WO2016181176A1 - Engrais contenant de l'alginite et des dérivés de lombricompost - Google Patents

Engrais contenant de l'alginite et des dérivés de lombricompost Download PDF

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Publication number
WO2016181176A1
WO2016181176A1 PCT/HU2016/050018 HU2016050018W WO2016181176A1 WO 2016181176 A1 WO2016181176 A1 WO 2016181176A1 HU 2016050018 W HU2016050018 W HU 2016050018W WO 2016181176 A1 WO2016181176 A1 WO 2016181176A1
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Prior art keywords
alginite
vericompost
composition
hydrolysate
weight
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PCT/HU2016/050018
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English (en)
Inventor
Endre SEBESTYÉN
György MÉDER
János APRÓ
Imre BURKUS
Zoltán GERGELY
József KARSAI
Gyula Bogumil BALOGH
Balázs GYULAI
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Plantaco Logisztikai És Szolgáltató Kft.
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Priority to EP16736222.7A priority Critical patent/EP3294688A1/fr
Publication of WO2016181176A1 publication Critical patent/WO2016181176A1/fr

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    • C—CHEMISTRY; METALLURGY
    • C05—FERTILISERS; MANUFACTURE THEREOF
    • C05F—ORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
    • C05F9/00—Fertilisers from household or town refuse
    • C05F9/04—Biological compost
    • C—CHEMISTRY; METALLURGY
    • C05—FERTILISERS; MANUFACTURE THEREOF
    • C05F—ORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
    • C05F11/00—Other organic fertilisers
    • C—CHEMISTRY; METALLURGY
    • C05—FERTILISERS; MANUFACTURE THEREOF
    • C05F—ORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
    • C05F11/00—Other organic fertilisers
    • C05F11/02—Other organic fertilisers from peat, brown coal, and similar vegetable deposits
    • C—CHEMISTRY; METALLURGY
    • C05—FERTILISERS; MANUFACTURE THEREOF
    • C05F—ORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
    • C05F17/00—Preparation of fertilisers characterised by biological or biochemical treatment steps, e.g. composting or fermentation
    • C05F17/05—Treatments involving invertebrates, e.g. worms, flies or maggots
    • C—CHEMISTRY; METALLURGY
    • C05—FERTILISERS; MANUFACTURE THEREOF
    • C05F—ORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
    • C05F3/00—Fertilisers from human or animal excrements, e.g. manure
    • C—CHEMISTRY; METALLURGY
    • C05—FERTILISERS; MANUFACTURE THEREOF
    • C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G1/00—Mixtures of fertilisers belonging individually to different subclasses of C05
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K17/00—Soil-conditioning materials or soil-stabilising materials
    • C09K17/40—Soil-conditioning materials or soil-stabilising materials containing mixtures of inorganic and organic compounds
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A40/00—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production
    • Y02A40/10—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in agriculture
    • Y02A40/20—Fertilizers of biological origin, e.g. guano or fertilizers made from animal corpses
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/141—Feedstock
    • Y02P20/145—Feedstock the feedstock being materials of biological origin
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00—Technologies for solid waste management
    • Y02W30/40—Bio-organic fraction processing; Production of fertilisers from the organic fraction of waste or refuse

Definitions

  • Present invention relates the use of alginite hydrolyzate or derivative thereof and vericompost hydrolysate or derivative thereof together as plant and/or soil conditioner. More particularly the present invention relates such plant and soil conditioners, preparation and use thereof which comprise alginite hydrolysate and vericompost hydrolysate or derivatives thereof.
  • plant and soil conditioners preparation and use thereof which comprise alginite hydrolysate and vericompost hydrolysate or derivatives thereof.
  • the advantageous embodiments of the present invention are granules, wettable powders, gels, suspensions or suspoemulsions
  • the present invention relates plant and soil conditioners which can be used preferably in agriculture, horticulture and the preparation and use thereof.
  • the area of the having high sand content are 750.000 hectares
  • the acidic soil areas are 1 .200.000 hectares
  • the salinity areas are about 1 .000.000 hectares
  • the area of shallow topsoil areas are 1 .200.000 hectares.
  • the organic content of the soil has to be at least 2 %.
  • the soil provides the life conditions of microorganisms which mineralize the organic materials and which activities determine basically the fertilizer capability of the soil.
  • Soils having less organic content are unable to maintain the nutrients evolved from the mineralized organic compounds, thus these are washed out from the soil caused severe environmental problems e.g. the lack of microelements in food plants which cause sever health problems for humans at the end of the food chain.
  • the forms of the disadvantageous changes of soils are the compactness of the soil, bad air and water management, the starting of the salinization on the watered areas, the erosion and deflation.
  • the basic cause of these changes is the degradation of the organic-mineral colloids of soil which results that there are no reactants enough in suitable amount or composition for the chemical and biological reaction in the soil.
  • the mineral elements for the life of the microorganisms are provided by a so called organic-mineral, in other words organomineral complex.
  • organomineral complex The restoration of the structure and the function of these organomineral complexes is the primary purpose of the soil improvement and soil conditioning.
  • the productivity of soils is largely determined by the quality and particle sizes of the complexes are in the soil.
  • the complexes composed from montmorillonite and different clay minerals and the high nitrogen containing humic acids which seem to be effective if their particle sizes are about 2 micrometers. These complexes provide the nutrients for the microorganisms of soil too.
  • the dispersions and sol-s have further important role in the structure of the soil and in which the quality of the ingredient can be identified but these behaves as real solutions. Sol-s are able moving individually in soil using their cation exchanging capacity, but only in vertical direction. The different nutrients get to the inner part of the particles of lower layers of the soil through sol-s.
  • the alginite is a rock which containing fossil biomass, rotted basaltic and lime stone having high organic material and its very important physical property is that it absorbs 0.5-1 liters of water by kilogram and 80-90% of it is composed by clay and rock flour fractions. Average humus content is about 30% sometimes can reach 45%. Lime content is in calcium carbonate form is 33% and sometimes reaches the 40%.
  • the extraction of alginates are carried out by acidic treatment.
  • the useful ionic solution was treated as much weight of soda as much as weight of organic acid was used for the extraction of the alginate content of the fossil. Because it is reacted with sodium, magnesium or potassium alkali metals, the ionic alginic acid and soda are connected to Na, K or Mg.
  • vericompost has also extraordinary efficacy compared to other compounds for soil improving agents and plant conditioners which is the result of the method of the preparation and the selection of raw materials.
  • the used raw material which is a mixture of cow manure, leaf litter, peat is treated with 400-800 of live worms/m 2 and the thus prepared compost which is rich in humus materials and which further contains besides humic acids amino acids, proteins, antibacterial and antiviral compounds which can be found in the epithelial cells of the worms gut.
  • the vericompost mostly used as a component of the horticultural soil mixtures.
  • the vericompost is extracted with warm water or treated with KOH solution used in a high weight rate.
  • composition having bio-stimulant which has a plant and/ soil conditioner effect alone, but suitable for improving the effect of usual soil improving compositions, fertilizers, synthetic fertilizers and composts and suitable for the use with pesticides. It was important that it should be dispensed together with the usual fertilizer, soil treatment agents and pesticides.
  • Our aim was to develop a plant conditioner composition which suitable for the improvement of the cultivation environments of plants, thus an economical intensification of cultivation.
  • hydrolysate of alginite or a derivative thereof with hydrolysate of vericompost or a derivative thereof together as plant or soil conditioner, or as a basis of a plant or soil conditioner.
  • the object of the present invention is the use of hydrolysate of alginite or a derivative thereof and hydrolysate of vericompost or derivative thereof in combination as plant and/or plant conditioner agent.
  • Essential recognition of the present invention is that useful components for plants of alginite and vericompost are transformed into easily accessible forms in course of acidic or alkaline treatments of alginite and vericompost. Furthermore we found that the thus obtained easily accessible nutrients using together with micronized alginite and optionally with a carrier having high specific surface area and sorption capacity can be used and put to the plants more advantageously. Thus we can provide that followed the use of the easily absorbable components further required amounts of nutrients also available for plants e.g. from the decomposition of alginite.
  • hydrolysates from alginite and vericompost have a synergistic effect.
  • On the 42th day from sowing we measured the mass of the biomass by pieces (root and leaves) and the germination percentage.
  • the derivatives of the hydrolysates mean the products which are prepared by the treatment of the extracts and comprise the valuable components for plants.
  • Such derivatives can be for example lyophilized or concentrated extracts, or solid products separated from hydrolysate e.g. humic acids trace elements or mineral salts or hydrolysates absorbed onto solid carrier or dried versions thereof.
  • a efficacy % of component A where kg/hectare is the application value of the component.
  • b efficacy % of component B where kg/hectare is the application value of the component.
  • E calculated effect of A + B components in %, a+b is application value of components in kg/hectare.
  • the two compounds inhibit each other (antagonism), if the % of effect equal to the calculated value (E) the two components have additive effect. If the % effect of the combination of the two components is higher than the calculated effect according to formula above (E), the compounds have synergistic effect.
  • the measured and calculated additive data are as follows:
  • GH composition containing derivative of hydrolysate of vericompost
  • ALG composition containing derivative of hydrolysate of alginite.
  • ALG-GH composition containing a mixture of derivative of hydrolysates alginite and vericompost which hydrolysates were produced by using vericompost and alginit in a weight ratio of 1 : 1 .
  • humic acids resulted from different origin (raw material) and the salts of these humic acids shows synergistic effect even they are formed into a composition.
  • alginite hydrolysate or a derivative thereof, vericompost hydrolysate or a derivative thereof and at least one more component are used as soil or plant conditioner composition.
  • Such further component can be one or more nutrients, plant hormones, solid carrier, pesticides, and/or formulation excipients.
