WO2016167960A1 - Filter unit - Google Patents

Filter unit Download PDF

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Publication number
WO2016167960A1
WO2016167960A1 PCT/US2016/024915 US2016024915W WO2016167960A1 WO 2016167960 A1 WO2016167960 A1 WO 2016167960A1 US 2016024915 W US2016024915 W US 2016024915W WO 2016167960 A1 WO2016167960 A1 WO 2016167960A1
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WO
WIPO (PCT)
Prior art keywords
base
filter
angle
layer
stem portion
Prior art date
Application number
PCT/US2016/024915
Other languages
English (en)
French (fr)
Inventor
Mari Nonogi
Tadahiro TAKASHINA
Hideyuki Okada
Makoto Sasaki
Original Assignee
3M Innovative Properties Company
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 3M Innovative Properties Company filed Critical 3M Innovative Properties Company
Publication of WO2016167960A1 publication Critical patent/WO2016167960A1/en

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D39/00—Filtering material for liquid or gaseous fluids
    • A—HUMAN NECESSITIES
    • A62—LIFE-SAVING; FIRE-FIGHTING
    • A62B—DEVICES, APPARATUS OR METHODS FOR LIFE-SAVING
    • A62B23/00—Filters for breathing-protection purposes
    • A62B23/02—Filters for breathing-protection purposes for respirators
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2239/00—Aspects relating to filtering material for liquid or gaseous fluids
    • B01D2239/06—Filter cloth, e.g. knitted, woven non-woven; self-supported material
    • B01D2239/065—More than one layer present in the filtering material

Definitions

  • a filter for a mask is conventionally known.
  • This filter is one type of filter for a gas having a function such as dust removal or filtration.
  • As such a filter there is one having a plurality of types of adsorption functions.
  • JP 2002-12611 OA describes a dust mask filter.
  • the following description is in JP 2002-126110A : "A filter used in a dust mask, wherein the filter is made multilayered by filtration materials with different functions.”
  • JP 2006-346166A describes a filter member.
  • a filter member comprising: a rear end portion positioned on a mask side when installed to a mask; and a tip portion positioned on an opposite side of the rear end portion; wherein the tip portion is formed with a first connection means that separably connects a filter member other than the filter member, the rear end portion is formed with a second connection means that separably connects to the mask, and shapes of the first connection means and the second connection means are in a relationship of being separably connectable to each other.”
  • the filter member described in JP 2006-346166A can be obtained by connecting together a cylindrical canister and a dust filter member; however, because a scavenger and a filtration material are respectively filled in the canister and the dust filter member, pressure loss of the mask once again increases. Therefore, desired is to provide a multifunctional mask filter unit that can realize both suppression of pressure loss and improvement of filtering efficiency.
  • multifunctional signifies the filter unit having a plurality of types of adsorption functions.
  • a filter unit is a filter unit for a mask that covers at least a portion of the face of a person, provided with: a charged filter that has an inflow surface through which air inflows, an outflow surface through which the air outflows, and a side surface that extends from the inflow surface to the outflow surface; wherein the charged filter is provided with a base layer, which is formed by a single sheet layer or formed by consecutively stacking a plurality of sheet layers, and an additional function layer that is different from the base layer and adjacent to the base layer; each sheet layer is provided with a base and a plurality of solid protrusions that extends from a surface of the base, the protrusions having a stem portion that has a root-side side surface and a tip-side side surface; the additional function layer is provided with a base; a first angle formed between the base of the sheet layer and the root-side side surface of the stem portion of the sheet layer is present; a second angle that is an angle formed between the tip-
  • a corner of a flow path of a gas is ensured to be wide on a root side and a tip side, respectively, of the stem portion of the protrusion, in the flow path, which is formed by two adjacent protrusions, the gas comes to travel not only near a center thereof but also near the corner, facilitating the gas flowing in the filter.
  • the protrusion is solid, a layer structure of the filter can be stabilized and a flow path between the layers can continue to be maintained. Therefore, suppression of pressure loss and improvement of filtering efficiency can be realized.
  • filtering efficiency in the additional function layer also improves.
  • FIG. 1 is a perspective view illustrating an example of a mask provided with a filter unit according to an embodiment.
  • FIG. 2 is a perspective view of a sheet (layer) used in the filter unit according to the embodiment.
  • FIGs. 3 A and 3B are side views illustrating examples of a protrusion on the sheet.
  • FIG. 4 is a diagram for describing a projection of the protrusion onto a virtual surface.
  • FIG. 5 is a diagram illustrating several examples of a projection image of the protrusion.
  • FIG. 6 is a diagram illustrating several examples of the projection image of the protrusion.
  • FIG. 7 is a diagram for describing a relationship between a shape of the protrusion and filtering efficiency and pressure loss.
  • FIG. 8 is a diagram illustrating several examples of the projection image of the protrusion.
  • FIG. 9 is a diagram illustrating several examples of the projection image of the protrusion.
  • FIG. 10 is a diagram illustrating several examples of the projection image of the protrusion.
  • FIG. 11 is a diagram illustrating several examples of the projection image of the protrusion.
  • FIG. 12 is a diagram illustrating several examples of the projection image of the protrusion.
  • FIG. 13 is a diagram illustrating an example of the sheet.
  • FIG. 14 is a diagram illustrating an example of the sheet.
  • FIG. 15 is a diagram illustrating an example of stacking.
  • FIG. 16 is a diagram illustrating an example of stacking.
  • FIG. 17 is a diagram illustrating an example of stacking.
  • FIG. 18 is a diagram illustrating an example of stacking.
  • FIG. 19 is a perspective view and a partial enlarged view of a filter unit according to the embodiment.
  • FIG. 20 is a perspective view and a partial enlarged view of a filter unit according to the embodiment.
  • FIG. 21 is a perspective view of a filter unit according to the embodiment.
  • FIG. 22 is a perspective view illustrating another example of a filter unit according to the embodiment.
  • FIG. 23 is a perspective view illustrating another example of a mask provided with the filter unit according to the embodiment.
  • FIG. 24 is an enlarged view of a filter housing portion illustrated in FIG. 23.
  • FIG. 25 is a table indicating results of examples and comparative examples.
  • a structure of a filter unit according to the embodiment is described.
  • a "filter unit” in the present specification is an article having at least a function of removing a fine particle (a minute solid or foreign matter) mixed in a gas (for example, air).
  • a gas for example, air
  • the fine particle dust, dirt, pollen, and the like can be mentioned; however, an object to be removed by the filter unit is not limited thereto, and the filter unit may remove any fine particle in the gas.
  • the filter unit in the present embodiment further has a function of removing foreign matter different from the fine particle (for example, some sort of toxic gas, unpleasant odor, or the like).
  • the filter unit is used for a mask.
  • a “mask” in the present specification is an article or a device that covers at least a portion of the face of a person (particularly, the nose and the mouth of the person) and is more specifically an article or a device provided with a portion that covers at least a portion of face of the person.
  • FIG. 1 A mask 200 is described in detail below, but this mask 200 is provided with a filter unit lOOC. Air taken into the mask 200 for respiration of a user is inhaled by the user after passing through the filter unit lOOC.
  • filter unit for a mask and “filter unit is used for a mask” signify that the filter unit relates to use of the mask in some aspect. More specifically, they signify that the filter unit is used as at least a portion of a function of the mask or to assist the function of the mask.
  • a “mask provided with a filter unit” is a mask having a structure where air to be inhaled by a person (wearer of the mask) passes through the filter unit.
  • a mask where the filter unit is provided in a portion covering at least a portion (nose and mouth) of the face of the person but also a mask where the filter unit is provided to a component different from a component covering at least a portion (nose and mouth) of the face of the person (for example, respiration protection equipment with an electric fan) corresponds to the "mask" in the present specification.
  • the filter unit is provided with at least a charged filter. First, this charged filter is described in detail.
  • the charged filter is provided with a plurality of layers. At least a portion of the plurality of layers is formed by a sheet 10 illustrated in FIG. 2.
  • the sheet 10 is a thin, platelike member and is provided with a base 11 and a plurality of solid protrusions 20 disposed on the base 11.
  • a "protrusion" in the present specification is a structure extending outward from one surface of the base 11.
  • the surface on which the protrusion 20 is present is defined as a front surface of the layer, the sheet 10, or the base 11 and a surface on which the protrusion 20 is not present is defined as a back surface of the layer, the sheet 10, or the base 11.
  • Dimensions of the sheet 10 are not limited and may be set based on any standard, such as a manufacturing process of the charged filter, dimensions of the filter unit, or dimensions of the charged filter.
  • a length and a width of the sheet 10 can take on various values.
  • the length and the width of the sheet 10 can take on values of various ranges, from several centimeters to several decameters.
  • a thickness of the sheet 10 is set in consideration of, for example, both a dust removal effect (dust collection effect) and ensuring a flow path of the gas, but this thickness is also not limited.
  • the thickness of the sheet 10 is a distance from the back surface of the base 11 to the highest point of the protrusion 20.
