot and the flow of the plasma particles to the regeneration system such as the pelietizer.
  • the trajectory of the pumped ignition particles may be such that impacting the PV converter may be avoided.
  • the particle trajectory may further be towards a desired portion of the cell wall such as a portion with no penetrations such as the electrode penetrations.
  • At least one of the electrodes and the ignition plasma has a component of the current along the z-axis and a component in the xy-plane, and the magnets such as 8c and 8c I are oriented to provide a magnetic field thai is crossed with the current.
  • the crossed applied magnetic field from magnets causes a Lorentz force having a component in the transverse xy-plane as well as the z-axis direction.
  • the z-direeted force may eject the plasma and any shot adhering to the electrodes.
  • the xy-p lane-directed force may cause the ignition particles to be forced to the ceil walls to be recovered.
  • the electrodes are offset along the z-axis (one having a slightly higher height than the other) such that a component of at least one of the ignition and plasma current is along the z-axis as well as in xy-plane.
  • the ignition particles may be force along a curved trajectory in a clockwise or counter clockwise direction with the origin at the ignition point of the electrodes.
  • the curved path may at least one of (i) direct the particles to the wall opposite the location of the penetrations of the bus bars 9 aad 10 (FIGURE 2114) and electrodes 8 and (ii) transport the particles to the inlet of the pelietizer.
  • the electrodes and any mirror surrounding them may direct the emitted light to the PV converter 26a.
  • the particles are prevented from impacting and adhering to the PV converter by at least one plasma and particle deflector such as a central cone in the exit of the channel with the tip of the cone facing the direction of the ignition electrodes.
  • the deflector may comprise two cones joined at the base to facilitate return of particles to the pelletizer.
  • the plasma may be directed to at least one additional plasma deflector that selectively deflects the plasma and light to the PV converter.
  • the particles may collide with the plurality of deflectors to lose velocity and at least one of fall and flow into the inlet of the pelletizer.
  • the plasma may follow about an S-shaped trajectory through the channel formed by the central and peripheral deflectors while the particles are stopped so that they may flow to the inlet of the pelletizer.
  • the particles are prevented from impacting and adhering to the PV converter by ai least one physical barrier that selectively transmits the plasma and light while at least partially blocking the ignition particles.
  • the physical barrier may comprise a plurality of elements located along the z-axis, each comprising a partially open physical barrier wherein the line of site along the z-axis through an open portion of the nth element is at least partially blocked by another element of a series of n elements wherein n is an integer.
  • the plurality of physical elements may comprise a plurality of horizontal ly staggered grids such as screens positioned along the direction from the point of ignition towards the PV converter. The elements may permit the physical transmission of plasma and light while blocking the particles.
  • the plasma gas may flow around the staggered grid while the particles impact the blocking portion to lose momentum to facilitate the recovery of the particles into the inlet of the pelletizer.
  • the electrode assembly may further comprise a source of magnetic fields such as permanent or electromagnets.
  • the plasma may be at least one of confined, focused, and directed to the region 81 (FIGURE 2112) such that the light from the plasma is directed to the PV converter.
  • the electrode magnets may force the plasma from the gap 8g to the cell region 81.
  • the magnets may further provide confinement to the plasma to cause it to emit light in the direction of the PV converter.
  • the confinement magnets may comprise a magnetic bottle. Magnets such as 8c of FIGURE 2110 may further comprise an ignition product recovery system of the disclosure.
  • the SF-CIHT cell may further comprise electrodes such as grid electrodes of the disclosure that may be circumferential to the plasma and contain the plasma predominantly in a selected region such thai it emits in a desired direction such as in the direction of the PV converter 26a.
  • the plasma and the particles from the ignition may be oppositely charged and migrate at different rates such that their respective migrations in the cell are separated in time.
  • the plasma may be comprised of ions and electrons.
  • the particles may be relatively massive.
  • the plasma may be negatively charged due to the much higher mobility of the electrons.
  • the particles may be positively charged.
  • the plasma may migrate much faster that the particles such that it expands from the electrodes before the particles.
  • Electrodes such as grid electrodes that are open to the flow of particles may be used to at least one of selectively direct and confine the plasma such that the light is directed to the PV converter 26a while the Lorentz force directs the particles to a desired region of the cell such as away from the PV converter 26a and back to the pelletizer.
  • the electrodes may be at least one of floating, grounded, and charged to achieve at least one of selective transport and confinement of the plasma to a desired region of the cell such 81.
  • the applied voltages and polarities may be controlled to achieved the at least one of selective transport and
  • the shot may be formed to have a small diameter such that the surface tension to maintain about a spherical shape is greater than electrode adhesion forces; so, the shot does not adhere to the electrodes.
  • the shot size may be la at least one diameter range of about 0.01 mm to 10 mm, 0.1 mm to 5 mm, and 0.5 mm to 1.5 mm.
  • the shot may be made with a smaller diameter by using at least one of a smaller nozzle 5q, a higher melt flow rate, a higher melt pressure, and a lower melt viscosity.
  • the electrodes comprise a shot splitter such as at least one thin wire such as a refractory wire across the gap where the shot ignition is desired.
  • exemplary wires comprise at least one of copper, nickel, nickel with silver chromate and zinc plating for corrosion resistance, iron, nickel-iron, chromium, noble metals, tungsten, molybdenum, yttrium, iridium, palladium, carbides such as SiC, TiC, WC, and nitrides such as titanium nitride,
  • the at least one wire may divide the shot into a plurality of segments that are spread out over a larger area than the un-spiit shot.
  • the electrode gap may be sufficiently large such as larger than the shot such that the shot passes through the gap without firing in the absence of the splitter.
  • the splitter may spread the shot and cause the current to flow through the spread shot. The spreading of the shot may cause the ignition to be confined to the wide gap region such that adherence to the electrode is avoided by way of avoiding contact of the shot with other regions of the electrode where the shot may otherwise adhere.
  • the electrodes may be beveled to form an upright V-shape such ihat the light is emitted in region 51 directed towards the PV converter.
  • the shot splitter may be movable and the electrode gap adjustable such that the spreading may be used during startup and elevated electrode temperature used during long duration operation to prevent the shot from adhering to the electrodes.
  • the ignition system further comprises an alignment mechanism such as a mechanical or piezoelectric one that adjusts the position of at least one of the electrodes 8 aod the nozzle 5q such that the shots 5t travel from the nozzle to the desired position of the electrodes such as the center hole or gap Sg.
  • the alignment may be sensed and controlled by a sensor and controller such as an optical or electrical sensor and a computer.
  • the alignment mechanism ma further serve to short the electrodes during staitup wherein the shorting serves to heat the electrodes.
  • the nozzle 5q may be off center at an angle to prevent melt from dripping back and disrupting the stream wherein the adjustment mechanism may maintain that the shots 5t are injected into the gap 8g from underneath the electrodes 8.
  • the cell may be operated under evacuated conditions.
  • the ceil 26 may comprise a vacuum chamber such as a cylindrical chamber or conical cylindrical chamber thai may have domed end caps.
  • the cell may comprise a right cylinder with a conical base to the fuel recovery and injection systems such as the pelleiizer.
  • the electrodes may penetrate at anodized feed throughs that may be vacuum tight.
  • the cell 26 may be housed in a chamber 5b3 and the electromagnetic pump 5k may be housed in lower vacuum-capable chamber 5b5.
  • the iniet of the pelleiizer and the outlet such as the nozzle may feed through the cell wail into the vacuum space of the cell maintained with seals for each inlet and outlet feed through.
  • the inside of the cell 26 may comprise surface that resists adherence of silver such as at least one of an Al, W, WC, Mo, and graphite surface.
  • At least one of the inside of the cell 26, the bus bars 9 and 10, and electrode components other than those that directly contact the melt to supply the ignition current may be coated with material that resists adherence of the melt.
  • Exemplary coatings comprise alurninurn such as polished anodized aluminum, W, Mo, WC, graphite, boron carbide, fluorocarbon polymer such as Teflon (PTFE), zirconia + 8% yttria, Mullite, or Muilite-YSZ.
  • the leads and electrode components may be covered with a housing such as a high-temperature stainless sieel housing that may be coated with a material of the disclosure that resists adherence of the melt.
  • the coatings may be sprayed, polished, or deposited by other means of the disclosure as well as others known in the art.
  • the coating may be on a support such as a refractory metal such as zirconium, niobium, titanium, or tantalum, or a high temperature stainless steel such as Hasiei!oy X.
  • the inside of the vacuum cell may comprise a conical liner having the anti-adhering surface.
  • the liner may comprise the wail materials and coatings of the disclosure.
  • the pelleiizer may comprise at least a reducer from the first vessel 5b to the pump tube of first pump 5k, an expander from the pipe tube to the second vessel 5c, and straight reducer between the second vessel 5c and the pump rube of the second pump 5k.
  • the pump tube is about 3/8" OD and the vessels are each be about 1 " ID.
  • the pelleiizer inlet is at the bottom of the ceil cone 26.
  • the pelleiizer outlet comprising the second vessel 5c and nozzle 5q may inject underneath the electrodes 8 (FIGURES 2114 and 2115) or at the top of the electrodes (FIGURES 2117 and 2118).
  • At least one of the first electrode EM pump comprising magnets 8c and channel 8g and second electrode EM pump comprising magnets 8c 1 and second electrode channel 8g i may at least one of (i) facilitate injecting the shot and particles into the gap 8g to cause ignition, (ii) facilitate recovering the ignition product and un-ignited shot to the pelleiizer, (iii) at least one of facilitate the directing and guiding of ignition particles away from PV converter 26a to avoid particle impact, and (iv) provide confinement to increase tine yield of hydrinos.
  • the confinement may create a pressure in at least one range of about I aim to 10,000 aim, 2 atm to 1000 atm, and 5 arm and 100 atm.
  • the excess injected Ag shot and particles may be at least one of pumped, directed, and facilitated to the pelletizer inlet.
  • the system may operate with a bottom wall temperature of about 1000 °C such that the silver remains molten. So, even if not all of shot participates in ignition, the energy loss may be mostly pump energy that may be very low, A minimum of heating in the first vessel may be necessary since some of the energy from ignition of the solid fuel may heat the silver.
  • the cell floor comprising the cell wall In the region of the inlet to the pelletizer may be heated by at least one of the ignition product and the ignition process.
  • the floor may be operated at a high temperature such as above the melting point of the metal of the fuel such as silver.
  • the floor may heat at least a portion of the recovered product.
  • the recovered product that is collected hot and the recovered product heated by the floor may flow into the pelletizer as preheated to consume less energy.
  • the melted ignition product may flow from the floor to the pelletizer as a liquid. Shot 5t that does not ignite at the electrodes 8 fail to the floor and flow into the pelletizer as well.
  • the flow may be as a liquid or a solid. In the case of appreciable power being absorbed by the ignition product before being cleared, the ignition product may become very hot such that the energy dissipated in the pelletizer may be consequently lowered.
  • the bottom of the celi cone comprises a melt reservoir or cone reservoir 5b.
  • the cell cone may comprise a material has at least one property of the group of silver adherence resistance, capable of high temperature, and non-magnetic.
  • Exemplary materials for at least one component, of the cell such as at least one of the cone reservoir and an upper cone comprising the cell walls are graphite, tungsten, molybdenum, tungsten carbide, boron nitride, boron carbide, silicon carbide, SiC coated graphite, and high temperature stainless steel.
  • the material may be coated.
  • Exemplary embodiments are SiC coated graphite, Mullite, and Mullite-YSZ coated stainless steel.
  • At least one of the inside of the cell 26, the bus bars 9 and 10, and electrode components other than those that directly contact the melt to supply the ignition current such as the magnets 8c and 8cl , channel 8gl , connection of the electrodes 8 to the bus bars 9 and 10, nozzle 5q, and injector 521 may be coated with material that resists adherence of the melt.
  • Exemplary coatings comprise aluminum such as polished anodized aluminum, W, Mo, WC, graphite, boron carbide, fluorocarbon polymer such as Teflon (PTFE), zirconia + 8% yttria, Mullite, or Mullite-YSZ.
  • the leads and electrode components may be covered with a housing such as a high-temperature stainless steel housing that may be coated with a material of the disclosure that resists adherence of the melt.
  • the SF-CIHT cell may further comprise a means to at least one of monitor the integrity of the coating and apply more coating such as graphite.
  • the SF-C3HT ceil may further comprise a graphite coating applicator such as a sprayer.
  • the sprayer may comprise ai least one nozzle that directs the spray comprising graphite onto the cone surface and a source of graphite such as dry graphite lubricant known in the art.
  • the material such as graphite may ⁇ be polished.
  • the polished may be performed with a fine abrasive such as one comprising at least aluminum oxide, silicon carbide, and diamond powder.
  • the cone reservoir comprising graphite may be fabricated by 3D printing.
  • the cell cone cut from graphite by a cutter may comprise a laser or water jet.
  • the cutter may comprise a mechanical saw.
  • the cutter may be angled and rotated.
  • the cone may be cut from a tilted and rotated graphite block.
  • the cone may be made in a plural ity of sections such as an upper cylinder, a middle cone such as one with 45° walls, and a bottom cone reservoir.
  • the cone comprises segmented pieces such as triangular pieces thai are assembled to form a cone.
  • the pieces may be sheefs.
  • the sheets may be cut in triangular pieces and fitted together to form the cone.
  • the pieces may comprise cladding of a support structure such as a stainless steel conical frame or cone.
  • the pieces comprising male pieces in an assembly mechanism may be fitted into top and bottom rings comprising female slots to receive the male pieces.
  • the top and bottom rings may be fastened to a frame directly or indirectly such as the vacuum chamber 26 wherein the fastening causes the pieces to be held together.
  • the bottom ring may further comprise a flange that attaches to the cone reservoir 5b.
  • the attachment points of cone elements comprised of graphite may comprise expansion joints.
  • Exemplary embodiments of ai least one of the upper cone and the cone reservoir are at least one of graphite and SiC coated graphite formed into a cone, at least one of graphite and SiC coated graphite lining a support such as a stainless cone, at least one of segmented graphite and SiC coated graphite plates lining a stainless cone, at least one of segmented graphite and SiC coated graphite plates mechanically held together, W foil formed into a cone, W plated stainless steel cone, W foil lining a support such as a stainless steel cone, segmented W plates lining a stainless steel cone, segmented W plates mechanically held together, stainless steel having a steep angle such as about 60° and Muliite or Muliite-YSZ coated, Mo foil formed into a cone, Mo plated stainless steel cone, Mo foil lining a support such as a stainless steel cone, segmented Mo plates lining a stainless steel cone, segmented Mo plates mechanically held together, stainless steel having a steep grade
  • a cone such as a stainless steel cone that is heated above the melting point of the melt such as the Ag or Ag-Cu alloy melt.
