WO2016116504A1 - Organic molecules for use in optoelectronic components - Google Patents

Organic molecules for use in optoelectronic components Download PDF

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WO2016116504A1
WO2016116504A1 PCT/EP2016/051138 EP2016051138W WO2016116504A1 WO 2016116504 A1 WO2016116504 A1 WO 2016116504A1 EP 2016051138 W EP2016051138 W EP 2016051138W WO 2016116504 A1 WO2016116504 A1 WO 2016116504A1
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group
radicals
substituted
formula
atoms
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PCT/EP2016/051138
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German (de)
French (fr)
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David Ambrosek
Michael Danz
Harald FLÜGGE
Jana Friedrichs
Tobias Grab
Andreas Jacob
Stefan Seifermann
Daniel Volz
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Cynora Gmbh
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Priority to DE112016000384.6T priority Critical patent/DE112016000384A5/en
Publication of WO2016116504A1 publication Critical patent/WO2016116504A1/en

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Definitions

  • the invention relates to purely organic molecules, in particular with dibenzannel faced, nitrogen-containing 6- and 7-rings and their use in organic light-emitting diodes (OLEDs) and in other optoelectronic devices.
  • OLED organic light-emitting diodes
  • OLEDs are usually realized in layer structures, which consist predominantly of organic materials.
  • layer structures consist predominantly of organic materials.
  • FIG. 1 The heart of such components is the emitter layer, in which usually emitting molecules are embedded in a matrix.
  • the energy contained in the excitons can be emitted by the corresponding emitters in the form of light, in this case speaking of electroluminescence.
  • An overview of the function of OLEDs can be found, for example, in H. Yersin, Top. Curr. Chem., 2004, 241, 1 and H. Yersin, "Highly Efficient OLEDs with Phosphorescent Materials”; Wiley-VCH, Weinheim, Germany, 2008.
  • a new generation of OLEDs is based on the utilization of delayed fluorescence (TADF: thermally activated delayed fluorescence or singlet harvesting).
  • TADF thermally activated delayed fluorescence or singlet harvesting
  • Cu (I) complexes can be used which, due to a small energy gap between the lowest triplet state ⁇ and the overlying singlet state Si (AE (Si-Ti)), can thermally recombine triplet exitones into a singlet state.
  • AE overlying singlet state Si
  • transition metal complexes purely organic molecules can exploit this effect.
  • Some such TADF materials have already been used in first optoelectronic devices.
  • the TADF materials often do not have sufficient long-term stability, sufficient thermal or sufficient chemical stability to water and oxygen in the optoelectronic components.
  • not all important emission colors are available.
  • some TADF materials are not vaporizable and therefore not suitable for use in commercial optoelectronic devices.
  • some TADF materials do not have adequate energy layers to the other materials used in the optoelectronic device (e.g., HOMO energies of TADF emitters greater than or equal to -5.9 eV). It is not possible to achieve sufficiently high efficiencies of the optoelectronic components with high current densities or high luminances with all TADF materials.
  • the syntheses of some TADF materials are expensive.
  • the invention relates in one aspect to the provision of organic molecules having a structure of formula 1 or having a structure of formula 1:
  • formula 1 AF1 is a first chemical entity comprising a conjugated system, in particular at least six conjugated ⁇ -electrons (eg in the form of at least one aromatic system);
  • AF2 is a second chemical entity comprising a conjugated system, in particular at least six conjugated ⁇ -electrons (eg in the form of at least one aromatic system);
  • Such organic molecules have an AF1 of the formula Ia or have an AF1 with a structure of the formula 1 a:
  • Y is O, S, NR *, PR *, AsR *, GeR * 2 , BR *, SiR * 2 , 1, 1 'cyclohexyl, methylene, S0 2 , 1, 2-phenylene, 1, 1-dicyanoethylene
  • C C (CN) 2 , CMe 2 , 2,2'-diphenyl ether fragment, 2,2'-diphenyl thioether fragment, 2,2'-benzophenone fragment, 2,2'-diphenylmethane fragment, 2, 2'-Diphenyl-dicyanomethan fragment, wherein fragment means that the attachment of these units takes place via their 2,2'-position to a quaternary carbon atom, for which Y stands in this case.
  • Y is selected from the group consisting of O, S, NR *, PR *, AsR *, GeR * 2 , BR *, SiR * 2 , 1, 1 'cyclohexyl, methylene, 1, 2-phenylene, 1, 1-dicyanoethylene, CMe 2, 2,2'-diphenyl ether fragment, 2,2'-diphenyl thioether fragment, 2,2'-benzophenone fragment, 2,2'-diphenylmethane fragment and 2,2 'diphenyl-dicyanomethane fragment.
  • Y is selected from the group consisting of O, S, NR *, PR *, AsR *, GeR * 2 , BR *, SiR * 2 , 1, 1 'cyclohexyl, methylene, 1, 2-phenylene, 1, 1-dicyanoethylene and CMe 2.
  • Y is selected from the group consisting of SO 2 , AsR *, GeR * 2 , BR *, 1,1-dicyanoethylene, 2,2'-benzophenone fragment and 2,2'-diphenyldicyanomethane fragment.
  • Y is selected from the group consisting of AsR *, GeR * 2 , BR *, 1,1-dicyanoethylene, 2,2'-benzophenone fragment, and 2,2'-diphenyl-dicyanomethane fragment.
  • R ** is either a radical R * or denotes the attachment position to the chemical moiety AF2; two or more substituents R ** may also together form a mono- or polycyclic aliphatic ring system; wherein the attachment to the chemical entity AF2 can also take place via an atom of the radical R ** or R *; and wherein in the molecule exactly one chemical unit AF2 is present.
  • R 3 is independently selected for each occurrence from the group consisting of H, deuterium, phenyl, naphthyl, CF 3 or an aliphatic, aromatic and / or heteroaromatic hydrocarbon radical having 1 to 20 carbon atoms, in which also one or more H Atoms may be replaced by F or CF 3 ; two or more substituents R 3 may also together form a mono- or polycyclic, aliphatic ring system.
  • R is independently selected in each occurrence from the group consisting of H, deuterium, phenyl, naphthyl, F, CF 3 or an aliphatic, aromatic and / or heteroaromatic hydrocarbon radical having 1 to 20 carbon atoms, in which also one or more H Atoms can be replaced by F or CF 3 ; two or more substituents R 8 may also together form a mono- or polycyclic, aliphatic ring system.
  • An aryl group in the sense of this invention contains 6 to 60 aromatic ring atoms;
  • a heteroaryl group contains 5 to 60 aromatic ring atoms, at least one of which represents a heteroatom.
  • the heteroatoms are in particular N, O, and S. If other definitions are given at points in the description, for example with regard to the number of aromatic ring atoms or the heteroatoms contained therein, these other definitions apply.
  • An aryl group or heteroaryl group is understood to mean a simple aromatic cycle, ie benzene, or a simple heteroaromatic cycle, for example pyridine, pyrimidine or thiophene, or a heteroaromatic polycycle, for example naphthalene, phenanthrene, quinoline or carbazole.
  • a condensed (fused) aromatic or heteroaromatic polycycle consists in the context of the present application of two or more fused simple aromatic or heteroaromatic cycles.
  • An aryl or heteroaryl group which may be substituted in each case by the abovementioned radicals and which may be linked via any position on the aromatic or heteroaromatic compounds is understood in particular to mean groups which are derived from benzene, naphthalene, anthracene, phenanthrene, pyrene, Dihydropyrenes, chrysene, perylene, fluoranthene, benzanthracene, benzphenanthrene, tetracene, pentacene, benzpyrene, furan, benzofuran, isobenzofuran, dibenzofuran, thiophene, benzothiophene, isobenzothiophene, dibenzothiophene; Pyrrole, indole, isoindole, carbazole, pyridine, quinoline, isoquinoline, acridine, phenanthridine, benzo-5,6-quinoline, isoquinoline
  • An aromatic ring system in the sense of this invention contains 6 to 60 carbon atoms in the ring system.
  • a heteroaromatic ring system in the context of this invention contains 5 to 60 aromatic ring atoms, at least one of which represents a heteroatom.
  • the heteroatoms are in particular selected from, N, O and / or S.
  • An aromatic or heteroaromatic ring system in the sense of this invention is to be understood as meaning a system which does not necessarily contain only aryl or heteroaryl groups but in which also several aryl or heteroaryl groups by a non-aromatic moiety (in particular less than 10% of the various atoms), such as, for example, a sp3-hybridized C, Si or N atom, an sp 2 -hybridized C, N or O atom or a sp-hybridized carbon atom, may be connected.
  • systems such as 9, T-diaryl fluorene, triarylamine, diaryl ethers, stilbene, etc.
  • aromatic ring systems in the context of this invention, and also systems in which two or more aryl groups, for example by a linear or cyclic alkyl, alkenyl - or Alkynyl group or by a silyl group are connected.
  • systems in which two or more aryl or heteroaryl groups are linked together via single bonds are understood as aromatic or heteroaromatic ring systems in the context of this invention, such as systems such as biphenyl, terphenyl or diphenyltriazine.
  • aromatic or heteroaromatic ring system having 5 to 60 aromatic ring atoms, which may be substituted in each case with radicals as defined above and which may be linked via any positions on the aromatic or heteroaromatic, are understood in particular groups which are derived from benzene, naphthalene , Anthracene, benzanthracene, phenanthrene, benzphenanthrene, pyrene, chrysene, perylene, fluoranthene, naphthacene, pentacene, benzpyrene, biphenyl, biphenylene, terphenyl, terphenyls, quaterphenyl, fluorene, spirobifluorene, dihydrophenanthrene, dihydropyrene, tetrahydro-pyrene, cis- or trans- indenofluorene, truxene, isotruxene, spirotruxene, spiroiso
  • connection of the chemical units AF1 and AF2 to each other takes place in one embodiment when selecting the AF1 from Table 1 and selecting the AF2 from Table 2 in each case over the lower case letters designated positions of each AF (Table 1 and Table 2).
  • AF2 always has a lower HOMO numerical value compared to AF1 (and correspondingly a LUMO numerical value lower in magnitude) than AF2 (
  • the organic molecules are characterized in that
  • the energy values HOMO (AF1), HOMO (AF2), LUMO (AF1), LUMO (AF2) are calculated using the density functional theory (DFT), whereby the attachment positions of the ambifunctional units are saturated with a hydrogen atom according to their chemical valences.
  • DFT density functional theory
  • the limits given refer to orbital energies in eV calculated with the BP86 functional (Becke, A.D. Phys Rev. A1988, 38, 3098-3100, Perdew, J.P. Phys. Rev. B1986, 33, 8822-8827).
  • the chemical entities AF1 and AF2 are linked to one another such that the electronic communication between them is interrupted. This disruption is characterized by localization of the HOMO and LUMO frontier orbits on separate parts of the molecule, allowing for a charge-transfer transition.
  • the electronic communication between the two chemical entities AF1 and AF2 via conjugated bonds is interrupted when the frontier orbitals HOMO and LUMO are located on separate parts of the molecule, allowing for a charge-transfer transition.
  • the localization of the frontier orbitals HOMO or LUMO is determined using the density functional theory (DFT) with the BP86 functional (Becke, AD Phys.Rev.A1988, 38, 3098-3100, Perdew, JP Phys. Rev. B1986, 33, 8822-8827 ):
  • the single electron wave function calculates the single electron density by squaring and integrates it over the space occupied by the part of the molecule.
  • This space can be determined from the atomic coordinates and van der Waals radii of the atoms. The resulting number corresponds to the proportion of orbital on the moiety. A majority separation of the frontier orbitals corresponds to an overlap parameter O in the range 0.1-20% to allow a batch transfer transition.
  • the organic molecules have a structure of the formula 2a-2c or have a structure of the formula 2a-2c, wherein
  • Formula 2a Formula 2b Formula 2c and R *, Y and AF2 are as defined above.
  • organic molecules AF1-AF2 are used, AF1 being selected from the following Table 1:
  • Table 1 List of the first chemical units AF1
  • organic molecules AF1-AF2 are used, with AF1 being selected from the following Table 1 a:
  • Table 1a List of the first chemical units AF1
  • organic molecules AF1-AF2 are used with AF2 selected from Table 2.
  • Table 2 List of the second chemical units AF2.
  • n 0 or 1
  • o 0 or 1
  • p is 0 or 1;
  • VG1 bridging group, is selected from the group consisting of
  • VG2 bridging group at each occurrence is independently selected from the group consisting of CR ** 2 , NR **, O, S and a CC single bond, where two units VG2 are not simultaneously equal to one CC single bond;
  • R ** is independently a residue R * at each occurrence and / or marks a point of attachment to the unit AF1, where exactly one R ** is a point of attachment to a unit AF1.
  • the unit AF2 has a structure of the formula 4 or has a structure of the formula 4
  • the unit AF2 of the organic molecule has a structure of the formula 4A1-4A7 or has a structure of the formula 4A1-4A7
  • X is C (R **) 2 , NR **, oxygen, sulfur; and, moreover, the definitions given for formula 3 apply.
  • the organic molecules have a structure of the formula 5a or have a structure of the formula 5a
  • X is CR * 2 , NR *, oxygen, sulfur, a direct bond, with a maximum of two wildcards X being simultaneously a direct bond, which are not part of the same ring;
  • R ' is R * or is selected from the following units, wherein a maximum of two of the radicals R' are simultaneously one of the following units:
  • the organic molecules have a structure of the formula 6a or have a structure of the formula 6a
  • X is CR * 2 , NR *, oxygen, sulfur, a direct bond, with a maximum of two wildcards X being simultaneously a direct bond, which are not part of the same ring;
  • R ' is R * or is selected from the following units, wherein a maximum of two of the radicals R' are simultaneously one of the following units:
  • the organic molecules have a structure of the formula 7a or have a structure of the formula 7a
  • R ' is R * or is selected from the following units, wherein a maximum of two of the radicals R' are simultaneously one of the following units:
  • Table 3 Examples of organic molecules according to the invention (AF1 -S-AF2). The naming of the molecules on the left contains the component from AF1 from Table 1, which is bound directly to a second chemical group AF2 (from Table 2), which is named on the right.
  • the permissibility of a quantum mechanical transition is, as is well known, accessible either by theoretically derivable spectroscopic selection rules (symmetric molecules) or by measuring the extinction coefficient (UV / VIS spectroscopy) or quantum chemical calculation of the oscillator strength, with permission characterized by a large oscillator strength.
  • the greater the oscillator strength the faster the associated process.
  • saturation effects quickly occur at high current intensities, which adversely affects the component lifetime and prevents the achievement of high brightness levels.
  • the quantum mechanical overlap integral increases so that the decay time drops to values below 50 ps. This is achieved by the AF1 according to the invention.
  • Organic molecules of the present invention are shown in Table 4 which result from combining the above-defined pairs of chemical entities AF1 and AF2 and establishing the linkage.
  • Other organic molecules can be obtained by combining the mentioned molecular units.
  • the naming of the molecules is carried out according to the scheme AF-S-AF, with respect to the naming of the chemical units AF1 on Table 1 and with respect to the naming of the chemical unit AF2 on Table 2, since the numbers used in Tables 1 and 2 also in Table 4. For the sake of clarity, the two numbers are separated by the letter S.
  • Table 4 Inventive organic molecules according to the scheme AF-S-AF. In brackets the values for AHOMO, ALUMO and Gap are given.
  • 53 - S - 1 15 (1.31 1.57 1.58)
  • 53 - S - 1 18 (0.92 0.99 2.16)
  • 53 - S - 1 19 (0.89 1.21 1.95)
  • 53 - S - 132 (0.86 0.92 2.24)
  • 53 - S-449 (0.96 1.53 1.62)
  • 53 - S-451 (1.30 2.14 1.01)
  • 53 - S-452 (1.35 1.80 1.36)
  • 53 - S-460 (1.08 1.88 1.28)
  • 71 - S - 20 (0.96 0.86 2.04)
  • 71 - S - 27 (0.87 1.03 1.87)
  • 71 - S - 28 (0.94 1.30 1.60)
  • 71 - S - 36 (.10 1.81 1.09)
  • 71 - S- 43 (1.51 1.67 1.23)
  • 71 - S- 46 (2.11 1.19 1.71)
  • 71 - S- 61 (0.85 1.01 1.90)
  • 71 - S- 65 (0.86 0.80 2.10)
  • 71 - S- 144 (0.95 1.35 1.55)
  • 71 - S - 150 (2.44 1.31 1.59)
  • 71 - S - 151 (2.35 1.57 1.33)
  • 71 - S - 152 (2.99 1.87 1.03)
  • 77 - S- 29 (1.15 1.23 1.42)
  • 77 - S- 40 (0.98 1.23 1.42)
  • 77 - S- 46 (2.56 1.40 1.26)
  • 77 - S- 61 (.30 1.22 1.44)
  • 77- S- 62 (.18 1.42 1.24)
  • 77- S- 65 (1.31 1.01 1.64)
  • 77- S- 68 (.02 0.97 1.68)
  • 77- S- 79 (.30 1.39 1.27)
  • 77 - S- 80 (.25 1.35 1.31) 77 - S- 81 (1.33 1.47 1.19) 77 - S- 82 (.06 1.66 1.00) 77 - S- 85 (.81 1.20 1.46)
  • 77 - S-233 (1.68 1.17 1.48)
  • 77 - S-234 (1.50 1.26 1.40)
  • 77 - S-237 (1.51 1.55 1.10)
  • 77 - S-238 (0.81 1.41 1.24)
  • 77 - S-462 (0.91 1.58 1.07) 77 - S-467 (0.91 0.98 1.68) 77 - S-468 (1.1 1 1.28 1.37) 77 - S-469 (1.20 1.71 0.95)
  • 337- S- 56 (1.21 1.24 2.07) 337- S- 61 (.19 1.76 1.55) 337- S- 62 (.07 1.96 1.35) 337- S- 65 (.20 1.55 1.76)
  • 337- S-454 (0.98 1.14 2.17) 337- S-455 (0.97 1.41 1.90) 337- S-457 (1.12 1.91 1.39) 337- S-459 (0.90 2.15 1.16) 337- S- 460 (1.39 2.35 0.96) 337- S-461 (1.1 1 2.11 1.20) 337- S-462 (0.80 2.12 1.19) 337- S-468 (1.00 1.82 1.49)
  • 354- S-205 (0.92 1.26 1.96)
  • 354- S-206 (0.91 2.18 1.05)
  • 354- S-207 (1.43 2.12 1.10)
  • 354- S-213 (1.36 1.16 2.07)
  • 354- S-231 (1.91 1.93 1.29)
  • 354- S-233 (1.29 1.36 1.87)
  • 354- S-234 (1.1 1 1.44 1.79)
  • 354- S-237 (1.12 1.73 1.49)
  • 354- S-286 (0.95 1.02 2.20) 354- S-289 (1.00 0.81 2.41) 354- S-290 (1.03 1.44 1.79) 354- S-291 (2.17 1.84 1.38)
  • 354- S-342 (2.91 1.86 1.36)
  • 354- S-358 (0.81 1.17 2.05)
  • 354- S- 367 (1.44 1.81 1.42)
  • 354- S-371 (2.60 1.95 1.27)
  • further residues R are added to the chemically substitutable positions of the organic molecules so obtained in order to increase the solubility of the emitters and / or to allow the polymerizability without significantly changing the electronic properties of the molecule, so that even when using R is an emitter, where
  • R 3 in each occurrence is identical or different H, deuterium, F, CF 3 or an aliphatic, aromatic and / or heteroaromatic hydrocarbon radical having 1 to 20 carbon atoms, in which one or more H atoms replaced by F or CF 3 could be; two or more substituents R 3 may also together form a mono- or polycyclic, aliphatic ring system.
  • Polymerizable radicals are those radicals which carry polymerizable functional units which can be homopolymerized with themselves or copolymerized with other monomers.
  • the molecules of the invention can be obtained as a polymer having the following repeating units of the formulas 8 and 9, which can be used as polymers in the light-emitting layer of the optoelectronic component.
  • L1 and L2 represent the same or different linker groups having 0 to 20, especially 1 to 15, or 2 to 10 carbon atoms, and wherein the wavy line indicates the position by which the linker group bonds to the organic molecule of the Formula 1 is connected.
  • the linker group L1 and / or L2 has a form -X-L3-, where X is O or S and L3 is a linker group selected from the group consisting of a substituted and unsubstituted alkylene group (linear, branched or cyclic) and a substituted and unsubstituted arylene group, in particular a substituted or unsubstituted alkylene group having 1 to 10 carbon atoms or a substituted or unsubstituted phenylene group, whereby combinations are possible.
  • R is independently selected in each occurrence from the group consisting of H, deuterium, phenyl, naphthyl, F, CF 3 or an aliphatic, aromatic and / or heteroaromatic hydrocarbon radical having 1 to 20 carbon atoms, in which also one or more H Atoms can be replaced by F or CF 3 ; It can have two or more Substituents R can also form a mono- or polycyclic aliphatic ring system with one another, furthermore R can be: a linear alkoxy or thioalkoxy group with 1 to 40 C atoms or a linear alkenyl or alkinyl group with 2 to 40 C atoms or a branched or cyclic alkyl, alkenyl, alkynyl, alkoxy or thioalkoxy group having 3 to 40 carbon atoms.
  • the polymerisable functional units via a linker group of the formulas 16 to 21, which have a hydroxyl moiety are attached to an organic molecule of the formula 1 and the resulting compounds with themselves homopolymerized or copolymerized with other suitable monomers.
  • Polymers having a unit according to formula 8 or formula 9 can either exclusively comprise repeat units having a structure of general formula 8 or 9, or repeat units having a different structure.
  • repeat units having other structures include moieties resulting from corresponding monomers typically used or used in copolymerizations.
  • Examples of such repeating units, which consist of Monomers are repeating units having unsaturated moieties such as ethylene or styrene.
  • AE Si-T "i) value between the lowest excited singlet (Si) and the underlying triplet (T-i) state of less than 0.2 eV, in particular less than 0.1 eV, and / or
  • the invention relates in one aspect to the use of an organic molecule according to the invention as a luminescent emitter and / or as a host material and / or as an electron transport material and / or as a hole injection material and / or as a hole blocking material in an optoelectronic component, which is produced in particular by a vacuum evaporation method or from solution , wherein the optoelectronic component is in particular selected from the group consisting of:
  • OLEDs organic light emitting diodes
  • the proportion of the organic molecule according to the invention on the luminescent emitter and / or host material and / or electron transport material and / or hole injection material and / or hole blocking material in one embodiment is 1% to 99% (wt%), in particular the proportion of the emitter in optical light-emitting components especially in OLEDs, between 5% and 80%.
  • the invention relates to optoelectronic components comprising an organic molecule according to the invention, wherein the optoelectronic component is in particular formed as a component selected from the group consisting of organic light-emitting diode (OLED), light-emitting electrochemical cell, OLED sensor, in particular in non-hermetically externally shielded gas and vapor sensors, organic diode, organic solar cell, organic transistor, organic field effect transistor, organic laser and down-conversion Element.
  • OLED organic light-emitting diode
  • OLED sensor light-emitting electrochemical cell
  • OLED sensor in particular in non-hermetically externally shielded gas and vapor sensors
  • organic diode organic solar cell
  • organic transistor organic field effect transistor
  • organic laser and down-conversion Element organic laser and down-conversion Element
  • One embodiment relates to the optoelectronic component according to the invention comprising a substrate, an anode and a cathode, wherein the anode and the cathode are applied to the substrate, and at least one light-emitting layer which is arranged between anode and cathode and which contains an organic molecule according to the invention.
  • the organic molecule is used as the emission material in an emission layer, wherein it can be used in combination with at least one host material or, in particular, as a pure layer.
  • the proportion of the organic molecule as emission material in an emission layer in optical light-emitting components, in particular in OLEDs is between 5% and 80% (% by weight).
  • the light-emitting layer having an organic molecule according to the invention is applied to a substrate.
  • the invention relates to an optoelectronic component in which the light-emitting layer comprises only an organic molecule according to the invention in 100% concentration, wherein the anode and the cathode is applied to the substrate, and the light-emitting layer between the anode and cathode is applied.
  • the optoelectronic component has at least one host material, in particular the excited singlet state (Si) and / or the excited triplet state (Ti) of the at least one host material being higher than the excited singlet state (Si) and / or the excited triplet state (Ti) of the organic molecule, and wherein the anode and the cathode are deposited on the substrate, and the light emitting layer is disposed between the anode and the cathode.
  • the optoelectronic component comprises a substrate, an anode, a cathode and at least one hole-injecting and an electron-injecting layer and at least one light-emitting layer, wherein the at least one light-emitting layer comprises an organic molecule according to the invention and a host material whose triplet ( ⁇ ) and singlet (Si) energy levels are higher in energy than the triplet ( ⁇ ) and singlet (Si) energy levels of the organic molecule, and where the anode and cathode are deposited on the substrate, and the hole and electron injecting Layer between the anode and cathode is applied and the light-emitting layer between holes and electron injecting layer is applied.
  • the optoelectronic component comprises a substrate, an anode, a cathode and at least one hole-injecting and an electron-injecting layer, and at least one hole-transporting and one electron-transporting layer, and at least one light-emitting layer, wherein the at least one light-emitting layer
  • the organic molecule and a host material whose triplet (Ti) and singlet (Si) energy levels are higher in energy than the triplet (Ti) and singlet (Si) energy levels of the organic molecule, and wherein the anode and the cathode the substrate is applied, and the hole and electron injecting layer is applied between anode and cathode, and the hole and electron transporting layer is applied between hole and electron injecting layer, and the light emitting layer between holes and electronentr is applied ansportierende layer.
  • the optoelectronic component has at least one host material made from a material according to formula 1.
  • the light-emitting layer contains fluorescent or phosphorescent materials which have a structure of formula 1.
  • the optoelectronic component form an organic molecule according to formula 1 and a functional material, for example in the form of another emitter material, a host material, or another organic molecule which is used to form an exciplex with the molecule of formula 1 is capable of an exciplex.
  • Functional materials include, for example, host materials such as MCP, electron transport materials such as TPBI and hole transport materials such as NPD or MTDATA.
  • Exciplexes are adducts of electronically excited and electronically grounded molecules capable of emitting light.
  • the emission is characterized by thermally activated delayed fluorescence (TADF).
  • TADF thermally activated delayed fluorescence
  • organic molecules according to formula 1 are used as charge transport layer.
  • the invention in one aspect relates to a light-emitting material comprising an organic molecule and a host material according to the invention, wherein the triplet ( ⁇ ) and singlet (Si) energy levels of the host material are higher than the triplet (Ti) and singlet (Si) energies.
  • One aspect of the invention relates to a method for producing an optoelectronic component comprising an organic molecule according to the invention.
  • the method comprises processing the organic molecule by a vacuum evaporation method or from a solution.
  • the method comprises applying the organic molecule to a carrier, the application being carried out in particular wet-chemically, by means of colloidal suspension or by means of sublimation.
  • One aspect of the invention relates to a method for changing the emission and / or absorption properties of an electronic component, wherein an organic molecule according to the invention is introduced into a matrix material for conducting electrons or holes in an optoelectronic component.
  • the invention additionally relates to the use of a molecule according to the invention for converting UV radiation or blue light into visible light, in particular into green, yellow or red light (down conversion), in particular in an optoelectronic component of the type described here ,
  • the invention relates to an application in which at least one material with a structure according to formula 1 is excited to emit by external energetic excitation.
  • the external stimulation can be electronic or optical or radioactive.
  • the optoelectronic component form an organic molecule according to formula 1 and a functional material, for example in the form of another emitter material, a host material, or another organic molecule which is used to form an exciplex with the molecule of formula 1 is capable of an exciplex.
  • Functional materials include host materials such as MCP, electron transport materials such as TPBI and hole transport materials such as NPD or MTDATA.
  • Exciplexes are adducts of electronically excited and electronically grounded molecules capable of emitting light.
  • BP86 functional (Becke, AD Phys Rev. A1988, 38, 3098-3100, Perdew, JP Phys Rev. B1986, 33, 8822-8827) was used, with the resolution-of-identity Approach (RI) (Sierka, M., Hogekamp, A., Ahlrichs, RJ Chem. Phys., 2003, 18, 9136-9148; Becke, AD, J. Chem. Phys., 98 (1993) 5648-5652; Lee, C; Yang, W; Parr, RG Phys. Rev. B 37 (1988) 785-789).
  • RI resolution-of-identity Approach
  • Excitation energies were determined in the BP86 optimized structure using the time-dependent DFT method (TD-DFT) using the B3LYP functional (Becke, AD, J. Chem. Phys. 98 (1993) 5648-5652, Lee, C; Yang, W; Parr, RG Phys Rev. B 37 (1988) 785-789; Vosko, SH; Wilk, L; Nusair, M. Can. J. Phys. 58 (1980) 1200-121 1; Stephens, PJ Devlin, FJ; Chabalowski, CF; Frisch, MJJ Phys. Chem 98 (1994) 1 1623-1 1627).
  • def2-SV (P) base sets Weigend, F., Ahlrichs, R. Phys. Chem. Chem. Phys., 2005, 7, 3297-3305, Rappoport, D .; Furche, FJ Chem. Phys. 2010, 133, 134105 / 1-134105 / 1
  • All DFT calculations were performed with the Turbomole program package (version 6.5) (TURBOMOLE V6.4 2012, University of Düsseldorf and Anlagens scholar Düsseldorf GmbH, 1989-2007, TURBOMOLE GmbH, since 2007, http://www.turbomole.com) ,

Abstract

The invention relates to organic molecules, in particular for use in optoelectronic components, such as OLEDs. The organic molecule according to the invention has a structure of formula 1 (I) AF1 is a first chemical entity having a conjugated system; AF2 is a second chemical entity having a conjugated system; and AF1 ≠ AF2; AF1 having a structure of formula 1a or having a structure of formula 1a (1a).

Description

Organische Moleküle  Organic molecules
zur Verwendung in optoelektronischen Bauelementen  for use in optoelectronic devices
Die Erfindung betrifft rein organische Moleküle, insbesondere mit dibenzannelierten, stickstoffhaltigen 6- und 7-Ringen sowie deren Verwendung in organischen lichtemittierenden Dioden (OLEDs) und in anderen optoelektronischen Bauelementen. The invention relates to purely organic molecules, in particular with dibenzannelierten, nitrogen-containing 6- and 7-rings and their use in organic light-emitting diodes (OLEDs) and in other optoelectronic devices.
Stand der Technik State of the art
In den letzten Jahren hat sich die auf OLED (organische lichtemittierende Dioden) basierende Technik im Bereich Bildschirmtechnik etabliert, so dass nun die ersten hierauf aufbauenden kommerziellen Produkte erhältlich werden. Neben der Bildschirmtechnik eignen sich OLEDs auch für die Anwendung in flächiger Beleuchtungstechnik. Aus diesem Grund wird bezüglich der Entwicklung neuer Materialien intensive Forschung betrieben. In recent years, the technology based on OLED (organic light-emitting diodes) has established itself in the field of display technology, so that now the first commercial products based on it are available. In addition to screen technology, OLEDs are also suitable for use in flat lighting technology. For this reason, intensive research is being conducted on the development of new materials.
OLEDs sind in der Regel in Schichtenstrukturen realisiert, welche überwiegend aus organischen Materialien bestehen. Zum besseren Verständnis ist in Figur 1 ein vereinfachter Aufbau exemplarisch dargestellt. Herzstück solcher Bauteile ist die Emitterschicht, in der in der Regel emittierende Moleküle in einer Matrix eingebettet sind. In dieser Schicht treffen sich negative Ladungsträger (Elektronen) und positive Ladungsträger (Löcher), die zu sogenannten Exzitonen (= angeregte Zustände) rekombinieren. Die in den Exzitonen enthaltene Energie kann von den entsprechenden Emittern in Form von Licht abgegeben werden, wobei man in diesem Fall von Elektrolumineszenz spricht. Einen Überblick über die Funktion von OLEDs findet sich beispielsweise bei H. Yersin, Top. Curr. Chem. 2004, 241 , 1 und H. Yersin, „Highly Efficient OLEDs with Phosphorescent Materials"; Wiley-VCH, Weinheim, Germany, 2008. OLEDs are usually realized in layer structures, which consist predominantly of organic materials. For a better understanding, a simplified structure is shown by way of example in FIG. The heart of such components is the emitter layer, in which usually emitting molecules are embedded in a matrix. In this layer, negative charge carriers (electrons) and positive charge carriers (holes) meet, which recombine to form so-called excitons (= excited states). The energy contained in the excitons can be emitted by the corresponding emitters in the form of light, in this case speaking of electroluminescence. An overview of the function of OLEDs can be found, for example, in H. Yersin, Top. Curr. Chem., 2004, 241, 1 and H. Yersin, "Highly Efficient OLEDs with Phosphorescent Materials"; Wiley-VCH, Weinheim, Germany, 2008.
Seit den ersten Berichten bezüglich OLEDs (Tang et al. Appl. Phys. Lett. 1987, 51 , 913) ist diese Technik besonders auf dem Gebiet der Emittermaterialien immer weiterentwickelt worden. Während die ersten Materialien, die auf rein organischen Molekülen beruhen, aufgrund von Spinstatistik maximal 25 % der Exzitonen in Licht umwandeln konnten, konnte durch die Verwendung von phosphoreszierenden Verbindungen dieses grundsätzliche Problem umgangen werden, so dass zumindest theoretisch alle Exzitonen in Licht umgewandelt werden können. Bei diesen Materialien handelt es sich in der Regel um Übergangsmetall-Komplexverbindungen, in denen das Metall aus der dritten Periode der Übergangsmetalle gewählt wird. Hierbei werden vorwiegend sehr teure Edelmetalle wie Iridium, Platin oder auch Gold eingesetzt. (Siehe dazu auch H. Yersin, Top. Curr. Chem. 2004, 241 , 1 und M. A. Baldo, D. F. O'Brien, M. E. Thompson, S. R. Forrest, Phys. Rev. B 1999, 60, 14422). Neben den Kosten ist auch die Stabilität der Materialien zum Teil nachteilig für die Verwendung. Since the first reports on OLEDs (Tang et al., Appl. Phys. Lett., 1987, 51, 913), this technique has been developed further, especially in the field of emitter materials. While the first materials, which are based on purely organic molecules, could convert up to 25% of the excitons into light due to spin statistics, the use of phosphorescent compounds has circumvented this fundamental problem, so that at least theoretically all excitons can be converted into light. These materials are typically transition metal complex compounds in which the metal is selected from the third period of the transition metals. Here are mainly used very expensive precious metals such as iridium, platinum or gold. (See also H. Yersin, Top. Curr. Chem. 2004, 241, 1, and MA Baldo, DF O'Brien, ME Thompson, SR Forrest, Phys. Rev. B 1999, 60, 14422). In addition to the cost and the stability of the materials is partly detrimental to the use.
Eine neue Generation von OLEDs basiert auf der Ausnutzung von verzögerter Fluoreszenz (TADF: thermally activated delayed fluorescence oder auch singlet harvesting). Hierbei können beispielsweise Cu(l)-Komplexe verwendet werden, die aufgrund eines geringen Energieabstandes zwischen dem untersten Triplett-Zustand ΤΊ und dem darüberliegenden Singulett-Zustand Si (AE(Si-T-i) Triplett-Exitonen thermisch in einen Singulett-Zustand rückbesetzen können. Neben der Verwendung von Übergangsmetallkomplexen können auch rein organische Moleküle diesen Effekt ausnutzen.  A new generation of OLEDs is based on the utilization of delayed fluorescence (TADF: thermally activated delayed fluorescence or singlet harvesting). In this case, for example, Cu (I) complexes can be used which, due to a small energy gap between the lowest triplet state ΤΊ and the overlying singlet state Si (AE (Si-Ti)), can thermally recombine triplet exitones into a singlet state. In addition to the use of transition metal complexes, purely organic molecules can exploit this effect.
Einige solcher TADF-Materialien wurden bereits in ersten optoelektronischen Bauelementen eingesetzt. Die bisherigen Lösungen weisen jedoch Nachteile und Probleme auf: Die TADF- Materialien weisen in den optoelektronischen Bauelementen oftmals keine ausreichende Langzeitstabilität, keine ausreichende thermische oder keine ausreichende chemische Stabilität gegenüber Wasser und Sauerstoff auf. Außerdem sind nicht alle wichtigen Emissionsfarben verfügbar. Weiterhin sind einige TADF-Materialien nicht verdampfbar und dadurch für den Einsatz in kommerziellen optoelektronischen Bauteilen nicht geeignet. Auch weisen einige TADF-Materialien keine passenden Energielagen zu den weiteren im optoelektronischen Bauteil verwendeten Materialien (z.B. HOMO-Energien von TADF- Emittern von größer gleich -5,9 eV) auf. Nicht mit allen TADF-Materialien lassen sich ausreichend hohe Effizienzen der optoelektronischen Bauelemente bei hohen Stromdichten bzw. hohe Leuchtdichten erreichen. Weiterhin sind die Synthesen einiger TADF-Materialien aufwendig.  Some such TADF materials have already been used in first optoelectronic devices. However, the previous solutions have disadvantages and problems: The TADF materials often do not have sufficient long-term stability, sufficient thermal or sufficient chemical stability to water and oxygen in the optoelectronic components. In addition, not all important emission colors are available. Furthermore, some TADF materials are not vaporizable and therefore not suitable for use in commercial optoelectronic devices. Also, some TADF materials do not have adequate energy layers to the other materials used in the optoelectronic device (e.g., HOMO energies of TADF emitters greater than or equal to -5.9 eV). It is not possible to achieve sufficiently high efficiencies of the optoelectronic components with high current densities or high luminances with all TADF materials. Furthermore, the syntheses of some TADF materials are expensive.
Beschreibung description
Die Erfindung betrifft in einem Aspekt durch die Bereitstellung von organischen Molekülen gelöst, die eine Struktur der Formel 1 aufweisen oder eine Struktur der Formel 1 haben: The invention relates in one aspect to the provision of organic molecules having a structure of formula 1 or having a structure of formula 1:
Figure imgf000004_0001
Figure imgf000004_0001
Formel 1 AF1 ist eine erste chemische Einheit, aufweisend ein konjugiertes System, insbesondere mindestens sechs in Konjugation stehende π-Elektronen (z. B. in Form mindestens eines aromatischen Systems); formula 1 AF1 is a first chemical entity comprising a conjugated system, in particular at least six conjugated π-electrons (eg in the form of at least one aromatic system);
AF2 ist eine zweite chemische Einheit, aufweisend ein konjugiertes System, insbesondere mindestens sechs in Konjugation stehende π-Elektronen (z. B. in Form mindestens eines aromatischen Systems);  AF2 is a second chemical entity comprising a conjugated system, in particular at least six conjugated π-electrons (eg in the form of at least one aromatic system);
wobei AF1 + AF2; where AF1 + AF2;
Derartige organische Moleküle (Emitter) weisen eine AF1 der Formel 1 a auf oder haben eine AF1 mit einer Struktur nach Formel 1 a: Such organic molecules (emitters) have an AF1 of the formula Ia or have an AF1 with a structure of the formula 1 a:
Figure imgf000005_0001
Figure imgf000005_0001
Formel 1 a Formula 1 a
In Formel 1 a bedeutet: In formula 1 a means:
Y ist O, S, NR*, PR*, AsR*, GeR*2, BR*, SiR*2, 1 , 1 '-Cyclohexyl, Methylen, S02, 1 ,2- Phenylen, 1 , 1-Dicyanoethylen C=C(CN)2, CMe2, 2,2'-Diphenylether-Fragment, 2,2'- Diphenylthioether-Fragment, 2,2'-Benzophenon-Fragment, 2,2'-Diphenyl-methan-Fragment, 2,2'-Diphenyl-dicyanomethan-Fragment, wobei Fragment dabei bedeutet, dass die Anbindung dieser Einheiten über deren 2,2'-Position an ein quaternäres C-Atom erfolgt, wofür Y in diesem Falle steht. Y is O, S, NR *, PR *, AsR *, GeR * 2 , BR *, SiR * 2 , 1, 1 'cyclohexyl, methylene, S0 2 , 1, 2-phenylene, 1, 1-dicyanoethylene C = C (CN) 2 , CMe 2 , 2,2'-diphenyl ether fragment, 2,2'-diphenyl thioether fragment, 2,2'-benzophenone fragment, 2,2'-diphenylmethane fragment, 2, 2'-Diphenyl-dicyanomethan fragment, wherein fragment means that the attachment of these units takes place via their 2,2'-position to a quaternary carbon atom, for which Y stands in this case.
In einer Ausführungsform ist Y ausgewählt aus der Gruppe bestehend aus O, S, NR*, PR*, AsR*, GeR*2, BR*, SiR*2, 1 ,1 '-Cyclohexyl, Methylen, 1 ,2-Phenylen, 1 ,1 -Dicyanoethylen, CMe2, 2,2'-Diphenylether-Fragment, 2,2'-Diphenylthioether-Fragment, 2,2'-Benzophenon- Fragment, 2,2'-Diphenyl-methan-Fragment und 2,2'-Diphenyl-dicyanomethan-Fragment. In one embodiment, Y is selected from the group consisting of O, S, NR *, PR *, AsR *, GeR * 2 , BR *, SiR * 2 , 1, 1 'cyclohexyl, methylene, 1, 2-phenylene, 1, 1-dicyanoethylene, CMe 2, 2,2'-diphenyl ether fragment, 2,2'-diphenyl thioether fragment, 2,2'-benzophenone fragment, 2,2'-diphenylmethane fragment and 2,2 'diphenyl-dicyanomethane fragment.
In einer Ausführungsform ist Y ausgewählt aus der Gruppe bestehend aus O, S, NR*, PR*, AsR*, GeR*2, BR*, SiR*2, 1 , 1 '-Cyclohexyl, Methylen, 1 ,2-Phenylen, 1 , 1 -Dicyanoethylen und CMe2. In einer Ausführungsform ist Y ausgewählt aus der Gruppe bestehend aus S02, AsR*, GeR*2, BR*, 1 , 1-Dicyanoethylen, 2,2'-Benzophenon-Fragment und 2,2'-Diphenyl- dicyanomethan-Fragment. In one embodiment, Y is selected from the group consisting of O, S, NR *, PR *, AsR *, GeR * 2 , BR *, SiR * 2 , 1, 1 'cyclohexyl, methylene, 1, 2-phenylene, 1, 1-dicyanoethylene and CMe 2. In one embodiment, Y is selected from the group consisting of SO 2 , AsR *, GeR * 2 , BR *, 1,1-dicyanoethylene, 2,2'-benzophenone fragment and 2,2'-diphenyldicyanomethane fragment.
In einer Ausführungsform ist Y ausgewählt aus der Gruppe bestehend aus AsR*, GeR*2, BR*, 1 ,1 -Dicyanoethylen, 2,2'-Benzophenon-Fragment und 2,2'-Diphenyl-dicyanomethan- Fragment. In one embodiment, Y is selected from the group consisting of AsR *, GeR * 2 , BR *, 1,1-dicyanoethylene, 2,2'-benzophenone fragment, and 2,2'-diphenyl-dicyanomethane fragment.
R** ist entweder ein Rest R* oder kennzeichnet die Anknüpfungsposition an die chemische Einheit AF2; dabei können zwei oder mehrere Substituenten R** auch miteinander ein mono- oder polycyclisches, aliphatisches Ringsystem bilden; wobei die Anknüpfung an die chemische Einheit AF2 auch über ein Atom des Rests R** oder R* erfolgen kann; und wobei im Molekül genau eine chemische Einheit AF2 vorhanden ist. R ** is either a radical R * or denotes the attachment position to the chemical moiety AF2; two or more substituents R ** may also together form a mono- or polycyclic aliphatic ring system; wherein the attachment to the chemical entity AF2 can also take place via an atom of the radical R ** or R *; and wherein in the molecule exactly one chemical unit AF2 is present.
R* ist bei jedem Auftreten unabhängig voneinander ausgewählt aus der Gruppe bestehend aus H, Deuterium, Phenyl, Naphthyl, N(R2)2, -CN, -NC, -SCN, -CF3, -N02, C(=0)OH, C(=0)OR3, C(=0)N(R3)2, C(=0)SR3, C(=S)SR3, Si(R4)3, B(OR5)2, B(N(R6)2)2, C(=0)R3, P(=0)(R7)2, As(=0)(R7)2, P(=S)(R7)2, As(=S)(R7)2, S(=0)R3, S=NR3, S(=0)NR3, S(=0)2NR3, S(=0)2R3, 0-S(=0)2R3, SF5, eine lineare Alkyl-, Alkoxy- oder Thioalkoxygruppe mit 1 bis 40 C-Atomen oder eine lineare Alkenyl- oder Alkinylgruppe mit 2 bis 40 C-Atomen oder eine verzweigte oder cyclische Alkyl-, Alkenyl-, Alkinyl-, Alkoxy- oder Thioalkoxygruppe mit 3 bis 40 C-Atomen, die jeweils mit einem oder mehreren Resten R9 substituiert sein kann, wobei eine oder mehrere benachbarte CH2-Gruppen durch -R9C=CR9-, -C=C-, bzw. eine benachbarte CH2-Gruppe durch -Si(R4)2-, -Ge(R4)2-, -Sn(R4)2-, -C(=0)-, -C(=S)-, -C(=Se)-, - C=N-, -C(=0)0-, -C(=0)N(R3)-, -P(=0)(R7)-, -As(=0)(R7)-, -P(=S)(R7), -As(=S)(R7)-, -S(=0)-, -S(=0)2-, -NR2-, -O-, oder -S- ersetzt sein können und wobei ein oder mehrere H-Atome durch Deuterium, F, Cl, Br, I, CN, CF3 oder N02 ersetzt sein können, oder ein aromatisches oder heteroaromatisches Ringsystem mit 5 bis 60 aromatischen Ringatomen, das jeweils durch einen oder mehrere Reste R2 substituiert sein kann, oder eine Aryloxy- oder Heteroaryloxygruppe mit 5 bis 60 aromatischen Ringatomen, die durch einen oder mehrere Reste R9 substituiert sein kann, oder eine Diarylaminogruppe, Diheteroarylaminogruppe oder Arylheteroarylaminogruppe mit 10 bis 40 aromatischen Ringatomen, welche durch einen oder mehrere Reste R9 substituiert sein kann, oder eine Kombination dieser Systeme; dabei können zwei oder mehrere dieser Substituenten R* auch miteinander ein mono- oder polycyclisches, aliphatisches, aromatisches und/oder benzoannelliertes Ringsystem bilden. In einer Ausführungsform können zwei oder mehrere dieser Substituenten R* auch miteinander ein monozyklisches aliphatisches Ringsystem mit insgesamt fünf oder sechs Ringgliedern bilden. R * in each occurrence is independently selected from the group consisting of H, deuterium, phenyl, naphthyl, N (R 2 ) 2 , -CN, -NC, -SCN, -CF 3 , -NO 2 , C (= 0 ) OH, C (= O) OR 3 , C (= O) N (R 3 ) 2 , C (= O) SR 3 , C (= S) SR 3 , Si (R 4 ) 3 , B (OR 5 ) 2 , B (N (R 6 ) 2 ) 2 , C (= O) R 3 , P (= O) (R 7 ) 2 , As (= O) (R 7 ) 2 , P (= S) ( R 7 ) 2 , As (= S) (R 7 ) 2 , S (= O) R 3 , S = NR 3 , S (= O) NR 3 , S (= O) 2 NR 3 , S (= 0 ) 2 R 3 , 0-S (= O) 2 R 3 , SF 5 , a linear alkyl, alkoxy or thioalkoxy group having 1 to 40 carbon atoms or a linear alkenyl or alkynyl group having 2 to 40 carbon atoms or a branched or cyclic alkyl, alkenyl, alkynyl, alkoxy or thioalkoxy group having from 3 to 40 carbon atoms, each of which may be substituted with one or more R 9 radicals, one or more adjacent CH 2 groups represented by -R 9 C = CR 9 -, -C = C-, or an adjacent CH 2 group by -Si (R 4 ) 2 -, -Ge (R 4 ) 2 -, -Sn (R 4 ) 2 -, - C (= O) -, -C (= S) -, -C (= Se) -, - C = N-, -C (= O) O-, -C (= O) N (R 3 ) - , -P (= 0) (R 7 ) -, -As (= 0) (R 7 ) -, -P (= S) (R 7 ), -As (= S) (R 7 ) -, -S (= O) -, -S (= 0) 2 -, -NR 2 -, -O-, or -S- may be replaced and wherein one or more H atoms may be replaced by deuterium, F, Cl, Br, I, CN, CF 3 or N0 2 , or an aromatic or heteroaromatic ring system having 5 to 60 aromatic ring atoms, each of which may be substituted by one or more radicals R 2 , or an aryloxy or heteroaryloxy group having 5 to 60 aromatic ring atoms which are substituted by one or more radicals R 9 may, or a Diarylaminogruppe, Diheteroarylaminogruppe or arylheteroarylamino group having 10 to 40 aromatic ring atoms, which may be substituted by one or more radicals R 9 , or a combination of these systems; two or more of these substituents R * may also together form a mono- or polycyclic, aliphatic, aromatic and / or benzoannellated ring system. In one embodiment, two or more of these substituents R * may also together form a monocyclic aliphatic ring system with a total of five or six ring members.
R2 ist bei jedem Auftreten unabhängig voneinander ausgewählt aus der Gruppe bestehend aus H, Deuterium, Phenyl, Naphthyl, CF3, C(=0)OR3, C(=0)N(R2)2, Si(R4)3, C(=0)R3, P(=0)(R7)2, As(=0)(R7)2 P(=S)(R7)2, As(=S)(R7)2, S(=0)R3, S(=0)2R3, eine lineare Alkyl-, Alkoxy- oder Thioalkoxygruppe mit 1 bis 40 C-Atomen oder eine lineare Alkenyl- oder Alkinylgruppe mit 2 bis 40 C-Atomen oder eine verzweigte oder cyclische Alkyl-, Alkenyl-, Alkinyl-, Alkoxy- oder Thioalkoxygruppe mit 3 bis 40 C-Atomen, die jeweils mit einem oder mehreren Resten R9 substituiert sein kann, wobei eine oder mehrere benachbarte CH2- Gruppen durch -R9C=CR9-, -C=C-, bzw. eine benachbarte CH2-Gruppe durch -Si(R4)2-, - Ge(R4)2-, -Sn(R4)2-, -C(=0)-, -C(=S)-, -C(=Se)-, -C=N-, -C(=0)0-, -C(=0)N(R3)-, -P(=0)(R7)-, -As(=0)(R7)-, -P(=S)(R7)-, -As(=S)(R7)-, -S(=0)-, -S(=0)2-, -NR2-, -O-, oder -S- ersetzt sein können und wobei ein oder mehrere H-Atome durch Deuterium, F, Cl, Br, I, CN, CF3 oder N02 ersetzt sein können, oder ein aromatisches oder heteroaromatisches Ringsystem mit 5 bis 60 aromatischen Ringatomen, das jeweils durch einen oder mehrere Reste R9 substituiert sein kann, oder eine Aryloxy- oder Heteroaryloxygruppe mit 5 bis 60 aromatischen Ringatomen, die durch einen oder mehrere Reste R9 substituiert sein kann, oder eine Diarylaminogruppe, Diheteroarylaminogruppe oder Arylheteroarylaminogruppe mit 10 bis 40 aromatischen Ringatomen, welche durch einen oder mehrere Reste R9 substituiert sein kann, oder eine Kombination dieser Systeme; dabei können zwei oder mehrere dieser Substituenten R2 auch miteinander ein mono- oder polycyclisches, aliphatisches, aromatisches und/oder benzoannelliertes Ringsystem bilden. R 2 is independently selected from the group consisting of H, deuterium, phenyl, naphthyl, CF 3 , C (= O) OR 3 , C (= O) N (R 2 ) 2 , Si (R 4 ) 3 , C (= O) R 3 , P (= O) (R 7 ) 2 , As (= O) (R 7 ) 2 P (= S) (R 7 ) 2 , As (= S) (R 7 ) 2 , S (= O) R 3 , S (= O) 2 R 3 , a linear alkyl, alkoxy or thioalkoxy group having 1 to 40 carbon atoms or a linear alkenyl or alkynyl group having 2 to 40 carbon atoms or a branched or cyclic alkyl, alkenyl, alkynyl, alkoxy or thioalkoxy group having 3 to 40 carbon atoms, each of which may be substituted by one or more radicals R 9 , wherein one or more adjacent CH 2 - groups by - R 9 C = CR 9 -, -C = C-, or an adjacent CH 2 group by -Si (R 4 ) 2 -, - Ge (R 4 ) 2 -, -Sn (R 4 ) 2 -, -C (= O) -, -C (= S) -, -C (= Se) -, -C = N-, -C (= O) O-, -C (= O) N (R 3 ) -, -P (= 0) (R 7 ) -, -As (= 0) (R 7 ) -, -P (= S) (R 7 ) -, -As (= S) (R 7 ) -, -S (= 0) -, -S (= 0) 2 -, -NR 2 -, -O-, or -S- may be replaced and wherein one or more H atoms by De uterium, F, Cl, Br, I, CN, CF 3 or N0 2 may be replaced, or an aromatic or heteroaromatic ring system having 5 to 60 aromatic ring atoms, each of which may be substituted by one or more R 9 , or an aryloxy or heteroaryloxy group having 5 to 60 aromatic ring atoms which may be substituted by one or more radicals R 9 , or a diarylamino group, diheteroarylamino group or arylheteroarylamino group having 10 to 40 aromatic ring atoms, which may be substituted by one or more radicals R 9 , or a Combination of these systems; two or more of these substituents R 2 may also together form a mono- or polycyclic, aliphatic, aromatic and / or benzoannellated ring system.
R3 ist bei jedem Auftreten unabhängig voneinander ausgewählt aus der Gruppe bestehend aus H, Deuterium, Phenyl, Naphthyl, CF3 oder ein aliphatischer, aromatischer und/oder heteroaromatischer Kohlenwasserstoffrest mit 1 bis 20 C-Atomen, in dem auch ein oder mehrere H-Atome durch F oder CF3 ersetzt sein können; dabei können zwei oder mehrere Substituenten R3 auch miteinander ein mono- oder polycyclisches, aliphatisches Ringsystem bilden. R 3 is independently selected for each occurrence from the group consisting of H, deuterium, phenyl, naphthyl, CF 3 or an aliphatic, aromatic and / or heteroaromatic hydrocarbon radical having 1 to 20 carbon atoms, in which also one or more H Atoms may be replaced by F or CF 3 ; two or more substituents R 3 may also together form a mono- or polycyclic, aliphatic ring system.
R4 ist bei jedem Auftreten unabhängig voneinander ausgewählt aus der Gruppe bestehend aus H, Deuterium, Phenyl, Naphthyl, N(R2)2, CN, CF3, OH, C(=0)OR3, C(=0)N(R3)2, C(=0)R3, P(=0)(R7)2, As(=0)(R7)2, P(=S)(R7)2, As(=S)(R7)2, eine lineare Alkyl-, Alkoxy- oder Thioalkoxygruppe mit 1 bis 40 C-Atomen oder eine lineare Alkenyl- oder Alkinylgruppe mit 2 bis 40 C-Atomen oder eine verzweigte oder cyclische Alkyl-, Alkenyl-, Alkinyl-, Alkoxy- oder Thioalkoxygruppe mit 3 bis 40 C-Atomen, die jeweils mit einem oder mehreren Resten R9 substituiert sein kann, wobei eine oder mehrere benachbarte CH2-Gruppen durch - R9C=CR9-, -CEC-, bzw. eine benachbarte CH2-Gruppe durch -Si(R4)2-, -Ge(R4)2-, -Sn(R4)2, - C(=0)-, -C(=S)-, -C(=Se)-, -C=N-, -C(=0)0-, -C(=0)N(R3)-, -P(=0)(R7)-, -As(=0)(R7)-, - P(=S)(R7), -As(=S)(R7)-, -S(=0)-, -S(=0)2-, -NR2-, -O-, oder -S- ersetzt sein können und wobei ein oder mehrere H-Atome durch Deuterium, F, Cl, Br, I, CN, CF3 oder N02 ersetzt sein können, oder ein aromatisches oder heteroaromatisches Ringsystem mit 5 bis 60 aromatischen Ringatomen, das jeweils durch einen oder mehrere Reste R8 substituiert sein kann, oder eine Aryloxy- oder Heteroaryloxygruppe mit 5 bis 60 aromatischen Ringatomen, die durch einen oder mehrere Reste R9 substituiert sein kann, oder eine Diarylaminogruppe, Diheteroarylaminogruppe oder Arylheteroarylaminogruppe mit 10 bis 40 aromatischen Ringatomen, welche durch einen oder mehrere Reste R9 substituiert sein kann, oder eine Kombination dieser Systeme; dabei können zwei oder mehrere dieser Substituenten R4 auch miteinander ein mono- oder polycyclisches, aliphatisches, aromatisches und/oder benzoannelliertes Ringsystem bilden. R 4 in each occurrence is independently selected from the group consisting of H, deuterium, phenyl, naphthyl, N (R 2 ) 2 , CN, CF 3 , OH, C (= O) OR 3 , C (= O) N (R 3 ) 2 , C (= O) R 3 , P (= O) (R 7 ) 2 , As (= O) (R 7 ) 2 , P (= S) (R 7 ) 2 , As (= S) (R 7 ) 2 , a linear alkyl, alkoxy or thioalkoxy group having 1 to 40 carbon atoms or a linear alkenyl or alkynyl group having 2 to 40 carbon atoms or a branched or cyclic alkyl, alkenyl, alkynyl -, alkoxy or Thioalkoxygruppe having 3 to 40 carbon atoms, each with one or more radicals R 9 may be substituted, wherein one or more adjacent CH 2 groups by - R 9 C = CR 9 -, -CEC-, or an adjacent CH 2 group by -Si (R 4 ) 2 -, -Ge (R 4 ) 2 -, -Sn (R 4 ) 2 , - C (= O) -, -C (= S) -, -C (= Se) -, -C = N-, -C (= 0) O- , -C (= O) N (R 3 ) -, -P (= O) (R 7 ) -, -As (= O) (R 7 ) -, - P (= S) (R 7 ), - As (= S) (R 7 ) -, -S (= O) -, -S (= O) 2 -, -NR 2 -, -O-, or -S- may be replaced and wherein one or more H Atoms can be replaced by deuterium, F, Cl, Br, I, CN, CF 3 or NO 2 , or an aromatic or heteroaromatic ring system having 5 to 60 aromatic ring atoms, each of which may be substituted by one or more radicals R 8 , or an aryloxy or heteroaryloxy group having 5 to 60 aromatic ring atoms which may be substituted by one or more radicals R 9 , or a diarylamino, diheteroarylamino or arylheteroarylamino group having 10 to 40 aromatic ring atoms which may be substituted by one or more radicals R 9 , or a combo ation of these systems; two or more of these substituents R 4 may also together form a mono- or polycyclic, aliphatic, aromatic and / or benzoannellated ring system.
