WO2016136254A1 - High temperature wear-resistant aluminum-bronze-based material - Google Patents
High temperature wear-resistant aluminum-bronze-based material Download PDFInfo
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- WO2016136254A1 WO2016136254A1 PCT/JP2016/000987 JP2016000987W WO2016136254A1 WO 2016136254 A1 WO2016136254 A1 WO 2016136254A1 JP 2016000987 W JP2016000987 W JP 2016000987W WO 2016136254 A1 WO2016136254 A1 WO 2016136254A1
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C9/00—Alloys based on copper
- C22C9/01—Alloys based on copper with aluminium as the next major constituent
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D27/00—Treating the metal in the mould while it is molten or ductile ; Pressure or vacuum casting
- B22D27/20—Measures not previously mentioned for influencing the grain structure or texture; Selection of compositions therefor
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C9/00—Alloys based on copper
- C22C9/05—Alloys based on copper with manganese as the next major constituent
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- the high temperature wear resistant aluminum bronze material of the present invention has an Al content of 9.0 mass% or more and 11.0 mass% or less, an Ni content of 1.0 mass% or more and 3.0 mass% or less, and an Mn content. 8.5 mass% to 15.0 mass%, Si content is 2.0 mass% to 4.0 mass%, Fe content is 0.5 mass% to 5.0 mass%, and Co content is 0.01 mass % To 1.5% by mass, and the balance is substantially Cu.
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Abstract
Provided is a material endowed with high wear resistance in high-temperature environments. This high temperature wear-resistant aluminum-bronze-based material has an Al content of 9.0 mass% to 11.0 mass%, inclusive, an Ni content of 1.0 mass% to 3.0 mass%, inclusive, an Mn content of 8.5 mass% to 15.0 mass%, inclusive, an Si content of 2.0 mass% to 4.0 mass%, inclusive, an Fe content of 0.5 mass% to 5.0 mass%, inclusive, and a Co content of 0.01 mass% to 1.5 mass%, inclusive, with the remainder being substantially Cu.
Description
本発明は、高温雰囲気下で優れた耐摩耗性を有するアルミニウム青銅系材料に関するものである。
The present invention relates to an aluminum bronze material having excellent wear resistance in a high temperature atmosphere.
焼却炉等の産業機械や設備における高温雰囲気下で、エキゾーストバルブブッシュなどの摺動部材には、高力黄銅鋳物などの銅合金が一般的に用いられている。
Copper alloys such as high-strength brass castings are generally used for sliding members such as exhaust valve bushes in a high temperature atmosphere in industrial machines and equipment such as incinerators.
そのような摺動部材の例として、特許文献１には、質量%で、3～15%Al、1～8%Mn、0.05～5%Si、0.5～5%Ni、1～10%Feを含有し、残部不可避的不純物及びCuからなり、Fe-Mn-Si系硬質物が分散した銅系軸受摺動材料が開示されている。
As an example of such a sliding member, Patent Document 1 includes 3 to 15% Al, 1 to 8% Mn, 0.05 to 5% Si, 0.5 to 5% Ni, and 1 to 10% Fe in mass%. There is disclosed a copper-based bearing sliding material containing the balance, inevitable impurities and Cu, in which an Fe-Mn-Si-based hard material is dispersed.
しかしながら、特許文献１のような従来のアルミニウム青銅系の摺動部材は、高温雰囲気中（例えば、150℃～350℃の高温雰囲気）では母材硬度の低下から許容面圧値が低くなり、耐摩耗性も十分とはいえない。したがって、交換が容易ではない劣悪な環境下で使用される産業用機械の摺動部材の交換頻度を減らすために更なる高性能素材の供給が望まれている。
However, the conventional aluminum bronze-type sliding member such as Patent Document 1 has a lower allowable surface pressure value due to a decrease in the hardness of the base material in a high temperature atmosphere (for example, a high temperature atmosphere of 150 ° C. to 350 ° C.). Abrasion is not sufficient. Therefore, in order to reduce the replacement frequency of the sliding member of the industrial machine used in the poor environment where replacement | exchange is not easy, supply of the further high performance material is desired.