  • the heating may be achieved by at least one of a heater such as an inductively coupled heater and a resistive heater and by the hydrino reaction.
  • a heater such as an inductively coupled heater and a resistive heater and by the hydrino reaction.
  • Other materials for ai least one of the upper cone, windows such as PV windows, and housings to prevent ignition product adhesion comprise at least one of sapphire, alumina, boro-silica glass, K4gF 2 , and ceramic glass.
  • the cell walls above the cone reservoir may comprise a material such as a metal such as aluminum thai may have a lower melting point than the operating temperature of the cone reservoir.
  • the corresponding upper cone such as one comprising segmented aluminum pieces or plates may end before the cone reservoir and may further extend over the otherwise connecting edge with the cone reservoir such thai returning melt may flow over the edge into the cone reservoir.
  • the upper cone may at least one of comprise a heat sink such as thick plates and may be cooled to prevent melting.
  • the surface may comprise an oxide such as aluminum oxide to prevent adhesion of the melt.
  • At least one of the conical ceil 26 and cone reservoir 5b may comprise or is coated with at least one of mica, wood, cellulose, lignin, carbon fiber, and carbon fiber-reinforced carbon wherein at least some of the surface may be carbonized to graphite.
  • the heat from the hydrino process may cause the cone wall to overheat.
  • the wood cone reservoir or cone cell may comprise a backing heat sink such as a metal sink thai may be cooled.
  • the cooling may comprise a heat exchanger that may be attached to the cone reservoir or cone cell wail
  • the heat exchanger may comprise a coolant that may be cooled by a chiller 31 a.
  • the heat exchanger may comprise pipes that are fastened to the cone wall wherein a gas such as air is followed through the pipes by an air mover such as a fan.
  • the system may be open such that the wall is cooled by air-cooling.
  • the metal in the reservoir may be melted or maintained in a molten state by heating.
  • the metal may be heated indirectly by heating the outside of the reservoir or heat directly,
  • the reservoir may be heated with a heater such as at least one of a resistive heater and an external or internal inductively coupled heater 5m comprising leads 5p and coil 5f. Since silver has a high thermal conductivity, the internal heat should be rapidly and evenly transferred for an internal resistive heater.
  • Suitable resistive heaters capable of high temperature are ones comprising Nichrome, graphite, tungsten, molybdenum, tantalum, SiC, or MoSi2 s precious metals, and refractory metal heating elements.
  • the geometry may be such that there is rapid heat transfer with a minimization of space such as a pancake-shaped heater.
  • the heater may be treated with the appropriate protective coating to interface with at least one of steam and hydrogen.
  • the heating element may be protected from reaction with at least one of water and hydrogen by being wetted with the melt such as silver.
  • the light from the ignition of the fuel propagates predominantly upward to the PV converter 26a; however, any light and heat that propagates downward may serve to heat the ignition products such as those in the cone reservoir 5b to limit the amount of heater power
  • the reservoir may be maintained in the vacuum of the ceil provided by lower vacuum-capable chamber 5b5 and vacuum connection 5b6 to decrease heat loss by means such as conduction and convection.
  • the reservoir may further comprise radiation shields that may have passages for the return of the ignition product such as molten silver.
  • the reservoir may comprise a thermos or vacuum jacketed walls such that heat loss is minimum, in an idle condition of the SF-CiHT ceil, the reservoir may only need heating periodically to maintain the melt such that the ceil is in a ready condition to operate.
  • the reservoir may comprise at least one bubbler tube 5z to supply and incorporate at least one of water and hydrogen into the melt.
  • the bubbler tubes 5z may comprise a serpentine gas flow field or diffuser such as one known in the art of fuel ceils such as molten fuel cells.
  • the bubbler tubes may comprise an inverted cup to trap the injected gases such as H2O and H2 to be at least one of dissolved and mixed into the melt.
  • the gas may be released inside the inverted cup-shaped diffuser.
  • the diffuser may be submerged under the melt, and the melt may flow around the top of the diffuser to the underside to receive the gases.
  • the trapped gas may provide pressure to facilitate the flow of the melt into the electromagnetic pump 5k.
  • the bubbler rube 5z such as a flow field may comprise a material that silver does not wet such as at least one of graphite, W, and WC.
  • the lack of wettability may prevent the silver from clogging the gas holes of the bubbler.
  • the pipe bubbler 5z may comprise a hydrogen permeable membrane such as at least one comprising carbon such as wood, cellulose, or Hgnin wherein the surface may be carbonized, and grapiiite, carbon fiber- reinforced carbon, and Pd-Ag alloy, Ni, niobium, Pd, Pt, Ir, noble metal, and other hydrogen permeable membrane known in the art.
  • the membrane may receive hydrogen gas such as from source 5 and facilitate its diffusion across the membrane to the melt such as at least one of Ag, Ag-Cu alloy, and Cu melt.
  • the pipe bubbler 5z may further comprise a water- permeable membrane or frit such as a porous ceramic membrane or frit.
  • the 3 ⁇ 40 permeable frit may comprise a material such as zirconia, Muiliie, Mullite-YSZ, or porous graphite that is unreactive with H 2 0 and is not wetted by the melt.
  • the membrane may comprise a honeycomb.
  • exemplary membranes and frits comprise yrtria-stabilized zirconia, scandia stabilized zirconia, gadolinium doped ceria thai may further comprise a cermet.
  • Alternative membranes comprise cellulose, wood, carbonized wood, and carbon fiber- reinforced carbon. The pressure from the source such as 5u and 5v may control the rate thai 3 ⁇ 4 and H 2 0 are supplied to the melt.
  • the pelletizer 5a comprising a molten metal fuel further comprises at least two values to selectively, alternatively seal the second vessel 5c and the gas from manifold 5y such that pressurized gas such as at least one of 3 ⁇ 40 and 3 ⁇ 4 are applied to the melt in the second vessel 5c.
  • a valve on the inlet of the second vessel 5c is ciosed to prevent backflow into the first EM pump 5k, and a manifold valve is opened to allow the melt to be treated with pressured gases supplied through manifold 5y.
  • the second pump 5k and the gas pressure may force the gas-treaied melt out of the second vessel 5c and through the nozzle 5q.
  • the valve to the manifold 5y is closed and the value at the inlet to the second vessel 5c is opened to allow the first EM pump 5k to pump melt into the second vessel 5c to repeat a cycle of pressured gas treatment and ejection of the treated melt.
  • Alternative valve, pump, and gas and melt lines and connections known to those skilled in the art are within the scope of the disclosure.
  • the pelletizer may comprise a plurality if second chambers 5c with inlet and manifold values.
  • the fuel hydration may be
  • the plurality of bubblers may be fed off a manifold 5y.
  • At least one of Hi and H2O may be supplied a source of each gas such as 5u and 5v.
  • at least one of water, water vapor, and steam are provided from source 5v.
  • At least one of water vapor and steam may be supplied by at least one of a water vapor generator and steam generator 5v.
  • the water vapor generator may comprise a carrier gas and a water source wherein the carrier gas is bubbled through the water such as water reservoir 5v.
  • Hydrogen may comprise the carrier gas bubbled through 3 ⁇ 40 to also serve as a reactant in the hydrino reaction.
  • the SF-CIHT generator may further comprise a recovery and recirculation system of any unreacted 3 ⁇ 4 that may be recycled.
  • the recovery system may comprise a getter such as a metal that selectively binds hydrogen to provide it to the recirculation system such as a pump.
  • the recovery system may comprise a selective filter for H 2 or other system known by those skilled in the art.
  • the carrier gas may comprise an inert gas such as a noble gas such as argon.
  • the SF-CIHT generator may further comprise a recovery and recirculation system of the carrier gas that may be recycled.
  • the recovery system may comprise a selective filter for the carrier gas or other system known by those skilled in the art.
  • the fuel comprising melt that has absorbed at least one of H 2 0 and 3 ⁇ 4 may be transported out of the reservoir.
  • the reservoir may outlet to an electromagnetic (EM) pump 5k.
  • the EM pump may outlet into the second vessel 5c comprising an injection tube that may be trace heated with a heater such as an inductively coupled heater 5o.
  • the tubing such as one of the disclosure may be very efficient at absorbing the inductively coupled heater radiation.
  • the tube may have a low emissivity such as polished or electro-polished tubing that may be run in a vacuum chamber,
  • the heater such as a resistive heater of the second vessel 5c may be inside of the second vessel wherein the second vessel has sufficient diameter or size to accommodate the internal heater.
  • the pump rube 5k6 may be filled with the fuel metal such as silver or silver-copper alloy to increase the heat transfer cross sectional area.
  • the area may be increased to increase the rate that heat is conducted along the tubing from the heated cone reservoir 5b to the inlet to the pump 5k.
  • the pump tubing may be heated with resistive trace heating, or the tubing may be insulated.
  • the tubing comprises insulation thai is variable or adjustable to control the teat transfer between insulating and effect at heat transfer.
  • variable, adjustable, or controllable insulation comprises a vacuum jacket the surrounds the pump tubing.
  • the vacuum jacket may be evacuated during start up, and gas can be added to the jacket for rapid heat transfer after the pump is operating.
  • the outside of manifold of the vacuum jacket may be cooled with water-cooling to provide addition heat removal capacity to prevent overheating.
  • the pump tubing and bus bars may comprise a high temperature material such as Ta that is capable of operating at a temperature in excess of that achievable during operation of the pump.
  • the high-temperature capable pump tube such a Ta pump tube may be coated with a high-temperature oxidation-resistant coating.
  • the bus bars may comprise a more conductive metal than the pump tube metal.
  • the bus bars may be capable of operating at high temperature. Radiative heat transfer may limit the maximum operating temperature.
  • the pump tube may comprise elements such as fins that increase the surface area to increase the heat transfer.
  • the hig -temperature capable tube may comprise a coating to prevent oxidation.
  • the pump tube may comprise a cooling system such a water coils in contact with its surface wherein the water is initially evacuated during startup. Once the pump is at operating at temperature, the water or other suitable coolant may be pumped through the cooling system to remove excess heat as needed in a controlled manner.
  • the control may be achieved by controlling the coolant pump speed, the chiller heat rejection rate, and the coolant inlet and outlet temperatures.
  • the electromagnetic pump is housed in a lower chamber 5b5 that may be filled with a heat transfer gas such as an inert gas such as argon or helium.
  • the inert gas may further comprise hydrogen such as noble gas-hydrogen mixture such as one comprising about 1 to 5% 3 ⁇ 4 in order to prevent the oxidation of the pump tube.
  • the lower chamber 5b5 may be sealed to the cell 26 with a flange and a gasket such as a graphite gasket.
  • the pressure may be adjusted to control the pump tube temperature.
  • the cooling system may comprise an inert gas tank, pump, pressure gauge, pressure controller, and temperature recorder to control the heat transfer rate from the pump tube.
  • the second vessel 5c comprises a bend at its inlet end and an injection section that ends at the nozzle 5q wherein it receives melt from the pump 5k and serves as a conduit to transport it to the nozzle 5q to be injected into the electrodes 8.
  • the cell cone reservoir may tapper into the inlet of the pump tube 5k.
  • the pump tube may be oriented vertically.
  • the second vessel may bend in in an arc in the range of about 90° to 300° so that the injection section of the second vessel is oriented towards the electrodes 8.
  • the second vessel 5c may travel back through the cone reservoir in route to inject the melt into the electrodes.
  • the diameter or size of the peiletizer components such as the second vessel may be selected such that the drag on the flow is not excessive.
  • the second vessel may be heated such as trace heated by a heater such as a resistive or inductively coupled heater.
  • the heater such as the inductively coupled heater to heat the injection section may comprise a coil such as 5F that heats the inlet portion and may further comprise coiJ 5o that may penetrate the wall of cell 26 and heat the injection section.
  • the inlet portion of the second vessel may comprise a tubular loop that is heated by an inductively coupled heater having a coil 5f that surrounds the tubular loop.
  • the eel! wall 26 comprises a material resistant to silver adherence such as at least one of graphite, graphite coated metal such as graphite coated high temperature stainless steel, tungsten, and tungsten carbide.
  • the cell wall may taper into a conical bottom.
  • the cel l bottom may comprise a flange that may connect to a mating flange connecting to a cone reservoir 5b to contain melt such as silver melt.
  • the cone reservoir 5b may be capable of high temperature operation and may comprise a material such as graphite, tantalum, niobium, titanium, nickel, molybdenum, tungsten or other- high- temperature or refractory material or metal such as a high temperature stainless steel.
  • the cone reservoir may be lined with material that resists adherence of the melt such as silver melt.
  • An exemplary cone reservoir and liner comprise graphite or tantalum or niobium lined with graphite.
  • the graphite liner may be connected to the cell. The connection may be by mating flanges that are fastened together by fasteners such as high- temperature screws such as Mo, Ta, or Nb screws.
  • the fasteners may comprise anchors with mating bolt or screws that thread into the anchors.
  • the cone reservoir is in vacuum or an inert atmosphere, it may also comprise graphite with no liner.
  • the vacuum or inert atmosphere may be provided by a vacuum-capable lower chamber 5b5.
  • the cone reservoir may comprise a bottom flange that connects to a mating flange of the inlet of a pump tube of an electromagnetic pump 5k.
  • An inductively coupled heater comprising surrounding coil 5f may heat the cone reservoir 5b and at least a portion of the inlet to the pump 5 k to a temperature above the melting point of the melted metal such as at least one of silver, silver copper alloy, and copper metal.
  • the tube may initially point downward and then form a loop having a suitable radius of curvature to place the tube in a vertical direction to intersect, the cone reservoir 5b,
  • the inlet may transition into the straight pump tube 5k6 wherein the direction of pumping may be oriented vertically.
  • the outlet tube of the pump may run vertically to intersect the cone reservoir wall.
  • the intersection may be at the cones largest radius to provide the maximal distance of the pump yoke and magnets 5k4 and 5k5 (FIGUKJi 2116) from the cone reservoir 5 b to provide for operating these pump components at a suitably lower temperature than that of the cone reservoir.
  • the pump magnetic circuit 5k4 and 5k5 may be oriented tangentialiy to the cone reservoir, and the bus bars 5k2 may be short and oriented perpendicularly to the cone reservoir with leads 5k3 to the current source at about 90° to the direction of the bus bars 5k2. The orientation of the magnetic circuit 5k4 and 5k5 may maximize the distance from the elevated temperature components.