R5 ist bei jedem Auftreten unabhängig voneinander ausgewählt aus der Gruppe bestehend aus Phenyl, Naphthyl, CF3, C(=0)R3, P(=0)(R7)2, As(=0)(R7)2, eine lineare Alkyl-, Alkoxy- oder Thioalkoxygruppe mit 1 bis 40 C-Atomen oder eine lineare Alkenyl- oder Alkinylgruppe mit 2 bis 40 C-Atomen oder eine verzweigte oder cyclische Alkyl-, Alkenyl-, Alkinyl-, Alkoxy- oder Thioalkoxygruppe mit 3 bis 40 C-Atomen, die jeweils mit einem oder mehreren Resten R9 substituiert sein kann, wobei eine oder mehrere benachbarte CH2-Gruppen durch - R9C=CR9-, -CEC-, bzw. eine benachbarte CH2-Gruppe durch -Si(R4)2-, -Ge(R4)2-, -Sn(R4)2-, - C(=0)-, -C(=S)-, -C(=Se)-, -C=N-, -C(=0)0-, -C(=0)N(R3)-, -P(=0)(R7)-, -As(=0)(R7)-, - P(=S)(R7)-, -As(=S)(R7)-, -S(=0)-, -S(=0)2-, -NR2-, -O-, oder -S- ersetzt sein können und wobei ein oder mehrere H-Atome durch Deuterium, F, Cl, Br, I, CN, CF3 oder N02 ersetzt sein können, oder ein aromatisches oder heteroaromatisches Ringsystem mit 5 bis 60 aromatischen Ringatomen, das jeweils durch einen oder mehrere Reste R9 substituiert sein kann, oder eine Aryloxy- oder Heteroaryloxygruppe mit 5 bis 60 aromatischen Ringatomen, die durch einen oder mehrere Reste R9 substituiert sein kann, oder eine Diarylaminogruppe, Diheteroarylaminogruppe oder Arylheteroarylaminogruppe mit 10 bis 40 aromatischen Ringatomen, welche durch einen oder mehrere Reste R9 substituiert sein kann, oder eine Kombination dieser Systeme; dabei können zwei oder mehrere dieser Substituenten R5 auch miteinander ein mono- oder polycyclisches, aliphatisches, aromatisches und/oder benzoannelliertes Ringsystem bilden. Each R 5 is independently selected from the group consisting of phenyl, naphthyl, CF 3 , C (= O) R 3 , P (= O) (R 7 ) 2 , As (= O) (R 7 ) 2 , a linear alkyl, alkoxy or thioalkoxy group having 1 to 40 carbon atoms or a linear alkenyl or alkynyl group having 2 to 40 carbon atoms or a branched or cyclic alkyl, alkenyl, alkynyl, alkoxy or thioalkoxy group with 3 to 40 carbon atoms, each of which may be substituted by one or more R 9 radicals, one or more adjacent CH 2 groups being replaced by - R 9 C = CR 9 -, -CEC-, or an adjacent CH 2 - Group represented by -Si (R 4 ) 2 -, -Ge (R 4 ) 2 -, -Sn (R 4 ) 2 -, - C (= 0) -, -C (= S) -, -C (= Se ) -, -C = N-, -C (= O) O-, -C (= O) N (R 3 ) -, -P (= O) (R 7 ) -, -As (= O) ( R 7 ) -, - P (= S) (R 7 ) -, -As (= S) (R 7 ) -, -S (= O) -, -S (= O) 2 -, -NR 2 - Or one or more H atoms may be replaced by deuterium, F, Cl, Br, I, CN, CF 3 or NO 2 , or an aromatic or heteroaromatic R ing system with 5 to 60 aromatic ring atoms, which may each be substituted by one or more radicals R 9 , or an aryloxy or heteroaryloxy group having 5 to 60 aromatic ring atoms, which may be substituted by one or more radicals R 9 , or a diarylamino group, A diheteroarylamino group or arylheteroarylamino group having from 10 to 40 aromatic ring atoms which may be substituted by one or more of R 9 , or a combination of these systems; two or more of these substituents R 5 may also together form a mono- or polycyclic, aliphatic, aromatic and / or benzoannellated ring system.
R6 ist bei jedem Auftreten unabhängig voneinander ausgewählt aus der Gruppe bestehend aus Phenyl, Naphthyl, CF3, Si(R4)3, C(=0)R3, P(=0)(R7)2, eine lineare Alkyl-, Alkoxy- oder Thioalkoxygruppe mit 1 bis 40 C-Atomen oder eine lineare Alkenyl- oder Alkinylgruppe mit 2 bis 40 C-Atomen oder eine verzweigte oder cyclische Alkyl-, Alkenyl-, Alkinyl-, Alkoxy- oder Thioalkoxygruppe mit 3 bis 40 C-Atomen, die jeweils mit einem oder mehreren Resten R9 substituiert sein kann, wobei eine oder mehrere benachbarte CH2-Gruppen durch - R9C=CR9-, -CEC-, bzw. eine benachbarte CH2-Gruppe durch-Si(R4)2-, -Ge(R4)2-, -Sn(R4)2, - C(=0)-, -C(=S)-, -C(=Se)-, -C=N-, -C(=0)0-, -C(=0)N(R3)-, -P(=0)(R7)-, -As(=0)(R7)-, - P(=S)(R7), -As(=S)(R7)-, -S(=0)-, -S(=0)2-, -NR2-, -O-, oder -S- ersetzt sein können und wobei ein oder mehrere H-Atome durch Deuterium, F, Cl, Br, I, CN, CF3 oder N02 ersetzt sein können, oder ein aromatisches oder heteroaromatisches Ringsystem mit 5 bis 60 aromatischen Ringatomen, das jeweils durch einen oder mehrere Reste R9 substituiert sein kann, oder eine Aryloxy- oder Heteroaryloxygruppe mit 5 bis 60 aromatischen Ringatomen, die durch einen oder mehrere Reste R* substituiert sein kann, oder eine Diarylaminogruppe, Diheteroarylaminogruppe oder Arylheteroarylaminogruppe mit 10 bis 40 aromatischen Ringatomen, welche durch einen oder mehrere Reste R9 substituiert sein kann, oder eine Kombination dieser Systeme; dabei können zwei oder mehrere dieser Substituenten R6 auch miteinander ein mono- oder polycyclisches, aliphatisches, aromatisches und/oder benzoannelliertes Ringsystem bilden. R 6 in each occurrence is independently selected from the group consisting of phenyl, naphthyl, CF 3 , Si (R 4 ) 3 , C (= O) R 3 , P (= O) (R 7 ) 2 , a linear alkyl -, alkoxy or Thioalkoxy group having 1 to 40 carbon atoms or a linear alkenyl or alkynyl group having 2 to 40 carbon atoms or a branched or cyclic alkyl, alkenyl, alkynyl, alkoxy or thioalkoxy group having 3 to 40 carbon atoms, each may be substituted by one or more radicals R 9 , wherein one or more adjacent CH 2 groups by - R 9 C = CR 9 -, -CEC-, or an adjacent CH 2 group by-Si (R 4 ) 2 -, -Ge (R 4 ) 2 -, -Sn (R 4 ) 2 , - C (= 0) -, -C (= S) -, -C (= Se) -, -C = N-, - C (= 0) 0-, -C (= 0) N (R 3) -, -P (= 0) (R 7) -, -As (= 0) (R 7) -, - P (= S ) (R 7 ), -As (= S) (R 7 ) -, -S (= O) -, -S (= O) 2 -, -NR 2 -, -O-, or -S- be replaced and wherein one or more H atoms can be replaced by deuterium, F, Cl, Br, I, CN, CF 3 or NO 2 , or an aromatic or heteroaromatic ring system having 5 to 60 aromatic ring atoms, each by one or more R 9 may be substituted, or an aryloxy or heteroaryloxy group having 5 to 60 aromatic ring atoms which may be substituted by one or more radicals R *, or a diarylamino group, diheteroarylamino group or arylheteroarylamino group having 10 to 40 aromatic ring atoms which may be substituted by one or more radicals R 9 , or a combination of these systems; two or more of these substituents R 6 may also together form a mono- or polycyclic, aliphatic, aromatic and / or benzoannulated ring system.
R7 ist bei jedem Auftreten unabhängig voneinander ausgewählt aus der Gruppe bestehend aus, Phenyl, Naphthyl, N(R2)2, CN, CF3, C(=0)OR3, C(=0)N(R3)2, Si(R4)3, C(=0)R3, eine lineare Alkyl-, Alkoxy- oder Thioalkoxygruppe mit 1 bis 40 C-Atomen oder eine lineare Alkenyl- oder Alkinylgruppe mit 2 bis 40 C-Atomen oder eine verzweigte oder cyclische Alkyl- , Alkenyl-, Alkinyl-, Alkoxy- oder Thioalkoxygruppe mit 3 bis 40 C-Atomen, die jeweils mit einem oder mehreren Resten R9 substituiert sein kann, wobei eine oder mehrere benachbarte CH2-Gruppen durch -R9C=CR9-, -C=C-, bzw. eine benachbarte CH2-Gruppe durch -Si(R4)2-, -Ge(R4)2-, -Sn(R4)2, -C(=0)-, -C(=S)-, -C(=Se)-, -C=N-, -C(=0)0-, - C(=0)N(R3)-, -P(=0)(R7)-, -As(=0)(R7)-, -P(=S)(R7), -As(=S)(R7)-, -S(=0)-, -S(=0)2-, -NR2-, - O-, oder -S- ersetzt sein können und wobei ein oder mehrere H-Atome durch Deuterium, F, Cl, Br, I, CN, CF3 oder N02 ersetzt sein können, oder ein aromatisches oder heteroaromatisches Ringsystem mit 5 bis 60 aromatischen Ringatomen, das jeweils durch einen oder mehrere Reste R9 substituiert sein kann, oder eine Aryloxy- oder Heteroaryloxygruppe mit 5 bis 60 aromatischen Ringatomen, die durch einen oder mehrere Reste R9 substituiert sein kann, oder eine Diarylaminogruppe, Diheteroarylaminogruppe oder Arylheteroarylaminogruppe mit 10 bis 40 aromatischen Ringatomen, welche durch einen oder mehrere Reste R3 substituiert sein kann, oder eine Kombination dieser Systeme; dabei können zwei oder mehrere dieser Substituenten R7 auch miteinander ein mono- oder polycyclisches, aliphatisches, aromatisches und/oder benzoannelliertes Ringsystem bilden. R ist bei jedem Auftreten unabhängig voneinander ausgewählt aus der Gruppe bestehend aus H, Deuterium, Phenyl, Naphthyl, F, CF3 oder ein aliphatischer, aromatischer und/oder heteroaromatischer Kohlenwasserstoffrest mit 1 bis 20 C-Atomen, in dem auch ein oder mehrere H-Atome durch F oder CF3 ersetzt sein können; dabei können zwei oder mehrere Substituenten R8 auch miteinander ein mono- oder polycyclisches, aliphatisches Ringsystem bilden. Each R 7 is independently selected from the group consisting of phenyl, naphthyl, N (R 2 ) 2 , CN, CF 3 , C (= O) OR 3 , C (= O) N (R 3 ) 2 , Si (R 4 ) 3 , C (= O) R 3 , a linear alkyl, alkoxy or thioalkoxy group having 1 to 40 carbon atoms or a linear alkenyl or alkynyl group having 2 to 40 carbon atoms or a branched or cyclic alkyl, alkenyl, alkynyl, alkoxy or thioalkoxy group having 3 to 40 carbon atoms, each of which may be substituted with one or more R 9 radicals, wherein one or more adjacent CH 2 groups is replaced by -R 9 C = CR 9 -, -C = C-, or an adjacent CH 2 group by -Si (R 4 ) 2 -, -Ge (R 4 ) 2 -, -Sn (R 4 ) 2 , -C (= 0 ) -, -C (= S) -, -C (= Se) -, -C = N-, -C (= O) O-, -C (= O) N (R 3 ) -, -P ( = 0) (R 7 ) -, -As (= 0) (R 7 ) -, -P (= S) (R 7 ), -As (= S) (R 7 ) -, -S (= 0) -, -S (= O) 2 -, -NR 2 -, - O-, or -S- may be replaced and wherein one or more H atoms by deuterium, F, Cl, Br, I, CN, CF 3 or N0 2 may be replaced, or an aromatic o the heteroaromatic ring system having 5 to 60 aromatic ring atoms, which may be substituted by one or more radicals R 9 , or an aryloxy or heteroaryloxy group having 5 to 60 aromatic ring atoms, which may be substituted by one or more radicals R 9 , or a Diarylamino group, diheteroarylamino group or arylheteroarylamino group having 10 to 40 aromatic ring atoms which may be substituted by one or more of R 3 , or a combination of these systems; two or more of these substituents R 7 may also together form a mono- or polycyclic, aliphatic, aromatic and / or benzoannellated ring system. R is independently selected in each occurrence from the group consisting of H, deuterium, phenyl, naphthyl, F, CF 3 or an aliphatic, aromatic and / or heteroaromatic hydrocarbon radical having 1 to 20 carbon atoms, in which also one or more H Atoms can be replaced by F or CF 3 ; two or more substituents R 8 may also together form a mono- or polycyclic, aliphatic ring system.
R9 ist bei jedem Auftreten unabhängig voneinander ausgewählt aus der Gruppe bestehend aus H, Deuterium, Phenyl, Naphthyl, N(R2)2, CN, CF3, N02, OH, COOH, C(=0)OR3, C(=0)N(R3)2, Si(R4)3, B(OR5)2, C(=0)R3, P(=0)(R7)2, P(=S)(R7)2, As(=0)(R7)2, P(=S)(R7)2, S(=0)R3, S(=0)2R3, OS02R3, eine lineare Alkyl-, Alkoxy- oder Thioalkoxygruppe mit 1 bis 40 C-Atomen oder eine lineare Alkenyl- oder Alkinylgruppe mit 2 bis 40 C-Atomen oder eine verzweigte oder cyclische Alkyl-, Alkenyl-, Alkinyl-, Alkoxy- oder Thioalkoxygruppe mit 3 bis 40 C-Atomen, die jeweils mit einem oder mehreren Resten R8 substituiert sein kann, wobei eine oder mehrere nicht benachbarte CH2-Gruppen durch -R3C=CR3-, -C=C-, bzw. eine benachbarte CH2-Gruppe durch -Si(R4)2-, -Ge(R4)2-, -Sn(R4)2-, -C(=0)-, -C(=S)-, -C(=Se)-, - C=N-, -C(=0)0-, -C(=0)N(R3)-, -P(=0)(R7)-, -As(=0)(R7)-, -P(=S)(R7), -As(=S)(R7)-, -S(=0)-, -S(=0)2-, -NR2-, -O-, oder -S- ersetzt sein können und wobei ein oder mehrere H-Atome durch Deuterium, F, Cl, Br, I, CN, CF3 oder N02 ersetzt sein können, oder ein aromatisches oder heteroaromatisches Ringsystem mit 5 bis 60 aromatischen Ringatomen, das jeweils durch einen oder mehrere Reste R8 substituiert sein kann, oder eine Aryloxy- oder Heteroaryloxygruppe mit 5 bis 60 aromatischen Ringatomen, die durch einen oder mehrere Reste R3 substituiert sein kann, oder eine Diarylaminogruppe, Diheteroarylaminogruppe oder Arylheteroarylaminogruppe mit 10 bis 40 aromatischen Ringatomen, welche durch einen oder mehrere Reste R8 substituiert sein kann, oder eine Kombination dieser Systeme; dabei können zwei oder mehrere dieser Substituenten R9 auch miteinander ein mono- oder polycyclisches, aliphatisches, aromatisches und/oder benzoannelliertes Ringsystem bilden. Each R 9 is independently selected from the group consisting of H, deuterium, phenyl, naphthyl, N (R 2 ) 2 , CN, CF 3 , NO 2 , OH, COOH, C (= O) OR 3 , C (= 0) N (R 3 ) 2 , Si (R 4 ) 3 , B (OR 5 ) 2 , C (= O) R 3 , P (= O) (R 7 ) 2 , P (= S) ( R 7 ) 2 , As (= O) (R 7 ) 2 , P (= S) (R 7 ) 2 , S (= O) R 3 , S (= O) 2 R 3 , OSO 2 R 3 , a linear alkyl, alkoxy or thioalkoxy group having 1 to 40 carbon atoms or a linear alkenyl or alkynyl group having 2 to 40 carbon atoms or a branched or cyclic alkyl, alkenyl, alkynyl, alkoxy or thioalkoxy group having 3 to 40 C atoms, each of which may be substituted with one or more R 8 , wherein one or more non-adjacent CH 2 groups by -R 3 C = CR 3 -, -C = C-, or an adjacent CH 2 -Si (R 4 ) 2 -, -Ge (R 4 ) 2 -, -Sn (R 4 ) 2 -, -C (= 0) -, -C (= S) -, -C (= Se) -, - C = N-, -C (= O) O-, -C (= O) N (R 3 ) -, -P (= O) (R 7 ) -, -As (= O) (R 7 ) -, -P (= S) (R 7 ), -As (= S) (R 7 ) -, -S (= O) -, -S (= O) 2 -, -NR 2 - , -O-, or -S- e and one or more H atoms may be replaced by deuterium, F, Cl, Br, I, CN, CF 3 or NO 2 , or an aromatic or heteroaromatic ring system having from 5 to 60 aromatic ring atoms, each being replaced by one or a plurality of radicals R 8 may be substituted, or an aryloxy or heteroaryloxy group having 5 to 60 aromatic ring atoms, which may be substituted by one or more radicals R 3 , or a Diarylaminogruppe, Diheteroarylaminogruppe or Arylheteroarylaminogruppe having 10 to 40 aromatic ring atoms, which one or more radicals R 8 may be substituted, or a combination of these systems; two or more of these substituents R 9 may also together form a mono- or polycyclic, aliphatic, aromatic and / or benzoannellated ring system.
Eine Arylgruppe im Sinne dieser Erfindung enthält 6 bis 60 aromatische Ringatome; eine Heteroarylgruppe im Sinne dieser Erfindung enthält 5 bis 60 aromatische Ringatome, von denen mindestens eines ein Heteroatom darstellt. Die Heteroatome sind insbesondere N, O, und S. Werden an Stellen in der Beschreibung andere Definitionen angegeben, beispielsweise bezüglich der Zahl der aromatischen Ringatome oder der enthaltenen Heteroatome, so gelten diese anderen Definitionen. Dabei wird unter einer Arylgruppe bzw. Heteroarylgruppe ein einfacher aromatischer Cyclus, also Benzol, bzw. ein einfacher heteroaromatischer Cyclus, beispielsweise Pyridin, Pyrimidin oder Thiophen, oder ein heteroaromatischer Polycyclus, beispielsweise Napthalin, Phenanthren, Chinolin oder Carbazol verstanden. Ein kondensierter (annelierter) aromatischer bzw. heteroaromatischer Polycyclus besteht im Sinne der vorliegenden Anmeldung aus zwei oder mehr miteinander kondensierten einfachen aromatischen bzw. heteroaromatischen Cyclen. An aryl group in the sense of this invention contains 6 to 60 aromatic ring atoms; For the purposes of this invention, a heteroaryl group contains 5 to 60 aromatic ring atoms, at least one of which represents a heteroatom. The heteroatoms are in particular N, O, and S. If other definitions are given at points in the description, for example with regard to the number of aromatic ring atoms or the heteroatoms contained therein, these other definitions apply. An aryl group or heteroaryl group is understood to mean a simple aromatic cycle, ie benzene, or a simple heteroaromatic cycle, for example pyridine, pyrimidine or thiophene, or a heteroaromatic polycycle, for example naphthalene, phenanthrene, quinoline or carbazole. A condensed (fused) aromatic or heteroaromatic polycycle consists in the context of the present application of two or more fused simple aromatic or heteroaromatic cycles.
Unter einer Aryl- oder Heteroarylgruppe, die jeweils mit den oben genannten Resten substituiert sein kann und die über beliebige Positionen am Aromaten bzw. Heteroaromaten verknüpft sein kann, werden insbesondere Gruppen verstanden, welche abgeleitet sind von Benzol, Naphthalin, Anthracen, Phenanthren, Pyren, Dihydropyren, Chrysen, Perylen, Fluoranthen, Benzanthracen, Benzphenanthren, Tetracen, Pentacen, Benzpyren, Furan, Benzofuran, Isobenzofuran, Dibenzofuran, Thiophen, Benzothiophen, Isobenzothiophen, Dibenzothiophen; Pyrrol, Indol, Isoindol, Carbazol, Pyridin, Chinolin, Isochinolin, Acridin, Phenanthridin, Benzo-5,6-chinolin, Isochinolin, Benzo-6,7-chinolin, Benzo-7,8-chinolin, Phenothiazin, Phenoxazin, Pyrazol, Indazol, Imidazol, Benzimidazol, Naphthimidazol, Phenanthrimidazol, Pyridimidazol, Pyrazinimidazol, Chinoxalinimidazol, Oxazol, Benzoxazol, Napthoxazol, Anthroxazol, Phenanthroxazol, Isoxazol, 1 ,2-Thiazol, 1 ,3-Thiazol, Benzothiazol, Pyridazin, Benzopyridazin, Pyrimidin, Benzpyrimidin, Chinoxalin, Pyrazin, Phenazin, Naphthyridin, Azacarbazol, Benzocarbolin, Phenanthrolin, 1 ,2,3-Triazol, 1 ,2,4- Triazol, Benztriazol, 1 ,2,3-Oxadiazol, 1 ,2,4-Oxadiazol, 1 ,2,5-Oxadiazol, 1 ,2,3,4-Tetrazin, Purin, Pteridin, Indolizin und Benzothiadiazol. An aryl or heteroaryl group which may be substituted in each case by the abovementioned radicals and which may be linked via any position on the aromatic or heteroaromatic compounds is understood in particular to mean groups which are derived from benzene, naphthalene, anthracene, phenanthrene, pyrene, Dihydropyrenes, chrysene, perylene, fluoranthene, benzanthracene, benzphenanthrene, tetracene, pentacene, benzpyrene, furan, benzofuran, isobenzofuran, dibenzofuran, thiophene, benzothiophene, isobenzothiophene, dibenzothiophene; Pyrrole, indole, isoindole, carbazole, pyridine, quinoline, isoquinoline, acridine, phenanthridine, benzo-5,6-quinoline, isoquinoline, benzo-6,7-quinoline, benzo-7,8-quinoline, phenothiazine, phenoxazine, pyrazole, Indazole, imidazole, benzimidazole, naphthimidazole, phenanthrimidazole, pyridimidazole, pyrazine imidazole, quinoxaline imidazole, oxazole, benzoxazole, napthoxazole, anthroxazole, phenanthroxazole, isoxazole, 1, 2-thiazole, 1, 3-thiazole, benzothiazole, pyridazine, benzopyridazine, pyrimidine, benzpyrimidine, Quinoxaline, pyrazine, phenazine, naphthyridine, azacarbazole, benzocarboline, phenanthroline, 1, 2,3-triazole, 1, 2,4-triazole, benzotriazole, 1, 2,3-oxadiazole, 1, 2,4-oxadiazole, 1, 2,5-oxadiazole, 1,2,3,4-tetrazine, purine, pteridine, indolizine and benzothiadiazole.
Ein aromatisches Ringsystem im Sinne dieser Erfindung enthält 6 bis 60 C-Atome im Ringsystem. Ein heteroaromatisches Ringsystem im Sinne dieser Erfindung enthält 5 bis 60 aromatische Ringatome, von denen mindestens eines ein Heteroatom darstellt. Die Heteroatome sind insbesondere ausgewählt aus, N, O und/oder S. Unter einem aromatischen oder heteroaromatischen Ringsystem im Sinne dieser Erfindung soll ein System verstanden werden, das nicht notwendigerweise nur Aryl- oder Heteroarylgruppen enthält, sondern in dem auch mehrere Aryl- oder Heteroarylgruppen durch eine nichtaromatische Einheit (insbesondere weniger als 10% der verschiedenen Atome), wie z.B. ein sp3-hybridisiert.es C-, Si-, oder N-Atom, ein sp2-hybridisiert.es C-, N- oder O-Atom oder ein sp-hybridisiertes C-Atom, verbunden sein können. So sollen beispielsweise auch Systeme wie 9,£T-Diarylfluoren, Triarylamin, Diarylether, Stilben etc. als aromatische Ringsysteme im Sinne dieser Erfindung verstanden werden, und ebenso Systeme, in denen zwei oder mehrere Arylgruppen beispielsweise durch eine lineare oder cyclische Alkyl-, Alkenyl- oder Alkinylgruppe oder durch eine Silyigruppe verbunden sind. Weiterhin werden auch Systeme, in denen zwei oder mehr Aryl- oder Heteroarylgruppen über Einfachbindungen miteinander verknüpft sind, als aromatische oder heteroaromatische Ringsysteme im Sinne dieser Erfindung verstanden, wie beispielsweise Systeme wie Biphenyl, Terphenyl oder Diphenyltriazin. An aromatic ring system in the sense of this invention contains 6 to 60 carbon atoms in the ring system. A heteroaromatic ring system in the context of this invention contains 5 to 60 aromatic ring atoms, at least one of which represents a heteroatom. The heteroatoms are in particular selected from, N, O and / or S. An aromatic or heteroaromatic ring system in the sense of this invention is to be understood as meaning a system which does not necessarily contain only aryl or heteroaryl groups but in which also several aryl or heteroaryl groups by a non-aromatic moiety (in particular less than 10% of the various atoms), such as, for example, a sp3-hybridized C, Si or N atom, an sp 2 -hybridized C, N or O atom or a sp-hybridized carbon atom, may be connected. Thus, for example, systems such as 9, T-diaryl fluorene, triarylamine, diaryl ethers, stilbene, etc. are to be understood as aromatic ring systems in the context of this invention, and also systems in which two or more aryl groups, for example by a linear or cyclic alkyl, alkenyl - or Alkynyl group or by a silyl group are connected. Furthermore, systems in which two or more aryl or heteroaryl groups are linked together via single bonds are understood as aromatic or heteroaromatic ring systems in the context of this invention, such as systems such as biphenyl, terphenyl or diphenyltriazine.
Unter einem aromatischen oder heteroaromatischen Ringsystem mit 5 bis 60 aromatischen Ringatomen, welches noch jeweils mit Resten wie oben definiert substituiert sein kann und welches über beliebige Positionen am Aromaten bzw. Heteroaromaten verknüpft sein kann, werden insbesondere Gruppen verstanden, die abgeleitet sind von Benzol, Naphthalin, Anthracen, Benzanthracen, Phenanthren, Benzphenanthren, Pyren, Chrysen, Perylen, Fluoranthen, Napthacen, Pentacen, Benzpyren, Biphenyl, Biphenylen, Terphenyl, Terphenylen, Quaterphenyl, Fluoren, Spirobifluoren, Dihydrophenanthren, Dihydropyren, Tetra hydro pyren, eis- oder trans-lndenofluoren, Truxen, Isotruxen, Spirotruxen, Spiroisotruxen, Furan, Benzofuran, Isobenzofuran, Dibenzofuran, Thiophen, Benzothiophen, Isobenzothiophen, Dibenzothiophen, Pyrrol, Indol, Isoindol, Carbazol, Indolocarbazol, Indenocarbazol, Pyridin, Chinolin, Isochinolin, Acridin, Phenanthridin, Benzo-5,6-chinolin Benzo-6,7-chinolin, Benzo-7,8-chinolin, Phenothiazin, Phenoxazin, Pyrazol, Indazol, Imidazol, Benzimidazol, Naphthimidazol, Phenanthrimidazol, Pyridimidazol, Pyarzinimidazol, Chinoxalinimidazol, Oxazol, Benzoxazol, Napthoxazol, Anthroxazol, Phenanthroxazol, Isoxazol, 1 ,2-Thiazol, 1 ,3-Thiazol, Benzothiazol, Pyridazin, Benzopyridazin, Pyrimidin, Benzpyrimidin, Chinoxalin, 1 ,5-Diazaanthracen, 2,7-Diazapyren, 2,3-Diazapyren, 1 ,6- Diazapyren, 1 ,8-Diazapyren, 4,5-Diazapyren, 4,5,9, 10-Tetraazaperylen, Pyrazin, Phenazin, Phenoxazin, Phenothiazin, Fluorubin, Naphthyridin, Azacarbazol, Benzocarbolin, Phenanthrolin, 1 ,2,3-Triazol, 1 ,2,4-Triazol, Benzotriazol, 1 ,2,3-Oxadiazol, 1 ,2,4-Oxadiazol, 1 ,2,5-Oxadiazol, 1 ,2,3-Oxadiazol, 1 ,2,3-Thiadiazol, 1 ,2,5-Thiadiazol, 1 ,3,4-Thiadiazol, 1 ,3,5- Triazin, 1 ,2,4-Triazin, 1 ,2,3-Triazin, Tetrazol, 1 ,2,3,5-Tetrazin, 1 ,2,3,4-Tetrazin, Purin, Pteridin, Indolizin und Benzothiadiazol oder Kombinationen dieser Gruppen. By an aromatic or heteroaromatic ring system having 5 to 60 aromatic ring atoms, which may be substituted in each case with radicals as defined above and which may be linked via any positions on the aromatic or heteroaromatic, are understood in particular groups which are derived from benzene, naphthalene , Anthracene, benzanthracene, phenanthrene, benzphenanthrene, pyrene, chrysene, perylene, fluoranthene, naphthacene, pentacene, benzpyrene, biphenyl, biphenylene, terphenyl, terphenyls, quaterphenyl, fluorene, spirobifluorene, dihydrophenanthrene, dihydropyrene, tetrahydro-pyrene, cis- or trans- indenofluorene, truxene, isotruxene, spirotruxene, spiroisotruxene, furan, benzofuran, isobenzofuran, dibenzofuran, thiophene, benzothiophene, isobenzothiophene, dibenzothiophene, pyrrole, indole, isoindole, carbazole, indolocarbazole, indenocarbazole, pyridine, quinoline, isoquinoline, acridine, phenanthridine, benzoin 5,6-quinoline benzo-6,7-quinoline, benzo-7,8-quinoline, phenothiazine, phen oxazine, pyrazole, indazole, imidazole, benzimidazole, naphthimidazole, phenanthrimidazole, pyrimididazole, pyrazine imidazole, quinoxaline imidazole, oxazole, benzoxazole, napthoxazole, anthroxazole, phenanthroxazole, isoxazole, 1, 2-thiazole, 1, 3-thiazole, benzothiazole, pyridazine, benzopyridazine, Pyrimidine, benzpyrimidine, quinoxaline, 1,5-diazaanthracene, 2,7-diazapyrene, 2,3-diazapyrene, 1, 6-diazapyrene, 1, 8-diazapyrene, 4,5-diazapyrene, 4,5,9, 10 Tetraazaperylene, pyrazine, phenazine, phenoxazine, phenothiazine, fluorubin, naphthyridine, azacarbazole, benzocarboline, phenanthroline, 1, 2,3-triazole, 1, 2,4-triazole, benzotriazole, 1, 2,3-oxadiazole, 1, 2, 4-oxadiazole, 1, 2,5-oxadiazole, 1, 2,3-oxadiazole, 1, 2,3-thiadiazole, 1, 2,5-thiadiazole, 1, 3,4-thiadiazole, 1, 3,5- Triazine, 1, 2,4-triazine, 1, 2,3-triazine, tetrazole, 1, 2,3,5-tetrazine, 1, 2,3,4-tetrazine, purine, pteridine, indolizine and benzothiadiazole, or combinations thereof Groups.
Die Anbindung der chemischen Einheiten AF1 und AF2 aneinander erfolgt in einer Ausführungsform bei Auswahl der AF1 aus Tabelle 1 und Auswahl der AF2 aus Tabelle 2 jeweils über die mit Kleinbuchstaben bezeichneten Positionen der einzelnen AF (Tabelle 1 und Tabelle 2). The connection of the chemical units AF1 and AF2 to each other takes place in one embodiment when selecting the AF1 from Table 1 and selecting the AF2 from Table 2 in each case over the lower case letters designated positions of each AF (Table 1 and Table 2).
Insbesondere weist AF2 im Vergleich zu AF1 immer einen betragsmäßig niedrigeren HOMO- Zahlenwert auf (und damit auch entsprechend einen betragsmäßig niedrigeren LUMO- Zahlenwert) als AF2 ( | EHOMO(AF2) | < | EHOMO(AF1 ) | und | ELUMo(AF2) | < | ELUMo(AF1 ) | ). In einer Ausführungsform zeichnen sich die organischen Moleküle dadurch aus, dassIn particular, AF2 always has a lower HOMO numerical value compared to AF1 (and correspondingly a LUMO numerical value lower in magnitude) than AF2 (| E HO MO (AF2) | <| E HO MO (AF1) | and | E LUM o (AF2) | <| E LUM o (AF1) |). In one embodiment, the organic molecules are characterized in that
- die Differenz der Energie des HOMO der zweiten chemischen Einheit AF2 und der Energie des HOMO der ersten chemischen Einheit AF1 > 0,8 eV ist (Δ HOMO = HOMO(AF2) - HOMO(AF1 ) > 0,8 eV); the difference of the energy of the HOMO of the second chemical entity AF2 and the energy of the HOMO of the first chemical entity AF1 is> 0.8 eV (ΔHOMO = HOMO (AF2) -HOMO (AF1)> 0.8 eV);
- die Differenz der Energie des LUMO der zweiten chemischen Einheit AF2 und der Energie des LUMO der ersten chemischen Einheit AF1 > 0,8 eV ist (Δ LUMO = LUMO(AF2) - LUMO(AF1 ) > 0,8 eV); und/oder  the difference of the energy of the LUMO of the second chemical unit AF2 and the energy of the LUMO of the first chemical unit AF1 is> 0.8 eV (Δ LUMO = LUMO (AF2) -LUMO (AF1)> 0.8 eV); and or
- die Differenz der Energie des LUMO der ersten chemischen Einheit AF1 und der Energie des HOMO der zweiten chemischen Einheit AF2 > 0,9 eV ist (Δ Gap = LUMO (AF1 ) - HOMO(AF2)> 0,9 eV).  the difference of the energy of the LUMO of the first chemical entity AF1 and the energy of the HOMO of the second chemical entity AF2> 0.9 eV is (ΔGap = LUMO (AF1) -HOMO (AF2)> 0.9 eV).
Dabei werden die Energiewerte HOMO(AF1 ), HOMO(AF2), LUMO(AF1 ), LUMO(AF2) mithilfe der Dichtefunktionaltheorie (DFT) berechnet, wobei die Anknüpfungspositionen der ambifunktionalen Einheiten mit einem Wasserstoffatom entsprechend ihrer chemischen Valenzen abgesättigt werden. Die angegebenen Grenzen beziehen sich auf Orbitalenergien in eV, die mit dem BP86-Funktional berechnet werden (Becke, A. D. Phys. Rev. A1988, 38, 3098-3100; Perdew, J. P. Phys. Rev. B1986, 33, 8822-8827). The energy values HOMO (AF1), HOMO (AF2), LUMO (AF1), LUMO (AF2) are calculated using the density functional theory (DFT), whereby the attachment positions of the ambifunctional units are saturated with a hydrogen atom according to their chemical valences. The limits given refer to orbital energies in eV calculated with the BP86 functional (Becke, A.D. Phys Rev. A1988, 38, 3098-3100, Perdew, J.P. Phys. Rev. B1986, 33, 8822-8827).
In einer Ausführungsform sind die chemischen Einheiten AF1 und AF2 derart miteinander verknüpft, dass die elektronische Kommunikation zwischen ihnen unterbrochen wird. Diese Unterbrechung ist durch eine Lokalisierung der Grenzorbitale HOMO und LUMO auf separaten Molekülteilen gekennzeichnet, sodass ein Charge-Transfer Übergang ermöglicht wird. In one embodiment, the chemical entities AF1 and AF2 are linked to one another such that the electronic communication between them is interrupted. This disruption is characterized by localization of the HOMO and LUMO frontier orbits on separate parts of the molecule, allowing for a charge-transfer transition.
Die elektronische Kommunikation zwischen den zwei chemischen Einheiten AF1 und AF2 über konjugierte Bindungen ist unterbrochen, wenn die Grenzorbitale HOMO und LUMO auf separaten Molekülteilen lokalisiert sind, sodass ein Charge-Transfer Übergang ermöglicht wird. Die Lokalisierung der Grenzorbitale HOMO oder LUMO wird dabei mithilfe der Dichtefunktionaltheorie (DFT) mit dem BP86-Funktional (Becke, A. D. Phys. Rev. A1988, 38, 3098-3100; Perdew, J. P. Phys. Rev. B1986, 33, 8822-8827) visualisiert: Aus der Einelektronen-Wellenfunktion wird die Einelektronendichte durch Quadrieren berechnet und über den Raum integriert, den der untersuchte Molekülteil einnimmt. Dieser Raum kann aus den Atomkoordinaten und den van-der-Waals-Radien der Atome bestimmt werden. Die resultierende Zahl entspricht dem Anteil des Orbitals auf dem Molekülteil. Eine mehrheitliche Trennung der Grenzorbitale entspricht dabei einem Überlappungsparameter O im Bereich 0.1-20%, um einen Charge-Transfer Übergang zu ermöglichen. Der Überlappungsparameter O zwischen der HOMO-Wellenfunktion φ3 und der der LUMO- Wellenfunktion ergibt sich aus dem Integral über den gesamten Raum über den jeweils kleineren Wert der quadrierten Wellenfunktion: n 0 =The electronic communication between the two chemical entities AF1 and AF2 via conjugated bonds is interrupted when the frontier orbitals HOMO and LUMO are located on separate parts of the molecule, allowing for a charge-transfer transition. The localization of the frontier orbitals HOMO or LUMO is determined using the density functional theory (DFT) with the BP86 functional (Becke, AD Phys.Rev.A1988, 38, 3098-3100, Perdew, JP Phys. Rev. B1986, 33, 8822-8827 ): The single electron wave function calculates the single electron density by squaring and integrates it over the space occupied by the part of the molecule. This space can be determined from the atomic coordinates and van der Waals radii of the atoms. The resulting number corresponds to the proportion of orbital on the moiety. A majority separation of the frontier orbitals corresponds to an overlap parameter O in the range 0.1-20% to allow a batch transfer transition. The overlap parameter O between the HOMO wave function φ 3 and that of the LUMO wave function results from the integral over the entire space over the respective smaller value of the squared wave function: n 0 =
Figure imgf000014_0001
Figure imgf000014_0001
In einer Ausführungsform weisen die organischen Moleküle eine Struktur der Formel 2a-2c auf oder haben eine Struktur der Formel 2a-2c, wobei In one embodiment, the organic molecules have a structure of the formula 2a-2c or have a structure of the formula 2a-2c, wherein
Figure imgf000014_0002
Figure imgf000014_0002
Formel 2a Formel2b Formel 2c und R*, Y und AF2 wie oben definiert sind. Formula 2a Formula 2b Formula 2c and R *, Y and AF2 are as defined above.
In einer Ausführungsform werden organische Moleküle AF1-AF2 verwendet, wobei AF1 ausgewählt wird aus der nachfolgenden Tabelle 1 : In one embodiment, organic molecules AF1-AF2 are used, AF1 being selected from the following Table 1:
Tabelle 1 : Auflistung der ersten chemischen Einheiten AF1 Table 1: List of the first chemical units AF1
Figure imgf000015_0001
Figure imgf000015_0001
405 425  405 425
477 478 Anknüpfungspositionen zur AF2 sind hier mit kleinen Buchstaben (a, b, ...) gekennzeichnet. C-H und N-H können durch chemisches Substitution auch C-R* bzw. N-R* bedeuten. 477 478 Link positions to AF2 are here marked with small letters (a, b, ...). CH and NH can also be CR * or NR * by chemical substitution.
In einer Ausführungsform werden organische Moleküle AF1-AF2 verwendet, wobei AF1 ausgewählt wird aus der nachfolgenden Tabelle 1 a: In one embodiment, organic molecules AF1-AF2 are used, with AF1 being selected from the following Table 1 a:
Tabelle 1a: Auflistung der ersten chemischen Einheiten AF1 Table 1a: List of the first chemical units AF1
Figure imgf000016_0001
Figure imgf000016_0001
98 354 405 98 354 405
In einer Ausführungsform werden organische Moleküle AF1-AF2 verwendet, wobei AF2 ausgewählt ist aus Tabelle 2. In one embodiment, organic molecules AF1-AF2 are used with AF2 selected from Table 2.
Tabelle 2: Auflistung der zweiten chemischen Einheiten AF2. Table 2: List of the second chemical units AF2.
Figure imgf000017_0001
Figure imgf000018_0001
Figure imgf000017_0001
Figure imgf000018_0001
Figure imgf000018_0002
Figure imgf000019_0001
Figure imgf000018_0002
Figure imgf000019_0001
Figure imgf000020_0001
Figure imgf000020_0001
66
Figure imgf000021_0001
66
Figure imgf000021_0001
Figure imgf000022_0001
ı99
Figure imgf000022_0001
I99
Figure imgf000023_0001
Figure imgf000023_0001
Figure imgf000023_0002
Figure imgf000023_0002
Figure imgf000024_0001
Figure imgf000025_0001
Figure imgf000024_0001
Figure imgf000025_0001
Figure imgf000026_0001
Formel 3
Figure imgf000026_0001
Formula 3
wobei gilt: m ist 1 ; where m is 1;
n ist 0 oder 1 , wobei bei m = 0 immer auch n = 0 ist; n is 0 or 1, where m = 0 always also n = 0;
o ist 0 oder 1 ; o is 0 or 1;
p ist 0 oder 1 ; p is 0 or 1;
A ist CR*** wenn o = 0, ansonsten C; A is CR *** if o = 0, otherwise C;
VG1 = verbrückende Gruppe, ist ausgewählt aus der Gruppe bestehend aus VG1 = bridging group, is selected from the group consisting of
- NR**, CR**2, O, S und einer C-C-Einfachbindung; oder - NR **, CR ** 2 , O, S and a CC single bond; or
- NR**, CR**2, O, S, einer C-C-Einfachbindung, BR**, AsR**, SiR**2, GeR**2, NR **, CR ** 2 , O, S, a CC single bond, BR **, AsR **, SiR ** 2 , GeR ** 2 ,
Figure imgf000027_0001
Figure imgf000027_0001
VG2 = verbrückende Gruppe ist bei jedem Auftreten unabhängig voneinander ausgewählt aus der Gruppe bestehend aus CR**2, NR**, O, S und einer C-C-Einfachbindung, wobei nicht zwei Einheiten VG2 gleichzeitig gleich einer C-C-Einfachbindung sind; VG2 = bridging group at each occurrence is independently selected from the group consisting of CR ** 2 , NR **, O, S and a CC single bond, where two units VG2 are not simultaneously equal to one CC single bond;
Figure imgf000027_0002
Figure imgf000027_0002
G ist C wenn o = 1 und gleichzeitig m = 1 ; ist CR** wenn o = 0 und gleichzeitig m = 1 ; ist CR**, CR**2, wenn o = 1 und gleichzeitig m = 0; ist R* wenn o = 0 und gleichzeitig m = 0; ist CR**, CR**2, N, NR* wenn m = 0 und gleichzeitig VG1 eine C-C-Einfachbindung ist; G is C if o = 1 and m = 1 at the same time; is CR ** if o = 0 and at the same time m = 1; is CR **, CR ** 2 if o = 1 and m = 0 at the same time; is R * if o = 0 and at the same time m = 0; is CR **, CR ** 2 , N, NR * when m = 0 and at the same time VG1 is a CC single bond;
J ist C wenn m = 1 ; ist CR**, CR**2, NR** wenn m = 0; J is C when m = 1; is CR **, CR ** 2 , NR ** when m = 0;
L ist CR*** wenn n = 0; ist CR**, C (bei kovalenter Bindung zu VG2) wenn n = 1 ; R*** ist R** oder ist ausgewählt aus den folgenden Einheiten, wobei maximal zwei der Reste R*** gleichzeitig gleich einer der folgenden Einheiten sind: L is CR *** if n = 0; is CR **, C (when covalently linked to VG2) when n = 1; R *** is R ** or is selected from the following units, wherein a maximum of two of the radicals R *** are simultaneously one of the following units:
Figure imgf000028_0001
Figure imgf000028_0001
R** ist bei jedem Auftreten unabhängig voneinander ein Rest R* und/oder markiert eine Anknüpfungsstelle an die Einheit AF1 , wobei genau ein R** eine Anknüpfungsstelle an eine Einheit AF1 ist. R ** is independently a residue R * at each occurrence and / or marks a point of attachment to the unit AF1, where exactly one R ** is a point of attachment to a unit AF1.
In einer weiteren Ausführungsform weist die Einheit AF2 eine Struktur der Formel 4 auf oder hat eine Struktur der Formel 4 In a further embodiment, the unit AF2 has a structure of the formula 4 or has a structure of the formula 4
Figure imgf000028_0002
Figure imgf000028_0002
Formel 4 wobei in Formel 4 bedeutet: p ist 0 oder 1 ; t = 4 - 2p; X ist CR**2, NR**, Sauerstoff, Schwefel, eine direkte Bindung, wobei maximal zwei Platzhalter X gleichzeitig eine direkte Bindung sind, wobei diese nicht Bestandteil desselben Rings sind; und im Übrigen die für Formel 3 gegebenen Definitionen gelten. Formula 4 wherein in formula 4: p is 0 or 1; t = 4 - 2p; X is CR ** 2 , NR **, oxygen, sulfur, a direct bond, with a maximum of two placeholders X being simultaneously a direct bond, which are not part of the same ring; and, moreover, the definitions given for formula 3 apply.
In einer weiteren Ausführungsform weist die Einheit AF2 des organischen Moleküls eine Struktur der Formel 4A1-4A7 auf oder hat eine Struktur der Formel 4A1-4A7 In a further embodiment, the unit AF2 of the organic molecule has a structure of the formula 4A1-4A7 or has a structure of the formula 4A1-4A7
Figure imgf000029_0001
Figure imgf000029_0001
Formel 4A4 Formel 4A5 Formel 4A6  Formula 4A4 Formula 4A5 Formula 4A6
Figure imgf000029_0002
Figure imgf000029_0002
Formel 4A7 wobei in Formel 4A1 -4A7 gilt: Formula 4A7 where in formula 4A1 -4A7:
X ist C(R**)2, NR**, Sauerstoff, Schwefel; und im Übrigen die für Formel 3 gegebenen Definitionen gelten. X is C (R **) 2 , NR **, oxygen, sulfur; and, moreover, the definitions given for formula 3 apply.
In einer weiteren Ausführungsform weisen die organischen Moleküle eine Struktur der Formel 5a auf oder haben eine Struktur der Formel 5a In a further embodiment, the organic molecules have a structure of the formula 5a or have a structure of the formula 5a
Figure imgf000030_0001
Figure imgf000030_0001
Formel 5a wobei in Formel 5a bedeutet: p ist 0 oder 1 ; t = 4 - 2p; Formula 5a wherein in formula 5a: p is 0 or 1; t = 4 - 2p;
X ist CR*2, NR*, Sauerstoff, Schwefel, eine direkte Bindung, wobei maximal zwei Platzhalter X gleichzeitig eine direkte Bindung sind, wobei diese nicht Bestandteil desselben Rings sind; X is CR * 2 , NR *, oxygen, sulfur, a direct bond, with a maximum of two wildcards X being simultaneously a direct bond, which are not part of the same ring;
Y ist S02, 1 ,2-Phenylen, C=C(CN)2, 2,2'-Benzophenon-Fragment, 2,2'-Diphenyl- dicyanomethan-Fragment, BR*; Y is S0 2 , 1, 2-phenylene, C = C (CN) 2 , 2,2'-benzophenone fragment, 2,2'-diphenyldicyanomethane fragment, BR *;
R' ist R* oder ist ausgewählt aus den folgenden Einheiten, wobei maximal zwei der Reste R' gleichzeitig gleich einer der folgenden Einheiten sind:  R 'is R * or is selected from the following units, wherein a maximum of two of the radicals R' are simultaneously one of the following units:
Figure imgf000030_0002
und im Übrigen die für Formel 3 bzw. 1 a gegebenen Definitionen gelten. In einer weiteren Ausführungsform weisen die organischen Moleküle eine Struktur der Formel 6a auf oder haben eine Struktur der Formel 6a
Figure imgf000030_0002
and, moreover, the definitions given for formula 3 or 1 a apply. In a further embodiment, the organic molecules have a structure of the formula 6a or have a structure of the formula 6a
Figure imgf000031_0001
Figure imgf000031_0001
Formel 6a Formula 6a
wobei in Formel 6a bedeutet: p ist 0 oder 1 ; t = 4 - 2p; wherein in formula 6a: p is 0 or 1; t = 4 - 2p;
X ist CR*2, NR*, Sauerstoff, Schwefel, eine direkte Bindung, wobei maximal zwei Platzhalter X gleichzeitig eine direkte Bindung sind, wobei diese nicht Bestandteil desselben Rings sind; X is CR * 2 , NR *, oxygen, sulfur, a direct bond, with a maximum of two wildcards X being simultaneously a direct bond, which are not part of the same ring;
Y ist S02, 1 ,2-Phenylen, C=C(CN)2, BR*, 2,2'-Benzophenon-Fragment, 2,2'-Diphenyl- dicyanomethan-Fragment, Y is S0 2 , 1, 2-phenylene, C = C (CN) 2 , BR *, 2,2'-benzophenone fragment, 2,2'-diphenyl-dicyanomethane fragment,
R' ist R* oder ist ausgewählt aus den folgenden Einheiten, wobei maximal zwei der Reste R' gleichzeitig gleich einer der folgenden Einheiten sind: R 'is R * or is selected from the following units, wherein a maximum of two of the radicals R' are simultaneously one of the following units:
Figure imgf000032_0001
und im Übrigen die für Formel 3 bzw. 1 a gegebenen Definitionen gelten.
Figure imgf000032_0001
and, moreover, the definitions given for formula 3 or 1 a apply.
In einer weiteren Ausführungsform weisen die organischen Moleküle eine Struktur der Formel 7a auf oder haben eine Struktur der Formel 7a In a further embodiment, the organic molecules have a structure of the formula 7a or have a structure of the formula 7a
Figure imgf000032_0002
Figure imgf000032_0002
Formel 7a wobei in Formel 7a bedeutet: p ist 0 oder 1 ; t = 4 - 2p; X ist CR*2, NR*, Sauerstoff, Schwefel, eine direkte Bindung, wobei maximal zwei Platzhalter X gleichzeitig eine direkte Bindung sind, wobei diese nicht Bestandteil desselben Rings sind; Formula 7a wherein in formula 7a: p is 0 or 1; t = 4 - 2p; X is CR * 2 , NR *, oxygen, sulfur, a direct bond, with a maximum of two wildcards X being simultaneously a direct bond, which are not part of the same ring;
Y ist S02, 1 ,2-Phenylen, C=C(CN)2, BR*, 2,2'-Benzophenon-Fragment, 2,2'-Diphenyl- dicyanomethan-Fragment, Y is S0 2 , 1, 2-phenylene, C = C (CN) 2 , BR *, 2,2'-benzophenone fragment, 2,2'-diphenyl-dicyanomethane fragment,
R' ist R* oder ist ausgewählt aus den folgenden Einheiten, wobei maximal zwei der Reste R' gleichzeitig gleich einer der folgenden Einheiten sind:  R 'is R * or is selected from the following units, wherein a maximum of two of the radicals R' are simultaneously one of the following units:
Figure imgf000033_0001
und im Übrigen die für Formel 3 bzw. 1 a gegebenen Definitionen gelten.
Figure imgf000033_0001
and, moreover, the definitions given for formula 3 or 1 a apply.
Tabelle 3: Beispiele für erfindungsgemäße organische Moleküle (AF1 -S-AF2). Die Benennung der Moleküle enthält links die Komponente aus AF1 aus Tabelle 1 , die direkt eine zweite chemische Gruppe AF2 (aus Tabelle 2) gebunden ist, die rechts genannt ist. Table 3: Examples of organic molecules according to the invention (AF1 -S-AF2). The naming of the molecules on the left contains the component from AF1 from Table 1, which is bound directly to a second chemical group AF2 (from Table 2), which is named on the right.
Figure imgf000033_0002
Figure imgf000034_0001
Figure imgf000033_0002
Figure imgf000034_0001
Figure imgf000034_0002
Figure imgf000035_0001
Figure imgf000036_0001
Figure imgf000034_0002
Figure imgf000035_0001
Figure imgf000036_0001
Figure imgf000037_0001
Figure imgf000037_0001
Figure imgf000037_0002
Figure imgf000037_0002
Figure imgf000038_0001
Figure imgf000038_0001
Figure imgf000038_0002
Figure imgf000039_0001
Figure imgf000038_0002
Figure imgf000039_0001
Figure imgf000039_0002
Figure imgf000040_0001
Figure imgf000039_0002
Figure imgf000040_0001
Figure imgf000040_0002
Figure imgf000040_0002
Figure imgf000041_0001
Figure imgf000041_0001
Figure imgf000042_0001
Figure imgf000043_0001
Figure imgf000044_0001
Figure imgf000045_0001
Figure imgf000046_0001
Figure imgf000047_0001
Figure imgf000042_0001
Figure imgf000043_0001
Figure imgf000044_0001
Figure imgf000045_0001
Figure imgf000046_0001
Figure imgf000047_0001
Figure imgf000047_0002
Figure imgf000048_0001
Figure imgf000049_0001
Figure imgf000050_0001
Figure imgf000050_0002
Figure imgf000050_0003
Figure imgf000051_0001
Figure imgf000051_0002
Figure imgf000051_0003
In Tabelle 1 und 2 sind mögliche Anknüpfungspositionen sind mit Kleinbuchstaben a bis z bezeichnet. Jede aromatische C-H und N-H Bindung ist optional mit einem löslichkeitsvermittelnden und/oder einem die Polymerisierbarkeit ermöglichenden Rest R substituiert.
Figure imgf000047_0002
Figure imgf000048_0001
Figure imgf000049_0001
Figure imgf000050_0001
Figure imgf000050_0002
Figure imgf000050_0003
Figure imgf000051_0001
Figure imgf000051_0002
Figure imgf000051_0003
In Table 1 and 2, possible link positions are indicated by lower case letters a through z. Each aromatic CH and NH bond is optionally substituted with a solubilising and / or a polymerisable R.
Die Erlaubtheit eines quantenmechanischen Überganges ist, wie allgemein bekannt, entweder durch theoretisch ableitbare spektroskopische Auswahlregeln (symmetrische Moleküle) oder durch Messung des Extinktionskoeffizienten (UV/VIS-Spektroskopie) oder quantenchemische Berechnung der Oszillatorstärke zugänglich, wobei sich Erlaubtheit durch eine große Oszillatorstärke auszeichnet. Je größer die Oszillatorstärke, desto schneller der damit verbundene Prozess. Bei einer langen Abklingdauer des (organischen) Emitters kommt es bei hohen Stromstärken schnell zu Sättigungseffekten, was die Bauteillebensdauer negativ beeinflusst und die Erreichung hoher Helligkeiten verhindert. Wird wie in der vorliegenden Erfindung durch eine geeignete Wahl des Anknüpfungsmotivs der AF1 eine gewisse Durchdringung von HOMO und LUMO erreicht, steigt das quantenmechanische Überlappungsintegral, und damit auch die Oszillatorstärke, so dass die Abklingzeit auf Werte unter 50 ps absinkt. Dies wird durch die erfindungsgemäße AF1 erreicht. The permissibility of a quantum mechanical transition is, as is well known, accessible either by theoretically derivable spectroscopic selection rules (symmetric molecules) or by measuring the extinction coefficient (UV / VIS spectroscopy) or quantum chemical calculation of the oscillator strength, with permission characterized by a large oscillator strength. The greater the oscillator strength, the faster the associated process. With a long decay time of the (organic) emitter, saturation effects quickly occur at high current intensities, which adversely affects the component lifetime and prevents the achievement of high brightness levels. If, as in the present invention, a certain penetration of HOMO and LUMO is achieved by a suitable choice of the attachment motif of the AF1, the quantum mechanical overlap integral, and thus also the oscillator strength, increases so that the decay time drops to values below 50 ps. This is achieved by the AF1 according to the invention.
Durch Kombination der oben definierten Paare aus chemischen Einheiten AF1 und AF2 ergeben sich entsprechend die beispielhaften erfindungsgemäßen Moleküle der Tabelle 3. Weitere organische Moleküle können durch Kombination der genannten Moleküleinheiten analog erhalten werden. By combining the above-defined pairs of chemical units AF1 and AF2, the exemplary inventive molecules of Table 3 are correspondingly obtained. Further organic molecules can be obtained analogously by combining said molecular units.
Erfindungsgemäße organische Moleküle sind in Tabelle 4 dargestellt die sich durch Kombination der oben definierten Paare aus chemischen Einheiten AF1 und AF2 und der Festlegung der Verknüpfung ergeben. Weitere organische Moleküle können durch Kombination der genannten Moleküleinheiten erhalten werden. Die Benennung der Moleküle erfolgt nach dem Schema AF-S-AF, wobei hinsichtlich der Benennung der chemischen Einheiten AF1 auf Tabelle 1 und hinsichtlich der Benennung der chemischen Einheit AF2 auf Tabelle 2 verweisen wird, da die in den Tabellen 1 und 2 verwendeten Nummern auch in Tabelle 4 verwendet werden. Der Übersichtlichkeit halber werden die beiden Nummern durch den Buchstaben S getrennt. Tabelle 4: Erfindungsgemäße organische Moleküle nach dem Schema AF-S-AF. In Klammern sind die Werte für AHOMO, ALUMO und Gap angegeben. Organic molecules of the present invention are shown in Table 4 which result from combining the above-defined pairs of chemical entities AF1 and AF2 and establishing the linkage. Other organic molecules can be obtained by combining the mentioned molecular units. The naming of the molecules is carried out according to the scheme AF-S-AF, with respect to the naming of the chemical units AF1 on Table 1 and with respect to the naming of the chemical unit AF2 on Table 2, since the numbers used in Tables 1 and 2 also in Table 4. For the sake of clarity, the two numbers are separated by the letter S. Table 4: Inventive organic molecules according to the scheme AF-S-AF. In brackets the values for AHOMO, ALUMO and Gap are given.