  • Advantageous embodiments of the present invention are granules, wettable powders, gel, solution, suspension or suspoemulsion.
  • the present invention is a soil and/or plant conditioner composition which contains hydrolysate of alginite or a derivative thereof and hydrolysate of vericompost or a derivative thereof.
  • the hydrolysate of alginite or vericompost means the hydrolysates of vericompost or alginite prepared in alkaline or acidic media. According to an embodiment of the present invention at least one component the vericompost or the alginite hydrolysate is separated from the solid residue of the reaction mixture of hydrolysis. According to the other embodiment of the present invention the hydrolysates contain the solid components of reaction mixture.
  • the derivatives of the hydrolysates of vericompost and alginite mean according to the present invention materials which produced during the extraction procedure and contain the valuable compounds for plants.
  • Such as can be lyophilized or concentrated solutions of hydrolysates, solid particles precipitated from hydrolysates such as precipitated humic acids, trace element containing organic or mineral salts, hydrolysates absorbed onto solid carriers or dried version thereof.
  • composition according to the present comprises a mixture of vericompost and alginite hydrolysates or derivatives thereof which is prepared of amount of alginit and vericomopost in a weight ratio of 1 : 10-10:1 preferably 5: 1 -1 :5, more preferably 1 :3-3: 1 .
  • the composition comprises as alginite and vericompost hydrolysates a vericompost hydrolysate or derivative thereof which was prepared by treating the vericompost in an acidic pH and/or alkaline environment and an alginite hydrolysate or a derivative thereof which were treated in acidic and/or alkaline environment.
  • at least of one of the hydrolysates is present in a solid derivative form in the composition.
  • the composition also contains a sold carrier.
  • Solid carrier according to the present invention is such a solid material which ad- or absorbs on its surface or absorbs if a porous material in pores the hydrolysate(s) of vericompost or/and alginite.
  • Such solid carriers can be organic or inorganic materials.
  • organic material peat, corncob, coconut fiber, hemp, straw, sawdust as inorganic materials stone fines or artificial materials such as artificial zeolites, or fertilizers, as natural inorganic solid carrier zeolite containing rhyolite tuff, dolomite, alginite, diatomaceous earth, bentonite, charcoal most preferably alginite or zeolite can be used.
  • organomineral complex the organic material and mineral colloid content of the soil, the so called organomineral complex.
  • the plant absorbs the most of the required base elements from this complex.
  • One of the mineral components of the organomineral complex is zeolite and clay minerals evolved from weathering volcanic glass. Zeolites are in rhyolite tuff and in the holes of neo-volcanic stones which are interesting firstly from the point of view of the present invention because their ion exchanging activities due to their structures. It is known that in the cations bound to the holes of the crosslinked structure of zeolites can be exchanged. From the point of view of ion exchange Zeolites seem like solid solutions.
  • domestic zeolites due to ion exchanging properties they capable for storing the active ingredients of several agrochemical agents then it release slowly provide them for the plants and soil.
  • potassium trachyte optionally with rhyolite tuff containing zeolite of the formula (Me n+ )/[(AIO2)X(SiO2)y] * mH2O in which Me stand for Na+, K+, Mg2+, Ca2+, Zn2+, Cu2+, Mn2+,Fe2+ ion and the ratio between silicon and aluminum is y:x 1 : 1 -10: 1 , m means the amount of crystal water between 0-20 or the mixture thereof with other natural or synthetic zeolites.
  • zeolite faujasit As natural and/or synthetic zeolite faujasit, cabazite, gmenilit, mordenite, ofretite, zeolite ZSM-35, or Zeolite P can be used.
  • the extracts of alginite and vericompost applied onto the fins of alginite or zeolite behave like the organiomineral complexes in the soil as so called organomineral complex which are composed from clay colloids + humus colloids.
  • the microelements from alginite and zeolite are in complex bounds providing the safe microelement supply for plants. Different calcium containing compounds have an advantageous effect for the soil structure and the stability of the different mineral colloids.
  • Calcium, magnesium and potassium ions bind to the crystalline structure in strongly bound clay soil by exchange of sodium ions and improve the air and water management of them, consequently increasing the amount of nitrogen absorbing microorganisms furthermore increases the activity of cellulose decomposing bacteria, therefore speeds up the decomposition of the partially converted into humus, decomposed organic materials having high lignin content in degraded soils by air providing easily absorbable organic carbon sources for the nitrogen phosphor and potassium binding bacteria.
  • alginit hydrolysate and vericompost hydrolysate or derivatives are in an amount which can be extracted from a weight ratio of alginite and vericompost between 10: 1 -1 :10 preferably, 1 :5-5: 1 , more preferably 1 :3-3: 1 .
  • the compositions of the present invention have to meet for these requirements not only by their composition but particle sizes of organomineral complexes.
  • the catalysts organomineral complexes
  • the dispersion medium is the capillary water in the pores of the soil, the disperse parts are organomineral complexes.
  • the equivalent diameter of 2 micrometer can be seen as highest limit of the colloid size.
  • the clay components of solid phase and the organic materials meet these criteria.
  • This phenomenon does not a result of a DNA, RNA or a protein of a algae species which composed the fossil and which could modify the genetic or epigenetic properties of the soil bacteria because these chemical compounds surely decomposed in this time span but it must be a result of some small molecular organic compounds having stimulant or hormone-like effect.
  • compositions containing zeolite that the composition takes its effect also horizontally either a hydrolysate of alginite or vericompost is on zeolite carrier having a diameter 3-5 micrometers:
  • the composition was applied in an amount of 20 l/hectare on sweetcorn plantation after sowing in the spacing centerline from which the plants were planted 38 centimeters far. The area was 100 meters long and it has 40 row spacing wide. During the examination 10 rows were treated then 20 rows were untreated. After silking we have measured the nitrogen contents of the leaves against the cob, the height of the plant and the amount of the raw cob crop. The crop from the two treated extreme area 3-3 rows and the crops of the untreated 9-1 1 and 16-17 rows were measured. The nitrogen contents of the leaves against cobs, the height of plants and the amount of the raw cob crop are in table below:
  • alginite is treated with acidic and/or alkaline hydrolysate of alginite in an amount of 0.1 -20 weight%, preferably 2.5-10 weight% based on air-dry alginite and the average particle size of the alginite less than 10 micrometers the result a disperse system which has a very similar effect to the effect of organomineral complex of soil.
  • Such advantageous composition can be produced comprising hydrolysate of alginite and alginite if appropriate the milled alginite is hydrolyzed and the thus obtained reaction mixture is used in the composition with or without neutralization as hydrolysate.
  • the above-mentioned solid carriers are in micronized form in the compositions preferably.
  • the average particle sizes of the solid carriers used in compositions are between 0.05-500 micrometers, preferably 0.05-100 micrometers, more preferably 0.05-40 micrometers, most preferably 0.1 -10 micrometers.
  • the average particle is size according to the present description the median (D 50 ).
  • Particle size measurement and particle distribution analysis has been carried out using an Analysette 22 type laser particle analyzer, which operates on the basis of Fraunhoffer light deflection.
  • the measurement range of the instrument can be selected between 0.1 and 1000 microns.
  • the sample requirement is 0.5 to 1 .0 g which is suspended in 250 ml of liquid (distilled water).
  • distilled water is not suitable as suspending liquid, different other liquids (alcohols, glycerol, mineral and organic oils) can be used as well.
  • the agglomerates are dispersed by ultrasonication and the homogeneous dispersion is maintained.
  • the average particle size can be expressed as an algebraic average (S), geometrical mean (M), square quadratic mean (N) or harmonic mean (H) of the geometric particle size (x). Based on the distribution curves, the following values characterizing the particle size can also be reported. Median is the particle size belonging to the 50% point of the cumulative curve. The modal value is the particle size measured at the maximum of the density distribution curve. In the present specification, under average particle size, the median is meant, which is the particle size belonging to the 50% point of the cumulative curve.
  • the plant or soil conditioners according to the present invention besides of hydrolysates of alginite and vericompost can contain further nutrients.
  • compositions according to the present invention as nutrient can contain biologically quickly recoverable carbon and nitrogen sources such as organic acids, preferably malonic acid, fumaric acid, succinic acid, ascorbic acid, phosphor and potassium containing synthetic fertilizers, urea-formaldehyde condensates, urea phosphate, potassium phosphate, oxamide, as fertilizer phosphates, nitrates, preferably, phosphoric acid, ammonium phosphate, ammonium sulfate, ammonium nitrate, potassium phosphate, potassium nitrate, calcium nitrate, micronized alginite, or a mixture thereof, plant or animal proteins, peptides, e.g.
  • Myoglobin and hemoglobin are rich of amino acids and form complexes with metal ions which are evolve from zeolite which is used optionally as solid carrier and protects them from the binding to the soil controls their concentration and their absorbability from the soil.
  • compositions carbon and nitrogen sources such as Amalgerol Premium which comprises mostly animal and plant oils, herbal extracts, trace elements, essentials and a minimal amount of seaweed extract or Gullemax (Hechenbichler GmbH Austria) which comprises mostly animal and plant oils, herbal extracts, trace elements an essentials or Radipharm (Valagro, Italy) which comprises complex sugars, saponines, proteins, special amino acids, vitamins and chelate complexes of microelements.
  • Amalgerol Premium which comprises mostly animal and plant oils, herbal extracts, trace elements, essentials and a minimal amount of seaweed extract or Gullemax (Hechenbichler GmbH Austria) which comprises mostly animal and plant oils, herbal extracts, trace elements an essentials or Radipharm (Valagro, Italy) which comprises complex sugars, saponines, proteins, special amino acids, vitamins and chelate complexes of microelements.