  • the high-operating-temperature components such as the cone reservoir and the inlet tube, pump tube 5k6, and outlet tube are required to be above the melting point of the melt, and the low-operating-temperature components such as the magnetic circuit 5k4 and 5k5 of the EM pump 5k are required to be at a much lower temperature such as less than about 300 °C.
  • the peiletizer may comprise insulation between the
  • the magnetic circuit may be cooled by a cooling system such as one comprising water-cooled heat transfer plates 5k! and a chiller 3 la.
  • the water-cooled coils of the inductively coupled heater 5f may also serve to cool the magnetic circuit of the electromagnetic pump 5k and vice versa.
  • the cone reservoir and the pump inlet may comprise the first vessel 5b.
  • the electromagnetic (EM) pump 5k may pump the melt such as the silver melt from the cone reservoir to the electrodes through the second vessel 5c that may comprise pump outlet tube such as a tantalum or niobium tube of about 3/8 inch diameter and nozzle 5q.
  • the loop of the pump inlet and outlet tubes may comprise a bend of at least about 180 s back through the cone reservoir wall.
  • the tube 5c may travel inside of the cone reservoir 5b in a region such as one below the silver melt level contained in the cone reservoir, and protrude above the melt level ending in nozzle 5q.
  • the nozzle may be slightly above the melt level such that the melt remains molten while flowing in the tube without the need of a vessel heater.
  • heating is applied to the distal injection section of the second vessel by a heater such as an inductively coupled heater.
  • the electrodes may be located very close to the level of the melt.
  • the separation distance of the melt and the electrodes is within at least one range of about 1 mm to 100 mm, 1 mm to 50 mm, and 1 mm to 10 mm.
  • the cell may have a larger diameter vacuum housing flange at the bottom of the cell containing the inner cone reservoir flange and the inlet to the cone reservoir.
  • a lower chamber 5b5 capable of maintaining a vacuum or an inert atmosphere may be connected to the vacuum housing flange.
  • the interior vacuum of die vacuum housing may be connected to the interior vacuum of the ceil by a vacuum connection line 5b6.
  • the vacuum connection line 5b6 may connect to a common manifold to the ceil vacuum pump 13a.
  • the lower vacuum-capable chamber 5b5 may comprise a right cylinder that may have a domed end cap.
  • the lower vacuum-capable chamber 5b5 may contain at least one of the cone reservoir 5b, at least a portion of the electromagnetic pump 5k comprising the pump tube 5k6 and its inlet and outlet, the EM pump bus bars 5k2 and at least a portion of the magnetic circuit 5k4 and 5k5, and the heating coil 5f.
  • the electrical connection to bus bars of the EM pump 5k3, the leads to the inductively coupled heater coil 5p, and any sensor leads may penetrate the walls of the lower vacuum-capable chamber 5b5.
  • a portion of the EM pump magnetic circuit 5k4 and Sid may penetrate or have flux penetrate the lower vacuum-capable chamber 5b5 wherein the magnets and optionally a portion of the magnetic circuit 5k4 and 5k5 may be outside of the lower vacuum-capable chamber 5b5.
  • the vacuum may protect air sensitive materials such as graphite, Ta, and Nb from oxidation, in another embodiment, the lower chamber 5b5 capable of maintaining a vacuum or seal from atmosphere may not be connected to the vacuum of the cell.
  • the lower chamber 5b5 may be filled with an inert gas such as nitrogen or a noble gas such as argon. Further protection may be achieved by coating atmospheric gas reactive materials with a protective coating such as an electroplated or physical coating such as ceramic.
  • the inductively coupled heater coil leads penetrate into a sealed section of the generator such as at least one of the cell 26 or the lower chamber 5b5.
  • the lead 5p penetration of the corresponding wail such as at least one of the cell, chamber 5b5, and a partition between the two such as a electromagnetic pump flange plate may be electrically isolated such that the leads 5p to not electrically short.
  • the penetrations may occur at the wall or may occur at a location distant from the wall in order to provide a location wherein the temperature is lower than at the wall.
  • the wail may be connected to the distant location by a conduit that houses the lead without electrical contact.
  • the conduit end that is opposite the sealed penetrations may be welded to the wall to be penetrated to form a seal at the wall location.
  • the lead may pass through a hole in the element such as the electromagnetic pump flange plate without making electrical contact with the element.
  • the leads may be polished to lower the emissivity and heat transfer to the leads.
  • the conduit may be vacuum-sealed about the lead with an electrical insulator at the opposite end of the conduit from the hot conducting element where the temperature is much lower.
  • the insulator may comprise a low temperature seal such as a Teflon seal such as a Teflon SwageSok or Utra-Torr with alrez O-ring.
  • the vacuum tight lead penetrations may comprise commercially available hig -temperature RF penetrations.
  • the cone reservoir and chamber 5b are threaded and screwed together in the vacuum connector to a top plate of the vacuum housing.
  • the pump tube may penetrate the top plate, Vessel 5b may be attached to the top plate by means such as welds.
  • the pump tube 5k6 may be heated independently by a heater such as an inductively coupled heater thai maintains the tube at a desired temperature above that of the melting point of the melt.
  • one inductively coupled heater RF power unit may be multiplexed to a plurality of inductively coupled heater coils.
  • the pump tube heater may comprise a heater coil thai is intermittendy driven by the RF generator for the cone reservoir heater at a duty cycle of the RF generator that is switched over timed between driving the cone reservoir heater coil and the pump tube heater coil.
  • the duty cycle may be controlled to maintain the cone reservoir and the pump tube at desired temperatures.
  • An exemplary duty cycle range is about 10 % to 90%.
  • the EM pump tube may be heated by heat transferred from a hot section of the generator.
  • the heat may be from a heater or from the hydrino reaction.
  • the heat transfer is from the heated cone reservoir 5b transferred by a conductive medium such as copper that may comprise heat transfer blocks 5k7 (FIGURE 2126).
  • the blocks may be machined or cast to contact the cone reservoir and the pump tube.
  • the pump tube may be coated with a heat transfer compound such as Thermon T-99.
  • Each bus bar 9 and 10 may comprise a connection to a capacitor bank.
  • the capacitor bank may comprise a plurality (e.g. two) of parallel sets of two capacitors in series with one connected to the positive bus bar and one connected to the negative bus bar with the corresponding opposite polarity capacitor terminals connected by a bus bar.
  • the circuit may be completed with the arrival of shot between the electrodes.
  • the capacitors may be connected to a source of electrical power to charge the capacitors and maintain their voltage during operation wherein the voltage is sensed at the capacitors.
  • Each bus bar may vertically penetrate the cell wall and comprise a mount such as a copper block with threads to receive the threads of the terminal of the corresponding capacitor.
  • a horizontal bus bar may screw into the threaded end of each vertical bus bar, and the electrodes may slide onto the ends of the horizontal sections.
  • the electrodes may be secured by fasteners such as clamps with bolts or set screws.
  • the electrodes may comprise one of the disclosure such as a downward V -shape the forms a channel at the gap 8 towards the PV converter 26a and further comprises an electrode EM pump comprising channel 8 and magnets 8c and optionally a second electrode EM pump comprising magnets 8c 1 and channel 8gi.
  • the magnets such as 8c and 8c 1 may be located outside of the cell 26.
  • the magnetic Geld may be supplied to the channel such as 8g and 8g l by a magnetic circuit 8c (FIGURE 2129) such as ferromagnetic yolks that may operate at high temperature such as at least one of iron, cobalt and Hiperco ® 50 Alloy (49% Co, 49% Fe, 2% V) yokes.
  • the yokes may comprise one material such as Co or Hiperco ® 50 Alloy at the gap where the temperature is greatest and another material such as iron at the lower-temperature portion interfacing the magnets.
  • the magnets may comprise a material that has a high maximum operating iemperaiure such as CoSm magnets.
  • the magnetic circuit may comprise an inner magnet that may operate at higher temperature such as an A! Co magnet that may operate at a maximum temperature of up to 525 °C compared to 350 °C for CoSm.
  • the electrode EM pump magnetic circuit may comprise the magnets and the yokes and each may penetrate the cell wall 26.
  • the magnetic flux may penetrate the wail from a first outside magnetic circuit section to a second magnetic circuit section inside of the cell.
  • An exemplary wall material that permits the flux penetration is a high temperature stainless steel.
  • the nozzle 5q may be positioned in close proximity to the electrodes 8 such that the pressure from the EM pump 5k pumps the melt through the electrode gap 8g and optionally 8g l wherein at least one of the first and second electrode EM pumps are optional.
  • the nozzle 5q may comprise a non-conductor such as quartz or a low conductor such as graphite such that it may be in proxim ty to the gap 8g or may be in contact with the electrodes 8 to facilitate direct pumping of the melt through at least one electrode gap or channel 8g and 8gl .
  • the nozzle may be tipped with a non-conducior such as a quartz or ceramic sleeve, coated with a nonconductor such as boron nitride, or comprise a conductor such as the material of the pump tube, but a minimum gap may be maintained between the nozzle and electrodes 8.
  • the cell may electrically floated, rather than being grounded to prevent the flow of electricity through the nozzle to other components in the cell.
  • the cell walls, bus bars 9 and 10, and any other elements in the cell may be covered with a sheath that resists adherence of the melt such as silver or silver-copper alloy such as Ag 72 wt%-Cu 28 t%.
  • a exemplary sheath material is graphite, boron carbide, fluorocarbon polymer such as Teflon (PTFE), zirconia + 8% yttria, Muliite, or Muiliie-YSZ.
  • the shot ignited by the electrodes may comprise molten metal such as molten Ag that may further comprise at least one of gas of the group of 3 ⁇ 40 and hydrogen.
  • the cone reservoir 5b may comprise at least one gas or water line such as a line from a manifold 5y connected to a source of at least one of H 0 and 3 ⁇ 4 5u and 5v and a pipe bubbler or gas flow field 5z to add the gases to the melt.
  • the line may penetrate the wall of the cone reservoir 5b to connect to the pipe bubbler 5z or gas flow field.
  • At least one of H 2 0 and 3 ⁇ 4 may be added by injection by an injector 5zl regulated by injector regulator and valve 5z2 at the electrodes 8.
  • the injector 5z l may- inject at least one of H 2 0 and H 2 into at least one of a portion of the ignition plasma, the center of the ignition plasma, into the a portion of the melt and substantially into the middle of the stream of the melt to maximize the incorporation of the at. least one of H 2 0 and 3 ⁇ 4 into at least one of the melt and the plasma.
  • An exemplary injector 5zl comprises a stainless steel tube having a 50 um hole at the end that injects H 2 0 directly into the plasma.
  • the injector may comprise a nozzle comprising at least one pinhole such as each having a diameter in the range of about 0.001 um to 5 mm.
  • the gas may directionally flow from the injector 5zl .
  • the gas may comprise a gas jet or molecular beam such as at least one of a H 2 0 and H 2 jet or beam.
  • the nozzle may be located close to the point of ignition such as within 0, 1 to 5 mm of the electrode gap 8g to efficiently supply the gases to the ignition while avoiding excess gas to be pumped from the cell.
  • the injection may occur above of below the electrode gap 8g.
  • the tip of the injector 5z l may comprise a material that is resistant to heat damage such as a refractory metal such as one of the disclosure such as W or Mo.
  • the nozzle of the injector 5zl may comprise a plurality or array of pinholes such as ones aligned along the length of the electrodes to inject gases into the molten metal.
  • the pinholes are about 25 um in diameter.
  • the injection may be at high velocity. The high velocity may assist in impregnation of the metal with the gases so that the gases may be introduced to the reaction mixture with a greater yield.
  • the molecular beam may facilitate the formation of HOH catalyst, in an embodiment, the tip of the injector 5zl may comprise a diffuser to form a fme mist of the water injected into the plasma or fuel to be ignited.
  • the injector 5zi is designed to limit the heat transfer rate from the plasma to the injector such that the water at its flow rate to sustain a desired power from the hydrino process does not boil while within the injector.
  • the injector 5zl may comprise i.) a minimum surface area, ii.) material of low heat transfer rate, iii.) surface insulation, and iv.) radiation shields to limit the heat transfer to the flowing water.
  • the hydrino reaction is 3 ⁇ 40 to 3 ⁇ 4(l /4) + 3/2 ⁇ 3 ⁇ 4 + 50 MI
  • the minimum water flow rate to generate X watts of power is given by
  • the power to cause 0. 18 mi per second of water to boil from an initial temperature of 0 °C is 490 W.
  • the injector 5zl is designed such that its maximum rate of acceptance of heat from the cell such as from the plasma corresponds to a power of less than 490 W.
  • P ⁇ pv J (40) wherein P is the pressure, p is the density of water, and v is the velocity, a water injection pressure of 3 arm corresponds to a nozzle 5q flow rate of 25 m/s.
  • the size of the orifice of the nozzle 5q to deliver 0, 18 rrd/s (0.18 X 10 " * ⁇ ) at this flow rate is 7.2 X 10 "9 m 2 (95 um diameter disk).
  • Exemplary heat resistant nozzles with a low heat acceptance rate comprise alumina or zirconia that may be stabilized with caicia or yttria.
  • the nozzle 5q such as one comprising a pinhole may have a shape to cause the water stream to spread into a volume that disperses the water throughout a desired portion of the plasma. The spread may comprise an even dispersion of the water in the plasma.
  • the water source 5v may comprise a water reservoir and a pump to supply the water to the injector 5zl .
  • the valve, flow meter, and regulator 5z2 may control the rate of water flow to be injected through nozzle 5q.
  • the injector 5zi may comprise a humidifier that may maintain a desired partial 3 ⁇ 40 pressure in the region of the eiectrodes such as one in at least one range of about 0.01 Torr to 1000 Torr, 0.1 Torr to 1 00 Torr, 0.1 Torr to 50 Torr, and 1 Torr to 25 Torr.
  • the molecular beam may be cooled to form ice crystals that may increase the rate of the hydrino reaction.
  • the cooling may be provided by chiller 31a.
  • the cooling may be achieved by cooling a carrier gas such as hydrogen or a noble gas.
  • the water may be cooled to the limit of freezing.
  • the freezing point may be lowered by dissolving carrier gas such as hydrogen in the water to form super-cooled water.
  • the super-cooled water may be aerosolized by bubbling the carrier gas such as hydrogen.
  • micro-water droplets such as in the range of 0.1 to 100 urn diameter may be formed by an aerosolizer such as an ultrasonic aerosolizer.
  • the ultrasonic frequency may be high such as in a range of about 1 kHz to 100 kHz.
  • the aerosolization may result in the formation of ice crystals.
  • the water may be injected into vacuum.
  • the expansion into vacuum may cool the water to form ace.
  • the evaporation of the water injected into vacuum may form the ice.
  • the evaporation may cool the tip of the injector 5zl that may cause the injected water to form ice.