  • a lower limit of the thickness of the sheet 10 may be 60 ⁇ , 100 ⁇ , or 140 ⁇ , and an upper limit thereof may be 2,000 ⁇ , 900 ⁇ , or 600 ⁇ .
  • the thickness of the base 11 and a height of the protrusion 20 can be suitably set within a range of the thickness of the sheet 10. In a certain aspect, the height of the protrusion 20 can be made greater than the thickness of the base 11.
  • the protrusion 20 of the present embodiment is provided with at least a stem portion 21 extending from the front surface of the base 11.
  • the protrusion 20 may be provided with a cap portion 22 formed on a tip of this stem portion 21, and in this situation, the protrusion 20 exhibits a mushroom shape overall.
  • a shape of the protrusion 20 is not limited to the example of FIG. 3, and as described below, various shapes are conceivable.
  • An upper surface of the protrusion 20 (that is, an upper surface of the stem portion 21 or the cap portion 22) may be flat or wavy (that is, jagged).
  • the thickness of the base 11, the height of the protrusion 20, a height of the stem portion 21, a maximum width of a bottom of the stem portion 21, a width of the tip of the stem portion 21, a maximum width of the cap portion 22, and a protrusion amount of the cap portion 22 from the stem portion 21 may all be freely set.
  • a density of the protrusions 20 on the base 11 is also not limited. For example, this density may be about 60 to about 1,550 per square centimeter, about 125 to 690 per square centimeter, or about 200 to about 500 per square centimeter.
  • a material of the sheet 10 is a thermoplastic resin, and a thermoplastic resin suited to extrusion molding can be used.
  • the thermoplastic resin includes a polyester such as
  • a polypropylene resin (PP), a mixture of a polypropylene resin (PP) and a polyethylene resin (PE), and an ethylene-vinyl acetate copolymer (EVA) resin can be mentioned as specific examples.
  • the PP and the PE may be mixed at a weight ratio of about 95:5 to 30:70.
  • the PP may be a homopolymer or a copolymer.
  • LDPE low-density polyethylene
  • HDPE high-density polyethylene
  • LLDPE linear low-density polyethylene
  • Materials of the base 11 and the protrusion 20 in the sheet 10 may be the same material or different materials.
  • One is a method described in JP 2005-514976U.
  • this method first, by extruding the thermoplastic resin from an extrusion die having an opening cut by electrical discharge machining, a strip is formed where a plurality of rail-shaped ribs having a cross-sectional shape of the protrusion is lined up on a base sheet. Next, this strip is pulled by a roller in a cooling tank filled with a cooling liquid such as water. Next, by making an incision in a width direction in each rib at a plurality of positions separated from each other along a longitudinal direction of the rib, for each rib, a plurality of portions corresponding to a thickness of the protrusion is formed.
  • the base sheet of the strip is stretched by a predetermined stretch ratio. Specifically, the base sheet is stretched along the longitudinal direction of the rib between a first pair of nip rollers and a second pair of nip rollers driven at mutually different surface speeds. In this process, the base sheet may be stabilized by cooling one of the second pair of nip rollers, which is positioned downstream, while heating the base sheet by heating one of the first pair of nip rollers, which is positioned upstream.
  • a space arises between a plurality of portions of the rib, and this portion becomes the protrusion 20.
  • the other example is a method described in JP 2008-532699U.
  • a band-shaped base material is formed where a plurality of columnar bodies forming a plurality of original shapes of the protrusion is lined up on the front surface.
  • the protrusion having the cap portion can be formed by smashing a tip portion of each columnar body by a calender roller while heated. By this process, one sheet 10 is obtained.
  • An electret treatment is applied to the sheet 10.
  • the layer applied with the electret treatment functions as a charged layer, and the charged filter is obtained.
  • the electret treatment is a treatment that charges the sheet 10 by a corona discharge, heating and cooling, spraying charged particles, or the like. By charging the sheet 10, an effect of dust removal or filtration of each layer can be increased.
  • FIG. 4 are projection images of various protrusions 20; in these diagrams, to facilitate description, the projection image is labeled with the same reference signs as those of the protrusion.
  • Both a first outer edge 23 and a second outer edge 24 of the projection image illustrated in FIG. 5, 6, and 8 to 12 are an outer edge corresponding to a side surface of the stem portion 21.
  • a portion that includes a connection portion with the base 1 1 is referred to as a "root-side side surface” and a portion that includes the tip of the stem portion 21 is referred to as a "tip-side side surface.”
  • a reference line L is illustrated that indicates an extension direction of the stem portion 21. This reference line L is a line that connects midpoints between the first outer edge 23 and the second outer edge 24.
  • the base 11 on a lower side corresponds to a base of a first layer
  • the stem portion 21 corresponds to a protrusion of the first layer
  • the base 11 on an upper side illustrated for convenience corresponds to a base of a second layer. Note that in each pattern, an additional function layer that is described below can be positioned in place of the base 11 on the upper side.
  • the protrusion 20 is not provided with the cap portion 22 and is formed from only the stem portion 21.
  • the stem portion 21 exhibits a straight columnar shape. Both the first edge 23 and the second edge 24 do not bend or curve and are a straight line. It can also be said that the first outer edge 23 and the second outer edge 24 extend along the reference line L.
  • An angle ⁇ formed between the base 1 1 and the root-side side surface of the stem portion 21 is 90°, and an angle ⁇ formed between the tip-side side surface of the stem portion 21 and the base 1 1 of the adjacent layer is also 90°. Note here that the angles ⁇ , ⁇ in the present specification are angles corresponding to a shape of the flow path of the gas (space) and not angles relating to the solid stem portion 21 itself.
  • the angle ⁇ corresponds to a first angle that is described below, and the angle ⁇ corresponds to a second angle that is described below.
  • An individual "flow path" in the present specification is a space formed between two adjacent protrusions 20.
  • the angles ⁇ , ⁇ are measured in the projection image of the protrusion 20.
  • the gas By setting the angles ⁇ , ⁇ to be right angles, the gas also travels near each corner; therefore, the gas flowing in the flow path is facilitated, which in turn enables suppression of pressure loss of the charged filter.
  • the minute particle in the gas can be collected even in the corner of the flow path or a portion near this corner.
  • the angles ⁇ , ⁇ are crucial elements that affect a flowability of the gas and a value of pressure loss and can also affect filtering efficiency.
  • Pattern 2 illustrates the protrusion 20 with the cap portion 22 provided on the tip of the stem portion 21 illustrated in pattern 1.
  • the angle ⁇ indicating a shape of the corner of the flow path is the angle formed between the tip-side side surface of the stem portion 21 and the base 11 of the adjacent layer and is therefore also 90° in this pattern 2. In this manner, the presence of the cap portion 22 does not affect a determination of the angle ⁇ .
  • description is given based on an aspect of the protrusion 20 where the cap portion 22 is not had.
  • the stem portion 21 exhibits a tapered shape that tapers toward the tip. Both the first edge 23 and the second edge 24 do not bend or curve and are a straight line.
  • the angle ⁇ formed between the base 11 and the root-side side surface of the stem portion 21 is obtuse.
  • the angle ⁇ formed between the tip-side side surface of the stem portion 21 and the base 11 of the adjacent layer is acute but is set to be 45° or more.
  • the stem portion 21 exhibits a tapered shape that tapers toward the bottom. Both the first edge 23 and the second edge 24 do not bend or curve and are a straight line.
  • the angle ⁇ formed between the base 11 and the root-side side surface of the stem portion 21 is acute but set to be 45° or more. Meanwhile, the angle ⁇ formed between the tip-side side surface of the stem portion 21 and the base 11 of the adjacent layer is obtuse. By setting the angle ⁇ to be obtuse, travel of the gas near the corner corresponding to this angle ⁇ is further facilitated. Moreover, even if the angle ⁇ is acute, if this angle is 45° or more, no less than a certain amount of the gas travels even near the corner corresponding to the angle ⁇ . Focusing on the shape of the flow path, because pattern 4 is substantially the same as pattern 3, similar to pattern 3, suppression of pressure loss and improvement of filtering efficiency can be realized.
  • the stem portion 21 exhibits a tapered shape that tapers toward the tip. With both the first outer edge 23 and the second outer edge 24, an entirety thereof curves so as to be convex toward an inner portion of the projection image.
  • the angle ⁇ formed between the base 11 and the root-side side surface of the stem portion 21 (angle formed between the base 11 and an auxiliary line M) is obtuse. Meanwhile, the angle ⁇ formed between the tip-side side surface of the stem portion 21 and the base 11 of the adjacent layer is 90°.
  • the stem portion 21 exhibits a tapered shape that tapers toward the bottom. With both the first outer edge 23 and the second outer edge 24, the entirety thereof curves so as to be convex toward the inner portion of the projection image.
  • the angle ⁇ formed between the base 11 and the root-side side surface of the stem portion 21 is 90°.
  • the angle ⁇ formed between the tip-side side surface of the stem portion 21 and the base 11 of the adjacent layer is obtuse.