  • compositions according to present invention can contain as nutrient nitrogen containing fertilizers, preferably potassium, calcium, ammonium, sodium nitrate, ammonium sulfate, ammonium chloride, calcium cyanamide, urea, urea- formaldehyde condensates, and /or phosphor containing fertilizers, preferably ammonium and calcium phosphate, triple superphosphate, urea-phosphate, potassium phosphate, thermo phosphate, ammonium phosphate, ammonium trimethylene phosphoric acid, di-ammonium hydrogen phosphate, ammonium carbonate, ammonium acetate, tri-ammonium phosphate, ammonium hydrogen carbonate, ammonium hydrogen sulfate, carboxamide, raw phosphate, bone meal, potassium containing fertilizers, such as potassium chloride, potassium nitrate, potassium sulfate, potassium phosphate, patentkali or a mixture thereof, vitamins, preferably riboflavin, thiamine, nicotinic
  • compositions according to the present invention can contain plant hormones preferably 2-(indol-3-yl)acetic acid, 2-(naphatalene-1 -yl)acetic acid, 4- (indol-3-yl)butanoic acid, abscisinic acid, giberelin acid or ammonium, potassium, sodium, calcium or magnesium salts thereof, zeatin or a mixture thereof, plant extracts preferably seaweed extracts, fitoalexin elicitors e.g. laminarine, yeast extracts, plant oils, preferably natural aromatic oils or a mixture thereof in an amount of 0.001 -0.01 -8 weight%.
  • plant hormones preferably 2-(indol-3-yl)acetic acid, 2-(naphatalene-1 -yl)acetic acid, 4- (indol-3-yl)butanoic acid, abscisinic acid, giberelin acid or ammonium, potassium, sodium, calcium or magnesium salts thereof, ze
  • compositions according to the present invention further can contain as active ingredient plant extracts and pesticides as pyrethrum, azadirachtin, toenon, nicotine extracts and a mixture thereof in an amount of 0.1 -20 weight% preferably 1 .0-10.0weight%.
  • pesticides are e.g.
  • Degradable oleic acids and carboxylic acids are in the base components of the compositions of the present invention. It is known, that the alkane carboxylic acids behave as a surfactant at a specified pH. The strongest surface tension reduction effect of the everyday used alkali carboxylic acid sodium salts, soaps, is in alkaline range (pH 7-10). In course of our examinations we found surprisingly an unexpected result that in course of the alkaline extraction of alginite and/or diatomaceous earth and/or peat in aqueous media in case of the oils containing different organic and inorganic contaminants, the pH range is significantly lower (pH 4.5-6.5).
  • the oils of the composition of the present invention (preferably 50g/l) reduce the surface tension between pH 5.8-6 to 40dyn/cm: We have examined the surface tensions of the compositions of the present invention: Table 3
  • oils extracted from diatoms, alginite or peat are advantageous components of the compositions of the present invention.
  • the efficacy of the chemicals used in agricultural industry is largely depends on the sprayed spray forms spheroid drops or flat spreads on the surface of leaves. For the better wetting and adhesion different oil derivatives are used.
  • the efficacy of the sprayed pesticide depends on that how the drops spread on the surface of leaves, between the soil colloid and soil solution also a rule that the greater surface contact results higher physical and chemical reaction rate in the soil colloids.
  • the oil extract from alginite, peat or diatomaceous earth can be used whish do not reduce the surface tension only but they have biological activity too.
  • oils, peat oil, diatomaceous oil, and oils from alginite can be prepared by milling alginite and/or peat and/or diatomaceous earth particle size between of 10- 1000 micrometer, preferably 40-200 micrometers.
  • the ground raw material is treated in alkaline media with alkali or alkali earth metal hydroxides and/or carbonates and/or hydrogen carbonates, optionally with ammonium hydroxide, where the alkaline compounds are used 0.0001 -0.2 moles amount, so that pH of the reaction mixture is between 9.0-12.0, preferably 9.5-10.5 and the weight rate of the used aqueous phase and the alginite and/or peat and/or diatomaceous earth is between 50: 1 -10.0, preferably 20:0.5-2.0.
  • the reaction mixture is kept under continuous stirring for 30-60 minutes at 35-40°C in an autoclave equipped heating and cooling system, then the mixture is kept to stay for 20-24 hours, and then the supernatants were filtered. The filtrate was frozen and the oil is separated from the frozen water.
  • the composition comprises auxiliary agent formulation.
  • According to the present invention can contain if necessary further compounds and excipients which are usually used in agricultural industry such as binders, disintegrating agents, antiadhesives and chemical stabilizing agents, disperging agent, surfactants, penetration enhancer, complex forming agent, stabilizers, solvents, suspension stabilizers or a mixture thereof.
  • binders disintegrating agents, antiadhesives and chemical stabilizing agents, disperging agent, surfactants, penetration enhancer, complex forming agent, stabilizers, solvents, suspension stabilizers or a mixture thereof.
  • binder and disintegrating agents e.g. lignin sulfonates, humates, humic acid extracts, starch, cellulose, natural plant extracts or a mixture thereof, as antiadhesive and chemical stabilizer preferably sodium sulfate, zinc sulfate, aluminum sulfate, iron sulfate, magnesium hydroxide, sodium methacrylate or a mixture thereof, as dispersing agent naphthalene sulfonate (or methyl naphthalene) and sodium or ammonium salts of formaldehyde containing condensates, sodim, calcium or ammonium salts of lignin sulfonates, poly- ethoxylated lignin sulfonates, sodium taurides, or sodium or ammonium salts of maleinic acid based copolymers or a mixture thereof, as surfactant ethoxylated natural or synthetic alcohols or a compound of the general formula (II)
  • ammonium sulfate As penetration enhancer ammonium sulfate, ammonium phosphate, ammonium tri-methylene phosphoric acid, di-ammonium hydrogen phosphate, ammonium carbonate, ammonium acetate, tri-ammonium phosphate, ammonium hydrogen carbonate, urea, ammonium hydrogen sulfate or a mixture thereof can be contained.
  • the amount of the binders and disintegrating agents are 1 -10 weight%, preferably 2-5 weight% in the composition.
  • ammonium sulfate, sodium sulfate, tri-sodium citrate, nitrilotriacetic acid tri-sodium salt, salts of ethylene-diamine tetra acetic acid, citric acid, malic acid, ammonium phosphates, hydroxyethane diphosphoric acid salts, nitrile-tris-methylene phosphoric acid salts can be used which are in an amount of 0.5-5.0 weight%preferably, 0.75-4.5 weight% in the composition.
  • the calcium and magnesium content of surface water and formation water which are used for the preparation of spray can be neutralized with the complex forming agents of the compositions.
  • composition according to the present invention can further contain natural oils, preferably natural aromatic oils in an amount on the weight of in an amount of 0.001 -60 weight%, preferably 0.001 -10 weight%, most preferably 0.01 -8 weight%.
  • compositions for foliage treatment of the present invention can further contain such materials which influence advantageously their biological efficacy and application.
  • they can contain solvents, preferably water, ethanol, 1 ,2- propyleneglycol, mineral and plant oils or mixtures thereof, in an amount of 15-60 weight% based on the weight of the composition, preferably 10-30 weight%, suspension stabilizers e.g. poly-vinyl-alcohols, poly-ethylene-glycols, potassium palmitate, ammonium laurate etc. or a mixture thereof in an amount of 1 -5 weight%, preferably 1 -2 weight% based on the weight of the composition.
  • a very effective composition can be prepared by using surfactants containing quaternary ammonium sub-structures.
  • compositions of the present invention can be granules, wettable powders, solutions, suspensions or suspoemulsions.
  • compositions of the present invention are powders containing extracts adsorbed on a solid porous carrier, preferably spray powders, granules, preferably soil fertilizers, suspensions, suspoemiulsions which contain further nutrient biological useful or other auxiliary agents which help the use of the compositions.
  • a solid porous carrier preferably spray powders, granules, preferably soil fertilizers, suspensions, suspoemiulsions which contain further nutrient biological useful or other auxiliary agents which help the use of the compositions.
  • spray powders granules, preferably soil fertilizers, suspensions, suspoemiulsions which contain further nutrient biological useful or other auxiliary agents which help the use of the compositions.
  • suitable biological or technological useful components are mentioned above.
  • compositions of the present invention which comprises solid porous carrier and hydrolysate or a derivative of hydrolysate of alginite and hydrolysate or a derivative of hydrolysate of vericompost and optionally further nutrients biological or technological useful or other auxiliary agents which help the use of the compositions can be used as spray powder, in form of granule, as soil fertilizer, suspension, dispersion, suspoemulsion, preferably as foliar fertilizers or concentrate of foliar fertilizers.
  • compositions of the present invention can be used also as soil fertilizer which comprises besides the hydrolysate or a derivative of hydrolysate of alginite and hydrolysate or a derivative of hydrolysate of vericompost optionally further comprises a solid carrier or besides the porous solid carrier treated with hydrolysate or a derivative of hydrolysate of alginite and hydrolysate or a derivative of hydrolysate of vericompost, if necessary contains nitrogen, phosphor or potassium containing fertilizer such as urea, urea-formaldehyde condensate, urea-phosphate, potassium phosphate, oxamide, mono-ammonium phosphate, di- ammonium phosphate, superphosphate, triple-phosphate, gasfa phosphate, as potassium containing component e.g.
  • potassium chloride potassium nitrate, potassium sulfate, potassium phosphate.
  • nitrogen content can be between 0.01 -10 weight%
  • phosphor content as phosphor pentoxide can be between 0.01 -20weight%
  • potassium content as potassium oxide 0.1 -10 weight%.
  • nitrogen content of the composition can be between 0.01 -20.0 weight%
  • phosphor content can be between 0.01 -20.0 weight%
  • potassium content can be between 0.01 -20.0 weight%.
  • the composition of the present invention is not necessary to apply to the whole area, but it is enough to apply to the sown seed or to the root of the planted seedlings. Even more because the composition of the present invention also moves horizontally in the soil, depending the applied row spacing the composition has to be applied only in specified rows.