38 — S— 43 (1.20 1.21 1.55) 38 — S— 57 ( 1.46 1.75 1.01) 38 — S— 70 (1.26 1.42 1.34) 38 — S— 89 ( .01 1.16 1.60) 38 - S- 43 (1.20 1.21 1.55) 38 - S- 57 (1.46 1.75 1.01) 38 - S- 70 (1.26 1.42 1.34) 38 - S- 89 (.01 1.16 1.60)
38 — S— 90 (0.92 1.01 1.75) 38 — S— 108 (0.86 1.08 1.67) 38 — S— 109 (1.10 1.22 1.54) 38 — S— 1 15 (0.97 0.83 1.93)38 - S - 90 (0.92 1.01 1.75) 38 - S - 108 (0.86 1.08 1.67) 38 - S - 109 (1.10 1.22 1.54) 38 - S - 1 15 (0.97 0.83 1.93)
38 — S— 133 (1.30 0.98 1.77) 38 — S— 150 (2.12 0.86 1.90) 38 — S— 151 (2.03 1.12 1.64) 38 — S— 152 (2.68 1.41 1.34)38 - S-133 (1.30 0.98 1.77) 38 - S-150 (2.12 0.86 1.90) 38 - S-151 (2.03 1.12 1.64) 38 - S-152 (2.68 1.41 1.34)
38 — S— 153 (2.06 0.96 1.80) 38 — S— 165 (0.97 1.83 0.93) 38 — S— 192 (1.48 0.97 1.79) 38 — S— 207 (1.05 1.27 1.48)38 - S - 153 (2.06 0.96 1.80) 38 - S - 165 (0.97 1.83 0.93) 38 - S - 192 (1.48 0.97 1.79) 38 - S - 207 (1.05 1.27 1.48)
38 — S— 215 (1.28 1.54 1.22) 38 — S— 231 (1.52 1.08 1.68) 38 — S— 246 (1.05 0.84 1.92) 38 — S— 248 (1.1 1 1.39 1.37)38 - S-215 (1.28 1.54 1.22) 38 - S-231 (1.52 1.08 1.68) 38 - S-246 (1.05 0.84 1.92) 38 - S-248 (1.1 1 1.39 1.37)
38 — S— 255 (1.44 1.06 1.70) 38 — S— 265 (1.01 0.98 1.78) 38 — S— 268 (0.99 1.13 1.63) 38 — S— 269 (0.95 1.06 1.70)38 - S - 255 (1.44 1.06 1.70) 38 - S - 265 (1.01 0.98 1.78) 38 - S - 268 (0.99 1.13 1.63) 38 - S - 269 (0.95 1.06 1.70)
38 — S— 270 (1.09 1.74 1.02) 38 — S— 271 (1.70 1.15 1.61) 38 — S— 291 (1.78 0.99 1.76) 38 — S— 306 (1.16 1.06 1.70)38 - S-270 (1.09 1.74 1.02) 38 - S-271 (1.70 1.15 1.61) 38 - S-291 (1.78 0.99 1.76) 38 - S-306 (1.16 1.06 1.70)
38 — S— 307 (0.89 1.19 1.57) 38 — S— 320 (1.38 1.48 1.28) 38 — S— 329 (1.10 1.26 1.49) 38 — S— 342 (2.53 1.01 1.74)38 - S-307 (0.89 1.19 1.57) 38 - S-320 (1.38 1.48 1.28) 38 - S-329 (1.10 1.26 1.49) 38 - S-342 (2.53 1.01 1.74)
38 — S— 343 (3.06 1.51 1.25) 38 — S— 364 (1.24 1.64 1.12) 38 — S— 367 (1.05 0.96 1.80) 38 — S— 368 (1.16 1.50 1.26)38 - S-343 (3.06 1.51 1.25) 38 - S-364 (1.24 1.64 1.12) 38 - S-367 (1.05 0.96 1.80) 38 - S-368 (1.16 1.50 1.26)
38 — S— 371 (2.21 1.10 1.66) 38 — S— 395 (1.25 0.80 1.95) 38 — S— 447 (0.87 0.83 1.93) 38 — S— 451 (0.95 1.40 1.35)38 - S-371 (2.21 1.10 1.66) 38 - S-395 (1.25 0.80 1.95) 38 - S-447 (0.87 0.83 1.93) 38 - S-451 (0.95 1.40 1.35)
38 — S— 452 (1.01 1.06 1.70) 38 — S— 463 (0.89 1.51 1.25) 38 — S— 472 (1.61 1.78 0.98) 38 — S— 473 (1.08 0.98 1.77)38 - S-452 (1.01 1.06 1.70) 38 - S-463 (0.89 1.51 1.25) 38 - S-472 (1.61 1.78 0.98) 38 - S-473 (1.08 0.98 1.77)
38 — S— 474 (0.94 0.87 1.88) 39 — S— 0 (1 00 1.50 1.86) 39 — S— 9 (1.12 1.04 2.32) 39 — S— 20 ( .22 1.58 1.78)38 - S - 474 (0.94 0.87 1.88) 39 - S - 0 (1 00 1.50 1.86) 39 - S - 9 (1.12 1.04 2.32) 39 - S - 20 (.22 1.58 1.78)
39 — S— 27 (1.13 1.75 1.61) 39 — S— 28 ( 1.20 2.02 1.34) 39 — S— 29 (0.96 1.74 1.62) 39 — S— 43 ( .77 2.38 0.97)39 - S-27 (1.13 1.75 1.61) 39 - S-28 (1.20 2.02 1.34) 39 - S- 29 (0.96 1.74 1.62) 39 - S- 43 (.77 2.38 0.97)
39 — S— 44 (0.85 0.90 2.46) 39 — S— 46 (2.37 1.90 1.45) 39 — S— 56 (1.12 1.21 2.15) 39 — S— 61 ( .11 1.72 1.63)39 - S- 44 (0.85 0.90 2.46) 39 - S- 46 (2.37 1.90 1.45) 39 - S- 56 (1.12 1.21 2.15) 39 - S- 61 (.11 1.72 1.63)
39 — S— 62 (0.99 1.92 1.43) 39 — S— 65 ( 1.12 1.52 1.84) 39 — S— 68 (0.83 1.48 1.88) 39 — S— 79 ( .10 1.89 1.46)39 - S- 62 (0.99 1.92 1.43) 39 - S- 65 (1.12 1.52 1.84) 39 - S- 68 (0.83 1.48 1.88) 39 - S- 79 (.10 1.89 1.46)
39 — S— 80 (1.06 1.85 1.50) 39 — S— 81 ( 1.13 1.98 1.38) 39 — S— 82 (0.86 2.16 1.19) 39 — S— 83 ( .16 1.15 2.21)39 - S- 80 (1.06 1.85 1.50) 39 - S- 81 (1.13 1.98 1.38) 39 - S-82 (0.86 2.16 1.19) 39 - S-83 (.16 1.15 2.21)
39 — S— 85 (1.62 1.71 1.65) 39 — S— 86 (0.83 2.08 1.28) 39 — S— 89 (1.59 2.33 1.02) 39 — S— 90 ( .50 2.18 1.17)39 - S- 85 (1.62 1.71 1.65) 39 - S- 86 (0.83 2.08 1.28) 39 - S- 89 (1.59 2.33 1.02) 39 - S- 90 (.50 2.18 1.17)
39 — S— 101 (1.26 2.03 1.32) 39 — S— 102 (0.88 1.04 2.31) 39 — S— 105 (1.42 1.13 2.23) 39 — S— 107 (1.88 1.87 1.49)39 - S-101 (1.26 2.03 1.32) 39 - S-102 (0.88 1.04 2.31) 39 - S-105 (1.42 1.13 2.23) 39 - S-107 (1.88 1.87 1.49)
39 — S— 108 (1.44 2.26 1.10) 39 — S— 109 (1.67 2.39 0.96) 39 — S— 1 10 (1.17 2.03 1.32) 39 — S— 1 11 (1.87 1.15 2.20)39 - S-108 (1.44 2.26 1.10) 39 - S-109 (1.67 2.39 0.96) 39 - S-1 10 (1.17 2.03 1.32) 39 - S-1 11 (1.87 1.15 2.20)
39 — S— 1 12 (1.06 1.53 1.83) 39 — S— 1 13 (1.27 2.45 0.91) 39 — S— 1 15 (1.54 2.01 1.35) 39 — S— 1 18 (1.15 1.43 1.93)39 - S - 1 12 (1.06 1.53 1.83) 39 - S - 1 13 (1.27 2.45 0.91) 39 - S - 1 15 (1.54 2.01 1.35) 39 - S - 1 18 (1.15 1.43 1.93)
39 — S— 1 19 (1.13 1.64 1.71) 39 — S— 131 (1.18 1.1 1 2.25) 39 — S— 132 (1.09 1.35 2.01) 39 — S— 133 (1.88 2.16 1.20)39 - S-1 19 (1.13 1.64 1.71) 39 - S-131 (1.18 1.1 1 2.25) 39 - S-132 (1.09 1.35 2.01) 39 - S-133 (1.88 2.16 1.20)
39 — S— 144 (1.21 2.07 1.29) 39 — S— 148 (0.87 0.94 2.42) 39 — S— 150 (2.70 2.03 1.32) 39 — S— 151 (2.61 2.29 1.07)39 - S - 144 (1.21 2.07 1.29) 39 - S - 148 (0.87 0.94 2.42) 39 - S - 150 (2.70 2.03 1.32) 39 - S - 151 (2.61 2.29 1.07)
39 — S— 153 (2.63 2.13 1.22) 39 — S— 154 (2.17 1.26 2.10) 39 — S— 166 (1.89 1.09 2.27) 39 — S— 171 (1.66 1.08 2.27)39 - S-153 (2.63 2.13 1.22) 39 - S- 154 (2.17 1.26 2.10) 39 - S- 166 (1.89 1.09 2.27) 39 - S-171 (1.66 1.08 2.27)
39 — S— 177 (1.71 1.81 1.54) 39 — S— 183 (1.36 2.15 1.21) 39 — S— 184 (2.45 1.62 1.73) 39 — S— 187 (1.59 1.00 2.36)39 - S-177 (1.71 1.81 1.54) 39 - S-183 (1.36 2.15 1.21) 39 - S-184 (2.45 1.62 1.73) 39 - S-187 (1.59 1.00 2.36)
39 — S— 188 (2.03 1.04 2.32) 39 — S— 192 (2.06 2.14 1.21) 39 — S— 193 (0.97 1.31 2.05) 39 — S— 195 (1.88 1.47 1.89)39 - S-188 (2.03 1.04 2.32) 39 - S-192 (2.06 2.14 1.21) 39 - S-193 (0.97 1.31 2.05) 39 - S-195 (1.88 1.47 1.89)
39 — S— 198 (1.59 1.53 1.83) 39 — S— 205 (1.1 1 1.59 1.77) 39 — S— 207 (1.63 2.45 0.91) 39 — S— 208 (1.07 1.06 2.30)39 - S-198 (1.59 1.53 1.83) 39 - S-205 (1.1 1 1.59 1.77) 39 - S-207 (1.63 2.45 0.91) 39 - S-208 (1.07 1.06 2.30)
39 — S— 209 (0.82 1.14 2.22) 39 — S— 213 (1.56 1.48 1.87) 39 — S— 217 (0.98 1.52 1.84) 39 — S— 218 (0.95 1.69 1.66)39 - S-209 (0.82 1.14 2.22) 39 - S-213 (1.56 1.48 1.87) 39 - S-217 (0.98 1.52 1.84) 39 - S-218 (0.95 1.69 1.66)
39 — S— 222 (0.86 1.10 2.26) 39 — S— 231 (2.10 2.26 1.10) 39 — S— 233 (1.48 1.68 1.68) 39 — S— 234 (1.30 1.76 1.59)39 - S-222 (0.86 1.10 2.26) 39 - S-231 (2.10 2.26 1.10) 39 - S-233 (1.48 1.68 1.68) 39 - S-234 (1.30 1.76 1.59)
39 — S— 237 (1.32 2.06 1.30) 39 — S— 243 (2.05 0.89 2.47) 39 — S— 244 (1.37 1.67 1.68) 39 — S— 245 (1.29 1.45 1.91)39 - S-237 (1.32 2.06 1.30) 39 - S-243 (2.05 0.89 2.47) 39 - S-244 (1.37 1.67 1.68) 39 - S-245 (1.29 1.45 1.91)
39 — S— 246 (1.62 2.01 1.34) 39 — S— 249 (1.16 2.40 0.95) 39 — S— 251 (1.13 2.26 1.10) 39 — S— 254 (1.12 1.37 1.99)39 - S-246 (1.62 2.01 1.34) 39 - S-249 (1.16 2.40 0.95) 39 - S-251 (1.13 2.26 1.10) 39 - S-254 (1.12 1.37 1.99)
39 — S— 255 (2.02 2.23 1.12) 39 — S— 265 (1.59 2.15 1.20) 39 — S— 266 (1.22 1.73 1.62) 39 — S— 267 (1.02 1.43 1.92)39 - S-255 (2.02 2.23 1.12) 39 - S-265 (1.59 2.15 1.20) 39 - S-266 (1.22 1.73 1.62) 39 - S-267 (1.02 1.43 1.92)
39 — S— 268 (1.56 2.30 1.05) 39 — S— 269 (1.53 2.23 1.12) 39 — S— 271 (2.28 2.32 1.03) 39 — S— 274 (0.89 1.23 2.12)39 - S - 268 (1.56 2.30 1.05) 39 - S - 269 (1.53 2.23 1.12) 39 - S - 271 (2.28 2.32 1.03) 39 - S - 274 (0.89 1.23 2.12)
39 — S— 277 (1.1 1 1.50 1.86) 39 — S— 279 (1.16 1.56 1.79) 39 — S— 280 (0.84 1.24 2.1 1) 39 — S— 282 (0.96 1.07 2.29)39 - S-277 (1.1 1 1.50 1.86) 39 - S-279 (1.16 1.56 1.79) 39 - S-280 (0.84 1.24 2.1 1) 39 - S-282 (0.96 1.07 2.29)
39 — S— 285 (0.89 1.44 1.91) 39 — S— 286 (1.14 1.35 2.01) 39 — S— 287 (0.95 1.36 2.00) 39 — S— 288 (0.93 1.30 2.06)39 - S-285 (0.89 1.44 1.91) 39 - S-286 (1.14 1.35 2.01) 39 - S-287 (0.95 1.36 2.00) 39 - S-288 (0.93 1.30 2.06)
39 — S— 289 (1.19 1.14 2.22) 39 — S— 290 (1.22 1.76 1.59) 39 — S— 291 (2.36 2.17 1.19) 39 — S— 292 (1.69 1.83 1.53)39 - S-289 (1.19 1.14 2.22) 39 - S-290 (1.22 1.76 1.59) 39 - S-291 (2.36 2.17 1.19) 39 - S-292 (1.69 1.83 1.53)
39 — S— 293 (1.20 1.64 1.72) 39 — S— 294 (1.65 1.67 1.69) 39 — S— 295 (1.41 1.91 1.44) 39 — S— 296 (1.68 1.91 1.45)39 - S-293 (1.20 1.64 1.72) 39 - S-294 (1.65 1.67 1.69) 39 - S-295 (1.41 1.91 1.44) 39 - S-296 (1.68 1.91 1.45)
39 — S— 297 (1.00 1.04 2.32) 39 — S— 298 (1.25 1.51 1.84) 39 — S— 300 (1.26 0.91 2.44) 39 — S— 303 (1.02 0.89 2.47)39 - S - 297 (1.00 1.04 2.32) 39 - S - 298 (1.25 1.51 1.84) 39 - S - 300 (1.26 0.91 2.44) 39 - S - 303 (1.02 0.89 2.47)
39 — S— 304 (1.06 1.36 2.00) 39 — S— 305 (1.57 1.58 1.78) 39 — S— 306 (1.73 2.23 1.13) 39 — S— 307 (1.46 2.36 1.00)39 - S-304 (1.06 1.36 2.00) 39 - S-305 (1.57 1.58 1.78) 39 - S-306 (1.73 2.23 1.13) 39 - S-307 (1.46 2.36 1.00)
39 — S— 310 (1.17 0.97 2.38) 39 — S— 311 (0.90 1.25 2.1 1) 39 — S— 312 (0.99 1.12 2.24) 39 — S— 316 (1.06 1.58 1.78)39 - S-310 (1.17 0.97 2.38) 39 - S-311 (0.90 1.25 2.1 1) 39 - S-312 (0.99 1.12 2.24) 39 - S-316 (1.06 1.58 1.78)
39 — S— 327 (1.35 1.98 1.38) 39 — S— 329 (1.68 2.44 0.92) 39 — S— 331 (1.21 1.16 2.20) 39 — S— 332 (1.06 1.33 2.03)39 - S-327 (1.35 1.98 1.38) 39 - S-329 (1.68 2.44 0.92) 39 - S-331 (1.21 1.16 2.20) 39 - S-332 (1.06 1.33 2.03)
39 — S— 336 (1.16 1.22 2.14) 39 — S— 342 (3.10 2.19 1.17) 39 — S— 356 (0.83 1.04 2.32) 39 — S— 358 (1.00 1.50 1.86)39 - S-336 (1.16 1.22 2.14) 39 - S-342 (3.10 2.19 1.17) 39 - S-356 (0.83 1.04 2.32) 39 - S-358 (1.00 1.50 1.86)
39 — S— 367 (1.63 2.13 1.22) 39 — S— 370 (0.97 1.56 1.79) 39 — S— 371 (2.79 2.28 1.08) 39 — S— 372 (1.20 1.26 2.09)39 - S-367 (1.63 2.13 1.22) 39 - S-370 (0.97 1.56 1.79) 39 - S-371 (2.79 2.28 1.08) 39 - S-372 (1.20 1.26 2.09)
39 — S— 374 (0.81 1.76 1.60) 39 — S— 379 (0.88 1.26 2.10) 39 — S— 382 (0.95 1.44 1.92) 39 — S— 391 (0.89 1.25 2.1 1)39 - S-374 (0.81 1.76 1.60) 39 - S-379 (0.88 1.26 2.10) 39 - S-382 (0.95 1.44 1.92) 39 - S-391 (0.89 1.25 2.1 1)
39 — S— 395 (1.82 1.98 1.38) 39 — S— 396 (1.25 1.42 1.94) 39 — S— 397 (1.05 1.26 2.10) 39 — S— 415 (0.94 1.14 2.21)39 - S-395 (1.82 1.98 1.38) 39 - S-396 (1.25 1.42 1.94) 39 - S-397 (1.05 1.26 2.10) 39 - S-415 (0.94 1.14 2.21)
39 — S— 430 (0.83 2.08 1.28) 39 — S— 434 (0.90 1.55 1.81) 39 — S— 435 (0.98 1.72 1.64) 39 — S— 437 (1.16 1.10 2.26)39 - S - 430 (0.83 2.08 1.28) 39 - S - 434 (0.90 1.55 1.81) 39 - S - 435 (0.98 1.72 1.64) 39 - S - 437 (1.16 1.10 2.26)
39 — S— 440 (1.51 1.89 1.47) 39 — S— 441 (1.44 1.81 1.54) 39 — S— 443 (0.91 2.43 0.93) 39 — S— 447 (1.45 2.00 1.36)39 - S - 440 (1.51 1.89 1.47) 39 - S - 441 (1.44 1.81 1.54) 39 - S - 443 (0.91 2.43 0.93) 39 - S - 447 (1.45 2.00 1.36)
39 — S— 449 (1.19 1.97 1.39) 39 — S— 450 (0.81 1.64 1.72) 39 — S— 452 (1.59 2.24 1.12) 39 — S— 453 (1.08 0.94 2.42)39 - S - 449 (1.19 1.97 1.39) 39 - S - 450 (0.81 1.64 1.72) 39 - S - 452 (1.59 2.24 1.12) 39 - S - 453 (1.08 0.94 2.42)
39 — S— 454 (0.90 1.1 1 2.25) 39 — S— 455 (0.89 1.38 1.98) 39 — S— 457 (1.03 1.88 1.48) 39 — S— 459 (0.82 2.1 1 1.24)39 - S - 454 (0.90 1.1 1 2.25) 39 - S - 455 (0.89 1.38 1.98) 39 - S - 457 (1.03 1.88 1.48) 39 - S - 459 (0.82 2.1 1 1.24)
39 — S— 460 (1.31 2.31 1.04) 39 — S— 461 (1.03 2.07 1.28) 39 — S— 468 (0.91 1.79 1.57) 39 — S— 469 (1.01 2.21 1.14)39 - S - 460 (1.31 2.31 1.04) 39 - S - 461 (1.03 2.07 1.28) 39 - S - 468 (0.91 1.79 1.57) 39 - S - 469 (1.01 2.21 1.14)
39 — S— 471 (1.61 1.54 1.81) 39 — S— 473 (1.66 2.16 1.20) 39 — S— 474 (1.51 2.05 1.31) 41 — S— 0 (1 32 1.34 1.55)39 - S - 471 (1.61 1.54 1.81) 39 - S - 473 (1.66 2.16 1.20) 39 - S - 474 (1.51 2.05 1.31) 41 - S - 0 (1 32 1.34 1.55)
41 — S— 9 (1.43 0.88 2.01) 41 — S— 20 ( 1.53 1.43 1.46) 41 — S— 27 (1.45 1.60 1.30) 41 — S— 28 ( .51 1.87 1.03)41 - S - 9 (1.43 0.88 2.01) 41 - S - 20 (1.53 1.43 1.46) 41 - S - 27 (1.45 1.60 1.30) 41 - S - 28 (.51 1.87 1.03)
41 — S— 29 (1.27 1.59 1.30) 41 — S— 38 (0.89 1.02 1.87) 41 — S— 40 (1.09 1.59 1.30) 41 — S— 46 (2.68 1.75 1.14)41 - S-29 (1.27 1.59 1.30) 41 - S-38 (0.89 1.02 1.87) 41 - S-40 (1.09 1.59 1.30) 41 - S-46 (2.68 1.75 1.14)
41 — S— 56 (1.44 1.06 1.83) 41 — S— 61 (1.42 1.57 1.32) 41 — S— 62 (1.30 1.77 1.12) 41 — S— 65 ( .43 1.37 1.53) — S— 68 ( .14 1.33 1.56) 41— S— 79 (1.42 1.74 1.15) 41— S— 80 ( .37 1.70 1.19) 41— S— 81 ( .44 1.82 1.07)41 - S- 56 (1.44 1.06 1.83) 41 - S- 61 (1.42 1.57 1.32) 41 - S- 62 (1.30 1.77 1.12) 41 - S- 65 (.43 1.37 1.53) - S- 68 (.14 1.33 1.56) 41- S- 79 (1.42 1.74 1.15) 41- S- 80 (.37 1.70 1.19) 41- S- 81 (.44 1.82 1.07)
— S— 83 ( .48 1.00 1.89) 41 — S— 85 (1.93 1.55 1.34) 41 — S— 86 ( .15 1.92 0.97) 41 — S— 101 (1.57 1.88 1.01)- S-83 (.48 1.00 1.89) 41 - S-85 (1.93 1.55 1.34) 41 - S-86 (.15 1.92 0.97) 41 - S-101 (1.57 1.88 1.01)
— S— 102 (1.19 0.89 2.00) 41 — S— 105 (1.73 0.98 1.91) 41 — S— 107 (2.19 1.72 1.18) 41 — S— 1 10 (1.48 1.88 1.01)- S - 102 (1.19 0.89 2.00) 41 - S - 105 (1.73 0.98 1.91) 41 - S - 107 (2.19 1.72 1.18) 41 - S - 1 10 (1.48 1.88 1.01)
— S— 1 11 (2.18 1.00 1.89) 41 — S— 1 12 (1.38 1.38 1.51) 41 — S— 1 15 (1.86 1.86 1.04) 41 — S— 1 18 (1.47 1.28 1.61)- S - 1 11 (2.18 1.00 1.89) 41 - S - 1 12 (1.38 1.38 1.51) 41 - S - 1 15 (1.86 1.86 1.04) 41 - S - 1 18 (1.47 1.28 1.61)
— S— 1 19 (1.44 1.49 1.40) 41 — S— 123 (1.08 1.62 1.27) 41 — S— 131 (1.49 0.95 1.94) 41 — S— 132 (1.40 1.20 1.69)- S - 1 19 (1.44 1.49 1.40) 41 - S - 123 (1.08 1.62 1.27) 41 - S - 131 (1.49 0.95 1.94) 41 - S - 132 (1.40 1.20 1.69)
— S— 144 (1.53 1.92 0.97) 41 — S— 147 (0.93 1.49 1.40) 41 — S— 150 (3.01 1.88 1.01) 41 — S— 153 (2.95 1.98 0.91)41 - S-147 (0.93 1.49 1.40) 41 - S-150 (3.01 1.88 1.01) 41 - S-153 (2.95 1.98 0.91) - S- 144 (1.53 1.92 0.97)
— S— 154 (2.48 1.1 1 1.78) 41 — S— 166 (2.20 0.94 1.96) 41 — S— 171 (1.97 0.93 1.96) 41 — S— 177 (2.03 1.66 1.23)- S - 154 (2.48 1.1 1 1.78) 41 - S - 166 (2.20 0.94 1.96) 41 - S - 171 (1.97 0.93 1.96) 41 - S - 177 (2.03 1.66 1.23)
— S— 184 (2.76 1.47 1.42) 41 — S— 187 (1.91 0.84 2.05) 41 — S— 188 (2.34 0.88 2.01) 41 — S— 193 (1.29 1.16 1.74)- S - 184 (2.76 1.47 1.42) 41 - S - 187 (1.91 0.84 2.05) 41 - S - 188 (2.34 0.88 2.01) 41 - S - 193 (1.29 1.16 1.74)
— S— 195 (2.19 1.32 1.57) 41 — S— 198 (1.90 1.38 1.51) 41 — S— 205 (1.42 1.44 1.45) 41 — S— 208 (1.39 0.91 1.98)- S - 195 (2.19 1.32 1.57) 41 - S - 198 (1.90 1.38 1.51) 41 - S - 205 (1.42 1.44 1.45) 41 - S - 208 (1.39 0.91 1.98)
— S— 209 (1.13 0.99 1.91) 41 — S— 213 (1.87 1.33 1.56) 41 — S— 217 (1.29 1.37 1.53) 41 — S— 218 (1.26 1.54 1.35)- S-209 (1.13 0.99 1.91) 41 - S-213 (1.87 1.33 1.56) 41 - S-217 (1.29 1.37 1.53) 41 - S-218 (1.26 1.54 1.35)
— S— 219 (1.07 1.10 1.79) 41 — S— 222 (1.18 0.95 1.94) 41 — S— 228 (0.81 1.10 1.79) 41 — S— 233 (1.80 1.53 1.36)- S - 219 (1.07 1.10 1.79) 41 - S - 222 (1.18 0.95 1.94) 41 - S - 228 (0.81 1.10 1.79) 41 - S - 233 (1.80 1.53 1.36)
— S— 234 (1.62 1.61 1.28) 41 — S— 237 (1.63 1.91 0.98) 41 — S— 238 (0.93 1.77 1.13) 41 — S— 244 (1.68 1.52 1.37)- S - 234 (1.62 1.61 1.28) 41 - S - 237 (1.63 1.91 0.98) 41 - S - 238 (0.93 1.77 1.13) 41 - S - 244 (1.68 1.52 1.37)
— S— 245 (1.60 1.30 1.60) 41 — S— 246 (1.94 1.86 1.03) 41 — S— 254 (1.44 1.22 1.67) 41 — S— 266 (1.54 1.58 1.31)- S-245 (1.60 1.30 1.60) 41 - S-246 (1.94 1.86 1.03) 41 - S-254 (1.44 1.22 1.67) 41 - S-266 (1.54 1.58 1.31)
— S— 267 (1.34 1.28 1.61) 41 — S— 274 (1.20 1.08 1.81) 41 — S— 275 (1.01 1.50 1.39) 41 — S— 277 (1.42 1.35 1.54)41 - S-274 (1.20 1.08 1.81) 41 - S-275 (1.01 1.50 1.39) 41 - S-277 (1.42 1.35 1.54)
— S— 279 (1.48 1.41 1.48) 41 — S— 280 (1.16 1.09 1.80) 41 — S— 282 (1.27 0.92 1.97) 41 — S— 284 (1.05 0.92 1.97)- S - 279 (1.48 1.41 1.48) 41 - S - 280 (1.16 1.09 1.80) 41 - S - 282 (1.27 0.92 1.97) 41 - S - 284 (1.05 0.92 1.97)
— S— 285 (1.20 1.29 1.60) 41 — S— 286 (1.45 1.20 1.69) 41 — S— 287 (1.26 1.21 1.68) 41 — S— 288 (1.25 1.15 1.74)- S - 285 (1.20 1.29 1.60) 41 - S - 286 (1.45 1.20 1.69) 41 - S - 287 (1.26 1.21 1.68) 41 - S - 288 (1.25 1.15 1.74)
— S— 289 (1.50 0.99 1.91) 41 — S— 290 (1.54 1.61 1.28) 41 — S— 292 (2.01 1.68 1.21) 41 — S— 293 (1.51 1.49 1.40)- S-289 (1.50 0.99 1.91) 41 - S-290 (1.54 1.61 1.28) 41 - S-292 (2.01 1.68 1.21) 41 - S-293 (1.51 1.49 1.40)
— S— 294 (1.96 1.52 1.37) 41 — S— 295 (1.72 1.76 1.13) 41 — S— 296 (2.00 1.76 1.13) 41 — S— 297 (1.31 0.89 2.00)- S - 294 (1.96 1.52 1.37) 41 - S - 295 (1.72 1.76 1.13) 41 - S - 296 (2.00 1.76 1.13) 41 - S - 297 (1.31 0.89 2.00)
— S— 298 (1.57 1.36 1.53) 41 — S— 299 (0.82 1.70 1.19) 41 — S— 304 (1.37 1.21 1.68) 41 — S— 305 (1.89 1.43 1.47)- S - 298 (1.57 1.36 1.53) 41 - S - 299 (0.82 1.70 1.19) 41 - S - 304 (1.37 1.21 1.68) 41 - S - 305 (1.89 1.43 1.47)
— S— 310 (1.49 0.82 2.07) 41 — S— 311 (1.21 1.10 1.79) 41 — S— 312 (1.31 0.97 1.92) 41 — S— 313 (1.08 1.14 1.75)- S - 310 (1.49 0.82 2.07) 41 - S - 311 (1.21 1.10 1.79) 41 - S - 312 (1.31 0.97 1.92) 41 - S - 313 (1.08 1.14 1.75)
— S— 316 (1.37 1.42 1.47) 41 — S— 327 (1.66 1.83 1.06) 41 — S— 330 (0.99 0.83 2.06) 41 — S— 331 (1.52 1.01 1.89)- S - 316 (1.37 1.42 1.47) 41 - S - 327 (1.66 1.83 1.06) 41 - S - 330 (0.99 0.83 2.06) 41 - S - 331 (1.52 1.01 1.89)
— S— 332 (1.37 1.18 1.71) 41 — S— 336 (1.47 1.07 1.82) 41 — S— 341 (0.97 1.70 1.19) 41 — S— 356 (1.14 0.89 2.01)- S-332 (1.37 1.18 1.71) 41 - S-336 (1.47 1.07 1.82) 41 - S-341 (0.97 1.70 1.19) 41 - S-356 (1.14 0.89 2.01)
— S— 358 (1.32 1.34 1.55) 41 — S— 367 (1.94 1.98 0.91) 41 — S— 370 (1.29 1.41 1.48) 41 — S— 372 (1.51 1.1 1 1.78)- S-358 (1.32 1.34 1.55) 41 - S-367 (1.94 1.98 0.91) 41 - S-370 (1.29 1.41 1.48) 41 - S-372 (1.51 1.1 1 1.78)
— S— 373 (0.90 1.12 1.78) 41 — S— 374 (1.12 1.60 1.29) 41 — S— 379 (1.20 1.1 1 1.78) 41 — S— 382 (1.27 1.29 1.60)41 - S-374 (1.12 1.60 1.29) 41 - S-379 (1.20 1.1 1 1.78) 41 - S-382 (1.27 1.29 1.60) - S-373 (0.90 1.12 1.78)
— S— 391 (1.21 1.09 1.80) 41 — S— 395 (2.13 1.83 1.07) 41 — S— 396 (1.56 1.26 1.63) 41 — S— 397 (1.36 1.1 1 1.78)- S-391 (1.21 1.09 1.80) 41 - S-395 (2.13 1.83 1.07) 41 - S-396 (1.56 1.26 1.63) 41 - S-397 (1.36 1.1 1 1.78)
— S— 415 (1.25 0.99 1.90) 41 — S— 430 (1.15 1.93 0.97) 41 — S— 434 (1.21 1.40 1.49) 41 — S— 435 (1.30 1.57 1.32)- S - 415 (1.25 0.99 1.90) 41 - S - 430 (1.15 1.93 0.97) 41 - S - 434 (1.21 1.40 1.49) 41 - S - 435 (1.30 1.57 1.32)
— S— 437 (1.48 0.94 1.95) 41 — S— 440 (1.82 1.74 1.16) 41 — S— 441 (1.75 1.66 1.23) 41 — S— 447 (1.76 1.85 1.04)41- S-440 (1.82 1.74 1.16) 41- S-441 (1.75 1.66 1.23) 41- S-447 (1.76 1.85 1.04)
— S— 449 (1.50 1.82 1.07) 41 — S— 450 (1.12 1.48 1.41) 41 — S— 454 (1.22 0.95 1.94) 41 — S— 455 (1.20 1.22 1.67)- S - 449 (1.50 1.82 1.07) 41 - S - 450 (1.12 1.48 1.41) 41 - S - 454 (1.22 0.95 1.94) 41 - S - 455 (1.20 1.22 1.67)
— S— 456 (0.89 0.94 1.96) 41 — S— 457 (1.35 1.73 1.16) 41 — S— 458 (0.89 1.52 1.37) 41 — S— 459 (1.13 1.96 0.93)41 - S-457 (1.35 1.73 1.16) 41 - S-458 (0.89 1.52 1.37) 41 - S-459 (1.13 1.96 0.93)
— S— 461 (1.34 1.92 0.97) 41 — S— 462 (1.03 1.94 0.96) 41 — S— 467 (1.03 1.33 1.56) 41 — S— 468 (1.23 1.64 1.26)- S-461 (1.34 1.92 0.97) 41 - S-462 (1.03 1.94 0.96) 41 - S-467 (1.03 1.33 1.56) 41 - S-468 (1.23 1.64 1.26)
— S— 471 (1.93 1.39 1.50) 41 — S— 474 (1.83 1.90 1.00) 41 — S— 482 (0.86 1.51 1.38) 41 — S— 483 (0.90 1.58 1.31)- S-471 (1.93 1.39 1.50) 41 - S-474 (1.83 1.90 1.00) 41 - S-482 (0.86 1.51 1.38) 41 - S-483 (0.90 1.58 1.31)
— S— 43 (0.92 1.49 1.82) 44 — S— 46 (1.52 1.01 2.30) 44 — S— 57 ( .19 2.02 1.28) 44 — S— 70 (0.99 1.70 1.61)- S-43 (0.92 1.49 1.82) 44 - S- 46 (1.52 1.01 2.30) 44 - S- 57 (.19 2.02 1.28) 44 - S- 70 (0.99 1.70 1.61)
— S— 107 (1.03 0.97 2.34) 44 — S— 109 (0.82 1.50 1.81) 44 — S— 133 (1.03 1.26 2.05) 44 — S— 150 (1.85 1.13 2.17)- S-107 (1.03 0.97 2.34) 44 - S-109 (0.82 1.50 1.81) 44 - S-133 (1.03 1.26 2.05) 44 - S-150 (1.85 1.13 2.17)
— S— 151 (1.76 1.39 1.92) 44 — S— 152 (2.40 1.69 1.62) 44 — S— 153 (1.78 1.23 2.07) 44 — S— 177 (0.86 0.91 2.39)- S - 151 (1.76 1.39 1.92) 44 - S - 152 (2.40 1.69 1.62) 44 - S - 153 (1.78 1.23 2.07) 44 - S - 177 (0.86 0.91 2.39)
— S— 192 (1.21 1.25 2.06) 44 — S— 215 (1.01 1.82 1.49) 44 — S— 231 (1.25 1.36 1.95) 44 — S— 247 (0.91 2.32 0.99)- S-192 (1.21 1.25 2.06) 44 - S-215 (1.01 1.82 1.49) 44 - S-231 (1.25 1.36 1.95) 44 - S-247 (0.91 2.32 0.99)
— S— 248 (0.84 1.66 1.64) 44 — S— 255 (1.17 1.33 1.97) 44 — S— 259 (1.02 2.15 1.16) 44 — S— 270 (0.82 2.01 1.29)- S - 248 (0.84 1.66 1.64) 44 - S - 255 (1.17 1.33 1.97) 44 - S - 259 (1.02 2.15 1.16) 44 - S - 270 (0.82 2.01 1.29)
— S— 271 (1.43 1.43 1.88) 44 — S— 291 (1.51 1.27 2.04) 44 — S— 292 (0.84 0.93 2.38) 44 — S— 296 (0.83 1.01 2.30)- S-271 (1.43 1.43 1.88) 44 - S-291 (1.51 1.27 2.04) 44 - S-292 (0.84 0.93 2.38) 44 - S-296 (0.83 1.01 2.30)
— S— 306 (0.89 1.33 1.97) 44 — S— 320 (1.1 1 1.75 1.56) 44 — S— 324 (1.08 2.25 1.06) 44 — S— 329 (0.83 1.54 1.77)- S - 306 (0.89 1.33 1.97) 44 - S - 320 (1.1 1 1.75 1.56) 44 - S - 324 (1.08 2.25 1.06) 44 - S - 329 (0.83 1.54 1.77)
— S— 342 (2.25 1.29 2.02) 44 — S— 343 (2.78 1.78 1.53) 44 — S— 364 (0.96 1.91 1.40) 44 — S— 368 (0.89 1.78 1.53)- S-342 (2.25 1.29 2.02) 44 - S-343 (2.78 1.78 1.53) 44 - S-364 (0.96 1.91 1.40) 44 - S-368 (0.89 1.78 1.53)
— S— 371 (1.94 1.38 1.93) 44 — S— 395 (0.97 1.08 2.23) 44 — S— 472 (1.34 2.06 1.25) 44 — S— 473 (0.81 1.26 2.05)- S-371 (1.94 1.38 1.93) 44 - S-395 (0.97 1.08 2.23) 44 - S-472 (1.34 2.06 1.25) 44 - S-473 (0.81 1.26 2.05)
— S— 0 (1 80 1.50 1.07) 49 — S— 5 (1.03 1.01 1.57) 49 — S— 9 (1 91 1.04 1.53) 49 — S— H ( .02 1.28 1.29)- S - 0 (1 80 1.50 1.07) 49 - S - 5 (1.03 1.01 1.57) 49 - S - 9 (1 91 1.04 1.53) 49 - S - H (.02 1.28 1.29)
— S— 19 ( .48 0.94 1.63) 49 — S— 20 (2.01 1.59 0.98) 49 — S— 30 ( .16 0.96 1.61) 49 — S— 31 ( .18 0.92 1.65)- S - 19 (.48 0.94 1.63) 49 - S - 20 (2.01 1.59 0.98) 49 - S - 30 (.16 0.96 1.61) 49 - S - 31 (.18 0.92 1.65)
— S— 33 ( .21 0.80 1.77) 49 — S— 38 (1.37 1.18 1.39) 49 — S— 44 ( .64 0.90 1.67) 49 — S— 45 ( .04 1.39 1.18)- S- 33 (.21 0.80 1.77) 49 - S- 38 (1.37 1.18 1.39) 49 - S- 44 (.64 0.90 1.67) 49 - S- 45 (.04 1.39 1.18)
— S— 47 (0.90 1.22 1.35) 49 — S— 48 (0.97 1.25 1.32) 49 — S— 56 ( .92 1.22 1.36) 49 — S— 58 ( .06 0.98 1.60)- S-47 (0.90 1.22 1.35) 49 - S-48 (0.97 1.25 1.32) 49 - S- 56 (.92 1.22 1.36) 49 - S-58 (.06 0.98 1.60)
— S— 59 ( .10 0.95 1.62) 49 — S— 60 (1.20 0.83 1.74) 49 — S— 65 ( .91 1.53 1.05) 49 — S— 68 ( .62 1.49 1.08)- S- 59 (.10 0.95 1.62) 49 - S- 60 (1.20 0.83 1.74) 49 - S- 65 (.91 1.53 1.05) 49 - S- 68 (.62 1.49 1.08)
— S— 74 ( .07 1.06 1.51) 49 — S— 83 (1.95 1.16 1.41) 49 — S— 88 ( .12 0.83 1.74) 49 — S— 96 (0.99 1.52 1.06)- S- 74 (.07 1.06 1.51) 49 - S- 83 (1.95 1.16 1.41) 49 - S- 88 (.12 0.83 1.74) 49 - S- 96 (0.99 1.52 1.06)
— S— 98 ( .12 0.89 1.68) 49 — S— 102 (1.67 1.05 1.52) 49 — S— 105 (2.21 1.14 1.43) 49 — S— 1 11 (2.66 1.16 1.41)- S - 98 (.12 0.89 1.68) 49 - S - 102 (1.67 1.05 1.52) 49 - S - 105 (2.21 1.14 1.43) 49 - S - 1 11 (2.66 1.16 1.41)
— S— 1 12 (1.86 1.54 1.03) 49 — S— 1 14 (1.50 0.81 1.76) 49 — S— 1 18 (1.95 1.44 1.14) 49 — S— 1 19 (1.92 1.65 0.92)- S - 1 12 (1.86 1.54 1.03) 49 - S - 1 14 (1.50 0.81 1.76) 49 - S - 1 18 (1.95 1.44 1.14) 49 - S - 1 19 (1.92 1.65 0.92)
— S— 124 (0.81 1.04 1.53) 49 — S— 131 (1.97 1.1 1 1.46) 49 — S— 132 (1.88 1.36 1.21) 49 — S— 138 (1.20 1.09 1.48)- S - 124 (0.81 1.04 1.53) 49 - S - 131 (1.97 1.1 1 1.46) 49 - S - 132 (1.88 1.36 1.21) 49 - S - 138 (1.20 1.09 1.48)
— S— 147 (1.41 1.65 0.92) 49 — S— 148 (1.66 0.94 1.63) 49 — S— 154 (2.96 1.27 1.30) 49 — S— 166 (2.68 1.09 1.48)- S - 147 (1.41 1.65 0.92) 49 - S - 148 (1.66 0.94 1.63) 49 - S - 154 (2.96 1.27 1.30) 49 - S - 166 (2.68 1.09 1.48)
— S— 171 (2.45 1.09 1.48) 49 — S— 184 (3.24 1.63 0.94) 49 — S— 187 (2.39 1.00 1.57) 49 — S— 188 (2.82 1.04 1.53)- S-171 (2.45 1.09 1.48) 49 - S-184 (3.24 1.63 0.94) 49 - S-187 (2.39 1.00 1.57) 49 - S-188 (2.82 1.04 1.53)
— S— 193 (1.77 1.31 1.26) 49 — S— 195 (2.67 1.48 1.10) 49 — S— 198 (2.38 1.54 1.04) 49 — S— 205 (1.90 1.60 0.98)- S-193 (1.77 1.31 1.26) 49 - S-195 (2.67 1.48 1.10) 49 - S-198 (2.38 1.54 1.04) 49 - S-205 (1.90 1.60 0.98)
— S— 208 (1.87 1.07 1.50) 49 — S— 209 (1.61 1.15 1.43) 49 — S— 211 (0.96 1.31 1.26) 49 — S— 213 (2.35 1.49 1.08)- S-208 (1.87 1.07 1.50) 49 - S-209 (1.61 1.15 1.43) 49 - S-211 (0.96 1.31 1.26) 49 - S-213 (2.35 1.49 1.08)
— S— 217 (1.77 1.52 1.05) 49 — S— 219 (1.54 1.26 1.31) 49 — S— 222 (1.66 1.1 1 1.47) 49 — S— 225 (1.15 1.1 1 1.46)- S-217 (1.77 1.52 1.05) 49 - S-219 (1.54 1.26 1.31) 49 - S-222 (1.66 1.1 1 1.47) 49 - S-225 (1.15 1.1 1 1.46)
— S— 227 (0.95 1.63 0.94) 49 — S— 228 (1.28 1.26 1.31) 49 — S— 230 (1.59 0.93 1.64) 49 — S— 243 (2.85 0.90 1.68)- S - 227 (0.95 1.63 0.94) 49 - S - 228 (1.28 1.26 1.31) 49 - S - 230 (1.59 0.93 1.64) 49 - S - 243 (2.85 0.90 1.68)
— S— 245 (2.08 1.45 1.12) 49 — S— 254 (1.92 1.38 1.19) 49 — S— 267 (1.81 1.44 1.13) 49 — S— 274 (1.68 1.24 1.33)- S-245 (2.08 1.45 1.12) 49 - S-254 (1.92 1.38 1.19) 49 - S-267 (1.81 1.44 1.13) 49 - S-274 (1.68 1.24 1.33)
— S— 275 (1.49 1.66 0.91) 49 — S— 277 (1.90 1.51 1.06) 49 — S— 279 (1.96 1.57 1.00) 49 — S— 280 (1.63 1.25 1.32) 49— S— 282 (1.75 1.08 1.50) 49— S— 284 (1.53 1.08 1.49) 49— S— 285 (1.68 1.45 1.12) 49— S— 286 (1.93 1.36 1.22)- S-275 (1.49 1.66 0.91) 49 - S-277 (1.90 1.51 1.06) 49 - S-279 (1.96 1.57 1.00) 49 - S-280 (1.63 1.25 1.32) 49- S-282 (1.75 1.08 1.50) 49- S-284 (1.53 1.08 1.49) 49- S-285 (1.68 1.45 1.12) 49- S-286 (1.93 1.36 1.22)
49 — S— 287 (1.74 1.37 1.20) 49 — S— 288 (1.72 1.31 1.27) 49 — S— 289 (1.98 1.14 1.43) 49 — S— 293 (1.99 1.65 0.93)49 - S-287 (1.74 1.37 1.20) 49 - S-288 (1.72 1.31 1.27) 49 - S-289 (1.98 1.14 1.43) 49 - S-293 (1.99 1.65 0.93)
49 — S— 297 (1.79 1.05 1.52) 49 — S— 298 (2.04 1.52 1.05) 49 — S— 300 (2.05 0.92 1.65) 49 — S— 303 (1.81 0.89 1.68)49 - S - 297 (1.79 1.05 1.52) 49 - S - 298 (2.04 1.52 1.05) 49 - S - 300 (2.05 0.92 1.65) 49 - S - 303 (1.81 0.89 1.68)
49 — S— 304 (1.85 1.37 1.20) 49 — S— 305 (2.37 1.58 0.99) 49 — S— 310 (1.96 0.98 1.59) 49 — S— 311 (1.69 1.26 1.32)49 - S-304 (1.85 1.37 1.20) 49 - S-305 (2.37 1.58 0.99) 49 - S-310 (1.96 0.98 1.59) 49 - S-311 (1.69 1.26 1.32)
49 — S— 312 (1.79 1.13 1.44) 49 — S— 313 (1.56 1.30 1.28) 49 — S— 316 (1.85 1.58 0.99) 49 — S— 319 (1.05 1.44 1.13)49 - S-312 (1.79 1.13 1.44) 49 - S-313 (1.56 1.30 1.28) 49 - S-316 (1.85 1.58 0.99) 49 - S-319 (1.05 1.44 1.13)
49 — S— 325 (0.90 1.38 1.19) 49 — S— 330 (1.47 0.99 1.58) 49 — S— 331 (2.00 1.16 1.41) 49 — S— 332 (1.85 1.34 1.23)49 - S- 325 (0.90 1.38 1.19) 49 - S-330 (1.47 0.99 1.58) 49 - S-331 (2.00 1.16 1.41) 49 - S-332 (1.85 1.34 1.23)
49 — S— 336 (1.95 1.23 1.34) 49 — S— 356 (1.62 1.04 1.53) 49 — S— 358 (1.80 1.50 1.07) 49 — S— 360 (1.24 0.90 1.67)49 - S-336 (1.95 1.23 1.34) 49 - S-356 (1.62 1.04 1.53) 49 - S-358 (1.80 1.50 1.07) 49 - S-360 (1.24 0.90 1.67)
49 — S— 370 (1.76 1.57 1.00) 49 — S— 372 (1.99 1.27 1.30) 49 — S— 373 (1.38 1.28 1.30) 49 — S— 378 (1.12 1.1 1 1.46)49 - S-370 (1.76 1.57 1.00) 49 - S-372 (1.99 1.27 1.30) 49 - S-373 (1.38 1.28 1.30) 49 - S-378 (1.12 1.1 1 1.46)
49 — S— 379 (1.68 1.27 1.31) 49 — S— 381 (1.25 1.44 1.14) 49 — S— 382 (1.75 1.45 1.12) 49 — S— 391 (1.68 1.25 1.32)49 - S-379 (1.68 1.27 1.31) 49 - S-381 (1.25 1.44 1.14) 49 - S-382 (1.75 1.45 1.12) 49 - S-391 (1.68 1.25 1.32)
49 — S— 396 (2.04 1.42 1.15) 49 — S— 397 (1.84 1.27 1.30) 49 — S— 415 (1.73 1.15 1.42) 49 — S— 419 (1.13 1.25 1.33)49 - S-396 (2.04 1.42 1.15) 49 - S-397 (1.84 1.27 1.30) 49 - S-415 (1.73 1.15 1.42) 49 - S-419 (1.13 1.25 1.33)
49 — S— 422 (1.03 0.84 1.73) 49 — S— 434 (1.69 1.56 1.01) 49 — S— 437 (1.96 1.10 1.47) 49 — S— 450 (1.60 1.64 0.93)49 - S-422 (1.03 0.84 1.73) 49 - S-434 (1.69 1.56 1.01) 49 - S-437 (1.96 1.10 1.47) 49 - S-450 (1.60 1.64 0.93)
49 — S— 453 (1.87 0.95 1.62) 49 — S— 454 (1.69 1.1 1 1.46) 49 — S— 455 (1.68 1.38 1.19) 49 — S— 456 (1.37 1.09 1.48)49 - S-453 (1.87 0.95 1.62) 49 - S-454 (1.69 1.1 1 1.46) 49 - S-455 (1.68 1.38 1.19) 49 - S-456 (1.37 1.09 1.48)
49 — S— 466 (1.20 0.97 1.61) 49 — S— 467 (1.51 1.49 1.08) 49 — S— 471 (2.40 1.55 1.02) 49 — S— 475 (1.24 1.18 1.40)49 - S-466 (1.20 0.97 1.61) 49 - S-467 (1.51 1.49 1.08) 49 - S-471 (2.40 1.55 1.02) 49 - S-475 (1.24 1.18 1.40)
49 — S— 476 (0.92 1.21 1.37) 49 — S— 482 (1.33 1.67 0.91) 53 — S— 20 (0.99 1.15 2.01) 53 — S— 27 (0.90 1.31 1.84)49 - S-476 (0.92 1.21 1.37) 49 - S-482 (1.33 1.67 0.91) 53 - S-20 (0.99 1.15 2.01) 53 - S-27 (0.90 1.31 1.84)
53 — S— 28 (0.96 1.58 1.57) 53 — S— 36 ( 1.12 2.09 1.06) 53 — S— 43 (1.54 1.95 1.21) 53 — S— 46 (2.13 1.47 1.69)53 - S-28 (0.96 1.58 1.57) 53 - S-36 (1.12 2.09 1.06) 53 - S-43 (1.54 1.95 1.21) 53 - S-46 (2.13 1.47 1.69)
53 — S— 61 (0.87 1.29 1.87) 53 — S— 65 (0.88 1.08 2.07) 53 — S— 70 (1.60 2.16 1.00) 53 — S— 79 (0.87 1.46 1.70)53 - S- 61 (0.87 1.29 1.87) 53 - S- 65 (0.88 1.08 2.07) 53 - S-70 (1.60 2.16 1.00) 53 - S- 79 (0.87 1.46 1.70)
53 — S— 80 (0.82 1.42 1.74) 53 — S— 81 (0.90 1.54 1.61) 53 — S— 85 (1.38 1.27 1.89) 53 — S— 89 ( .36 1.90 1.26)53 - S- 80 (0.82 1.42 1.74) 53 - S- 81 (0.90 1.54 1.61) 53 - S- 85 (1.38 1.27 1.89) 53 - S- 89 (.36 1.90 1.26)
53 — S— 90 (1.27 1.75 1.41) 53 — S— 101 (1.02 1.60 1.56) 53 — S— 107 (1.64 1.43 1.72) 53 — S— 108 (1.20 1.82 1.33)53 - S-90 (1.27 1.75 1.41) 53 - S-101 (1.02 1.60 1.56) 53 - S-107 (1.64 1.43 1.72) 53 - S-108 (1.20 1.82 1.33)
53 — S— 109 (1.44 1.96 1.20) 53 — S— 1 10 (0.93 1.60 1.56) 53 — S— 1 12 (0.83 1.10 2.06) 53 — S— 1 13 (1.04 2.01 1.14)53 - S - 109 (1.44 1.96 1.20) 53 - S - 1 10 (0.93 1.60 1.56) 53 - S - 1 12 (0.83 1.10 2.06) 53 - S - 1 13 (1.04 2.01 1.14)
53 — S— 1 15 (1.31 1.57 1.58) 53 — S— 1 18 (0.92 0.99 2.16) 53 — S— 1 19 (0.89 1.21 1.95) 53 — S— 132 (0.86 0.92 2.24)53 - S - 1 15 (1.31 1.57 1.58) 53 - S - 1 18 (0.92 0.99 2.16) 53 - S - 1 19 (0.89 1.21 1.95) 53 - S - 132 (0.86 0.92 2.24)
53 — S— 133 (1.65 1.72 1.43) 53 — S— 144 (0.98 1.63 1.52) 53 — S— 150 (2.47 1.60 1.56) 53 — S— 151 (2.37 1.85 1.30)53 - S-133 (1.65 1.72 1.43) 53 - S-144 (0.98 1.63 1.52) 53 - S-150 (2.47 1.60 1.56) 53 - S-151 (2.37 1.85 1.30)
53 — S— 152 (3.02 2.15 1.00) 53 — S— 153 (2.40 1.70 1.46) 53 — S— 154 (1.93 0.83 2.33) 53 — S— 177 (1.48 1.38 1.78)53 - S-152 (3.02 2.15 1.00) 53 - S-153 (2.40 1.70 1.46) 53 - S-154 (1.93 0.83 2.33) 53 - S-177 (1.48 1.38 1.78)
53 — S— 183 (1.13 1.71 1.44) 53 — S— 184 (2.21 1.19 1.97) 53 — S— 192 (1.82 1.71 1.45) 53 — S— 195 (1.65 1.03 2.12)53 - S-183 (1.13 1.71 1.44) 53 - S-184 (2.21 1.19 1.97) 53 - S-192 (1.82 1.71 1.45) 53 - S-195 (1.65 1.03 2.12)
53 — S— 198 (1.36 1.09 2.06) 53 — S— 205 (0.88 1.15 2.00) 53 — S— 206 (0.87 2.07 1.09) 53 — S— 207 (1.39 2.01 1.14)53 - S-198 (1.36 1.09 2.06) 53 - S-205 (0.88 1.15 2.00) 53 - S-206 (0.87 2.07 1.09) 53 - S-207 (1.39 2.01 1.14)
53 — S— 213 (1.32 1.05 2.1 1) 53 — S— 231 (1.86 1.82 1.33) 53 — S— 233 (1.25 1.25 1.91) 53 — S— 234 (1.07 1.33 1.83)53 - S-213 (1.32 1.05 2.1 1) 53 - S-231 (1.86 1.82 1.33) 53 - S-233 (1.25 1.25 1.91) 53 - S-234 (1.07 1.33 1.83)
53 — S— 237 (1.08 1.62 1.53) 53 — S— 244 (1.14 1.24 1.92) 53 — S— 245 (1.05 1.01 2.14) 53 — S— 246 (1.39 1.58 1.58)53 - S-237 (1.08 1.62 1.53) 53 - S-244 (1.14 1.24 1.92) 53 - S-245 (1.05 1.01 2.14) 53 - S-246 (1.39 1.58 1.58)
53 — S— 248 (1.46 2.13 1.03) 53 — S— 249 (0.93 1.97 1.19) 53 — S— 251 (0.90 1.83 1.33) 53 — S— 254 (0.89 0.94 2.22)53 - S-248 (1.46 2.13 1.03) 53 - S-249 (0.93 1.97 1.19) 53 - S-251 (0.90 1.83 1.33) 53 - S-254 (0.89 0.94 2.22)
53 — S— 255 (1.78 1.80 1.36) 53 — S— 258 (0.85 2.24 0.91) 53 — S— 260 (0.91 2.25 0.91) 53 — S— 265 (1.35 1.72 1.44)53 - S- 255 (1.78 1.80 1.36) 53 - S - 258 (0.85 2.24 0.91) 53 - S - 260 (0.91 2.25 0.91) 53 - S - 265 (1.35 1.72 1.44)
53 — S— 266 (0.99 1.30 1.86) 53 — S— 268 (1.33 1.87 1.29) 53 — S— 269 (1.29 1.80 1.36) 53 — S— 271 (2.04 1.89 1.27)53 - S-266 (0.99 1.30 1.86) 53 - S-268 (1.33 1.87 1.29) 53 - S-269 (1.29 1.80 1.36) 53 - S-271 (2.04 1.89 1.27)
53 — S— 277 (0.88 1.07 2.09) 53 — S— 279 (0.93 1.13 2.03) 53 — S— 286 (0.91 0.91 2.24) 53 — S— 290 (0.99 1.33 1.83)53 - S-277 (0.88 1.07 2.09) 53 - S-279 (0.93 1.13 2.03) 53 - S-286 (0.91 0.91 2.24) 53 - S-290 (0.99 1.33 1.83)
53 — S— 291 (2.13 1.73 1.42) 53 — S— 292 (1.46 1.39 1.76) 53 — S— 293 (0.96 1.20 1.95) 53 — S— 294 (1.42 1.24 1.92)53 - S-291 (2.13 1.73 1.42) 53 - S-292 (1.46 1.39 1.76) 53 - S-293 (0.96 1.20 1.95) 53 - S-294 (1.42 1.24 1.92)
53 — S— 295 (1.17 1.48 1.68) 53 — S— 296 (1.45 1.47 1.68) 53 — S— 298 (1.02 1.08 2.08) 53 — S— 304 (0.82 0.93 2.23)53 - S - 295 (1.17 1.48 1.68) 53 - S - 296 (1.45 1.47 1.68) 53 - S - 298 (1.02 1.08 2.08) 53 - S - 304 (0.82 0.93 2.23)
53 — S— 305 (1.34 1.14 2.01) 53 — S— 306 (1.50 1.80 1.36) 53 — S— 307 (1.23 1.93 1.23) 53 — S— 316 (0.82 1.14 2.02)53 - S-305 (1.34 1.14 2.01) 53 - S-306 (1.50 1.80 1.36) 53 - S-307 (1.23 1.93 1.23) 53 - S-316 (0.82 1.14 2.02)
53 — S— 320 (1.72 2.21 0.94) 53 — S— 327 (1.1 1 1.54 1.61) 53 — S— 329 (1.44 2.00 1.15) 53 — S— 332 (0.83 0.90 2.26)53 - S-320 (1.72 2.21 0.94) 53 - S-327 (1.1 1 1.54 1.61) 53 - S-329 (1.44 2.00 1.15) 53 - S-332 (0.83 0.90 2.26)
53 — S— 342 (2.87 1.75 1.40) 53 — S— 343 (3.40 2.25 0.91) 53 — S— 367 (1.39 1.70 1.46) 53 — S— 368 (1.51 2.24 0.92)53 - S-342 (2.87 1.75 1.40) 53 - S-343 (3.40 2.25 0.91) 53 - S-367 (1.39 1.70 1.46) 53 - S-368 (1.51 2.24 0.92)
53 — S— 371 (2.56 1.84 1.31) 53 — S— 372 (0.97 0.83 2.33) 53 — S— 395 (1.59 1.54 1.61) 53 — S— 396 (1.01 0.98 2.18)53 - S-371 (2.56 1.84 1.31) 53 - S-372 (0.97 0.83 2.33) 53 - S-395 (1.59 1.54 1.61) 53 - S-396 (1.01 0.98 2.18)
53 — S— 397 (0.82 0.82 2.33) 53 — S— 440 (1.27 1.45 1.70) 53 — S— 441 (1.20 1.38 1.78) 53 — S— 447 (1.21 1.57 1.59)53 - S - 397 (0.82 0.82 2.33) 53 - S - 440 (1.27 1.45 1.70) 53 - S - 441 (1.20 1.38 1.78) 53 - S - 447 (1.21 1.57 1.59)
53 — S— 449 (0.96 1.53 1.62) 53 — S— 451 (1.30 2.14 1.01) 53 — S— 452 (1.35 1.80 1.36) 53 — S— 460 (1.08 1.88 1.28)53 - S-449 (0.96 1.53 1.62) 53 - S-451 (1.30 2.14 1.01) 53 - S-452 (1.35 1.80 1.36) 53 - S-460 (1.08 1.88 1.28)
53 — S— 463 (1.23 2.25 0.91) 53 — S— 471 (1.38 1.1 1 2.05) 53 — S— 473 (1.42 1.72 1.43) 53 — S— 474 (1.28 1.61 1.54)53 - S-463 (1.23 2.25 0.91) 53 - S-471 (1.38 1.1 1 2.05) 53 - S-473 (1.42 1.72 1.43) 53 - S-474 (1.28 1.61 1.54)
71 — S— 20 (0.96 0.86 2.04) 71 — S— 27 (0.87 1.03 1.87) 71 — S— 28 (0.94 1.30 1.60) 71 — S— 36 ( .10 1.81 1.09)71 - S - 20 (0.96 0.86 2.04) 71 - S - 27 (0.87 1.03 1.87) 71 - S - 28 (0.94 1.30 1.60) 71 - S - 36 (.10 1.81 1.09)
71 — S— 43 (1.51 1.67 1.23) 71 — S— 46 (2.11 1.19 1.71) 71 — S— 61 (0.85 1.01 1.90) 71 — S— 65 (0.86 0.80 2.10)71 - S- 43 (1.51 1.67 1.23) 71 - S- 46 (2.11 1.19 1.71) 71 - S- 61 (0.85 1.01 1.90) 71 - S- 65 (0.86 0.80 2.10)
71 — S— 70 (1.57 1.88 1.02) 71 — S— 79 (0.84 1.18 1.72) 71 — S— 81 (0.87 1.26 1.64) 71 — S— 85 ( .36 0.99 1.91)71 - S- 70 (1.57 1.88 1.02) 71 - S- 79 (0.84 1.18 1.72) 71 - S- 81 (0.87 1.26 1.64) 71 - S- 85 (.36 0.99 1.91)
71 — S— 89 (1.33 1.62 1.29) 71 — S— 90 (1.24 1.47 1.44) 71 — S— 101 (0.99 1.32 1.58) 71 — S— 107 (1.62 1.15 1.75)71 - S- 89 (1.33 1.62 1.29) 71 - S- 90 (1.24 1.47 1.44) 71 - S-101 (0.99 1.32 1.58) 71 - S-107 (1.62 1.15 1.75)
71 — S— 108 (1.18 1.54 1.36) 71 — S— 109 (1.41 1.68 1.22) 71 — S— 1 10 (0.91 1.32 1.59) 71 — S— 1 12 (0.80 0.81 2.09)71 - S- 108 (1.18 1.54 1.36) 71 - S - 109 (1.41 1.68 1.22) 71 - S - 1 10 (0.91 1.32 1.59) 71 - S - 1 12 (0.80 0.81 2.09)
71 — S— 1 13 (1.01 1.73 1.17) 71 — S— 1 15 (1.28 1.29 1.61) 71 — S— 1 19 (0.86 0.93 1.97) 71 — S— 133 (1.62 1.44 1.46)71 - S- 1 13 (1.01 1.73 1.17) 71 - S- 1 15 (1.28 1.29 1.61) 71 - S- 1 19 (0.86 0.93 1.97) 71 - S- 133 (1.62 1.44 1.46)
71 — S— 144 (0.95 1.35 1.55) 71 — S— 150 (2.44 1.31 1.59) 71 — S— 151 (2.35 1.57 1.33) 71 — S— 152 (2.99 1.87 1.03)71 - S- 144 (0.95 1.35 1.55) 71 - S - 150 (2.44 1.31 1.59) 71 - S - 151 (2.35 1.57 1.33) 71 - S - 152 (2.99 1.87 1.03)
71 — S— 153 (2.37 1.42 1.49) 71 — S— 177 (1.45 1.09 1.81) 71 — S— 183 (1.10 1.43 1.47) 71 — S— 184 (2.19 0.91 1.99)71 - S-153 (2.37 1.42 1.49) 71 - S-177 (1.45 1.09 1.81) 71 - S-183 (1.10 1.43 1.47) 71 - S-184 (2.19 0.91 1.99)
71 — S— 192 (1.79 1.43 1.47) 71 — S— 198 (1.33 0.81 2.09) 71 — S— 205 (0.85 0.87 2.03) 71 — S— 206 (0.84 1.78 1.12)71 - S - 192 (1.79 1.43 1.47) 71 - S - 198 (1.33 0.81 2.09) 71 - S - 205 (0.85 0.87 2.03) 71 - S - 206 (0.84 1.78 1.12)
71 — S— 207 (1.36 1.73 1.17) 71 — S— 215 (1.60 2.00 0.90) 71 — S— 231 (1.84 1.54 1.36) 71 — S— 233 (1.22 0.96 1.94)71 - S-207 (1.36 1.73 1.17) 71 - S-215 (1.60 2.00 0.90) 71 - S-231 (1.84 1.54 1.36) 71 - S-233 (1.22 0.96 1.94)