本発明は、このような従来の問題を解決するためになされたもので、常温雰囲気のみならず、高温雰囲気において耐面圧性と耐摩耗性とを兼ね備えた素材を提供することにある。
The present invention has been made to solve such a conventional problem, and is to provide a material having both surface pressure resistance and wear resistance not only in a normal temperature atmosphere but also in a high temperature atmosphere.
本発明の高温耐摩耗性アルミニウム青銅系材料は、Alの含有量が9.0質量％以上11.0質量％以下であり、Niの含有量が1.0質量％以上3.0質量％以下であり、Mnの含有量が8.5質量％以上15.0質量％以下であり、Siの含有量が2.0質量％以上4.0質量％以下であり、Feの含有量が0.5質量％以上5.0質量％以下であり、Coの含有量が0.01質量％以上1.5質量％以下であり、残部が実質的にCuであることを特徴とする。
The high temperature wear resistant aluminum bronze material of the present invention has an Al content of 9.0 mass% or more and 11.0 mass% or less, an Ni content of 1.0 mass% or more and 3.0 mass% or less, and an Mn content. 8.5 mass% to 15.0 mass%, Si content is 2.0 mass% to 4.0 mass%, Fe content is 0.5 mass% to 5.0 mass%, and Co content is 0.01 mass % To 1.5% by mass, and the balance is substantially Cu.
本発明の高温耐摩耗性アルミニウム青銅系材料によれば、高温雰囲気においても耐面圧性と耐摩耗性とを兼ね備えた摺動部材を提供することが可能となる。摺動による摩耗量を減らすことで、摺動部材の交換が容易ではない産業用機械や金型において、摺動部材などの部品交換回数を大幅に削減することが可能となる。
According to the high temperature wear resistant aluminum bronze material of the present invention, it is possible to provide a sliding member having both surface pressure resistance and wear resistance even in a high temperature atmosphere. By reducing the amount of wear due to sliding, it is possible to greatly reduce the number of times of replacement of parts such as sliding members in industrial machines and molds in which replacement of sliding members is not easy.
以下、本発明の実施形態である高温耐摩耗性アルミニウム青銅系材料について、詳細に説明をする。
Hereinafter, the high temperature wear resistant aluminum bronze material which is an embodiment of the present invention will be described in detail.
本実施形態の高温耐摩耗性アルミニウム青銅系材料は、Al、Ni、Mn、Si、Fe、及びCoを所定の質量％で含有し、残部が実質的にCuの材料である。
The high-temperature wear-resistant aluminum bronze material of this embodiment contains Al, Ni, Mn, Si, Fe, and Co at a predetermined mass%, and the balance is substantially Cu.
本実施形態の高温耐摩耗性アルミニウム青銅系材料では、Alの含有量が、9.0質量％以上、11.0質量％以下、好ましくは9.0質量％以上、10.0質量％以下である。Alの含有量が上記数値範囲内であることにより、HV280以上の適切な母材の硬度が得られ、耐面圧性が向上する。なお、母材の硬度は、JIS Z2243 2008に準ずる方法で測定される。
In the high temperature wear resistant aluminum bronze material of the present embodiment, the Al content is 9.0 mass% or more and 11.0 mass% or less, preferably 9.0 mass% or more and 10.0 mass% or less. When the Al content is within the above numerical range, an appropriate base metal hardness of HV280 or higher is obtained, and surface pressure resistance is improved. The hardness of the base material is measured by a method according to JIS Z2243 2008.
Alの含有量が上記数値範囲未満である場合には、硬度が不十分となる。一方、Alの含有量が上記数値範囲を超える場合には、硬度は高くなるものの、靭性が下がる。そのため、耐熱性の低下を招く。
When the Al content is less than the above numerical range, the hardness is insufficient. On the other hand, when the Al content exceeds the above numerical range, the hardness increases, but the toughness decreases. Therefore, heat resistance is reduced.
また、本実施形態の高温耐摩耗性アルミニウム青銅系材料では、Niの含有量が、1.0質量％以上、3.0質量％以下、好ましくは1.5質量％以上、2.5質量％以下である。Niを含有することにより、α相におけるAlの個溶限を広げることが可能となり、加えて、母材の融点を上げ耐熱性が向上する。さらに、Niを含有することにより、後述するFe-Si-Mnと共に硬質物の析出にも寄与する。
In the high-temperature wear-resistant aluminum bronze material of the present embodiment, the Ni content is 1.0% by mass or more and 3.0% by mass or less, preferably 1.5% by mass or more and 2.5% by mass or less. By containing Ni, the individual solubility limit of Al in the α phase can be expanded, and in addition, the melting point of the base material is increased and the heat resistance is improved. Furthermore, by containing Ni, it contributes also to precipitation of a hard material with Fe-Si-Mn mentioned later.