  • the size of the fertilizer preferably varied between 0.5-4.5 mm depending on the used mechanical spraying technology needs.
  • the porous carriers having homogeny particle size fraction can be prepared by milling of the raw mine porous carrier to an appropriate particle size, or it is granulated from powder using known method.
  • the particle size of the compositions of the present invention for use as foliage fertilizer is preferably between 0.5-5 micrometers.
  • the foliage fertilizers can be prepared as spray powder, suspension or suspoemulsion.
  • the compositions can contain further nutrients.
  • As nutrient preferably can be used nitrogen, phosphor or potassium containing fertilizers such as urea, urea-formaldehyde condensate, urea-phosphate, potassium phosphate, oxamide,
  • the composition of the present invention can have a nitrogen content between 0.0-20.0 weight%, phosphor content between 0.0-20.0 weight%, potassium content between 0.0-20.0 weight%.
  • compositions can contain humic acids or potassium sodium or magnesium salts thereof or a mixture thereof, amino acids, glycine, tryptophan, methionine, tyrosine, phenylalanine or potassium calcium or magnesium salts thereof or a mixture thereof, plant hormones as indole-acetic acid, gibberellin acid, abscissin acid or salts thereof, seaweeds, seaweeds extracts, fitoalexin elicitors such as laminarine, yeast extracts plant oils aromatic oils having natural origin in an amount of 0.001 -10 weight%, preferably 0.01 -8 weight%.
  • the foliage treating composition of the present invention can further contain such materials, which helps the application of the composition and influence the biological efficacy of the composition.
  • compositions can contain e.g solvents, preferably water, ethanol, 1 ,2-propyleneglycol and plant oils or a mixture thereof in an amount of 15- 60 weight%, preferably 10-30weight%, suspension stabilizers, e.g. poly-vinyl- alcohols, polyethylene-glycols, potassium palmitate, ammonium laurate etc. or a mixture thereof in an amount of 1 -5 weight%, preferably 1 -2 weight% based on the weight of the composition.
  • suspension stabilizers e.g. poly-vinyl- alcohols, polyethylene-glycols, potassium palmitate, ammonium laurate etc. or a mixture thereof in an amount of 1 -5 weight%, preferably 1 -2 weight% based on the weight of the composition.
  • a very effective composition can be prepared by using surfactants containing quaternary ammonium sub-structures.
  • the efficacy of the suspension composition of the present invention can be improved by using different oil additives firstly by added oil extracted from diatomaceous earth.
  • the weight ratio of the suspension and solid particles is between 1 :0.05- 0.25.
  • the mixture of the suspension is pre milled in bead mill to a particle size of 5-10 micrometers with suspension stabilizers and auxiliary agents which improve the usability of the suspension and pH is adjusted 6.5-7.5.
  • composition according to the present invention as active ingredient further can contain of 0.1 -20 weight%, preferably 1 .0-10.0 weight% of plant extract, pesticides having natural origin such as pyrethrum, azadirachtin, toenon, nicotine extracts and a mixture thereof.
  • the compositions according to the present invention can be used in field crops, forests, plantations, greenhouses, orchards, vines, grasses and ornamentals.
  • the composition can be applied to plants as foliar spray, powders, granules, mists, foams, capsulated compositions, suspensions, for soil and root treatment in fluid form, powders, granules, smokes, seed treatment fluid solution, suspension or powder, for bole treatment as injection, paste or paint.
  • the plants tolerate well the compositions of the present invention in the concentration which necessary to achieve the required effects, thus they can be used for the treatment of seeds, plant parts over the ground and roots.
  • the scope of the protection of the present invention covers the processes too in which the plants are treated with an effective amount of growth regulator compositions according to the present invention.
  • the chemical compounds and the compositions containing thereof can be used with known methods in an effective amount. From these processes here we mention for example the leaf or soil treatment, seed treatment or the dipping of roots of seedlings.
  • Another aspect of the present invention is a process for the preparation of soil and/or plant conditioners which can be achieved that a.) alginite and vericompost are hydrolyzed in alkaline or acidic media separated each other, then the obtained hydrolysates optionally transformed to derivatives thereof, and the thus obtained alginite and vericompost hydrolysates or derivatives thereof are mixed, or b.) alginite and vericomost are hydrolyzed in alkaline or acidic media together and the obtained mixture of hydrolysates of alginite and vericompost optionally transformed to derivatives and the thus obtained mixture is optionally formulated.
  • the thus obtained mixture of hydrolysates of vericompost and alginite are suitable alone for the use as plant or soil conditioner.
  • the obtained mixture is formulated in a well manageable form which can be applied with generally used application techniques of agricultural industry.
  • Such forms are e.g. granules, wettable powders, gels, solutions, suspension or suspoemulsoions.
  • the hydrolysis in alkaline media means that alginite, vericompost, optionally a mixture thereof in presence of water or humidity, reacted with inorganic bases.
  • the hydrolysis in acidic media means that alginite, vericompost, optionally a mixture thereof in presence of water or humidity, reacted with organic or inorganic acids, or with salts which show acidic pH in their aqueous solutions or suspensions.
  • Hydrolysis of alginite and vericompost can be carried out either in separated reaction mixtures, or with the mixture of alginite and vericompost.
  • the reaction mixtures besides alginite and vericompost can contain further components which can be also hydrolyzed e.g.
  • peat or diatomaceous earth or such components which helps the further use of the thus obtained hydrolysates, but do not take part in the reaction such nutrients organic or inorganic carriers which influence the practical applicability of the thus obtained solution for plant or soil conditioner.
  • Such compounds which can help the formulation or the applicability of the obtained solution can be the auxiliary agents used in the agriculture, e.g binder, disintegrating agent, antiadhesive and chemical stabilizers dispersant, surfactant, penetration enhancer, complex forming compound, stabilizers, solvents, suspension stabilizers, or a mixture thereof.
  • the hydrolysate is separated from the reaction mixture after completion of the reaction by removing the solid residue and the fluid phase is further used. According to another embodiment of the present invention the hydrolysate is not separated from the reaction mixture but the whole reaction mixture is used implemented with other reaction steps such as the pH adjustment.
  • phosphorous acid based on 1 moles KOH
  • the precipitated materials which precipitated because of added acid are not separated but it handled in the obtained form with adding alginite or optionally with rhyolite tuff containing zeolite.
  • the phosphorous acid and/or salts thereof can be between 5-10weight% the amount of alginite and vericompost between 10-60 weight%
  • the composition according to the present invention can also contain humates , humic acids in an amount of 0.1 -5 weight%.
  • the extracts of alginite and/or vericompost are transformed into extract derivative(s).
  • These derivatives are according to the present invention materials which formed with treatments of these hydrolysates and contain the explored compounds from the hydrolysates which valuable components for plants.
  • Such derivatives can be the lyophilized or concentrated hydrolysates, or solid components separated from hydrolysates such as separated humic acids, organic or inorganic salt of trace elements, hydrolysates absorbed onto sold carriers or dried variations thereof.
  • the hydrolysates are transformed from fluid form to a solid form by the adjustment of pH of alkaline hydrolysate, e.g. with the acidification the humic acids are precipitated and can be separated.
  • compositions according to the present invention can contain of the non-soluble components of alginite or vericompost. Which means that is not necessary the separation of active components extracted by alkaline or acidic extraction.
  • the extracts of the composition containing extracts of alginite and vericompost can be prepared by the treatment of the mixture of alginite and vericompost.
  • alkali metal or alkali earth metal hydroxides ammonium, alkali metal, alkali earth metal hydro- carbonates, ammonium, alkali metal, alkali earth metal carbonates, alkali metal, alkali earth metal oxides, more preferably ammonium, sodium, potassium and calcium hydroxides, hydrogen carbonates, calcium oxide, sodium, potassium and ammonium carbonate are used.
  • the weight rate of the NaOH or KOH and NH 4 OH based 100 weight% base are 20-1 : 1 -10, preferably, 10-1 : 1 -10, more preferably 5: 1 -1 :5, most preferably 5: 1.
  • alginite hydrolysate which is rich of microelements that alginite and/or peat are milled to 10-1000 micrometers preferably 40 micrometers.
  • the milled raw material is treated with acidic or alkaline treatment.
  • the treatment is carried out between 15-100°C, preferably 30-60°C, more preferably 30-45°C.
  • the solid residue is filtered off and fluid phase can be used in unchanged form or the pH of the fluid phase can be adjusted in a required value (pH 7.0-7.5).
  • acidic hydrolysis as inorganic acid preferably hydrochloric acid, nitric acid, phosphoric acid, sulfuric acid, as organic preferably citric acid, fumaric acid, malonic acid, succinic acid, formic acid, acetic acid, propionic acid, oxalic acid, as salt which shows acid pH in aqueous solution preferably ammonium nitrate, calcium chloride, zinc sulfate monohydrate, mono ammonium phosphate, potassium hydrogen sulfate can be used.
  • the process a.) is carried out so that the one of the components of alginite and vericompost is hydrolyzed in acidic media, while the other is hydrolyzed in alkaline media.
  • the alkaline hydrolysate of alginite or a derivative thereof and the acidic hydrolysate of vericompost or derivatives thereof are mixed and used alone or formed into composition by using blended with further nutrients and/or formulation excipients.
  • alginite and vericompost are used in a weight ratio of 1 : 10-10: 1 , preferably 1 :5-5: 1 more preferably 1 :-3: 1.
  • the hydrolysis is carried out with milled alginite and vericompost having an average particle size of 0.5-500 micrometers, preferably 0.5-200 micrometers, most preferably 0.5-40 micrometers.