71 — S— 234 (1.04 1.05 1.86) 71 — S— 237 (1.05 1.34 1.56) 71 — S— 244 (1.1 1 0.96 1.94) 71 — S— 246 (1.36 1.30 1.60)71 - S-234 (1.04 1.05 1.86) 71 - S-237 (1.05 1.34 1.56) 71 - S-244 (1.1 1 0.96 1.94) 71 - S-246 (1.36 1.30 1.60)
71 — S— 248 (1.43 1.84 1.06) 71 — S— 249 (0.90 1.69 1.22) 71 — S— 251 (0.87 1.54 1.36) 71 — S— 255 (1.75 1.52 1.39)71 - S - 248 (1.43 1.84 1.06) 71 - S - 249 (0.90 1.69 1.22) 71 - S - 251 (0.87 1.54 1.36) 71 - S - 255 (1.75 1.52 1.39)
71 — S— 258 (0.82 1.96 0.94) 71 — S— 260 (0.88 1.97 0.94) 71 — S— 265 (1.32 1.44 1.46) 71 — S— 266 (0.96 1.02 1.89)71 - S - 258 (0.82 1.96 0.94) 71 - S - 260 (0.88 1.97 0.94) 71 - S - 265 (1.32 1.44 1.46) 71 - S - 266 (0.96 1.02 1.89)
71 — S— 268 (1.30 1.59 1.31) 71 — S— 269 (1.27 1.52 1.39) 71 — S— 271 (2.02 1.61 1.29) 71 — S— 279 (0.90 0.85 2.06)71 - S - 268 (1.30 1.59 1.31) 71 - S - 269 (1.27 1.52 1.39) 71 - S - 271 (2.02 1.61 1.29) 71 - S - 279 (0.90 0.85 2.06)
71 — S— 290 (0.96 1.05 1.85) 71 — S— 291 (2.10 1.45 1.45) 71 — S— 292 (1.43 1.1 1 1.79) 71 — S— 293 (0.94 0.92 1.98)71 - S - 290 (0.96 1.05 1.85) 71 - S - 291 (2.10 1.45 1.45) 71 - S - 292 (1.43 1.1 1 1.79) 71 - S - 293 (0.94 0.92 1.98)
71 — S— 294 (1.39 0.95 1.95) 71 — S— 295 (1.14 1.20 1.70) 71 — S— 296 (1.42 1.19 1.71) 71 — S— 305 (1.31 0.86 2.04)71 - S-294 (1.39 0.95 1.95) 71 - S-295 (1.14 1.20 1.70) 71 - S-296 (1.42 1.19 1.71) 71 - S-305 (1.31 0.86 2.04)
71 — S— 306 (1.47 1.51 1.39) 71 — S— 307 (1.20 1.64 1.26) 71 — S— 320 (1.69 1.93 0.97) 71 — S— 327 (1.09 1.26 1.64)71 - S-306 (1.47 1.51 1.39) 71 - S-307 (1.20 1.64 1.26) 71 - S-320 (1.69 1.93 0.97) 71 - S-327 (1.09 1.26 1.64)
71 — S— 329 (1.41 1.72 1.18) 71 — S— 342 (2.84 1.47 1.43) 71 — S— 343 (3.37 1.96 0.94) 71 — S— 367 (1.37 1.42 1.49) 71— S— 368 (1.48 1.96 0.94) 71— S— 371 (2.53 1.56 1.34) 71— S— 395 (1.56 1.26 1.64) 71— S— 440 (1.24 1.17 1.73)71 - S-329 (1.41 1.72 1.18) 71 - S-342 (2.84 1.47 1.43) 71 - S-343 (3.37 1.96 0.94) 71 - S-367 (1.37 1.42 1.49) 71- S- 368 (1.48 1.96 0.94) 71- S-371 (2.53 1.56 1.34) 71- S-395 (1.56 1.26 1.64) 71- S-440 (1.24 1.17 1.73)
71 — S— 441 (1.18 1.10 1.81) 71 — S— 447 (1.19 1.28 1.62) 71 — S— 449 (0.93 1.25 1.65) 71 — S— 451 (1.27 1.86 1.04)71 - S-441 (1.18 1.10 1.81) 71 - S-447 (1.19 1.28 1.62) 71 - S-449 (0.93 1.25 1.65) 71 - S-451 (1.27 1.86 1.04)
71 — S— 452 (1.32 1.52 1.38) 71 — S— 460 (1.05 1.60 1.31) 71 — S— 463 (1.20 1.97 0.94) 71 — S— 471 (1.35 0.83 2.07)71 - S-452 (1.32 1.52 1.38) 71 - S-460 (1.05 1.60 1.31) 71 - S-463 (1.20 1.97 0.94) 71 - S-471 (1.35 0.83 2.07)
71 — S— 473 (1.40 1.44 1.46) 71 — S— 474 (1.25 1.33 1.57) 72 — S— 0 (1 01 1.53 1.86) 72 — S— 9 (1.12 1.07 2.32)71 - S-473 (1.40 1.44 1.46) 71 - S-474 (1.25 1.33 1.57) 72 - S-0 (1 01 1.53 1.86) 72 - S-9 (1.12 1.07 2.32)
72 — S— 20 ( .23 1.62 1.77) 72 — S— 27 (1.14 1.78 1.60) 72 — S— 28 ( .20 2.05 1.34) 72 — S— 29 (0.96 1.78 1.61)72 - S- 20 (.23 1.62 1.77) 72 - S- 27 (1.14 1.78 1.60) 72 - S- 28 (.20 2.05 1.34) 72 - S- 29 (0.96 1.78 1.61)
72 — S— 43 ( .78 2.42 0.97) 72 — S— 44 (0.85 0.93 2.45) 72 — S— 46 (2.37 1.94 1.45) 72 — S— 56 (1.13 1.24 2.14)72 - S- 43 (.78 2.42 0.97) 72 - S- 44 (0.85 0.93 2.45) 72 - S- 46 (2.37 1.94 1.45) 72 - S- 56 (1.13 1.24 2.14)
72 — S— 61 ( .11 1.76 1.63) 72 — S— 62 (0.99 1.96 1.43) 72 — S— 65 ( .12 1.55 1.83) 72 — S— 68 (0.83 1.52 1.87)72 - S- 61 (.11 1.76 1.63) 72 - S- 62 (0.99 1.96 1.43) 72 - S- 65 (.12 1.55 1.83) 72 - S- 68 (0.83 1.52 1.87)
72 — S— 79 ( .11 1.93 1.46) 72 — S— 80 (1.06 1.89 1.50) 72 — S— 81 ( .14 2.01 1.38) 72 — S— 82 (0.87 2.20 1.19)72 - S- 79 (.11 1.93 1.46) 72 - S- 80 (1.06 1.89 1.50) 72 - S- 81 (.14 2.01 1.38) 72 - S- 82 (0.87 2.20 1.19)
72 — S— 83 ( .17 1.19 2.20) 72 — S— 85 (1.62 1.74 1.65) 72 — S— 86 (0.84 2.1 1 1.28) 72 — S— 89 (1.60 2.37 1.02)72 - S- 83 (.17 1.19 2.20) 72 - S- 85 (1.62 1.74 1.65) 72 - S- 86 (0.84 2.1 1 1.28) 72 - S- 89 (1.60 2.37 1.02)
72 — S— 90 ( .50 2.22 1.17) 72 — S— 101 (1.26 2.07 1.32) 72 — S— 102 (0.88 1.08 2.31) 72 — S— 105 (1.42 1.17 2.22)72 - S-90 (.50 2.22 1.17) 72 - S-101 (1.26 2.07 1.32) 72 - S-102 (0.88 1.08 2.31) 72 - S-105 (1.42 1.17 2.22)
72 — S— 107 (1.88 1.90 1.48) 72 — S— 108 (1.44 2.29 1.09) 72 — S— 109 (1.68 2.43 0.96) 72 — S— 1 10 (1.17 2.07 1.32)72 - S-107 (1.88 1.90 1.48) 72 - S- 108 (1.44 2.29 1.09) 72 - S-109 (1.68 2.43 0.96) 72 - S- 1 10 (1.17 2.07 1.32)
72 — S— 1 11 (1.88 1.19 2.20) 72 — S— 1 12 (1.07 1.57 1.82) 72 — S— 1 13 (1.28 2.48 0.90) 72 — S— 1 15 (1.55 2.04 1.34)72 - S- 1 11 (1.88 1.19 2.20) 72 - S- 1 12 (1.07 1.57 1.82) 72 - S- 1 13 (1.28 2.48 0.90) 72 - S- 1 15 (1.55 2.04 1.34)
72 — S— 1 18 (1.16 1.46 1.92) 72 — S— 1 19 (1.13 1.68 1.71) 72 — S— 131 (1.18 1.14 2.25) 72 — S— 132 (1.10 1.39 2.00)72 - S- 1 18 (1.16 1.46 1.92) 72 - S- 1 19 (1.13 1.68 1.71) 72 - S- 131 (1.18 1.14 2.25) 72 - S- 132 (1.10 1.39 2.00)
72 — S— 133 (1.88 2.19 1.19) 72 — S— 144 (1.22 2.10 1.28) 72 — S— 148 (0.88 0.97 2.41) 72 — S— 150 (2.70 2.07 1.32)72 - S-133 (1.88 2.19 1.19) 72 - S- 144 (1.22 2.10 1.28) 72 - S- 148 (0.88 0.97 2.41) 72 - S-150 (2.70 2.07 1.32)
72 — S— 151 (2.61 2.32 1.06) 72 — S— 153 (2.64 2.17 1.22) 72 — S— 154 (2.17 1.30 2.09) 72 — S— 166 (1.89 1.12 2.26)72 - S- 151 (2.61 2.32 1.06) 72 - S- 153 (2.64 2.17 1.22) 72 - S- 154 (2.17 1.30 2.09) 72 - S- 166 (1.89 1.12 2.26)
72 — S— 167 (1.75 0.81 2.58) 72 — S— 171 (1.66 1.12 2.27) 72 — S— 177 (1.72 1.85 1.54) 72 — S— 183 (1.37 2.18 1.20)72 - S-167 (1.75 0.81 2.58) 72 - S-171 (1.66 1.12 2.27) 72 - S-177 (1.72 1.85 1.54) 72 - S-183 (1.37 2.18 1.20)
72 — S— 184 (2.45 1.66 1.73) 72 — S— 187 (1.60 1.03 2.36) 72 — S— 188 (2.03 1.07 2.32) 72 — S— 192 (2.06 2.18 1.21)72 - S-184 (2.45 1.66 1.73) 72 - S-187 (1.60 1.03 2.36) 72 - S-188 (2.03 1.07 2.32) 72 - S-192 (2.06 2.18 1.21)
72 — S— 193 (0.98 1.34 2.05) 72 — S— 195 (1.88 1.50 1.88) 72 — S— 198 (1.60 1.56 1.82) 72 — S— 205 (1.12 1.62 1.76)72 - S-193 (0.98 1.34 2.05) 72 - S-195 (1.88 1.50 1.88) 72 - S-198 (1.60 1.56 1.82) 72 - S-205 (1.12 1.62 1.76)
72 — S— 207 (1.63 2.48 0.90) 72 — S— 208 (1.08 1.10 2.29) 72 — S— 209 (0.83 1.17 2.21) 72 — S— 213 (1.56 1.52 1.87)72 - S-207 (1.63 2.48 0.90) 72 - S-208 (1.08 1.10 2.29) 72 - S-209 (0.83 1.17 2.21) 72 - S-213 (1.56 1.52 1.87)
72 — S— 217 (0.99 1.55 1.83) 72 — S— 218 (0.96 1.73 1.66) 72 — S— 222 (0.87 1.13 2.25) 72 — S— 231 (2.10 2.29 1.09)72 - S-217 (0.99 1.55 1.83) 72 - S-218 (0.96 1.73 1.66) 72 - S-222 (0.87 1.13 2.25) 72 - S-231 (2.10 2.29 1.09)
72 — S— 233 (1.49 1.72 1.67) 72 — S— 234 (1.31 1.80 1.59) 72 — S— 237 (1.32 2.09 1.29) 72 — S— 243 (2.06 0.92 2.46)72 - S-233 (1.49 1.72 1.67) 72 - S-234 (1.31 1.80 1.59) 72 - S-237 (1.32 2.09 1.29) 72 - S-243 (2.06 0.92 2.46)
72 — S— 244 (1.37 1.71 1.68) 72 — S— 245 (1.29 1.48 1.90) 72 — S— 246 (1.63 2.05 1.34) 72 — S— 249 (1.17 2.44 0.95)72 - S- 244 (1.37 1.71 1.68) 72 - S- 245 (1.29 1.48 1.90) 72 - S-246 (1.63 2.05 1.34) 72 - S-249 (1.17 2.44 0.95)
72 — S— 251 (1.14 2.30 1.09) 72 — S— 254 (1.13 1.41 1.98) 72 — S— 255 (2.02 2.27 1.12) 72 — S— 265 (1.59 2.19 1.20)72 - S-251 (1.14 2.30 1.09) 72 - S-254 (1.13 1.41 1.98) 72 - S- 255 (2.02 2.27 1.12) 72 - S-265 (1.59 2.19 1.20)
72 — S— 266 (1.23 1.77 1.62) 72 — S— 267 (1.03 1.47 1.92) 72 — S— 268 (1.57 2.34 1.05) 72 — S— 269 (1.53 2.27 1.12)72 - S - 266 (1.23 1.77 1.62) 72 - S - 267 (1.03 1.47 1.92) 72 - S - 268 (1.57 2.34 1.05) 72 - S - 269 (1.53 2.27 1.12)
72 — S— 271 (2.28 2.36 1.03) 72 — S— 272 (1.41 0.81 2.57) 72 — S— 274 (0.90 1.27 2.12) 72 — S— 277 (1.1 1 1.54 1.85)72 - S-271 (2.28 2.36 1.03) 72 - S-272 (1.41 0.81 2.57) 72 - S-274 (0.90 1.27 2.12) 72 - S-277 (1.1 1 1.54 1.85)
72 — S— 279 (1.17 1.60 1.79) 72 — S— 280 (0.85 1.28 2.1 1) 72 — S— 282 (0.97 1.10 2.28) 72 — S— 285 (0.89 1.48 1.91)72 - S-279 (1.17 1.60 1.79) 72 - S- 280 (0.85 1.28 2.1 1) 72 - S-282 (0.97 1.10 2.28) 72 - S-285 (0.89 1.48 1.91)
72 — S— 286 (1.14 1.38 2.00) 72 — S— 287 (0.95 1.39 1.99) 72 — S— 288 (0.94 1.33 2.05) 72 — S— 289 (1.20 1.17 2.21)72 - S-286 (1.14 1.38 2.00) 72 - S-287 (0.95 1.39 1.99) 72 - S-288 (0.94 1.33 2.05) 72 - S-289 (1.20 1.17 2.21)
72 — S— 290 (1.23 1.80 1.59) 72 — S— 291 (2.37 2.20 1.18) 72 — S— 292 (1.70 1.86 1.52) 72 — S— 293 (1.20 1.67 1.71)72 - S-290 (1.23 1.80 1.59) 72 - S-291 (2.37 2.20 1.18) 72 - S-292 (1.70 1.86 1.52) 72 - S-293 (1.20 1.67 1.71)
72 — S— 294 (1.66 1.71 1.68) 72 — S— 295 (1.41 1.95 1.44) 72 — S— 296 (1.69 1.95 1.44) 72 — S— 297 (1.00 1.08 2.31)72 - S-294 (1.66 1.71 1.68) 72 - S-295 (1.41 1.95 1.44) 72 - S-296 (1.69 1.95 1.44) 72 - S-297 (1.00 1.08 2.31)
72 — S— 298 (1.26 1.55 1.84) 72 — S— 300 (1.26 0.95 2.44) 72 — S— 303 (1.02 0.92 2.46) 72 — S— 304 (1.06 1.40 1.99)72 - S - 298 (1.26 1.55 1.84) 72 - S - 300 (1.26 0.95 2.44) 72 - S - 303 (1.02 0.92 2.46) 72 - S - 304 (1.06 1.40 1.99)
72 — S— 305 (1.58 1.61 1.77) 72 — S— 306 (1.74 2.27 1.12) 72 — S— 307 (1.47 2.40 0.99) 72 — S— 310 (1.18 1.01 2.38)72 - S-305 (1.74 2.27 1.12) 72 - S-306 (1.74 2.27 1.12) 72 - S-307 (1.47 2.40 0.99) 72 - S-310 (1.18 1.01 2.38)
72 — S— 311 (0.90 1.28 2.10) 72 — S— 312 (1.00 1.16 2.23) 72 — S— 316 (1.06 1.61 1.78) 72 — S— 327 (1.35 2.01 1.37)72 - S-311 (0.90 1.28 2.10) 72 - S-312 (1.00 1.16 2.23) 72 - S-316 (1.06 1.61 1.78) 72 - S-327 (1.35 2.01 1.37)
72 — S— 329 (1.68 2.47 0.91) 72 — S— 331 (1.21 1.19 2.20) 72 — S— 332 (1.07 1.37 2.02) 72 — S— 336 (1.17 1.26 2.13)72 - S-329 (1.68 2.47 0.91) 72 - S-331 (1.21 1.19 2.20) 72 - S-332 (1.07 1.37 2.02) 72 - S-336 (1.17 1.26 2.13)
72 — S— 342 (3.1 1 2.22 1.16) 72 — S— 356 (0.83 1.07 2.31) 72 — S— 357 (1.53 0.82 2.57) 72 — S— 358 (1.01 1.53 1.86)72 - S-342 (3.1 1 2.22 1.16) 72 - S-356 (0.83 1.07 2.31) 72 - S-357 (1.53 0.82 2.57) 72 - S-358 (1.01 1.53 1.86)
72 — S— 367 (1.63 2.17 1.22) 72 — S— 370 (0.98 1.60 1.79) 72 — S— 371 (2.80 2.31 1.07) 72 — S— 372 (1.21 1.30 2.09)72 - S-367 (1.63 2.17 1.22) 72 - S-370 (0.98 1.60 1.79) 72 - S-371 (2.80 2.31 1.07) 72 - S-372 (1.21 1.30 2.09)
72 — S— 374 (0.82 1.79 1.60) 72 — S— 379 (0.89 1.29 2.09) 72 — S— 382 (0.96 1.48 1.91) 72 — S— 391 (0.90 1.28 2.1 1)72 - S-374 (0.82 1.79 1.60) 72 - S-379 (0.89 1.29 2.09) 72 - S-382 (0.96 1.48 1.91) 72 - S-391 (0.90 1.28 2.1 1)
72 — S— 395 (1.83 2.01 1.37) 72 — S— 396 (1.25 1.45 1.94) 72 — S— 397 (1.05 1.29 2.09) 72 — S— 415 (0.95 1.18 2.21)72 - S-395 (1.83 2.01 1.37) 72 - S-396 (1.25 1.45 1.94) 72 - S-397 (1.05 1.29 2.09) 72 - S-415 (0.95 1.18 2.21)
72 — S— 430 (0.84 2.1 1 1.27) 72 — S— 434 (0.90 1.59 1.80) 72 — S— 435 (0.99 1.75 1.63) 72 — S— 437 (1.17 1.13 2.26)72 - S- 430 (0.84 2.1 1 1.27) 72 - S- 434 (0.90 1.59 1.80) 72 - S- 435 (0.99 1.75 1.63) 72 - S-437 (1.17 1.13 2.26)
72 — S— 440 (1.51 1.92 1.47) 72 — S— 441 (1.44 1.85 1.54) 72 — S— 443 (0.92 2.46 0.92) 72 — S— 447 (1.45 2.04 1.35)72 - S-440 (1.51 1.92 1.47) 72 - S-441 (1.44 1.85 1.54) 72 - S-443 (0.92 2.46 0.92) 72 - S-447 (1.45 2.04 1.35)
72 — S— 449 (1.19 2.00 1.38) 72 — S— 450 (0.82 1.67 1.72) 72 — S— 452 (1.59 2.27 1.12) 72 — S— 453 (1.08 0.98 2.41)72 - S-449 (1.19 2.00 1.38) 72 - S-450 (0.82 1.67 1.72) 72 - S-452 (1.59 2.27 1.12) 72 - S-453 (1.08 0.98 2.41)
72 — S— 454 (0.91 1.14 2.25) 72 — S— 455 (0.89 1.41 1.98) 72 — S— 457 (1.04 1.92 1.47) 72 — S— 459 (0.83 2.15 1.24)72 - S- 454 (0.91 1.14 2.25) 72 - S- 455 (0.89 1.41 1.98) 72 - S-457 (1.04 1.92 1.47) 72 - S-459 (0.83 2.15 1.24)
72 — S— 460 (1.32 2.35 1.04) 72 — S— 461 (1.03 2.1 1 1.28) 72 — S— 468 (0.92 1.82 1.56) 72 — S— 469 (1.01 2.25 1.14)72 - S-466 (1.32 2.35 1.04) 72 - S-461 (1.03 2.1 1 1.28) 72 - S-468 (0.92 1.82 1.56) 72 - S-469 (1.01 2.25 1.14)
72 — S— 471 (1.62 1.58 1.81) 72 — S— 473 (1.66 2.19 1.19) 72 — S— 474 (1.52 2.08 1.30) 73 — S— 0 (0.91 1.56 1.96)72 - S - 471 (1.62 1.58 1.81) 72 - S - 473 (1.66 2.19 1.19) 72 - S - 474 (1.52 2.08 1.30) 73 - S - 0 (0.91 1.56 1.96)
73 — S— 9 (1 02 1.10 2.42) 73 — S— 20 (1.12 1.65 1.87) 73 — S— 27 ( .04 1.81 1.71) 73 — S— 28 (1.10 2.08 1.44)73 - S-9 (1 02 1.10 2.42) 73 - S-20 (1.12 1.65 1.87) 73 - S-27 (.04 1.81 1.71) 73 - S-28 (1.10 2.08 1.44)
73 — S— 29 (0.86 1.81 1.71) 73 — S— 36 (1.26 2.60 0.93) 73 — S— 43 ( .67 2.45 1.07) 73 — S— 46 (2.27 1.97 1.55)73 - S- 29 (0.86 1.81 1.71) 73 - S- 36 (1.26 2.60 0.93) 73 - S- 43 (.67 2.45 1.07) 73 - S- 46 (2.27 1.97 1.55)
73 — S— 56 ( .02 1.28 2.25) 73 — S— 61 (1.01 1.79 1.73) 73 — S— 62 (0.89 1.99 1.53) 73 — S— 65 (1.02 1.59 1.94)73 - S- 56 (.02 1.28 2.25) 73 - S- 61 (1.01 1.79 1.73) 73 - S- 62 (0.89 1.99 1.53) 73 - S- 65 (1.02 1.59 1.94)
73 — S— 79 ( .00 1.96 1.56) 73 — S— 80 (0.96 1.92 1.60) 73 — S— 81 ( .03 2.04 1.48) 73 — S— 83 (1.06 1.22 2.30)73 - S- 79 (.00 1.96 1.56) 73 - S-80 (0.96 1.92 1.60) 73 - S- 81 (.03 2.04 1.48) 73 - S-83 (1.06 1.22 2.30)
73 — S— 85 ( .52 1.77 1.75) 73 — S— 89 (1.49 2.40 1.12) 73 — S— 90 ( .40 2.25 1.27) 73 — S— 101 (1.16 2.10 1.42)73 - S- 85 (.52 1.77 1.75) 73 - S- 89 (1.49 2.40 1.12) 73 - S- 90 (.40 2.25 1.27) 73 - S-101 (1.16 2.10 1.42)
73 — S— 105 (1.32 1.20 2.32) 73 — S— 107 (1.78 1.93 1.59) 73 — S— 108 (1.34 2.33 1.20) 73 — S— 109 (1.58 2.46 1.06)73 - S-105 (1.32 1.20 2.32) 73 - S-107 (1.78 1.93 1.59) 73 - S-108 (1.34 2.33 1.20) 73 - S-109 (1.58 2.46 1.06)
73 — S— 1 10 (1.07 2.10 1.42) 73 — S— 1 11 (1.77 1.22 2.30) 73 — S— 1 12 (0.97 1.60 1.92) 73 — S— 1 13 (1.18 2.52 1.01)73 - S- 1 10 (1.07 2.10 1.42) 73 - S- 1 11 (1.77 1.22 2.30) 73 - S- 1 12 (0.97 1.60 1.92) 73 - S- 1 13 (1.18 2.52 1.01)
73 — S— 1 15 (1.45 2.07 1.45) 73 — S— 1 18 (1.06 1.50 2.03) 73 — S— 1 19 (1.03 1.71 1.81) 73 — S— 131 (1.08 1.17 2.35)73 - S-1 15 (1.45 2.07 1.45) 73 - S-1 18 (1.06 1.50 2.03) 73 - S-1 19 (1.03 1.71 1.81) 73 - S-131 (1.08 1.17 2.35)
73 — S— 132 (0.99 1.42 2.10) 73 — S— 133 (1.78 2.23 1.30) 73 — S— 144 (1.12 2.14 1.39) 73 — S— 150 (2.60 2.10 1.42)73 - S- 132 (0.99 1.42 2.10) 73 - S-133 (1.78 2.23 1.30) 73 - S- 144 (1.12 2.14 1.39) 73 - S-150 (2.60 2.10 1.42)
73 — S— 151 (2.51 2.36 1.17) 73 — S— 153 (2.53 2.20 1.32) 73 — S— 154 (2.07 1.33 2.19) 73 — S— 166 (1.79 1.15 2.37)73 - S-151 (2.51 2.36 1.17) 73 - S-153 (2.53 2.20 1.32) 73 - S- 154 (2.07 1.33 2.19) 73 - S-166 (1.79 1.15 2.37)
73 — S— 167 (1.65 0.84 2.68) 73 — S— 171 (1.56 1.15 2.37) 73 — S— 177 (1.61 1.88 1.64) 73 — S— 183 (1.26 2.21 1.31)73 - S-167 (1.65 0.84 2.68) 73 - S-171 (1.56 1.15 2.37) 73 - S-177 (1.61 1.88 1.64) 73 - S-183 (1.26 2.21 1.31)
73 — S— 184 (2.35 1.69 1.83) 73 — S— 187 (1.50 1.06 2.46) 73 — S— 188 (1.93 1.10 2.42) 73 — S— 192 (1.96 2.21 1.31)73 - S-184 (2.35 1.69 1.83) 73 - S-187 (1.50 1.06 2.46) 73 - S-188 (1.93 1.10 2.42) 73 - S-192 (1.96 2.21 1.31)
73 — S— 193 (0.87 1.37 2.15) 73 — S— 194 (1.73 0.82 2.71) 73 — S— 195 (1.78 1.54 1.99) 73 — S— 198 (1.49 1.60 1.93)73 - S-193 (0.87 1.37 2.15) 73 - S-194 (1.73 0.82 2.71) 73 - S-195 (1.78 1.54 1.99) 73 - S-198 (1.49 1.60 1.93)
73 — S— 205 (1.01 1.66 1.87) 73 — S— 206 (1.01 2.57 0.95) 73 — S— 207 (1.53 2.52 1.01) 73 — S— 208 (0.98 1.13 2.39) 73— S— 213 (1.46 1.55 1.97) 73— S— 217 (0.88 1.58 1.94) 73— S— 218 (0.85 1.76 1.76) 73— S— 231 (2.00 2.32 1.20)73 - S-205 (1.01 1.66 1.87) 73 - S-206 (1.01 2.57 0.95) 73 - S-207 (1.53 2.52 1.01) 73 - S-208 (0.98 1.13 2.39) 73- S-213 (1.46 1.55 1.97) 73- S-217 (0.88 1.58 1.94) 73- S-218 (0.85 1.76 1.76) 73- S-231 (2.00 2.32 1.20)
73 — S— 233 (1.39 1.75 1.77) 73 — S— 234 (1.21 1.83 1.69) 73 — S— 237 (1.22 2.13 1.40) 73 — S— 243 (1.96 0.96 2.57)73 - S-233 (1.39 1.75 1.77) 73 - S-234 (1.21 1.83 1.69) 73 - S-237 (1.22 2.13 1.40) 73 - S-243 (1.96 0.96 2.57)
73 — S— 244 (1.27 1.74 1.78) 73 — S— 245 (1.19 1.51 2.01) 73 — S— 246 (1.53 2.08 1.44) 73 — S— 249 (1.06 2.47 1.05)73 - S-244 (1.27 1.74 1.78) 73 - S-245 (1.19 1.51 2.01) 73 - S-246 (1.53 2.08 1.44) 73 - S-249 (1.06 2.47 1.05)
73 — S— 251 (1.03 2.33 1.19) 73 — S— 254 (1.03 1.44 2.08) 73 — S— 255 (1.92 2.30 1.22) 73 — S— 265 (1.49 2.22 1.30)73 - S-251 (1.03 2.33 1.19) 73 - S-254 (1.03 1.44 2.08) 73 - S- 255 (1.92 2.30 1.22) 73 - S-265 (1.49 2.22 1.30)
73 — S— 266 (1.12 1.80 1.72) 73 — S— 267 (0.92 1.50 2.02) 73 — S— 268 (1.47 2.37 1.15) 73 — S— 269 (1.43 2.30 1.22)73 - S-266 (1.12 1.80 1.72) 73 - S-267 (0.92 1.50 2.02) 73 - S-268 (1.47 2.37 1.15) 73 - S-269 (1.43 2.30 1.22)
73 — S— 271 (2.18 2.39 1.13) 73 — S— 272 (1.31 0.84 2.68) 73 — S— 277 (1.01 1.57 1.95) 73 — S— 279 (1.06 1.63 1.89)73 - S-271 (2.18 2.39 1.13) 73 - S-272 (1.31 0.84 2.68) 73 - S-277 (1.01 1.57 1.95) 73 - S-279 (1.06 1.63 1.89)
73 — S— 282 (0.86 1.14 2.39) 73 — S— 286 (1.04 1.42 2.1 1) 73 — S— 287 (0.85 1.43 2.10) 73 — S— 288 (0.83 1.37 2.16)73 - S-282 (0.86 1.14 2.39) 73 - S-286 (1.04 1.42 2.1 1) 73 - S-287 (0.85 1.43 2.10) 73 - S-288 (0.83 1.37 2.16)
73 — S— 289 (1.09 1.20 2.32) 73 — S— 290 (1.12 1.83 1.69) 73 — S— 291 (2.26 2.24 1.29) 73 — S— 292 (1.60 1.90 1.63)73 - S-289 (1.09 1.20 2.32) 73 - S-290 (1.12 1.83 1.69) 73 - S-291 (2.26 2.24 1.29) 73 - S-292 (1.60 1.90 1.63)
73 — S— 293 (1.10 1.71 1.82) 73 — S— 294 (1.55 1.74 1.78) 73 — S— 295 (1.31 1.98 1.54) 73 — S— 296 (1.59 1.98 1.54)73 - S-293 (1.10 1.71 1.82) 73 - S-294 (1.55 1.74 1.78) 73 - S-295 (1.31 1.98 1.54) 73 - S-296 (1.59 1.98 1.54)
73 — S— 297 (0.90 1.1 1 2.41) 73 — S— 298 (1.15 1.58 1.94) 73 — S— 300 (1.16 0.98 2.54) 73 — S— 303 (0.92 0.95 2.57)73 - S - 297 (0.90 1.1 1 2.41) 73 - S - 298 (1.15 1.58 1.94) 73 - S - 300 (1.16 0.98 2.54) 73 - S - 303 (0.92 0.95 2.57)
73 — S— 304 (0.96 1.43 2.09) 73 — S— 305 (1.48 1.64 1.88) 73 — S— 306 (1.64 2.30 1.22) 73 — S— 307 (1.37 2.43 1.09)73 - S-304 (0.96 1.43 2.09) 73 - S-305 (1.48 1.64 1.88) 73 - S-306 (1.64 2.30 1.22) 73 - S-307 (1.37 2.43 1.09)
73 — S— 310 (1.07 1.04 2.48) 73 — S— 312 (0.90 1.19 2.33) 73 — S— 316 (0.96 1.64 1.88) 73 — S— 327 (1.25 2.05 1.48)73 - S-310 (1.07 1.04 2.48) 73 - S-312 (0.90 1.19 2.33) 73 - S-316 (0.96 1.64 1.88) 73 - S-327 (1.25 2.05 1.48)
73 — S— 329 (1.58 2.51 1.02) 73 — S— 331 (1.1 1 1.22 2.30) 73 — S— 332 (0.96 1.40 2.12) 73 — S— 336 (1.06 1.29 2.23)73 - S- 329 (1.58 2.51 1.02) 73 - S-331 (1.1 1 1.22 2.30) 73 - S-332 (0.96 1.40 2.12) 73 - S-336 (1.06 1.29 2.23)
73 — S— 342 (3.00 2.26 1.27) 73 — S— 357 (1.42 0.85 2.67) 73 — S— 358 (0.91 1.56 1.96) 73 — S— 367 (1.53 2.20 1.32)73 - S-342 (3.00 2.26 1.27) 73 - S-357 (1.42 0.85 2.67) 73 - S-358 (0.91 1.56 1.96) 73 - S-367 (1.53 2.20 1.32)
73 — S— 370 (0.87 1.63 1.89) 73 — S— 371 (2.69 2.34 1.18) 73 — S— 372 (1.10 1.33 2.19) 73 — S— 382 (0.86 1.51 2.01)73 - S-370 (0.87 1.63 1.89) 73 - S-371 (2.69 2.34 1.18) 73 - S-372 (1.10 1.33 2.19) 73 - S-382 (0.86 1.51 2.01)
73 — S— 395 (1.72 2.04 1.48) 73 — S— 396 (1.15 1.48 2.04) 73 — S— 397 (0.95 1.33 2.20) 73 — S— 415 (0.84 1.21 2.31)73 - S-395 (1.72 2.04 1.48) 73 - S-396 (1.15 1.48 2.04) 73 - S-397 (0.95 1.33 2.20) 73 - S-415 (0.84 1.21 2.31)
73 — S— 420 (0.90 2.52 1.00) 73 — S— 432 (0.97 0.82 2.70) 73 — S— 435 (0.88 1.79 1.74) 73 — S— 437 (1.06 1.16 2.36)73 - S-420 (0.90 2.52 1.00) 73 - S-432 (0.97 0.82 2.70) 73 - S-435 (0.88 1.79 1.74) 73 - S-437 (1.06 1.16 2.36)
73 — S— 440 (1.41 1.95 1.57) 73 — S— 441 (1.34 1.88 1.64) 73 — S— 443 (0.81 2.50 1.03) 73 — S— 447 (1.35 2.07 1.45)73 - S-440 (1.41 1.95 1.57) 73 - S-441 (1.34 1.88 1.64) 73 - S-443 (0.81 2.50 1.03) 73 - S-447 (1.35 2.07 1.45)
73 — S— 449 (1.09 2.04 1.49) 73 — S— 452 (1.49 2.30 1.22) 73 — S— 453 (0.98 1.01 2.51) 73 — S— 454 (0.80 1.17 2.35)73 - S-449 (1.09 2.04 1.49) 73 - S-452 (1.49 2.30 1.22) 73 - S-453 (0.98 1.01 2.51) 73 - S-454 (0.80 1.17 2.35)
73 — S— 457 (0.94 1.95 1.57) 73 — S— 460 (1.21 2.38 1.14) 73 — S— 461 (0.93 2.14 1.38) 73 — S— 468 (0.82 1.85 1.67)73 - S-457 (0.94 1.95 1.57) 73 - S-460 (1.21 2.38 1.14) 73 - S-461 (0.93 2.14 1.38) 73 - S-468 (0.82 1.85 1.67)
73 — S— 469 (0.91 2.28 1.24) 73 — S— 471 (1.51 1.61 1.91) 73 — S— 473 (1.56 2.23 1.30) 73 — S— 474 (1.41 2.1 1 1.41)73 - S-469 (0.91 2.28 1.24) 73 - S-471 (1.51 1.61 1.91) 73 - S-473 (1.56 2.23 1.30) 73 - S-474 (1.41 2.1 1 1.41)
75 — S— 27 ( .48 0.90 1.26) 75 — S— 28 ( .55 1.17 0.99) 75 — S— 29 ( .31 0.89 1.27) 75 — S— 40 ( .13 0.89 1.27)75 - S- 27 (.48 0.90 1.26) 75 - S- 28 (.55 1.17 0.99) 75 - S- 29 (.31 0.89 1.27) 75 - S- 40 (.13 0.89 1.27)
75 — S— 46 (2.72 1.06 1.10) 75 — S— 61 ( .46 0.88 1.28) 75 — S— 62 ( .34 1.08 1.08) 75 — S— 79 ( .45 1.05 1.11)75 - S- 46 (2.72 1.06 1.10) 75 - S- 61 (.46 0.88 1.28) 75 - S- 62 (.34 1.08 1.08) 75 - S- 79 (.45 1.05 1.11)
75 — S— 80 ( .40 1.01 1.15) 75 — S— 81 ( .48 1.13 1.03) 75 — S— 85 ( .97 0.86 1.30) 75 — S— 86 ( .18 1.23 0.93)75 - S- 80 (.40 1.01 1.15) 75 - S- 81 (.48 1.13 1.03) 75 - S- 85 (.97 0.86 1.30) 75 - S- 86 (.18 1.23 0.93)
75 — S— 101 (1.60 1.19 0.97) 75 — S— 107 (2.23 1.02 1.14) 75 — S— 1 10 (1.52 1.19 0.97) 75 — S— 1 15 (1.89 1.16 1.00)75 - S-101 (1.60 1.19 0.97) 75 - S-107 (2.23 1.02 1.14) 75 - S- 1 10 (1.52 1.19 0.97) 75 - S- 1 15 (1.89 1.16 1.00)
75 — S— 123 (1.12 0.93 1.23) 75 — S— 144 (1.56 1.22 0.94) 75 — S— 150 (3.05 1.19 0.98) 75 — S— 177 (2.06 0.97 1.20)75 - S-123 (1.12 0.93 1.23) 75 - S- 144 (1.56 1.22 0.94) 75 - S-150 (3.05 1.19 0.98) 75 - S-177 (2.06 0.97 1.20)
75 — S— 218 (1.30 0.85 1.31) 75 — S— 233 (1.83 0.84 1.33) 75 — S— 234 (1.65 0.92 1.24) 75 — S— 237 (1.66 1.21 0.95)75 - S - 218 (1.30 0.85 1.31) 75 - S - 233 (1.83 0.84 1.33) 75 - S - 234 (1.65 0.92 1.24) 75 - S - 237 (1.66 1.21 0.95)
75 — S— 238 (0.96 1.07 1.09) 75 — S— 244 (1.72 0.83 1.33) 75 — S— 246 (1.97 1.17 0.99) 75 — S— 266 (1.57 0.89 1.28)75 - S - 238 (0.96 1.07 1.09) 75 - S - 244 (1.72 0.83 1.33) 75 - S - 246 (1.97 1.17 0.99) 75 - S - 266 (1.57 0.89 1.28)
75 — S— 275 (1.05 0.81 1.35) 75 — S— 290 (1.57 0.92 1.24) 75 — S— 292 (2.04 0.98 1.18) 75 — S— 294 (2.00 0.82 1.34)75 - S - 275 (1.05 0.81 1.35) 75 - S - 290 (1.57 0.92 1.24) 75 - S - 292 (2.04 0.98 1.18) 75 - S - 294 (2.00 0.82 1.34)
75 — S— 295 (1.76 1.07 1.09) 75 — S— 296 (2.03 1.06 1.10) 75 — S— 299 (0.86 1.01 1.15) 75 — S— 327 (1.70 1.13 1.03)75 - S-295 (1.76 1.07 1.09) 75 - S-296 (2.03 1.06 1.10) 75 - S-299 (0.86 1.01 1.15) 75 - S-327 (1.70 1.13 1.03)
75 — S— 341 (1.01 1.00 1.16) 75 — S— 374 (1.16 0.91 1.25) 75 — S— 395 (2.17 1.13 1.03) 75 — S— 430 (1.18 1.23 0.93)75 - S-341 (1.01 1.00 1.16) 75 - S-374 (1.16 0.91 1.25) 75 - S-395 (2.17 1.13 1.03) 75 - S-430 (1.18 1.23 0.93)
75 — S— 435 (1.33 0.87 1.29) 75 — S— 440 (1.86 1.04 1.12) 75 — S— 441 (1.79 0.97 1.19) 75 — S— 447 (1.80 1.15 1.01)75 - S-435 (1.33 0.87 1.29) 75 - S-440 (1.86 1.04 1.12) 75 - S-441 (1.79 0.97 1.19) 75 - S-447 (1.80 1.15 1.01)
75 — S— 449 (1.54 1.12 1.04) 75 — S— 457 (1.38 1.03 1.13) 75 — S— 458 (0.93 0.83 1.33) 75 — S— 461 (1.38 1.23 0.93)75 - S - 449 (1.54 1.12 1.04) 75 - S - 457 (1.38 1.03 1.13) 75 - S - 458 (0.93 0.83 1.33) 75 - S - 461 (1.38 1.23 0.93)
75 — S— 462 (1.07 1.24 0.92) 75 — S— 468 (1.26 0.94 1.22) 75 — S— 474 (1.86 1.20 0.96) 75 — S— 482 (0.89 0.81 1.35)75 - S - 462 (1.07 1.24 0.92) 75 - S - 468 (1.26 0.94 1.22) 75 - S - 474 (1.86 1.20 0.96) 75 - S - 482 (0.89 0.81 1.35)
75 — S— 483 (0.94 0.89 1.28) 76 — S— 0 (1 68 1.10 1.18) 76 — S— 1 1 (0.90 0.88 1.40) 76 — S— 20 ( .90 1.19 1.09)75 - S - 483 (0.94 0.89 1.28) 76 - S - 0 (1 68 1.10 1.18) 76 - S - 1 1 (0.90 0.88 1.40) 76 - S - 20 (.90 1.19 1.09)
76 — S— 27 ( .81 1.35 0.93) 76 — S— 29 ( .64 1.35 0.94) 76 — S— 40 ( .46 1.35 0.94) 76 — S— 45 (0.93 0.99 1.29)76 - S- 27 (.81 1.35 0.93) 76 - S- 29 (.64 1.35 0.94) 76 - S- 40 (.46 1.35 0.94) 76 - S- 45 (0.93 0.99 1.29)
76 — S— 48 (0.86 0.85 1.43) 76 — S— 56 ( .80 0.82 1.47) 76 — S— 61 ( .79 1.33 0.95) 76 — S— 65 ( .80 1.12 1.16)76 - S- 48 (0.86 0.85 1.43) 76 - S- 56 (.80 0.82 1.47) 76 - S- 61 (.79 1.33 0.95) 76 - S- 65 (.80 1.12 1.16)
76 — S— 68 ( .51 1.09 1.19) 76 — S— 85 (2.30 1.31 0.97) 76 — S— 96 (0.88 1.12 1.17) 76 — S— 1 12 (1.74 1.14 1.15)76 - S- 68 (.51 1.09 1.19) 76 - S- 85 (2.30 1.31 0.97) 76 - S- 96 (0.88 1.12 1.17) 76 - S- 1 12 (1.74 1.14 1.15)
76 — S— 1 18 (1.83 1.04 1.25) 76 — S— 1 19 (1.81 1.25 1.03) 76 — S— 123 (1.45 1.38 0.90) 76 — S— 132 (1.77 0.96 1.32)76 - S - 1 18 (1.83 1.04 1.25) 76 - S - 1 19 (1.81 1.25 1.03) 76 - S - 123 (1.45 1.38 0.90) 76 - S - 132 (1.77 0.96 1.32)
76 — S— 147 (1.30 1.25 1.03) 76 — S— 154 (2.85 0.87 1.42) 76 — S— 184 (3.13 1.23 1.05) 76 — S— 193 (1.65 0.91 1.37)76 - S - 147 (1.30 1.25 1.03) 76 - S - 154 (2.85 0.87 1.42) 76 - S - 184 (3.13 1.23 1.05) 76 - S - 193 (1.65 0.91 1.37)
76 — S— 195 (2.56 1.07 1.21) 76 — S— 198 (2.27 1.13 1.15) 76 — S— 205 (1.79 1.19 1.09) 76 — S— 211 (0.85 0.91 1.37)76 - S - 195 (2.56 1.07 1.21) 76 - S - 198 (2.27 1.13 1.15) 76 - S - 205 (1.79 1.19 1.09) 76 - S - 211 (0.85 0.91 1.37)
76 — S— 213 (2.24 1.09 1.19) 76 — S— 217 (1.66 1.12 1.16) 76 — S— 218 (1.63 1.30 0.98) 76 — S— 219 (1.43 0.86 1.43)76 - S - 213 (2.24 1.09 1.19) 76 - S - 217 (1.66 1.12 1.16) 76 - S - 218 (1.63 1.30 0.98) 76 - S - 219 (1.43 0.86 1.43)
76 — S— 227 (0.83 1.23 1.05) 76 — S— 228 (1.17 0.86 1.43) 76 — S— 233 (2.17 1.29 0.99) 76 — S— 234 (1.99 1.37 0.91)76 - S - 227 (0.83 1.23 1.05) 76 - S - 228 (1.17 0.86 1.43) 76 - S - 233 (2.17 1.29 0.99) 76 - S - 234 (1.99 1.37 0.91)
76 — S— 244 (2.05 1.28 1.00) 76 — S— 245 (1.97 1.05 1.23) 76 — S— 254 (1.80 0.98 1.31) 76 — S— 266 (1.90 1.34 0.94)76 - S - 244 (2.05 1.28 1.00) 76 - S - 245 (1.97 1.05 1.23) 76 - S - 254 (1.80 0.98 1.31) 76 - S - 266 (1.90 1.34 0.94)
76 — S— 267 (1.70 1.04 1.24) 76 — S— 274 (1.57 0.84 1.44) 76 — S— 275 (1.38 1.26 1.02) 76 — S— 277 (1.79 1.1 1 1.18)76 - S-267 (1.70 1.04 1.24) 76 - S-274 (1.57 0.84 1.44) 76 - S-275 (1.38 1.26 1.02) 76 - S-277 (1.79 1.1 1 1.18)
76 — S— 279 (1.84 1.17 1.1 1) 76 — S— 280 (1.52 0.85 1.43) 76 — S— 285 (1.57 1.05 1.23) 76 — S— 286 (1.82 0.95 1.33)76 - S - 279 (1.84 1.17 1.1 1) 76 - S - 280 (1.52 0.85 1.43) 76 - S - 285 (1.57 1.05 1.23) 76 - S - 286 (1.82 0.95 1.33)
76 — S— 287 (1.63 0.97 1.32) 76 — S— 288 (1.61 0.91 1.38) 76 — S— 290 (1.90 1.37 0.91) 76 — S— 293 (1.88 1.24 1.04)76 - S - 287 (1.63 0.97 1.32) 76 - S - 288 (1.61 0.91 1.38) 76 - S - 290 (1.90 1.37 0.91) 76 - S - 293 (1.88 1.24 1.04)
76 — S— 294 (2.33 1.28 1.01) 76 — S— 298 (1.93 1.12 1.16) 76 — S— 304 (1.74 0.97 1.32) 76 — S— 305 (2.25 1.18 1.10)76 - S - 294 (2.33 1.28 1.01) 76 - S - 298 (1.93 1.12 1.16) 76 - S - 304 (1.74 0.97 1.32) 76 - S - 305 (2.25 1.18 1.10)
76 — S— 311 (1.58 0.85 1.43) 76 — S— 313 (1.45 0.89 1.39) 76 — S— 316 (1.74 1.18 1.10) 76 — S— 319 (0.94 1.04 1.24)76 - S - 311 (1.58 0.85 1.43) 76 - S - 313 (1.45 0.89 1.39) 76 - S - 316 (1.74 1.18 1.10) 76 - S - 319 (0.94 1.04 1.24)
76 — S— 332 (1.74 0.94 1.35) 76 — S— 336 (1.84 0.83 1.46) 76 — S— 358 (1.68 1.10 1.18) 76 — S— 370 (1.65 1.17 1.11)76 - S - 332 (1.74 0.94 1.35) 76 - S - 336 (1.84 0.83 1.46) 76 - S - 358 (1.68 1.10 1.18) 76 - S - 370 (1.65 1.17 1.11)
76 — S— 372 (1.88 0.87 1.41) 76 — S— 373 (1.27 0.87 1.41) 76 — S— 374 (1.49 1.36 0.92) 76 — S— 379 (1.57 0.87 1.42)76 - S-372 (1.88 0.87 1.41) 76 - S-373 (1.27 0.87 1.41) 76 - S-374 (1.49 1.36 0.92) 76 - S-379 (1.57 0.87 1.42)
76 — S— 381 (1.14 1.03 1.25) 76 — S— 382 (1.63 1.05 1.24) 76 — S— 391 (1.57 0.85 1.43) 76 — S— 396 (1.93 1.02 1.26)76 - S-381 (1.14 1.03 1.25) 76 - S-382 (1.63 1.05 1.24) 76 - S-391 (1.57 0.85 1.43) 76 - S-396 (1.93 1.02 1.26)
76 — S— 397 (1.73 0.87 1.42) 76 — S— 419 (1.01 0.85 1.44) 76 — S— 434 (1.58 1.16 1.13) 76 — S— 435 (1.66 1.33 0.96)76 - S - 397 (1.73 0.87 1.42) 76 - S - 419 (1.01 0.85 1.44) 76 - S - 434 (1.58 1.16 1.13) 76 - S - 435 (1.66 1.33 0.96)
76 — S— 450 (1.49 1.24 1.04) 76 — S— 455 (1.57 0.98 1.30) 76 — S— 458 (1.26 1.28 1.00) 76 — S— 467 (1.40 1.09 1.19)76 - S-450 (1.49 1.24 1.04) 76 - S-455 (1.57 0.98 1.30) 76 - S-458 (1.26 1.28 1.00) 76 - S-467 (1.40 1.09 1.19)
76 — S— 471 (2.29 1.15 1.13) 76 — S— 476 (0.81 0.80 1.48) 76 — S— 482 (1.22 1.26 1.02) 76 — S— 483 (1.27 1.34 0.94)76 - S - 471 (2.29 1.15 1.13) 76 - S - 476 (0.81 0.80 1.48) 76 - S - 482 (1.22 1.26 1.02) 76 - S - 483 (1.27 1.34 0.94)
77 — S— 0 (1.20 0.99 1.67) 77 — S— 20 ( .42 1.07 1.58) 77 — S— 27 ( .33 1.24 1.41) 77 — S— 28 ( .39 1.51 1.15)77 - S- 0 (1.20 0.99 1.67) 77 - S- 20 (.42 1.07 1.58) 77 - S- 27 (.33 1.24 1.41) 77 - S- 28 (.39 1.51 1.15)
77 — S— 29 (1.15 1.23 1.42) 77 — S— 40 (0.98 1.23 1.42) 77 — S— 46 (2.56 1.40 1.26) 77 — S— 61 ( .30 1.22 1.44) 77— S— 62 ( .18 1.42 1.24) 77— S— 65 (1.31 1.01 1.64) 77— S— 68 ( .02 0.97 1.68) 77— S— 79 ( .30 1.39 1.27)77 - S- 29 (1.15 1.23 1.42) 77 - S- 40 (0.98 1.23 1.42) 77 - S- 46 (2.56 1.40 1.26) 77 - S- 61 (.30 1.22 1.44) 77- S- 62 (.18 1.42 1.24) 77- S- 65 (1.31 1.01 1.64) 77- S- 68 (.02 0.97 1.68) 77- S- 79 (.30 1.39 1.27)
77 — S— 80 ( .25 1.35 1.31) 77 — S— 81 (1.33 1.47 1.19) 77 — S— 82 ( .06 1.66 1.00) 77 — S— 85 ( .81 1.20 1.46)77 - S- 80 (.25 1.35 1.31) 77 - S- 81 (1.33 1.47 1.19) 77 - S- 82 (.06 1.66 1.00) 77 - S- 85 (.81 1.20 1.46)
77 — S— 86 ( .03 1.57 1.09) 77 — S— 90 (1.69 1.67 0.98) 77 — S— 101 (1.45 1.53 1.13) 77 — S— 107 (2.07 1.36 1.29)77 - S- 86 (.03 1.57 1.09) 77 - S- 90 (1.69 1.67 0.98) 77 - S-101 (1.45 1.53 1.13) 77 - S-107 (2.07 1.36 1.29)
77 — S— 108 (1.63 1.75 0.90) 77 — S— 1 10 (1.36 1.53 1.13) 77 — S— 1 12 (1.26 1.02 1.63) 77 — S— 1 15 (1.74 1.50 1.15)77 - S- 108 (1.63 1.75 0.90) 77 - S - 1 10 (1.36 1.53 1.13) 77 - S - 1 12 (1.26 1.02 1.63) 77 - S - 1 15 (1.74 1.50 1.15)
77 — S— 1 18 (1.35 0.92 1.73) 77 — S— 1 19 (1.32 1.14 1.52) 77 — S— 123 (0.96 1.27 1.39) 77 — S— 132 (1.29 0.84 1.81)77 - S - 1 18 (1.35 0.92 1.73) 77 - S - 1 19 (1.32 1.14 1.52) 77 - S - 123 (0.96 1.27 1.39) 77 - S - 132 (1.29 0.84 1.81)
77 — S— 133 (2.07 1.65 1.00) 77 — S— 144 (1.41 1.56 1.09) 77 — S— 147 (0.81 1.14 1.52) 77 — S— 150 (2.89 1.52 1.13)77 - S- 133 (2.07 1.65 1.00) 77 - S-144 (1.41 1.56 1.09) 77 - S-147 (0.81 1.14 1.52) 77 - S-150 (2.89 1.52 1.13)
77 — S— 153 (2.83 1.63 1.03) 77 — S— 177 (1.91 1.30 1.35) 77 — S— 183 (1.56 1.64 1.01) 77 — S— 184 (2.64 1.12 1.54)77 - S-153 (2.83 1.63 1.03) 77 - S-177 (1.91 1.30 1.35) 77 - S-183 (1.56 1.64 1.01) 77 - S-184 (2.64 1.12 1.54)
77 — S— 192 (2.25 1.64 1.02) 77 — S— 195 (2.07 0.96 1.69) 77 — S— 198 (1.79 1.02 1.63) 77 — S— 205 (1.31 1.08 1.57)77 - S-192 (2.25 1.64 1.02) 77 - S-195 (2.07 0.96 1.69) 77 - S-198 (1.79 1.02 1.63) 77 - S-205 (1.31 1.08 1.57)
77 — S— 213 (1.75 0.98 1.68) 77 — S— 217 (1.18 1.01 1.64) 77 — S— 218 (1.15 1.19 1.47) 77 — S— 231 (2.29 1.75 0.90)77 - S-213 (1.75 0.98 1.68) 77 - S-217 (1.18 1.01 1.64) 77 - S-218 (1.15 1.19 1.47) 77 - S-231 (2.29 1.75 0.90)
77 — S— 233 (1.68 1.17 1.48) 77 — S— 234 (1.50 1.26 1.40) 77 — S— 237 (1.51 1.55 1.10) 77 — S— 238 (0.81 1.41 1.24)77 - S-233 (1.68 1.17 1.48) 77 - S-234 (1.50 1.26 1.40) 77 - S-237 (1.51 1.55 1.10) 77 - S-238 (0.81 1.41 1.24)
77 — S— 244 (1.56 1.17 1.49) 77 — S— 245 (1.48 0.94 1.71) 77 — S— 246 (1.82 1.51 1.15) 77 — S— 251 (1.33 1.75 0.90)77 - S - 244 (1.56 1.17 1.49) 77 - S - 245 (1.48 0.94 1.71) 77 - S - 246 (1.82 1.51 1.15) 77 - S - 251 (1.33 1.75 0.90)
77 — S— 254 (1.32 0.86 1.79) 77 — S— 255 (2.21 1.73 0.93) 77 — S— 265 (1.78 1.65 1.01) 77 — S— 266 (1.42 1.22 1.43)77 - S - 254 (1.32 0.86 1.79) 77 - S - 255 (2.21 1.73 0.93) 77 - S - 265 (1.78 1.65 1.01) 77 - S - 266 (1.42 1.22 1.43)
77 — S— 267 (1.22 0.92 1.73) 77 — S— 269 (1.72 1.73 0.93) 77 — S— 275 (0.89 1.15 1.51) 77 — S— 277 (1.30 0.99 1.66)77 - S-267 (1.22 0.92 1.73) 77 - S-269 (1.72 1.73 0.93) 77 - S-275 (0.89 1.15 1.51) 77 - S-277 (1.30 0.99 1.66)
77 — S— 279 (1.36 1.06 1.60) 77 — S— 285 (1.08 0.94 1.72) 77 — S— 286 (1.33 0.84 1.81) 77 — S— 287 (1.14 0.85 1.80)77 - S-279 (1.36 1.06 1.60) 77 - S-285 (1.08 0.94 1.72) 77 - S-286 (1.33 0.84 1.81) 77 - S-287 (1.14 0.85 1.80)
77 — S— 290 (1.42 1.26 1.40) 77 — S— 291 (2.56 1.66 0.99) 77 — S— 292 (1.89 1.32 1.33) 77 — S— 293 (1.39 1.13 1.52)77 - S - 290 (1.42 1.26 1.40) 77 - S - 291 (2.56 1.66 0.99) 77 - S - 292 (1.89 1.32 1.33) 77 - S - 293 (1.39 1.13 1.52)
77 — S— 294 (1.85 1.16 1.49) 77 — S— 295 (1.60 1.41 1.25) 77 — S— 296 (1.88 1.40 1.25) 77 — S— 298 (1.45 1.01 1.65)77 - S - 294 (1.85 1.16 1.49) 77 - S - 295 (1.60 1.41 1.25) 77 - S - 296 (1.88 1.40 1.25) 77 - S - 298 (1.45 1.01 1.65)
77 — S— 304 (1.25 0.85 1.80) 77 — S— 305 (1.77 1.07 1.58) 77 — S— 306 (1.93 1.72 0.93) 77 — S— 316 (1.25 1.07 1.59)77 - S - 304 (1.25 0.85 1.80) 77 - S - 305 (1.77 1.07 1.58) 77 - S - 306 (1.93 1.72 0.93) 77 - S - 316 (1.25 1.07 1.59)
77 — S— 327 (1.54 1.47 1.18) 77 — S— 332 (1.26 0.82 1.83) 77 — S— 341 (0.85 1.34 1.31) 77 — S— 342 (3.30 1.68 0.97)77 - S- 327 (1.54 1.47 1.18) 77 - S-332 (1.26 0.82 1.83) 77 - S-341 (0.85 1.34 1.31) 77 - S-342 (3.30 1.68 0.97)
77 — S— 358 (1.20 0.99 1.67) 77 — S— 367 (1.82 1.63 1.03) 77 — S— 370 (1.17 1.06 1.60) 77 — S— 374 (1.01 1.25 1.41)77 - S-358 (1.20 0.99 1.67) 77 - S-367 (1.82 1.63 1.03) 77 - S-370 (1.17 1.06 1.60) 77 - S-374 (1.01 1.25 1.41)
77 — S— 382 (1.15 0.93 1.72) 77 — S— 395 (2.02 1.47 1.18) 77 — S— 396 (1.44 0.91 1.75) 77 — S— 430 (1.03 1.57 1.08)77 - S-382 (1.15 0.93 1.72) 77 - S-395 (2.02 1.47 1.18) 77 - S-396 (1.44 0.91 1.75) 77 - S-430 (1.03 1.57 1.08)
77 — S— 434 (1.09 1.04 1.61) 77 — S— 435 (1.18 1.21 1.44) 77 — S— 440 (1.70 1.38 1.28) 77 — S— 441 (1.63 1.31 1.35)77 - S-434 (1.09 1.04 1.61) 77 - S-435 (1.18 1.21 1.44) 77 - S-440 (1.70 1.38 1.28) 77 - S-441 (1.63 1.31 1.35)
77 — S— 447 (1.64 1.49 1.16) 77 — S— 449 (1.38 1.46 1.19) 77 — S— 450 (1.01 1.13 1.53) 77 — S— 452 (1.78 1.73 0.93)77 - S- 447 (1.64 1.49 1.16) 77 - S-449 (1.38 1.46 1.19) 77 - S- 450 (1.01 1.13 1.53) 77 - S-452 (1.78 1.73 0.93)
77 — S— 455 (1.08 0.87 1.79) 77 — S— 457 (1.23 1.37 1.28) 77 — S— 459 (1.02 1.61 1.05) 77 — S— 461 (1.22 1.57 1.09)77 - S-455 (1.08 0.87 1.79) 77 - S-457 (1.23 1.37 1.28) 77 - S-459 (1.02 1.61 1.05) 77 - S-461 (1.22 1.57 1.09)
77 — S— 462 (0.91 1.58 1.07) 77 — S— 467 (0.91 0.98 1.68) 77 — S— 468 (1.1 1 1.28 1.37) 77 — S— 469 (1.20 1.71 0.95)77 - S-462 (0.91 1.58 1.07) 77 - S-467 (0.91 0.98 1.68) 77 - S-468 (1.1 1 1.28 1.37) 77 - S-469 (1.20 1.71 0.95)
77 — S— 471 (1.81 1.04 1.62) 77 — S— 473 (1.85 1.65 1.00) 77 — S— 474 (1.71 1.54 1.1 1) 78 — S— 0 (1 37 1.04 1.49)77 - S - 471 (1.81 1.04 1.62) 77 - S - 473 (1.85 1.65 1.00) 77 - S - 474 (1.71 1.54 1.1 1) 78 - S - 0 (1 37 1.04 1.49)
78 — S— 20 ( .59 1.13 1.40) 78 — S— 27 (1.51 1.29 1.24) 78 — S— 28 ( .57 1.56 0.97) 78 — S— 29 ( .33 1.29 1.25)78 - S - 20 (.59 1.13 1.40) 78 - S - 27 (1.51 1.29 1.24) 78 - S - 28 (.57 1.56 0.97) 78 - S - 29 (.33 1.29 1.25)
78 — S— 40 ( .15 1.28 1.25) 78 — S— 46 (2.74 1.45 1.08) 78 — S— 61 ( .48 1.27 1.26) 78 — S— 62 ( .36 1.47 1.06)78 - S- 40 (.15 1.28 1.25) 78 - S- 46 (2.74 1.45 1.08) 78 - S- 61 (.48 1.27 1.26) 78 - P-62 (.36 1.47 1.06)
78 — S— 65 ( .49 1.06 1.47) 78 — S— 68 (1.20 1.03 1.50) 78 — S— 79 ( .47 1.44 1.09) 78 — S— 80 ( .43 1.40 1.13)78 - S- 65 (.49 1.06 1.47) 78 - S- 68 (1.20 1.03 1.50) 78 - S- 79 (.47 1.44 1.09) 78 - S- 80 (.43 1.40 1.13)
78 — S— 81 ( .50 1.52 1.01) 78 — S— 85 (1.99 1.25 1.28) 78 — S— 86 ( .21 1.62 0.91) 78 — S— 101 (1.63 1.58 0.95)78 - S- 81 (.50 1.52 1.01) 78 - S- 85 (1.99 1.25 1.28) 78 - S- 86 (.21 1.62 0.91) 78 - S-101 (1.63 1.58 0.95)
78 — S— 107 (2.25 1.41 1.12) 78 — S— 1 10 (1.54 1.58 0.95) 78 — S— 1 12 (1.44 1.08 1.45) 78 — S— 1 15 (1.91 1.55 0.98)78 - S - 107 (2.25 1.41 1.12) 78 - S - 1 10 (1.54 1.58 0.95) 78 - S - 1 12 (1.44 1.08 1.45) 78 - S - 1 15 (1.91 1.55 0.98)
78 — S— 1 18 (1.53 0.97 1.56) 78 — S— 1 19 (1.50 1.19 1.34) 78 — S— 123 (1.14 1.32 1.21) 78 — S— 132 (1.46 0.90 1.63)78 - S - 1 18 (1.53 0.97 1.56) 78 - S - 1 19 (1.50 1.19 1.34) 78 - S - 123 (1.14 1.32 1.21) 78 - S - 132 (1.46 0.90 1.63)
78 — S— 144 (1.59 1.61 0.92) 78 — S— 147 (0.99 1.19 1.34) 78 — S— 150 (3.07 1.58 0.95) 78 — S— 154 (2.54 0.81 1.72)78 - S - 144 (1.59 1.61 0.92) 78 - S - 147 (0.99 1.19 1.34) 78 - S - 150 (3.07 1.58 0.95) 78 - S - 154 (2.54 0.81 1.72)
78 — S— 177 (2.08 1.36 1.17) 78 — S— 184 (2.82 1.17 1.36) 78 — S— 193 (1.34 0.85 1.68) 78 — S— 195 (2.25 1.01 1.52)78 - S - 177 (2.08 1.36 1.17) 78 - S - 184 (2.82 1.17 1.36) 78 - S - 193 (1.34 0.85 1.68) 78 - S - 195 (2.25 1.01 1.52)
78 — S— 198 (1.96 1.07 1.46) 78 — S— 205 (1.48 1.13 1.40) 78 — S— 213 (1.93 1.03 1.50) 78 — S— 217 (1.35 1.06 1.47)78 - S-198 (1.96 1.07 1.46) 78 - S-205 (1.48 1.13 1.40) 78 - S-213 (1.93 1.03 1.50) 78 - S-217 (1.35 1.06 1.47)
78 — S— 218 (1.32 1.24 1.29) 78 — S— 233 (1.86 1.23 1.30) 78 — S— 234 (1.68 1.31 1.22) 78 — S— 237 (1.69 1.60 0.93)78 - S - 218 (1.32 1.24 1.29) 78 - S - 233 (1.86 1.23 1.30) 78 - S - 234 (1.68 1.31 1.22) 78 - S - 237 (1.69 1.60 0.93)
78 — S— 238 (0.98 1.46 1.07) 78 — S— 244 (1.74 1.22 1.31) 78 — S— 245 (1.66 0.99 1.54) 78 — S— 246 (2.00 1.56 0.97)78 - S - 238 (0.98 1.46 1.07) 78 - S - 244 (1.74 1.22 1.31) 78 - S - 245 (1.66 0.99 1.54) 78 - S - 246 (2.00 1.56 0.97)