  • the stem portion 21 exhibits a shape where a central portion in the extension direction thereof is tapered. With both the first outer edge 23 and the second outer edge 24, the entirety thereof curves so as to be convex toward the inner portion of the projection image.
  • the angle ⁇ formed between the base 1 1 and the root-side side surface of the stem portion 21 is obtuse.
  • the angle ⁇ formed between the tip-side side surface of the stem portion 21 and the base 1 1 of the adjacent layer is also obtuse.
  • travel of the gas is further facilitated near all corners of the flow path; therefore, pressure loss of the charged filter can be further suppressed and more of the minute particle in the gas can be collected.
  • the stem portion 21 exhibits a shape where the central portion in the extension direction is tapered.
  • the entirety of the first outer edge 23 is formed by straight lines and is bent so as to be convex toward the inner portion of the projection image.
  • the second outer edge 24 is also of a shape similar to that of the first outer edge 23.
  • the angle ⁇ formed between the base 11 and the root-side side surface of the stem portion 21 is obtuse.
  • the angle ⁇ formed between the tip-side side surface of the stem portion 21 and the base 11 of the adjacent layer is also obtuse.
  • Flow of the gas is smoother in a situation where the angle of the corner of the flow path is a right angle rather than acute and further smoother in a situation where this angle is obtuse rather than a right angle.
  • the angles of the corners of the flow path are all a right angle (see patterns 1, 2)
  • the gas also travels near each corner, flow of the gas in the flow path is facilitated.
  • the gas flows favorably; therefore, pressure loss can be suppressed to an extent equivalent to or greater than the situation where the angles of the corners of the flow path are all a right angle.
  • FIG. 7 is a diagram that illustrates a cross-sectional shape of a flow path 90 of the gas formed by two adjacent protrusions 20 for these three patterns. It is assumed that an area of the cross-sectional shape of the flow path 90 is the same in these three patterns. At this time, a length of a line segment (frame) F demarcating the cross-sectional shape is longer in pattern 3 than in pattern 1 and longer in pattern 7 than in pattern 3. Because the length of this line segment F can be said to represent a surface area when a depth of the filter is also taken into consideration, it can be said that the longer the line segment F, the lesser pressure loss.
  • pattern 3 while the angle of a portion of the corners of the flow path is acute, because the line segment F is longer than in pattern 1, it can be said that pressure loss due to the filter surface area is lower than that of pattern 1. In this manner, a high and low of pressure loss between pattern 1 and pattern 3 depends on a balance between the angle of the corner of the flow path 90 and the length of the line segment F (surface area).
  • pattern 7 because the angles of the corners of the flow path 90 are all obtuse and the line segment F is longer than in patterns 1, 3, it can be said that pressure loss is lower than in patterns 1, 3.
  • the shape of the stem portion 21 is not limited if, with the angle formed between the base 11 and the root-side side surface of the stem portion 21 and the angle formed between the tip-side side surface of the stem portion 21 and the base 11 of the adjacent layer, one is set to 90° or more and less than 180° and the other is set to 45° or more and less than 180°.
  • Various shapes of the stem portion 21 are illustrated below.
  • the stem portion 21 exhibits a shape where the central portion in the extension direction is tapered at a plurality of locations. Both the first outer edge 23 and the second outer edge 24 curve so as to be convex toward the inner portion of the projection image at two locations. Defining these two locations as concave portions, a region surrounded by these concave portions is convex toward an outer portion of the projection image. Therefore, in this example, only a portion of the first outer edge 23 and only a portion of the second outer edge 24 are convex toward an inner side of the projection image.
  • the angle ⁇ formed between the base 11 and the root-side side surface of the stem portion 21 (angle formed between the base 11 and the auxiliary line M) is 90°. Moreover, the angle ⁇ formed between the tip-side side surface of the stem portion 21 and the base 11 of the adjacent layer (angle between the auxiliary line N and the adjacent base 11) is also 90°.
  • a root side of the stem portion 21 is a straight columnar shape, and a remaining portion of the stem portion 21 exhibits a tapered shape that tapers toward the tip.
  • a root side of the first outer edge 23 and the second outer edge 24 is a straight line and can also be said to extend along the reference line L.
  • a tip side of the first outer edge 23 and the second outer edge 24 curves so as to be convex toward the outer portion of the projection image.
  • the angle ⁇ formed between the base 11 and the root-side side surface of the stem portion 21 is 90°.
  • the angle ⁇ formed between the tip-side side surface of the stem portion 21 and the base 11 of the adjacent layer is acute at 45° or more.
  • the stem portion 21 exhibits a shape where the central portion in the extension direction thereof is tapered. With both the first outer edge 23 and the second outer edge 24, the central portion thereof curves so as to be convex toward the inner portion of the projection image.
  • the angle ⁇ formed between the base 11 and the root-side side surface of the stem portion 21 (angle formed between the base 11 and the auxiliary line M) is 90°.
  • the angle ⁇ formed between the tip-side side surface of the stem portion 21 and the base 11 of the adjacent layer is also 90°.
  • the stem portion 21 exhibits a shape where the central portion in the extension direction is tapered at a plurality of locations.
  • Both the first outer edge 23 and the second outer edge 24 are formed by straight lines and are bent so as to be convex toward the inner portion of the projection image at two locations. Defining these two locations as concave portions, the region surrounded by these concave portions is convex toward the outer portion of the projection image. Therefore, in this example, only a portion of the first outer edge 23 and only a portion of the second outer edge 24 are convex toward the inner side of the projection image.
  • the angle ⁇ formed between the base 11 and the root-side side surface of the stem portion 21 is obtuse. Moreover, the angle ⁇ formed between the tip-side side surface of the stem portion 21 and the base 11 of the adjacent layer is also obtuse.
  • Patterns 13 to 15 are examples where the projection image of the stem portion 21 is not linearly symmetrical.
  • the stem portion 21 exhibits a tapered shape that tapers toward the bottom.
  • the first outer edge 23 is neither bent nor curved and is a straight line.
  • the second outer edge 24 the entirety thereof curves so as to be convex toward the inner portion of the projection image.
  • An angle 0 a formed between the base 11 and the root side of the first outer edge 23 (root-side side surface of the stem portion 21) is 90°.
  • An angle 9b formed between the base 11 and the root side of the second outer edge 24 (root-side side surface of the stem portion 21) is also 90°.
  • An angle (p a formed between the tip side of the first outer edge 23 (tip- side side surface of the stem portion 21) and the base 11 of the adjacent layer is also 90°.
  • An angle (pb formed between the tip side of the second outer edge 24 (tip-side side surface of the stem portion 21) and the base 11 of the adjacent layer is obtuse.
  • the stem portion 21 exhibits a tapered shape that tapers toward the tip.
  • Both the first edge 23 and the second edge 24 do not bend or curve and are a straight line.
  • the angle 0 a formed between the base 11 and the root side of the first outer edge 23 (root-side side surface of the stem portion 21) is obtuse.
  • the angle 0b formed between the base 1 1 and the root side of the second outer edge 24 (root-side side surface of the stem portion 21) is 90°.
  • the angle (p a formed between the tip side of the first outer edge 23 (tip-side side surface of the stem portion 21) and the base 1 1 of the adjacent layer is acute at 45° or more.
  • the angle (pb formed between the tip side of the second outer edge 24 (tip-side side surface of the stem portion 21) and the base 11 of the adjacent layer is 90°.
  • the stem portion 21 exhibits a tapered shape that tapers toward the tip.
  • the angle 0 a formed between the base 11 and the root side of the first outer edge 23 (root-side side surface of the stem portion 21) (angle between the base 11 and an auxiliary line M a ) is obtuse.
  • the angle 0b formed between the base 11 and the root side of the second outer edge 24 (root-side side surface of the stem portion 21) (angle between the base 1 1 and an auxiliary line Mb) is 90°.
  • the angle (p a formed between the tip side of the first outer edge 23 (tip-side side surface of the stem portion 21) and the base 1 1 of the adjacent layer is also 90°.
  • the angle (pb formed between the tip side of the second outer edge 24 (tip-side side surface of the stem portion 21) and the base 11 of the adjacent layer is acute at 45° or more.
  • the stem portion 21 may include a branch 25 in an
  • the branch 25 is formed on both the first edge portion 23 and the second edge portion 24, but a position and number of branches 25 are not limited to this example.
  • the angle ⁇ formed between the base 11 and the root-side side surface of the stem portion 21 is 90°, and the angle ⁇ formed between the tip-side side surface of the stem portion 21 and the base 11 of the adjacent layer is also 90°.
  • the stem portion 21 when viewed in the projection image, is bifurcated and as a result is of an aspect where a gap 26 is present.
  • the root side may be bifurcated, the tip side may be bifurcated, or both sides may be bifurcated.
  • the gas can also flow in the gap 26, "flow path" defined as above in the present specification is a concept that does not include the gap 26.
  • the stem portion 21 exhibits a tapered shape that tapers toward the tip. With both the first outer edge 23 and the second outer edge 24, the entirety thereof curves so as to be convex toward the inner portion of the projection image.