  • alginite and/or vericompost are suspended in water than an inorganic base is added to the reaction mixture, then the reaction mixture left to stay or under stirring if necessary, or b. ) alginite and/or vericompost are suspended in water than an inorganic or organic acid or salts showing acidic pH in their aqueous solution or suspensions are added to the reaction mixture in a form of solution, suspension or solid form, then the reaction mixture left to stay or under stirring if necessary.
  • the hydrolysis takes a period of time between 4 hours and 6 days, preferably 1 -5 days.
  • the hydrolysis is carried out at temperature between 15-100°C, preferably between 30-60°C, most preferably between 30-45°C.
  • the pH value of the reaction mixture during the alkaline hydrolysis is 9-12, preferably 9.5-10.5, in the case of acidic hydrolysis less than 6.2.
  • the aqueous mixture of alginite and vericompost can be stirred for 12 hours at 30- 35°C, then it is treated with alkali metal hydroxide and/or carbonate and/or hydrogen carbonate, preferably ammonium hydroxide and/or sodium carbonate and/or potassium hydrogen carbonate in a manner that the pH of the reaction mixture is slightly basic the pH between 7.2-7.4.
  • the mixture is stirred for 4-6 hours at 30-35°C then after a necessary dilution the thus obtained tailings and supernatant together with formulation auxiliary agents are milled with bead mill to a particle size of 2-5 micrometers.
  • alkaline extract and acidic extract are prepared separately, then mixed in a weight ratio of 100: 1 -1 : 100, preferably 10: 1 -1 : 10 more preferably 2: 1 -1 :2 and then milled as above mentioned.
  • the necessary time for the hydrolysis is depends strongly from the strengths of the used acid or base, concentration and the used temperature. For example the use of less soluble calcium hydroxide requires more time than the use of KOH which is very soluble in water using same temperature.
  • the selection of the basis or acid besides the technological point of view depends on that the salts formed with the used acid, or the cations of the used base which remain in a salt form in the composition are meet the technological requirements. For example with using hydrochloric acid treatment of alginite or vericompost the extraction is faster than using citric acid but with this composition many chloride ions are introduce to the soil, furthermore, salts of hydrochloric acid are unable for complex forming and quickly washed out from the soil.
  • the person skilled in the art based on the requirement of the use and the plant variety can select the most suitable base or acid mixtures which results the best composition. After the selection of these, the person skilled in the art based on the present description and the working example can clearly define the time necessary and the suitable process.
  • the composition can be carried out by adding further one or more nutrient(s) and/or formulation excipients are added besides the alginite and vericompost.
  • the alkaline hydrolysis can be carried out, that alginite and/or vericompost in presence of a base in a fluidization reactor is fluidized between 60-100°C, preferably between 75-95°C, more preferably between 80-85°C in a gas having 60-100% relative humidity preferably in saturated humid gas, for 2-6 hours.
  • base alkali metal carbonates preferably sodium or potassium carbonate can be used.
  • composition containing the obtained hydrolysate of vericompost or/and derivatives and the obtained alginite hydrolysate or the derivative thereof are mixed with one or more further nutrients, and optionally with plant hormones, and/or formulation excipients too and in a known manner transformed to granules, wettable powders, solution, gel composition or suspoemulsion.
  • vericompost hydrolysate and/or the derivative thereof and the alginite hydrolysate and/or derivatives thereof are applied on the surface of a solid carrier or adsorbed by a porous carrier.
  • granules can also be produced by precipitation of humic acids from the mixture of the hydrolysates of alginite and vericompost or by the evaporation of the hydrolysates to dryness.
  • the thus given derivatives are milled to an average particle size preferably between 0.05-10 micrometers, more preferably 0.5-5 micrometers, most preferably 0.5-3 micrometers and mixed with a solid carrier having an average particle size between 0.05-400 micrometer, preferably 10-200 micrometer, most preferably 40-100 micrometers, preferably with rhyolite tuff containing zeolite, the mixture is homogenized and formed into granules by wet granulation using binders such as aqueous solution of lignin sulfonate and further excipients if necessary.
  • binders such as aqueous solution of lignin sulfonate and further excipients if necessary.
  • the thus obtained granules are dried and optionally spheronised.
  • the alginite and the vericompost is used in a weight ratio of 1 : 10-10:1 preferably 1 :5-5: 1 more preferably 1 :3-3: 1 .
  • the thus obtained granules comprise 1 -40 weight%, preferably 2.5-15 weight%, most preferably 5-10 weight hydrolysate mixtures of alginite and vericompost dried under the granulation process or dried derivatives thereof, 10-20 weight% , preferably 2-15 weight% , most preferably 2- 15 weight% of binder, 60-98 weight%, preferably 75-90 weight% , most preferably 80-90 weight% of solid carrier.
  • the hydrolysate was prepared from only one components e.g. from vericompost, the other extract (alginite) is added during the formulation or in course of hydrolysis.
  • the granules according to the present invention can be prepared that alginite or vericompost or a mixture thereof are milled in an aqueous solution or suspension containing acidic salts preferably to an average particles size between 0.05-10 micrometers, preferably 0.5-5 micrometers, most preferably 0.5-3 micrometers, then the thus obtained suspension applied onto a solid carrier.
  • a solid carrier the above mentioned carriers or a mixture thereof can be used.
  • the suspension is applied on potassium tuff, zeolite, alginite or a mixture thereof.
  • the weight ratio of the solid carrier and the suspension are 10:90-30:70, more preferably 20-80:25-75.
  • the carrier treated with the suspension is mixed with formulation excipients and optionally with further nutrients and then granulated.
  • the hydrolysate was prepared from only one component e.g. from vericompost, the other extract (from alginite) is added during the formulation or in course of hydrolysis.
  • soil conditioner inorganic fertilizer is can be prepared in which the first step is the alkaline hydrolysis of a mixture of alginite and vericompost.
  • alginite and vericompost are added to a dilute potassium hydroxide solution.
  • concentration of the basis solution using KOH is preferably between 1 -10 weight%, more preferably 1 -5 weight% most preferably 1 .5-2.5 weight%.
  • the weight rate of alginite + vericompost/KOH solution in the hydrolysis mixture is 0.1 : 1 -0.5: 1 preferably 0.2-1 :0.4-1 most preferably 0.3-1 :0.4-1 .
  • the hydrolysis is carried out for 2-24 hours, preferably 6-18 hours, more preferably 10- 12 hours between a temperature 20-100°C, preferably between 30-60°C, more preferably between 30-45°C and the mixture is stirred in every few hours.
  • To the thus obtained hydrolysis mixture further nutrients e.g alginite, seaweed powder, and nutrients such as reduced D-fructose are added and the solid particles of this mixture are milled to an average particle size between 0.5-50 micrometers, preferably 1 -10 micrometers, more preferably 1 -5 micrometers.
  • the thus obtained fluid composition can be used as bio-stimulant alone.
  • Hydrolysate obtained in the first step or the bio-stimulant obtained in the second step can be used for the preparation a starting fertilizer according to the present invention so, that the hydrolysate of first step or the bio-stimulant are absorbed with a porous solid carrier, preferably with zeolite.
  • the weight ratio of the carrier and the used fluid is between 95:5-75:25, preferably 90: 10-80:20.
  • the particle size of the used carrier, preferably zeolite is between 0.1 -1 mm, more preferably 0.4- 0.8 mm.
  • the obtained impregnated zeolite is mixed with nutrients e.g. fertilizers, natural plant nutrients having particle size between 0.1 -1 mm, more preferably 0.4- 0.8 mm and binder solution is added to the mixture containing preferably carboxy- methyl-cellulose sodium salt solution.
  • solutions are prepared which can be used for foliage treatment alone or as auxiliary agent for such compositions.
  • These can be prepared such a manner that alginite and vericompost are hydrolyzed in alkaline media.
  • alginite and vericompost is added to a diluted solution of potassium hydroxide.
  • concentration of base using KOH is 1 -10 weight%, preferably 1 -5 weight%, most preferably 1 .5-2.5 weight%.
  • the weight ratio of alginite and vericompost in the hydrolysis mixture preferably alginite+vericompost / KOH solution is 0.01 -1 :0.5-1 , more preferably 0.2: 1 -0,4-1 , most preferably 0.3: 1 -0.4-1 .
  • the ratio of vericompost and alginite is 1 : 10-1 :10, preferably 1 :5-5: 1 , more preferably 1 :3-3: 1 .
  • the hydrolysis is carried out for 2-24 hours, preferably 6-18 hours, more preferably 10-12 hours between a temperature 20-100°C, preferably between 30-60°C, more preferably between 30- 45°C and the mixture is stirred in every few hours.
  • the thus obtained hydrolysate is milled in a colloid mill then sieved in a pressure used for filter with a filter cartridge having screen of 200-300 mesh then the clear filtrate is used for the preparation of different compositions for foliage treatment.
  • two-two weight parts of peat and vericompost having 85 weight% dry matter content and 1 weight part of dried alginite are suspended in 6-7 weight parts of 2.5 weight% KOH solution and kept between 30-40°C for 72 hours.
  • the pH of the reaction mixture is adjusted to between pH of 8.5-9 by adding diluted phosphoric acid (25 weight%) and ammonium-thiosulfate added to the mixture in which contains 12 weight% of nitrogen and 26 weight% of sulfur.
  • the thus obtained mixture is stirred with high shear slurry pump once or twice for three or four hours and kept the temperature of the mixture below 60-65°C.
  • the pH of the mixture is adjusted between 7.2-7.5 with weak acid or base.
  • the thus obtained composition can be used for increase of the efficacy of NPK fertilizers in an amount of 10-25 kg/hectare dose so that in case of the use of PK fertilizer the adjuvant is applied onto the surface of the fertilizer in an a mount of 3- 6 kg/100 kg in a suitable mixer.
  • the adjuvant is applied onto a carrier having high specific surface preferably onto a rhyolite tuff containing zeolite in an amount of 10-30 weight%.