Niの含有量が上記数値範囲未満である場合には、母材の耐熱性を満足しない。一方、Niの含有量が上記数値範囲を超える場合には、母材を脆化させ、かつ、Niはレアメタルのため製品が高価になるという欠点がある。
When the Ni content is less than the above numerical range, the heat resistance of the base material is not satisfied. On the other hand, when the Ni content exceeds the above numerical range, the base material is embrittled, and since Ni is a rare metal, the product is expensive.
また、本実施形態の高温耐摩耗性アルミニウム青銅系材料は、Fe-Mn-Si系硬質物が分散した組織とすることで、摺動部材として耐摩耗性が向上する。
Further, the high temperature wear resistant aluminum bronze material of the present embodiment has a structure in which the Fe—Mn—Si hard material is dispersed, thereby improving the wear resistance as a sliding member.
本実施形態の高温耐摩耗性アルミニウム青銅系材料では、Mnの含有量が、8.5質量％以上、15.0質量％以下、好ましくは8.5質量％以上、13.0質量％以下、より好ましくは8.5質量％以上10.0質量％以下である。Mnの含有量が上記数値範囲内であることにより、後述するSi、Mnなどと共に、Fe-Si-Mn系硬質物を母材中に析出させて、耐摩耗性が向上する。また、Mnの含有比率を高めることで母材の好適な靱性が得られる。
In the high-temperature wear-resistant aluminum bronze material of the present embodiment, the Mn content is 8.5% by mass or more and 15.0% by mass or less, preferably 8.5% by mass or more and 13.0% by mass or less, more preferably 8.5% by mass or more and 10.0% by mass. It is below mass%. When the Mn content is within the above numerical range, Fe—Si—Mn hard materials are precipitated in the base material together with Si, Mn, etc. described later, and the wear resistance is improved. Moreover, suitable toughness of the base material can be obtained by increasing the content ratio of Mn.
Mnの含有量が上記数値範囲未満である場合には、母材として必要十分な靭性は得られない。Mnの含有量が上記数値範囲を超える場合には、必要以上の靱性となる。
When the Mn content is less than the above numerical range, sufficient toughness necessary as a base material cannot be obtained. When the Mn content exceeds the above numerical range, the toughness is more than necessary.
また、本実施形態の高温耐摩耗性アルミニウム青銅系材料では、Feの含有量が0.5質量％以上、5.0質量％以下、好ましくは1.0質量％以上、5.0質量％以下、より好ましくは1.5質量％以上、5.0質量％以下である。Feの含有量が上記数値範囲内であることにより、Mn-Siなどと硬質物として母材中に析出し、特に上記硬質物組織の微細化に寄与することで摺動部材としての性質が向上する。
In the high-temperature wear-resistant aluminum bronze material of the present embodiment, the Fe content is 0.5% by mass or more and 5.0% by mass or less, preferably 1.0% by mass or more and 5.0% by mass or less, more preferably 1.5% by mass or more. 5.0 mass% or less. When the Fe content is within the above numerical range, Mn-Si and other hard materials are precipitated in the base material, and especially contribute to the refinement of the hard material structure, improving the properties as a sliding member. To do.
Feの含有量が上記数値範囲を超える場合には、耐食性の低下を招き、固溶限（包共晶点）以上の溶解により組織中に偏析したFeは摩擦係数の増加を招くため、相手材攻撃性が高まる。摺動の相手材が主に鋼材であることを考慮すると、Feの過剰な含有により凝着し易くなるため摺動性は下がることとなる。
If the Fe content exceeds the above numerical range, the corrosion resistance will decrease, and Fe segregated in the structure due to dissolution above the solid solubility limit (inclusion eutectic point) will cause an increase in the coefficient of friction. Increases aggressiveness. Considering that the material to be slid is mainly a steel material, the slidability is lowered because it becomes easy to adhere due to excessive inclusion of Fe.