78 — S— 254 (1.50 0.92 1.61) 78 — S— 266 (1.59 1.28 1.25) 78 — S— 267 (1.39 0.98 1.55) 78 — S— 275 (1.07 1.20 1.33)78 - S - 254 (1.50 0.92 1.61) 78 - S - 266 (1.59 1.28 1.25) 78 - S - 267 (1.39 0.98 1.55) 78 - S-275 (1.07 1.20 1.33)
78 — S— 277 (1.48 1.05 1.48) 78 — S— 279 (1.53 1.1 1 1.42) 78 — S— 285 (1.26 0.99 1.54) 78 — S— 286 (1.51 0.89 1.64)78 - S-277 (1.48 1.05 1.48) 78 - S-279 (1.53 1.1 1 1.42) 78 - S-285 (1.26 0.99 1.54) 78 - S-286 (1.51 0.89 1.64)
78 — S— 287 (1.32 0.90 1.63) 78 — S— 288 (1.30 0.84 1.69) 78 — S— 290 (1.59 1.31 1.22) 78 — S— 292 (2.07 1.37 1.16)78 - S-287 (1.32 0.90 1.63) 78 - S-288 (1.30 0.84 1.69) 78 - S-290 (1.59 1.31 1.22) 78 - S-292 (2.07 1.37 1.16)
78 — S— 293 (1.57 1.18 1.35) 78 — S— 294 (2.02 1.22 1.31) 78 — S— 295 (1.78 1.46 1.07) 78 — S— 296 (2.05 1.46 1.08)78 - S-293 (1.57 1.18 1.35) 78 - S-294 (2.02 1.22 1.31) 78 - S-295 (1.78 1.46 1.07) 78 - S-296 (2.05 1.46 1.08)
78 — S— 298 (1.62 1.06 1.47) 78 — S— 299 (0.88 1.40 1.13) 78 — S— 304 (1.43 0.91 1.62) 78 — S— 305 (1.95 1.12 1.41)78 - S - 298 (1.62 1.06 1.47) 78 - S - 299 (0.88 1.40 1.13) 78 - S - 304 (1.43 0.91 1.62) 78 - S - 305 (1.95 1.12 1.41)
78 — S— 313 (1.14 0.83 1.70) 78 — S— 316 (1.43 1.12 1.41) 78 — S— 327 (1.72 1.52 1.01) 78 — S— 332 (1.43 0.88 1.65)78 - S-313 (1.14 0.83 1.70) 78 - S-316 (1.43 1.12 1.41) 78 - S-327 (1.72 1.52 1.01) 78 - S-332 (1.43 0.88 1.65)
78 — S— 341 (1.03 1.39 1.14) 78 — S— 358 (1.37 1.04 1.49) 78 — S— 370 (1.34 1.1 1 1.42) 78 — S— 372 (1.57 0.81 1.72)78 - S-341 (1.03 1.39 1.14) 78 - S-358 (1.37 1.04 1.49) 78 - S-370 (1.34 1.1 1 1.42) 78 - S-372 (1.57 0.81 1.72)
78 — S— 373 (0.96 0.81 1.72) 78 — S— 374 (1.18 1.30 1.23) 78 — S— 379 (1.26 0.80 1.73) 78 — S— 381 (0.83 0.97 1.56)78 - S-373 (0.96 0.81 1.72) 78 - S-374 (1.18 1.30 1.23) 78 - S-379 (1.26 0.80 1.73) 78 - S-381 (0.83 0.97 1.56)
78 — S— 382 (1.33 0.99 1.54) 78 — S— 395 (2.19 1.52 1.01) 78 — S— 396 (1.62 0.96 1.57) 78 — S— 397 (1.42 0.80 1.73)78 - S - 382 (1.33 0.99 1.54) 78 - S - 395 (2.19 1.52 1.01) 78 - S - 396 (1.62 0.96 1.57) 78 - S - 397 (1.42 0.80 1.73)
78 — S— 430 (1.20 1.62 0.91) 78 — S— 434 (1.27 1.10 1.43) 78 — S— 435 (1.35 1.26 1.27) 78 — S— 440 (1.88 1.43 1.10)78 - S - 430 (1.20 1.62 0.91) 78 - S - 434 (1.27 1.10 1.43) 78 - S - 435 (1.35 1.26 1.27) 78 - S - 440 (1.88 1.43 1.10)
78 — S— 441 (1.81 1.36 1.17) 78 — S— 447 (1.82 1.55 0.98) 78 — S— 449 (1.56 1.51 1.02) 78 — S— 450 (1.18 1.18 1.35)78 - S-441 (1.81 1.36 1.17) 78 - S-447 (1.82 1.55 0.98) 78 - S-449 (1.56 1.51 1.02) 78 - S-450 (1.18 1.18 1.35)
78 — S— 455 (1.26 0.92 1.61) 78 — S— 457 (1.41 1.43 1.10) 78 — S— 458 (0.95 1.22 1.31) 78 — S— 461 (1.40 1.62 0.91)78 - S-455 (1.26 0.92 1.61) 78 - S-457 (1.41 1.43 1.10) 78 - S-458 (0.95 1.22 1.31) 78 - S-461 (1.40 1.62 0.91)
78 — S— 467 (1.09 1.03 1.50) 78 — S— 468 (1.29 1.33 1.20) 78 — S— 471 (1.98 1.09 1.44) 78 — S— 474 (1.88 1.59 0.94)78 - S - 467 (1.09 1.03 1.50) 78 - S - 468 (1.29 1.33 1.20) 78 - S - 471 (1.98 1.09 1.44) 78 - S - 474 (1.88 1.59 0.94)
78 — S— 482 (0.91 1.20 1.33) 78 — S— 483 (0.96 1.28 1.25) 82 — S— 247 (0.89 1.06 1.00) 82 — S— 259 (1.01 0.89 1.17)78 - S-482 (0.91 1.20 1.33) 78 - S-483 (0.96 1.28 1.25) 82 - S-247 (0.89 1.06 1.00) 82 - S-259 (1.01 0.89 1.17)
82 — S— 324 (1.06 0.98 1.08) 94 — S— 0 (0.93 1.10 1.93) 94 — S— 20 ( .15 1.18 1.85) 94 — S— 27 ( .06 1.35 1.68)82 - S- 324 (1.06 0.98 1.08) 94 - S- 0 (0.93 1.10 1.93) 94 - S- 20 (.15 1.18 1.85) 94 - S- 27 (.06 1.35 1.68)
94 — S— 28 ( .13 1.62 1.41) 94 — S— 29 (0.89 1.34 1.69) 94 — S— 43 ( .70 1.98 1.04) 94 — S— 46 (2.30 1.50 1.52)94 - S - 28 (.13 1.62 1.41) 94 - S - 29 (0.89 1.34 1.69) 94 - S - 43 (.70 1.98 1.04) 94 - S - 46 (2.30 1.50 1.52)
94 — S— 56 ( .05 0.81 2.22) 94 — S— 61 (1.04 1.32 1.70) 94 — S— 62 (0.92 1.52 1.51) 94 — S— 65 ( .05 1.12 1.91)94 - S- 56 (.05 0.81 2.22) 94 - S- 61 (1.04 1.32 1.70) 94 - S- 62 (0.92 1.52 1.51) 94 - S- 65 (.05 1.12 1.91)
94 — S— 79 ( .03 1.50 1.53) 94 — S— 80 (0.98 1.45 1.58) 94 — S— 81 ( .06 1.58 1.45) 94 — S— 85 ( .55 1.31 1.72)94 - S- 79 (.03 1.50 1.53) 94 - S- 80 (0.98 1.45 1.58) 94 - S- 81 (.06 1.58 1.45) 94 - S- 85 (.55 1.31 1.72)
94 — S— 89 ( .52 1.93 1.10) 94 — S— 90 (1.43 1.78 1.25) 94 — S— 101 (1.18 1.63 1.39) 94 — S— 107 (1.81 1.47 1.56)94 - S - 89 (.52 1.93 1.10) 94 - S - 90 (1.43 1.78 1.25) 94 - S - 101 (1.18 1.63 1.39) 94 - S - 107 (1.81 1.47 1.56)
94 — S— 108 (1.37 1.86 1.17) 94 — S— 109 (1.60 1.99 1.03) 94 — S— 1 10 (1.10 1.63 1.39) 94 — S— 1 12 (0.99 1.13 1.90)94 - S- 108 (1.37 1.86 1.17) 94 - S-109 (1.60 1.99 1.03) 94 - S- 1 10 (1.10 1.63 1.39) 94 - S- 1 12 (0.99 1.13 1.90)
94 — S— 1 13 (1.20 2.05 0.98) 94 — S— 1 15 (1.47 1.61 1.42) 94 — S— 1 18 (1.08 1.03 2.00) 94 — S— 1 19 (1.05 1.24 1.78) 94— S— 132 (1.02 0.95 2.08) 94— S— 133 (1.81 1.76 1.27) 94— S— 144 (1.14 1.67 1.36) 94— S— 150 (2.63 1.63 1.40)94 - S - 1 13 (1.20 2.05 0.98) 94 - S - 1 15 (1.47 1.61 1.42) 94 - S - 1 18 (1.08 1.03 2.00) 94 - S - 1 19 (1.05 1.24 1.78) 94- S- 132 (1.02 0.95 2.08) 94- S- 133 (1.81 1.76 1.27) 94- S- 144 (1.14 1.67 1.36) 94- S-150 (2.63 1.63 1.40)
94 — S— 151 (2.54 1.89 1.14) 94 — S— 153 (2.56 1.73 1.30) 94 — S— 154 (2.09 0.86 2.17) 94 — S— 177 (1.64 1.41 1.62)94 - S - 151 (2.54 1.89 1.14) 94 - S - 153 (2.56 1.73 1.30) 94 - S - 154 (2.09 0.86 2.17) 94 - S - 177 (1.64 1.41 1.62)
94 — S— 183 (1.29 1.75 1.28) 94 — S— 184 (2.38 1.22 1.80) 94 — S— 192 (1.98 1.74 1.28) 94 — S— 193 (0.90 0.91 2.12)94 - S - 183 (1.29 1.75 1.28) 94 - S - 184 (2.38 1.22 1.80) 94 - S - 192 (1.98 1.74 1.28) 94 - S - 193 (0.90 0.91 2.12)
94 — S— 195 (1.81 1.07 1.96) 94 — S— 198 (1.52 1.13 1.90) 94 — S— 205 (1.04 1.19 1.84) 94 — S— 206 (1.03 2.10 0.93)94 - S-198 (1.81 1.07 1.96) 94 - S-198 (1.52 1.13 1.90) 94 - S-205 (1.04 1.19 1.84) 94 - S-206 (1.03 2.10 0.93)
94 — S— 207 (1.55 2.05 0.98) 94 — S— 213 (1.49 1.08 1.94) 94 — S— 217 (0.91 1.12 1.91) 94 — S— 218 (0.88 1.29 1.73)94 - S - 217 (1.49 1.08 1.94) 94 - S - 217 (0.91 1.12 1.91) 94 - S - 218 (0.88 1.29 1.73)
94 — S— 231 (2.03 1.86 1.17) 94 — S— 233 (1.41 1.28 1.75) 94 — S— 234 (1.23 1.36 1.66) 94 — S— 237 (1.24 1.66 1.37)94 - S-231 (1.43 1.86 1.17) 94 - S-233 (1.41 1.28 1.75) 94 - S-234 (1.23 1.36 1.66) 94 - S-237 (1.24 1.66 1.37)
94 — S— 244 (1.30 1.27 1.75) 94 — S— 245 (1.22 1.05 1.98) 94 — S— 246 (1.55 1.61 1.41) 94 — S— 249 (1.09 2.00 1.02)94 - S - 244 (1.30 1.27 1.75) 94 - S - 245 (1.22 1.05 1.98) 94 - S - 246 (1.55 1.61 1.41) 94 - S - 249 (1.09 2.00 1.02)
94 — S— 251 (1.06 1.86 1.17) 94 — S— 254 (1.05 0.97 2.06) 94 — S— 255 (1.94 1.83 1.20) 94 — S— 265 (1.51 1.75 1.27)94 - S - 251 (1.06 1.86 1.17) 94 - S - 254 (1.05 0.97 2.06) 94 - S - 255 (1.94 1.83 1.20) 94 - S - 265 (1.51 1.75 1.27)
94 — S— 266 (1.15 1.33 1.70) 94 — S— 267 (0.95 1.03 2.00) 94 — S— 268 (1.49 1.90 1.12) 94 — S— 269 (1.46 1.83 1.19)94 - S - 266 (1.15 1.33 1.70) 94 - S - 267 (0.95 1.03 2.00) 94 - S - 268 (1.49 1.90 1.12) 94 - S - 269 (1.46 1.83 1.19)
94 — S— 271 (2.21 1.92 1.10) 94 — S— 274 (0.82 0.83 2.19) 94 — S— 277 (1.04 1.10 1.93) 94 — S— 279 (1.09 1.16 1.86)94 - S-271 (2.21 1.92 1.10) 94 - S-274 (0.82 0.83 2.19) 94 - S-277 (1.04 1.10 1.93) 94 - S-279 (1.09 1.16 1.86)
94 — S— 285 (0.82 1.04 1.98) 94 — S— 286 (1.07 0.95 2.08) 94 — S— 287 (0.88 0.96 2.07) 94 — S— 288 (0.86 0.90 2.13)94 - S-285 (0.82 1.04 1.98) 94 - S-286 (1.07 0.95 2.08) 94 - S-287 (0.88 0.96 2.07) 94 - S-288 (0.86 0.90 2.13)
94 — S— 290 (1.15 1.36 1.66) 94 — S— 291 (2.29 1.77 1.26) 94 — S— 292 (1.62 1.43 1.60) 94 — S— 293 (1.13 1.24 1.79)94 - S - 290 (1.15 1.36 1.66) 94 - S - 291 (2.29 1.77 1.26) 94 - S - 292 (1.62 1.43 1.60) 94 - S - 293 (1.13 1.24 1.79)
94 — S— 294 (1.58 1.27 1.76) 94 — S— 295 (1.33 1.51 1.51) 94 — S— 296 (1.61 1.51 1.52) 94 — S— 298 (1.18 1.12 1.91)94 - S - 294 (1.58 1.27 1.76) 94 - S - 295 (1.33 1.51 1.51) 94 - S - 296 (1.61 1.51 1.52) 94 - S - 298 (1.18 1.12 1.91)
94 — S— 304 (0.99 0.96 2.07) 94 — S— 305 (1.50 1.18 1.85) 94 — S— 306 (1.66 1.83 1.20) 94 — S— 307 (1.39 1.96 1.07)94 - S - 304 (0.99 0.96 2.07) 94 - S - 305 (1.50 1.18 1.85) 94 - S - 306 (1.66 1.83 1.20) 94 - S - 307 (1.39 1.96 1.07)
94 — S— 311 (0.82 0.85 2.18) 94 — S— 316 (0.99 1.18 1.85) 94 — S— 327 (1.28 1.58 1.45) 94 — S— 329 (1.60 2.04 0.99)94 - S - 311 (0.82 0.85 2.18) 94 - S - 316 (0.99 1.18 1.85) 94 - S - 327 (1.28 1.58 1.45) 94 - S - 329 (1.60 2.04 0.99)
94 — S— 332 (0.99 0.93 2.10) 94 — S— 336 (1.09 0.82 2.21) 94 — S— 342 (3.03 1.79 1.24) 94 — S— 358 (0.93 1.10 1.93)94 - S-332 (0.99 0.93 2.10) 94 - S-336 (1.09 0.82 2.21) 94 - S-342 (3.03 1.79 1.24) 94 - S-358 (0.93 1.10 1.93)
94 — S— 367 (1.56 1.73 1.30) 94 — S— 370 (0.90 1.16 1.87) 94 — S— 371 (2.72 1.88 1.15) 94 — S— 372 (1.13 0.86 2.16)94 - S-370 (0.90 1.16 1.87) 94 - S- 371 (2.72 1.88 1.15) 94 - S-371 (2.72 1.88 1.15) 94 - S-372 (1.13 0.86 2.16)
94 — S— 379 (0.81 0.86 2.17) 94 — S— 382 (0.88 1.04 1.99) 94 — S— 391 (0.82 0.85 2.18) 94 — S— 395 (1.75 1.58 1.45)94 - S - 379 (0.81 0.86 2.17) 94 - S - 382 (0.88 1.04 1.99) 94 - S - 391 (0.82 0.85 2.18) 94 - S - 395 (1.75 1.58 1.45)
94 — S— 396 (1.18 1.02 2.01) 94 — S— 397 (0.98 0.86 2.17) 94 — S— 420 (0.93 2.06 0.97) 94 — S— 434 (0.83 1.15 1.88)94 - S - 396 (1.18 1.02 2.01) 94 - S - 397 (0.98 0.86 2.17) 94 - S - 420 (0.93 2.06 0.97) 94 - S - 434 (0.83 1.15 1.88)
94 — S— 435 (0.91 1.32 1.71) 94 — S— 440 (1.44 1.49 1.54) 94 — S— 441 (1.37 1.41 1.61) 94 — S— 443 (0.84 2.03 1.00)94 - S - 435 (0.91 1.32 1.71) 94 - S - 440 (1.44 1.49 1.54) 94 - S - 441 (1.37 1.41 1.61) 94 - S - 443 (0.84 2.03 1.00)
94 — S— 447 (1.38 1.60 1.43) 94 — S— 449 (1.12 1.57 1.46) 94 — S— 452 (1.52 1.84 1.19) 94 — S— 455 (0.82 0.98 2.05)94 - S - 447 (1.38 1.60 1.43) 94 - S - 449 (1.12 1.57 1.46) 94 - S - 452 (1.52 1.84 1.19) 94 - S - 455 (0.82 0.98 2.05)
94 — S— 457 (0.96 1.48 1.55) 94 — S— 460 (1.24 1.91 1.12) 94 — S— 461 (0.96 1.67 1.36) 94 — S— 468 (0.84 1.39 1.64)94 - S - 457 (0.96 1.48 1.55) 94 - S - 460 (1.24 1.91 1.12) 94 - S - 461 (0.96 1.67 1.36) 94 - S - 468 (0.84 1.39 1.64)
94 — S— 469 (0.93 1.81 1.21) 94 — S— 471 (1.54 1.15 1.88) 94 — S— 473 (1.59 1.76 1.27) 94 — S— 474 (1.44 1.65 1.38)94 - S - 469 (0.93 1.81 1.21) 94 - S - 471 (1.54 1.15 1.88) 94 - S - 473 (1.59 1.76 1.27) 94 - S - 474 (1.44 1.65 1.38)
95 — S— 0 (0.93 0.98 1.94) 95 — S— 20 ( .14 1.07 1.85) 95 — S— 27 ( .06 1.23 1.68) 95 — S— 28 ( .12 1.50 1.42)95 - S- 0 (0.93 0.98 1.94) 95 - S- 20 (.14 1.07 1.85) 95 - S- 27 (.06 1.23 1.68) 95 - S- 28 (.12 1.50 1.42)
95 — S— 29 (0.88 1.23 1.69) 95 — S— 36 ( .28 2.01 0.90) 95 — S— 43 ( .70 1.87 1.05) 95 — S— 46 (2.29 1.39 1.53)95 - S- 29 (0.88 1.23 1.69) 95 - S- 36 (.28 2.01 0.90) 95 - S- 43 (.70 1.87 1.05) 95 - S- 46 (2.29 1.39 1.53)
95 — S— 61 (1.03 1.21 1.71) 95 — S— 62 (0.91 1.41 1.51) 95 — S— 65 ( .04 1.00 1.91) 95 — S— 79 ( .03 1.38 1.54)95 - S- 61 (1.03 1.21 1.71) 95 - S- 62 (0.91 1.41 1.51) 95 - S- 65 (.04 1.00 1.91) 95 - S- 79 (.03 1.38 1.54)
95 — S— 80 (0.98 1.34 1.58) 95 — S— 81 ( .06 1.46 1.46) 95 — S— 85 ( .54 1.19 1.73) 95 — S— 89 ( .52 1.82 1.10)95 - S- 80 (0.98 1.34 1.58) 95 - S- 81 (.06 1.46 1.46) 95 - S- 85 (.54 1.19 1.73) 95 - S- 89 (.52 1.82 1.10)
95 — S— 90 (1.42 1.67 1.25) 95 — S— 101 (1.18 1.52 1.40) 95 — S— 107 (1.80 1.35 1.56) 95 — S— 108 (1.36 1.74 1.17)95 - S - 90 (1.42 1.67 1.25) 95 - S - 101 (1.18 1.52 1.40) 95 - S - 107 (1.80 1.35 1.56) 95 - S - 108 (1.36 1.74 1.17)
95 — S— 109 (1.60 1.88 1.04) 95 — S— 1 10 (1.09 1.52 1.40) 95 — S— 1 12 (0.99 1.02 1.90) 95 — S— 1 13 (1.20 1.93 0.98)95 - S - 109 (1.60 1.88 1.04) 95 - S - 1 10 (1.09 1.52 1.40) 95 - S - 1 12 (0.99 1.02 1.90) 95 - S - 1 13 (1.20 1.93 0.98)
95 — S— 1 15 (1.47 1.49 1.42) 95 — S— 1 18 (1.08 0.91 2.00) 95 — S— 1 19 (1.05 1.13 1.79) 95 — S— 132 (1.02 0.84 2.08)95 - S - 1 15 (1.47 1.49 1.42) 95 - S - 1 18 (1.08 0.91 2.00) 95 - S - 1 19 (1.05 1.13 1.79) 95 - S - 132 (1.02 0.84 2.08)
95 — S— 133 (1.80 1.64 1.27) 95 — S— 144 (1.14 1.55 1.36) 95 — S— 150 (2.62 1.52 1.40) 95 — S— 151 (2.53 1.78 1.14)95 - S - 133 (1.80 1.64 1.27) 95 - S - 144 (1.14 1.55 1.36) 95 - S - 150 (2.62 1.52 1.40) 95 - S - 151 (2.53 1.78 1.14)
95 — S— 153 (2.56 1.62 1.30) 95 — S— 177 (1.64 1.30 1.62) 95 — S— 183 (1.29 1.63 1.28) 95 — S— 184 (2.37 1.1 1 1.81)95 - S-153 (2.56 1.62 1.30) 95 - S-177 (1.64 1.30 1.62) 95 - S-183 (1.29 1.63 1.28) 95 - S-184 (2.37 1.1 1 1.81)
95 — S— 192 (1.98 1.63 1.29) 95 — S— 195 (1.80 0.95 1.96) 95 — S— 198 (1.52 1.01 1.90) 95 — S— 205 (1.04 1.07 1.84)95 - S-192 (1.98 1.63 1.29) 95 - S-195 (1.80 0.95 1.96) 95 - S-198 (1.52 1.01 1.90) 95 - S-205 (1.04 1.07 1.84)
95 — S— 206 (1.03 1.99 0.93) 95 — S— 207 (1.55 1.93 0.98) 95 — S— 213 (1.48 0.97 1.95) 95 — S— 217 (0.91 1.00 1.91)95 - S-206 (1.03 1.99 0.93) 95 - S-207 (1.55 1.93 0.98) 95 - S-213 (1.48 0.97 1.95) 95 - S-217 (0.91 1.00 1.91)
95 — S— 218 (0.88 1.18 1.74) 95 — S— 231 (2.02 1.74 1.17) 95 — S— 233 (1.41 1.17 1.75) 95 — S— 234 (1.23 1.25 1.67)95 - S-218 (0.88 1.18 1.74) 95 - S-231 (2.02 1.74 1.17) 95 - S-233 (1.41 1.17 1.75) 95 - S-234 (1.23 1.25 1.67)
95 — S— 237 (1.24 1.54 1.37) 95 — S— 244 (1.29 1.16 1.76) 95 — S— 245 (1.21 0.93 1.98) 95 — S— 246 (1.55 1.50 1.42)95 - S-237 (1.24 1.54 1.37) 95 - S-244 (1.29 1.16 1.76) 95 - S-245 (1.21 0.93 1.98) 95 - S-246 (1.55 1.50 1.42)
95 — S— 249 (1.09 1.89 1.03) 95 — S— 251 (1.05 1.75 1.17) 95 — S— 254 (1.05 0.86 2.06) 95 — S— 255 (1.94 1.72 1.20)95 - S-249 (1.09 1.89 1.03) 95 - S-251 (1.05 1.75 1.17) 95 - S-254 (1.05 0.86 2.06) 95 - S-255 (1.94 1.72 1.20)
95 — S— 265 (1.51 1.64 1.28) 95 — S— 266 (1.15 1.22 1.70) 95 — S— 267 (0.95 0.92 2.00) 95 — S— 268 (1.49 1.79 1.13)95 - S - 265 (1.51 1.64 1.28) 95 - S - 266 (1.15 1.22 1.70) 95 - S - 267 (0.95 0.92 2.00) 95 - S - 268 (1.49 1.79 1.13)
95 — S— 269 (1.45 1.72 1.20) 95 — S— 271 (2.20 1.81 1.1 1) 95 — S— 277 (1.03 0.99 1.93) 95 — S— 279 (1.09 1.05 1.87)95 - S- 269 (1.45 1.72 1.20) 95 - S-271 (2.20 1.81 1.1 1) 95 - S-277 (1.03 0.99 1.93) 95 - S-279 (1.09 1.05 1.87)
95 — S— 285 (0.81 0.93 1.99) 95 — S— 286 (1.06 0.83 2.08) 95 — S— 287 (0.87 0.85 2.07) 95 — S— 290 (1.15 1.25 1.67)95 - S-285 (0.81 0.93 1.99) 95 - S-286 (1.06 0.83 2.08) 95 - S-287 (0.87 0.85 2.07) 95 - S-290 (1.15 1.25 1.67)
95 — S— 291 (2.28 1.65 1.26) 95 — S— 292 (1.62 1.31 1.60) 95 — S— 293 (1.12 1.12 1.79) 95 — S— 294 (1.58 1.16 1.76)95 - S-291 (2.28 1.65 1.26) 95 - S-292 (1.62 1.31 1.60) 95 - S-293 (1.12 1.12 1.79) 95 - S-294 (1.58 1.16 1.76)
95 — S— 295 (1.33 1.40 1.52) 95 — S— 296 (1.61 1.40 1.52) 95 — S— 298 (1.18 1.00 1.92) 95 — S— 304 (0.98 0.85 2.07)95 - S-295 (1.33 1.40 1.52) 95 - S-296 (1.61 1.40 1.52) 95 - S-298 (1.18 1.00 1.92) 95 - S-304 (0.98 0.85 2.07)
95 — S— 305 (1.50 1.06 1.85) 95 — S— 306 (1.66 1.72 1.20) 95 — S— 307 (1.39 1.85 1.07) 95 — S— 316 (0.98 1.06 1.86)95 - S-305 (1.50 1.06 1.85) 95 - S-306 (1.66 1.72 1.20) 95 - S-307 (1.39 1.85 1.07) 95 - S-316 (0.98 1.06 1.86)
95 — S— 327 (1.27 1.46 1.45) 95 — S— 329 (1.60 1.92 0.99) 95 — S— 332 (0.99 0.82 2.10) 95 — S— 342 (3.03 1.67 1.24)95 - S- 327 (1.27 1.46 1.45) 95 - S- 329 (1.60 1.92 0.99) 95 - S-332 (0.99 0.82 2.10) 95 - S-342 (3.03 1.67 1.24)
95 — S— 358 (0.93 0.98 1.94) 95 — S— 367 (1.55 1.62 1.30) 95 — S— 370 (0.90 1.05 1.87) 95 — S— 371 (2.72 1.76 1.15)95 - S-358 (0.93 0.98 1.94) 95 - S-367 (1.55 1.62 1.30) 95 - S-370 (0.90 1.05 1.87) 95 - S-371 (2.72 1.76 1.15)
95 — S— 382 (0.88 0.93 1.99) 95 — S— 395 (1.75 1.46 1.45) 95 — S— 396 (1.17 0.90 2.02) 95 — S— 420 (0.93 1.94 0.97)95 - S-382 (0.88 0.93 1.99) 95 - S-395 (1.75 1.46 1.45) 95 - S-396 (1.17 0.90 2.02) 95 - S-420 (0.93 1.94 0.97)
95 — S— 434 (0.82 1.04 1.88) 95 — S— 435 (0.91 1.20 1.71) 95 — S— 440 (1.43 1.37 1.55) 95 — S— 441 (1.36 1.30 1.62)95 - S - 434 (0.82 1.04 1.88) 95 - S - 435 (0.91 1.20 1.71) 95 - S - 440 (1.43 1.37 1.55) 95 - S - 441 (1.36 1.30 1.62)
95 — S— 443 (0.84 1.91 1.00) 95 — S— 447 (1.37 1.49 1.43) 95 — S— 449 (1.1 1 1.45 1.46) 95 — S— 452 (1.51 1.72 1.20)95 - S-443 (0.84 1.91 1.00) 95 - S-447 (1.37 1.49 1.43) 95 - S-449 (1.1 1 1.45 1.46) 95 - S-452 (1.51 1.72 1.20)
95 — S— 455 (0.81 0.86 2.06) 95 — S— 457 (0.96 1.37 1.55) 95 — S— 460 (1.24 1.80 1.12) 95 — S— 461 (0.95 1.56 1.36)95 - S-455 (0.81 0.86 2.06) 95 - S-457 (0.96 1.37 1.55) 95 - S-460 (1.24 1.80 1.12) 95 - S-461 (0.95 1.56 1.36)
95 — S— 468 (0.84 1.27 1.64) 95 — S— 469 (0.93 1.70 1.22) 95 — S— 471 (1.54 1.03 1.89) 95 — S— 473 (1.58 1.64 1.27)95 - S - 468 (0.84 1.27 1.64) 95 - S - 469 (0.93 1.70 1.22) 95 - S - 471 (1.54 1.03 1.89) 95 - S - 473 (1.58 1.64 1.27)
95 — S— 474 (1.44 1.53 1.38) 96 — S— 36 ( .16 1.02 1.03) 96 — S— 43 ( .57 0.87 1.17) 96 — S— 70 ( .64 1.08 0.96)95 - S- 474 (1.44 1.53 1.38) 96 - S- 36 (.16 1.02 1.03) 96 - S- 43 (.57 0.87 1.17) 96 - S- 70 (.64 1.08 0.96)
96 — S— 89 (1.39 0.82 1.22) 96 — S— 109 (1.47 0.89 1.16) 96 — S— 1 13 (1.07 0.94 1.1 1) 96 — S— 152 (3.05 1.08 0.97)96 - S-89 (1.39 0.82 1.22) 96 - S-109 (1.47 0.89 1.16) 96 - S- 1 13 (1.07 0.94 1.1 1) 96 - S-152 (3.05 1.08 0.97)
96 — S— 206 (0.91 0.99 1.06) 96 — S— 207 (1.43 0.94 1.1 1) 96 — S— 248 (1.49 1.05 0.99) 96 — S— 249 (0.96 0.89 1.15)96 - S-206 (0.91 0.99 1.06) 96 - S-207 (1.43 0.94 1.1 1) 96 - S-248 (1.49 1.05 0.99) 96 - S-249 (0.96 0.89 1.15)
96 — S— 271 (2.08 0.82 1.23) 96 — S— 307 (1.26 0.85 1.20) 96 — S— 320 (1.76 1.14 0.91) 96 — S— 329 (1.48 0.93 1.12)96 - S-271 (2.08 0.82 1.23) 96 - S-307 (1.26 0.85 1.20) 96 - S-320 (1.76 1.14 0.91) 96 - S-329 (1.48 0.93 1.12)
96 — S— 420 (0.80 0.95 1.10) 96 — S— 451 (1.33 1.07 0.98) 96 — S— 460 (1.1 1 0.80 1.24) 97 — S— 0 (1.02 1.22 1.84)96 - S - 420 (0.80 0.95 1.10) 96 - S - 451 (1.33 1.07 0.98) 96 - S - 460 (1.1 1 0.80 1.24) 97 - S - 0 (1.02 1.22 1.84)
97 — S— 20 (1.24 1.31 1.76) 97 — S— 27 ( .15 1.47 1.59) 97 — S— 28 ( .22 1.74 1.32) 97 — S— 29 (0.98 1.46 1.60)97 - S- 20 (1.24 1.31 1.76) 97 - S- 27 (.15 1.47 1.59) 97 - S- 28 (.22 1.74 1.32) 97 - S- 29 (0.98 1.46 1.60)
97 — S— 43 (1.79 2.1 1 0.95) 97 — S— 46 (2.39 1.63 1.43) 97 — S— 56 ( .14 0.93 2.13) 97 — S— 61 (1.13 1.45 1.61) 97— S— 62 ( .001.651.42) 97— S— 65 ( .141.241.82) 97— S— 68 (0.851.211.86) 97— S— 79 ( .121.621.44)97 - S - 43 (1.79 2.1 1 0.95) 97 - S - 46 (2.39 1.63 1.43) 97 - S - 56 (.14 0.93 2.13) 97 - S - 61 (1.13 1.45 1.61) 97- S- 62 (.001.651.42) 97- S- 65 (.141.241.82) 97- S- 68 (0.851.211.86) 97- S- 79 (.121.621.44)
97— S— 80 ( .071.581.49) 97— S— 81 ( .151.701.36) 97— S— 82 (0.881.891.18) 97— S— 83 ( .180.872.19)97- S- 80 (.071.581.49) 97- S- 81 (.151.701.36) 97- S- 82 (0.881.891.18) 97- S- 83 (.180.872.19)
97— S— 85 ( .641.431.63) 97— S— 86 (0.851.801.26) 97— S— 89 ( .612.061.01) 97— S— 90 ( .521.911.16)97- S- 85 (.641.431.63) 97- S- 86 (0.851.801.26) 97- S- 89 (.612.061.01) 97- S- 90 (.521.911.16)
97— S— 101 (1.271.761.30) 97— S— 105 (1.430.852.21) 97— S— 107 (1.901.591.47) 97— S— 108 (1.461.981.08)97- S-101 (1.271.761.30) 97- S-105 (1.430.852.21) 97- S-107 (1.901.591.47) 97- S-108 (1.461.981.08)
97— S— 109 (1.692.120.94) 97— S— 110 (1.191.761.30) 97— S— 111 (1.890.882.19) 97— S— 112 (1.081.261.81)97- S-109 (1.692.120.94) 97- S-110 (1.191.761.30) 97- S-111 (1.890.882.19) 97- S-112 (1.081.261.81)
97— S— 115 (1.561.731.33) 97— S— 118 (1.171.151.91) 97— S— 119 (1.141.371.69) 97— S— 131 (1.200.832.23)97- S-115 (1.561.731.33) 97- S-118 (1.171.151.91) 97- S-119 (1.141.371.69) 97- S-131 (1.200.832.23)
97— S— 132 (1.111.081.99) 97— S— 133 (1.901.881.18) 97— S— 144 (1.231.791.27) 97— S— 150 (2.721.761.31)97- S-132 (1,111,081.99) 97- S-133 (1,901,881.18) 97- S-144 (1,231,791.27) 97- S-150 (2,721,761.31)
97— S— 151 (2.632.011.05) 97— S— 153 (2.651.861.21) 97— S— 154 (2.180.992.08) 97— S— 166 (1.900.812.25)97- S-151 (2.632.011.05) 97- S-153 (2.651.861.21) 97- S- 154 (2,180,992.08) 97- S-166 (1,900,812.25)
97— S— 171 (1.670.812.25) 97— S— 177 (1.731.541.53) 97— S— 183 (1.381.871.19) 97— S— 184 (2.471.351.71)97- S-171 (1,670,812.25) 97- S-177 (1,731,541.53) 97- S-183 (1,381,871.19) 97- S-184 (2,471,351.71)
97— S— 192 (2.071.871.19) 97— S— 193 (0.991.032.03) 97— S— 195 (1.901.191.87) 97— S— 198 (1.611.251.81)97-S-192 (2,071,871.19) 97-S-193 (0.991.032.03) 97-S-195 (1.901.191.87) 97-S-198 (1.611.251.81)
97— S— 205 (1.131.311.75) 97— S— 209 (0.840.862.20) 97— S— 213 (1.581.211.85) 97— S— 217 (1.001.241.82)97-S-205 (1,131,311.75) 97-S-209 (0.840.862.20) 97-S-213 (1.581.211.85) 97-S-217 (1.001.241.82)
97— S— 218 (0.971.421.64) 97— S— 222 (0.880.822.24) 97— S— 231 (2.121.981.08) 97— S— 233 (1.501.411.66)97-S-218 (0.971.421.64) 97-S-222 (0.880.822.24) 97-S-231 (2.121.981.08) 97-S-233 (1.501.411.66)
97— S— 234 (1.321.491.58) 97— S— 237 (1.331.781.28) 97— S— 244 (1.391.401.66) 97— S— 245 (1.311.171.89)97-S-234 (1,321,491.58) 97-S-237 (1,331,781.28) 97-S-244 (1,391,401,666) 97-S-245 (1,311,171,89)
97— S— 246 (1.641.741.32) 97— S— 249 (1.182.130.94) 97— S— 251 (1.151.991.08) 97— S— 254 (1.141.101.97)97- S-246 (1,641,741.32) 97- S-249 (1,182,130.94) 97- S-251 (1,151,991.08) 97- S-254 (1.141.101.97)
97— S— 255 (2.031.961.11) 97— S— 265 (1.601.881.18) 97— S— 266 (1.241.461.61) 97— S— 267 (1.041.161.91)97-S-255 (2,031,961.11) 97-S-265 (1,601,881.18) 97-S-266 (1,241,461.61) 97-S-267 (1,041,161.91)
97— S— 268 (1.582.031.03) 97— S— 269 (1.551.961.11) 97— S— 271 (2.302.051.01) 97— S— 274 (0.910.962.10)97- S- 268 (1.582.031.03) 97- S- 269 (1.551.961.11) 97- S-271 (2.302.051.01) 97- S-274 (0.910.962.10)
97— S— 277 (1.131.231.84) 97— S— 279 (1.181.291.78) 97— S— 280 (0.860.972.10) 97— S— 285 (0.901.171.89)97-S-277 (1,131,231.84) 97-S-279 (1,181,291.78) 97-S-280 (0,860,972.10) 97-S-285 (0.901.171.89)
97— S— 286 (1.161.071.99) 97— S— 287 (0.971.081.98) 97— S— 288 (0.951.022.04) 97— S— 289 (1.210.862.20)97- S-286 (1.161.071.99) 97- S-287 (0.971.081.98) 97- S-288 (0.951.022.04) 97- S-289 (1.210.862.20)
97— S— 290 (1.241.491.57) 97— S— 291 (2.381.891.17) 97— S— 292 (1.711.551.51) 97— S— 293 (1.221.361.70)97- S-290 (1.241.491.57) 97- S-291 (2.381.891.17) 97- S-292 (1.711.551.51) 97- S-293 (1.221.361.70)
97— S— 294 (1.671.401.67) 97— S— 295 (1.421.641.42) 97— S— 296 (1.701.631.43) 97— S— 298 (1.271.241.82)97-S-294 (1671.401.67) 97-S-295 (1421.641.42) 97-S-296 (1.701.631.43) 97-S-298 (1.271.241.82)
97— S— 304 (1.081.091.98) 97— S— 305 (1.591.301.76) 97— S— 306 (1.751.961.11) 97— S— 307 (1.482.090.98)97- S-304 (1.081.091.98) 97- S-305 (1.591.301.76) 97- S-306 (1.751.961.11) 97- S-307 (1.482.090.98)
97— S— 311 (0.910.972.09) 97— S— 312 (1.010.852.22) 97— S— 316 (1.081.301.76) 97— S— 327 (1.371.701.36)97- S-311 (0.910.972.09) 97- S-312 (1.010.852.22) 97- S-316 (1081.301.76) 97- S-327 (1.371.701.36)
97— S— 331 (1.230.882.18) 97— S— 332 (1.081.062.01) 97— S— 336 (1.180.952.12) 97— S— 342 (3.121.911.15)97- S-331 (1.230.882.18) 97- S-332 (1.081.062.01) 97- S-336 (1.180.952.12) 97- S-342 (3.121.911.15)
97— S— 358 (1.021.221.84) 97— S— 367 (1.651.861.21) 97— S— 370 (0.991.291.78) 97— S— 371 (2.812.001.06)97- S-358 (1.021.221.84) 97- S-367 (1.651.861.21) 97- S-370 (0.991.291.78) 97- S-371 (2.812.001.06)
97— S— 372 (1.220.992.08) 97— S— 374 (0.831.481.58) 97— S— 379 (0.900.982.08) 97— S— 382 (0.971.171.90)97- S-372 (1.220.992.08) 97- S-374 (0.831.481.58) 97- S-379 (0.900.982.08) 97- S-382 (0.971.171.90)
97— S— 391 (0.910.972.09) 97— S— 395 (1.841.701.36) 97— S— 396 (1.261.141.92) 97— S— 397 (1.070.982.08)97- S-391 (0.910.972.09) 97- S-395 (1.841.701.36) 97- S-396 (1.261.141.92) 97- S-397 (1.070.982.08)
97— S— 415 (0.960.872.20) 97— S— 430 (0.851.801.26) 97— S— 434 (0.921.281.79) 97— S— 435 (1.001.441.62)97-S-415 (0.960.872.20) 97-S-430 (0.851.801.26) 97-S-434 (0.921.281.79) 97-S-435 (1.001.441.62)
97— S— 437 (1.180.822.24) 97— S— 440 (1.531.611.45) 97— S— 441 (1.461.541.52) 97— S— 443 (0.932.150.91)97-S-437 (1,180,822.24) 97-S-440 (1,531,611.45) 97-S-441 (1,461,541.52) 97-S-443 (0.932.150.91)
97— S— 447 (1.471.731.34) 97— S— 449 (1.211.691.37) 97— S— 450 (0.831.361.70) 97— S— 452 (1.611.961.10)97- S-447 (1.471.731.34) 97- S-449 (1.211.691.37) 97- S- 450 (0.831.361.70) 97- S-452 (1.611.961.10)
97— S— 454 (0.920.832.23) 97— S— 455 (0.901.101.96) 97— S— 457 (1.051.611.46) 97— S— 459 (0.841.841.23)97- S-454 (0.920.832.23) 97- S-455 (0.901.101.96) 97- S-457 (1.051.611.46) 97- S-459 (0.841.841.23)
97— S— 460 (1.332.041.03) 97— S— 461 (1.051.801.27) 97— S— 468 (0.931.511.55) 97— S— 469 (1.021.941.12)97- S-460 (1.332.041.03) 97- S-461 (1.051.801.27) 97- S-468 (0.931.511.55) 97- S-469 (1.021.941.12)
97— S— 471 (1.631.271.79) 97— S— 473 (1.681.881.18) 97— S— 474 (1.531.771.29) 98— S— 27 (0.800.871.94)97- S-471 (1631.271.79) 97- S-473 (1.681.881.18) 97- S-474 (1.531.771.29) 98- S-27 (0.800.871.94)
98— S— 28 (0.871.131.67) 98— S— 36 ( .031.651.16) 98— S— 43 ( .441.501.30) 98— S— 46 (2.041.021.78)98- S-28 (0.871.131.67) 98- S-36 (.031.651.16) 98- S-43 (.441.501.30) 98- S-46 (2.041.021.78)
98— S— 70 ( .501.711.09) 98— S— 81 (0.801.091.71) 98— S— 85 ( .290.821.98) 98— S— 89 ( .261.451.35)98- S- 70 (.501.711.09) 98- S- 81 (0.801.091.71) 98- S- 85 (.290.821.98) 98- S- 89 (.261.451.35)
98— S— 90 ( .171.301.51) 98— S— 101 (0.921.151.65) 98— S— 107 (1.550.981.82) 98— S— 108 (1.111.381.43)98- S-90 (.171.301.51) 98- S-101 (0.921.151.65) 98- S-107 (1.550.981.82) 98- S-108 (1.111.381.43)
98— S— 109 (1.341.511.29) 98— S— 110 (0.841.151.65) 98— S— 113 (0.941.571.24) 98— S— 115 (1.211.121.68)98- S-109 (1.341.511.29) 98- S-110 (0.841.151.65) 98- S-113 (0.941.571.24) 98- S-115 (1.211.121.68)
98— S— 133 (1.551.281.53) 98— S— 144 (0.881.191.62) 98— S— 145 (0.861.840.97) 98— S— 150 (2.371.151.66)98- S-133 (1,551,281.53) 98- S-144 (0.881.191.62) 98- S-145 (0.861.840.97) 98- S-150 (2,371,151.66)
98— S— 151 (2.281.411.40) 98— S— 152 (2.921.711.10) 98— S— 153 (2.301.251.55) 98— S— 177 (1.380.931.88)98- S-151 (2.281.411.40) 98- S-152 (2.921.711.10) 98- S-153 (2.301.251.55) 98- S-177 (1.380.931.88)
98— S— 183 (1.031.271.54) 98— S— 192 (1.731.261.54) 98— S— 207 (1.301.571.24) 98— S— 215 (1.531.830.97)98- S-183 (1031.271.54) 98- S-192 (1.731.261.54) 98- S-207 (1.301.571.24) 98- S-215 (1.531.830.97)
98— S— 231 (1.771.371.43) 98— S— 234 (0.970.881.92) 98— S— 237 (0.981.181.63) 98— S— 246 (1.291.131.67)98- S-231 (1,771,371.43) 98- S-234 (0.970.881.92) 98- S-237 (0.981.181.63) 98- S-246 (1.291.131.67)
98— S— 248 (1.361.681.13) 98— S— 249 (0.831.521.28) 98— S— 255 (1.681.351.46) 98— S— 260 (0.811.801.00)98- S-248 (1,361,681.13) 98- S-249 (0.831.521.28) 98- S- 255 (1.681.351.46) 98- S-260 (0.811.801.00)
98— S— 265 (1.251.271.53) 98— S— 266 (0.890.851.96) 98— S— 268 (1.231.421.38) 98— S— 269 (1.201.351.45)98- S-265 (1.251.271.53) 98- S-266 (0.890.851.96) 98- S-268 (1.231.421.38) 98- S-269 (1.201.351.45)
98— S— 271 (1.951.441.36) 98— S— 290 (0.890.881.92) 98— S— 291 (2.031.291.52) 98— S— 292 (1.360.951.86)98- S-271 (1.951.441.36) 98- S-290 (0.890.881.92) 98- S-291 (2.031.291.52) 98- S-292 (1,360,951.86)
98— S— 295 (1.081.031.77) 98— S— 296 (1.351.031.78) 98— S— 306 (1.401.351.46) 98— S— 307 (1.131.481.33)98- S-295 (1081.031.77) 98- S-296 (1.351.031.78) 98- S-306 (1.401.351.46) 98- S-307 (1.131.481.33)
98— S— 320 (1.621.771.04) 98— S— 327 (1.021.101.71) 98— S— 329 (1.341.561.25) 98— S— 342 (2.771.311.50)98- S-320 (1621.771.04) 98- S- 327 (1021.101.71) 98- S- 329 (1.341.561.25) 98- S-342 (2.771.311.50)
98— S— 343 (3.301.801.01) 98— S— 367 (1.301.251.55) 98— S— 368 (1.411.791.01) 98— S— 371 (2.461.391.41)98- S-343 (3.301.801.01) 98- S-367 (1.301.251.55) 98- S-368 (1.411.791.01) 98- S-371 (2.461.391.41)
98— S— 395 (1.491.101.71) 98— S— 440 (1.181.001.80) 98— S— 441 (1.110.931.87) 98— S— 447 (1.121.121.69)98- S-395 (1491101.71) 98- S-440 (1,181,001.80) 98- S-441 (1,110,931.87) 98- S-447 (1,121,121.69)
98— S— 449 (0.861.091.72) 98— S— 451 (1.201.701.11) 98— S— 452 (1.261.351.45) 98— S— 460 (0.981.431.38)98- S-449 (0.861.091.72) 98- S-451 (1.201.701.11) 98- S-452 (1.261.351.45) 98- S-460 (0.981.431.38)
98— S— 463 (1.131.801.00) 98— S— 473 (1.331.281.53) 98— S— 474 (1.181.161.64) 149- -s- -20 (0.981.312.02)98- S-463 (1,131,801.00) 98- S-473 (1,331,281.53) 98- S-474 (1,181,161.64) 149-s-20 (0.981.312.02)
149- -s- -27 (0.891.471.85) 149- -s- -28 (0.951.741.58) 149- -s- -36 (1.112.251.07) 149- -s- -43 (1.532.111.22)149- -s- -27 (0.891.471.85) 149- -s- -28 (0.951.741.58) 149- -s- -36 (1.112.251.07) 149- -s- -43 (1.532.111.22)
149- -s- -46 (2.121.631.70) 149- -s- -56 (0.880.932.39) 149- -s- -61 (0.861.451.88) 149- -s- -65 (0.871.242.08)149- s -46 (2,121,631.70) 149- s -56 (0.880.932.39) 149- s -61 (0.861.451.88) 149- s -65 (0.871.242.08)
149- -s- -70 (1.592.321.01) 149- -s- -79 (0.861.621.71) 149- -s- -80 (0.811.581.75) 149- -s- -81 (0.891.701.62)149-s-70 (1.592.321.01) 149-s-s- -79 (0.861.621.71) 149-s-s- -80 (0.811.581.75) 149-s-81 (0.891.701.62)
149- -s- -83 (0.920.872.45) 149- -s- -85 (1.371.431.90) 149- -s- -89 (1.352.061.27) 149- -s- -90 (1.261.911.42)149- -s- -83 (0.920.872.45) 149- -s- -85 (1.371.431.90) 149-s-s- -89 (1.352.061.27) 149- -s- -90 (1.261.911.42)
149- -s- - 101 (1.011.761.57) 149- -s- - 105 (1.170.852.47) 149- -s- - 107(1.631.591.73) 149- -s- - 108 (1.191.981.34)149- -s - 101 (1,011,761.57) 149- -s - 105 (1,170,852.47) 149- -s - 107 (1,631,591.73) 149-s - 108 (1.191.981.34)
149- -s- - 109(1.432.121.21) 149- -s- - 110(0.921.761.57) 149- -s- - 111 (1.630.882.45) 149- -s- - 112(0.821.252.07)149- -s- - 109 (1.432.121.21) 149- -s- - 110 (0.921.761.57) 149- -s- - 111 (1.630.882.45) 149-s-s- - 112 (0.821.252.07)
149- -s- - 113 (1.032.171.15) 149- -s- - 115 (1.301.731.59) 149- -s- - Iii (0.911.152.17) 149- -s- - 119 (0.881.371.96)149- -s - 113 (1.032.171.15) 149- -s- - 115 (1.301.731.59) 149-s-s- - Iii (0.911.152.17) 149-s-s- - 119 (0.881.371.96)
149- -s- - 131 (0.930.832.50) 149- -s- - 132 (0.851.082.25) 149- -s- - 133 (1.641.881.44) 149- -s- - 144 (0.971.791.53) 149— S— 150 (2.46 1.76 1.57) 149— S— 151 (2.36 2.01 1.31) 149— S— 152 (3.01 2.31 1.01) 149— S— 153 (2.39 1.86 1.47)149- -s - 131 (0.930.832.50) 149- -s- - 132 (0.851.082.25) 149-s-s- - 133 (1.641.881.44) 149-s-s- - 144 (0.971.791.53) 149- S-150 (2.46 1.76 1.57) 149- S-151 (2.36 2.01 1.31) 149- S-152 (3.01 2.31 1.01) 149- S-153 (2.39 1.86 1.47)
149— S— 154 (1.92 0.98 2.34) 149— S— 166 (1.64 0.81 2.51) 149— S— 171 (1.41 0.81 2.52) 149— S— 177 (1.47 1.54 1.79)149- S- 154 (1.92 0.98 2.34) 149- S- 166 (1.64 0.81 2.51) 149- S-171 (1.41 0.81 2.52) 149- S-177 (1.47 1.54 1.79)
149— S— 183 (1.12 1.87 1.45) 149— S— 184 (2.20 1.35 1.98) 149— S— 192 (1.81 1.87 1.46) 149— S— 195 (1.64 1.19 2.13)149- S-183 (1.12 1.87 1.45) 149- S-184 (2.20 1.35 1.98) 149- S-192 (1.81 1.87 1.46) 149- S-195 (1.64 1.19 2.13)
149— S— 198 (1.35 1.25 2.07) 149— S— 205 (0.87 1.31 2.01) 149— S— 206 (0.86 2.23 1.10) 149— S— 207 (1.38 2.17 1.15)149- S- 198 (1.35 1.25 2.07) 149- S- 205 (0.87 1.31 2.01) 149- S- 206 (0.86 2.23 1.10) 149- S-207 (1.38 2.17 1.15)
149— S— 213 (1.31 1.21 2.12) 149— S— 231 (1.85 1.98 1.34) 149— S— 233 (1.24 1.41 1.92) 149— S— 234 (1.06 1.49 1.84)149- S-213 (1.31 1.21 2.12) 149- S-231 (1.85 1.98 1.34) 149- S-233 (1.24 1.41 1.92) 149- S-234 (1.06 1.49 1.84)
149— S— 237 (1.07 1.78 1.54) 149— S— 244 (1.13 1.40 1.93) 149— S— 245 (1.04 1.17 2.15) 149— S— 246 (1.38 1.74 1.59)149- S-237 (1.07 1.78 1.54) 149- S-244 (1.13 1.40 1.93) 149- S-245 (1.04 1.17 2.15) 149- S-246 (1.38 1.74 1.59)
149— S— 248 (1.45 2.29 1.04) 149— S— 249 (0.92 2.13 1.20) 149— S— 251 (0.89 1.99 1.34) 149— S— 254 (0.88 1.10 2.23)149- S-248 (1.45 2.29 1.04) 149- S-249 (0.92 2.13 1.20) 149- S-251 (0.89 1.99 1.34) 149- S-254 (0.88 1.10 2.23)
149— S— 255 (1.77 1.96 1.37) 149— S— 258 (0.84 2.40 0.92) 149— S— 260 (0.90 2.41 0.92) 149— S— 265 (1.34 1.88 1.45)149- S- 255 (1.77 1.96 1.37) 149- S- 258 (0.84 2.40 0.92) 149- S- 260 (0.90 2.41 0.92) 149- S- 265 (1.34 1.88 1.45)
149— S— 266 (0.98 1.46 1.87) 149— S— 268 (1.32 2.03 1.30) 149— S— 269 (1.28 1.96 1.37) 149— S— 271 (2.03 2.05 1.28)149- S- 266 (0.98 1.46 1.87) 149- S- 268 (1.32 2.03 1.30) 149- S- 269 (1.28 1.96 1.37) 149- S-271 (2.03 2.05 1.28)
149— S— 277 (0.87 1.23 2.10) 149— S— 279 (0.92 1.29 2.04) 149— S— 286 (0.90 1.07 2.25) 149— S— 289 (0.95 0.86 2.46)149- S-277 (0.87 1.23 2.10) 149- S-279 (0.92 1.29 2.04) 149- S-286 (0.90 1.07 2.25) 149- S-289 (0.95 0.86 2.46)
149— S— 290 (0.98 1.49 1.84) 149— S— 291 (2.12 1.89 1.43) 149— S— 292 (1.45 1.55 1.77) 149— S— 293 (0.95 1.36 1.96)149- S-290 (0.98 1.49 1.84) 149- S-291 (2.12 1.89 1.43) 149- S-292 (1.45 1.55 1.77) 149- S-293 (0.95 1.36 1.96)
149— S— 294 (1.41 1.39 1.93) 149— S— 295 (1.16 1.64 1.69) 149— S— 296 (1.44 1.63 1.69) 149— S— 298 (1.01 1.24 2.09)149- S-294 (1.41 1.39 1.93) 149- S-295 (1.16 1.64 1.69) 149- S-296 (1.44 1.63 1.69) 149- S-298 (1.01 1.24 2.09)
149— S— 304 (0.81 1.09 2.24) 149— S— 305 (1.33 1.30 2.02) 149— S— 306 (1.49 1.96 1.37) 149— S— 307 (1.22 2.09 1.24)149- S-304 (0.81 1.09 2.24) 149- S-305 (1.33 1.30 2.02) 149- S-306 (1.49 1.96 1.37) 149- S-307 (1.22 2.09 1.24)
149— S— 316 (0.81 1.30 2.03) 149— S— 320 (1.71 2.37 0.95) 149— S— 327 (1.10 1.70 1.62) 149— S— 329 (1.43 2.16 1.16)149- S- 316 (0.81 1.30 2.03) 149- S- 320 (1.71 2.37 0.95) 149- S- 327 (1.10 1.70 1.62) 149- S- 329 (1.43 2.16 1.16)
149— S— 331 (0.96 0.88 2.44) 149— S— 332 (0.82 1.06 2.27) 149— S— 336 (0.92 0.94 2.38) 149— S— 342 (2.86 1.91 1.41)149- S-331 (0.96 0.88 2.44) 149- S-332 (0.82 1.06 2.27) 149- S-336 (0.92 0.94 2.38) 149- S-342 (2.86 1.91 1.41)
149— S— 343 (3.39 2.40 0.92) 149— S— 367 (1.38 1.86 1.47) 149— S— 368 (1.50 2.40 0.93) 149— S— 371 (2.55 2.00 1.32)149- S-343 (3.39 2.40 0.92) 149- S- 367 (1.38 1.86 1.47) 149- S- 368 (1.50 2.40 0.93) 149- S- 371 (2.55 2.00 1.32)
149— S— 372 (0.96 0.99 2.34) 149— S— 395 (1.58 1.70 1.62) 149— S— 396 (1.00 1.14 2.19) 149— S— 397 (0.81 0.98 2.34)149- S-372 (0.96 0.99 2.34) 149- S-395 (1.58 1.70 1.62) 149- S-396 (1.00 1.14 2.19) 149- S-397 (0.81 0.98 2.34)
149— S— 437 (0.92 0.82 2.51) 149— S— 440 (1.26 1.61 1.71) 149— S— 441 (1.19 1.54 1.79) 149— S— 447 (1.20 1.72 1.60)149- S-437 (0.92 0.82 2.51) 149- S-440 (1.26 1.61 1.71) 149- S-441 (1.19 1.54 1.79) 149- S-447 (1.20 1.72 1.60)
149— S— 449 (0.95 1.69 1.63) 149— S— 451 (1.29 2.30 1.02) 149— S— 452 (1.34 1.96 1.37) 149— S— 460 (1.07 2.04 1.29)149- S-449 (0.95 1.69 1.63) 149- S-451 (1.29 2.30 1.02) 149- S-452 (1.34 1.96 1.37) 149- S-460 (1.07 2.04 1.29)
149— S— 463 (1.22 2.41 0.92) 149— S— 471 (1.37 1.27 2.06) 149— S— 473 (1.41 1.88 1.44) 149— S— 474 (1.27 1.77 1.55)149- S-463 (1.22 2.41 0.92) 149- S-471 (1.37 1.27 2.06) 149- S-473 (1.41 1.88 1.44) 149- S-474 (1.27 1.77 1.55)
337— S— 0 (1 09 1.53 1.78) 337— S— 9 (1 20 1.07 2.24) 337— S— 27 ( .22 1.78 1.53) 337— S— 28 ( .28 2.05 1.26)337- S- 0 (1 09 1.53 1.78) 337- S- 9 (1 20 1.07 2.24) 337- S-27 (.22 1.78 1.53) 337- S-28 (.28 2.05 1.26)
337— S— 29 (1.04 1.77 1.53) 337— S— 40 (0.86 1.77 1.54) 337— S— 44 (0.93 0.93 2.38) 337— S— 46 (2.45 1.94 1.37)337- S-29 (1.04 1.77 1.53) 337- S-40 (0.86 1.77 1.54) 337- S-44 (0.93 0.93 2.38) 337- S-46 (2.45 1.94 1.37)
337— S— 56 (1.21 1.24 2.07) 337— S— 61 ( .19 1.76 1.55) 337— S— 62 ( .07 1.96 1.35) 337— S— 65 ( .20 1.55 1.76)337- S- 56 (1.21 1.24 2.07) 337- S- 61 (.19 1.76 1.55) 337- S- 62 (.07 1.96 1.35) 337- S- 65 (.20 1.55 1.76)
337— S— 68 (0.91 1.51 1.79) 337— S— 79 ( .18 1.93 1.38) 337— S— 80 ( .14 1.89 1.42) 337— S— 81 ( .21 2.01 1.30)337- S- 68 (0.91 1.51 1.79) 337- S- 79 (.18 1.93 1.38) 337- S- 80 (.14 1.89 1.42) 337- S- 81 (.21 2.01 1.30)
337— S— 82 (0.95 2.20 1.1 1) 337— S— 83 ( .24 1.18 2.12) 337— S— 85 ( .70 1.74 1.57) 337— S— 86 (0.92 2.1 1 1.20)337- S- 82 (0.95 2.20 1.1 1) 337- S- 83 (.24 1.18 2.12) 337- S- 85 (.70 1.74 1.57) 337- S- 86 (0.92 2.1 1 1.20)
337— S— 89 ( 1.67 2.37 0.94) 337— S— 90 ( .58 2.22 1.09) 337— S— 101 (1.34 2.07 1.24) 337— S— 102 (0.96 1.08 2.23)337- S-89 (1.67 2.37 0.94) 337- S-90 (.58 2.22 1.09) 337- S-101 (1.34 2.07 1.24) 337- S-102 (0.96 1.08 2.23)
337— S— 105 (1.50 1.16 2.14) 337— S— 107 (1.96 1.90 1.41) 337— S— 108 (1.52 2.29 1.02) 337— S— 110 (1.25 2.07 1.24)337- S-105 (1.50 1.16 2.14) 337- S-107 (1.96 1.90 1.41) 337- S-108 (1.52 2.29 1.02) 337- S-110 (1.25 2.07 1.24)
337— S— 11 1 (1.95 1.19 2.12) 337— S— 112 (1.15 1.56 1.74) 337— S— 115 (1.63 2.04 1.27) 337— S— 118 (1.24 1.46 1.85)337- S-11 1 (1.95 1.19 2.12) 337- S-112 (1.15 1.56 1.74) 337- S-115 (1.63 2.04 1.27) 337- S-118 (1.24 1.46 1.85)
337— S— 119 (1.21 1.68 1.63) 337— S— 123 (0.85 1.81 1.50) 337— S— 131 (1.26 1.14 2.17) 337— S— 132 (1.17 1.38 1.92)337- S-119 (1.21 1.68 1.63) 337- S-123 (0.85 1.81 1.50) 337- S-131 (1.26 1.14 2.17) 337- S- 132 (1.17 1.38 1.92)