  • the thus obtained mixture is applied alone or mixed with fertilizers to the productivity area in an amount of 50-300 kg.
  • composition so that the hydrolysate of alginite, peat and vericompost are filtered with a vibration sieve with 50 micrometer particle size.
  • ammonium thiosulfate To the thus obtained composition is added ammonium thiosulfate.
  • the weight ratio of the hydrolysate and thiosulfate is 1 : 1 .
  • To 0.9 weight parts of the mixture and 0.1 weight part of the beta-glucoside are mixed. The mixture is milled in colloid mill under particle size of 10 micrometer and sprayed in an amount 10-25 liter/hectare to the production area before or at the same time with spreading of fertilizers.
  • the advantage of the process that the produced press cake which is the side product can also be used because contains hydrolysates of alginte and vericompost.
  • the filter cake remaining the filter can be used for the preparation earthy compost so that peat and/or raw lignite and/or sawdust or any water absorbing organic material are layered in a high of 30-40 cm the onto this basic layer small amount of carbonated lime and slurry of the livestock farms which can be completed with ash and other organic waste which are not dangerous for the nature or the users.
  • the height of this layer is generally 10-20 cm which covered with good quality humus containing soil. These layers are repeated until the height of the prism exceeds the height of 1 .5-1 .6 m.
  • Suspensions which are suitable for soil or plant conditioners can also be prepared according to present invention.
  • the suspensions can be used alone as e.g. microelement concentrate, bio-stimulant, liquid fertilizer, a raw material for liquid fertilizers, as additive for solid fertilizers, as a base for gel compositions and as a component of pesticides.
  • Such suspensions can be prepared according to the present invention so that e.g. to an aqueous solution of inorganic or organic acids and/or salts having acidic pH alginite and/or vericompost are added having an average particle size between 0.5-500 micrometers, preferably 20-300 micrometers, more preferably 40-200 micrometers and the thus obtained mixture is kept between 20-100°C, preferably 30-60°C, more preferably 30-45°C for 2-24 hours, preferably 6-18 hours, most preferably 10-12 hours under stirring.
  • further nutrients and/or formulation excipients are also added to the reaction mixture. Then the reaction mixture is cooled and pH is adjusted to natural if necessary.
  • the particles of the thus obtained suspension are milled using bead mill between of average particle sizes of 0.5-20 micrometers, preferably 1 -10 micrometers, more preferably 0.5-5 micrometers and the obtained suspension is used alone or mixed with nutrients and/or with formulation excipients and formulated.
  • the suspension can be transformed into granules by evaporation of the suspension or applied onto a solid carrier and then e.g. granulated with wet granulation method using binders.
  • the alginite or vericompost or a mixture thereof are subjected of alkaline hydrolysis, but we can proceed that the alginite and /or vericompost is reacted in the presence of other components such as peat, phosphates and water reacted with the alkaline compounds listed above or a mixture thereof, preferably with calcium hydroxide.
  • the reaction is carried out at between 20-100°C, preferably 30-60°C, more preferably 30-45°C for 1/2-8 days, preferably 2-6-days, most preferably 4-5 days.
  • the thus obtained hydrolysis reaction mixture is milled using a slurry pump between average particle sizes of 10-500 micrometers, preferably 20-300 micrometers, more preferably 40-100 micrometers.
  • the hydrolysate was prepared only from one of the components e.g. from vericompost, the other hydrolysate (alginite) has to be added at this time to the composition.
  • the thus obtained composition containing hydrolysates of alginite and vercompost is mixed with further carrier and formulation excipients and optionally with nutrients then homogenized, and the solid particles of the suspension are milled having an average particle size between 0.1 -10 micrometers, preferably 0.5-8 micrometers, more preferably 1 -3 micrometers.
  • composition (A) vericompost, alginite and optionally peat are mixed and hydrolyzed in alkaline media using a method disclosed above.
  • the hydrolysis is carried out using KOH solution of the concentration of 1 -10weight%, preferably 1 .5-5 weight%, more preferably 2-3 weight% in an amount of 1 -10 fold, preferably 1 .5-5 fold, more preferably 2-4 fold weight based on the weight of the components to be hydrolyzed.
  • the pH value of the hydrolysate is adjusted between 7 and 8 with addition of ammonium sulfate preferably.
  • the thus obtained hydrolysate is milled in such a way that the average particle sizes of the solid particles of the suspension are between 0.5-15 micrometers, preferably 1 -10 micrometers, more preferably 1 -5 micrometers.
  • the (B) composition can be prepared with further transformation of composition (A) so that the composition (A) is mixed with further nutrients, optionally with organic or/and inorganic fertilizers and other excipients which increase the effects then the homogenized mixture is milled in colloid mill to get an average particle sizes between 0.5-15 micrometers, preferably 1 -10 micrometers, more preferably 1 -5 micrometers.
  • the suspension can contain preferably alginite, gafsaphosphate, urea, dried seaweed as nutrient and poly-glucosides and diatomaceous oil as enhancer.
  • the rate of the component (A) should be increased
  • the component (B) should be increased.
  • the suspensions mentioned above enhance the effect of fertilizers.
  • the suspensions are formulated together with the fertilizers.
  • the solid carrier can be any of the above mentioned carriers, but preferably rhyolite tuff containing zeolite and/or sedimentary limestone most preferably a mixture thereof can be used.
  • the thus impregnated solid carriers are milled preferably to particles having an average particle size of 40-100 micrometers and optionally mixed with further nutrients, and bind to the surface of fertilizer particles using appropriate binders.
  • compositions of the present invention also useful for the preparation of gel compositions in such a way that we prepare hydrolysate of alginite and voricompost, prepared used any process mentioned above, preferably using alkali media then the thus obtained hydrolysate is mixed with formulation excipients, preferably with surfactants and suspension stabilizers and the thus obtained mixture is adsorbed onto a solid carrier preferably onto potassium trachyte, alginite or zeolite. In the most preferable embodiment it is applied onto potassium trachyte and alginite separately.
  • the ratio of the suspension and the solid carrier are 5- 20:95-80, preferably 10-20:90-80, most preferably 25:85.
  • the average particle size of the carrier is between 15-40 micrometers.
  • the gel composition is prepared with the use of the (A) component which comprising impregnated potassium trachyte and component (B) which comprising impregnated alginite so that in course of the preparation of component (A) the impregnated potassium trachyte is mixed with oils, preferably a mixture of polyethoxylated hydrogenated castor oil, rape oil, peat oil and alkyl-amino bentonite complexes then wet milled into a grainy mass having a particle size 1 micrometer, meanwhile in course of the preparation of component (B) the impregnated alginite is mixed with different oily compounds, preferably with 3,5- dibromo-4-hydroxy-benzonitrileoctylester, polyoxyethylene-nonyl-phenylether, dialkyl-sulfosuccinate, polyoxyethylene, hydrogenated castor oil, fatty acid polymers, sunflower oil and alkyl-amino bentonite complexes and then milled at a particle
  • a plant conditioner and fungicide composition containing bio-stimulant is prepared so that in the first step alginite and vericompost are hydrolyzed in alkaline media using any of processes mentioned above or we can proceed more preferably that to the mixture potassium hydroxide and ammonium hydroxide are added and the obtained mixture is remixed in every hours with a high speed mixer.
  • the weigh rate of the alkaline solution containing potassium hydroxide, sodium hydroxide and optionally ammonium hydroxide is 3-15 fold, preferably 5-10 fold, more preferably 1 -9 fold based on the weight of used alginite and vericompost and the concentration of the alkaline solution is between 2-10 weight% preferably 2-8 weight%.
  • the hydrolysis mixture contains potassium hydroxide and ammonium hydroxide in a weight ratio is 10:1 - 1 : 10, preferably 5: 1 -1 :5, more preferably, 5: 1 .
  • further nutrients e.g. alginite and succinic acid are added to the mixture.
  • the thus obtained hydrolysate can be used as enhancing of efficacy of fertilizers in an amount of 5-10 weight% or further nutrients, pesticides, preferably alginite, pesticide and suspension stabilizer are added to the hydrolysate then the mixture is milled using bead mill to an average particle size between 5-10 micrometers and the thus obtained suspension can be used as a plant conditioner and fungistatic composition containing bio-stimulant.
  • a further embodiment of the present invention is the preparation of sulfur or copper containing plant conditioners, which is carried out by preparation suspension containing hydrolysates essentially as mentioned above which suspension is used alone or applied onto a solid carrier and mixed with ventilated elemental sulfur or micronized copper oxychloride and further excipients e.g. suspension stabilizer, and the particle size is adjusted of the solid particles of the mixture by milling if necessary.
  • preparation suspension containing hydrolysates essentially as mentioned above which suspension is used alone or applied onto a solid carrier and mixed with ventilated elemental sulfur or micronized copper oxychloride and further excipients e.g. suspension stabilizer, and the particle size is adjusted of the solid particles of the mixture by milling if necessary.
  • the preparation of the compositions the mixing, homogenizing, milling and other processes used generally in the chemical industry (e.g. the separation of particle fractions and selection of the fractions for the compositions) can be carried out according to the state of the art with apparatuses known also from the state of the art.
  • the preparation of granules, suspensions and suspoemulsions can be carried out with known methods and apparatus which also parts to state of the art.
  • the selection and optimization of used processes belong to the general knowledge of the person skilled in the art.
  • the extracts of the present invention not only can be applied together with the fertilizers but the can be formulated together. These formulations make possible to achieve a more effective result because the compositions of the present invention having bio-stimulant effect is placed in the same place with the other active ingredients.
  • compositions according to present invention make possible the formulation together pesticides with nutrients and bio-stimulant.
  • compositions can be prepared which besides the nutrition of plants meet the requirements of plant protection.