  • the angle ⁇ formed between the base 11 and the root-side side surface of the stem portion 21 (angle formed between the base 11 and an auxiliary line M) is obtuse.
  • the angle ⁇ formed between the tip-side side surface of the stem portion 21 and the base 11 of the adjacent layer is 90°.
  • the root side of the stem portion 21 is a straight columnar shape, and a remaining portion of the stem portion 21 exhibits a tapered shape that tapers toward the tip.
  • the root side of the first outer edge 23 and the second outer edge 24 is a straight line and can also be said to extend along the reference line L.
  • the tip side of the first outer edge 23 and the second outer edge 24 curves so as to be convex toward the outer portion of the projection image.
  • the angle ⁇ formed between the base 11 and the root-side side surface of the stem portion 21 is 90°.
  • the angle ⁇ formed between the tip-side side surface of the stem portion 21 and the base 1 1 of the adjacent layer is acute at 45° or more.
  • the stem portion 21 exhibits a straight columnar shape. Both the first edge 23 and the second edge 24 do not bend or curve and are a straight line. Alternatively, it can also be said that the first outer edge 23 and the second outer edge 24 extend along the reference line L.
  • the angle ⁇ formed between the base 1 1 and the root-side side surface of the stem portion 21 is 90°, and the angle ⁇ formed between the tip-side side surface of the stem portion 21 and the base 1 1 of the adjacent layer is also 90°.
  • the stem portion 21 exhibits a shape where the central portion in the extension direction thereof is tapered.
  • the gap 26 is present on both the root side and the tip side.
  • the entirety thereof curves so as to be convex toward the inner portion of the projection image.
  • the angle ⁇ formed between the base 11 and the root-side side surface of the stem portion 21 (angle formed between the base 11 and an auxiliary line M) is obtuse.
  • the angle ⁇ formed between the tip-side side surface of the stem portion 21 and the base 11 of the adjacent layer is also obtuse.
  • Patterns 21 to 23 are aspects formed with one or more holes 27 that penetrate in a direction orthogonal to the extension direction of the stem portion 21 (such a hole is simply referred to as a "through hole” hereinbelow).
  • a position and dimensions of an individual through hole 27 is not limited. While the gas can also flow in the through hole 27, "flow path" defined as above in the present specification is a concept that does not include the through hole 27.
  • the stem portion 21 exhibits a tapered shape that tapers toward the bottom.
  • Both the first edge 23 and the second edge 24 do not bend or curve and are a straight line.
  • the angle ⁇ formed between the base 11 and the root-side side surface of the stem portion 21 is acute but set to be 45° or more. Meanwhile, the angle ⁇ formed between the tip-side side surface of the stem portion 21 and the base 11 of the adjacent layer is obtuse.
  • the stem portion 21 exhibits a tapered shape that tapers toward the tip. With both the first outer edge 23 and the second outer edge 24, the entirety thereof curves so as to be convex toward the inner portion of the projection image.
  • the angle ⁇ formed between the base 11 and the root-side side surface of the stem portion 21 (angle formed between the base 11 and an auxiliary line M) is obtuse.
  • the angle ⁇ formed between the tip-side side surface of the stem portion 21 and the base 11 of the adjacent layer is 90°.
  • the stem portion 21 exhibits a tapered shape that tapers toward the tip and is not linearly symmetrical.
  • the entirety thereof curves so as to be convex toward the outer side of the projection image.
  • the second outer edge 24 is neither bent nor curved and is a straight line.
  • the angle 0 a formed between the base 11 and the root side of the first outer edge 23 (root-side side surface of the stem portion 21) (angle between the base 11 and an auxiliary line M) is 90°.
  • the angle 0b formed between the base 11 and the root side of the second outer edge 24 (root-side side surface of the stem portion 21) is also 90°.
  • the angle (p a formed between the tip side of the first outer edge 23 (tip-side side surface of the stem portion 21) and the base 11 of the adjacent layer is acute at 45° or more.
  • the angle (pb formed between the tip side of the second outer edge 24 (tip-side side surface of the stem portion 21) and the base 11 of the adjacent layer is 90°.
  • the stem portion 21 exhibits a tapered shape that tapers toward the tip. Both the first edge 23 and the second edge 24 do not bend or curve and are a straight line. In this example, a large number of minute holes 28 is formed in the stem portion 21, and the stem portion 21 is therefore porous. While the gas can also flow in the hole 28, "flow path" defined as above in the present specification is a concept that does not include the hole 28.
  • the angle ⁇ formed between the base 11 and the root-side side surface of the stem portion 21 is obtuse. Meanwhile, the angle ⁇ formed between the tip-side side surface of the stem portion 21 and the base 11 of the adjacent layer is acute but is set to be 45° or more.
  • the stem portion 21 exhibits an oblique columnar shape. Both the first edge 23 and the second edge 24 do not bend or curve and are a straight line. Alternatively, similarly to pattern 1, it can also be said that the first outer edge 23 and the second outer edge 24 extend along the reference line L.
  • the angle 0 a formed between the base 11 and the root side of the first outer edge 23 (root-side side surface of the stem portion 21) is obtuse.
  • the angle 0b formed between the base 11 and the root side of the second outer edge 24 is acute at 45° or more.
  • the angle (p a formed between the tip side of the first outer edge 23 (tip-side side surface of the stem portion 21) and the base 11 of the adjacent layer is acute at 45° or more.
  • the angle q3 ⁇ 4 formed between the tip side of the second outer edge 24 (tip-side side surface of the stem portion 21) and the base 11 of the adjacent layer is obtuse.
  • the stem portion 21 exhibits a columnar shape curved in an arc shape.
  • the first outer edge 23 and the second outer edge 24 extend along the reference line L.
  • the angle ⁇ formed between the base 11 and the root-side side surface of the stem portion 21 is 90°.
  • the angle (p a formed between the tip side of the first outer edge 23 (tip-side side surface of the stem portion 21) and the base 11 of the adjacent layer is acute but set to be 45° or more.
  • the angle q3 ⁇ 4 formed between an outer edge corresponding to the upper surface of the stem portion 21 and the base 11 of the adjacent layer is acute at 45° or more.
  • the stem portion 21 exhibits a columnar shape curved in a J shape.
  • the angle ⁇ formed between the base 11 and the root-side side surface of the stem portion 21 is 90°.
  • the angle ⁇ formed between the side surface of the stem portion 21 and the base 11 of the adjacent layer is acute but set to be 45° or more.
  • the stem portion 21 exhibits a columnar shape where a central vicinity is curved.
  • the first outer edge 23 and the second outer edge 24 extend along the reference line L.
  • the angle ⁇ formed between the base 11 and the root-side side surface of the stem portion 21 is 90°, and the angle ⁇ formed between the tip-side side surface of the stem portion 21 and the base 1 1 of the adjacent layer is also 90°.
  • the shapes of the protrusion 20 and the stem portion 21 are not limited if, with the angle formed between the base 11 and the root-side side surface of the stem portion 21 and the angle formed between the tip-side side surface of the stem portion 21 and the base 11 of the adjacent layer, one angle A p is set to 90° or more and less than 180° and the other angle A q is set to 45° or more and less than 180°.
  • a lower limit of the angle A P may be 100°, 110°, 120°, 130°, 140°, 150°, 160°, or 170°, and an upper limit thereof may be 100°, 110°, 120°, 130°, 140°, 150°, 160°, or 170°.
  • a lower limit of the angle A q may be 50°, 60°, 70°, 80°, 90°, 100°, 110°, 120°, 130°, 140°, 150°, 160°, or 170°
  • an upper limit thereof may be 50°, 60°, 70°, 80°, 90°, 100°, 110°, 120°, 130°, 140°, 150°, 160°, or 170°.
  • a shape of the upper surface of the protrusion 20 that is substantially parallel to the base 1 1 may be freely established.
  • the shape of this upper surface may be a circle, an ellipse, a rectangle, or a start shape.
  • the shape of this upper surface may be any polygon, such as a triangle or a hexagon, or a more complex shape.
  • a specific disposition aspect of the plurality of protrusions 20 on the base 1 1 is not limited.
  • the protrusions 20 may be disposed in a grid, in a zigzag pattern, or randomly.
  • the disposition aspect of the protrusions 20 is not limited thereto and may be any pattern as long as the flow path of the gas can be formed.
  • the protrusions 20 may be disposed on the base 11 evenly or unevenly.
  • a protrusion region where the protrusions 20 are present and a flat region where the protrusions 20 are not present may coexist.
  • Shapes of the protrusion region and the flat region are not limited and may be freely established (for example, a rectangle, a circle, an ellipse, a star shape, any polygon, a stripe shape, a grid, a wave shape, or a combination of such a plurality of types of shapes).
  • the protrusion region, where the sheet 10 is affixed, and the flat region, where the sheet 10 is not affixed may be formed. Because the gas flows smoothly in the flat region, pressure loss of the charged filter can be further suppressed overall.
  • a region where the protrusions 20 are dense (dense region) and a region where the protrusions 20 are sparse (sparse region) may coexist.