337— S— 133 (1.96 2.19 1.12) 337— S— 144 (1.30 2.10 1.21) 337— S— 148 (0.95 0.97 2.34) 337— S— 150 (2.78 2.07 1.24)337- S-133 (1.96 2.19 1.12) 337- S- 144 (1.30 2.10 1.21) 337- S- 148 (0.95 0.97 2.34) 337- S-150 (2.78 2.07 1.24)
337— S— 151 (2.69 2.32 0.98) 337— S— 153 (2.71 2.17 1.14) 337— S— 154 (2.25 1.29 2.01) 337— S— 166 (1.97 1.12 2.19)337- S-151 (2.69 2.32 0.98) 337- S-153 (2.71 2.17 1.14) 337- S- 154 (2.25 1.29 2.01) 337- S-166 (1.97 1.12 2.19)
337— S— 167 (1.83 0.81 2.50) 337— S— 171 (1.74 1.12 2.19) 337— S— 177 (1.79 1.85 1.46) 337— S— 183 (1.44 2.18 1.13)337- S-167 (1.83 0.81 2.50) 337- S-171 (1.74 1.12 2.19) 337- S-177 (1.79 1.85 1.46) 337- S-183 (1.44 2.18 1.13)
337— S— 184 (2.53 1.66 1.65) 337— S— 187 (1.68 1.03 2.28) 337— S— 188 (2.1 1 1.07 2.24) 337— S— 192 (2.14 2.18 1.13)337- S-184 (2.53 1.66 1.65) 337- S-187 (1.68 1.03 2.28) 337- S-188 (2.1 1 1.07 2.24) 337- S-192 (2.14 2.18 1.13)
337— S— 193 (1.06 1.34 1.97) 337— S— 195 (1.96 1.50 1.81) 337— S— 198 (1.67 1.56 1.75) 337— S— 205 (1.19 1.62 1.69)337- S-193 (1.06 1.34 1.97) 337- S-195 (1.96 1.50 1.81) 337- S-198 (1.67 1.56 1.75) 337- S-205 (1.19 1.62 1.69)
337— S— 208 (1.16 1.09 2.21) 337— S— 209 (0.90 1.17 2.14) 337— S— 213 (1.64 1.52 1.79) 337— S— 217 (1.06 1.55 1.76)337- S-208 (1.16 1.09 2.21) 337- S-209 (0.90 1.17 2.14) 337- S-213 (1.64 1.52 1.79) 337- S-217 (1.06 1.55 1.76)
337— S— 218 (1.03 1.73 1.58) 337— S— 219 (0.83 1.28 2.02) 337— S— 222 (0.95 1.13 2.18) 337— S— 230 (0.88 0.96 2.35)337- S-218 (1.03 1.73 1.58) 337- S-219 (0.83 1.28 2.02) 337- S-222 (0.95 1.13 2.18) 337- S-230 (0.88 0.96 2.35)
337— S— 231 (2.18 2.29 1.02) 337— S— 233 (1.57 1.71 1.59) 337— S— 234 (1.39 1.80 1.51) 337— S— 237 (1.40 2.09 1.22)337- S-231 (2.18 2.29 1.02) 337- S-233 (1.57 1.71 1.59) 337- S-234 (1.39 1.80 1.51) 337- S-237 (1.40 2.09 1.22)
337— S— 243 (2.14 0.92 2.39) 337— S— 244 (1.45 1.71 1.60) 337— S— 245 (1.37 1.48 1.83) 337— S— 246 (1.71 2.05 1.26)337- S-243 (2.14 0.92 2.39) 337- S-244 (1.45 1.71 1.60) 337- S-245 (1.37 1.48 1.83) 337- S-246 (1.71 2.05 1.26)
337— S— 251 (1.21 2.29 1.01) 337— S— 254 (1.21 1.40 1.90) 337— S— 255 (2.10 2.27 1.04) 337— S— 265 (1.67 2.19 1.12)337- S-251 (1.21 2.29 1.01) 337- S-254 (1.21 1.40 1.90) 337- S- 255 (2.10 2.27 1.04) 337- S- 265 (1.67 2.19 1.12)
337— S— 266 (1.30 1.77 1.54) 337— S— 267 (1.10 1.47 1.84) 337— S— 268 (1.65 2.34 0.97) 337— S— 269 (1.61 2.27 1.04)337- S- 266 (1.30 1.77 1.54) 337- S- 267 (1.10 1.47 1.84) 337- S- 268 (1.65 2.34 0.97) 337- S- 269 (1.61 2.27 1.04)
337— S— 271 (2.36 2.36 0.95) 337— S— 272 (1.49 0.81 2.50) 337— S— 274 (0.97 1.27 2.04) 337— S— 277 (1.19 1.53 1.77)337- S-271 (2.36 2.36 0.95) 337- S-272 (1.49 0.81 2.50) 337- S-274 (0.97 1.27 2.04) 337- S-277 (1.19 1.53 1.77)
337— S— 279 (1.25 1.60 1.71) 337— S— 280 (0.92 1.28 2.03) 337— S— 282 (1.04 1.10 2.21) 337— S— 284 (0.82 1.11 2.20)337- S-279 (1.25 1.60 1.71) 337- S- 280 (0.92 1.28 2.03) 337- S-282 (1.04 1.10 2.21) 337- S-284 (0.82 1.11 2.20)
337— S— 285 (0.97 1.48 1.83) 337— S— 286 (1.22 1.38 1.93) 337— S— 287 (1.03 1.39 1.91) 337— S— 288 (1.01 1.33 1.98)337- S-285 (0.97 1.48 1.83) 337- S-286 (1.22 1.38 1.93) 337- S-287 (1.03 1.39 1.91) 337- S-288 (1.01 1.33 1.98)
337— S— 289 (1.27 1.17 2.14) 337— S— 290 (1.30 1.80 1.51) 337— S— 291 (2.44 2.20 1.1 1) 337— S— 292 (1.78 1.86 1.45)337- S-289 (1.27 1.17 2.14) 337- S-290 (1.30 1.80 1.51) 337- S-291 (2.44 2.20 1.1 1) 337- S-292 (1.78 1.86 1.45)
337— S— 293 (1.28 1.67 1.64) 337— S— 294 (1.73 1.70 1.60) 337— S— 295 (1.49 1.95 1.36) 337— S— 296 (1.77 1.94 1.36)337- S-293 (1.28 1.67 1.64) 337- S-294 (1.73 1.70 1.60) 337- S-295 (1.49 1.95 1.36) 337- S-296 (1.77 1.94 1.36)
337— S— 297 (1.08 1.07 2.23) 337— S— 298 (1.33 1.55 1.76) 337— S— 300 (1.34 0.95 2.36) 337— S— 303 (1.10 0.92 2.39)337- S-297 (1.08 1.07 2.23) 337- S-298 (1.33 1.55 1.76) 337- S- 300 (1.34 0.95 2.36) 337- S-303 (1.10 0.92 2.39)
337— S— 304 (1.14 1.39 1.91) 337— S— 305 (1.66 1.61 1.70) 337— S— 306 (1.82 2.26 1.04) 337— S— 307 (1.55 2.39 0.91)337- S-304 (1.14 1.39 1.91) 337- S-305 (1.66 1.61 1.70) 337- S-306 (1.82 2.26 1.04) 337- S-307 (1.55 2.39 0.91)
337— S— 310 (1.25 1.01 2.30) 337— S— 31 1 (0.98 1.28 2.03) 337— S— 312 (1.08 1.15 2.15) 337— S— 313 (0.85 1.32 1.99)337- S- 310 (1.25 1.01 2.30) 337- S-31 1 (0.98 1.28 2.03) 337- S-312 (1.08 1.15 2.15) 337- S-313 (0.85 1.32 1.99)
337— S— 316 (1.14 1.61 1.70) 337— S— 327 (1.43 2.01 1.30) 337— S— 331 (1.29 1.19 2.12) 337— S— 332 (1.14 1.36 1.94)337- S-316 (1.14 1.61 1.70) 337- S-327 (1.43 2.01 1.30) 337- S-331 (1.29 1.19 2.12) 337- S-332 (1.14 1.36 1.94)
337— S— 336 (1.24 1.25 2.05) 337— S— 342 (3.18 2.22 1.09) 337— S— 356 (0.91 1.07 2.24) 337— S— 357 (1.60 0.82 2.49)337- S-336 (1.24 1.25 2.05) 337- S-342 (3.18 2.22 1.09) 337- S-356 (0.91 1.07 2.24) 337- S-357 (1.60 0.82 2.49)
337— S— 358 (1.09 1.53 1.78) 337— S— 367 (1.71 2.17 1.14) 337— S— 370 (1.05 1.60 1.71) 337— S— 371 (2.87 2.31 1.00)337- S-358 (1.09 1.53 1.78) 337- S-367 (1.71 2.17 1.14) 337- S-370 (1.05 1.60 1.71) 337- S-371 (2.87 2.31 1.00)
337— S— 372 (1.28 1.30 2.01) 337— S— 374 (0.89 1.79 1.52) 337— S— 379 (0.97 1.29 2.02) 337— S— 382 (1.04 1.47 1.83)337- S-372 (1.28 1.30 2.01) 337- S-374 (0.89 1.79 1.52) 337- S-379 (0.97 1.29 2.02) 337- S-382 (1.04 1.47 1.83)
337— S— 391 (0.97 1.28 2.03) 337— S— 395 (1.90 2.01 1.30) 337— S— 396 (1.33 1.45 1.86) 337— S— 397 (1.13 1.29 2.01)337- S-391 (0.97 1.28 2.03) 337- S-395 (1.90 2.01 1.30) 337- S-396 (1.33 1.45 1.86) 337- S-397 (1.13 1.29 2.01)
337— S— 415 (1.02 1.18 2.13) 337— S— 430 (0.91 2.11 1.20) 337— S— 434 (0.98 1.58 1.72) 337— S— 435 (1.06 1.75 1.56)337- S- 415 (1.02 1.18 2.13) 337- S- 430 (0.91 2.11 1.20) 337- S- 434 (0.98 1.58 1.72) 337- S- 435 (1.06 1.75 1.56)
337— S— 437 (1.25 1.13 2.18) 337— S— 440 (1.59 1.92 1.39) 337— S— 441 (1.52 1.85 1.46) 337— S— 447 (1.53 2.03 1.27)337- S-437 (1.25 1.13 2.18) 337- S-440 (1.59 1.92 1.39) 337- S-441 (1.52 1.85 1.46) 337- S-447 (1.53 2.03 1.27)
337— S— 449 (1.27 2.00 1.31) 337— S— 450 (0.89 1.67 1.64) 337— S— 452 (1.67 2.27 1.04) 337— S— 453 (1.16 0.97 2.33)337- S-449 (1.27 2.00 1.31) 337- S- 450 (0.89 1.67 1.64) 337- S-452 (1.67 2.27 1.04) 337- S-453 (1.16 0.97 2.33)
337— S— 454 (0.98 1.14 2.17) 337— S— 455 (0.97 1.41 1.90) 337— S— 457 (1.12 1.91 1.39) 337— S— 459 (0.90 2.15 1.16) 337— S— 460 (1.39 2.35 0.96) 337— S— 461 (1.1 1 2.11 1.20) 337— S— 462 (0.80 2.12 1.19) 337— S— 468 (1.00 1.82 1.49)337- S-454 (0.98 1.14 2.17) 337- S-455 (0.97 1.41 1.90) 337- S-457 (1.12 1.91 1.39) 337- S-459 (0.90 2.15 1.16) 337- S- 460 (1.39 2.35 0.96) 337- S-461 (1.1 1 2.11 1.20) 337- S-462 (0.80 2.12 1.19) 337- S-468 (1.00 1.82 1.49)
337— S— 469 (1.09 2.25 1.06) 337— S— 471 (1.69 1.58 1.73) 337— S— 473 (1.74 2.19 1.12) 337— S— 474 (1.59 2.08 1.23)337- S-469 (1.09 2.25 1.06) 337- S-471 (1.69 1.58 1.73) 337- S-473 (1.74 2.19 1.12) 337- S-474 (1.59 2.08 1.23)
354— S— 0 (0.81 1.17 2.05) 354— S— 20 (1.03 1.26 1.97) 354— S— 27 (0.94 1.42 1.80) 354— S— 28 (1.00 1.69 1.53)354- S- 0 (0.81 1.17 2.05) 354- S- 20 (1.03 1.26 1.97) 354- S- 27 (0.94 1.42 1.80) 354- S-28 (1.00 1.69 1.53)
354— S— 36 (1.16 2.20 1.02) 354— S— 43 (1.58 2.06 1.17) 354— S— 46 (2.17 1.58 1.65) 354— S— 56 (0.93 0.89 2.34)354- S- 36 (1.16 2.20 1.02) 354- S- 43 (1.58 2.06 1.17) 354- S- 46 (2.17 1.58 1.65) 354- S- 56 (0.93 0.89 2.34)
354— S— 61 (0.91 1.40 1.83) 354— S— 65 (0.92 1.19 2.03) 354— S— 70 (1.64 2.27 0.96) 354— S— 79 (0.91 1.57 1.65)354- S- 61 (0.91 1.40 1.83) 354- S- 65 (0.92 1.19 2.03) 354- S- 70 (1.64 2.27 0.96) 354- S- 79 (0.91 1.57 1.65)
354— S— 80 (0.86 1.53 1.70) 354— S— 81 (0.94 1.65 1.57) 354— S— 83 (0.97 0.83 2.40) 354— S— 85 (1.42 1.38 1.84)354- S- 80 (0.86 1.53 1.70) 354- S- 81 (0.94 1.65 1.57) 354- S- 83 (0.97 0.83 2.40) 354- S- 85 (1.42 1.38 1.84)
354— S— 89 (1.40 2.01 1.22) 354— S— 90 (1.31 1.86 1.37) 354— S— 101 (1.06 1.71 1.52) 354— S— 105 (1.22 0.81 2.42)354- S- 89 (1.40 2.01 1.22) 354- S- 90 (1.31 1.86 1.37) 354- S-101 (1.06 1.71 1.52) 354- S-105 (1.22 0.81 2.42)
354— S— 107 (1.68 1.54 1.68) 354— S— 108 (1.24 1.93 1.29) 354— S— 109 (1.48 2.07 1.16) 354— S— 110 (0.98 1.71 1.52)354- S-107 (1.68 1.54 1.68) 354- S-108 (1.24 1.93 1.29) 354- S-109 (1.48 2.07 1.16) 354- S-110 (0.98 1.71 1.52)
354— S— 11 1 (1.68 0.83 2.40) 354— S— 112 (0.87 1.21 2.02) 354— S— 113 (1.08 2.12 1.10) 354— S— 115 (1.35 1.68 1.54)354- S- 11 1 (1.68 0.83 2.40) 354- S-112 (0.87 1.21 2.02) 354- S-113 (1.08 2.12 1.10) 354- S-115 (1.35 1.68 1.54)
354— S— 118 (0.96 1.10 2.12) 354— S— 119 (0.93 1.32 1.91) 354— S— 132 (0.90 1.03 2.20) 354— S— 133 (1.69 1.83 1.39)354- S-118 (0.96 1.10 2.12) 354- S-119 (0.93 1.32 1.91) 354- S- 132 (0.90 1.03 2.20) 354- S- 133 (1.69 1.83 1.39)
354— S— 144 (1.02 1.74 1.48) 354— S— 150 (2.51 1.71 1.52) 354— S— 151 (2.41 1.97 1.26) 354— S— 152 (3.06 2.26 0.96)354- S- 144 (1.02 1.74 1.48) 354- S- 150 (2.51 1.71 1.52) 354- S- 151 (2.41 1.97 1.26) 354- S-152 (3.06 2.26 0.96)
354— S— 153 (2.44 1.81 1.42) 354— S— 154 (1.97 0.94 2.29) 354— S— 177 (1.52 1.49 1.74) 354— S— 183 (1.17 1.82 1.40)354- S-153 (2.44 1.81 1.42) 354- S- 154 (1.97 0.94 2.29) 354- S-177 (1.52 1.49 1.74) 354- S-183 (1.17 1.82 1.40)
354— S— 184 (2.26 1.30 1.93) 354— S— 192 (1.86 1.82 1.41) 354— S— 195 (1.69 1.14 2.08) 354— S— 198 (1.40 1.20 2.02)354- S-184 (2.26 1.30 1.93) 354- S-192 (1.86 1.82 1.41) 354- S-195 (1.69 1.14 2.08) 354- S-198 (1.40 1.20 2.02)
354— S— 205 (0.92 1.26 1.96) 354— S— 206 (0.91 2.18 1.05) 354— S— 207 (1.43 2.12 1.10) 354— S— 213 (1.36 1.16 2.07)354- S-205 (0.92 1.26 1.96) 354- S-206 (0.91 2.18 1.05) 354- S-207 (1.43 2.12 1.10) 354- S-213 (1.36 1.16 2.07)
354— S— 231 (1.91 1.93 1.29) 354— S— 233 (1.29 1.36 1.87) 354— S— 234 (1.1 1 1.44 1.79) 354— S— 237 (1.12 1.73 1.49)354- S-231 (1.91 1.93 1.29) 354- S-233 (1.29 1.36 1.87) 354- S-234 (1.1 1 1.44 1.79) 354- S-237 (1.12 1.73 1.49)
354— S— 244 (1.18 1.35 1.88) 354— S— 245 (1.09 1.12 2.10) 354— S— 246 (1.43 1.69 1.54) 354— S— 248 (1.50 2.24 0.99)354-S-244 (1.18 1.35 1.88) 354-S-245 (1.09 1.12 2.10) 354-S-246 (1.43 1.69 1.54) 354-S-248 (1.50 2.24 0.99)
354— S— 249 (0.97 2.08 1.15) 354— S— 251 (0.94 1.94 1.29) 354— S— 254 (0.93 1.05 2.18) 354— S— 255 (1.82 1.91 1.32)354- S-249 (0.97 2.08 1.15) 354- S-251 (0.94 1.94 1.29) 354- S-254 (0.93 1.05 2.18) 354- S- 255 (1.82 1.91 1.32)
354— S— 265 (1.39 1.83 1.40) 354— S— 266 (1.03 1.41 1.82) 354— S— 267 (0.83 1.11 2.12) 354— S— 268 (1.37 1.98 1.25)354- S- 265 (1.39 1.83 1.40) 354- S- 266 (1.03 1.41 1.82) 354- S- 267 (0.83 1.11 2.12) 354- S-268 (1.37 1.98 1.25)
354— S— 269 (1.34 1.91 1.32) 354— S— 271 (2.08 2.00 1.23) 354— S— 277 (0.92 1.18 2.05) 354— S— 279 (0.97 1.24 1.99)354- S- 269 (1.34 1.91 1.32) 354- S- 271 (2.08 2.00 1.23) 354- S- 277 (0.92 1.18 2.05) 354- S- 279 (0.97 1.24 1.99)
354— S— 286 (0.95 1.02 2.20) 354— S— 289 (1.00 0.81 2.41) 354— S— 290 (1.03 1.44 1.79) 354— S— 291 (2.17 1.84 1.38)354- S-286 (0.95 1.02 2.20) 354- S-289 (1.00 0.81 2.41) 354- S-290 (1.03 1.44 1.79) 354- S-291 (2.17 1.84 1.38)
354— S— 292 (1.50 1.50 1.72) 354— S— 293 (1.00 1.31 1.91) 354— S— 294 (1.46 1.35 1.88) 354— S— 295 (1.21 1.59 1.64)354- S-292 (1.50 1.50 1.72) 354- S-293 (1.00 1.31 1.91) 354- S-294 (1.46 1.35 1.88) 354- S-295 (1.21 1.59 1.64)
354— S— 296 (1.49 1.59 1.64) 354— S— 298 (1.06 1.19 2.04) 354— S— 304 (0.87 1.04 2.19) 354— S— 305 (1.38 1.25 1.97)354-S-296 (1.49 1.59 1.64) 354-S-298 (1.06 1.19 2.04) 354-S-304 (0.87 1.04 2.19) 354-S-305 (1.38 1.25 1.97)
354— S— 306 (1.54 1.91 1.32) 354— S— 307 (1.27 2.04 1.19) 354— S— 316 (0.86 1.25 1.97) 354— S— 327 (1.15 1.65 1.57)354- S-306 (1.54 1.91 1.32) 354- S-307 (1.27 2.04 1.19) 354- S-316 (0.86 1.25 1.97) 354- S-327 (1.15 1.65 1.57)
354— S— 329 (1.48 2.11 1.1 1) 354— S— 331 (1.01 0.83 2.39) 354— S— 332 (0.87 1.01 2.22) 354— S— 336 (0.97 0.90 2.33)354- S- 329 (1.48 2.11 1.1 1) 354- S-331 (1.01 0.83 2.39) 354- S-332 (0.87 1.01 2.22) 354- S-336 (0.97 0.90 2.33)
354— S— 342 (2.91 1.86 1.36) 354— S— 358 (0.81 1.17 2.05) 354— S— 367 (1.44 1.81 1.42) 354— S— 371 (2.60 1.95 1.27)354- S-342 (2.91 1.86 1.36) 354- S-358 (0.81 1.17 2.05) 354- S- 367 (1.44 1.81 1.42) 354- S-371 (2.60 1.95 1.27)
354— S— 372 (1.01 0.94 2.29) 354— S— 395 (1.63 1.65 1.57) 354— S— 396 (1.05 1.09 2.13) 354— S— 397 (0.86 0.94 2.29)354- S-372 (1.01 0.94 2.29) 354- S-395 (1.63 1.65 1.57) 354- S-396 (1.05 1.09 2.13) 354- S-397 (0.86 0.94 2.29)
354— S— 420 (0.81 2.13 1.09) 354— S— 440 (1.31 1.56 1.66) 354— S— 441 (1.24 1.49 1.74) 354— S— 447 (1.25 1.68 1.55)354- S-420 (0.81 2.13 1.09) 354- S-440 (1.31 1.56 1.66) 354- S-441 (1.24 1.49 1.74) 354- S-447 (1.25 1.68 1.55)
354— S— 449 (1.00 1.64 1.58) 354— S— 451 (1.34 2.26 0.97) 354— S— 452 (1.39 1.91 1.31) 354— S— 457 (0.84 1.56 1.67)354- S- 449 (1.00 1.64 1.58) 354- S-451 (1.34 2.26 0.97) 354- S-452 (1.39 1.91 1.31) 354- S-457 (0.84 1.56 1.67)
354— S— 460 (1.12 1.99 1.24) 354— S— 461 (0.83 1.75 1.48) 354— S— 469 (0.81 1.89 1.34) 354— S— 471 (1.42 1.22 2.01)354- S- 460 (1.12 1.99 1.24) 354- S-461 (0.83 1.75 1.48) 354- S- 469 (0.81 1.89 1.34) 354- S-471 (1.42 1.22 2.01)
354— S— 473 (1.47 1.83 1.39) 354— S— 474 (1.32 1.72 1.50) 400— S— 28 (1.31 0.90 1.22) 400— S— 62 (1.10 0.80 1.32)354- S- 473 (1.47 1.83 1.39) 354- S- 474 (1.32 1.72 1.50) 400- S- 28 (1.31 0.90 1.22) 400- S- 62 (1.10 0.80 1.32)
400— S— 81 (1.25 0.86 1.26) 400— S— 82 (0.98 1.04 1.08) 400— S— 86 (0.95 0.96 1.16) 400— S— 89 (1.71 1.21 0.91)400- S- 81 (1.25 0.86 1.26) 400- S- 82 (0.98 1.04 1.08) 400- S- 86 (0.95 0.96 1.16) 400- S- 89 (1.71 1.21 0.91)
400— S— 90 (1.62 1.06 1.06) 400— S— 101 (1.37 0.91 1.21) 400— S— 108 (1.55 1.14 0.98) 400— S— 110 (1.29 0.91 1.21)400- S- 90 (1.62 1.06 1.06) 400- S-101 (1.37 0.91 1.21) 400- S- 108 (1.55 1.14 0.98) 400- S- 110 (1.29 0.91 1.21)
400— S— 115 (1.66 0.89 1.23) 400— S— 133 (2.00 1.04 1.08) 400— S— 144 (1.33 0.95 1.17) 400— S— 150 (2.82 0.91 1.21)400- S- 115 (1.66 0.89 1.23) 400- S- 133 (2.00 1.04 1.08) 400- S- 144 (1.33 0.95 1.17) 400- S- 150 (2.82 0.91 1.21)
400— S— 151 (2.72 1.17 0.95) 400— S— 153 (2.75 1.01 1.1 1) 400— S— 183 (1.48 1.03 1.09) 400— S— 192 (2.17 1.03 1.10)400- S- 151 (2.72 1.17 0.95) 400- S- 153 (2.75 1.01 1.1 1) 400- S- 183 (1.48 1.03 1.09) 400- S- 192 (2.17 1.03 1.10)
400— S— 231 (2.22 1.14 0.98) 400— S— 237 (1.43 0.94 1.18) 400— S— 246 (1.74 0.89 1.23) 400— S— 251 (1.25 1.14 0.98)400- S- 231 (2.22 1.14 0.98) 400- S-237 (1.43 0.94 1.18) 400- S- 246 (1.74 0.89 1.23) 400- S- 251 (1.25 1.14 0.98)
400— S— 255 (2.13 1.11 1.01) 400— S— 265 (1.70 1.04 1.09) 400— S— 268 (1.68 1.18 0.94) 400— S— 269 (1.65 1.11 1.01)400- S- 255 (2.13 1.11 1.01) 400- S- 265 (1.70 1.04 1.09) 400- S- 268 (1.68 1.18 0.94) 400- S- 269 (1.65 1.11 1.01)
400— S— 271 (2.39 1.21 0.92) 400— S— 291 (2.48 1.05 1.07) 400— S— 306 (1.85 1.11 1.01) 400— S— 327 (1.46 0.86 1.26)400- S- 271 (2.39 1.21 0.92) 400- S- 291 (2.48 1.05 1.07) 400- S- 306 (1.85 1.11 1.01) 400- S- 327 (1.46 0.86 1.26)
400— S— 342 (3.22 1.07 1.05) 400— S— 367 (1.75 1.01 1.1 1) 400— S— 371 (2.91 1.16 0.96) 400— S— 395 (1.94 0.86 1.26)400- S- 342 (3.22 1.07 1.05) 400- S- 367 (1.75 1.01 1.1 1) 400- S- 371 (2.91 1.16 0.96) 400- S- 395 (1.94 0.86 1.26)
400— S— 430 (0.95 0.96 1.16) 400— S— 447 (1.56 0.88 1.24) 400— S— 449 (1.31 0.85 1.27) 400— S— 452 (1.70 1.12 1.00)400- S- 430 (0.95 0.96 1.16) 400- S- 447 (1.56 0.88 1.24) 400- S- 449 (1.31 0.85 1.27) 400- S- 452 (1.70 1.12 1.00)
400— S— 459 (0.94 0.99 1.13) 400— S— 460 (1.43 1.19 0.93) 400— S— 461 (1.14 0.95 1.17) 400— S— 462 (0.84 0.97 1.15)400- S- 459 (0.94 0.99 1.13) 400- S- 460 (1.43 1.19 0.93) 400- S- 461 (1.14 0.95 1.17) 400- S- 462 (0.84 0.97 1.15)
400— S— 469 (1.12 1.10 1.03) 400— S— 473 (1.78 1.04 1.08) 400— S— 474 (1.63 0.93 1.19) 405— S— 9 (0.89 0.83 2.55)400- S- 469 (1.12 1.10 1.03) 400- S- 473 (1.78 1.04 1.08) 400- S- 474 (1.63 0.93 1.19) 405- S- 9 (0.89 0.83 2.55)
405— S— 20 (0.99 1.38 2.00) 405— S— 27 (0.91 1.54 1.84) 405— S— 28 (0.97 1.81 1.57) 405— S— 36 (1.13 2.32 1.05)405- S- 20 (0.99 1.38 2.00) 405- S- 27 (0.91 1.54 1.84) 405- S- 28 (0.97 1.81 1.57) 405- S- 36 (1.13 2.32 1.05)
405— S— 43 (1.55 2.18 1.20) 405— S— 46 (2.14 1.70 1.68) 405— S— 56 (0.90 1.01 2.37) 405— S— 61 (0.88 1.52 1.86)405- S- 43 (1.55 2.18 1.20) 405- S- 46 (2.14 1.70 1.68) 405- S- 56 (0.90 1.01 2.37) 405- S- 61 (0.88 1.52 1.86)
405— S— 65 (0.89 1.31 2.06) 405— S— 70 (1.61 2.39 0.99) 405— S— 79 (0.88 1.69 1.69) 405— S— 80 (0.83 1.65 1.73)405- S- 65 (0.89 1.31 2.06) 405- S- 70 (1.61 2.39 0.99) 405- S- 79 (0.88 1.69 1.69) 405- S- 80 (0.83 1.65 1.73)
405— S— 81 (0.90 1.77 1.61) 405— S— 83 (0.94 0.95 2.43) 405— S— 85 (1.39 1.50 1.88) 405— S— 89 (1.36 2.13 1.25)405- S- 81 (0.90 1.77 1.61) 405- S- 83 (0.94 0.95 2.43) 405- S- 85 (1.39 1.50 1.88) 405- S- 89 (1.36 2.13 1.25)
405— S— 90 (1.27 1.98 1.40) 405— S— 101 (1.03 1.83 1.55) 405— S— 105 (1.19 0.93 2.45) 405— S— 107 (1.65 1.66 1.72)405-S-90 (1.27 1.98 1.40) 405-S-101 (1.03 1.83 1.55) 405-S-105 (1.19 0.93 2.45) 405-S-107 (1.65 1.66 1.72)
405— S— 108 (1.21 2.05 1.32) 405— S— 109 (1.45 2.19 1.19) 405— S— 110 (0.94 1.83 1.55) 405— S— 11 1 (1.64 0.95 2.43)405- S-108 (1.21 2.05 1.32) 405- S-109 (1.45 2.19 1.19) 405- S- 110 (0.94 1.83 1.55) 405- S- 11 1 (1.64 0.95 2.43)
405— S— 112 (0.84 1.33 2.05) 405— S— 113 (1.05 2.24 1.14) 405— S— 115 (1.32 1.80 1.58) 405— S— 118 (0.93 1.22 2.15)405- S-112 (0.84 1.33 2.05) 405- S-113 (1.05 2.24 1.14) 405- S- 115 (1.32 1.80 1.58) 405- S- 118 (0.93 1.22 2.15)
405— S— 119 (0.90 1.44 1.94) 405— S— 131 (0.95 0.90 2.48) 405— S— 132 (0.86 1.15 2.23) 405— S— 133 (1.65 1.95 1.42)405- S- 119 (0.90 1.44 1.94) 405- S- 131 (0.95 0.90 2.48) 405- S- 132 (0.86 1.15 2.23) 405- S- 133 (1.65 1.95 1.42)
405— S— 144 (0.99 1.86 1.51) 405— S— 150 (2.47 1.83 1.55) 405— S— 151 (2.38 2.09 1.29) 405— S— 152 (3.03 2.38 0.99)405- S- 144 (0.99 1.86 1.51) 405- S- 150 (2.47 1.83 1.55) 405- S- 151 (2.38 2.09 1.29) 405- S- 152 (3.03 2.38 0.99)
405— S— 153 (2.41 1.93 1.45) 405— S— 154 (1.94 1.06 2.32) 405— S— 166 (1.66 0.88 2.50) 405— S— 171 (1.43 0.88 2.50)405- S- 153 (2.41 1.93 1.45) 405- S- 154 (1.94 1.06 2.32) 405- S- 166 (1.66 0.88 2.50) 405- S- 171 (1.43 0.88 2.50)
405— S— 177 (1.49 1.61 1.77) 405— S— 183 (1.13 1.94 1.44) 405— S— 184 (2.22 1.42 1.96) 405— S— 188 (1.80 0.83 2.55)405-S-177 (1.49 1.61 1.77) 405-S-183 (1.13 1.94 1.44) 405-S-184 (2.22 1.42 1.96) 405-S-188 (1.80 0.83 2.55)
405— S— 192 (1.83 1.94 1.44) 405— S— 195 (1.65 1.26 2.1 1) 405— S— 198 (1.36 1.32 2.05) 405— S— 205 (0.88 1.38 1.99)405-S-192 (1.83 1.94 1.44) 405-S-195 (1.65 1.26 2.1 1) 405-S-198 (1.36 1.32 2.05) 405-S-205 (0.88 1.38 1.99)
405— S— 206 (0.88 2.30 1.08) 405— S— 207 (1.40 2.24 1.13) 405— S— 208 (0.85 0.86 2.52) 405— S— 213 (1.33 1.28 2.10)405- S- 206 (0.88 2.30 1.08) 405- S-207 (1.40 2.24 1.13) 405- S- 208 (0.85 0.86 2.52) 405- S- 213 (1.33 1.28 2.10)
405— S— 231 (1.87 2.05 1.33) 405— S— 233 (1.26 1.48 1.90) 405— S— 234 (1.08 1.56 1.82) 405— S— 237 (1.09 1.85 1.52)405-S-231 (1.87 2.05 1.33) 405-S-233 (1.26 1.48 1.90) 405-S-234 (1.08 1.56 1.82) 405-S-237 (1.09 1.85 1.52)
405— S— 244 (1.14 1.47 1.91) 405— S— 245 (1.06 1.24 2.14) 405— S— 246 (1.40 1.81 1.57) 405— S— 248 (1.46 2.36 1.02)405-S-244 (1.14 1.47 1.91) 405-S-245 (1.06 1.24 2.14) 405-S-246 (1.40 1.81 1.57) 405-S-248 (1.46 2.36 1.02)
405— S— 249 (0.94 2.20 1.18) 405— S— 251 (0.90 2.06 1.32) 405— S— 254 (0.90 1.17 2.21) 405— S— 255 (1.79 2.03 1.35) 405— S— 258 (0.85 2.47 0.91) 405— S— 260 (0.91 2.48 0.90) 405— S— 265 (1.36 1.95 1.43) 405— S— 266 (1.00 1.53 1.85)405- S- 249 (0.94 2.20 1.18) 405- S- 251 (0.90 2.06 1.32) 405- S- 254 (0.90 1.17 2.21) 405- S- 255 (1.79 2.03 1.35) 405- S- 258 (0.85 2.47 0.91) 405- S- 260 (0.91 2.48 0.90) 405- S- 265 (1.36 1.95 1.43) 405- S- 266 (1.00 1.53 1.85)
405— S— 268 (1.34 2.10 1.28) 405— S— 269 (1.30 2.03 1.35) 405— S— 271 (2.05 2.12 1.26) 405— S— 277 (0.88 1.30 2.08)405- S- 268 (1.34 2.10 1.28) 405- S- 269 (1.30 2.03 1.35) 405- S- 271 (2.05 2.12 1.26) 405- S- 277 (0.88 1.30 2.08)
405— S— 279 (0.94 1.36 2.02) 405— S— 286 (0.91 1.14 2.23) 405— S— 289 (0.97 0.93 2.45) 405— S— 290 (1.00 1.56 1.82)405-S-279 (0.94 1.36 2.02) 405-S-286 (0.91 1.14 2.23) 405-S-289 (0.97 0.93 2.45) 405-S-290 (1.00 1.56 1.82)
405— S— 291 (2.13 1.96 1.41) 405— S— 292 (1.47 1.62 1.75) 405— S— 293 (0.97 1.43 1.94) 405— S— 294 (1.42 1.47 1.91)405- S-291 (2.13 1.96 1.41) 405- S-292 (1.47 1.62 1.75) 405- S-293 (0.97 1.43 1.94) 405- S-294 (1.42 1.47 1.91)
405— S— 295 (1.18 1.71 1.67) 405— S— 296 (1.46 1.71 1.67) 405— S— 298 (1.03 1.31 2.07) 405— S— 304 (0.83 1.16 2.22)405- S-295 (1.18 1.71 1.67) 405- S-296 (1.46 1.71 1.67) 405- S- 298 (1.03 1.31 2.07) 405- S- 304 (0.83 1.16 2.22)
405— S— 305 (1.35 1.37 2.01) 405— S— 306 (1.51 2.03 1.35) 405— S— 307 (1.24 2.16 1.22) 405— S— 316 (0.83 1.37 2.01)405- S- 305 (1.35 1.37 2.01) 405- S- 306 (1.51 2.03 1.35) 405- S- 307 (1.24 2.16 1.22) 405- S- 316 (0.83 1.37 2.01)
405— S— 320 (1.73 2.45 0.93) 405— S— 327 (1.12 1.77 1.60) 405— S— 329 (1.45 2.23 1.15) 405— S— 331 (0.98 0.95 2.43)405- S- 320 (1.73 2.45 0.93) 405- S- 327 (1.12 1.77 1.60) 405- S- 329 (1.45 2.23 1.15) 405- S- 331 (0.98 0.95 2.43)
405— S— 332 (0.83 1.13 2.25) 405— S— 336 (0.93 1.02 2.36) 405— S— 342 (2.88 1.98 1.39) 405— S— 343 (3.41 2.48 0.90)405- S-332 (0.83 1.13 2.25) 405- S-336 (0.93 1.02 2.36) 405- S-342 (2.88 1.98 1.39) 405- S- 343 (3.41 2.48 0.90)
405— S— 367 (1.40 1.93 1.45) 405— S— 368 (1.51 2.47 0.91) 405— S— 371 (2.56 2.07 1.31) 405— S— 372 (0.97 1.06 2.32)405- S- 367 (1.40 1.93 1.45) 405- S- 368 (1.51 2.47 0.91) 405- S- 371 (2.56 2.07 1.31) 405- S- 372 (0.97 1.06 2.32)
405— S— 395 (1.59 1.77 1.61) 405— S— 396 (1.02 1.21 2.17) 405— S— 397 (0.82 1.06 2.32) 405— S— 437 (0.94 0.89 2.49)405-S-395 (1.59 1.77 1.61) 405-S-396 (1.02 1.21 2.17) 405-S-397 (0.82 1.06 2.32) 405-S-437 (0.94 0.89 2.49)
405— S— 440 (1.28 1.68 1.70) 405— S— 441 (1.21 1.61 1.77) 405— S— 447 (1.22 1.80 1.58) 405— S— 449 (0.96 1.76 1.61)405- S- 440 (1.28 1.68 1.70) 405- S- 441 (1.21 1.61 1.77) 405- S- 447 (1.22 1.80 1.58) 405- S- 449 (0.96 1.76 1.61)
405— S— 451 (1.30 2.38 1.00) 405— S— 452 (1.36 2.03 1.35) 405— S— 457 (0.81 1.68 1.70) 405— S— 460 (1.09 2.11 1.27)405- S- 451 (1.30 2.38 1.00) 405- S- 452 (1.36 2.03 1.35) 405- S- 457 (0.81 1.68 1.70) 405- S- 460 (1.09 2.11 1.27)
405— S— 463 (1.24 2.48 0.90) 405— S— 471 (1.39 1.34 2.04) 405— S— 473 (1.43 1.95 1.42) 405— S— 474 (1.29 1.84 1.54)405- S-463 (1.24 2.48 0.90) 405- S-471 (1.39 1.34 2.04) 405- S-473 (1.43 1.95 1.42) 405- S-474 (1.29 1.84 1.54)
425— S— 0 (1. 86 1.19 1.00) 425— S— 11 (1.08 0.97 1.22) 425— S— 20 (2.08 1.27 0.92) 425— S— 38 ( .44 0.87 1.32)425- S- 0 (1. 86 1.19 1.00) 425- S- 11 (1.08 0.97 1.22) 425- S- 20 (2.08 1.27 0.92) 425- S- 38 (.44 0.87 1.32)
425— S— 45 ( .1 1 1.08 1.1 1) 425— S— 47 (0.96 0.90 1.28) 425— S— 48 ( .03 0.93 1.25) 425— S— 56 ( .98 0.90 1.29)425- S- 45 (.1 1 1.08 1.1 1) 425- S- 47 (0.96 0.90 1.28) 425- S- 48 (.03 0.93 1.25) 425- S- 56 (.98 0.90 1.29)
425— S— 65 ( .98 1.21 0.98) 425— S— 68 (1.69 1.17 1.02) 425— S— 83 (2.02 0.84 1.35) 425— S— 96 ( .06 1.20 0.99)425- S- 65 (.98 1.21 0.98) 425- S- 68 (1.69 1.17 1.02) 425- S- 83 (2.02 0.84 1.35) 425- S- 96 (.06 1.20 0.99)
425— S— 105 (2.27 0.82 1.37) 425— S— 11 1 (2.73 0.84 1.34) 425— S— 112 (1.92 1.22 0.97) 425— S— 118 (2.01 1.12 1.07)425- S-105 (2.27 0.82 1.37) 425- S- 11 1 (2.73 0.84 1.34) 425- S-112 (1.92 1.22 0.97) 425- S-118 (2.01 1.12 1.07)
425— S— 132 (1.95 1.04 1.15) 425— S— 154 (3.02 0.95 1.24) 425— S— 193 (1.83 1.00 1.19) 425— S— 195 (2.74 1.16 1.03)425- S- 132 (1.95 1.04 1.15) 425- S- 154 (3.02 0.95 1.24) 425- S-193 (1.83 1.00 1.19) 425- S-195 (2.74 1.16 1.03)
425— S— 198 (2.45 1.22 0.97) 425— S— 205 (1.97 1.28 0.91) 425— S— 209 (1.68 0.83 1.36) 425— S— 21 1 (1.03 1.00 1.19)425- S- 198 (2.45 1.22 0.97) 425- S- 205 (1.97 1.28 0.91) 425- S-209 (1.68 0.83 1.36) 425- S- 21 1 (1.03 1.00 1.19)
425— S— 213 (2.42 1.18 1.01) 425— S— 217 (1.84 1.21 0.98) 425— S— 219 (1.61 0.94 1.25) 425— S— 228 (1.35 0.94 1.25)425- S- 213 (2.42 1.18 1.01) 425- S- 217 (1.84 1.21 0.98) 425- S- 219 (1.61 0.94 1.25) 425- S- 228 (1.35 0.94 1.25)
425— S— 245 (2.15 1.14 1.05) 425— S— 254 (1.98 1.06 1.13) 425— S— 267 (1.88 1.12 1.07) 425— S— 274 (1.75 0.92 1.26)425- S- 245 (2.15 1.14 1.05) 425- S- 254 (1.98 1.06 1.13) 425- S- 267 (1.88 1.12 1.07) 425- S-274 (1.75 0.92 1.26)
425— S— 277 (1.97 1.19 1.00) 425— S— 279 (2.02 1.25 0.93) 425— S— 280 (1.70 0.93 1.26) 425— S— 285 (1.75 1.14 1.05)425- S- 277 (1.97 1.19 1.00) 425- S- 279 (2.02 1.25 0.93) 425- S- 280 (1.70 0.93 1.26) 425- S- 285 (1.75 1.14 1.05)
425— S— 286 (2.00 1.04 1.15) 425— S— 287 (1.81 1.05 1.14) 425— S— 288 (1.79 0.99 1.20) 425— S— 289 (2.05 0.83 1.36)425- S-286 (2.00 1.04 1.15) 425- S-287 (1.81 1.05 1.14) 425- S- 288 (1.79 0.99 1.20) 425- S- 289 (2.05 0.83 1.36)
425— S— 298 (2.1 1 1.21 0.98) 425— S— 304 (1.92 1.05 1.14) 425— S— 305 (2.43 1.27 0.92) 425— S— 31 1 (1.75 0.94 1.25)425- S- 298 (2.1 1 1.21 0.98) 425- S- 304 (1.92 1.05 1.14) 425- S- 305 (2.43 1.27 0.92) 425- S- 31 1 (1.75 0.94 1.25)
425— S— 312 (1.85 0.81 1.38) 425— S— 313 (1.63 0.98 1.21) 425— S— 316 (1.92 1.27 0.92) 425— S— 319 (1.12 1.13 1.06)425- S-312 (1.85 0.81 1.38) 425- S-313 (1.63 0.98 1.21) 425- S-316 (1.92 1.27 0.92) 425- S-319 (1.12 1.13 1.06)
425— S— 325 (0.96 1.06 1.13) 425— S— 331 (2.07 0.85 1.34) 425— S— 332 (1.92 1.02 1.17) 425— S— 336 (2.02 0.91 1.28)425- S- 325 (0.96 1.06 1.13) 425- S- 331 (2.07 0.85 1.34) 425- S- 332 (1.92 1.02 1.17) 425- S- 336 (2.02 0.91 1.28)
425— S— 358 (1.86 1.19 1.00) 425— S— 370 (1.83 1.25 0.94) 425— S— 372 (2.06 0.95 1.23) 425— S— 373 (1.45 0.96 1.23)425- S- 358 (1.86 1.19 1.00) 425- S- 370 (1.83 1.25 0.94) 425- S- 372 (2.06 0.95 1.23) 425- S- 373 (1.45 0.96 1.23)
425— S— 379 (1.74 0.95 1.24) 425— S— 381 (1.31 1.12 1.07) 425— S— 382 (1.81 1.13 1.06) 425— S— 391 (1.75 0.94 1.25)425- S- 379 (1.74 0.95 1.24) 425- S-381 (1.31 1.12 1.07) 425- S-382 (1.81 1.13 1.06) 425- S- 391 (1.75 0.94 1.25)
425— S— 396 (2.1 1 1.11 1.08) 425— S— 397 (1.91 0.95 1.24) 425— S— 415 (1.80 0.83 1.36) 425— S— 419 (1.19 0.93 1.26)425- S- 396 (2.1 1 1.11 1.08) 425- S-397 (1.91 0.95 1.24) 425- S- 415 (1.80 0.83 1.36) 425- S- 419 (1.19 0.93 1.26)
425— S— 434 (1.76 1.24 0.95) 425— S— 455 (1.75 1.07 1.12) 425— S— 464 (0.80 1.25 0.94) 425— S— 467 (1.58 1.17 1.02)425- S- 434 (1.76 1.24 0.95) 425- S-455 (1.75 1.07 1.12) 425- S-464 (0.80 1.25 0.94) 425- S-467 (1.58 1.17 1.02)
425— S— 471 (2.47 1.24 0.95) 425— S— 475 (1.31 0.86 1.33) 425— S— 476 (0.99 0.89 1.30) 477— S— 0 (1 44 1.07 1.42)425- S-471 (2.47 1.24 0.95) 425- S-475 (1.31 0.86 1.33) 425- S-476 (0.99 0.89 1.30) 477- S- 0 (1 44 1.07 1.42)
477— S— 20 ( .66 1.16 1.34) 477— S— 27 (1.57 1.32 1.17) 477— S— 28 ( .64 1.59 0.90) 477— S— 29 ( .40 1.32 1.18)477- S- 20 (.66 1.16 1.34) 477- S- 27 (1.57 1.32 1.17) 477- S- 28 (.64 1.59 0.90) 477- S- 29 (.40 1.32 1.18)
477— S— 40 ( .22 1.31 1.18) 477— S— 46 (2.81 1.48 1.01) 477— S— 61 ( .55 1.30 1.19) 477— S— 62 ( .42 1.50 1.00)477- S- 40 (.22 1.31 1.18) 477- S- 46 (2.81 1.48 1.01) 477- S- 61 (.55 1.30 1.19) 477- S- 62 (.42 1.50 1.00)
477— S— 65 ( .56 1.09 1.40) 477— S— 68 (1.27 1.06 1.44) 477— S— 79 ( .54 1.47 1.02) 477— S— 80 ( .49 1.43 1.07)477- S- 65 (.56 1.09 1.40) 477- S- 68 (1.27 1.06 1.44) 477- S- 79 (.54 1.47 1.02) 477- S- 80 (.49 1.43 1.07)
477— S— 81 ( .57 1.55 0.94) 477— S— 85 (2.06 1.28 1.21) 477— S— 107 (2.32 1.44 1.05) 477— S— 112 (1.50 1.11 1.39)477- S- 81 (.57 1.55 0.94) 477- S- 85 (2.06 1.28 1.21) 477- S-107 (2.32 1.44 1.05) 477- S-112 (1.50 1.11 1.39)
477— S— 115 (1.98 1.58 0.91) 477— S— 118 (1.59 1.00 1.49) 477— S— 119 (1.56 1.22 1.27) 477— S— 123 (1.20 1.35 1.15)477- S-115 (1.98 1.58 0.91) 477- S-118 (1.59 1.00 1.49) 477- S-119 (1.56 1.22 1.27) 477- S-123 (1.20 1.35 1.15)
477— S— 132 (1.53 0.93 1.57) 477— S— 147 (1.06 1.22 1.27) 477— S— 154 (2.60 0.84 1.66) 477— S— 177 (2.15 1.39 1.1 1)477- S- 132 (1.53 0.93 1.57) 477- S- 147 (1.06 1.22 1.27) 477- S- 154 (2.60 0.84 1.66) 477- S-177 (2.15 1.39 1.1 1)
477— S— 184 (2.89 1.20 1.29) 477— S— 193 (1.41 0.88 1.61) 477— S— 195 (2.32 1.04 1.45) 477— S— 198 (2.03 1.10 1.39)477- S-184 (2.89 1.20 1.29) 477- S-193 (1.41 0.88 1.61) 477- S-195 (2.32 1.04 1.45) 477- S-198 (2.03 1.10 1.39)
477— S— 205 (1.55 1.16 1.33) 477— S— 213 (2.00 1.06 1.43) 477— S— 217 (1.42 1.09 1.40) 477— S— 218 (1.39 1.27 1.22)477- S-205 (1.55 1.16 1.33) 477- S-213 (2.00 1.06 1.43) 477- S-217 (1.42 1.09 1.40) 477- S-218 (1.39 1.27 1.22)
477— S— 219 (1.19 0.83 1.67) 477— S— 228 (0.93 0.83 1.67) 477— S— 233 (1.92 1.26 1.24) 477— S— 234 (1.74 1.34 1.16)477- S-219 (1.19 0.83 1.67) 477- S-228 (0.93 0.83 1.67) 477- S-233 (1.92 1.26 1.24) 477- S-234 (1.74 1.34 1.16)
477— S— 238 (1.05 1.49 1.00) 477— S— 244 (1.81 1.25 1.24) 477— S— 245 (1.73 1.02 1.47) 477— S— 246 (2.06 1.59 0.90)477- S-238 (1.05 1.49 1.00) 477- S-244 (1.81 1.25 1.24) 477- S-245 (1.73 1.02 1.47) 477- S-246 (2.06 1.59 0.90)
477— S— 254 (1.56 0.95 1.55) 477— S— 266 (1.66 1.31 1.19) 477— S— 267 (1.46 1.01 1.49) 477— S— 274 (1.33 0.81 1.68)477- S-254 (1.56 0.95 1.55) 477- S-266 (1.66 1.31 1.19) 477- S-267 (1.46 1.01 1.49) 477- S-274 (1.33 0.81 1.68)
477— S— 275 (1.14 1.23 1.26) 477— S— 277 (1.55 1.08 1.42) 477— S— 279 (1.60 1.14 1.36) 477— S— 280 (1.28 0.82 1.68)477- S-275 (1.14 1.23 1.26) 477- S-277 (1.55 1.08 1.42) 477- S-279 (1.60 1.14 1.36) 477- S- 280 (1.28 0.82 1.68)
477— S— 285 (1.33 1.02 1.47) 477— S— 286 (1.58 0.92 1.57) 477— S— 287 (1.39 0.94 1.56) 477— S— 288 (1.37 0.87 1.62)477- S-285 (1.33 1.02 1.47) 477- S-286 (1.58 0.92 1.57) 477- S-287 (1.39 0.94 1.56) 477- S-288 (1.37 0.87 1.62)
477— S— 290 (1.66 1.34 1.15) 477— S— 292 (2.13 1.40 1.09) 477— S— 293 (1.64 1.21 1.28) 477— S— 294 (2.09 1.25 1.25)477- S-290 (1.66 1.34 1.15) 477- S-292 (2.13 1.40 1.09) 477- S-293 (1.64 1.21 1.28) 477- S-294 (2.09 1.25 1.25)
477— S— 295 (1.84 1.49 1.00) 477— S— 296 (2.12 1.49 1.01) 477— S— 298 (1.69 1.09 1.40) 477— S— 299 (0.95 1.43 1.06)477- S-295 (1.84 1.49 1.00) 477- S-296 (2.12 1.49 1.01) 477- S-298 (1.69 1.09 1.40) 477- S-299 (0.95 1.43 1.06)
477— S— 304 (1.50 0.94 1.56) 477— S— 305 (2.01 1.15 1.34) 477— S— 31 1 (1.33 0.82 1.67) 477— S— 313 (1.21 0.86 1.63)477- S-304 (1.50 0.94 1.56) 477- S-305 (2.01 1.15 1.34) 477- S- 31 1 (1.33 0.82 1.67) 477- S-313 (1.21 0.86 1.63)
477— S— 316 (1.50 1.15 1.34) 477— S— 327 (1.79 1.55 0.94) 477— S— 332 (1.50 0.91 1.59) 477— S— 341 (1.10 1.42 1.07)477- S-316 (1.50 1.15 1.34) 477- S-327 (1.79 1.55 0.94) 477- S-332 (1.50 0.91 1.59) 477- S-341 (1.10 1.42 1.07)
477— S— 358 (1.44 1.07 1.42) 477— S— 370 (1.41 1.14 1.36) 477— S— 372 (1.64 0.84 1.66) 477— S— 373 (1.03 0.84 1.65)477- S-358 (1.44 1.07 1.42) 477- S-370 (1.41 1.14 1.36) 477- S-372 (1.64 0.84 1.66) 477- S-373 (1.03 0.84 1.65)
477— S— 374 (1.25 1.33 1.16) 477— S— 379 (1.32 0.83 1.66) 477— S— 381 (0.89 1.00 1.49) 477— S— 382 (1.39 1.02 1.48)477- S-374 (1.25 1.33 1.16) 477- S-379 (1.32 0.83 1.66) 477- S-381 (0.89 1.00 1.49) 477- S-382 (1.39 1.02 1.48)
477— S— 391 (1.33 0.82 1.67) 477— S— 395 (2.26 1.55 0.94) 477— S— 396 (1.69 0.99 1.50) 477— S— 397 (1.49 0.84 1.66)477- S-391 (1.33 0.82 1.67) 477- S-395 (2.26 1.55 0.94) 477- S-396 (1.69 0.99 1.50) 477- S-397 (1.49 0.84 1.66)
477— S— 434 (1.34 1.13 1.37) 477— S— 435 (1.42 1.29 1.20) 477— S— 440 (1.95 1.46 1.03) 477— S— 441 (1.88 1.39 1.10)477- S-434 (1.34 1.13 1.37) 477- S-435 (1.42 1.29 1.20) 477- S-440 (1.95 1.46 1.03) 477- S-441 (1.88 1.39 1.10)
477— S— 447 (1.89 1.58 0.92) 477— S— 449 (1.63 1.54 0.95) 477— S— 450 (1.25 1.21 1.28) 477— S— 455 (1.33 0.95 1.54)477- S- 447 (1.89 1.58 0.92) 477- S- 449 (1.63 1.54 0.95) 477- S- 450 (1.25 1.21 1.28) 477- S-455 (1.33 0.95 1.54)
477— S— 457 (1.47 1.46 1.04) 477— S— 458 (1.02 1.25 1.24) 477— S— 467 (1.16 1.06 1.44) 477— S— 468 (1.35 1.36 1.13)477- S-457 (1.47 1.46 1.04) 477- S-458 (1.02 1.25 1.24) 477- S-467 (1.16 1.06 1.44) 477- S-468 (1.35 1.36 1.13)
477— S— 471 (2.05 1.12 1.37) 477— S— 482 (0.98 1.23 1.26) 477— S— 483 (1.03 1.31 1.19) 478— S— 0 (1.51 1.12 1.36)477- S- 471 (2.05 1.12 1.37) 477- S- 482 (0.98 1.23 1.26) 477- S-483 (1.03 1.31 1.19) 478- S- 0 (1.51 1.12 1.36)
478— S— 20 ( .72 1.20 1.27) 478— S— 29 (1.46 1.36 1.1 1) 478— S— 40 ( .28 1.36 1.1 1) 478— S— 46 (2.87 1.53 0.95)478- S- 20 (.72 1.20 1.27) 478- S- 29 (1.46 1.36 1.1 1) 478- S- 40 (.28 1.36 1.1 1) 478- S-46 (2.87 1.53 0.95)
478— S— 56 ( .63 0.83 1.64) 478— S— 61 (1.61 1.34 1.13) 478— S— 62 ( .49 1.54 0.93) 478— S— 65 (1.62 1.14 1.33) 478— S— 68 (1.33 1.10 1.37) 478— S— 79 (1.61 1.52 0.96) 478— S— 80 ( .56 1.47 1.00) 478— S— 85 (2.12 1.33 1.15)478- S- 56 (.63 0.83 1.64) 478- S- 61 (1.61 1.34 1.13) 478- S- 62 (.49 1.54 0.93) 478- S- 65 (1.62 1.14 1.33) 478- S- 68 (1.33 1.10 1.37) 478- S- 79 (1.61 1.52 0.96) 478- S- 80 (.56 1.47 1.00) 478- S- 85 (2.12 1.33 1.15)
478 — S — 107 (2.38 1.49 0.99) 478 — S — 112 (1.57 1.15 1.32) 478 — S — 118 (1.66 1.05 1.42) 478 — S — 119 (1.63 1.26 1.21)478 - S - 107 (2.38 1.49 0.99) 478 - S - 112 (1.57 1.15 1.32) 478 - S - 118 (1.66 1.05 1.42) 478 - S - 119 (1.63 1.26 1.21)
478 — S — 123 (1.27 1.39 1.08) 478 — S — 132 (1.59 0.97 1.50) 478 — S — 147 (1.12 1.26 1.21) 478 — S — 154 (2.67 0.88 1.59)478 - S - 123 (1.27 1.39 1.08) 478 - S - 132 (1.59 0.97 1.50) 478 - S - 147 (1.12 1.26 1.21) 478 - S - 154 (2.67 0.88 1.59)
478 — S — 177 (2.22 1.43 1.04) 478 — S — 184 (2.95 1.24 1.23) 478 — S — 193 (1.48 0.93 1.55) 478 — S — 195 (2.38 1.09 1.38)478 - S - 177 (2.22 1.43 1.04) 478 - S - 184 (2.95 1.24 1.23) 478 - S - 193 (1.48 0.93 1.55) 478 - S - 195 (2.38 1.09 1.38)
478 — S — 198 (2.09 1.15 1.32) 478 — S — 205 (1.61 1.21 1.26) 478 — S — 213 (2.06 1.10 1.37) 478 — S — 217 (1.48 1.14 1.34)478 - S - 198 (2.09 1.15 1.32) 478 - S - 205 (1.61 1.21 1.26) 478 - S - 213 (2.06 1.10 1.37) 478 - S - 217 (1.48 1.14 1.34)
478 — S — 218 (1.45 1.31 1.16) 478 — S — 219 (1.26 0.87 1.60) 478 — S — 228 (1.00 0.87 1.60) 478 — S — 233 (1.99 1.30 1.17)478 - S - 218 (1.45 1.31 1.16) 478 - S - 219 (1.26 0.87 1.60) 478 - S - 228 (1.00 0.87 1.60) 478 - S - 233 (1.99 1.30 1.17)
478 — S — 234 (1.81 1.38 1.09) 478 — S — 238 (1.12 1.54 0.94) 478 — S — 244 (1.87 1.29 1.18) 478 — S — 245 (1.79 1.07 1.41)478 - S - 234 (1.81 1.38 1.09) 478 - S - 238 (1.12 1.54 0.94) 478 - S - 244 (1.87 1.29 1.18) 478 - S - 245 (1.79 1.07 1.41)
478 — S — 254 (1.63 0.99 1.48) 478 — S — 266 (1.73 1.35 1.12) 478 — S — 267 (1.53 1.05 1.42) 478 — S — 274 (1.39 0.85 1.62)478 - S - 254 (1.63 0.99 1.48) 478 - S - 266 (1.73 1.35 1.12) 478 - S - 267 (1.53 1.05 1.42) 478 - S - 274 (1.39 0.85 1.62)
478 — S — 275 (1.20 1.27 1.20) 478 — S — 277 (1.61 1.12 1.35) 478 — S — 279 (1.67 1.18 1.29) 478 — S — 280 (1.35 0.86 1.61)478 - S - 275 (1.20 1.27 1.20) 478 - S - 277 (1.61 1.12 1.35) 478 - S - 279 (1.67 1.18 1.29) 478 - S - 280 (1.35 0.86 1.61)
478 — S — 285 (1.39 1.07 1.41) 478 — S — 286 (1.64 0.97 1.50) 478 — S — 287 (1.45 0.98 1.49) 478 — S — 288 (1.44 0.92 1.55)478 - S - 285 (1.39 1.07 1.41) 478 - S - 286 (1.64 0.97 1.50) 478 - S - 287 (1.45 0.98 1.49) 478 - S - 288 (1.44 0.92 1.55)
478 — S — 290 (1.73 1.38 1.09) 478 — S — 292 (2.20 1.45 1.02) 478 — S — 293 (1.70 1.26 1.21) 478 — S — 294 (2.15 1.29 1.18)478 - S - 290 (1.73 1.38 1.09) 478 - S - 292 (2.20 1.45 1.02) 478 - S - 293 (1.70 1.26 1.21) 478 - S - 294 (2.15 1.29 1.18)
478 — S — 295 (1.91 1.53 0.94) 478 — S — 296 (2.19 1.53 0.94) 478 — S — 298 (1.76 1.14 1.34) 478 — S — 299 (1.01 1.48 1.00)478 - S - 295 (1.91 1.53 0.94) 478 - S - 296 (2.19 1.53 0.94) 478 - S - 298 (1.76 1.14 1.34) 478 - S - 299 (1.01 1.48 1.00)
478 — S — 304 (1.56 0.98 1.49) 478 — S — 305 (2.08 1.20 1.28) 478 — S — 31 1 (1.40 0.87 1.60) 478 — S — 313 (1.27 0.91 1.56)478 - S - 304 (1.56 0.98 1.49) 478 - S - 305 (2.08 1.20 1.28) 478 - S - 31 1 (1.40 0.87 1.60) 478 - S - 313 (1.27 0.91 1.56)
478 — S — 316 (1.56 1.20 1.28) 478 — S — 332 (1.56 0.95 1.52) 478 — S — 336 (1.66 0.84 1.63) 478 — S — 341 (1.16 1.47 1.00)478 - S - 316 (1.56 1.20 1.28) 478 - S - 332 (1.56 0.95 1.52) 478 - S - 336 (1.66 0.84 1.63) 478 - S - 341 (1.16 1.47 1.00)
478 — S — 358 (1.51 1.12 1.36) 478 — S — 370 (1.48 1.18 1.29) 478 — S — 372 (1.70 0.88 1.59) 478 — S — 373 (1.09 0.89 1.59)478 - S - 358 (1.51 1.12 1.36) 478 - S - 370 (1.48 1.18 1.29) 478 - S - 372 (1.70 0.88 1.59) 478 - S - 373 (1.09 0.89 1.59)