  • compositions of the present invention result that the passing down hydrolysates or derivatives thereof to the deeper layer of soil than 10-30 cm make advantageous life conditions for useful microorganisms in that depth, which followed by roots.
  • the deeper root system supports a safer water supply and greater root system which supply more carbon for the microorganisms.
  • compositions of the present invention we support more advantageous life conditions for the microorganisms which absorb more carbon dioxide from the atmosphere thus replace the organic fertilizers. Furthermore the more active microorganisms in deeper zone of soil absorb more nitrogen from the atmosphere too, thus ensure the required nutrient content even in the case of reduced of organic nutrients and fertilizer supply.
  • compositions according to the present invention the contradiction of the growing population of the world which has to be supplied by food in such a way that in the same time the cultivation technology has to be changed because of the result of changing weather conditions caused by global climate changing and besides the increasing requirements of authorities and society connected to the environmental protection.
  • these aims can be achieved only if the active zone of soil layer 10-30 cm, where the microbial activity is the most intensive is extended to the deeper zones. It can be achieved only if the life conditions of microorganisms are assured in the deeper layers of soil, which entails the penetration of the roots in deeper layers of soil.
  • This aim can be achieved with the use soil conditioners and soil structure improving compositions according to the present inventions and the organomineral fertilizers and soil improving compositions of the present invention.
  • soil conditioners, and soil improving agrochemicals which increase the amount and activity of nitrogen binding microorganisms in the deeper layers of the soil, furthermore, advantageously modify the base composition of soil.
  • These compositions and actions at the same time increase the CO2 absorbing ability of soil too.
  • This fact we fulfilled the first condition for the penetration of root systems to the deeper nutrient containing layers.
  • the interaction of the root system and microorganisms makes possible to penetration of further microorganisms, which entails further growing of roots leading the increase of absorption of further CO2.
  • the compounds of the present invention were used on the whole production area of the four crop plants (winter wheat, corn, rapeseed, sunflower), in case of 20% growing the amount of absorbed CO2 would be as much as are absorbed by our forests yearly.
  • the process of the present invention we can influence the natural nitrogen absorbing property of soil therefore it is not necessary to install new algae breeding farms, but we can reuse the algae breading sites which were operated 20-25 million years ago by nature by the milling of mine raw alginite to such particle size that their biological effect be prevailed.
  • the compositions of the present invention capable for that because their use results that the field crop production process can be changed easier, safer and causing less environment pollution as it is required by the changes in the natural environment and the society.
  • the present invention is illustrated in examples as follows without the limitation of the scope of the present invention to the examples.
  • a mixture of humic acids is prepared using 1 kg mixture of alginite and vericompost containing the components in a weight rate of 1 :1 .
  • a fluidization reactor 1 kg mixture of milled alginite and vericompost having a particle size of 0.2-0.3 mm, 50 g of soda and 50 g of raddle are added.
  • the conditioning tower air was saturated with water at 80°C and then it was adjusted to 60°C with1000 l/hour flow. This air was used to float the mixture for four hours meanwhile the production of humic acids has finished at a rate of 85%. The thus obtained mixture was used for the preparation of the subsequent composition.
  • the mixture prepared according to the step A/1 was milled in several steps using a bead mill of Dyno KD type to a particle size of 0.5-3.0 then the powder was applied onto the surface of rhyolite tuff containing zeolite having a particle size between 40-100 micrometers, where the amount of the mixture of A/1 is 7.5 weight%.
  • 5 weight% of calcium lignin sulfonate are added and homogenized in a Lodige mixer and the thus obtained homogenate is pressed through holes having 1 mm diameter using a twin-screw extruder of the type APV- LM 50 with 70°C of steam-jacket.
  • E calculated effect of A + B components in %, a+b is application value of components in kg/hectare. If the % of effect of the combined components is less than the calculated (E) value according to formula above, the two compounds inhibit each other (antagonism), if the % of effect equal to the calculated value (E) the two components have additive effects. If the % effect of the combination of the two components is higher than the calculated effect according to formula above (E), the compounds have synergistic effect. (CS. R. Colby: Calculating Synergistic and antagonistic Pesporse of Herbicide Combinations Weed Sci. vol. 15. p 20-22/1962.)
  • Example 3 Microelement concentrate prepared from alqinite and
  • the micro and trace elements evolved from the alginite and reacted with the organic complex forming components of alginite and vericompost and form metal ion complexes and using the ammonium ions of ammonium nitrate forms metal-ammonium alginates.
  • the process from the diatom powders are extracted saturated and unsaturated fatty acids and oleic acids partly saponified and increase the wetting of the composition by the reduction of the surface tension.
  • a suspension prepared according to Example 3/A is milled to a particle size of 1 - 10 micrometers in bead mill and applied in an amount of 1 -20 weight% onto surface of porous solid carrier, preferably rhyolite tuff containing zeolite which was pretreated with 2.5 weight% of 75 weight% of phosphoric acid.
  • the particle size of the thus prepared composition in direct use is between 0.4-1 .2 mm.
  • the thus prepared composition can be used as microelement donor and regulator agent together with other solid fertilizers.
  • xanthan gum 0, 10 weight%
  • Example 4 process for preparation of diatomaceous oil emulsion
  • Example 4/B process for preparation of peat oil emulsion 4/B/1 step process for preparation of peat oil
  • Example 5 preparation of solid granules with acidic extraction of alqinite and vericompost. 5/A mixture of alginite and vericompost extracts with using acidic salts sour baltic peat 10 weight%
  • the mixture is milled in Dynopan bead mill to a particle size of 1 -10 micrometer and let to stay for 2 weeks so that the mixture is remixed 3-4 times a day with a high shear slurry pump.
  • Example 5/B Process for the preparation of granules From the mixture of the Example 5/A 25weight% are applied onto potassium tuff, from which 90 weight% is treated with 7.5 weight percent of diatomaceous earth powder and 2.5 weight% of alginite powder and the thus prepared composition is used for the preparation of granules.
  • composition according to 5/B compared to the untreated control increased the crop of potato of 40-90%.
  • the combination of the composition of 5/B and NPK fertilizer increased the potato crop in an amount of 20-80% per hectares compared parcels on which NPK fertilizer was used alone.
  • Example 6 Process for the preparation of fluid soil conditioners with alkaline extraction of alginite and vericompost.
  • Step 6/1 process for the preparation of alcaline hvdrolvsate of alginite and vericompost
  • Step 6/11 process for the preparation of liquid soil conditioners
  • the demineralized water is measured. Then under continuous stirring propylene-glycol, Ethoxylated phosphated castor oil, Ammonium-lignin-sulfonate, antifoam agent are added then further added gafsa phosphate, zeolite powder, alginite silicon, and the emulsion of the Example 6/1 and diatomaceous emulsion and the neem oil. Then the mixture is thickened by xanthane gum and solid particles are milled to 1 -3 micrometers in bead mill.
  • Biological test :
  • Example 6 We have examined the effects of the suspension of Example 6 on the activities of nitrogen binding bacteria (azobacter) in soil and the cellulose-degrading bacteria in open field in clay-loam soils.
  • the used dose 15 and 30 kg/hectare doses, the layers are in depths of 0-20, 20 ⁇ 10, 40-60 cm at the 90. day after the treatment.
  • the data are added in % on the basis of the control.
  • compositions of the present invention improve the biologic activity of soil in even in the deeper layers.
  • Step 7/A/a Process for preparation of hydrolysate
  • the mixture containing raw particles is milled to having a particle size of 1 -5 micrometers with using colloid mill and the thus obtained mixture is used as bio- stimulant added to different organic and mineral fertilizers.
  • Step 7/B Micro-granulated starter fertilizer Step 7/B/a: preparation of impregnated zeolite powder
  • the bio-stimulant of the Example 7/A is absorbed by rhyolite tuff containing zeolite of the particle size 0.4-0.8 mm in an amount of 15 weight%.
  • Step 7/B/b preparation of starter fertilizer (with using bio-stimulant)
  • Example 8 The use of the filtrate and filter cake which produced during the process for the preparation of bio-stimulant
  • Example 8/a The use of filtered hydrolysate for the compositions of foliage treatment: In course the preparation of soil conditioner of Example 7 that the after the hydrolysis according to step 7/A/a the hydrolysate is milled in a colloid mill then the thus obtained hydrolysate is milled in a colloid mill then sieved in a pressure filter with a filler cartridge having a screen of 200-300 mesh then the clear filtrate is used for /b the preparation of different compositions for foliage treatment.
  • Earthy compost can be prepared so that peat and/or raw lignite and/or sawdust or any water absorbing organic material are layered in a high of 30-40 cm the onto this basic layer small amount of carbonated lime and slurry of the livestock farms which can be completed with ash and other organic waste which are not dangerous for the nature or the users.
  • the height of this layer is generally 10-20 cm which covered with good quality humus containing soil. These layers are repeated until the height of the prism exceeds the height of 1.5-1 .6 m.
  • To keep of the humidity of the site is solved by spraying a suspension made by soaking of filter cake in warm water. Usually 5 kg milled of filter cake are added to 100 I of water.
  • the starting humidity of prism is about 65-75 %.
  • the humidity has to be reduced to 10-20%.
  • a 0.01 -0.1 kg of multi-strain bacteria manure of EM1 and 0.4-0.5 weight% namely 4-5 kg ammonium sulfate fertilizer are also mixed per ton.
  • the thus prepared active carrier can be used for the preparation of organo-mineral fertilizer complexes.
  • Example 9 Liquid plant conditioner and fungistatic composition containing nitrogen and bio-stimulant of the present invention
  • the mixture is milled in Dyno KD bead mill to a particle size of 5-10 micrometers and the thus obtained composition is used for the treatment of plants.
  • Triazol 250 FW 0,8 l/ha
  • a component hydrolysate of voricompost and alginite applied on peat.