  • At least one of the injected water and tip may be cooled by chiller 3 ia.
  • the cooling may be to a temperature that results in ice crystal formation of the injected water while preventing the tip from icing up and clogging.
  • the formation of ice crystals may be further facilitated by bubbling cooled carrier gas.
  • the super-cooling may also be achieved by at least one of reducing the pressure and elimination of nucleation sites in the water reservoir such as the bubbler.
  • an additive may be added to the water to lower the freezing point.
  • Exemplary additives are salts, inorganic compounds, and organic compounds.
  • the organic compound may be consumed and replaced during operation of the ceil, Gas such as hydrogen gas may be bubbled through the water to form ice crystals that may be injected into the melt to serve as a source of at least one of H and HOH catalyst for the hydrino reaction.
  • ice may be sublimated and directed to the electrodes. The vaporized ice may be flowed through a manifold.
  • the ice may nucleate or undergo deposition to larger crystals by physical contact with a suitable surface wherein the larger particles may be flowed into the ignition site.
  • the flow may be through the manifold having a plurality of pinholes.
  • the injector may be located in the walls of the electrodes such as in the channel 8g.
  • the injector 5zl is on the opposite side of the nozzle 5q. in an exemplary embodiment, the nozzle 5q injects melt into the electrodes 8, and the injector Sz l injects at least one of H2O and 3 ⁇ 4 from the top, on the other side of the electrodes such as in the channel 8g.
  • the water may be in the form of at least one of fine ice crystals, vapor, and liquid water.
  • input gas from a source such as 5u and 5v is injected into the ceil thai is maintained under a vacuum.
  • Controlling the input pressure that may be less atmospheric may control the flow rate of the gas through the injector 5zl .
  • At least one of the input gas pressures for injection and flow rate may be controlled by valve, pump, flow controller, and pressure monitor and controller 5z2.
  • the cell vacuum may be maintained with a water vapor condenser such as at least one of a chiller, cryopump, and vacuum pump 13a.
  • the cell vacuum may be maintained with a water trap and a pump such as a vacuum pump such as a Scroll pump.
  • the water condenser may comprise at least one of a chiller and a cryotrap.
  • the pump may comprise a high-ieniperarure pump mat maintains the cell gas at an elevated temperature while pumping such that the water vapor component essentially behaves as an ideal gas. Any- injected or formed water may be removed as steam that may serve as a means to cool the cell.
  • die cell comprises a chemical getter for removing the water vapor from the cell gas to maintain vacuum.
  • the getter may comprise a compound that reacts with water such as a metal that may form an oxide.
  • the water reaction product may be reversible by heating.
  • the getter may comprise a hydroscopic compound such as a desiccant such as at least one of a molecular sieve, silica gel, clay such as Montmorilionite clay, a dehydrated base such as an alkaline earth oxide such as CaG, a dehydrated hydrate compound such as an alkaline earth compound comprising an oxyanion such as a sulfate such as CaSO ⁇ and an alkali halide that forms a hydrate such as LiBr to absorb the water vapor in the cell.
  • the compound may be regenerated by heating. The heat may be from the excess heat produced by the cell.
  • the compound may be cyclically removed from contact with cell gases, regenerated, and returned.
  • the compound may remain in a sealed chamber when heated such that a steam pressure above atmospheric is generated.
  • the steam at an initial high pressure may be vented through a valve that is opened.
  • the valve may be closed at a reduced pressure relative to the initial pressure that is still greater than atmospheric such that air does not flow into the chamber.
  • the chamber may be cooled and the compound exposed to cell gases to absorb water in a repeat cycle.
  • the transport of the compound may be by a means of the disclosure such as by mechanical means such as by an auger or by using a pump.
  • the transport may be by using a pneumatic means such as one of the disclosure.
  • the compound is in a chamber with at least two valves.
  • a first absorption valve controls the connection with the cell gases and a second exhaust valve controls the connection to the water exhaust region such as the ambient atmosphere.
  • the absorption valve is opened and the exhaust valve is closed.
  • the absorption valve is closed and the exhaust valve is open. The valves may alternately open and close to achieve the water absorption and exhaust.
  • the absorption valve may comprise a large valve such as a gate valve to increase the gas flow exposed to the compound.
  • the exhaust valve may comprise a smaller pressure-regulated valve such as a blow-off valve that opens at a desired pressure and closes at a lower desired pressure.
  • the chamber may be in proximity to the cell such that the cell ordinarily heats it.
  • the chiller such s 31 a may cool the chamber.
  • the cooiing may be suspended to a! low the ceil to heat up during the exhaust phase. The suspension may be achieved by stopping the coolant flow.
  • the cooiant may have a boiling point that is higher than the highest operating temperature of the chamber, in another embodiment, heat may be removed or supplied to the chamber by a heat exchanger such as a heat pipe, in an embodiment, water may be removed continuously by a plurality of reciprocating two-valve desiccant chamber water removal systems wherein at least one system operates in the absorption phase while another operates in the exhaust phase.
  • the ultraviolet and extreme ultraviolet light from the hydrino reaction causes the water vapor in the ceil to dissociate into hydrogen and oxygen.
  • the hydrogen and oxygen are separated by means of the disclosure to provide a supply of these valuable industrial gases.
  • the hydrogen and oxygen product mixture of the photon dissociated water may be separated by at least one method known in the art such as one or more from the group of separation of 3 ⁇ 4 by a micro-porous membrane, separation of (3 ⁇ 4 by an electro-diffusion membrane such as a refractory oxide such as CaO, CeCb, Y2O3, and ZrC , separation of 3 ⁇ 4 by a nonporous metallic membrane such as a palladium or Pd-Ag membrane, gas separation by creating a high-speed jet using an orifice and a beam skimmer, gas separation by cenrrifugation, and gas separation by cryo-distiilatioa.
  • the gases may be converted into electricity by supplying the hydrogen and oxygen to a fuel ceil such as at least one of a proton-exchange-membrane fuel cell, a molten carbonate fuel cell and other fuel cells known in the art.
  • a fuel ceil such as at least one of a proton-exchange-membrane fuel cell, a molten carbonate fuel cell and other fuel cells known in the art.
  • the hydrogen and the oxygen or atmospheric oxygen may be combusted in a heat engine such as at least one of an internal combustion engine, a Brayton cycle engine, a gas turbine, and other heat engines known in the art.
  • the injector 5zl may comprise a manifold having a plurality of pinholes to deliver at least one of Hi and H 2 0 wherein the H 2 0 may comprise ice crystals.
  • the injector further comprises a pump 5z2.
  • the water reservoir 5v may be cooled to at least the freezing point of water.
  • the reservoir may be operated under a pressure less than atmospheric by pump 5z2.
  • the low pressure may cause ice to sublime in a super cooled state wherein the vapor has a temperature below the freezing point of water at atmospheric pressure.
  • the surface area of ice may be increased to increase the sublimation rate.
  • the pump 5z2 may compress the super cooled water vapor to cause it to freeze.
  • the pump may change the pressure to cause a phase change form liquid to solid.
  • the pump may comprise a peristaltic pump.
  • Bubble chambers use a pressure change to cause a phase change as well as given in https://en.wikipedia.org wiki Bubbie chamber. This principle may be applied to cause the formation of fine ice crystal for injection into the ignition plasma, the plasma formed by igniting the hydrino reactants.
  • the pump parts that contact the super cooled water vapor and the formed ice crystals may be cooled with a chiller such as 3 la.
  • the ice crystals may be pumped into the injector 5zl such as the manifold having a plurality of pinholes by the pump 522, and the crysia!s may be injected into the fuel ignition site.
  • the hydrogen injector 5zl may comprise a hydrogen permeable membrane such as a nickel, graphite or pailadium-siiver alloy membrane wherein the hydrogen permeates the membrane and is delivered to the melt that is maintained under low pressure.
  • the hydrogen permeable membrane may decrease the hydrogen flow rate to a desirable one wherein the hydrogen is injected into a low-pressure region such as in the cell at the electrodes.
  • the flow rate may be one that does not contributed to a corresponding significant consumption of power.
  • the flow rate may be manageable for the vacuum pump 13a to maintain the cell pressure.
  • the hydrogen flow rate may be in at least one range of about 0.1 standard cubic centimeters per minute (seem) to 10 standard liters per minute (slm), 1 seem to 1 slm, and 10 seem to 100 seem per a ceil that produces about 100 kW of light.
  • Electrolysis of 3 ⁇ 4D may comprise the source of hydrogen 5u.
  • the membrane such as a palladium or Pd-Ag membrane, may perform at least one function of separating hydrogen from oxygen of an aqueous electrolysis gas mixture, injecting H 2 into the hydrino plasma such as at the electrodes in a controlled manner, and dissociating molecular hydrogen into atomic hydrogen.
  • the permeation rate and selectively for hydrogen permeation may be controlled by controlling the membrane temperature such as in the range of about 100 "C to 500 °C.
  • the hydrino plasma may provide the membrane heating, in other embodiments, hydrogen and oxygen of an electrolysis product mixture may be separated by at least one method known in the art such as one or more form the group of separation of 3 ⁇ 4 by a microporous membrane, separation of 0 2 by an electro-diffusion membrane such as a refractory oxide such as CaO, Ce0 2 , Y2O3, and Zr0 2 , separation of Hi by a nonporous metallic membrane such as a palladium or Pd-Ag membrane, gas separation by creating a high-speed jet using an orifice and a beam skimmer, gas separation by centrifugation, and gas separation by cryo-distillation.
  • the injector supplies a jet of ice crystals into the molten metal wherein the ice crystals may be impregnated into the melt due to their high velocity
  • the jet comprises a carrier gas such as hydrogen or a noble gas such as argon for iransporting water vapor
  • substitution of ice crystal for water vapor may significantly increase the amount and concentration of water delivered to the ignition per carrier gas volume.
  • the ice crystals may also be formed mechanically by means known in the art such as by an ice shaver or chipper.
  • the mechanical ice crystal machine may comprise at least one rotating blade that breaks solid ice into small ice particles of a desired size.
  • the ice may be supplied to the electrodes by at least one machine tool such as a high-speed grinder such as a Dremel tool or a high-speed drill or grinder such as a dentist drill or grinder.
  • the tool or drill may be rastered over an ice surface that may be advanced as it is consumed.
  • the rastering may be produced by a raster mechanism.
  • a column of ice with the surface at the top may be advanced by a corresponding mechanism with replenishment from a freezing front at the base.
  • a chiller such as 3 l a may be used to achieve the freezing.
  • the mechanical frequency may be in the range of about 1000 RPM to 50,000 RPM.
  • the ice may be supplied chilling water in a reservoir such as 5u by a chiller such as 33a.
  • low temperature may limit the H 2 G vapor pressure to favor HOH formation.
  • the Type ⁇ ice structure may also enhance the hydrino reaction rate, in an embodiment, the solid fuel reaction mixture to form hydrmos comprises ice as a source of at least one of H and HOH.
  • the ice may be in a physical form to provide a high surface area such as ice crystals that may be injected by injector 5z ⁇ .
  • the ice may be formed in an ice supply 5v that may further comprise a means to form fine powdered ice or small ice crystals such as a chiller such as 3 la to freeze water and a grinder.
  • the ice supply naay comprise an ace crystal maker such as one comprising a source of chilled expanding or aerosolized i3 ⁇ 40.
  • the injector 5zl comprises an mjection nozzle.
  • the nozzle of the injector may comprise a gas mani old such as one aligned with the trough of the electrodes 8.
  • the nozzle may further comprise a plurality of pinholes from the manifold that deliver a plurality of gas jets of at least one of 3 ⁇ 40 and 3 ⁇ 4.
  • 3 ⁇ 4 is bubbled through a reservoir of HiO such as 5v at a pressure greater than that of the cell, and the 3 ⁇ 40 is entrained in the 3 ⁇ 4 carrier gas.
  • the elevated pressure gas mixture flows through the pinholes into the melt to maintain the gas jets.
  • the flow may be regulated by pressure controller or flow controller 5z2 that is supplied at an elevated pressure greater than thai of the cell such as in at least one range of about 1 mTorr to 10,000 Torr, 1 mTorr to 1000 Torr, and 1 mTorr to 100 Torr,
  • the gas that may be a mixture
  • the corresponding fuel mixture may ignite to form hydrinos.
  • the pinholes may be laser, water jet, or mechanically drilled.
  • the gases in the injector may be pressurized to facilitate the formation of a plurality of high velocity gas injection jets or molecular beams. Gas that is not consumed in formation of hydrinos may be collected by means such as the pump 13a and recycled. Water may be condensed and recycled. The condensation may be achieved using a cryopump. Hydrogen may be recycled wherein it may be separated from other gases before recycling. The separation may be achieved with a selective filter.
  • the timing of injection may be such that the creation of plasma in the shot and gases are simultaneous.
  • the injection may be about continuous.
  • the continuous gas flow rate may be adjusted to at least one of the ignition frequency and fuel flow rate.
  • the fuel injection may be intermittent and synchronized with the ignition of the shot.
  • the timing may be achieved by the mechanical resonances in the injector and the pressure wave of the nth ignition delaying and compressing the injection gases for the n + 1 th ignition, wherein n is an integer.
  • a valve such as a solenoid valve 5z2 of the injector 5z 1 may control the injection.
  • the valve 5z2 may be activated by the ignition current.
  • An exemplary valve is a mechanical feedback servo valve.
  • the valve may comprise a pressure control valve such as one at the injector outlet wherein an excess pressure may be maintained in the supply side of the valve.
  • the water may be at least one of supplied and injected as at least one of liquid or gas.
  • the gas supplies may be from sources 5u and 5 v.
  • At least one of very high power and energy may be achieved by the hydrogen undergoing transitions io hydrinos of high p values in Eq. (18) in a process herein referred io as disproporiionation as given in Mills GUT Chp. 5 which is incorporated by- reference.
  • the EUV light from the hydrino process may dissociate the dihydrino molecules and the resulting hydrino atoms may serve as catalysis to transition to lower energy states.
  • An exemplary reaction comprises the catalysis ⁇ to H(l/17) by H(l/4) wherein H(i/4) may be a reaction product of the catalysis of another H by HOH. Disproporiionation reactions of hydrinos are predicted to given rise io features in the X-ray region. As shown by Eqs, (5-8) a.
  • p + intermediate (e.g. Eq, (16) and £q. (43)) is predicted to have a short wavelength cutoff and energy Tl given by
  • the generator may produce high power and energy with a low pressure of 3 ⁇ 4G.
  • the water vapor pressure may be in at least one range of about 0.001 Torr to 100 Torr, 0.1 mTorr to 50 Torr, 1 mTorr and 5 Torr, 10 mTorr to 1 Torr, and 100 mTorr to 800 Torr.