また、本実施形態の高温耐摩耗性アルミニウム青銅系材料では、Siの含有量が2.0質量％以上、4.0質量％以下、好ましくは2.0質量％以上、3.0質量％以下、より好ましくは2.5質量％以上、3.0質量％以下である。Siの含有量を上記数値範囲内とすることにより、MnおよびFeと共に共晶硬質物を析出し、摺動性を向上させることができる。
In the high-temperature wear-resistant aluminum bronze material of the present embodiment, the Si content is 2.0% by mass or more and 4.0% by mass or less, preferably 2.0% by mass or more and 3.0% by mass or less, more preferably 2.5% by mass or more. 3.0 mass% or less. By setting the Si content within the above numerical range, eutectic hard materials can be precipitated together with Mn and Fe, and the slidability can be improved.
また、本実施形態の高温耐摩耗性アルミニウム青銅系材料は、Coの含有量が0.01質量％以上1.5質量％以下である。本実施形態によれば、Coを含有することにより、耐熱性が向上する。
Moreover, the high-temperature wear-resistant aluminum bronze material of the present embodiment has a Co content of 0.01% by mass or more and 1.5% by mass or less. According to this embodiment, heat resistance improves by containing Co.
図１から４は、本実施形態の高温耐摩耗性アルミニウム青銅系材料を基材に用いた摺動部材の構成を示す図である。図１は固体潤滑材がないタイプの板状の摺動部材１を示す。図２は複数の固体潤滑材３が埋め込まれたタイプの板状の摺動部材２を示す。図３は固体潤滑剤がないタイプの中空円筒状の摺動部材４を示す。図４は複数の固体潤滑剤６が埋め込まれたタイプの中空円筒状の摺動部材５を示す。なお、図１から４は、摺動部材の形態の例を示すものであり、摺動部材の形態はこれに限られない。
FIGS. 1 to 4 are diagrams showing the configuration of a sliding member using the high-temperature wear-resistant aluminum bronze material of the present embodiment as a base material. FIG. 1 shows a plate-like sliding member 1 of a type without a solid lubricant. FIG. 2 shows a plate-like sliding member 2 of a type in which a plurality of solid lubricants 3 are embedded. FIG. 3 shows a hollow cylindrical sliding member 4 of the type without a solid lubricant. FIG. 4 shows a hollow cylindrical sliding member 5 of a type in which a plurality of solid lubricants 6 are embedded. 1 to 4 show examples of the form of the sliding member, and the form of the sliding member is not limited to this.
図に示すように、本実施形態の高温耐摩耗性アルミニウム青銅系材料からなる摺動面には、自己潤滑作用を有する複数の固体潤滑剤が埋設されてもよい。本実施形態の固体潤滑剤には、例えば、黒鉛系、PTFE系、MoS2系、Pb合金系等の固体潤滑剤を用いることができる。
As shown in the drawing, a plurality of solid lubricants having a self-lubricating action may be embedded in the sliding surface made of the high temperature wear resistant aluminum bronze material of the present embodiment. As the solid lubricant of the present embodiment, for example, a solid lubricant such as graphite, PTFE, MoS2 or Pb alloy can be used.
本実施形態によれば、固体潤滑剤が埋設された摺動面を有することにより、高温雰囲気でも潤滑材が摺動面に分散する。これにより、滑り性能を向上させ摺動部材として好適となる。
According to the present embodiment, the lubricant is dispersed on the sliding surface even in a high temperature atmosphere by having the sliding surface in which the solid lubricant is embedded. Thereby, sliding performance is improved and it becomes suitable as a sliding member.
また、本実施形態の高温耐摩耗性アルミニウム青銅系材料のビッカース硬度はHV280以上であり、伸びは0.5％以上であり、引張強さは500N／mm2以上であることが好ましい。硬度をHV280以上とすることにより、高温雰囲気での耐面圧性及び耐摩耗性が向上する。
The high temperature wear resistant aluminum bronze material of the present embodiment preferably has a Vickers hardness of HV280 or more, an elongation of 0.5% or more, and a tensile strength of 500 N / mm 2 or more. By setting the hardness to HV280 or more, surface pressure resistance and wear resistance in a high temperature atmosphere are improved.