  • Component "A” is prepared with hydrolysis of vericompost and alginite. To 100 weight parts of 2.5 weight% of KOH solution, 20 weight parts vericompost and 10 weight parts alginite are added. The addition is carried out under continuous stirring. After completion of adding the mixture is under stirring for 4-6 hours at 35- 40°C. The hydrolysis is completed during 4-6 days which is signed by stabilization of the pH at between 9.0-9.5. The mixture of 5 weight% of ammonium sulfate are added which reduces the pH to e.g. 7.5-8.0. Then 10 weight% of peat powder is added to the mixture and the mixture is milled to a particle size of 1 -5 micrometers using a colloid mill.
  • the thus obtained grain comprises the humates of vericompost, the partally saponified oils from peat, humates and partly degraded celluloses furthermore, the rich mineral element set of alginite with different compounds having bio-stimulant effects.
  • the physical composition of hydrolysate comprises differently dispersed materials, solution, sol and solid phase.
  • component B we prepare a suspension from components which have advantageous effect to the activity of the soil microorganisms.
  • an autoclave equipped cooling and heating system 50weigth% of demineralized is added, then alginite (20 weight%) gafsa phosphate (10 weight%), beta poly-glucoside (5 weight%), urea (5 weight%), dried seaweed (5 weight%), diatomaceous oil (1 weight%) and formulation excipients and the remaining 4 weight% of water are added.
  • the mixture is milled to a particle size between 1 -5 micrometers in a colloid mill.
  • composition according to the present invention is prepared by mixing of Components A and B.
  • the nature of the biological effect can be adjusted with the change of rates of the compositions A and B.
  • the rate of the component (A) should be increased, in the case of the aim is increasing the microbial activity the component (B) should be increased in the composition of the present invention.
  • the test was carried out with a mixture of directly mixed of the two components which was sprayed in liquid form or the mixture was applied onto a porous carrier namely, rhyolite tuff containing zeolite.
  • a porous carrier namely, rhyolite tuff containing zeolite.
  • the B component which has a better enhancing effect on the activity of microorganisms was applied on the surface of charcoal which also can be used as carbon source.
  • the compositions applied onto different carriers are mixed in a weight rate of 1 :1 then the mixture is homogenized, milled to a particle size between 40-100 micrometers then granulated with added binder.
  • granules of components A and B also prepared. The particle sizes of the granules were between 2.5-3.1 mm.
  • composition of the present invention has advantageous effects of the nutrients and the microbial activity which can be seen from the amount of crop.
  • composition which can be used advantageously for conditioning sandy soil
  • Step 11 /A preparation of suspension
  • the components are mixed and milled into particle sizes between 1 -5 micrometers with using wet milling process for 30 minutes.
  • the components A and B are mixed in a rate that the rate of the alginite and potassium trachyte in the composition is 1 :2 and the so prepared gel composition is used for biological tests.
  • Gel compositions were dissolved in the watering solution at planting and the planted plants were watered per plant 0.5 l/plant, 1 .0 l/plant and 2.0 l/plant. We have measured the crop and the rate of downy mildew infection of leaves after the third harvesting.
  • Example 12 Enhancing of the use of organic-mineral fertilizers, NPK- complex fertilizers.
  • a composition of the present invention is prepared so that that the soil conditioner composition of Example 7/A/b and a marketed fertilizer containing a rate of N: P205: K20 of 8:24:24 was used as fall fertilizer fund.
  • the suspension of example 7/A/b was absorbed in an amount of 15 weight% with a mixture of rhyolite tuff containing zeolite and sedimentary limestone in a rate of 3: 1 then the mixture is milled into a particle size between 40- 100 micrometers.
  • the grist was mixed with peat powder in a weight ratio of 1 : 1 and in an amount of 45 weight% is bound to the complex fertilizer by using 5 weight% of binder.
  • the biological efficacy of the NPK fertilizer composition enhanced by organic component of the present invention according to the present invention considerably exceeds the effect which could be a result of nutrient effect.
  • the NPK composition of the present invention acts not only as fertilizer but as plant conditioner.
  • the acidic hydrolysate and ammonium thiosulfate is applied onto the surface of zeolite.
  • the alginite powder also applied onto the surface of zeolite which was previously treated with the alkaline hydrolysate. With this the zeolite treated an acidic solution gets a surface treatment and as a result of the acid-base reaction carrying out on the surface alginit is bound.
  • Example 14 Enhancer for fertilizers containing potassium tuff and potassium fertilizer
  • Example 15 micro-granulated starter fertilizer
  • Example 13 We proceed similarly to the Example 13 except that the powder components are applied onto the particles in two steps. Firstly the mixture of diatomaceous earth with microbilogic fertilizer then the alginite is applied onto the particles.
  • Example 17 Composition containing useful living organisms
  • the solid components are milled and homogenized. Under continuous stirring the hydrolysate of the Example 6 is added. After the completion of homogenization the composition of the Example 3, peat oil is added. If necessary, the product humidified with water then formed, dried and packed.
  • composition weight% Sedimental limestone (particle size 1 -3 mm) 52,5
  • Zeolite and the limestone are mixed with the hydrolysate. After the minerals absorbed the hydrolysate waterglass solution is sprayed on and then the mixture is sieved through a vibration sieve cascade having holes 1 .5-4.2 mm. The product which meets the size range above is dried and packed.
  • Example 20 Composition which regulate the carbon and nitrogen flow advantageously
  • composition A The effect of the composition was examined in sandy loam soil, which has a pH of 5.7, organic material content 1 .2 %, P205 and K20 content 78 and 105 mg/kg soil were respectively.
  • composition B We also examined the effect in clay loam soil which has a pH of 7.3 and organic content 2.9%, P205 138, K20 213 mg/kg soil were (Composition B) results are as follows:
  • composition increased the either the root weight or also the crop in both soils.
  • Example 21 Copper containing plant conditioner composition
  • Example 7 With the use of the soil conditioner composition of Example 7 copper containing foliage fertilizer is prepared.
  • the soil conditioner composition of the Example 7/A/b was used for the preparation of a copper containing wettable powder composition.
  • 15 weight% of diluted soil conditioner of Example 7 was sprayed which was diluted in a weight ratio of 1 :3 onto 25 weight% of dried alginite composition, then 25 weight% of copper oxychloride of particle size between 0.5- 2.0 micrometers, 2 weight% of alkyl sulfonic acid sodium salt humectant, 3 weight% of Dispergielstoff 1494-t (cresol-formaldehyd condensate), 5 weight% of dried seaweeds and 32.5 weight% of kaolin carrier were added.
  • the mixture was homogenized by stirring then it was milled with reflective pin mill type of Alpine 63 to a particle size about 5 micrometers.
  • Example 22 sulphur containing plant conditioner composition
  • suspoemulsion can be used for field cultures and plantations early spring as plant conditioning remover spray or as sulfur fertilizer for sulfur demanding plants.
  • the alginite and vericompost can be used in a weight ratio of 1 :10-10: 1 , preferably 1 :5-5: 1 , more preferably 1 :3-3: 1 .
  • Adjuvant containing ammonium thiosulfate and use thereof Adjuvant containing ammonium thiosulfate and use thereof.
  • the thus obtained composition can be used for enhancing of efficacy of different NPK fertilizers in an dose of 10-15 kg /hectare so that the adjuvant is used in the case of PK that in a rate of 3-6kg/100 kg and the adjuvant is applied in a suitable mixer onto the surface of the fertilizer.
  • the adjuvant composition is applied in an amount of 10-30 weight% onto a carrier having high surface area, preferably rhyolite tuff containing zeolite. From the thus obtained mixture 50-300 kg alone or together with fertilizer are applied to the field.
  • We can use also the composition that the hydrolysates of peat, vericompost and alginit are filtered using vibration sieve to particle size 50 micrometer.
  • ammonium sulfate To this filtrate is added ammonium sulfate.
  • the weight rate of hydrolysate and ammonium thiosulfate is 1 : 1.
  • the mixture is milled to a particle size lower than 10 micrometers and in a dose of 10-25 l/hectare is sprayed to the production area before or at the same time with the application of fertilizes.

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Abstract

La présente invention concerne l'utilisation d'hydrolysat d'alginite et d'hydrolysat de lombricompost ou de ses dérivés en tant qu'engrais et/ou qu'amendement. L'hydrolysat est préparé par traitement basique ou acide d'alginite ou de lombricompost séparément ou d'un mélange de ceux-ci. Le mélange d'hydrolysats ou les mélanges d'hydrolysats séchés peuvent être utilisés comme engrais ou amendement. Selon un mode de réalisation avantageux, les hydrolysats sont absorbés ensemble ou séparément sur un support solide et les particules solides ainsi obtenues sont granulées ou sont transformées en suspension ou suspoémulsion.
PCT/HU2016/050018 2015-05-11 2016-05-10 Engrais contenant de l'alginite et des dérivés de lombricompost WO2016181176A1 (fr)

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HUP1500219A HU231372B1 (hu) 2015-05-11 2015-05-11 Alginit hidrolizátumot és gilisztahumusz hidrolizátumot tartalmazó talaj/vagy növénykondicionáló készítmények
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US20220154072A1 (en) * 2019-01-25 2022-05-19 Hayward Baker, Inc. Method of reducing the swelling capacity of clay-containing soil
CN114560739A (zh) * 2022-03-14 2022-05-31 重庆大学 一种硅藻土基复合有机硅肥及其制备方法和用途

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Publication number Priority date Publication date Assignee Title
US20220154072A1 (en) * 2019-01-25 2022-05-19 Hayward Baker, Inc. Method of reducing the swelling capacity of clay-containing soil
CN114560739A (zh) * 2022-03-14 2022-05-31 重庆大学 一种硅藻土基复合有机硅肥及其制备方法和用途

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