478 — S — 374 (1.31 1.38 1.10) 478 — S — 379 (1.39 0.88 1.59) 478 — S — 381 (0.96 1.05 1.42) 478 — S — 382 (1.46 1.06 1.41)478 - S - 374 (1.31 1.38 1.10) 478 - S - 379 (1.39 0.88 1.59) 478 - S - 381 (0.96 1.05 1.42) 478 - S - 382 (1.46 1.06 1.41)
478 — S — 391 (1.40 0.87 1.61) 478 — S — 396 (1.75 1.04 1.44) 478 — S — 397 (1.55 0.88 1.59) 478 — S — 419 (0.84 0.86 1.61)478 - S - 391 (1.40 0.87 1.61) 478 - S - 396 (1.75 1.04 1.44) 478 - S - 397 (1.55 0.88 1.59) 478 - S - 419 (0.84 0.86 1.61)
478 — S — 434 (1.40 1.17 1.30) 478 — S — 435 (1.49 1.34 1.13) 478 — S — 440 (2.01 1.51 0.97) 478 — S — 441 (1.94 1.43 1.04)478 - S - 434 (1.40 1.17 1.30) 478 - S - 435 (1.49 1.34 1.13) 478 - S - 440 (2.01 1.51 0.97) 478 - S - 441 (1.94 1.43 1.04)
478 — S — 450 (1.31 1.26 1.22) 478 — S — 455 (1.39 1.00 1.48) 478 — S — 457 (1.54 1.50 0.97) 478 — S — 458 (1.08 1.30 1.18)478 - S - 450 (1.31 1.26 1.22) 478 - S - 455 (1.39 1.00 1.48) 478 - S - 457 (1.54 1.50 0.97) 478 - S - 458 (1.08 1.30 1.18)
478 — S — 467 (1.22 1.10 1.37) 478 — S — 468 (1.42 1.41 1.07) 478 — S — 471 (2.12 1.17 1.31) 478 — S — 482 (1.05 1.28 1.19)478 - S - 467 (1.22 1.10 1.37) 478 - S - 468 (1.42 1.41 1.07) 478 - S - 471 (2.12 1.17 1.31) 478 - S - 482 (1.05 1.28 1.19)
478 — S — 483 (1.09 1.35 1.12) 478 - S - 483 (1.09 1.35 1.12)
17 - - S - - 38 (0.89 1.22 1.55) 23 - - S - - 38 (0.87 1.29 1.57) 26 - - S - - 38 (0.97 1.07 1.47) 17 - - S - - 38 (0.89 1.22 1.55) 23 - - S - - 38 (0.87 1.29 1.57) 26 - - S - - 38 (0.97 1.07 1.47)
41 - - S - - 38 (0.89 1.18 1.55) 124 — S — 82 (0.85 0.87 3.06) 137 — S — 3i 3 (0.84 0.93 1.59) 355— S— 38 (1.38 1.26 1.06) 41 - - S - - 38 (0.89 1.18 1.55) 124 - S - 82 (0.85 0.87 3.06) 137 - S - 3i 3 (0.84 0.93 1.59) 355- S- 38 (1.38 1.26 1.06)
385 — S — 38 (0.90 1.17 1.53) 386 — S — 38 (0.88 0.89 1.55) 390 — S — 3i 3 (0.95 0.90 1.48) 413— S— 38 (1.18 1.41 1.26)385 - S - 38 (0.90 1.17 1.53) 386 - S - 38 (0.88 0.89 1.55) 390 - S - 3i 3 (0.95 0.90 1.48) 413- S-38 (1.18 1.41 1.26)
413 — s — 53 (0.84 0.91 1.75) 413 — S — 149 (0.85 0.85 1.82) 414 — S — 3i i (1.19 1.96 1.24) 414— S— 53 (0.85 1.46 1.74)413 - s - 53 (0.84 0.91 1.75) 413 - S - 149 (0.85 0.85 1.82) 414 - S - 3i i (1.19 1.96 1.24) 414- S- 53 (0.85 1.46 1.74)
414 — s — 71 (0.88 1.17 2.03) 414 — S — 96 (0.82 1.17 2.04) 414 — S — 9! i (0.95 1.33 1.87) 414— S— 149 (0.86 1.40 1.81)414 - s - 71 (0.88 1.17 2.03) 414 - S - 96 (0.82 1.17 2.04) 414 - S - 9! i (0.95 1.33 1.87) 414- S-149 (0.86 1.40 1.81)
414 — s — 354 (0.81 1.13 2.07) 425 — S — 38 (1.44 1.1 1 1.00) 428 — S — 3i i (1.18 1.20 1.26) 414 - s - 354 (0.81 1.13 2.07) 425 - S - 38 (1.44 1.1 1 1.00) 428 - S - 3i i (1.18 1.20 1.26)
In einer Ausführungsform werden an die chemisch substituierbaren Positionen der so erhaltenen organischen Moleküle weitere Reste R angefügt, um die Löslichkeit der Emitter zu steigern und/oder die Polymerisierbarkeit zu ermöglichen ohne dabei die elektronischen Eigenscahften des Moleküls signifikant zu verändern, so dass auch bei Verwendung von R ein Emitter vorliegt, wobei In one embodiment, further residues R are added to the chemically substitutable positions of the organic molecules so obtained in order to increase the solubility of the emitters and / or to allow the polymerizability without significantly changing the electronic properties of the molecule, so that even when using R is an emitter, where
jedes R und bei jedem Auftreten gleich oder verschieden ist H, Deuterium, F, Cl, Br, I, N(R2)2, CN, CF3, N02, OH, COOH, COOR2, CO(NR2)2, Si(R2)3, B(OR2)2, C(=0)R2, P(=0)(R2)2, S(=0)R2, S(=0)2R2, OS02R2, eine lineare Alkyl-, Alkoxy- oder Thioalkoxygruppe mit 1 bis 40 C-Atomen oder eine lineare Alkenyl- oder Alkinylgruppe mit 2 bis 40 C-Atomen oder eine verzweigte oder cyclische Alkyl-, Alkenyl-, Alkinyl-, Alkoxy- oder Thioalkoxygruppe mit 3 bis 40 C-Atomen, die jeweils mit einem oder mehreren Resten R2 substituiert sein kann, wobei eine oder mehrere nicht benachbarte CH2-Gruppen durch R2C=CR2, C=C, Si(R2)2, Ge(R2)2, Sn(R2)2, C=0, C=S, C=Se, C=NR2, P(=0)(R2), SO, S02, NR2, O, S oder CONR2 ersetzt sein können und wobei ein oder mehrere H-Atome durch Deuterium, F, Cl, Br, I, CN, CF3 oder N02 ersetzt sein können, oder ein aromatisches oder heteroaromatisches Ringsystem mit 5 bis 60 aromatischen Ringatomen, das jeweils durch einen oder mehrere Reste R2 substituiert sein kann, oder eine Aryloxy- oder Heteroaryloxygruppe mit 5 bis 60 aromatischen Ringatomen, die durch einen oder mehrere Reste R2 substituiert sein kann, oder eine Diarylaminogruppe, Diheteroarylaminogruppe oder Arylheteroarylaminogruppe mit 10 bis 40 aromatischen Ringatomen, welche durch einen oder mehrere Reste R2 substituiert sein kann, oder eine Kombination dieser Systeme; dabei können zwei oder mehrere dieser Substituenten R1 auch miteinander ein mono- oder polycyclisches, aliphatisches, aromatisches und/oder benzoannelliertes Ringsystem bilden; each R and the same or different occurrence is H, Deuterium, F, Cl, Br, I, N (R 2 ) 2 , CN, CF 3 , NO 2 , OH, COOH, COOR 2 , CO (NR 2 ) 2 , Si (R 2 ) 3 , B (OR 2 ) 2 , C (= O) R 2 , P (= O) (R 2 ) 2 , S (= O) R 2 , S (= O) 2 R 2 , OSO 2 R 2 , a linear alkyl, alkoxy or thioalkoxy group having 1 to 40 C atoms or a linear alkenyl or alkynyl group having 2 to 40 C atoms or a branched or cyclic alkyl, alkenyl, alkynyl, Alkoxy or Thioalkoxygruppe having 3 to 40 carbon atoms, each of which may be substituted with one or more radicals R 2 , wherein one or more non-adjacent CH 2 groups by R 2 C = CR 2 , C = C, Si (R 2 ) 2 , Ge (R 2 ) 2 , Sn (R 2 ) 2 , C = O, C = S, C = Se, C = NR 2 , P (= O) (R 2 ), SO, S0 2 , NR 2 , O, S or CONR 2 can be replaced and wherein one or more H atoms can be replaced by deuterium, F, Cl, Br, I, CN, CF 3 or NO 2 , or an aromatic or heteroaromatic ring system with 5 up to 60 aromatic ring atoms, the dur ch is one or more radicals R 2 may be substituted, or an aryloxy or heteroaryloxy group having 5 to 60 aromatic ring atoms which may be substituted by one or more radicals R 2 , or a Diarylaminogruppe, Diheteroarylaminogruppe or Arylheteroarylaminogruppe having 10 to 40 aromatic ring atoms, which may be substituted by one or more radicals R 2 , or a combination of these systems; two or more of these substituents R 1 may also together form a mono- or polycyclic, aliphatic, aromatic and / or benzoannellated ring system;
R2 bei jedem Auftreten gleich oder verschieden ist H, Deuterium, F, Cl, Br, I, N(R3)2, CN, CF3, N02, OH, COOH, COOR3, CO(NR3)2, Si(R3)3, B(OR3)2, C(=0)R3, P(=0)(R3)2, S(=0)R3, S(=0)2R3, OS02R3, eine lineare Alkyl-, Alkoxy- oder Thioalkoxygruppe mit 1 bis 40 C- Atomen oder eine lineare Alkenyl- oder Alkinylgruppe mit 2 bis 40 C-Atomen oder eine verzweigte oder cyclische Alkyl-, Alkenyl-, Alkinyl-, Alkoxy- oder Thioalkoxygruppe mit 3 bis 40 C-Atomen, die jeweils mit einem oder mehreren Resten R3 substituiert sein kann, wobei eine oder mehrere nicht benachbarte CH2-Gruppen durch R3C=CR3, C=C, Si(R3)2, Ge(R3)2, Sn(R3)2, C=0, C=S, C=Se, C=NR3, P(=0)(R3), SO, S02, NR3, O, S oder CONR3 ersetzt sein können und wobei ein oder mehrere H-Atome durch Deuterium, F, Cl, Br, I, CN, CF3 oder N02 ersetzt sein können, oder ein aromatisches oder heteroaromatisches Ringsystem mit 5 bis 60 aromatischen Ringatomen, das jeweils durch einen oder mehrere Reste R3 substituiert sein kann, oder eine Aryloxy- oder Heteroaryloxygruppe mit 5 bis 60 aromatischen Ringatomen, die durch einen oder mehrere Reste R3 substituiert sein kann, oder eine Diarylaminogruppe, Diheteroarylaminogruppe oder Arylheteroarylaminogruppe mit 10 bis 40 aromatischen Ringatomen, welche durch einen oder mehrere Reste R3 substituiert sein kann, oder eine Kombination dieser Systeme; dabei können zwei oder mehrere dieser Substituenten R2 auch miteinander ein mono- oder polycyclisches, aliphatisches, aromatisches und/oder benzoannelliertes Ringsystem bilden; R 2 is the same or different at each occurrence, is H, deuterium, F, Cl, Br, I, N (R 3 ) 2 , CN, CF 3 , NO 2 , OH, COOH, COOR 3 , CO (NR 3 ) 2 , Si (R 3 ) 3 , B (OR 3 ) 2 , C (= O) R 3 , P (= O) (R 3 ) 2 , S (= O) R 3 , S (= O) 2 R 3 , OSO 2 R 3 , a linear alkyl, alkoxy or thioalkoxy group having 1 to 40 C atoms or a linear alkenyl or alkynyl group having 2 to 40 C atoms or a branched or cyclic alkyl, alkenyl, alkynyl, alkoxy or thioalkoxy group having 3 to 40 carbon atoms, each of which may be substituted with one or more R 3 radicals, wherein one or more non-adjacent CH 2 groups is represented by R 3 C = CR 3 , C = C, Si (R 3 ) 2 , Ge (R 3 ) 2 , Sn (R 3 ) 2 , C = O, C = S, C = Se, C = NR 3 , P (= O) (R 3 ), SO, SO 2 , NR 3 , O, S or CONR 3 can be replaced and wherein one or more H atoms can be replaced by deuterium, F, Cl, Br, I, CN, CF 3 or N0 2 , or an aromatic or heteroaromatic ring system with 5 bis 60 aromatic ring atoms, each by a n or more radicals R 3 may be substituted, or an aryloxy or heteroaryloxy group having 5 to 60 aromatic ring atoms which may be substituted by one or more radicals R 3 , or a Diarylaminogruppe, Diheteroarylaminogruppe or Arylheteroarylaminogruppe 10 to 40 aromatic ring atoms, which may be substituted by one or more radicals R 3 , or a combination of these systems; two or more of these substituents R 2 may also together form a mono- or polycyclic, aliphatic, aromatic and / or benzoannellated ring system;
R3 bei jedem Auftreten gleich oder verschieden ist H, Deuterium, F, CF3 oder ein aliphatischer, aromatischer und/oder heteroaromatischer Kohlenwasserstoffrest mit 1 bis 20 C-Atomen, in dem auch ein oder mehrere H-Atome durch F oder CF3 ersetzt sein können; dabei können zwei oder mehrere Substituenten R3 auch miteinander ein mono- oder polycyclisches, aliphatisches Ringsystem bilden. R 3 in each occurrence is identical or different H, deuterium, F, CF 3 or an aliphatic, aromatic and / or heteroaromatic hydrocarbon radical having 1 to 20 carbon atoms, in which one or more H atoms replaced by F or CF 3 could be; two or more substituents R 3 may also together form a mono- or polycyclic, aliphatic ring system.
Polymerisierbare Reste sind solche Reste, die polymerisierbare funktionelle Einheiten tragen, die mit sich selbst homopolymerisiert oder mit anderen Monomeren copolymiersiert werden können. Somit können die erfindungsgemäßen Moleküle als Polymer mit folgenden Wiederholungseinheiten der Formeln 8 und 9 erhalten werden, die als Polymere in der lichtemittierenden Schicht des optoelektronischen Bauelements Verwendung finden können. Polymerizable radicals are those radicals which carry polymerizable functional units which can be homopolymerized with themselves or copolymerized with other monomers. Thus, the molecules of the invention can be obtained as a polymer having the following repeating units of the formulas 8 and 9, which can be used as polymers in the light-emitting layer of the optoelectronic component.
Figure imgf000066_0001
Figure imgf000066_0001
Formel 8 Formel 9 Formula 8 Formula 9
R ist dabei wie oben angegeben definiert. In Formel 8 und 9 stehen L1 und L2 für gleiche oder verschiedene Linkergruppen, die 0 bis 20, insbesondere 1 bis 15, oder 2 bis 10 Kohlenstoffatome aufweist, und wobei die gewellte Linie die Position kennzeichnet, über die die Linkergruppe an das organische Molekül der Formel 1 angebunden ist. In einer Ausführungsform weist die Linkergruppe L1 und/oder L2 eine Form -X-L3- auf, wobei X für O oder S steht und L3 für eine Linkergruppe ausgewählt aus der Gruppe aus einer substituierten und unsubstituierten Alkylengruppe (linear, verzweigt oder cyclisch) und einer substituierten und unsubstituierten Arylengruppe, insbesondere eine substituierte oder unsubstituierte Alkylengruppe mit 1 bis 10 Kohlenstoffatomen oder eine substituierte oder unsubstituierte Phenylengruppe, wobei auch Kombinationen möglich sind. In einer weiteren Ausführungsform weist die Linkergruppe L1 und/oder L2 eine Form -C(=0)0- auf. R ist bei jedem Auftreten unabhängig voneinander ausgewählt aus der Gruppe bestehend aus H, Deuterium, Phenyl, Naphthyl, F, CF3 oder ein aliphatischer, aromatischer und/oder heteroaromatischer Kohlenwasserstoffrest mit 1 bis 20 C-Atomen, in dem auch ein oder mehrere H-Atome durch F oder CF3 ersetzt sein können; dabei können zwei oder mehrere Substituenten R auch miteinander ein mono- oder polycyclisches, aliphatisches Ringsystem bilden, außerdem kann R sein: eine lineare Alkoxy- oder Thioalkoxygruppe mit 1 bis 40 C- Atomen oder eine lineare Alkenyl- oder Alkinylgruppe mit 2 bis 40 C-Atomen oder eine verzweigte oder cyclische Alkyl-, Alkenyl-, Alkinyl-, Alkoxy- oder Thioalkoxygruppe mit 3 bis 40 C-Atomen. R is defined as indicated above. In formulas 8 and 9, L1 and L2 represent the same or different linker groups having 0 to 20, especially 1 to 15, or 2 to 10 carbon atoms, and wherein the wavy line indicates the position by which the linker group bonds to the organic molecule of the Formula 1 is connected. In one embodiment, the linker group L1 and / or L2 has a form -X-L3-, where X is O or S and L3 is a linker group selected from the group consisting of a substituted and unsubstituted alkylene group (linear, branched or cyclic) and a substituted and unsubstituted arylene group, in particular a substituted or unsubstituted alkylene group having 1 to 10 carbon atoms or a substituted or unsubstituted phenylene group, whereby combinations are possible. In a further embodiment, the linker group L1 and / or L2 has a form -C (= O) O-. R is independently selected in each occurrence from the group consisting of H, deuterium, phenyl, naphthyl, F, CF 3 or an aliphatic, aromatic and / or heteroaromatic hydrocarbon radical having 1 to 20 carbon atoms, in which also one or more H Atoms can be replaced by F or CF 3 ; It can have two or more Substituents R can also form a mono- or polycyclic aliphatic ring system with one another, furthermore R can be: a linear alkoxy or thioalkoxy group with 1 to 40 C atoms or a linear alkenyl or alkinyl group with 2 to 40 C atoms or a branched or cyclic alkyl, alkenyl, alkynyl, alkoxy or thioalkoxy group having 3 to 40 carbon atoms.
Vorteilhafte Ausführungsformen der Wiederholungseinheiten sind Strukturen der Formeln 10 bis 15: Advantageous embodiments of the repeating units are structures of the formulas 10 to 15:
Figure imgf000067_0001
Figure imgf000067_0001
Formel 10 Formel 11 Formel 12 Formel 13 Formel 14 Formel 15 Formula 10 Formula 11 Formula 12 Formula 13 Formula 14 Formula 15
Zur Herstellung der Polymere, die die Wiederholungseinheiten gemäß Formel 10 bis 15 aufweisen, werden die polymerisierbaren funktionellen Einheiten über eine Linkergruppe der Formeln 16 bis 21 , die eine Hydroxyleinheit aufweisen, an ein organisches Molekül der Formel 1 angebunden und die daraus resultierenden Verbindungen mit sich selbst homopolymerisiert oder mit anderen geeigneten Monomeren copolymerisiert. For the preparation of the polymers having the repeating units according to formulas 10 to 15, the polymerisable functional units via a linker group of the formulas 16 to 21, which have a hydroxyl moiety, are attached to an organic molecule of the formula 1 and the resulting compounds with themselves homopolymerized or copolymerized with other suitable monomers.
Figure imgf000067_0002
Figure imgf000067_0002
Formel 16 Formel 17 Formel 18 Formel 19 Formel 20 Formel 21 Formula 16 Formula 17 Formula 18 Formula 19 Formula 20 Formula 21
Polymere, die eine Einheit gemäß Formel 8 oder Formel 9 aufweisen, können dabei entweder ausschließlich Wiederholungseinheiten mit einer Struktur der allgemeinen Formel 8 oder 9, oder Wiederholungseinheiten mit einer anderen Struktur aufweisen. Beispiele von Wiederholungseinheiten mit anderen Strukturen weisen Einheiten auf, die sich aus entsprechenden Monomeren ergeben, die typischerweise in Copolymerisationen eingesetzt oder verwendet werden. Beispiele für derartige Wiederholungseinheiten, die sich aus Monomeren ergeben, sind Wiederholungseinheiten, die ungesättigte Einheiten wie Ethylen oder Styrol aufweisen. Polymers having a unit according to formula 8 or formula 9 can either exclusively comprise repeat units having a structure of general formula 8 or 9, or repeat units having a different structure. Examples of repeat units having other structures include moieties resulting from corresponding monomers typically used or used in copolymerizations. Examples of such repeating units, which consist of Monomers are repeating units having unsaturated moieties such as ethylene or styrene.
Eine Ausführungsform der Erfindung betrifft organischen Moleküle, welche One embodiment of the invention relates to organic molecules which
- einen AE(Si-T"i)-Wert zwischen dem untersten angeregten Singulett (Si)- und dem darunter liegenden Triplett (T-i)-Zustand von kleiner als 0,2 eV, insbesondere kleiner als 0, 1 eV aufweisen und/oder  have an AE (Si-T "i) value between the lowest excited singlet (Si) and the underlying triplet (T-i) state of less than 0.2 eV, in particular less than 0.1 eV, and / or
- eine Emissionslebensdauer von höchstens 50 ps aufweisen.  - have an emission lifetime of 50 ps or less.
Die Erfindung betrifft in einem Aspekt die Verwendung eines erfindungsgemäßen organischen Moleküls als lumineszierender Emitter und/oder als Hostmaterial und/oder als Elektronentransportmaterial und/oder als Lochinjektionsmaterial und/oder als Lochblockiermaterial in einem optoelektronischen Bauelement, das insbesondere durch ein Vakuumverdampfungsverfahren oder aus Lösung hergestellt wird, wobei das optoelektronische Bauelement insbesondere ausgewählt ist aus der Gruppe bestehend aus: The invention relates in one aspect to the use of an organic molecule according to the invention as a luminescent emitter and / or as a host material and / or as an electron transport material and / or as a hole injection material and / or as a hole blocking material in an optoelectronic component, which is produced in particular by a vacuum evaporation method or from solution , wherein the optoelectronic component is in particular selected from the group consisting of:
- organischen lichtemittierenden Dioden (OLEDs),  organic light emitting diodes (OLEDs),
- lichtemittierenden elektrochemischen Zellen,  light-emitting electrochemical cells,
- OLED-Sensoren, insbesondere in nicht hermetisch nach außen abgeschirmten Gas- und Dampf-Sensoren,  - OLED sensors, in particular in non-hermetically shielded gas and vapor sensors,
- organischen Dioden  - organic diodes
- organischen Solarzellen,  - organic solar cells,
- organischen Transistoren,  organic transistors,
- organischen Feldeffekttransistoren,  organic field effect transistors,
- organischen Lasern und  - organic lasers and
- Down-Konversions-Elementen.  - Down conversion elements.
Der Anteil des erfindungsgemäßen organischen Moleküls am lumineszierenden Emitter und/oder Hostmaterial und/oder Elektronentransportmaterial und/oder Lochinjektionsmaterial und/oder Lochblockiermaterial beträgt in einer Ausführungsform 1 % bis 99 % (Gew%), insbesondere beträgt der Anteil am Emitter in optischen Licht emittierenden Bauelementen, insbesondere in OLEDs, zwischen 5 % und 80 %. The proportion of the organic molecule according to the invention on the luminescent emitter and / or host material and / or electron transport material and / or hole injection material and / or hole blocking material in one embodiment is 1% to 99% (wt%), in particular the proportion of the emitter in optical light-emitting components especially in OLEDs, between 5% and 80%.
Die Erfindung betrifft in einem weiteren Aspekt optoelektronische Bauelemente, aufweisend ein erfindungsgemäßes organisches Molekül, wobei das optoelektronische Bauelement insbesondere ausgeformt ist als ein Bauelement ausgewählt aus der Gruppe bestehend aus organischer lichtemittierender Diode (OLED), Licht-emittierender elektrochemischer Zelle, OLED-Sensor, insbesondere in nicht hermetisch nach außen abgeschirmten Gas- und Dampf-Sensoren, organischer Diode, organischer Solarzelle, organischem Transistor, organischem Feldeffekttransistor, organischem Laser und Down-Konversion-Element. In a further aspect, the invention relates to optoelectronic components comprising an organic molecule according to the invention, wherein the optoelectronic component is in particular formed as a component selected from the group consisting of organic light-emitting diode (OLED), light-emitting electrochemical cell, OLED sensor, in particular in non-hermetically externally shielded gas and vapor sensors, organic diode, organic solar cell, organic transistor, organic field effect transistor, organic laser and down-conversion Element.
Eine Ausführungsform betrifft das erfindungsgemäße optoelektronische Bauelement aufweisend ein Substrat, eine Anode und eine Kathode, wobei die Anode und die Kathode auf das Substrat aufgebracht sind, und mindestens eine lichtemittierende Schicht, welche zwischen Anode und Kathode angeordnet ist und die ein erfindungsgemäßes organisches Molekül enthält. One embodiment relates to the optoelectronic component according to the invention comprising a substrate, an anode and a cathode, wherein the anode and the cathode are applied to the substrate, and at least one light-emitting layer which is arranged between anode and cathode and which contains an organic molecule according to the invention.
In einer weiteren Ausführungsform des Bauelements wird das organische Molekül als Emissionsmaterial in einer Emissionsschicht eingesetzt, wobei sie in Kombination mit mindestens einem Hostmaterial oder insbesondere als Reinschicht eingesetzt werden kann. In einer Ausführungsform beträgt dabei der Anteil des organischen Moleküls als Emissionsmaterial in einer Emissionsschicht in optischen Licht-emittierenden Bauelementen, insbesondere in OLEDs, zwischen 5 % und 80 % (Gew%). In a further embodiment of the component, the organic molecule is used as the emission material in an emission layer, wherein it can be used in combination with at least one host material or, in particular, as a pure layer. In one embodiment, the proportion of the organic molecule as emission material in an emission layer in optical light-emitting components, in particular in OLEDs, is between 5% and 80% (% by weight).
In einer weiteren Ausführungsform des erfindungsgemäßen Bauelements ist die ein erfindungsgemäßes organisches Molekül aufweisende lichtemittierende Schicht auf ein Substrat aufgebracht. In a further embodiment of the component according to the invention, the light-emitting layer having an organic molecule according to the invention is applied to a substrate.
In einer Ausführungsform betrifft die Erfindung ein optoelektronisches Bauelement, bei dem die lichtemittierende Schicht ausschließlich ein erfindungsgemäßes organisches Molekül in 100 % Konzentration aufweist, wobei die Anode und die Kathode auf das Substrat aufgebracht ist, und die lichtemittierende Schicht zwischen Anode und Kathode aufgebracht ist. In one embodiment, the invention relates to an optoelectronic component in which the light-emitting layer comprises only an organic molecule according to the invention in 100% concentration, wherein the anode and the cathode is applied to the substrate, and the light-emitting layer between the anode and cathode is applied.
In einer weiteren Ausführungsform weist das optoelektronische Bauelement neben dem erfindungsgemäßen organischen Molekül mindestens ein Hostmaterial auf, wobei insbesondere der angeregte Singulettzustand (Si) und/oder der angeregte Triplettzustand (T-i) des mindestens einen Hostmaterials höher ist als der angeregte Singulettzustand (Si) und/oder der angeregte Triplettzustand (T-i) des organischen Moleküls, und wobei die Anode und die Kathode auf das Substrat aufgebracht ist, und die lichtemittierende Schicht zwischen Anode und Kathode aufgebracht ist. In einer weiteren Ausführungsform weist das optoelektronische Bauelement ein Substrat, eine Anode, eine Kathode und mindestens je eine löcherinjizierende und eine elektroneninjizierende Schicht und mindestens eine lichtemittierende Schicht auf, wobei die mindestens eine lichtemittierende Schicht ein erfindungsgemäßes organisches Molekül und ein Hostmaterial aufweist, dessen Triplett (ΤΊ)- und Singulett (S-i)-Energieniveaus energetisch höher liegen als die Triplett (ΤΊ)- und Singulett (S-i)-Energieniveaus des organischen Moleküls, und wobei die Anode und die Kathode auf das Substrat aufgebracht ist, und die löcher- und elektroneninjizierende Schicht zwischen Anode und Kathode aufgebracht ist und die lichtemittierende Schicht zwischen löcher- und elektroneninjizierende Schicht aufgebracht ist. In a further embodiment, in addition to the organic molecule according to the invention, the optoelectronic component has at least one host material, in particular the excited singlet state (Si) and / or the excited triplet state (Ti) of the at least one host material being higher than the excited singlet state (Si) and / or the excited triplet state (Ti) of the organic molecule, and wherein the anode and the cathode are deposited on the substrate, and the light emitting layer is disposed between the anode and the cathode. In a further embodiment, the optoelectronic component comprises a substrate, an anode, a cathode and at least one hole-injecting and an electron-injecting layer and at least one light-emitting layer, wherein the at least one light-emitting layer comprises an organic molecule according to the invention and a host material whose triplet ( ΤΊ) and singlet (Si) energy levels are higher in energy than the triplet (ΤΊ) and singlet (Si) energy levels of the organic molecule, and where the anode and cathode are deposited on the substrate, and the hole and electron injecting Layer between the anode and cathode is applied and the light-emitting layer between holes and electron injecting layer is applied.
In einer weiteren Ausführungsform weist das optoelektronische Bauelement ein Substrat, eine Anode, eine Kathode und mindestens je eine löcherinjizierende und eine elektroneninjizierende Schicht, und mindestens je eine löchertransportierende und eine elektronentransportierende Schicht, und mindestens eine lichtemittierende Schicht auf, wobei die mindestens eine lichtemittierende Schicht ein erfindungsgemäßes organisches Molekül sowie ein Hostmaterial aufweist, dessen Triplett (T-i)- und Singulett (Si)- Energieniveaus energetisch höher liegen als die Triplett (T-i)- und Singulett (Si)- Energieniveaus des organischen Moleküls, und wobei die Anode und die Kathode auf das Substrat aufgebracht ist, und die löcher- und elektroneninjizierende Schicht zwischen Anode und Kathode aufgebracht ist, und die löcher- und elektronentransportierende Schicht zwischen löcher- und elektroneninjizierende Schicht aufgebracht ist, und die lichtemittierende Schicht zwischen löcher- und elektronentransportierende Schicht aufgebracht ist. In a further embodiment, the optoelectronic component comprises a substrate, an anode, a cathode and at least one hole-injecting and an electron-injecting layer, and at least one hole-transporting and one electron-transporting layer, and at least one light-emitting layer, wherein the at least one light-emitting layer According to the invention, the organic molecule and a host material whose triplet (Ti) and singlet (Si) energy levels are higher in energy than the triplet (Ti) and singlet (Si) energy levels of the organic molecule, and wherein the anode and the cathode the substrate is applied, and the hole and electron injecting layer is applied between anode and cathode, and the hole and electron transporting layer is applied between hole and electron injecting layer, and the light emitting layer between holes and electronentr is applied ansportierende layer.
In einer weiteren Ausführungsform weist das optoelektronische Bauelement mindestens ein Hostmaterial aus einem Material gemäß Formel 1 auf. In a further embodiment, the optoelectronic component has at least one host material made from a material according to formula 1.
In einer weiteren Ausführungsform des optoelektronischen Bauelements beinhaltet die lichtemittierende Schicht fluoreszente oder phosphoreszente Materialien, welche eine Struktur der Formel 1 aufweisen. In a further embodiment of the optoelectronic component, the light-emitting layer contains fluorescent or phosphorescent materials which have a structure of formula 1.
In einer weiteren Ausführungsform des optoelektronischen Bauelements bilden ein organisches Molekül gemäß Formel 1 und ein funktionelles Material, beispielsweise in Form eines weiteren Emitter-Materials, eines Host-Materials, oder eines weiteren organischen Moleküls, welches zur Bildung eines Exciplex mit dem Molekül gemäß Formel 1 befähigt ist, einen Exciplex. Funktionelle Materialien sind beispielsweise Hostmaterialien wie MCP, Elektronentransportmaterialien wie TPBI und Lochtransportmaterialien wie NPD oder MTDATA. Exciplexe sind Addukte aus elektronisch angeregten Molekülen und solchen im elektronischen Grundzustand, die zur Lichtemission fähig sind. In a further embodiment of the optoelectronic component form an organic molecule according to formula 1 and a functional material, for example in the form of another emitter material, a host material, or another organic molecule which is used to form an exciplex with the molecule of formula 1 is capable of an exciplex. Functional materials include, for example, host materials such as MCP, electron transport materials such as TPBI and hole transport materials such as NPD or MTDATA. Exciplexes are adducts of electronically excited and electronically grounded molecules capable of emitting light.
In einer weiteren Ausführungsform des optoelektronischen Bauelements ist die Emission durch thermisch aktivierte verzögerte Fluoreszenz (TADF) charakterisiert. In a further embodiment of the optoelectronic component, the emission is characterized by thermally activated delayed fluorescence (TADF).
In einer weiteren Ausführungsform des optoelektronischen Bauelements werden organische Moleküle gemäß Formel 1 als Ladungstransportschicht verwendet. In a further embodiment of the optoelectronic component, organic molecules according to formula 1 are used as charge transport layer.
Die Erfindung betrifft in einem Aspekt ein lichtemittierendes Material, aufweisend ein erfindungsgemäßes organisches Molekül und ein Hostmaterial, wobei die Triplett (ΤΊ)- und Singulett (S-i)-Energieniveaus des Hostmaterials energetisch höher liegen als die Triplett (T-i )- und Singulett (S-i)-Energieniveaus des organischen Moleküls, und wobei das organische Molekül Fluoreszenz oder thermisch aktivierte verzögerte Fluoreszenz (TADF) emittiert, und einen AE(Si-T-i)-Wert zwischen dem untersten angeregten Singulett (Si )- und dem darunter liegenden Triplett (T-i )-Zustand von kleiner als 0,2 eV, insbesondere kleiner als 0, 1 eV aufweist. The invention in one aspect relates to a light-emitting material comprising an organic molecule and a host material according to the invention, wherein the triplet (ΤΊ) and singlet (Si) energy levels of the host material are higher than the triplet (Ti) and singlet (Si) energies. Energy levels of the organic molecule, and wherein the organic molecule emits fluorescence or thermally activated delayed fluorescence (TADF), and an AE (Si-Ti) value between the lowest excited singlet (Si) and the underlying triplet (Ti) - Condition of less than 0.2 eV, in particular less than 0, 1 eV has.
Ein Aspekt der Erfindung betrifft ein Verfahren zur Herstellung eines optoelektronischen Bauelements aufweisend ein erfindungsgemäßes organisches Molekül. In einer Ausführungsform weist das Verfahren die Verarbeitung des organischen Moleküls mittels eines Vakuumverdampfungsverfahrens oder aus einer Lösung auf. One aspect of the invention relates to a method for producing an optoelectronic component comprising an organic molecule according to the invention. In one embodiment, the method comprises processing the organic molecule by a vacuum evaporation method or from a solution.
In einer Ausführungsform weist das Verfahren das Aufbringen des organischen Moleküls auf einen Träger auf, wobei das Aufbringen insbesondere nass-chemisch, mittels kolloidaler Suspension oder mittels Sublimation erfolgt. In one embodiment, the method comprises applying the organic molecule to a carrier, the application being carried out in particular wet-chemically, by means of colloidal suspension or by means of sublimation.
In einer weiteren Ausführungsform des Verfahrens wird mindestens eine Schicht In a further embodiment of the method, at least one layer
- mit einem Sublimationsverfahren beschichtet  - coated with a sublimation process
- mit einem OVPD (Organic Vapor Phase Deposition) Verfahren beschichtet  - coated with an OVPD (Organic Vapor Phase Deposition) method
- mit Hilfe einer Trägergassublimation beschichtet oder  - coated with the aid of a carrier gas sublimation or
- aus Lösung oder mit einem beliebigen Druckverfahren hergestellt.  - made from solution or any printing process.
Ein Aspekt der Erfindung betrifft ein Verfahren zur Veränderung der Emissions- und/oder Absorptionseigenschaften eines elektronischen Bauelements, wobei ein erfindungsgemäßes organisches Molekül in ein Matrixmaterial zur Leitung von Elektronen oder Löchern in einem optoelektronischen Bauelement eingebracht wird. Die Erfindung betrifft zudem in einem weiteren Aspekt die Verwendung eines erfindungsgemäßen Moleküls zur Umwandlung von UV-Strahlung oder von blauem Licht in sichtbares Licht, insbesondere in grünes, gelbes oder rotes Licht (Down-Konversion), insbesondere in einem optoelektronischen Bauelement der hier beschriebenen Art. One aspect of the invention relates to a method for changing the emission and / or absorption properties of an electronic component, wherein an organic molecule according to the invention is introduced into a matrix material for conducting electrons or holes in an optoelectronic component. In a further aspect, the invention additionally relates to the use of a molecule according to the invention for converting UV radiation or blue light into visible light, in particular into green, yellow or red light (down conversion), in particular in an optoelectronic component of the type described here ,
In einem weiteren Aspekt betrifft die Erfindung eine Anwendung, in der mindestens ein Material mit einer Struktur gemäß Formel 1 , durch äußere energetische Anregung zum Leuchten angeregt wird. Die äußere Anregung kann elektronisch oder optisch oder radioaktiv sein. In a further aspect, the invention relates to an application in which at least one material with a structure according to formula 1 is excited to emit by external energetic excitation. The external stimulation can be electronic or optical or radioactive.
In einer weiteren Ausführungsform des optoelektronischen Bauelements bilden ein organisches Molekül gemäß Formel 1 und ein funktionelles Material, beispielsweise in Form eines weiteren Emitter-Materials, eines Host-Materials, oder eines weiteren organisches Moleküls, welches zur Bildung eines Exciplex mit dem Molekül gemäß Formel 1 befähigt ist, einen Exciplex. Funktionelle Materialien sind beispielsweise Hostmaterialien wie MCP, Elektronentransportmaterialien wie TPBI und Lochtransportmaterialien wie NPD oder MTDATA. Exciplexe sind Addukte aus elektronisch angeregten Molekülen und solchen im elektronischen Grundzustand, die zur Lichtemission fähig sind. In a further embodiment of the optoelectronic component form an organic molecule according to formula 1 and a functional material, for example in the form of another emitter material, a host material, or another organic molecule which is used to form an exciplex with the molecule of formula 1 is capable of an exciplex. Functional materials include host materials such as MCP, electron transport materials such as TPBI and hole transport materials such as NPD or MTDATA. Exciplexes are adducts of electronically excited and electronically grounded molecules capable of emitting light.