また、伸びを0.5％以上とすることにより、摺動部材に好適な材料強度が得られる。なお、ここでいう「伸び」とは、JIS Z2241に記載の引張試験片による測定結果の伸び率を表す。また、引張強さを500N／mm2以上とすることにより、高温雰囲気での耐荷重性能が向上する。本発明の摺動性については、実施例により詳しく説明する。
Moreover, material strength suitable for a sliding member is obtained by making elongation into 0.5% or more. In addition, "elongation" here represents the elongation rate of the measurement result by the tensile test piece as described in JIS Z2241. In addition, by setting the tensile strength to 500 N / mm 2 or more, the load bearing performance in a high temperature atmosphere is improved. The slidability of the present invention will be described in detail with reference to examples.
以下に、本発明の実施例について説明をする。なお、本発明は以下の実施例に限定されない。
Hereinafter, examples of the present invention will be described. The present invention is not limited to the following examples.
表1に示すように、組成の銅合金を高周波炉で溶解して金型を用いて鋳造し、実施例１から８、及び、比較例１から５に示すブロック試験片を作製した。表１に実施例１から８、及び、比較例１から５の試験片の組成値[Wt％]を記載する。組成値は、ICP発光分光分析法で分析を行った結果である。
As shown in Table 1, a copper alloy having a composition was melted in a high frequency furnace and cast using a mold, and block test pieces shown in Examples 1 to 8 and Comparative Examples 1 to 5 were produced. Table 1 shows the composition values [Wt%] of the test pieces of Examples 1 to 8 and Comparative Examples 1 to 5. The composition value is the result of analysis by ICP emission spectroscopy.
表１に示すように、実施例１から実施例８の試験片の組成は、Alの含有量が9.0質量％以上11.0質量％以下であり、Mnの含有量が8.5質量％以上15.0質量％以下であり、Feの含有量が0.5質量％以上5.0質量％以下であり、Niの含有量が1.0質量％以上3.0質量％以下であり、Siの含有量が2.0質量％以上4.0質量％以下であり、Coの含有量が0.01質量％以上1.5質量％以下であり、残部が実質的にCuである。
As shown in Table 1, the compositions of the test pieces of Examples 1 to 8 have an Al content of 9.0% to 11.0% by mass, and an Mn content of 8.5% to 15.0% by mass. Fe content is 0.5% by mass or more and 5.0% by mass or less, Ni content is 1.0% by mass or more and 3.0% by mass or less, and Si content is 2.0% by mass or more and 4.0% by mass or less. , Co content is 0.01 mass% or more and 1.5 mass% or less, and the balance is substantially Cu.
一方、比較例１から比較例５については、その一部の金属の組成が、上記実施例の範囲外となっている。
On the other hand, in Comparative Examples 1 to 5, the composition of some of the metals is out of the range of the above examples.
表２は、実施例１から８、及び、比較例１から５に示すブロック試験片の硬度及び摩耗量を測定した結果を示す。
Table 2 shows the results of measuring the hardness and wear amount of the block test pieces shown in Examples 1 to 8 and Comparative Examples 1 to 5.
硬度は、実施例１から８、及び、比較例１から５に示すブロック試験片のビッカース硬度を室温で測定した。表2に示すように、実施例１から８の試験片の硬度は280以上であることがわかる。
Hardness was determined by measuring the Vickers hardness of the block test pieces shown in Examples 1 to 8 and Comparative Examples 1 to 5 at room temperature. As shown in Table 2, it can be seen that the hardness of the test pieces of Examples 1 to 8 is 280 or more.
摩耗量は、実施例１から８、及び、比較例１から５に示すブロック試験片について、ブロック・オン・リング方式の摺動試験を行い、測定した。摺動試験の条件は、面圧10MPa、摺動速度10m/min、雰囲気温度250℃、摺動距離は500ｍである。摺動試験は専用の試験機を用いて行い、試験機内温度が250℃一定の状態でブロック試験片をリング試験片に押し当てて荷重を与え、リング試験片を一定速度で回転させた。尚、相手材のリング試験片はS45C（高周波焼入れ焼き戻し）を用いた。
The amount of wear was measured by performing a block-on-ring sliding test on the block test pieces shown in Examples 1 to 8 and Comparative Examples 1 to 5. The sliding test conditions were as follows: contact pressure 10 MPa, sliding speed 10 m / min, ambient temperature 250 ° C., sliding distance 500 m. The sliding test was performed using a dedicated testing machine. A block test piece was pressed against the ring test piece at a constant temperature of 250 ° C., a load was applied, and the ring test piece was rotated at a constant speed. In addition, S45C (induction hardening tempering) was used for the ring test piece of the other material.