  • Shapes of the dense region and the sparse region are not limited and may be freely established (for example, a rectangle, a circle, an ellipse, a star shape, any polygon, a stripe shape, a grid, a wave shape, or a combination of such a plurality of types of shapes).
  • the dense region and the sparse region may be formed by using a thin plate-like member different from the sheet 10 as the base material and affixing the sheet 10 where the protrusions 20 are dense on a portion of this base material by adhesion or welding and affixing the sheet 10 where the protrusions 20 are sparse on a remaining portion by a similar method. Because the gas flows more smoothly in the sparse region than in the dense region, pressure loss of the charged filter can be further suppressed overall.
  • a plurality of types of protrusions may be provided on one base 11.
  • protrusions of different dimensions may be provided, protrusions of different shapes (patterns) may be provided, or protrusions of different dimensions and shapes may be provided.
  • a groove (concave portion) having a certain angle relative to a flow path direction for example, parallel or perpendicular to the flow path direction
  • a slit or an opening may be formed in the base 11.
  • the term, "slit” in the present specification is a concept that includes a slit-shaped groove and a slit-shaped through portion.
  • groove in the present specification indicates a state where an incision provided in one surface of the base 11 does not penetrate to the other surface.
  • This groove may be formed on the front surface or the back surface of the base 11.
  • through portion in the present specification indicates a state where a hole or an opening provided in the base 11 penetrates from one surface to the other surface.
  • a slit-shaped groove and a slit- shaped through portion may be collectively referred to simply as a "slit.”
  • a linear slit is illustrated, but the slit may be any shape; for example, a slit of a wave shape, a peak shape, an uneven shape, or the like may be formed in the base 11.
  • FIG. 13 illustrates an example of a slit 13 formed in the base 11
  • FIG. 14 illustrates an example of an opening 14 formed in the base 11, but aspects of the slit and the opening are various, as described below.
  • the slit can be formed by any conventionally-used method (for example, by a blade or laser cutting). Meanwhile, the opening can be formed by, for example, widening the base 1 1 formed with a slit-shaped through portion in a direction orthogonal to a slit column. As a means of widening the base 11, a machine such as a tenter or a roller, a manual operation, and the like can be mentioned. Alternatively, the opening may be formed without widening the base 1 1 but by cutting out a desired shape from the base 11.
  • the slit is disposed freely.
  • slits that continuously extend from one side vicinity to an opposite side vicinity of the base 11 may be lined up at predetermined intervals.
  • the slits may be disposed in a zigzag pattern or in a grid.
  • a density of the slits in the base 11 overall does not need to be constant, and in one base 11 there may be a portion where the slits are sparse and a portion where the slits are dense.
  • a length of an individual slit is not limited. Moreover, the lengths of individual slits in one base 11 may be uniform, or slits of different lengths may coexist. An interval between two adjacent slits in an extension direction of the slits is also not limited, and the interval between two adjacent slits in a direction orthogonal to this extension direction is also not limited.
  • intervals may be uniform or not uniform in one base 11.
  • the slit may extend so as to be parallel to one side of the base 1 1 or may be formed so as to incline at any angle ⁇ (0° ⁇ ⁇ ⁇ 90°) relative to the side of the base 1 1.
  • the opening is also disposed freely.
  • openings that continuously extend from one side vicinity to an opposite side vicinity of the base 1 1 may be lined up at predetermined intervals.
  • the openings may be disposed in a zigzag pattern or in a grid.
  • a portion where the openings are sparse and a portion where the openings are dense may coexist.
  • An interval between two adjacent openings is not limited, and these intervals may be uniform or not uniform.
  • the opening may be formed diagonally relative to a side of the base 11. In this manner, similarly to the situation of the slit, various modifications are conceivable for the disposition of the opening.
  • a shape of the opening is not limited and may be, for example, a rectangle, a rhombus, a circle, an ellipse, a rectangle, a star shape, a wave shape, or another polygon. Moreover, openings of a plurality of shapes may coexist in one base 1 1.
  • the slit and the opening may coexist. Obviously, dispositions of individual slits and openings may be freely established.
  • a layer whose thickness is one-tenth of that of the sheet 10 and is formed by the sheet 10 is defined as a sheet layer and a layer formed by a single sheet layer or formed by a plurality of sheet layers being consecutively stacked is referred to as a base layer.
  • consecutively stacking the plurality of sheet layers can be realized by, for example, folding one sheet 10 in a zigzag manner.
  • the charged filter according to the present embodiment is provided with this base layer and an additional function layer having an adsorption function that is different from the base layer.
  • An "adsorption function (of layer)" in the present specification is a function that removes some foreign matter included in the gas that flows in the charged filter from this gas.
  • An aspect of removing the foreign matter is not limited, and, for example, adsorption, absorption, neutralization, and catalysis can be mentioned, but in the present specification, this is expressed as an "adsorption function" regardless of the aspect thereof.
  • a type of the foreign matter removed by the base layer or the additional function layer is not limited, and this foreign matter may be in any state— solid, liquid, or gas— in the gas.
  • the base layer mainly has a function of removing the fine particle.
  • a main function of the additional function layer depends on a material of this layer.
  • the additional function layer may include activated carbon that performs removal or deodorization of an organic component, may include an absorbent such as a zeolite or an aluminosilicate, or may include a deodorizing catalyst such as copper-ascorbic acid.
  • the additional function layer may include a desiccant such as silica gel, a zeolite, calcium chloride, or activated alumina or may include a disinfectant of a UV disinfectant type or the like.
  • the additional function layer may include an ozone removal agent including a metal such as an oxide supported on a carrier such as alumina, silica alumina, zirconia, diatomaceous earth, silica zirconium, or titania.
  • a mixture of a plurality of types of materials where each exhibits the adsorption function may be used as the material of the additional function layer.
  • the additional function layer is provided with a base.
  • a material configuring the base of the additional function layer may be provided in a particle aspect.
  • the particle serving as the material of the additional function layer is referred to as an "adsorbent particle.”
  • the additional function layer may be formed by adhering the adsorbent particle on at least a front surface or a back surface of the base layer.
  • the function of the additional function layer (for example, filtering efficiency, pressure loss, service life) can be set to a desired level by adjusting an amount of the absorbent particle to be adhered or a region to which the absorbent particle is adhered.
  • An adhesion method is not limited; for example, an adhesive may be used, or a pressure-sensitive adhesive may be used.
  • an adhesive layer comes to be present in the charged filter.
  • the adhesive there is, for example, a one-liquid type, a two-liquid type, and a heat-sensitive type, but any may be used.
  • the pressure-sensitive adhesive for example, there is a method of directly coating and a method of use as a double-sided tape (a presence or absence of a base material is not taken into consideration), but either method may be adopted.
  • An adhesive or pressure-sensitive adhesive with a small volatile organic compound content (VOC) may be used.
  • a ratio of a thickness of the adhesive layer to a thickness of the base of the sheet layer is generally 2 or less, preferably 1 or less, and more preferably 0.3 or less.
  • the dimensions of the adsorbent particle may be adjusted in consideration of these points.
  • a particle of activated carbon that can fit in a 35 to 60 mesh in the ASTM El 1-01 sieve classification table regulated by the American Society for Testing Materials may be used.
  • the additional function layer may be formed by a means other than adhering the adsorbent particle to the base layer.
  • an additional function layer prepared in advance may be installed by welding to at least the front surface or the back surface of the base layer.
  • the charged filter according to the present embodiment is provided with a plurality of layers; more specifically, it is provided with at least one base layer and at least one additional function layer.
  • Providing the plurality of layers, that is, a stacked structure, can be obtained by stacking the base layer and the additional function layer in any aspect.
  • the stacked structure may be formed by bending or winding this sheet 10.
  • the stacked structure may be formed by stacking a plurality of sheets 10 where the additional function layer is formed on at least the front surface or the back surface of the sheet 10 (hereinbelow, such a sheet is referred to as a
  • multifunctional sheet for convenience.
  • the plurality of layers may be formed by winding after connecting different types of multifunctional sheets.
  • An adhesion layer or an adhesive layer may be provided on at least one surface of the sheet 10, and by this, shifting when stacking can be prevented.
  • FIG. 15 and 16 Examples of stacking the multifunctional sheets are illustrated in FIG. 15 and 16.
  • the multifunctional sheets may be stacked so an additional function layer 30 of an adjacent multifunctional sheet contacts the upper surface of the protrusion 20 of the base layer of a certain multifunctional sheet.
  • this base layer is made from one sheet layer.
  • An angle formed between the base of the sheet layer 10 and the root-side side surface of the stem portion of the sheet layer 10 is, for example, 90° or more and less than 180°.
  • An angle formed between the tip-side side surface of the stem portion of the sheet layer 10 and the base of the additional function layer 30 adjacent to the stem portion is, for example, 45° or more and less than 180°.
  • the first angle may be, for example, 45° or more and less than 180° and the second angle may be, for example, 90° or more and less than 180°.
  • the multifunctional sheets may be stacked so the protrusion 20 of the sheet layer 10 and the protrusion 20 of another sheet layer 10 adjacent to this sheet layer 10 face each other and so the additional function layer 30 and another additional functional layer 30 face each other.