  • the low 3 ⁇ 4G vapor pressure may be at least one of supplied and maintained by a source of water vapor and a means to control at least one of the flow rate and pressure.
  • the water supply may be sufficient to maintain a desired ignition rate.
  • the water vapor pressure may be controlled by at least one of steady state or dynamic control and equilibrium control.
  • Low-pressure water may be added to the plasma by humidifying the atmosphere in the region of the ignition such as the inter-electrode and electrode EM pump channel region 8g.
  • the generator may comprise a pump 13a that maintains a lower water vapor pressure in a desired region such as one outside of the electrode region.
  • the water may be removed by differential pumping such thai the regions of the eel! outside of the electrode region may have a lower pressure such as a lower partial pressure of water.
  • the lower pressure may be maintained to decrease the attenuation of tight such as EUV light that may be made incident to PV converter 26a,
  • the cell water vapor pressure may be maintained by a water reservoir/trap in connection with the cell.
  • the ceil water vapor pressure may be in at least one of steady state or equilibrium with the water vapor pressure above the water surface of the water reservoir/trap.
  • the water reservoir/trap may comprise a means to lower the vapor pressure such as at least one of a chiller to maintain a reduced temperature such as a cryo-temperature, a H 2 G absorbing material such as activated charcoal or a desiccant, and a solute.
  • the water vapor pressure may be a low pressure establ ished in equilibrium or steady state with ice that may be super-cooled.
  • the cooling may comprise a cryo-chiller or bath such as a carbon dioxide, liquid nitrogen, or liquid helium bath.
  • a solute may be added to the water reservoir/trap to lower the water vapor pressure.
  • the vapor pressure may be lowered according to aoult's Law.
  • the solute many be highly soluble and in high concentration.
  • Exemplary solutes are sugar and an ionic compound such as at lei one of alkali, alkaline earth, and ammonium halides, hydroxides, nitrates, sulphates, dichromates, carbonates, and acetates such as K 2 SG 4 , KNG 3 , KC1, NH4SO4, NaCi, NaN0 2 , Na 2 Cr 2 0 7 , Mg(N0 3 ) 2 , 2CO 3 , MgCij, QH3O2, LiCl, and KOH.
  • the trap desiccant may comprise a molecular sieve such as exemplary molecular sieve 13X, 4-8 mesh pellets.
  • the trap can be sealed and heated; then the liquid water can be pumped off or it can be vented as steam.
  • the trap can be re-cooled and rerun.
  • H 2 is added to the ceil 26 such in a region such as at the electrodes to react with O2 reaction product to convert it to water that is controlled with the water reservoir/trap.
  • the H 2 may be provided by electrolysis at a hydrogen permeable cathode such as a PdAg cathode.
  • the hydrogen pressure may be monitored with a sensor that provides feedback signals to a hydrogen supply controller such an electrolysis controller.
  • the water partial pressure is maintained at a desired pressure such as one in the range of about 50 mTorr to 500 mTorr by a hydrated molecular sieve such as 13X.
  • a desired pressure such as one in the range of about 50 mTorr to 500 mTorr by a hydrated molecular sieve such as 13X.
  • Any water released from the molecular sieve may be replaced with a water supply such as one from tank 5v supplied by manifold and lines 5x.
  • the area of the molecular sieves may be sufficient to supply water at a rate of at least that required to maintain the desired partial pressure.
  • the off gas rate of the molecular sieve may match the sum of the consumption rate of the hydrino process and the pump off rate. At least one of the rate of release aod the partial pressure may be controlled by controlling the temperature of the molecular sieves.
  • the cell may comprise a controller of the molecular sieves with a connection to the cell 26.
  • the container may further comprise a means to maintain the temperature of the molecular sieve such as a heater and a chiller and a temperature controller.
  • the water vapor pressure is maintained by a flow controller such as one thai controls at least one of the mass flow and the water vapor pressure in the cell.
  • the water supply rate may be adjusted to match thai consumed in the hydrino and any other cell reactions and that removed by means such as pumping.
  • the pump may comprise at least one of the water reservoir/trap, a cryopump, a vacuum pump, a mechanical vacuum pump, a scroll pump, and a turbo pump.
  • At least one of the supply and removal rates may be adjusted to achieve the desired cell water vapor pressure. Additionally, a desired partial pressure of hydrogen may be added. At least one of the 3 ⁇ 40 and 3 ⁇ 4 pressures may be sensed and controlled by sensors and controllers such as pressure gauges such as Baratron gauges and mass flow controllers. The gas may be supplied by a syringe pump. As an alternative to a mass flow controller, the water vapor pressure may be maintained by a high precision electronically controllable valve such as at least one of a needle valve, proportional electronic valve, and stepper motor valve.
  • the valve may be controlled by a water vapor pressure sensor and a computer to maintain the cell water vapor pressure at a desired value such as in the range of about 0.5 Ton to 2 Ton wherein the control may be to a small tolerance such as within 20%.
  • the valve may have a fast response to maintain the tolerance with rapid changes in water vapor pressure in the cell.
  • the dynamic range of the flow through the valve may be adjusted to accommodate different minimum and maximum ranges by changing the water vapor pressure on the supply side of the valve.
  • the supply side pressure may be increased or decreased by increasing or decreasing the temperature, respectively, of a water reservoir 5v.
  • the pump 5k comprises a submersible pump such as an electromagnetic pump that is submerged in the melt contained in the cone reservoir and pumps the melt vertically to the electrodes through a conduit such as a vessel such as a tube attached to the outlet of the pump 5k.
  • a submersible pump such as an electromagnetic pump that is submerged in the melt contained in the cone reservoir and pumps the melt vertically to the electrodes through a conduit such as a vessel such as a tube attached to the outlet of the pump 5k.
  • An exemplary pump containing single-phase electromagnetic windings is given in US Patent No. 5,277,551 , Jan. 1 1 , 1994.
  • the pump materials are capable of high temperature, in an embodiment, the submersible
  • electromagnetic pump may comprise a vertically (z-axis) oriented pump tube having its inlet submerged in the melt.
  • the pump may comprise a DC electromagnetic pump that may be oriented such that the current is along the x-axis and the magnetic field is applied along the y- axis.
  • the y-axis aligned magnetic circuit of the EM pump to apply the magnetic field of the Lorentz force may comprise minor image sets of an optional peripheral magnet cooling system such as a water cooled heat sink, a magnetic circuit comprising peripheral magnets such aeodymjum magnets, a magnetic yoke that may further comprise a thermal barrier or insulation in contact with the hot pump tube, and an optional cold plate that abuts the pump tube.
  • the thermal barrier comprises at least one of a gas gap or vacuum gap.
  • the thermal barrier may further comprise a means to reduce the thermal radiation across the gap such as at least one of a radiation reflector or shield and a reduced emissiviry of the hot parts of the pump such as the magnetic circuit parts such as the yokes, bus bars and the pump tube.
  • the ernissivity may be decreased by means such as forming a smooth surface such as a polished, electroplated, or electro-polished surface.
  • the Fe or Co yokes are electroplated with a material such as chromium that renders it to have low ernissivity.
  • a layer of copper may be first applied and then chromium.
  • An exemplary EM pump design comprises wide, highly conductive bus bars attached to the short side wall of the rectangular pump tube, and the perpendicular magnetic circuit having the layout: magnets such as neodymium or SmCo magnets (cooled)/yoke such as ferrite, iron, or cobalt (cooled) vacuum or gas gap/pump tube/vacuum or gas gap/ yoke such as ferrite, iron, or cobalt (cooled)/ neodymium or SmCo magnets (cooled).
  • the y-axis aligned pair of mirror- image current bus bars may be connected to a source of high current at the peripheral end and abutted to the side of the pump tube on the opposite end.
  • the xy-plane of the pump comprising the magnetic circuit and the current bus bars may be elevated outside of at least one of the melt and the hottest zone of the cone reservoir.
  • the pump may be placed in a protective housing at or below the melt level to maintain a gravity feed of melt to the pump, or the pump may be maintained in a primed state with metal in the pump current carryi ng section.
  • At least one of the bus bar and magnetic circuit may be at least partially located outside of the cell with penetrations through the cell walls.
  • the magnetic circuit may comprise magnets outside of the ceil that provide flux through a nonmagnetic wal l such as a stainless steel wall wherein the magnetic flux is concentrated in internal yolks of the magnetic circuit and guided across the pump tube.
  • the bus bar penetrations may each comprise a flange with a ceramic insulated conductor penetrating through the flange or other high-temperature-capable electrical feed-through known to those skilled in the art.
  • the materials of the EM pump such as the pump tube, magnets, and magnetic yolk may be capable of operating at high temperature.
  • the EM pump may comprise insulation, cold plates, heat exchangers, and other heat removal systems known in the art to cool the materials.
  • Exemplary ferromagnetic materials having a high Curie temperature suitable for the magnets and magnetic circuit are Co (1400K), Fe (1043 ), neodymium magnets (583-673K), and AlNiCo (973-1 133 ).
  • the magnets such as neodymium, AlNiCo, SmCo, and iron magnets have a high maximum operating temperature, in the case of magnets that are sensitive to demagnetization such as AlNiCo magnets, the magnets comprise a wrapper such as mu metal that will shield DC fields and a metal screen (Faraday cage) will screen RJF fields.
  • the components of the pump such as the magnetic circuits and bus bars may each be covered with a housing thai allows returning ignition products to flow over the housing and into the cone reservoir.
  • the housing may comprise or may be coated with a material that is resistant to the ignition products adhering.
  • Exemplary non-adhering materials for silver are graphite, WC, W, and At The outlet of the pump tube may connect to an injection section of the peileiizer comprising a conduit or vessel such as a rube to the nozzle 5q that injects the molten fuel such as molten silver comprising at least one of 3 ⁇ 40 and 3 ⁇ 4 into the electrodes 8.
  • a heater such as the inductively coupled heater to heat the injection section may comprise a coil such as 5o that may penetrate the wail of cell 26 and heat the injection section.
  • the cell cone reservoir can serve to store the metal that is pumped backwards by the EM pump with a reversal of the pump electrical current to evacuate the vessels and EM pump.
  • the metal may be allowed to solidify by removing heating power. Then during startup, first the heaters and then the EM pump may be activated with the pump action in the forward direction to return the SF-CIHT generator to operation.
  • water may be sprayed into the plasma using a sprayer wherein the pressure may be maintained low to avoid attenuation of short wavelength light such as UV light by the water vapor.
  • the water vapor pressure may be maintained less than 10 Torr.
  • the at least one of water such as steam and hydrogen may be simultaneously injected with the molten metal shot such as silver shot.
  • the at least one of water, steam, and hydrogen injector may comprise a delivery tube that is terminated in a fast solenoid valve.
  • the solenoid vale may be electrically connected in at least one of series and parallel to the electrodes such that current flows through the valve when current flows though the electrodes.
  • the injector system comprises an optical sensor and a controller to cause the injections.
  • the controller may open and close a fast valve such as a solenoid valve when the shot is sensed.
  • lines for the injection of at least two of the melt such as silver melt, water such as steam, and hydrogen may be coincident. The coincidence may be through a common line.
  • the injector comprises an injection nozzle.
  • the nozzle of the injector may comprise a gas manifold such as one aligned with the trough of the electrodes 8.
  • the nozzle may further comprise a plurality of pinholes from the manifold thai deliver a plurality of gas jets of at least one of 3 ⁇ 40 and 3 ⁇ 4.
  • 3 ⁇ 4 in bubbled through a reservoir of H 2 0 at a pressure greater than that of the cell, and the 3 ⁇ 40 is entrained in ihe H 2 carrier gas.
  • the elevated pressure gas mixture flows through the pinholes into the melt to maintain the gas jets.
  • the gas that may be a mixture, may be combined with the conductive matrix, the metal melt. With the application of a high current, the corresponding fuel mixture may ignite to form hydrinos.
  • FIGURE 21 i 7 The cross section of the pelletizer having a pipe bubbler in the second vessel to introduce the gasses such as 3 ⁇ 4 and steam to the melt, two electromagnetic pumps, and a nozzle to injection shot on the top of the electrodes is shown in FIGURE 21 i 7, details of the electrodes is shown in FIGURE 2118.
  • the pelletizer 5a inlet at the first vessel 5b may be solely located at the bottom of the cell 26.
  • the cell may be shaped in cone or funnel thai causes the ignition product to flow into the inlet of the pelletizer.
  • first vessel 5b, second vessel 5c, and nozzle 5q may form at least a portion of a loop with the first vessel 5b at the bottom of the cell 26 to receive ignition products and the second vessel 5c and nozzle 5q in a separate location to deliver shot to the electrodes 8.
  • the second vessel 5c may penetrate the side of the cell 26.
  • the second vessel 5c and nozzle 5q may elevate the ejection point of the fuel above the electrodes 8.
  • the nozzle may deliver the fuel to the second electrode section 8j (FiGURES 2132 and 2118) such that the ignition expansion and light emission occurs in the second cell region 81.
  • the ejection may be facilitated by at least one of gravity and pressure from the pump.
  • the first electrode section may comprise the electrode gap only or may be closed by an insulator such that the plasma only expands in the direction of the photovoltaic converter 26a.
  • the electrodes may comprise a bilayer set of electrodes comprising a top conductive layer upon which ignition occurs and a bottom plate of an insulator to form a floor in the gap 8g.
  • the conducting top layer may comprise at least one of copper, Mo, Ta, TaW, tungsten, tungsten carbide (WC), or graphite coated conductor such as graphite coated Cu or W, and the bottom non-conducting bottom layer may comprise a ceramic such as alumina, zirconia, MgO, and firebrick.
  • the top conduction layer may comprise or may be covered with a material to which silver does not stick such as aluminum that may be cooled, molybdenum, tungsten, Ta, TaW, tungsten carbide (WC), and graphite coated conductor such as graphite coated Cu or W electrodes 8.
  • a material to which silver does not stick such as aluminum that may be cooled, molybdenum, tungsten, Ta, TaW, tungsten carbide (WC), and graphite coated conductor such as graphite coated Cu or W electrodes 8.
  • Materials that are wetted by silver such as copper, silver, and CuAg alloy may each be covered with a material to which the shot such as silver shot does not adhere.
  • the electrode may comprise a plurality of layers such as a covering layer, an ignition layer, and a bottom non-conducting plate.
  • the non-adhering cover layer may comprise at least one of an insulator, a conductor of low conductivity relative to the portion of the electrode that causes the fuel ignition, and a conductor. In the case that the non-adhering layer is conductive, it may be electrically isolated from the ignition portion of the electrode.