表２に示すように、実施例１から８のブロック試験片については、摩耗量が35.5μｍ以上42.8μｍ以下となり、摩耗量が少ないことがわかる。一方、比較例１から５に示すブロック試験片については、摩耗量が48.0μｍ以上58.8μｍ以下となり、摩耗量が多いことがわかる。よって、本発明の実施例の効果が確認された。
As shown in Table 2, regarding the block test pieces of Examples 1 to 8, the wear amount is 35.5 μm or more and 42.8 μm or less, indicating that the wear amount is small. On the other hand, the block test pieces shown in Comparative Examples 1 to 5 have a wear amount of 48.0 μm or more and 58.8 μm or less, indicating that the wear amount is large. Therefore, the effect of the Example of this invention was confirmed.
特に、実施例４から実施例８では、摩耗量が40.8μｍ以下であるため、この組成とすることが好ましいことがわかる。さらに、実施例６から実施例８では、摩耗量が36.5μｍ以下であるため、この組成とすることがより好ましいことがわかる。
In particular, in Examples 4 to 8, since the wear amount is 40.8 μm or less, it can be seen that this composition is preferable. Furthermore, in Examples 6 to 8, since the wear amount is 36.5 μm or less, it can be seen that this composition is more preferable.
以上説明したように、本実施形態の高温耐摩耗性アルミニウム青銅系材料によれば、高温雰囲気において耐面圧性と耐摩耗性とを兼ね備えた摺動部材を提供することが可能となる。そして、摺動部材の摩耗量を減らすことで、摺動部材の交換が容易ではない産業用機械において、摺動部材の交換回数を大幅に削減することが可能となる。
As described above, according to the high-temperature wear-resistant aluminum bronze material of this embodiment, it is possible to provide a sliding member that has both surface pressure resistance and wear resistance in a high-temperature atmosphere. By reducing the amount of wear of the sliding member, the number of replacements of the sliding member can be greatly reduced in an industrial machine where the replacement of the sliding member is not easy.
Claims (4)
- Alの含有量が9.0質量％以上11.0質量％以下であり、
Niの含有量が1.0質量％以上3.0質量％以下であり、
Mnの含有量が8.5質量％以上15.0質量％以下であり、
Siの含有量が2.0質量％以上4.0質量％以下であり、
Feの含有量が0.5質量％以上5.0質量％以下であり、
Coの含有量が0.01質量％以上1.5質量％以下であり、
残部が実質的にCuである、
ことを特徴とする高温耐摩耗性アルミニウム青銅系材料。 Al content is 9.0 mass% or more and 11.0 mass% or less,
Ni content is 1.0 mass% or more and 3.0 mass% or less,
Mn content is 8.5 mass% or more and 15.0 mass% or less,
Si content is 2.0 mass% or more and 4.0 mass% or less,
Fe content is 0.5 mass% or more and 5.0 mass% or less,
Co content is 0.01 mass% or more and 1.5 mass% or less,
The balance is substantially Cu,
A high-temperature wear-resistant aluminum bronze material characterized by that. - 前記高温耐摩耗性アルミニウム青銅系材料は、Fe-Mn-Si系硬質物が分散した組織であることを特徴とする請求項１に記載の高温耐摩耗性アルミニウム青銅系材料。 The high-temperature wear-resistant aluminum bronze material according to claim 1, wherein the high-temperature wear-resistant aluminum bronze material has a structure in which an Fe-Mn-Si hard material is dispersed.
- 前記高温耐摩耗性アルミニウム青銅系材料のビッカース硬度は280以上、伸びは0.5％以上、引張強さは500N／mm2以上であることを特徴とする請求項１または２に記載の高温耐摩耗性アルミニウム青銅系材料。 The high-temperature wear resistance of the high-temperature wear-resistant aluminum bronze material is 280 or more, elongation is 0.5% or more, and tensile strength is 500 N / mm 2 or more. Aluminum bronze material.