  • This charged filter can be obtained by, for example, folding one multifunctional sheet in the zigzag pattern.
  • the angle formed between the base of the sheet layer 10 and the root-side side surface of the stem portion of the sheet layer 10 (first angle) is, for example, 90° or more and less than 180°.
  • the angle formed between the tip-side side surface of the stem portion of one sheet layer 10 and the base of another sheet layer 10 adjacent to the stem portion is, for example, 45° or more and less than 180°.
  • the second angle in FIG. 16 is an angle formed between a virtual extension line of the tip-side side surface of the stem portion of this one sheet layer 10 and the base of this other sheet layer 10.
  • the first angle may be, for example, 45° or more and less than 180° and the second angle may be, for example, 90° or more and less than 180°.
  • the additional function layer it is not necessary to adhere the additional function layer to the back surface of the base layer (sheet 10).
  • a sheet of the additional function layer independent from the sheet 10 may be further prepared and the two types of sheets may be stacked in any aspect.
  • the stacking illustrated in FIG. 15 and 16 can be realized.
  • one base layer may be formed by combining back surfaces of two sheet layers 10, and the additional function layer 30 may be inserted between these base layers.
  • the angle formed between the base of the sheet layer 10 and the root-side side surface of the stem portion of the sheet layer 10 is, for example, 90° or more and less than 180°.
  • the angle formed between the tip-side side surface of the stem portion of the sheet layer 10 and the base of the additional function layer 30 adjacent to the stem portion is, for example, 45° or more and less than 180°.
  • the first angle may be, for example, 45° or more and less than 180° and the second angle may be, for example, 90° or more and less than 180°.
  • one base layer may be formed by combining the upper surface of the protrusion 20 of one certain sheet layer 10 and the back surface of another sheet layer 10, and the additional function layer 30 may be inserted between these base layers.
  • the angle formed between the base of the sheet layer 10 and the root-side side surface of the stem portion of the sheet layer 10 is, for example, 90° or more and less than 180°.
  • the angle formed between the tip-side side surface of the stem portion of the sheet layer 10 and the base of the other sheet layer 10 adjacent to the stem portion is, for example, 45° or more and less than 180°.
  • the angle formed between the tip-side side surface of the stem portion of the sheet layer 10 and the base of the additional function layer 30 adjacent to the stem portion is, for example, 45° or more and less than 180°.
  • the first angle may be, for example, 45° or more and less than 180° and the second angle may be, for example, 90° or more and less than 180°.
  • a ratio of a thickness of the base layer and a thickness of the additional function layer to be stacked may be freely established.
  • this ratio may be 1 : 1, 2: 1, 3 : 1, 1 :2, or another ratio.
  • the first angle and the second angle above are present. In a situation where there is a plurality of types of angles corresponding to the second angle, these angles may be the same or different from each other.
  • a front surface of the additional function layer 30 does not have to be completely flat and can include a situation of being uneven.
  • a minute unevenness can arise on the front surface of the additional function layer 30.
  • an additional function layer 30 with a completely flat front surface may be used.
  • the filter unit according to the present embodiment may be made from only the charged filter.
  • FIG. 19 to 21 illustrate examples of the charged filter and the filter unit made from only the charged filter. In these examples, the multifunctional sheet is used.
  • FIG. 19 illustrates a filter unit 100 made from a cylindrical charged filter 1 10.
  • the charged filter 110 is obtained by winding one multifunctional sheet into many layers.
  • One of two circular surfaces in which a large number of flow paths 90 is present is an inflow surface through which the air inflows and the other is an outflow surface through which this air outflows.
  • the depicted surface is an inflow surface 1 11 and an opposite surface thereof is an outflow surface 1 12.
  • the charged filter 110 has a side surface 1 13 that extends from the inflow surface 111 to the outflow surface 112.
  • a “side surface” of the charged filter is a surface that intersects both the inflow surface and the outflow surface of the charged filter and is a surface where at least a portion is formed based on the front surface or the back surface of the multifunctional sheet.
  • a plurality of protrusions 20 is lined up on any virtual line extending from the inflow surface to the outflow surface of the charged filter. Therefore, the side surface of the charged filter has a certain length or more, and this signifies that the charged filter has a thickness of an extent where a person can recognize it as a three-dimensional structure.
  • the thickness of the charged filter is the length of this side surface along a direction from the inflow surface to the outflow surface.
  • the side surface of the charged filter may be formed by the front surface or the back surface of the multifunctional sheet itself.
  • the side surface of the charged filter may be formed in an aspect where at least a portion of the front surface or the back surface of the multifunctional sheet is covered by another member.
  • FIG. 19 illustrates an example where an entirety of the side surface 113 of the charged filter is formed by the back surface of the multifunctional sheet (side of the additional function layer) itself.
  • the multifunctional sheet may be wound in many layers around a cylindrical member serving as an axis of the charged layer or the
  • multifunctional sheet may be wound without using this cylindrical member.
  • a rigidity of the multifunctional sheet itself decreases such that the multifunctional sheet more flexibly deforms, a work of tightly winding the multifunctional sheet is thereby facilitated, and a charged filter 110 where two adjacent layers are more reliably adhered can be made.
  • a flexibility of the multifunctional sheet can be suitably changed according to an attribute of the charged filter (manufacturing method, application scenario, or the like).
  • a film having contractility alone may be used without using a bonding agent or an adhesive.
  • the charged filter 110 is fixed by covering an outer peripheral surface of the charged filter 110 by the shrink film.
  • a heat shrink tube is adopted as the shrink film
  • the tube shrinks to hold in the charged filter 110 from an outer side.
  • a material of the heat shrink tube polyethylene terephthalate (PET) and biaxially-oriented polystyrene (BOPS) can be mentioned.
  • PET polyethylene terephthalate
  • BOPS biaxially-oriented polystyrene
  • the charged filter 110 may be held in from the outer side by winding the charged filter 110 with the shrink film while applying a tensile force on the shrink film.
  • FIG. 20 illustrates a filter unit 100 A made from a charged filter 110A.
  • the charged filter 110A can be obtained by folding one multifunctional sheet in the zigzag pattern or by stacking a plurality of multifunctional sheets of the same shape. Alternatively, the charged filter 110A may be obtained by trimming the side surface of the charged filter after stacking a plurality of multifunctional sheets.
  • One surface in which the flow path 90 is present is the inflow surface through which the air inflows, and an opposite side of this surface is the outflow surface through which this air outflows.
  • the depicted surface is an inflow surface 111 A and an opposite surface thereof is an outflow surface 112A.
  • the charged filter 110A has a side surface 113A that extends from the inflow surface 111 A to the outflow surface 112A.
  • FIG. 20 illustrates an example where a portion of the side surface 113 A of the charged filter is formed by the front surface or the back surface of the multifunctional sheet itself and the remaining side surface 113 A is formed by stacking the multifunctional sheets.
  • the charged filter 110A illustrated in FIG. 20 is a rectangular parallelepiped, but a shape of the charged filter 110A is not limited thereto and may be a cylinder, an elliptical cylinder, any polygonal column, or a more complex shape.
  • FIG. 21 illustrates a filter unit 100B made from a charged filter HOB that includes a conical portion.
  • the charged filter 11 OB is obtained by pulling a center (portion corresponding to a winding core) after winding one band-shaped multifunctional sheet into many layers.
  • One surface in which the flow path is present is the inflow surface through which the air inflows, and an opposite side of this surface is the outflow surface through which this air outflows.
  • the depicted surface is an inflow surface 11 IB and an opposite surface thereof is an outflow surface 112B.
  • the charged filter HOB has a side surface 113B that extends from the inflow surface 11 IB to the outflow surface 112B.
  • FIG. 21 illustrates an example where an entirety of the side surface 113B of the charged filter is formed by the back surface of the multifunctional sheet itself.
  • charged filter of various shapes can be made from one or a plurality of multifunctional sheets.
  • charged filters 110, 110A, and HOB such as those illustrated in FIG. 19 to 21 can also be made by preparing a sheet of the additional function layer independent from the sheet 10 and stacking two types of sheets into many layers in any aspect.
  • the charged filter according to the present embodiment has a large number of flow paths through which the gas flows (see the flow path 90 illustrated in the enlarged portions in FIG.
  • a thickness (flow path length of the filter) and a diameter of the charged filter overall can be set according to a type of the mask.
  • a lower limit of the thickness of the charged filter overall for a dust mask may be 3 mm or 5 mm and an upper limit thereof may be 150 mm or 100 mm.
  • a lower limit of the diameter of the charged filter for the dust mask may be 10 mm or 50 mm and an upper limit thereof may be 200 mm or 120 mm.
  • a lower limit of the thickness of the charged filter overall for respiration protection equipment with an electric fan may be 3 mm or 5 mm and an upper limit thereof may be 1,000 mm or 600 mm.
  • a lower limit of the diameter of the charged filter for the respiration equipment with the electric fan may be 10 mm or 50 mm and an upper limit thereof may be 500 mm or 300 mm.