  • the electrode may comprise a top shot non-adhering layer, a thin insulating spacer layer, and a highly conductive ignition portion layer that is exclusively connected to the source of electricity 2.
  • An exemplary top layer of low conductivity relative to the ignition portion of the electrode such as a silver or copper portion comprises graphite.
  • graphite or zirconia serves as a layer to which the shot such as silver shot does not adhere.
  • the non-adhering layer may be electrically isolated from the ignition portion such as a copper portion by an insulating layer such as a ceramic layer.
  • the non-adhering layer may comprise a funnel to guide shot in to the gap 8g of the ignition portion of the electrodes.
  • the electrode may comprise a biiayer electrode such as one comprising an upward V-shaped top layer such as graphite or zirconia top layer.
  • the top layer may guide the shot to a bottom ignition layer.
  • the bottom layer comprising a conductor may have vertical walls or near vertical walls towards the gap 8g.
  • Exemplary materials of the bottom or ignition layer are W, WC, and Mo.
  • the open circuit is closed by injection of the melt shot causing contact across the conductive parts of the gap 8g only in the bottom layer.
  • the shot may be delivered along the y-axis.
  • the nozzle 5q may deliver the shot horizontally along the y-axis to the top of the electrodes (FIGURES 21] 7 and 2118).
  • the light may constrained to predominantly propagate upward due to an electrode design that permits the plasma from the ignited top-loaded shot to expand predominantly in the positive z-direction along the z-axis towards the PV converter 26a.
  • the electrode may comprise a guiayer electrode such as one comprising a top layer comprising a upward V -shape, a middle current delivery layer such as a flat plate with the plate edge slightly extended into the gap 8g, and an downward V-shaped electrode layer that is recessed away from the gap Sg.
  • the top layer may comprise a material that resists adhesion of the shot melt such as silver shot melt .
  • Suitable exemplary materials are at least one of a nonconductor or poor conductor such as anodized aluminum, graphite, and zirconia or a conductor such as aluminum, molybdenum, tungsten, Ta, TaW, tungsten carbide (WC), and graphite coated conductor such as graphite coated Cu or W.
  • Low melting point electrodes such as aluminum electrodes may be cooled to prevent melting.
  • the top layer may be electrically insulated for the middle layer.
  • the middle current delivery layer may comprise a conductor with a high melting point and high hardness such as flat W, WC, or Mo plate.
  • the source of electricity 2 is may be connected to at least one of the middle layer and the bottom layer thai may serve as a lead layer.
  • the bottom electrode lead layer may comprise a high conductor that may also be highly thermal conductive to aid in heat transfer. Suitable exemplary materials are copper, silver, copper-silver alloy, and aluminum.
  • the bottom lead electrode layer also comprises a material that resists adhesion of the shot melt such as silver.
  • Suitable exemplary non-adhering lead electrodes are WC and W.
  • the lead electrode such as a copper electrode may be coated or clad with a surface mat is resistant for die adherence of the shot melt.
  • Suitable coatings or claddings are WC, W, carbon or graphite, boron carbide, fluorocarbon polymer such as Teflon (PTFE), zirconia + 8% yitria, Muiiiie, Muliite-YSZ, and zirconia.
  • the coating or claddi ng may be applied over the surface regions that are exposed to the shot melt during ignition.
  • the open circuit may be closed by injection of the melt shot causing contact across the conductive parts of the gap 8g only in the middle layer.
  • the bottom layer may be cooled by a coolant flow system such one comprising electrode internal conduits.
  • a coolant flow system such one comprising electrode internal conduits.
  • the contact between the middle and bottom cooled layer may heat sink and cool the middle layer.
  • the contact between the top and middle cooled layer may heat sink and cool the top layer, in a tested embodiment, the shot injection rate was 1000 Hz, the voltage drop across the electrodes was less than 0.5 V, and the ignition current was in the range of about 100 A to 10 kA,
  • Magnets such as 8c of FIGURES 2117 and 2118 may cause plasma particles such as those from the shot ignition to be directed away from the region 8k (FIGURE 211.2).
  • the magnets and channel 8g comprises an electromagnetic pump that performs at least one function of (i) injecting shot in region 8j into the gap 8g to be ignited, (ii) pumping shot that has adhered to the upper part of the electrodes such as at region 8j into the gap 8g to be ignited, (Hi) ejecting un-ignhed shot and particles from the region 8i and the gap 8g and (iv) recovering the ignition product and un-ignited shot to the pelietizer.
  • the ejection and recovery may be by the Lorentz force formed by a crossed applied magnetic field such as that from magnets 8c and ignition current through at least one of the plasma particles and shot such as silver shot adhering to the electrode surfaces such as 8i, 8g, and 8j.
  • the ignition current may be from the source of electrical power 2 (FIGURE 2110).
  • the electrodes may comprise an upward (positive z-axis oriented) V-shape with a gap at the 8g at the bottom of the V (FIGURES 2117 and 2118).
  • the open circuit may be closed by injection of the melt shot 5t from nozzle 5q causing contact across the conductive parts of the gap 8g at the bottom of the V.
  • the V may be formed by flat plate electrodes mounted on opposite faces of supports that form a V with a gap at the bottom.
  • Exemplary electrode materials comprising a conductor that operates a high temperature and resists adhesion of Ag are W, WC, and Mo.
  • the supports may be water-cooled.
  • the supports may be a least partially hollow.
  • the hollow portions may each comprise a conduit for coolant that flows through the conduits and cools the electrodes.
  • the electrodes may further comprise a lower section having vertical wails or near vertical wails at the gap 8g.
  • the wails may form a channel.
  • the electrodes further comprise a source of magnetic field such as a set of magnets at opposite ends of the channel of the electrodes.
  • the magnets may produce a magnetic field parallel to the electrodes or channel axis and perpendicular to the ignition current.
  • the channel with crossed current and magnetic field may comprise an
  • the EM pump may pump adhering shot into the electrodes to be ignited.
  • the Lorentz force due to the crossed magnetic field and ignition current may at least one of pump the shot adhering to the walls of the upper portion of the electrode downward to be ignited and pump ignition particles downward away from the PV converter to be recovered in the inlet to the pelletizer.
  • the shot 5t may be injected horizontally long the y-axis, on top of the V-shaped electrodes 8 (FIGURES 2117 and 2118).
  • magnets 8c are positioned to apply a magnetic field along the y-axis, along the trough of the V-shaped electrodes 8, The circuit is closed and x -axis-directed ignition current flows by shot providing a current path across the gap 8g wherein the magnetic field is transverse to the current.
  • the crossed current and magnetic field create a Lorentz force according to Eq. (37) to push out any metal shot adhering to the electrodes.
  • the Lorentz force may further push the ignition particles downward to region 8k (FIGURE 2 ⁇ 12) to recover un-ignited shot and to recover ignition particles.
  • the Lorentz force causes the flow of the adhering shot into the ignition section of the electrodes at the gap 8g and causes the ignition plasma to be directed and flow into a collection region such as ialef of the fuel regeneration system such as the pelietizer.
  • the electrodes and magnets may be designed to direct the plasma in an upward arch to perform at least one function of (i) injecting shot in region 8t into the gap 8g to be ignited, (ii) ejecting shot that has adhered to the upper part of the electrodes such as at region 8j, (ni) eject ing un-ignited shot and particles from the regions 8i, 8j, and the gap 8g and (iv) recovering the ignition product and un-ignited shot to the pelietizer, while avoiding guiding ignition particles to the PV converter 26a.
  • the shot is delivered along the y-axis (FIGURES 2 ⁇ 7 and 2 ⁇ 8).
  • the nozzle 5q may deliver the shot horizontally along the y-axis to the top of the electrodes.
  • the solid fuel may be delivered as a stream of shots, a continuous stream, or a combination of shot and a stream.
  • the light may constrained to predominantly propagate upward due to an electrode design that permits the plasma from the ignited top-loaded shot to expand predominantly in the positive z-direction along the z-axis lowards the PV converter 26a.
  • the electrodes may further comprise at least one magnet such as a set of magnets 8c separated at opposite ends of the electrodes to produce a magnetic field in a direction perpendicular to the ignition current.
  • the Lorentz force due to the crossed current and magnetic field may cause the ejection of adhering shot and the flow of the plasma particles to the regeneration system such as the pelietizer.
  • the Lorent2 force may be in the negative z-direction.
  • a region, section, or layer such as the ignition layer of the electrodes 8 may comprise a channel that may act as an electromagnetic pump for the ejection of ignition particles and shot that is not ejected as particles and plasma.
  • the size of the channel may be selected to provide flow restriction to the high pressure expanding ignition plasma that forces the plasma and light to expand towards the region 81 of the electrodes (FIGURE 2112).
  • the ignition portion of the electrodes may form a shallow channel comprising a short electromagnetic pump tube such that the particles and adhering shot fills the pump tube and restricts the path for the emitted light to be only along the positive z-axis.
  • the strength of the crossed current and magnetic field and well as the dimensions of the channel provide the pump pressure through the channel comprising the electromagnetic pump tube.
  • the width of the pump tube and any splay are selected to distribute the current from the source of electrical power 2 for ignition and pumping to achieve optimization of both.
  • the source of electrical power may deliver the ignition current without substantial time delay.
  • the injection may be timed to avoid the n + 1 th injection from being disrupted by the pressure wave from the ignition blast of the nth injection wherein n is an integer.
  • the timing may be achieved with blast and injection sensors such as at least one of optical, current, voltage, and pressure sensors and a controller.
  • the controller may control at least one of the electromagnetic pump pressure, the nozzle valve, and the ignition current.
  • the SF-CIHT generator may comprise a plurality of electrodes wherein each set may utilize at least one of (i) a common or separate, dedicated injection system, (ii) a common or separate, dedicated source of electrical power to cause ignition, and (iii) a common or separate, dedicated PV conversion system.
  • the ignition system may further comprise a cooling system of the ignition system as shown in FIGURE 2122.
  • the cooling system may comprise conduits through the bus bars 9 and 10 (FIGURE 2114) and electrodes 8 or inlet 3 i f and outlet coolant lines 31 g and a coolant pump and chiller 3 la to cool the coolant that is pumped through the conduits or lines.
  • the electrode coolant system may comprise one pair of coolant lines 3 If and 31g that serve both electrodes (FIGURE 2123), or each electrode may have an independent inlet line 31 f an outlet line 3 Ig (FIGURE 2122).
  • the area of contact of the line with the electrode may be adjusted depending on the average local coolant temperature to achieve efficient heat transfer from the electrode to the coolant.
  • the electrodes and bus bars of the ignition system may be cooled by a passive cooling system 31 h comprising a heat exchanger such as one comprising air fins and optionally heat pipes to the air fins.
  • the photovoltaic conversion system may also be cooled by a passive cooling system 3 i i comprising a heat exchanger such as one comprising air fins and optionally heat pipes to the air fins.
  • a passive cooling system 3 i i comprising a heat exchanger such as one comprising air fins and optionally heat pipes to the air fins.
  • the photovoltaic (PV) cells or panels 15 of the photovoltaic converter 26a are cooled with heat exchanger 87 wherein the hot coolant flows into the photovoltaic converter cooling system 3 1 through inlet 31b and chilled coolant exits through outlet 31 c.
  • the PV cells may be operated at elevated temperature such as 30 e C to 450 °C and may be operated under reduced ceil pressure to prevent water vapor from condensing on the PV cells.
  • the chiller such as at least one of 31 and 1 a may be driven by thermal power thai may comprise heat produced by the cell.
  • the heat power may be from internal dissipation and from the hydrino reaction.
  • the chiller may comprise an absorption chiller known by those skilled in the art.
  • heat to be rejected is absorbed by a coolant or refrigerant such as water that may vaporize.
  • the adsorption chiller may use heat to condense the refrigerant.
  • the water vapor is absorbed in an absorbing material (sorbent) such as Silicagel, Zeolith, or a nanostructure material such as that of P. McGrail of Pacific Northwest
  • the absorbed water is heated to cause its release in a chamber wherein the pressure increases sufficiently to cause the water to condense.
  • At least one of the velocity of the fuel, the shot size, the melt shot viscosity, the width of the gap 8g between the electrodes, and the shape of the electrodes 8 is selected to cause the ignition to occur predominantly in a region on the opposite side of the electrodes 81 relative to the injection side or region 8k.
  • the second section of the electrodes 8j serves as the inlet to the second region of the ceil 81 wherein the plasma and light are preferentially directed toward the PV converter 26a (FIGURE 212).
  • the velocity of the fuel such as the molten fuel may be in at least o «e range of about 0.01 m/s to 1000 m/s, 0.1 m/s to 100 m/s, and 0.1 m/s to 10 rn/s.
  • At least one of pressure at the nozzle 5q and the viscosity of the fuel may be used to control the fuel velocity.
  • the size of the nozzle orifice, the melt pressure, the melt flow rate, the melt viscosity, and the melt temperature may be used to control the melt shot size.
  • the heat balance may be controlled to control the temperature of the melt that in turn controls the melt viscosity.
  • electromagnetic pump 5k and nozzle orifice size may be controlled to control the pressure at the nozzle 5q. At least one of the heating power, insulation, cooling, and melt flow rate may be use to control the heat balance.
  • the electromagnetic pump power may be used to control the melt flow rate.
  • the melt temperature may be used to control the melt surface tension.
  • the electrode gap 5g may be selected manually. Alternatively, an adjustable or deformable electrode gap may be adjusted be means such as mechanically, hydrauIicaSiy, or
  • the electrode shape may be selected manually.
  • an adjustable or deformable electrode may be adjusted be mean such as mechanically, hydrauiically, or piezoelectrically.
  • a control system such as a computer, electromagnetic pump, nozzle valve, and heater control parameters such as the pressure, nozzle size, and melt temperature and viscosity to control the ejection velocity as well as the ejection rate.
  • the ejection velocity may be controlled to compensate for the deceleration of gravity to maintain a desire injection rate.
  • the height of the nozzle 5q may be adjusted to support a maximum injection rate.
  • the SF-CIHT generator comprises a user interface such as a touch-screen display of a computer to control the generator further comprising a computer with sensors and control systems of the injection system, the ignition system, the fuel recovery system, the fuel regeneration system such as the pelletizer, and the converter system such as at least one of the photovoltaic and photoelectron converter system.
  • the a computer with sensors and control systems may sense and control the electromagnetic pump, inductively coupled heaters, injector flow, nozzle, ignition system current and pulse rate, product recovery system such as applied magnets and currents and electrostatic precipitator (ESP), photovoltaic (PV) converter system, cooling systems, power conditioning and other system monitoring and controls to operate the generator known by those skilled in the art.