- 請求項１から３のいずれかに記載された高温耐摩耗性アルミニウム青銅系材料の基材を有することを特徴とする摺動部材。
A sliding member comprising the base material of the high-temperature wear-resistant aluminum bronze material according to any one of claims 1 to 3.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2017501943A JP6764397B2 (en) | 2015-02-24 | 2016-02-24 | High temperature abrasion resistant aluminum bronze material |
| EP16755004.5A EP3263721B1 (en) | 2015-02-24 | 2016-02-24 | High temperature wear-resistant aluminum-bronze-based material |
| US15/551,786 US20180037978A1 (en) | 2015-02-24 | 2016-02-24 | High temperature wear-resistant aluminum-bronze-based material |
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| JP2015-034357 | 2015-02-24 | ||
| JP2015034357 | 2015-02-24 |
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| PCT/JP2016/000987 WO2016136254A1 (en) | 2015-02-24 | 2016-02-24 | High temperature wear-resistant aluminum-bronze-based material |
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| US (1) | US20180037978A1 (en) |
| EP (1) | EP3263721B1 (en) |
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| JP2019091680A (en) * | 2017-11-13 | 2019-06-13 | トクデン株式会社 | Induction heating roller device |
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| CN109788593A (en) | 2017-11-13 | 2019-05-21 | 特电株式会社 | Incude heat generation roller device |
| CN110106393B (en) * | 2019-05-14 | 2021-04-16 | 中国兵器科学研究院宁波分院 | High-manganese wear-resistant aluminum bronze alloy and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS62235446A (en) * | 1986-04-04 | 1987-10-15 | Kobe Steel Ltd | High manganese-aluminum bronze having high strength and superior seizing resistance |
| JP2003147458A (en) * | 2001-11-09 | 2003-05-21 | Taiho Kogyo Co Ltd | Bearing material mede of copper having excellent high temperature wear resistance |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| JP2866384B2 (en) * | 1988-11-04 | 1999-03-08 | オイレス工業株式会社 | Aluminum bronze casting with wear resistance for sliding members |
| JP3300684B2 (en) * | 1999-07-08 | 2002-07-08 | 清仁 石田 | Copper-based alloy having shape memory characteristics and superelasticity, member made of the same, and method of manufacturing the same |
| FR2922898B1 (en) * | 2007-10-31 | 2009-12-04 | Auxitrol Sa | IMPROVEMENTS IN CU-AL-NI-FE ALLOYS AND PROBE FOR MEASURING A PHYSICAL PARAMETER COMPRISING AN ELEMENT IN SUCH ALLOY |
| JP5342882B2 (en) * | 2009-01-06 | 2013-11-13 | オイレス工業株式会社 | High strength brass alloy for sliding member and sliding member |
| US8950941B2 (en) * | 2010-05-21 | 2015-02-10 | Oiles Corporation | High-strength brass alloy for sliding member, and sliding member |
| JP5837487B2 (en) * | 2010-05-31 | 2015-12-24 | 一般社団法人日本銅センター | Copper-based alloy and structural material using the same |
-
2016
- 2016-02-24 US US15/551,786 patent/US20180037978A1/en not_active Abandoned
- 2016-02-24 EP EP16755004.5A patent/EP3263721B1/en active Active
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Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS62235446A (en) * | 1986-04-04 | 1987-10-15 | Kobe Steel Ltd | High manganese-aluminum bronze having high strength and superior seizing resistance |
| JP2003147458A (en) * | 2001-11-09 | 2003-05-21 | Taiho Kogyo Co Ltd | Bearing material mede of copper having excellent high temperature wear resistance |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2019091680A (en) * | 2017-11-13 | 2019-06-13 | トクデン株式会社 | Induction heating roller device |
| JP7213525B2 (en) | 2017-11-13 | 2023-01-27 | トクデン株式会社 | Induction heating roller device |
| TWI799466B (en) * | 2017-11-13 | 2023-04-21 | 日商特電股份有限公司 | Induction heated roll apparatus |
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| Publication number | Publication date |
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| JP6764397B2 (en) | 2020-09-30 |
| JPWO2016136254A1 (en) | 2017-12-07 |
| EP3263721A1 (en) | 2018-01-03 |
| EP3263721A4 (en) | 2018-08-08 |
| EP3263721B1 (en) | 2019-05-29 |
| US20180037978A1 (en) | 2018-02-08 |
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