  • the protrusions 20 When the charged filter is viewed facing the inflow surface or the outflow surface of the charged filter, the protrusions 20 may be aligned along the stacking direction, may be arranged in a zigzag pattern, or may be disposed randomly.
  • the charged filter may be provided with a plurality of types of base layers where shapes, dimensions, or densities of the solid protrusions are different from each other.
  • the charged filter may be provided with a plurality of types of additional function layers.
  • the filter unit may be further provided with a filter other than the charged filter.
  • the filter unit may be further provided with an inflow-side filter provided on a side of the inflow surface of the charged filter.
  • the filter unit may be further provided with an outflow-side filter provided on a side of the outflow surface of the charged filter.
  • the filter unit may be provided with the charged filter, the inflow-side filter, and the outflow-side filter.
  • a filter unit lOOC illustrated in FIG. 22 is provided with the charged filter 110 illustrated in FIG. 19, an inflow-side filter 120, and an outflow-side filter 130.
  • the inflow-side filter and the outflow-side filter may be collectively referred to as an "additional filter.”
  • the additional filter may contact the inflow surface or the outflow surface of the charged filter, and a gap may be formed between the additional filter and the inflow surface or outflow surface.
  • a plurality of additional filters may be provided on the side of the inflow surface or the outflow surface.
  • the additional filter may be a nonwoven fabric filter that is electret treated (that is, a charged additional filter) or a nonwoven fabric filter where no electret treatment is applied.
  • the additional filter may include activated carbon that performs removal or deodorization of an organic component, may include an absorbent such as a zeolite or an aluminosilicate, and may include a deodorizing catalyst such as copper-ascorbic acid.
  • the additional filter may include a desiccant such as silica gel, a zeolite, calcium chloride, or activated alumina; may include a disinfectant of a UV disinfectant type or the like; and may include an aromatic such as glyoxal, methacrylic ester, or a fragrance.
  • the additional filter may include an ozone removal agent including a metal such as an oxide supported on a carrier such as alumina, silica alumina, zirconia, diatomaceous earth, silica zirconium, or titania.
  • Structures, materials, and functions of the additional filter may be the same or different across the inflow-side filter 120 and the outflow-side filter 130.
  • both filters may be selected so pressure loss is lower in the outflow-side filter 130 than in the inflow-side filter 120.
  • both filters may be selected so filtering efficiency (for example, the Japanese national testing standard, "Testing According to Dust Mask Regulations (Notice No. 88)"; EN 143 (EFR) 2000, EN 149 (FFR) 2001; or NIOSH (42 CFR 84)) is higher in the outflow-side filter 130 than in the inflow-side filter 120.
  • the charged filter has a thickness of an extent where a person can recognize it as a three- dimensional structure.
  • the additional filter may have a structure where a person can recognize it as a flat structure (for example, a sheet shape) or a three-dimensional structure similar to that of the charged filter.
  • the charged filter may be thicker than at least one additional filter or thicker than all additional filters.
  • the charged filter may be thinner than at least one additional filter or thinner than all additional filters.
  • the charged filter and the additional filter may have the same thickness. In any case, because the charged filter has a dense stacked structure having a certain thickness, it can continue to maintain a shape thereof by itself. Therefore, when applying to a mask, there is no need to use another member to maintain the shape of the charged filter. This is an advantageous point compared to the pleated filter described in JP 2002-12611 OA above.
  • the mask 200 in FIG. 1 described above is an example of a mask that provides the filter unit in a portion that covers at least a portion of the face of a person.
  • FIG. 23 illustrates an example of a mask that provides the filter unit to a component different from a component covering at least a portion of the face of a person.
  • FIG. 24 is a partial enlarged view of FIG. 23.
  • Masks 200, 300 illustrated in these diagrams are but examples, and it should be noted that the filter unit according to the present invention can be applied to various masks.
  • the mask 200 illustrated in FIG. 1 is provided with a main body 210 that covers the face (more specifically, the nose and the mouth) of the user and a strap 220 for bringing the mask main body 210 into close contact with the face.
  • the strap 220 is installed to the mask main body 210 by being passed through a pair of slots 21 1 (only one slot is illustrated in FIG. 1) formed on both side surfaces on an outer side of the mask main body 210.
  • the strap 220 may be made by a material having elasticity so the mask main body 210 can be brought into close contact with the face of the user.
  • the mask main body 210 exhibits a substantially hemispherical shape and can thereby ensure a space necessary for respiration in a vicinity of the nose and the mouth of the user.
  • an external form of the mask main body 210 is not limited and may be any shape, such as a cone or a column.
  • a filter housing portion 230 for housing the filter unit is provided.
  • the filter unit lOOC is illustrated, but the filter unit 100 or 100B may be used instead.
  • An edge portion 212 of the mask main body 210 that contacts the face during use may have flexibility, and in this situation, an adhesion of the mask main body 210 to the face can be increased. Meanwhile, an apex-portion side of the mask main body 210 where the slot 211 and the filter housing portion 230 are provided may be hard. For example, by making the edge portion 212 of the mask main body by a rubber and making other portions by a synthetic resin, the adhesion of the mask main body 210 can be increased while ensuring the space necessary for respiration on the inner side of the mask main body 210.
  • the filter housing portion 230 is provided with a housing 231 that receives the filter unit lOOC and an annular stopping portion 232 for preventing the filter unit lOOC from flying out from the housing 231.
  • the filter unit lOOC is set in the mask 200 by disengaging the stopping portion 232, placing the filter unit lOOC in the housing 231, and afterward fitting the stopping portion 232 to the housing 231.
  • the filter housing portion 230 exhibits a cylindrical shape, but a shape of the filter housing portion 230 may be freely set to match the filter unit.
  • the filter housing portion may be a tubular shape with a square cross section to match the filter unit 100 A, and in this situation, a shape of the stopping portion is substantially square.
  • the filter housing portion may be a tubular shape with a triangular cross section, and in this situation, the shape of the stopping portion is substantially triangular.
  • the mask 300 illustrated in FIG. 23 is provided with a face contact body 310 that covers an entire head portion of the user, a hose 320 that extends from this face contact body 310, and a filter housing portion 330 that connects to one end of the hose 320 and is provided with an electric fan.
  • the air taken into the filter housing portion 330 by the electric fan flows into the face contact body 310 through the hose 320, and the user inhales this flowing air.
  • the filter housing portion 330 exhibits a tubular shape.
  • a connection port 331 to which the hose 320 connects and an intake port 332 for air formed on an opposite side of this connection port 331 are connected by a flow path 333 formed by an inner wall of a substantially cylindrical shape.
  • the filter unit is disposed in this flow path 333. Note that the electric fan that is not illustrated is disposed on an inner side of the intake port 332.
  • the filter unit 100 is illustrated, but the filter unit 100B or lOOC may be used instead.
  • the side surface 113 of the filter unit 100 (charging filter 110) contacts the inner wall of the flow path 333.
  • Air entering from the intake port 332 by the electric fan passes through the filter unit 100 provided in the filter housing portion 330 (more specifically, the flow path 90) and afterward flows in the hose 320.
  • the flow path 333 exhibits a cylindrical shape, but a shape of the flow path in the filter housing portion may be freely set to match the filter unit.
  • a cross- sectional shape of the flow path in a situation of being viewed along a direction in which the air flows may be rectangular to match the filter unit 100 A.
  • the mask 300 is a type of respiration protection equipment with an electric fan.
  • a mask of a direct-coupling type without a hose and where the electric fan and the filter housing portion are built into the face contact body also exists, and obviously, the filter unit according to the present invention can be built into this direct-coupling-type mask.
  • An aspect of providing the filter unit to the mask is not limited to the above example, and a system of installing the filter unit is not limited as long as all air that is taken in passes through the filter unit.
  • each protrusion is provided with the stem portion and the cap portion and is therefore of a shape corresponding to example (b) in FIG. 2.
  • the projection image of the stem portion obtained by projection onto the virtual surface corresponds to pattern 3 or 5 above.
  • the thickness of the base is made to be about 0.1 mm
  • the height of each protrusion is made to be about 0.3 mm or about 0.45 mm
  • the maximum width of the tip portion of the stem portion of each protrusion is made to be about 0.12 to 0.18 mm.
  • the protrusions are formed on the base so the individual protrusions are disposed in a grid at intervals of about 0.36 to 0.85 mm.
  • the formed sheet functions as the base layer of the charged layer.
  • the electret treatment is applied to this sheet.
  • a time of a heating process (100°C) is made to be 5 seconds
  • a time of a cooling process is also made to be 5 seconds
  • an applied voltage is made to be 13.5 KV.
  • the multifunctional sheet applied with the electret treatment is wound up in a roll shape (effective diameter: about 76 mm or about 84 mm), and by cutting this roll into a thickness of 20 mm or 25 mm, the charged filter of the cylindrical shape is obtained.
  • a roll shape effective diameter: about 76 mm or about 84 mm
  • two types of charged circular additional filters A, B are prepared.
  • the additional filters A, B are both sheet-shaped, and a diameter is made to be about 76 mm or about 84 mm.