  • the sensors may provide input to controller protect systems such as ones for melt flow and volume in the heated vessel sections and melt flow and volume input to the EM pump wherein the controllers shut off the heaters and EM pump when the flow or volume is below a tolerable limit.
  • the control system may further comprise programmable logic controllers and other such devices known by those skilled in the art in order to achieve control.
  • the SF-CLHT generator comprises the components having the parameters such as those of the disclosure thai are sensed and controlled, in embodiments the computer with sensors and control systems may sense and control, (i) the inlet and outlet temperatures and coolant pressure and flow rate of each chiller of each cooled system such as at least one of the PV converter, the electrodes, the inductively coupled heater, and the nozzle chiller, (ii) the ignition system voltage, current, power, frequency, and duty cycle, (iii) the shot trajectory using a sensor such as an optical sensor and controller, and the EM pump injection flow rate using a sensor such as an optical, Doppler, or electrode resistance sensor and controller, (iv) the voltages, currents, and powers of the inductively coupled heater, the augmented plasma railgun, the electromagnetic pump 5k, the electrode electromagnetic pump, and electrostatic precipitator recovery systems, (v) the pressure in the cell, (vi) the wall temperature of the cell, (vii) the consumption state of any getter, (viii) the heater power in each section, (ix
  • a parameter to be measured may be separated from a region of the system that has an elevated temperature thai would damage the sensor during its measurement.
  • the pressure of a gas such as at least one of H 2 and H 2 0 may be measured by using a connecting gas line such as a cooling tower thai connects to the cell such as 5b or 5c and cools the gas before entering a pressure transducer such as a Baratron capacitance manometer.
  • the cell may comprise few to no or moving parts, in an embodiment, the cooling may comprise heat rejection to an air-cooled heat exchanger. Exemplary, air-cooled systems for the electrodes 3 Ih and PV conversion system 3 l i are shown in FIGURE 2123.
  • the cell may comprise no or very Few moving parts.
  • the only moving part may comprise a mechanical pump to circulate coolant, and it may be replaced with one with no moving parts.
  • the coolant is a liquid metal such as an alkali metal such as sodium
  • the pump may comprise an electromagnetic pump that may have no moving parts.
  • the electromagnetic pump coolant may be nonflammable.
  • heat pipes and air fins or Peltier chillers may be used to remove the heat as a means of non- mechanical heat rejection.
  • Exemplary heat pipes are a copper heat pipe with soldered longitudinal copper fins using water or acetone as the working fluid and an aluminum heat pipe with soldered longitudinal aluminum fins using ammonia as the working fluid.
  • the source of heat may be the ignition electrodes wherein the heat may be rapidly conducted away from the electrode surface to the cooling system by large cross section thermal bus bars 9 and 10 comprising highly thermal conductive material such as copper, silver, or a silver- copper alloy.
  • the source of heat may also comprise the PV converter.
  • the mechanical vacuum pump may also be replaced to eliminate it as a system with moving parts.
  • the vacuum in the cell may be maintained by at least one getter 13b (FIGURE 2123) such as at least one for oxygen, hydrogen, and water.
  • An oxygen getter such an oxygen reactive material such as carbon or a metal that may be finely divided may scavenge any oxygen formed in the ceil.
  • the product carbon dioxide may be tapped with a C0 2 scrubber that may be reversible.
  • Carbon dioxide scrubbers are known in the art such as organic compounds such as amines such as monoethaoolamine, minerals and zeolites, sodium hydroxide, lithium hydroxide, and melai- oxide based systems.
  • the finely divided carbon getter may also serve the purpose of scavenging oxygen to protect oxygen sensitive materials in the cell such as vessels or pump tube comprising oxygen sensitive materials such as Mo, W, graphite, and Ta.
  • the carbon dioxide may be removed with a CO 2 scrubber or may be pumped off with the vacuum pump where fine-divided carbon is used solely for component protection.
  • the metal getter may selectively react with oxygen over H 2 0 such that it can be regenerated with hydrogen.
  • Exemplary metals having low water reactivity comprise those of the group of Cu, Ni, Pb, Sb, Bi. Co, Cd, Ge, Au, Ir, Fe, Hg. Mo, Os, Pd, Re, Rh, Ru, Se, Ag, Tc, Te, Tl, Sn, W, and Zn.
  • the getter or oxygen scrubber may be removed from the SF- CIHT cell and regenerated. The removal may be periodic or intermittent.
  • the regeneration may be achieved by hydrogen reduction.
  • the regeneration may occur- in situ.
  • the in situ regeneration may be intermittent or continuous.
  • Other oxygen getters and their regeneration such as zeolites and compounds that form reversible ligand bonds comprising oxygen such as salts of such as nitrate salts of the 2-amiaoterephthalato-linked deoxy system,
  • the highly combustible metals may also be used as a water scavenger.
  • Hydrogen storage materials may be used to scavenge hydrogen.
  • Exemplary hydrogen storage materials comprise a metal hydride, a mischmetal such as M l : La-rich mischmetal such as M lNi3.6sAlo.3Mno j or M l (NiCoMnCu) 5 , i, R-NL R-Ni + about 8 wt% Vulcan XC-72, LaNis, Cu, or Ni-Al, Ni-Cr such as about 10% Cr, Ce-Ni-Cr such as about 3/90/7 wt%, Cu- Al, or Cu-Ni-Al alloy, a species of a M-N-H system such as L H2, Li 2 NH, or LijN, aod a alkali metal hydride further comprising boron such as borohydrides or aluminum such as aluminoby
  • metal hydrides such as alkaline earth metal hydrides such as MgH 2 , metal alloy hydrides such as BaReH 9 , LaNijHg, FeTiHj.7, and MgNiHLj, metal borohydrides such as BeiBH ⁇ , Mg(BH4) 2 , Ca(B3 ⁇ 4) 2 , Zn(B3 ⁇ 4)2, Sc(BH )3, Ti(BE j, ⁇ ( ⁇ 3 ⁇ 4)2, ZtfBKfo, NaBB , L3BH4, KBH4, and AKB h, ASH3, NaAIRt, Na3AlH , LiALH , Li3Au3 ⁇ 4 LiH, LaNis3 ⁇ 4, La 2 CosN 93 ⁇ 4 t and TiFeHo,
  • metal hydrides such as alkaline earth metal hydrides such as MgH 2 , metal alloy hydrides such as BaReH 9 , LaNijHg, FeTiHj.7, and MgNiHLj
  • amine borane complexes such as amine borane, boron hydride ammooiates, hydrazuie-borane complexes, diboraae diammoniate, borazine, and ammonium octahydrotriborates or tetrahydroborates
  • imidazolium ionic liquids such as al
  • Further exemplary compounds are ammonia borane, alkali ammonia borane such as lithium ammonia borane, and borane alkyl amine complex such as borane dimethylamine complex, borane trimethylamine complex, and amino boranes and borane amines such as am nodiborane, n-dimethylaminodiborane, tris(dimethy]amino)borane, di-n- butylboronarmne, dimethylaminoborane, trirnethylarninoborane, ammonia-trimethylborane, and triethylaminoborane.
  • alkali ammonia borane such as lithium ammonia borane
  • borane alkyl amine complex such as borane dimethylamine complex, borane trimethylamine complex
  • amino boranes and borane amines such as am nodiborane, n-dimethylaminodibor
  • suitable hydrogen storage materials are organic liquids with absorbed hydrogen such as carbazole and derivatives such as 9-(2-ethylhexyl)carbazole, 9-eihylcarbazole, 9-phenylcarbazole, 9-methyicarbazole, and 4,4'-bis(N-carbazolyl)- i, l '- biphenyl.
  • the getter may comprise an alloy capable of storing hydrogen, such as one of the AB 5 (LaCePrNdNiCoMnAl) or A3 ⁇ 4 (VTiZrNiCrCoMnAlSn) type, where the "AB " designation refers to the ratio of the A type elements (LaCePrNd or TiZr) to that of the B type elements (VNiCrCoMnAlSn).
  • Additional suitable hydrogen getters are those used in metal hydride batteries such as nickel-metal hydride batteries that are known to those skilled in the Art.
  • Exemplary suitable getter material of hydride anodes comprise the hydrides of the group of R-Ni, L NisHs, LasCojNigHd, ZrCr 2 H- s .8, LaNi3.5sMno.4Alo.3Coo.75,
  • Suitable hydride getters are ZrFe 2 , Zro.5Cso.5Fe2, Zro.sSco.2Fe2, YNis, LaNis, LaNi 4 5C00 5, (Ce, La, Nd, Pr)N.i5, Mischmetal-nickel alloy, io.ggZro.oa o ⁇ Feo.ogCro.osMni.s, La 2 C0 [Ni9, FeNi, and TiMn 2 .
  • Getters of the disclosure and others known to those skilled in the art may comprise a getter of more than one species of ceil gas. Additional getters may be those known by ones skilled in the art.
  • An exemplary multi-gas getter comprises an alkali or alkaline earth metal such as lithium that may getter at least two of 0 2 , H 2 0, and H 2 .
  • the getter may be regenerated by methods known in the art such as by reduction, decomposition, and electrolysis.
  • the getter may comprise a cryotrap that at least one of condenses the gas such as at least one of water vapor, oxygen, and hydrogen and traps the gas in an absorbing material in a cooled state. The gas may be released form the absorbing material at a higher temperature such that with heating and pumping the off-gas, the getter may be regenerated.
  • Exemplary materials thai absorb ai least one of water vapor, oxygen, and hydrogen that can be regenerated by heating and pumping is carbon such as activated charcoal and zeolites.
  • the timing of the oxygen, hydrogen, and water scrubber regeneration may be determined when the corresponding gas level increases to a non-tolerable level as sensed by a sensor of the corresponding cell gas content.
  • at least one of the cell generated hydrogen and oxygen may be collected and sold as a commercial gas by systems and methods known by those skilled in the art. Alternatively, the collected hydrogen gas may be used in the SunCell.
  • the hydrogen and water that is incorporated into the melt may flow from the tanks 5u and 5v through manifolds and feed lines 5w and 5x under pressure produced by
  • the SF-CiHT generator may comprise a valve and reservoir and optionally a reservoir pump such as one of the disclosure such as a mechanical pump.
  • the fuel meta! such as silver may be pumped by at least the electromagnetic pump 5k into the reservoir for storage. The transfer of the metal may be for shutdown.
  • the reservoir may comprise a heater such as an inductively coupled heater to melt the fuel metal such as silver to restart the generator.
  • the metal may flow back into at least one of the first vessel 5b, the second vessel 5c, and the electromagnetic pump 5k by at least one of gravity and pumping.
  • the pumping may be by the reservoir pump.
  • the power for at least one of the heating and flow such as by pumping may be supplied by the energy storage of the disclosure such as by a battery or capacitor.
  • the electromagnetic pump 5k may comprise an electromagnetic pump heater such as a resistive or an inductively coupled heater.
  • the resistive heater may at least partially comprise the current source of the pump that generates the Lorentz force, in an embodiment, the electromagnetic pump and the heaters are stopped for shutdown. Startup is achieved by melting the fuel metal such as silver using the inductively coupled heaters such as those of 5f and 5o as well as the electromagnetic pump heater.
  • the power may be from the energy storage of the disclosure.
  • the generator is not shutdown, hut remains operating at a minimum power level to maintain the flow of the fuel metal.
  • the SF-CIHT comprises a switch on at least one of the
  • electromagnetic pumps such as 5k that reverses the polarity of the pump current to reverse the Lorentz force and the pumping direction.
  • electromagnetic pumps such as 5k that reverses the polarity of the pump current to reverse the Lorentz force and the pumping direction.
  • the direction of the magnetic field may be reversed to reverse the pumping direction.
  • the direction of pumping of the melt may be reversed to transport the metal to storage.
  • the storage may comprise at least one of a portion of the cell at its base such as the base cone at the iniei to the first vessel 5b, the first vessel 5b, and the inlet of the first EM pump 5k.
  • the melt may solidify in storage by removal of heating power, Startup may be achieved by applying heat to the First vessel 5b with the first inductively coupled heater 5f and applying heat to the EM pump 5k by the EM pump heater wherein the pump current flowing thougli the metal in the pump tube may serve as the pump heater.
  • the resulting melt may be pumped into the other sections of the pelletizer such as the second vessel 5c and nozzle 5q with heating by the other heaters such as the inductively coupled heater 5o thai heats the second vessel 5c.
  • the power for at least one of the heating and flow such as by pumping may be supplied by the energy storage of the disclosure such as by a battery or capacitor.
  • the SF-CIHT cell components and system are at least one of combined, miniaturized, and otherwise optimized to at least one of reduce weight and size, reduce cost, and reduce maintenance.
  • the SF-CIHT cell comprises a common compressor for the chiller and the cell vacuum pump.
  • the chiller for heat rejection may also serve as a cr opump to maintain the vacuum in the ceil. 3 ⁇ 40 and 0 2 may be condensed by the ciyopump to maintain the desired level of vacuum.
  • the ignition system comprising a bank of capacitors is miniaturized by using a reduced number of capacitors such as an exempiary single 2.75 V, 3400 F Maxwell super-capaciior as near to the electrodes as possible.
  • At least one capacitor may have its positive terminal directly connected to the positive bus bar or positive electrode and at least one capacitor may have its negative terminal directly connected to the negative bus bar or negative electrode wherein the other terminals of the capacitors of opposite polarity may be connected by a bus bar such that current flows through the circuit comprising the capacitors when shot closes the circuit by bridging the electrodes, in an embodiment, threaded capacitor terminals may be screwed directly into threaded electrodes, electrode mounts, or bus bars.
  • the set of capacitors connected across the electrodes in series may be replicated by an integer multiple to provide about the integer multiple times more current, if desirable.
  • the voltage on the capacitors may be maintained within a desired range by charging with power from the PV converter.
  • the voltage to control the charging current may be sensed at the capacitors. This remotely sensed voltage may be used by a controller such as a computer to control the charging current.
  • the capacitors and connecting bus bar or bars may be located such the nozzle 5q may have a clear path for shot injection and the ignition plasma is not unduly impeded to emit light to the PV converter.
  • the proximity of the source of electrical power 2 eliminates the extra voltage required to drive the high peak ignition current through extensive bus bars.
  • the reduced capacitance ignition system may be mounted at the electrodes and charged continuously with a steady current that may be significantly less thai the pulsed high ignition current such as that given by the peak pulse current times the duty cycle.
  • the circuit that carries the high current to the electrodes may comprise circuit elements having desired characteristics such as inductance, capacitance, and resistance to permit impedance matching of the capacitor to the ignition load.
  • DC power from the PV converter may supply at least one of the (i) the DC charging power of the capacitors of the ignition system comprising the source of electrical power 2 to the electrodes 8, (ii) the DC current of the at least one electromagnetic pump, (iii) the DC power of the resistive or inductively coupled heaters, (iv) the DC power of the duller comprising a DC electric motor, (v) the DC power of the vacuum pump comprising a DC electric motor, and (vi) the DC power to the computer and sensors.
  • the output power conditioning may comprise DC power from the PV converter or AC power from the conversion of DC power from the PV converter to AC using an inverter.
  • the light to electricity converter comprises the photovoltaic converter of the disclosure comprising photovoltaic (PV) cells that are responsive to a substantial wavelength region of the light emitted from the cell such as that corresponding to at least 10% of the optical power output.
  • the PV ceils are concentrator cells that can accept high intensity light, greater than that of sunlight such as in the intensity range of at least one of about 1 .5 suns to 75,000 suns, 10 suns to 10,000 suns, and 100 suns to 2000 suns.
  • the concentrator PV ceils may comprise c-Si that may be operated in the range of about 1 to 1000 suns.
  • the PV cells may comprise a plurality of junctions such as triple junctions.
  • the concentrator PV cells may comprise a plurality of layers such as those of Group ⁇ /V semiconductors such as at least one of the group of InGaP/InGaAs/Ge;
  • the plurality of junctions such as triple or double junctions may be connected in series, in another embodiment, the junctions may be connected in parallel.
  • the junctions may be mechanically stacked.
  • the junctions may be wafer bonded. In an embodiment, tunnel diodes between junctions may be replaced by wafer bonds.
  • the wafer bond may be electrically isolating and transparent for the wavelength region that is converted by subsequent or deeper junctions.
  • Each junction may be connected to an independent electrical connection or bus bar.
  • the independent bus bars may be connected in series or parallel.
  • the electrical contact for each electrically independent junction may comprise grid wires.
  • the wire shadow area may be minimized due to the distribution of current over multiple parallel circuits or interconnects for the independent junctions or groups of junctions.
  • the current may be removed laterally.
  • the wafer bond layer may comprise a transparent conductive layer.
  • An exemplary transparent conductor is a transparent conductive oxide (TCO) such as indium tin oxide ( ⁇ ), fluorine doped tin oxide (FTO), and doped zinc oxide and conductive polymers, graphene, and carbon nanotubes and others known to those skilled in the art.
  • Benzocyclobutene (BCB) may comprise an intermediate bonding layer.
  • the bonding may be between a transparent material such a glass such as borosiiicate glass and a PV semiconductor material.
  • An exemplary two-junction cell is one comprising a top layer of GalnP wafer bonded to a bottom layer of GaAs
  • An exemplary four-junction cell comprises GalnP/GaAs/GalnAsP/GalnAs on InP substrate wherein each junction may be individually separated by a tunnel diode ( ) or an isolating transparent wafer bond layer (//) such as a cell given by
  • the PV cell may comprise a single junction.
  • An exemplary single junction PV cell may comprise a monocrystalline silicon cell such as one of those given in Sater et ai. (B. L. Sater, N, D. Sater, "High voltage silicon VMJ solar cells for up to 1000 suns intensities",
  • the single junction cell may comprise GaAs or GaAs doped with other elements such as those from Groups HI and V.
  • the PV ceils comprise triple junction concentrator PV ceils or GaAs PV cells operated at about 1000 suns, in another exemplary embodiment, the PV ceils comprise c-Si operated at 250 suns, in an exemplary embodiment, the PV may comprise GaAs that may be selectively responsive for wavelengths less than 900 nm and InGaAs on at least one of biP, GaAs, and Ge that may be selectively responsive to wavelengths in the region between 900 nm and 1800 nm.
  • the two types of PV cells comprising GaAs and InGaAs on InP may be used in combination to increase the efficiency. Two such single junction types cells may be used to have the effect of a double junction cell.
  • each PV ceil comprises a poiychromat layer that separates and sorts incoming light, redirecting ⁇ to strike particular layers in a multi-junction cell.
  • the cell comprises an indium gallium phosphide layer for visible light and gallium arsenide layer for infrared light where the corresponding light is directed.
  • the cell may comprise a multi p-n junction cell such as a cell comprising an A1N top layer and GaN bottom layer to converter EUV and UV, respectively.
  • the photovoltaic cell may comprise a GaN p-layer cell with heavy p-doping near the surface to avoid excessive attenuation of short wavelength light such as UV and EUV.
  • the n-type bottom layer may comprise AlGaN or A1N.
  • the PV cell comprises GaN and Al x Gai.,(N that is heavily p-doped in the top layer of the p-n junction wherein the p- doped layer comprises a two-dimensional-hole gas.
  • the PV ceil may comprise at least one of GaN, AlGaN, and A1N with a semiconductor junction.
  • the PV cell may comprise n-type AlGaN or A1N with a metal junction.
  • the PV ceil responds to high-energy light above the band gap of the PV material with multiple electron-hole pairs. The light intensity may be sufficient to saturate
  • the converter may comprise a plurality of at least one of (i) GaN, (ii) AlGaN or A!N p-n junction, and (Hi) shallow ultra-thin p-n heterojunction photovoltaics ceils each
  • Each may comprise a lead to a metal film layer such as an Al thin film layer, an n- type layer, a depletion layer, a p-type layer aad a lead to a metal film layer such as an Ai thin film layer with no passivation layer due to the short wavelength light and vacuum operation.
  • a metal film layer such as an Al thin film layer, an n- type layer, a depletion layer, a p-type layer aad a lead to a metal film layer such as an Ai thin film layer with no passivation layer due to the short wavelength light and vacuum operation.
  • a metal of the appropriate work function may replace tine p-iayer to comprise a Schottky rectification barrier to comprise a Schottky barrier metai/semiconducior photovoltaic cell.
  • the converter may comprise at least one of phoiovoltaic (PV) cells, photoelectric (PE) cells, and a hybrid of PV ceils and PE cells.
  • the PE cell may comprise a solid-state cell such as a GaN PE cell.
  • the PE cells may each comprise a photocaihode, a gap layer, and an anode.
  • An exemplary PE cell comprises GaN (cathode) cessiated /AIN (separator or gap)/ Al, Yb, or Eu (anode) that may be cessiated.
  • the PV ceils may each comprise at least one of the GaN, AlGaN, and AIN PV ceils of the disclosure.
  • the PE cell may be the top layer and the PV ceil may be the bottom layer of the hybrid.
  • the PE ceil may convert the shortest wavelength light, in an embodiment, at least one of the cathode and anode layer of the PE cell and the p-layer and the n-layer of a PV cell may be turned upside down.
  • the architecture may be changed to improve current collection, in an embodiment, the light emission from the ignition of the fuel is polarized and the converter is optimized to use light polarization selective materials to optimize the penetration of the light into the active layers of the cell.
  • the light may be polarized by application of a field such as an electric field or a magnetic field by corresponding electrodes or magnets such as magnets 8c.
  • the fuel may comprise silver, copper, or Ag-Cu alloy shot or melt having at least one of trapped hydrogen and trapped 3 ⁇ 40.
  • the light emission may comprise predominantly ultraviolet light and extreme ultraviolet such as light in the wavelength region of about 10 nm to 300 ram.
  • the PV ceil may be response to at least a portion of the wavelength region of about 10 nm to 300 m,
  • the PV cells may comprise concentrator UV cells.
  • the incident light intensity may be in at least one range of about 2 to 100,000 suns and 10 to 10,000 suns.
  • the PV ceil may comprise a group III nilride such as at least one of InGaN, GaN, and AlGaN.
  • the PV cell may comprise a plurality of junctions. The junctions may be layered in series.
  • junctions are independent or electrically parallel.
  • the independent junctions may be mechanically stacked or wafer bonded.
  • An exemplary multi-junction PV cell comprises at least two junctions comprising n-p doped semiconductor such as a plurality from the group of InGaN, GaN, and AlGaN, The n dopant of GaN may comprise oxygen, and the p dopant may comprise Mg.
  • An exemplary triple junction ceil may comprise InGaN//GaN//AlGaN wherein // may refer to an isolating transparent wafer bond layer or mechanical stacking,
  • the PV may be run at high light intensity equivalent to that of concentrator photovoltaic (CPV).
  • CPV concentrator photovoltaic
  • the substrate may be at least one of sapphire, Si, SiC, and GaN wherein the latter two provide the best lattice matching for CPV applications.
  • Layers may he deposited using meta!organic vapor phase epitaxy (MOVPE) methods known in the art.
  • MOVPE meta!organic vapor phase epitaxy
  • the cells may be cooled by cold plates such as those used in CPV or diode lasers such as commercial GaN diode lasers.
  • the grid contacts may be mounted on the front and back surfaces of the cells as in the case of CPV cells.
  • At least one of the photovoltaic (PV) and photoelectric (PE) converter may have a protective vvindow that is substantially transparent to the light to which it is responsive.
  • the window may be at least 10% transparent to the responsive light.
  • the window may be transparent to UV light.
  • the window may comprise a coating such as a UV transparent coating on the PV or PE cells.
  • the coating may be applied by deposition such as vapor deposition.
  • the coating may comprise the material of UV windows of the disclosure such as a sapphire or MgFs window.
  • Other suitable windows comprise LiF and CaF . Any window such as a MgF 2 window may be made thin to limit the EUV atteauatioa.
  • the PV or PE material such as one that is hard, glass-like such as GaN serves as a cieanable surface.
  • the PV material such as GaN may serve as the window.
  • the surface electrodes of the PV or PE cells may comprise the window.
  • the electrodes and window may comprise aluminum.
  • the window may comprise at least one of aluminum, carbon, graphite, zirconia, grapheae, MgF 2 , an alkaline earth fluoride, an alkaline earth halide, Al 2 Oj, and sapphire.
  • the window may be very thin such as about 1 A to 100 A thick such that it is transparent to the UV and EUV emission from the cell. Exemplary thin traasparent thin films are Al, Yb, and Eu thin films.
  • the film may be applied by MOCVD, vapor deposition, sputtering and other methods known in the art.
  • at least one of the gravity recovery system, the plasma confinement system, the augmented plasma railgun recovery system, and the electrostatic precipitation recovery system may ameliorate the contact and impact of the ignition product with PV or its window.
  • the SF-CIHT generator may comprise a means to remove ignition product from the surface such as a mechanical scraper or an ion-sputtering beam.
  • the scraper may comprise carbon thai is not wetted by silver and also is non-abrasive.

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  • Physics & Mathematics (AREA)
  • Engineering & Computer Science (AREA)
  • Plasma & Fusion (AREA)
  • General Engineering & Computer Science (AREA)
  • High Energy & Nuclear Physics (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)

Abstract

L'invention concerne une source de conversion de combustible de métal fondu en plasma en électricité qui fournit de l'énergie électrique et/ou thermique comprenant (i) au moins une cellule réactionnelle servant à la catalyse de l'hydrogène atomique afin de former des hydrinos, (ii) un mélange de combustibles chimiques comprenant au moins deux composants choisis parmi : une source de catalyseur de H20 ou un catalyseur de H20; une source d'hydrogène atomique ou de l'hydrogène atomique; des réactifs servant à former la source de catalyseur de H20 ou le catalyseur de H20 et une source d'hydrogène atomique ou l'hydrogène atomique; et un métal fondu servant à rendre le combustible hautement conducteur, (iii) un système d'injection de combustible comprenant une pompe électromagnétique.
PCT/US2015/065826 2015-05-09 2015-12-15 Systèmes de génération d'énergie électrique ultraviolette et procédés associés WO2016182600A1 (fr)

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US201562159230P 2015-05-09 2015-05-09
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US201562165340P 2015-05-22 2015-05-22
US62/165,340 2015-05-22
US201562172169P 2015-06-07 2015-06-07
US62/172,169 2015-06-07
US201562173911P 2015-06-10 2015-06-10
US62/173,911 2015-06-10
US201562182421P 2015-06-19 2015-06-19
US62/182,421 2015-06-19
US201562191204P 2015-07-10 2015-07-10
US62/191,204 2015-07-10
US201562196751P 2015-07-24 2015-07-24
US62/196,751 2015-07-24
US201562200672P 2015-08-04 2015-08-04
US62/200,672 2015-08-04
US201562208205P 2015-08-21 2015-08-21
US62/208,205 2015-08-21
US201562217411P 2015-09-11 2015-09-11
US62/217,411 2015-09-11
US201562220582P 2015-09-18 2015-09-18
US62/220,582 2015-09-18
US201562237375P 2015-10-05 2015-10-05
US62/237,375 2015-10-05
US201562254104P 2015-11-11 2015-11-11
US62/254,104 2015-11-11
US201562257617P 2015-11-19 2015-11-19
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WO2017127447A1 (fr) * 2016-01-19 2017-07-27 Brilliant Light Power, Inc. Générateur d'énergie électrique thermophotovoltaïque
CN109187410A (zh) * 2018-08-30 2019-01-11 大连民族大学 一种一段式等离子体催化原位漫反射红外检测装置
US10819270B2 (en) 2018-03-16 2020-10-27 Uchicago Argonne, Llc High temperature selective emitters via critical coupling of weak absorbers
CN111934450A (zh) * 2020-08-26 2020-11-13 珠海格力电器股份有限公司 一种径向定子、磁悬浮轴承、安装方法及电机

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WO2014025443A2 (fr) * 2012-05-21 2014-02-13 Blacklight Power, Inc. Système électrique basé sur la ciht

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US20110026657A1 (en) * 2009-02-04 2011-02-03 Michel Georges Laberge Systems and methods for compressing plasma
WO2014025443A2 (fr) * 2012-05-21 2014-02-13 Blacklight Power, Inc. Système électrique basé sur la ciht

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2017127447A1 (fr) * 2016-01-19 2017-07-27 Brilliant Light Power, Inc. Générateur d'énergie électrique thermophotovoltaïque
JP2019512999A (ja) * 2016-01-19 2019-05-16 ブリリアント ライト パワー インコーポレーティド 熱光起電力電気的パワー発生器
US10819270B2 (en) 2018-03-16 2020-10-27 Uchicago Argonne, Llc High temperature selective emitters via critical coupling of weak absorbers
CN109187410A (zh) * 2018-08-30 2019-01-11 大连民族大学 一种一段式等离子体催化原位漫反射红外检测装置
CN111934450A (zh) * 2020-08-26 2020-11-13 珠海格力电器股份有限公司 一种径向定子、磁悬浮轴承、安装方法及电机
CN111934450B (zh) * 2020-08-26 2021-09-28 珠海格力电器股份有限公司 一种磁悬浮轴承径向定子、磁悬浮轴承、安装方法及电机

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