  • BMF blown microfiber filter made by 3M.
  • Examples 1 to 5 A filter unit of a three-layer structure where the additional filter A is disposed on the inflow surface of the charged filter and the additional filter B is disposed on the outflow surface of the charged filter. Combinations of the diameter of the filter unit and the height and the thickness of the protrusion of the charged filter are as indicated in FIG. 25.
  • Comparative example 1 A filter obtained by disposing the above charged filter for air purification on an inflow-surface side of a sheet obtained by interposing a carbon layer between two nonwoven fabric layers.
  • Comparative example 2 A flat filter and a flat carbon filter for being stacked thereon.
  • Comparative example 3 A filter obtained by pleating a nonwoven fabric of glass wool mixed with activated carbon fibers.
  • Pressure loss is a pressure difference between the inflow-surface side and the outflow-surface side of the filter when the air is flowed at a flow rate of 40 LPM (liters per minute), and the unit thereof is Pascals (Pa).
  • Pressure loss is a value obtained by performing a test of flowing air at the flow rate of 40 LPM (liters per minute) through the filter before filtration.
  • Escalation value of pressure loss is a value obtained by performing a test of flowing air at the flow rate of 40 LPM (liters per minute) through the filter after 100 mg of sodium chloride (NaCl) are loaded to provide clogging.
  • a measuring device made by TSI (model 8130) is used.
  • Sodium chloride (NaCl) is used in testing filtering efficiency.
  • a dimension of NaCl indicated by a particle count median diameter is about 0.06 to 0.10 ⁇ , and a geometric standard deviation of this dimension is less than 1.8.
  • a concentration of NaCl in the airstream is made to be about 50 mg/m 3 (15% fluctuation range) or less.
  • the flow rate is made to be 85 LPM, and a time until 100 mg of NaCl is finished being provided to the airstream is made to be a test time.
  • a filtering efficiency E (%) is obtained by the following formula, with a particle concentration in the airstream before passing through the filter being C a (mg/m 3 ) and a maximum particle concentration in the airstream after passing through the filter (mg/m 3 ) being Cb.
  • Service life is a time where the filter unit can continue to exhibit the function thereof, that is, a life of the filter unit.
  • Two types of evaluation methods are used for service life.
  • air with a cyclohexane concentration of 50 ppm is flowed at a flow rate of 30 LPM, and a time is measured where a cyclohexane concentration in the air on the outflow-surface side can be maintained at 5 ppm or less.
  • a temperature and a relative humidity of a testing environment are 20 ⁇ 2° and 70 ⁇ 5°, respectively.
  • This first method is used for all examples 1 to 5 and comparative examples 1 to 3.
  • the second method is the canister national test defined in "Sep. 18, 2001 Ministry of Health, Labour and Welfare Notice No.
  • Air with a cyclohexane concentration of 300 ppm is flowed at the flow rate of 30 LPM, and the time is measured where the cyclohexane concentration in the air on the outflow- surface side can be maintained in a state of 5 ppm or less. If this time is 50 minutes or more, the requirement of the national test is satisfied.
  • This second method is only performed on example 4.
  • FIG. 25 is a table indicating test results for the above examples and comparative examples.
  • "A” and “B” in the table respectively signify the additional filter A and the additional filter B.
  • "filter” is intended to include the filter unit.
  • the filter used in comparative example 3 is a filter that includes concentric circular pleats, an apparent filter outer diameter and thickness are indicated in the table.
  • an effective area and an apparent area of the filter unit are also described.
  • the effective area is a total surface area of a filter unit surface assumed to directly receive the flowing air.
  • the apparent area is an area of the inflow surface when the filter is viewed in a state of opposing the inflow surface of the filter and is sought by measuring a filter area
  • Activated carbon row indicates how the additional function layer is realized. "Integrated” signifies that the activated carbon is contained in the filter or a layer of the activated carbon is integrated with the filter. "Independent” signifies that the layer of the activated carbon is provided as an independent article.
  • a filter unit is a filter unit for a mask that covers at least a portion of the face of a person, provided with: a charged filter that has an inflow surface through which air inflows, an outflow surface through which the air outflows, and a side surface that extends from the inflow surface to the outflow surface; wherein the charged filter is provided with a base layer, which is formed by a single sheet layer or formed by consecutively stacking a plurality of sheet layers, and an additional function layer that is different from the base layer and adjacent to the base layer; each sheet layer is provided with a base and a plurality of solid protrusions that extends from a surface of the base, the protrusions having a stem portion that has a root-side side surface and a tip-side side surface; the additional function layer is provided with a base; a first angle formed between the base of the sheet layer and the root-side side surface of the stem portion of the sheet layer is present; a second angle that is an angle
  • a mask according to one aspect of the present invention is provided with the above filter unit.
  • a corner of a flow path of a gas is ensured to be wide on a root side and a tip side respectively of the stem portion of the protrusion, in the flow path, which is formed by two adjacent protrusions, the gas comes to travel not only near a center thereof but also near the corner, facilitating the gas flowing in the filter.
  • the protrusion is solid, a layer structure of the filter can be stabilized and a flow path between the layers can continue to be maintained. Therefore, suppression of pressure loss and improvement of filtering efficiency can be realized.
  • filtering efficiency in the additional function layer also improves.
  • the charged filter can be made by a simple method of stacking layers, manufacturing costs of the filter unit can be suppressed.
  • the filter unit according to the aspect above can make a width of the filter (thickness or flow path length) long and is of a structure where clogging is less likely to occur even if the width (thickness or flow path length) of the filter is made long, a filter unit can be obtained having a different structure and performance from a filter unit using a nonwoven fabric (for example, having a long product life).
  • suppression of pressure loss and maintenance of high filtering efficiency can be realized while suppressing an apparent area of the filter unit.
  • Being able to make the apparent area of the surface unit small signifies that even in a situation where the filter unit is provided in front of the face of the user a field of vision of this person is not obstructed. Therefore, in the above aspect, it can be said that favorable suppression of pressure loss and high filtering efficiency can be realized without blocking the field of vision of the user.
  • a process of increasing an effective area such as pleating the filter unit is also unnecessary, and the charged filter can be made by merely winding or stacking the sheet; therefore, suppression of
  • the additional function layer may be fixed to the base layer via an adhesive layer. In this situation, the additional function layer can be formed efficiently.
  • a ratio of a thickness of the adhesive layer relative to a thickness of the base of the sheet layer may be 0.3 or less.
  • an inflow-side filter provided on a side of the inflow surface may be further provided.
  • an outflow-side filter provided on a side of the outflow surface may be further provided.
  • filtering efficiency of the filter unit can be further increased.
  • the present invention is not limited to the above embodiment. With the present invention, various modifications are possible within a scope that does not depart from the spirit thereof.
  • the filter unit according to the present invention may be used for a mask of any shape. Therefore, the filter unit according to the present invention may be applied to any mask other than the masks 200, 300 in the above embodiment.

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  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Business, Economics & Management (AREA)
  • Emergency Management (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Filtering Materials (AREA)
  • Electrostatic Separation (AREA)
  • Respiratory Apparatuses And Protective Means (AREA)
PCT/US2016/024915 2015-04-17 2016-03-30 Filter unit WO2016167960A1 (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101846295B1 (ko) 2017-08-22 2018-05-18 주식회사 에스랩 휘발성 유기화합물 필터용 팩
IT202000013192A1 (it) * 2020-06-04 2021-12-04 Tacchificio Zanzani S R L Gruppo filtrante per maschere di protezione.
WO2022162675A1 (en) 2021-01-31 2022-08-04 Sion Biotext Medical Ltd. Filtration element and uses thereof

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR102129349B1 (ko) * 2018-06-01 2020-07-02 김필립 마스크용 두루마리형 필터 및 그 제조방법

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Publication number Priority date Publication date Assignee Title
US20020027101A1 (en) * 1998-06-18 2002-03-07 Thomas I. Insley Structured surface filtration media
US6986428B2 (en) * 2003-05-14 2006-01-17 3M Innovative Properties Company Fluid separation membrane module
US20070222119A1 (en) * 2005-05-02 2007-09-27 3M Innovative Properties Company Electret article having heteroatoms and low fluorosaturation ratio

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20020027101A1 (en) * 1998-06-18 2002-03-07 Thomas I. Insley Structured surface filtration media
US6986428B2 (en) * 2003-05-14 2006-01-17 3M Innovative Properties Company Fluid separation membrane module
US20070222119A1 (en) * 2005-05-02 2007-09-27 3M Innovative Properties Company Electret article having heteroatoms and low fluorosaturation ratio

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101846295B1 (ko) 2017-08-22 2018-05-18 주식회사 에스랩 휘발성 유기화합물 필터용 팩
IT202000013192A1 (it) * 2020-06-04 2021-12-04 Tacchificio Zanzani S R L Gruppo filtrante per maschere di protezione.
WO2022162675A1 (en) 2021-01-31 2022-08-04 Sion Biotext Medical Ltd. Filtration element and uses thereof

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