Beispiele Examples
Berechnungen nach der Dichtefuntionaltheorie Calculations according to the density functional theory
Variante 1 (BP86) Variant 1 (BP86)
Für die DFT-Rechnungen (Dichtefunktionaltheorie) wurde das BP86-Funktional (Becke, A. D. Phys. Rev. A1988, 38, 3098-3100; Perdew, J. P. Phys. Rev. B1986, 33, 8822-8827) und def2-SV(P)-Basissätze (Weigend, F.; Ahlrichs, R. Phys. Chem. Chem. Phys. 2005, 7, 3297- 3305; Rappoport, D.; Furche, F. J. Chem. Phys.2010, 133, 134105/1-134105/1 1 ) verwendet. Zur numerischen Integration kam das m4-Grid zum Einsatz und die resolution-of-identity- Näherung (Rl) (Häser, M.; Ahlrichs, R. J. Comput. Chem. 1989, 10, 104-1 1 1 ; Weigend, F.; Häser, M. Theor. Chem. Acc. 1997, 97, 331-340; Sierka, M.; Hogekamp, A.; Ahlrichs, R. J. Chem. Phys. 2003, 1 18, 9136-9148) wurde in allen Rechnungen verwendet. Die DFT- Rechnungen wurden mit dem Turbomole-Programmpaket (Version 6.5) (TURBOMOLE V6.4 2012, University of Karlsruhe/Forschungszentrum Karlsruhe GmbH, 1989-2007, TURBOMOLE GmbH, since 2007; http://www.turbomole.com) durchgeführt.  For DFT calculations (density functional theory), the BP86 functional (Becke, AD Phys Rev. A1988, 38, 3098-3100, Perdew, JP Phys Rev. B1986, 33, 8822-8827) and def2-SV (P Bases et al. (Weigend, F .; Ahlrichs, R. Phys. Chem. Chem. Phys., 2005, 7, 3297-3305, Rappoport, D .; Furche, FJ Chem. Phys., 133, 134105 / 1-134105 / 1 1) used. For numerical integration, the m4 grid was used and the resolution-of-identity approximation (Rl) (Häser, M., Ahlrichs, RJ Comput Chem 1989, 10, 104-111; Weigend, F .; Häser, M. Theor. Chem Acc, 1997, 97, 331-340; Sierka, M., Hogekamp, A., Ahlrichs, RJ Chem. Phys., 2003, 18, 9136-9148) was used in all calculations. The DFT calculations were performed with the Turbomole program package (version 6.5) (TURBOMOLE V6.4 2012, University of Karlsruhe / Forschungszentrum Karlsruhe GmbH, 1989-2007, TURBOMOLE GmbH, since 2007, http://www.turbomole.com) ,
Variante 2 (TD-B3LYP) Variant 2 (TD-B3LYP)
Für die Optimierung der Molekülstrukturen wurde das BP86-Funktional (Becke, A. D. Phys. Rev. A1988, 38, 3098-3100; Perdew, J. P. Phys. Rev. B1986, 33, 8822-8827) verwendet, wobei die resolution-of-identity-Näherung (Rl) (Sierka, M.; Hogekamp, A.; Ahlrichs, R. J. Chem. Phys. 2003, 1 18, 9136-9148; Becke, A.D. , J.Chem.Phys. 98 (1993) 5648-5652; Lee, C; Yang, W; Parr, R.G. Phys. Rev. B 37 (1988) 785-789) zum Einsatz kam. Anregungsenergien wurden bei der mit BP86 optimierten Struktur mit der Time-Dependent DFT-Methode (TD-DFT) unter Verwendung des B3LYP-Funktionals (Becke, A.D. , J.Chem.Phys. 98 (1993) 5648-5652; Lee, C; Yang, W; Parr, R.G. Phys. Rev. B 37 (1988) 785-789; Vosko, S. H.; Wilk, L; Nusair, M. Can. J. Phys. 58 (1980) 1200-121 1 ; Stephens, P. J.; Devlin, F. J.; Chabalowski, C. F. ; Frisch, M. J. J.Phys.Chem. 98 (1994) 1 1623-1 1627) berechnet. In allen Rechnungen wurden def2-SV(P)-Basissätze (Weigend, F.; Ahlrichs, R. Phys. Chem. Chem. Phys. 2005, 7, 3297-3305; Rappoport, D.; Furche, F. J. Chem. Phys.2010, 133, 134105/1-134105/1 1 ) und ein m4 -Grid zur numerischen Integration verwendet. Alle DFT-Rechnungen wurden mit dem Turbomole-Programmpaket (Version 6.5) (TURBOMOLE V6.4 2012, University of Karlsruhe und Forschungszentrum Karlsruhe GmbH, 1989-2007, TURBOMOLE GmbH, since 2007; http://www. turbomole.com) durchgeführt. For the optimization of molecular structures, the BP86 functional (Becke, AD Phys Rev. A1988, 38, 3098-3100, Perdew, JP Phys Rev. B1986, 33, 8822-8827) was used, with the resolution-of-identity Approach (RI) (Sierka, M., Hogekamp, A., Ahlrichs, RJ Chem. Phys., 2003, 18, 9136-9148; Becke, AD, J. Chem. Phys., 98 (1993) 5648-5652; Lee, C; Yang, W; Parr, RG Phys. Rev. B 37 (1988) 785-789). Excitation energies were determined in the BP86 optimized structure using the time-dependent DFT method (TD-DFT) using the B3LYP functional (Becke, AD, J. Chem. Phys. 98 (1993) 5648-5652, Lee, C; Yang, W; Parr, RG Phys Rev. B 37 (1988) 785-789; Vosko, SH; Wilk, L; Nusair, M. Can. J. Phys. 58 (1980) 1200-121 1; Stephens, PJ Devlin, FJ; Chabalowski, CF; Frisch, MJJ Phys. Chem 98 (1994) 1 1623-1 1627). In all calculations, def2-SV (P) base sets (Weigend, F., Ahlrichs, R. Phys. Chem. Chem. Phys., 2005, 7, 3297-3305, Rappoport, D .; Furche, FJ Chem. Phys. 2010, 133, 134105 / 1-134105 / 1 1) and an m4 grid for numerical integration. All DFT calculations were performed with the Turbomole program package (version 6.5) (TURBOMOLE V6.4 2012, University of Karlsruhe and Forschungszentrum Karlsruhe GmbH, 1989-2007, TURBOMOLE GmbH, since 2007, http://www.turbomole.com) ,
Figure imgf000074_0001
Figure imgf000074_0001
0.036eV) (0.046eV) (0.034eV)
Figure imgf000074_0002
0.036eV) (0.046eV) (0.034eV)
Figure imgf000074_0002
(0.056eV) (0.054eV) (0.056eV) (0.054eV)
Figure imgf000074_0003
Figure imgf000074_0003
(0.056eV) (0.014eV) Schematische Darstellung des Aufbaus einer organischen lichtemittierenden Diode (OLED). (0.056eV) (0.014eV) Schematic representation of the structure of an organic light emitting diode (OLED).
Schematische Darstellung des Energieniveaudiagrammes (relative Energie in eV) eines erfindungsgemäßen Emittermoleküls, aufweisend keinen Separator (Lichtemission resultiert aus dem Übergang LUMO AF1 hin zu HOMO AF2).  Schematic representation of the energy level diagram (relative energy in eV) of an emitter molecule according to the invention, having no separator (light emission results from the transition from LUMO AF1 to HOMO AF2).

Claims

Ansprüche claims
1. Organisches Molekül, aufweisend eine Struktur der Formel 1 : 1. Organic molecule having a structure of formula 1:
Figure imgf000076_0001
Figure imgf000076_0001
Formel 1 formula 1
AF1 ist eine erste chemische Einheit, aufweisend ein konjugiertes System; AF1 is a first chemical entity comprising a conjugated system;
AF2 ist eine zweite chemische Einheit, aufweisend ein konjugiertes System; AF2 is a second chemical entity comprising a conjugated system;
mit AF1 AF2; wobei AF1 eine Struktur der Formel 1 a aufweist: with AF1 AF2; wherein AF1 has a structure of formula 1a:
Figure imgf000076_0002
Figure imgf000076_0002
wobei in Formel 1 a bedeutet: where in formula 1 a is
Y ist O, S, NR*, PR*, AsR*, GeR*2, BR*, SiR*2, 1 , 1 '-Cyclohexyl, Methylen, S02, 1 ,2- Phenylen, 1 , 1-Dicyanoethylen C=C(CN)2, CMe2, 2,2'-Diphenylether-Fragment, 2,2'- Diphenylthioether-Fragment, 2,2'-Benzophenon-Fragment, 2,2'-Diphenyl-methan-Fragment oder ein 2,2'-Diphenyl-dicyanomethan-Fragment, Y is O, S, NR *, PR *, AsR *, GeR * 2 , BR *, SiR * 2 , 1, 1 'cyclohexyl, methylene, S0 2 , 1, 2-phenylene, 1, 1-dicyanoethylene C = C (CN) 2 , CMe 2 , 2,2'-diphenyl ether fragment, 2,2'-diphenyl thioether fragment, 2,2'-benzophenone fragment, 2,2'-diphenylmethane fragment or a 2 , 2'-diphenyl-dicyanomethane fragment
R** ist entweder ein Rest R* oder kennzeichnet die Anknüpfungsposition an die chemische Einheit AF2; dabei können zwei oder mehrere Substituenten R** auch miteinander ein mono- oder polycyclisches, aliphatisches Ringsystem bilden; wobei die Anknüpfung an die chemische Einheit AF2 auch ein Atom des Rests R** oder R* erfolgen kann; und wobei im Molekül genau eine chemische Einheit AF2 vorhanden ist;  R ** is either a radical R * or denotes the attachment position to the chemical moiety AF2; two or more substituents R ** may also together form a mono- or polycyclic aliphatic ring system; wherein the attachment to the chemical entity AF2 can also be an atom of the radical R ** or R *; and wherein in the molecule exactly one chemical unit AF2 is present;
und wobei AF2 eine Struktur der Formel 3 aufweist
Figure imgf000077_0001
and wherein AF2 has a structure of formula 3
Figure imgf000077_0001
Formel 3 Formula 3
wobei in Formel 3 gilt: m ist 1 ; where in formula 3: m is 1;
n ist 0 oder 1 , wobei bei m = 0 immer auch n = 0 ist; n is 0 or 1, where m = 0 always also n = 0;
o ist 0 oder 1 ; o is 0 or 1;
p ist 0 oder 1 ; p is 0 or 1;
A ist CR*** wenn o = 0, ansonsten C; A is CR *** if o = 0, otherwise C;
VG1 = verbrückende Gruppe, ist ausgewählt aus der Gruppe bestehend aus VG1 = bridging group, is selected from the group consisting of
- NR**, CR**2, O, S und einer C-C-Einfachbindung; oder - NR **, CR ** 2 , O, S and a CC single bond; or
- NR**, CR**2, O, S, einer C-C-Einfachbindung, BR**, AsR**, SiR**2, GeR**2, NR **, CR ** 2 , O, S, a CC single bond, BR **, AsR **, SiR ** 2 , GeR ** 2 ,
Figure imgf000077_0002
Figure imgf000077_0002
VG2 = verbrückende Gruppe ist bei jedem Auftreten unabhängig voneinander ausgewählt aus der Gruppe bestehend aus CR**2, NR**, O, S und einer C-C-Einfachbindung, wobei nicht zwei Einheiten VG2 gleichzeitig gleich einer C-C-Einfachbindung sind; VG2 = bridging group at each occurrence is independently selected from the group consisting of CR ** 2 , NR **, O, S and a CC single bond, where two units VG2 are not simultaneously equal to one CC single bond;
E ist ausgewählt aus der Gruppe bestehend aus NR
Figure imgf000077_0003
G ist C wenn o = 1 und gleichzeitig m = 1 ; E is selected from the group consisting of NR
Figure imgf000077_0003
G is C if o = 1 and m = 1 at the same time;
CR** wenn o = 0 und gleichzeitig m = 1 ; J ist C wenn m = 1 ; CR ** if o = 0 and m = 1 at the same time; J is C when m = 1;
L ist CR*** wenn n = 0; ist L is CR *** if n = 0; is
CR**oder C (bei kovalenter Bindung zu VG2) wenn n = 1 ; R*** ist R** oder ist ausgewählt aus der Gruppe der folgenden Einheiten, wobei maximal zwei der Reste R*** gleichzeitig gleich einer der folgenden Einheiten sind: CR ** or C (when covalently linked to VG2) when n = 1; R *** is R ** or is selected from the group of the following units, wherein a maximum of two of the radicals R *** are simultaneously one of the following units:
Figure imgf000078_0001
Figure imgf000078_0001
R** ist bei jedem Auftreten unabhängig voneinander ein Rest R* und/oder markiert eine Anknüpfungsstelle an die Einheit AF1 , wobei genau ein R** eine Anknüpfungsstelle an eine Einheit AF1 ist; und wobei für Formel 1 a und Formel 3 gilt: R ** is independently a residue R * at each occurrence and / or marks a point of attachment to the unit AF1, with exactly one R ** being a point of attachment to a unit AF1; and wherein for formula 1 a and formula 3:
R* ist bei jedem Auftreten unabhängig voneinander ausgewählt aus der Gruppe bestehend aus H, Deuterium, Phenyl, Naphthyl, N(R2)2, -CN, -NC, -SCN, -CF3, -N02, C(=0)OH, C(=0)OR3, C(=0)N(R3)2, C(=0)SR3, C(=S)SR3, Si(R4)3, B(OR5)2, B(N(R6)2)2, C(=0)R3, P(=0)(R7)2, As(=0)(R7)2, P(=S)(R7)2, As(=S)(R7)2, S(=0)R3, S=NR3, S(=0)NR3, S(=0)2NR3, S(=0)2R3, 0-S(=0)2R3, SF5, eine lineare Alkyl-, Alkoxy- oder Thioalkoxygruppe mit 1 bis 40 C-Atomen oder eine lineare Alkenyl- oder Alkinylgruppe mit 2 bis 40 C-Atomen oder eine verzweigte oder cyclische Alkyl-, Alkenyl-, Alkinyl-, Alkoxy- oder Thioalkoxygruppe mit 3 bis 40 C-Atomen, die jeweils mit einem oder mehreren Resten R9 substituiert sein kann, wobei eine oder mehrere benachbarte CH2-Gruppen durch -R9C=CR9-, -C=C-, oder eine benachbarte CH2-Gruppe durch -Si(R4)2-, -Ge(R4)2-, -Sn(R4)2-, -C(=0)-, -C(=S)-, -C(=Se)-, - C=N-, -C(=0)0-, -C(=0)N(R3)-, -P(=Q)(R7)-, -As(=0)(R7)-, -P(=S)(R7), -As(=S)(R7)-, -S(=0)-, -S(=0)2-, -NR2-, -O-, oder -S- ersetzt sein können und wobei ein oder mehrere H-Atome durch Deuterium, F, Cl, Br, I, CN, CF3 oder N02 ersetzt sein können, oder ein aromatisches oder heteroaromatisches Ringsystem mit 5 bis 60 aromatischen Ringatomen, das jeweils durch einen oder mehrere Reste R2 substituiert sein kann, oder eine Aryloxy- oder Heteroaryloxygruppe mit 5 bis 60 aromatischen Ringatomen, die durch einen oder mehrere Reste R9 substituiert sein kann, oder eine Diarylaminogruppe, Diheteroarylaminogruppe oder Arylheteroarylaminogruppe mit 10 bis 40 aromatischen Ringatomen, welche durch einen oder mehrere Reste R9 substituiert sein kann, oder eine Kombination dieser Systeme; dabei können zwei oder mehrere dieser Substituenten R* auch miteinander ein mono- oder polycyclisches, aliphatisches, aromatisches und/oder benzoannelliertes Ringsystem bilden; R * in each occurrence is independently selected from the group consisting of H, deuterium, phenyl, naphthyl, N (R 2 ) 2 , -CN, -NC, -SCN, -CF 3 , -NO 2 , C (= 0 ) OH, C (= O) OR 3 , C (= O) N (R 3 ) 2 , C (= O) SR 3 , C (= S) SR 3 , Si (R 4 ) 3 , B (OR 5 ) 2 , B (N (R 6 ) 2 ) 2 , C (= O) R 3 , P (= O) (R 7 ) 2 , As (= O) (R 7 ) 2 , P (= S) ( R 7 ) 2 , As (= S) (R 7 ) 2 , S (= O) R 3 , S = NR 3 , S (= O) NR 3 , S (= O) 2 NR 3 , S (= 0 ) 2 R 3 , 0-S (= O) 2 R 3 , SF 5 , a linear alkyl, alkoxy or thioalkoxy group having 1 to 40 carbon atoms or a linear alkenyl or alkynyl group having 2 to 40 carbon atoms or a branched or cyclic alkyl, alkenyl, alkynyl, alkoxy or thioalkoxy group having from 3 to 40 carbon atoms, each of which may be substituted with one or more R 9 radicals, one or more adjacent CH 2 groups represented by -R 9 C = CR 9 -, -C = C-, or an adjacent CH 2 group by -Si (R 4 ) 2 -, -Ge (R 4 ) 2 -, -Sn (R 4 ) 2 -, -C (= 0) -, -C (= S) -, -C (= Se) -, - C = N-, -C (= O) O-, -C (= O) N (R 3 ) -, -P (= Q) (R 7 ) -, -As (= O) (R 7 ) -, -P (= S) (R 7 ), -As (= S) (R 7 ) -, -S (= O) -, -S (= O) 2 -, -NR 2 -, -O-, or -S- may be replaced and wherein one or more H atoms by deuterium, F, Cl, Br, I, CN, CF 3 or N0 May be replaced, or an aromatic or heteroaromatic ring system having 5 to 60 aromatic ring atoms, each of which may be substituted by one or more radicals R 2 , or an aryloxy or heteroaryloxy group having 5 to 60 aromatic ring atoms, by one or more radicals R 9 may be substituted, or a diarylamino group, Diheteroarylaminogruppe or Arylheteroarylaminogruppe having 10 to 40 aromatic ring atoms which may be substituted by one or more radicals R 9 , or a combination of these systems; two or more of these substituents R * may also together form a mono- or polycyclic, aliphatic, aromatic and / or benzoannulated ring system;
R2 ist bei jedem Auftreten unabhängig voneinander ausgewählt aus der Gruppe bestehend aus H, Deuterium, Phenyl, Naphthyl, CF3, C(=0)OR3, C(=0)N(R2)2, Si(R4)3, C(=0)R3, P(=0)(R7)2, As(=0)(R7)2 P(=S)(R7)2, As(=S)(R7)2, S(=0)R3, S(=0)2R3, eine lineare Alkyl-, Alkoxy- oder Thioalkoxygruppe mit 1 bis 40 C-Atomen oder eine lineare Alkenyl- oder Alkinylgruppe mit 2 bis 40 C-Atomen oder eine verzweigte oder cyclische Alkyl-, Alkenyl-, Alkinyl-, Alkoxy- oder Thioalkoxygruppe mit 3 bis 40 C-Atomen, die jeweils mit einem oder mehreren Resten R9 substituiert sein kann, wobei eine oder mehrere benachbarte CH2- Gruppen durch -R9C=CR9-, -C=C-, oder eine benachbarte CH2-Gruppe durch -Si(R4)2-, - Ge(R4)2-, -Sn(R4)2, -C(=0)-, -C(=S)-, -C(=Se)-, -C=N-, -C(=0)0-, -C(=0)N(R3)-, -P(=0)(R7)-, -As(=0)(R7)-, -P(=S)(R7)-, -As(=S)(R7)-, -S(=0)-, -S(=0)2-, -NR2-, -O-, oder -S- ersetzt sein können und wobei ein oder mehrere H-Atome durch Deuterium, F, Cl, Br, I, CN, CF3 oder N02 ersetzt sein können, oder ein aromatisches oder heteroaromatisches Ringsystem mit 5 bis 60 aromatischen Ringatomen, das jeweils durch einen oder mehrere Reste R9 substituiert sein kann, oder eine Aryloxy- oder Heteroaryloxygruppe mit 5 bis 60 aromatischen Ringatomen, die durch einen oder mehrere Reste R9 substituiert sein kann, oder eine Diarylaminogruppe, Diheteroarylaminogruppe oder Arylheteroarylaminogruppe mit 10 bis 40 aromatischen Ringatomen, welche durch einen oder mehrere Reste R9 substituiert sein kann, oder eine Kombination dieser Systeme; dabei können zwei oder mehrere dieser Substituenten R2 auch miteinander ein mono- oder polycyclisches, aliphatisches, aromatisches und/oder benzoannelliertes Ringsystem bilden; R 2 is independently selected from the group consisting of H, deuterium, phenyl, naphthyl, CF 3 , C (= O) OR 3 , C (= O) N (R 2 ) 2 , Si (R 4 ) 3 , C (= O) R 3 , P (= O) (R 7 ) 2 , As (= O) (R 7 ) 2 P (= S) (R 7 ) 2 , As (= S) (R 7 ) 2 , S (= O) R 3 , S (= O) 2 R 3 , a linear alkyl, alkoxy or thioalkoxy group having 1 to 40 carbon atoms or a linear alkenyl or alkynyl group having 2 to 40 carbon atoms or a branched or cyclic alkyl, alkenyl, alkynyl, alkoxy or thioalkoxy group having 3 to 40 carbon atoms, each of which may be substituted by one or more radicals R 9 , wherein one or more adjacent CH 2 - groups by - R 9 C = CR 9 -, -C = C-, or an adjacent CH 2 group by -Si (R 4 ) 2 -, - Ge (R 4 ) 2 -, -Sn (R 4 ) 2 , -C (= 0) -, -C (= S) -, -C (= Se) -, -C = N-, -C (= O) O-, -C (= O) N (R 3 ) -, -P (= 0) (R 7 ) -, -As (= 0) (R 7 ) -, -P (= S) (R 7 ) -, -As (= S) (R 7 ) -, -S (= 0) -, -S (= 0) 2 -, -NR 2 -, -O-, or -S- may be replaced and wherein one or more H atoms by Deu terium, F, Cl, Br, I, CN, CF 3 or N0 2 may be replaced, or an aromatic or heteroaromatic ring system having 5 to 60 aromatic ring atoms, each of which may be substituted by one or more radicals R 9 , or an aryloxy or heteroaryloxy group having 5 to 60 aromatic ring atoms which may be substituted by one or more radicals R 9 , or a diarylamino group, diheteroarylamino group or arylheteroarylamino group having 10 to 40 aromatic ring atoms, which may be substituted by one or more radicals R 9 , or a Combination of these systems; two or more of these substituents R 2 may also together form a mono- or polycyclic, aliphatic, aromatic and / or benzoannellated ring system;
R3 ist bei jedem Auftreten unabhängig voneinander ausgewählt aus der Gruppe bestehend aus H, Deuterium, Phenyl, Naphthyl, CF3 oder ein aliphatischer, aromatischer und/oder heteroaromatischer Kohlenwasserstoffrest mit 1 bis 20 C-Atomen, in dem auch ein oder mehrere H-Atome durch F oder CF3 ersetzt sein können; dabei können zwei oder mehrere Substituenten R3 auch miteinander ein mono- oder polycyclisches, aliphatisches Ringsystem bilden; R 3 is independently selected for each occurrence from the group consisting of H, deuterium, phenyl, naphthyl, CF 3 or an aliphatic, aromatic and / or heteroaromatic hydrocarbon radical having 1 to 20 carbon atoms, in which also one or more H Atoms may be replaced by F or CF 3 ; It can have two or more Substituents R 3 also together form a mono- or polycyclic aliphatic ring system;
R4 ist bei jedem Auftreten unabhängig voneinander ausgewählt aus der Gruppe bestehend aus H, Deuterium, Phenyl, Naphthyl, N(R2)2, CN, CF3, OH, C(=0)OR3, C(=0)N(R3)2, C(=0)R3, P(=0)(R7)2, As(=0)(R7)2, P(=S)(R7)2, As(=S)(R7)2, eine lineare Alkyl-, Alkoxy- oder Thioalkoxygruppe mit 1 bis 40 C-Atomen oder eine lineare Alkenyl- oder Alkinylgruppe mit 2 bis 40 C-Atomen oder eine verzweigte oder cyclische Alkyl-, Alkenyl-, Alkinyl-, Alkoxy- oder Thioalkoxygruppe mit 3 bis 40 C-Atomen, die jeweils mit einem oder mehreren Resten R9 substituiert sein kann, wobei eine oder mehrere benachbarte CH2-Gruppen durch - R9C=CR9-, -CEC-, oder eine benachbarte CH2-Gruppe durch -Si(R4)2-, -Ge(R4)2-, -Sn(R4)2, - C(=0)-, -C(=S)-, -C(=Se)-, -C=N-, -C(=0)0-, -C(=0)N(R3)-, -P(=0)(R7)-, -As(=0)(R7)-, - P(=S)(R7), -As(=S)(R7)-, -S(=0)-, -S(=0)2-, -NR2-, -O-, oder -S- ersetzt sein können und wobei ein oder mehrere H-Atome durch Deuterium, F, Cl, Br, I, CN, CF3 oder N02 ersetzt sein können, oder ein aromatisches oder heteroaromatisches Ringsystem mit 5 bis 60 aromatischen Ringatomen, das jeweils durch einen oder mehrere Reste R8 substituiert sein kann, oder eine Aryloxy- oder Heteroaryloxygruppe mit 5 bis 60 aromatischen Ringatomen, die durch einen oder mehrere Reste R9 substituiert sein kann, oder eine Diarylaminogruppe, Diheteroarylaminogruppe oder Arylheteroarylaminogruppe mit 10 bis 40 aromatischen Ringatomen, welche durch einen oder mehrere Reste R9 substituiert sein kann, oder eine Kombination dieser Systeme; dabei können zwei oder mehrere dieser Substituenten R4 auch miteinander ein mono- oder polycyclisches, aliphatisches, aromatisches und/oder benzoannelliertes Ringsystem bilden; R 4 in each occurrence is independently selected from the group consisting of H, deuterium, phenyl, naphthyl, N (R 2 ) 2 , CN, CF 3 , OH, C (= O) OR 3 , C (= O) N (R 3 ) 2 , C (= O) R 3 , P (= O) (R 7 ) 2 , As (= O) (R 7 ) 2 , P (= S) (R 7 ) 2 , As (= S) (R 7 ) 2 , a linear alkyl, alkoxy or thioalkoxy group having 1 to 40 carbon atoms or a linear alkenyl or alkynyl group having 2 to 40 carbon atoms or a branched or cyclic alkyl, alkenyl, alkynyl , Alkoxy or thioalkoxy group having 3 to 40 carbon atoms, each of which may be substituted by one or more radicals R 9 , wherein one or more adjacent CH 2 groups by - R 9 C = CR 9 -, -CEC-, or an adjacent CH 2 group by -Si (R 4 ) 2 -, -Ge (R 4 ) 2 -, -Sn (R 4 ) 2 , - C (= 0) -, -C (= S) -, -C (= Se) -, -C = N-, -C (= O) O-, -C (= O) N (R 3 ) -, -P (= O) (R 7 ) -, -As (= 0) (R 7 ) -, - P (= S) (R 7 ), -As (= S) (R 7 ) -, -S (= O) -, -S (= O) 2 -, -NR 2 -, -O-, or -S- may be replaced and wherein one or more H atoms are represented by deuterium, F, Cl, B R, I, CN, CF 3 or N0 2 may be substituted, or an aromatic or heteroaromatic ring system having 5 to 60 aromatic ring atoms, each of which may be substituted by one or more R 8 , or an aryloxy or heteroaryloxy group having 5 to 60 aromatic ring atoms which may be substituted by one or more radicals R 9 , or a Diarylaminogruppe, Diheteroarylaminogruppe or Arylheteroarylaminogruppe having 10 to 40 aromatic ring atoms which may be substituted by one or more radicals R 9 , or a combination of these systems; two or more of these substituents R 4 may also together form a mono- or polycyclic, aliphatic, aromatic and / or benzoannellated ring system;
R5 ist bei jedem Auftreten unabhängig voneinander ausgewählt aus der Gruppe bestehend aus Phenyl, Naphthyl, CF3, C(=0)R3, P(=0)(R7)2, As(=0)(R7)2, eine lineare Alkyl-, Alkoxy- oder Thioalkoxygruppe mit 1 bis 40 C-Atomen oder eine lineare Alkenyl- oder Alkinylgruppe mit 2 bis 40 C-Atomen oder eine verzweigte oder cyclische Alkyl-, Alkenyl-, Alkinyl-, Alkoxy- oder Thioalkoxygruppe mit 3 bis 40 C-Atomen, die jeweils mit einem oder mehreren Resten R9 substituiert sein kann, wobei eine oder mehrere benachbarte CH2-Gruppen durch - R9C=CR9-, -CEC-, oder eine benachbarte CH2-Gruppe durch -Si(R4)2-, -Ge(R4)2-, -Sn(R4)2, - C(=0)-, -C(=S)-, -C(=Se)-, -C=N-, -C(=0)0-, -C(=0)N(R3)-, -P(=0)(R7)-, -As(=0)(R7)-, - P(=S)(R7)-, -As(=S)(R7)-, -S(=0)-, -S(=0)2-, -NR2-, -O-, oder -S- ersetzt sein können und wobei ein oder mehrere H-Atome durch Deuterium, F, Cl, Br, I, CN, CF3 oder N02 ersetzt sein können, oder ein aromatisches oder heteroaromatisches Ringsystem mit 5 bis 60 aromatischen Ringatomen, das jeweils durch einen oder mehrere Reste R9 substituiert sein kann, oder eine Aryloxy- oder Heteroaryloxygruppe mit 5 bis 60 aromatischen Ringatomen, die durch einen oder mehrere Reste R9 substituiert sein kann, oder eine Diarylaminogruppe, Diheteroarylaminogruppe oder Arylheteroarylaminogruppe mit 10 bis 40 aromatischen Ringatomen, welche durch einen oder mehrere Reste R9 substituiert sein kann, oder eine Kombination dieser Systeme; dabei können zwei oder mehrere dieser Substituenten R5 auch miteinander ein mono- oder polycyclisches, aliphatisches, aromatisches und/oder benzoannelliertes Ringsystem bilden; Each R 5 is independently selected from the group consisting of phenyl, naphthyl, CF 3 , C (= O) R 3 , P (= O) (R 7 ) 2 , As (= O) (R 7 ) 2 , a linear alkyl, alkoxy or thioalkoxy group having 1 to 40 carbon atoms or a linear alkenyl or alkynyl group having 2 to 40 carbon atoms or a branched or cyclic alkyl, alkenyl, alkynyl, alkoxy or thioalkoxy group with From 3 to 40 carbon atoms, each of which may be substituted with one or more R 9 radicals, wherein one or more adjacent CH 2 groups are represented by - R 9 C = CR 9 , -CEC, or an adjacent CH 2 group by -Si (R 4 ) 2 -, -Ge (R 4 ) 2 -, -Sn (R 4 ) 2 , - C (= 0) -, -C (= S) -, -C (= Se) - , -C = N-, -C (= O) O-, -C (= O) N (R 3 ) -, -P (= O) (R 7 ) -, -As (= O) (R 7 ) -, - P (= S) (R 7 ) -, -As (= S) (R 7 ) -, -S (= O) -, -S (= O) 2 -, -NR 2 -, - Wherein one or more H atoms may be replaced by deuterium, F, Cl, Br, I, CN, CF 3 or NO 2 , or an aromatic or heteroaromatic R i ngsystem having 5 to 60 aromatic ring atoms, each of which may be substituted by one or more radicals R 9 , or an aryloxy or heteroaryloxy group having 5 to 60 aromatic ring atoms, which may be substituted by one or more radicals R 9 , or a diarylamino group, diheteroarylamino group or arylheteroarylamino group having 10 to 40 aromatic ring atoms which may be substituted by one or more radicals R 9 , or a combination of these systems; two or more of these substituents R 5 may also together form a mono- or polycyclic, aliphatic, aromatic and / or benzoannellated ring system;
R6 ist bei jedem Auftreten unabhängig voneinander ausgewählt aus der Gruppe bestehend aus Phenyl, Naphthyl, CF3, Si(R4)3, C(=0)R3, P(=0)(R7)2, eine lineare Alkyl-, Alkoxy- oder Thioalkoxygruppe mit 1 bis 40 C-Atomen oder eine lineare Alkenyl- oder Alkinylgruppe mit 2 bis 40 C-Atomen oder eine verzweigte oder cyclische Alkyl-, Alkenyl-, Alkinyl-, Alkoxy- oder Thioalkoxygruppe mit 3 bis 40 C-Atomen, die jeweils mit einem oder mehreren Resten R9 substituiert sein kann, wobei eine oder mehrere benachbarte CH2-Gruppen durch - R9C=CR9-, -CEC-, oder eine benachbarte CH2-Gruppe durch-Si(R4)2-, -Ge(R4)2-, -Sn(R4)2, - C(=0)-, -C(=S)-, -C(=Se)-, -C=N-, -C(=0)0-, -C(=0)N(R3)-, -P(=0)(R7)-, -As(=0)(R7)-, - P(=S)(R7), -As(=S)(R7)-, -S(=0)-, -S(=0)2-, -NR2-, -O-, oder -S- ersetzt sein können und wobei ein oder mehrere H-Atome durch Deuterium, F, Cl, Br, I, CN, CF3 oder N02 ersetzt sein können, oder ein aromatisches oder heteroaromatisches Ringsystem mit 5 bis 60 aromatischen Ringatomen, das jeweils durch einen oder mehrere Reste R9 substituiert sein kann, oder eine Aryloxy- oder Heteroaryloxygruppe mit 5 bis 60 aromatischen Ringatomen, die durch einen oder mehrere Reste R* substituiert sein kann, oder eine Diarylaminogruppe, Diheteroarylaminogruppe oder Arylheteroarylaminogruppe mit 10 bis 40 aromatischen Ringatomen, welche durch einen oder mehrere Reste R9 substituiert sein kann, oder eine Kombination dieser Systeme; dabei können zwei oder mehrere dieser Substituenten R6 auch miteinander ein mono- oder polycyclisches, aliphatisches, aromatisches und/oder benzoannelliertes Ringsystem bilden; R 6 in each occurrence is independently selected from the group consisting of phenyl, naphthyl, CF 3 , Si (R 4 ) 3 , C (= O) R 3 , P (= O) (R 7 ) 2 , a linear alkyl , Alkoxy or thioalkoxy group having 1 to 40 carbon atoms or a linear alkenyl or alkynyl group having 2 to 40 carbon atoms or a branched or cyclic alkyl, alkenyl, alkynyl, alkoxy or thioalkoxy group having 3 to 40C Atoms each of which may be substituted with one or more R 9 radicals, one or more adjacent CH 2 groups being replaced by - R 9 C = CR 9 -, -CEC-, or an adjacent CH 2 - group by-Si ( R 4 ) 2 -, -Ge (R 4 ) 2 -, -Sn (R 4 ) 2 , - C (= 0) -, -C (= S) -, -C (= Se) -, -C = N-, -C (= O) O-, -C (= O) N (R 3 ) -, -P (= O) (R 7 ) -, -As (= O) (R 7 ) -, - P (= S) (R 7 ), -As (= S) (R 7 ) -, -S (= O) -, -S (= O) 2 -, -NR 2 -, -O-, or - S- may be replaced and wherein one or more H atoms may be replaced by deuterium, F, Cl, Br, I, CN, CF 3 or N0 2 , or an aromatic or heteroaromatic Ringsyst em with 5 to 60 aromatic ring atoms, each of which may be substituted by one or more radicals R 9 , or an aryloxy or heteroaryloxy group having 5 to 60 aromatic ring atoms, which may be substituted by one or more radicals R *, or a diarylamino group, A diheteroarylamino group or arylheteroarylamino group having from 10 to 40 aromatic ring atoms which may be substituted by one or more of R 9 , or a combination of these systems; two or more of these substituents R 6 may also together form a mono- or polycyclic, aliphatic, aromatic and / or benzoannellated ring system;
R7 ist bei jedem Auftreten unabhängig voneinander ausgewählt aus der Gruppe bestehend aus, Phenyl, Naphthyl, N(R2)2, CN, CF3, C(=0)OR3, C(=0)N(R3)2, Si(R4)3, C(=0)R3, eine lineare Alkyl-, Alkoxy- oder Thioalkoxygruppe mit 1 bis 40 C-Atomen oder eine lineare Alkenyl- oder Alkinylgruppe mit 2 bis 40 C-Atomen oder eine verzweigte oder cyclische Alkyl- , Alkenyl-, Alkinyl-, Alkoxy- oder Thioalkoxygruppe mit 3 bis 40 C-Atomen, die jeweils mit einem oder mehreren Resten R9 substituiert sein kann, wobei eine oder mehrere benachbarte CH2-Gruppen durch -R9C=CR9-, -C=C-, oder eine benachbarte CH2-Gruppe durch -Si(R4)2-, -Ge(R4)2-, -Sn(R4)2, -C(=0)-, -C(=S)-, -C(=Se)-, -C=N-, -C(=0)0-, - C(=0)N(R3)-, -P(=0)(R7)-, -As(=0)(R7)-, -P(=S)(R7), -As(=S)(R7)-, -S(=0)-, -S(=0)2-, -NR2-, - O-, oder -S- ersetzt sein können und wobei ein oder mehrere H-Atome durch Deuterium, F, Cl, Br, I, CN, CF3 oder N02 ersetzt sein können, oder ein aromatisches oder heteroaromatisches Ringsystem mit 5 bis 60 aromatischen Ringatomen, das jeweils durch einen oder mehrere Reste R9 substituiert sein kann, oder eine Aryloxy- oder Heteroaryloxygruppe mit 5 bis 60 aromatischen Ringatomen, die durch einen oder mehrere Reste R9 substituiert sein kann, oder eine Diarylaminogruppe, Diheteroarylaminogruppe oder Arylheteroarylaminogruppe mit 10 bis 40 aromatischen Ringatomen, welche durch einen oder mehrere Reste R3 substituiert sein kann, oder eine Kombination dieser Systeme; dabei können zwei oder mehrere dieser Substituenten R7 auch miteinander ein mono- oder polycyclisches, aliphatisches, aromatisches und/oder benzoannelliertes Ringsystem bilden; Each R 7 is independently selected from the group consisting of phenyl, naphthyl, N (R 2 ) 2 , CN, CF 3 , C (= O) OR 3 , C (= O) N (R 3 ) 2 , Si (R 4 ) 3 , C (= O) R 3 , a linear alkyl, alkoxy or thioalkoxy group having 1 to 40 carbon atoms or a linear alkenyl or alkynyl group having 2 to 40 carbon atoms or a branched or cyclic alkyl, alkenyl, alkynyl, alkoxy or thioalkoxy group having 3 to 40 carbon atoms, each of which may be substituted with one or more R 9 radicals, wherein one or more adjacent CH 2 groups is replaced by -R 9 C = CR 9 -, -C = C-, or an adjacent CH 2 group by -Si (R 4 ) 2 -, -Ge (R 4 ) 2 -, -Sn (R 4 ) 2 , -C (= 0) -, -C (= S) -, -C (= Se) -, -C = N-, -C (= O) O-, -C (= O) N (R 3 ) -, -P (= 0) (R 7 ) -, -As (= O) (R 7 ) -, -P (= S) (R 7 ), -As (= S) (R 7 ) -, -S (= 0) - , -S (= O) 2 -, -NR 2 -, - O-, or -S- may be replaced and where one or more H atoms are represented by deuterium, F, Cl, Br, I, CN, CF 3 or N0 2 may be replaced, or an aromatic or heteroaromatic ring system having 5 to 60 aromatic ring atoms, each of which may be substituted by one or more radicals R 9 , or an aryloxy or heteroaryloxy group with From 5 to 60 aromatic ring atoms which may be substituted by one or more radicals R 9 , or a diarylamino group, diheteroarylamino group or arylheteroarylamino group having from 10 to 40 aromatic ring atoms which may be substituted by one or more radicals R 3 , or a combination of these systems; two or more of these substituents R 7 may also together form a mono- or polycyclic, aliphatic, aromatic and / or benzoannellated ring system;
R8 ist bei jedem Auftreten unabhängig voneinander ausgewählt aus der Gruppe bestehend aus H, Deuterium, Phenyl, Naphthyl, F, CF3 oder ein aliphatischer, aromatischer und/oder heteroaromatischer Kohlenwasserstoffrest mit 1 bis 20 C-Atomen, in dem auch ein oder mehrere H-Atome durch F oder CF3 ersetzt sein können; dabei können zwei oder mehrere Substituenten R8 auch miteinander ein mono- oder polycyclisches, aliphatisches Ringsystem bilden; R 8 is independently selected in each occurrence from the group consisting of H, deuterium, phenyl, naphthyl, F, CF 3 or an aliphatic, aromatic and / or heteroaromatic hydrocarbon radical having 1 to 20 carbon atoms, in which also one or more H atoms can be replaced by F or CF 3 ; two or more substituents R 8 may also together form a mono- or polycyclic aliphatic ring system;
R9 ist bei jedem Auftreten unabhängig voneinander ausgewählt aus der Gruppe bestehend aus H, Deuterium, Phenyl, Naphthyl, N(R2)2, CN, CF3, N02, OH, COOH, C(=0)OR3, C(=0)N(R3)2, Si(R4)3, B(OR5)2, C(=0)R3, P(=0)(R7)2, P(=S)(R7)2, As(=0)(R7)2, P(=S)(R7)2, S(=0)R3, S(=0)2R3, OS02R3, eine lineare Alkyl-, Alkoxy- oder Thioalkoxygruppe mit 1 bis 40 C-Atomen oder eine lineare Alkenyl- oder Alkinylgruppe mit 2 bis 40 C-Atomen oder eine verzweigte oder cyclische Alkyl-, Alkenyl-, Alkinyl-, Alkoxy- oder Thioalkoxygruppe mit 3 bis 40 C-Atomen, die jeweils mit einem oder mehreren Resten R8 substituiert sein kann, wobei eine oder mehrere nicht benachbarte CH2-Gruppen durch -R3C=CR3-, -C=C-, oder eine benachbarte CH2-Gruppe durch -Si(R4)2-, -Ge(R4)2-, -Sn(R4)2, -C(=0)-, -C(=S)-, -C(=Se)-, - C=N-, -C(=0)0-, -C(=0)N(R3)-, -P(=0)(R7)-, -As(=0)(R7)-, -P(=S)(R7), -As(=S)(R7)-, -S(=0)-, -S(=0)2-, -NR2-, -O-, oder -S- ersetzt sein können und wobei ein oder mehrere H-Atome durch Deuterium, F, Cl, Br, I, CN, CF3 oder N02 ersetzt sein können, oder ein aromatisches oder heteroaromatisches Ringsystem mit 5 bis 60 aromatischen Ringatomen, das jeweils durch einen oder mehrere Reste R8 substituiert sein kann, oder eine Aryloxy- oder Heteroaryloxygruppe mit 5 bis 60 aromatischen Ringatomen, die durch einen oder mehrere Reste R3 substituiert sein kann, oder eine Diarylaminogruppe, Diheteroarylaminogruppe oder Arylheteroarylaminogruppe mit 10 bis 40 aromatischen Ringatomen, welche durch einen oder mehrere Reste R8 substituiert sein kann, oder eine Kombination dieser Systeme; dabei können zwei oder mehrere dieser Substituenten R9 auch miteinander ein mono- oder polycyclisches, aliphatisches, aromatisches und/oder benzoannelliertes Ringsystem bilden. Each R 9 is independently selected from the group consisting of H, deuterium, phenyl, naphthyl, N (R 2 ) 2 , CN, CF 3 , NO 2 , OH, COOH, C (= O) OR 3 , C (= 0) N (R 3 ) 2 , Si (R 4 ) 3 , B (OR 5 ) 2 , C (= O) R 3 , P (= O) (R 7 ) 2 , P (= S) ( R 7 ) 2 , As (= O) (R 7 ) 2 , P (= S) (R 7 ) 2 , S (= O) R 3 , S (= O) 2 R 3 , OSO 2 R 3 , a linear alkyl, alkoxy or thioalkoxy group having 1 to 40 carbon atoms or a linear alkenyl or alkynyl group having 2 to 40 carbon atoms or a branched or cyclic alkyl, alkenyl, alkynyl, alkoxy or thioalkoxy group having 3 to 40 C atoms each of which may be substituted with one or more R 8 radicals, one or more non-adjacent CH 2 groups being replaced by -R 3 C = CR 3 -, -C = C-, or an adjacent CH 2 - Group represented by -Si (R 4 ) 2 -, -Ge (R 4 ) 2 -, -Sn (R 4 ) 2 , -C (= O) -, -C (= S) -, -C (= Se) -, - C = N-, -C (= O) O-, -C (= O) N (R 3 ) -, -P (= O) (R 7 ) -, -As (= O) (R 7 ) -, -P (= S) (R 7 ), -As (= S) (R 7 ) -, -S (= O) -, -S (= O) 2 -, -NR 2 -, - O, or S he can be replaced by one or more H atoms by deuterium, F, Cl, Br, I, CN, CF 3 or N0 2 , or an aromatic or heteroaromatic ring system having 5 to 60 aromatic ring atoms, each by a or a plurality of radicals R 8 may be substituted, or an aryloxy or heteroaryloxy group having 5 to 60 aromatic ring atoms, which may be substituted by one or more radicals R 3 , or a Diarylaminogruppe, Diheteroarylaminogruppe or Arylheteroarylaminogruppe having 10 to 40 aromatic ring atoms, which one or more radicals R 8 may be substituted, or a combination of these systems; two or more of these substituents R 9 may also together form a mono- or polycyclic, aliphatic, aromatic and / or benzoannellated ring system.
2. Organisches Molekül nach Anspruch 1 , aufweisend eine Struktur der Formel 2a, 2b oder 2c 2. Organic molecule according to claim 1, having a structure of the formula 2a, 2b or 2c
Figure imgf000083_0001
Figure imgf000083_0001
Formel 2a Formel 2b Formel 2c wobei R*, R**, Y und AF2 wie in Anspruch 1 definiert sind. Formula 2a Formula 2b Formula 2c wherein R *, R **, Y and AF2 are as defined in claim 1.
3. Organisches Molekül nach Anspruch 1 oder Anspruch 2, wobei AF2 eine Struktur Formel 4 aufweist: 3. Organic molecule according to claim 1 or claim 2, wherein AF2 has a structure of formula 4:
Figure imgf000083_0002
Formel 4 wobei in Formel 4 bedeutet: p ist 0 oder 1 ; t = 4 - 2p;
Figure imgf000083_0002
Formula 4 wherein in formula 4: p is 0 or 1; t = 4 - 2p;
X ist ausgewählt aus der Gruppe bestehend aus CR**2, NR**, Sauerstoff, Schwefel, einer direkte Bindung, wobei maximal zwei Platzhalter X gleichzeitig eine direkte Bindung sind, wobei diese Platzhalter X nicht Bestandteil desselben Rings sind; und im Übrigen die in Anspruch 1 für Formel 3 genannten Definitionen gelten. X is selected from the group consisting of CR ** 2 , NR **, oxygen, sulfur, a direct bond, with a maximum of two placeholders X being simultaneously a direct bond, these placeholders X not being part of the same ring; and, moreover, the definitions given in claim 1 for formula 3 apply.
4. Organisches Molekül nach Anspruch 1 bis 3, wobei AF1 ausgewählt ist aus der Gruppe 4. Organic molecule according to claim 1 to 3, wherein AF1 is selected from the group
Figure imgf000084_0001
Figure imgf000084_0001
98 354 405 98 354 405
Unterformel 1 und die zweite chemische Einheit AF2 ausgewählt ist aus der Gruppe der nachfolgenden Verbindungen Sub-formula 1 and the second chemical entity AF2 is selected from the group of the following compounds
Figure imgf000085_0001
Figure imgf000085_0002
Figure imgf000085_0003
Figure imgf000086_0001
Figure imgf000086_0002
Figure imgf000085_0001
Figure imgf000085_0002
Figure imgf000085_0003
Figure imgf000086_0001
Figure imgf000086_0002
Figure imgf000086_0003
Figure imgf000086_0004
Figure imgf000087_0001
Figure imgf000087_0002
Figure imgf000086_0003
Figure imgf000086_0004
Figure imgf000087_0001
Figure imgf000087_0002
Figure imgf000087_0003
Figure imgf000087_0003
Figure imgf000088_0001
Figure imgf000088_0002
Figure imgf000088_0003
Figure imgf000088_0001
Figure imgf000088_0002
Figure imgf000088_0003
Figure imgf000088_0004
Figure imgf000088_0004
66
Figure imgf000089_0001
Figure imgf000089_0002
66
Figure imgf000089_0001
Figure imgf000089_0002
Figure imgf000089_0003
Figure imgf000089_0004
Figure imgf000089_0003
Figure imgf000089_0004
Figure imgf000090_0001
Figure imgf000090_0002
Figure imgf000090_0001
Figure imgf000090_0002
Figure imgf000090_0003
Figure imgf000090_0003
ı99 I99
Figure imgf000091_0001
Figure imgf000091_0001
Figure imgf000092_0001
Figure imgf000092_0002
Figure imgf000092_0003
Figure imgf000093_0001
Figure imgf000092_0001
Figure imgf000092_0002
Figure imgf000092_0003
Figure imgf000093_0001
Figure imgf000094_0001
wobei im Molekül genau eine AF1 und genau eine, dazu unterschiedliche, AF2 vorhanden ist und wobei die Anknüpfung der AF aneinander über die mit Kleinbuchstaben gekennzeichneten Positionen erfolgt.
Figure imgf000094_0001
where in the molecule exactly one AF1 and exactly one, in addition different, AF2 is present and whereby the connection of the AF takes place together over the positions indicated with lower case letters.
5. Organisches Molekül nach Anspruch 1 bis 4, wobei das Molekül eine Struktur der Formel 5a aufweist: 5. Organic molecule according to claim 1 to 4, wherein the molecule has a structure of formula 5a:
Figure imgf000095_0001
Figure imgf000095_0001
Formel 5a wobei in Formel 5a bedeutet: Formula 5a wherein in formula 5a means:
p ist 0 oder 1 ; p is 0 or 1;
t = 4 - 2p; t = 4 - 2p;
X ist CR*2, NR*, Sauerstoff, Schwefel, eine direkte Bindung, wobei maximal zwei Platzhalter X gleichzeitig eine direkte Bindung sind, wobei diese nicht Bestandteil desselben Rings sind; X is CR * 2 , NR *, oxygen, sulfur, a direct bond, with a maximum of two wildcards X being simultaneously a direct bond, which are not part of the same ring;
Y ist S02, 1 ,2-Phenylen, C=C(CN)2, 2,2'-Benzophenon-Fragment, 2,2'-Diphenyl- dicyanomethan-Fragment, BR*; Y is S0 2 , 1, 2-phenylene, C = C (CN) 2 , 2,2'-benzophenone fragment, 2,2'-diphenyldicyanomethane fragment, BR *;
R' ist R* oder ist ausgewählt aus den folgenden Einheiten, wobei maximal zwei der Reste R' gleichzeitig gleich einer der folgenden Einheiten sind:  R 'is R * or is selected from the following units, wherein a maximum of two of the radicals R' are simultaneously one of the following units:
Figure imgf000095_0002
und im Übrigen die in Anspruch 1 gegebenen Definitionen gelten.
Figure imgf000095_0002
and, moreover, the definitions given in claim 1 apply.
6. Organisches Molekül nach Anspruch 1 bis 4, wobei das Molekül eine Struktur der Formel 6a aufweist: 6. Organic molecule according to claim 1 to 4, wherein the molecule has a structure of formula 6a:
Figure imgf000096_0001
Figure imgf000096_0001
Formel 6a wobei in Formel 6a bedeutet: Formula 6a wherein in formula 6a:
p ist 0 oder 1 ; p is 0 or 1;
t = 4 - 2p; t = 4 - 2p;
X ist CR*2, NR*, Sauerstoff, Schwefel, eine direkte Bindung, wobei maximal zwei Platzhalter X gleichzeitig eine direkte Bindung sind, wobei diese nicht Bestandteil desselben Rings sind; X is CR * 2 , NR *, oxygen, sulfur, a direct bond, with a maximum of two wildcards X being simultaneously a direct bond, which are not part of the same ring;
Y ist S02, 1 ,2-Phenylen, C=C(CN)2, BR*, 2,2'-Benzophenon-Fragment, 2,2'-Diphenyl- dicyanomethan-Fragment, Y is S0 2 , 1, 2-phenylene, C = C (CN) 2 , BR *, 2,2'-benzophenone fragment, 2,2'-diphenyl-dicyanomethane fragment,
R' ist R* oder ist ausgewählt aus den folgenden Einheiten, wobei maximal zwei der Reste R' gleichzeitig gleich einer der folgenden Einheiten sind:  R 'is R * or is selected from the following units, wherein a maximum of two of the radicals R' are simultaneously one of the following units:
Figure imgf000096_0002
und im Übrigen die in Anspruch 1 gegebenen Definitionen gelten.
Figure imgf000096_0002
and, moreover, the definitions given in claim 1 apply.
7. Organisches Molekül nach Anspruch 1 bis 4, wobei das Molekül eine Struktur der Formel 7a aufweist: 7. Organic molecule according to claim 1 to 4, wherein the molecule has a structure of formula 7a:
Figure imgf000097_0001
Figure imgf000097_0001
Formel 7a wobei in Formel 7a bedeutet: Formula 7a wherein in formula 7a:
p ist 0 oder 1 ; p is 0 or 1;
t = 4 - 2p; t = 4 - 2p;
X ist CR*2, NR*, Sauerstoff, Schwefel, eine direkte Bindung, wobei maximal zwei Platzhalter X gleichzeitig eine direkte Bindung sind, wobei diese nicht Bestandteil desselben Rings sind; X is CR * 2 , NR *, oxygen, sulfur, a direct bond, with a maximum of two wildcards X being simultaneously a direct bond, which are not part of the same ring;
Y ist S02, 1 ,2-Phenylen, C=C(CN)2, BR*, 2,2'-Benzophenon-Fragment, 2,2'-Diphenyl- dicyanomethan-Fragment, Y is S0 2 , 1, 2-phenylene, C = C (CN) 2 , BR *, 2,2'-benzophenone fragment, 2,2'-diphenyl-dicyanomethane fragment,
R' ist R* oder ist ausgewählt aus den folgenden Einheiten, wobei maximal zwei der Reste R' gleichzeitig gleich einer der folgenden Einheiten sind: R 'is R * or is selected from the following units, wherein a maximum of two of the radicals R' are simultaneously one of the following units:
Figure imgf000098_0001
Figure imgf000098_0001
8. Organisches Molekül nach einem oder mehreren der Ansprüche 1 bis 7, wobei das organische Molekül an mindestens einer Position mindestens einen weiteren Rest R, insbesondere zur Steigerung der Löslichkeit und/oder der Polymerisierbarkeit, aufweist, wobei 8. Organic molecule according to one or more of claims 1 to 7, wherein the organic molecule at least one position at least one further radical R, in particular for increasing the solubility and / or the polymerizability, wherein
R ist bei jedem Auftreten unabhängig voneinander ausgewählt aus der Gruppe bestehend aus H, Deuterium, Phenyl, Naphthyl, F, Cl, Br, I, N(R2)2, -CN, -NC, -SCN, - CF3, -N02, -OH, C(=0)OH, C(=0)OR3, C(=0)N(R3)2, C(=0)SR3, C(=S)SR3, Si(R4)3, B(OR5)2, B(N(R6)2)2, C(=0)R3, P(=0)(R7)2, As(=0)(R7)2, P(=S)(R7)2, As(=S)(R7)2, S(=0)R3, S=NR3, S(=0)NR3, S(=0)2NR3, S(=0)2R3, 0-S(=0)2R3, SF5, eine lineare Alkyl-, Alkoxy- oder Thioalkoxygruppe mit 1 bis 40 C-Atomen oder eine lineare Alkenyl- oder Alkinylgruppe mit 2 bis 40 C-Atomen oder eine verzweigte oder cyclische Alkyl-, Alkenyl-, Alkinyl-, Alkoxy- oder Thioalkoxygruppe mit 3 bis 40 C- Atomen, die jeweils mit einem oder mehreren Resten R9 substituiert sein kann, wobei eine oder mehrere benachbarte CH2-Gruppen durch -R9C=CR9-, -C=C-, oder eine benachbarte CH2-Gruppe durch -Si(R4)2-, -Ge(R4)2-, -Sn(R4)2, -C(=0)-, -C(=S)-, - C(=Se)-, -C=N-, -C(=0)0-, -C(=0)N(R3)-, -P(=0)(R7)-, -As(=0)(R7)-, -P(=S)(R7)-, - As(=S)(R7)-, -S(=0)-, -S(=0)2-, -NR2-, -O-, oder -S- ersetzt sein können und wobei ein oder mehrere H-Atome durch Deuterium, F, Cl, Br, I, CN, CF3 oder N02 ersetzt sein können, oder ein aromatisches oder heteroaromatisches Ringsystem mit 5 bis 60 aromatischen Ringatomen, das jeweils durch einen oder mehrere Reste R2 substituiert sein kann, oder eine Aryloxy- oder Heteroaryloxygruppe mit 5 bis 60 aromatischen Ringatomen, die durch einen oder mehrere Reste R9 substituiert sein kann, oder eine Diarylaminogruppe, Diheteroarylaminogruppe oder Arylheteroarylaminogruppe mit 10 bis 40 aromatischen Ringatomen, welche durch einen oder mehrere Reste R9 substituiert sein kann, oder eine Kombination dieser Systeme; dabei können zwei oder mehrere dieser Substituenten R auch miteinander ein Ringsystem mit insgesamt fünf oder sechs Ringgliedern bilden; wobei R2 bis R9 definiert sind wie in Anspruch 1 ; R in each occurrence is independently selected from the group consisting of H, deuterium, phenyl, naphthyl, F, Cl, Br, I, N (R 2 ) 2 , -CN, -NC, -SCN, -CF 3 , - NO 2 , -OH, C (= O) OH, C (= O) OR 3 , C (= O) N (R 3 ) 2 , C (= O) SR 3 , C (= S) SR 3 , Si (R 4 ) 3 , B (OR 5 ) 2 , B (N (R 6 ) 2 ) 2 , C (= O) R 3 , P (= O) (R 7 ) 2 , As (= O) (R 7 ) 2 , P (= S) (R 7 ) 2 , As (= S) (R 7 ) 2 , S (= 0) R 3 , S = NR 3 , S (= 0) NR 3 , S (= 0) 2 NR 3 , S (= O) 2 R 3 , O-S (= O) 2 R 3 , SF 5 , a linear alkyl, alkoxy or thioalkoxy group having 1 to 40 C atoms or a linear alkenyl group or alkynyl group having 2 to 40 carbon atoms or a branched or cyclic alkyl, alkenyl, alkynyl, alkoxy or thioalkoxy group having 3 to 40 carbon atoms, each of which may be substituted by one or more radicals R 9 , wherein a or several adjacent CH 2 groups by -R 9 C = CR 9 -, -C = C-, or an adjacent CH 2 group by -Si (R 4 ) 2 -, -Ge (R 4 ) 2 -, - Sn (R 4 ) 2 , -C (= O) -, -C (= S) -, - C (= Se) -, -C = N-, -C (= O) O-, -C (= 0) N (R 3 ) -, -P (= O) (R 7 ) -, -As (= O) (R 7 ) -, -P (= S) (R 7 ) -, - As (= S) (R 7 ) -, -S (= 0) -, -S (= 0) 2 -, -NR 2 -, -O-, or -S- may be replaced and wherein one or more H atoms are represented by deuterium, F, Cl, Br, I, CN, CF 3 or N0 2 may be replaced, or an aromatic or heteroaromatic ring system having 5 to 60 aromatic ring atoms, each by one or more radicals R 2 or an aryloxy or heteroaryloxy group having 5 to 60 aromatic ring atoms, which may be substituted by one or more radicals R 9 , or a Diarylaminogruppe, Diheteroarylaminogruppe or Arylheteroarylaminogruppe having 10 to 40 aromatic ring atoms, which by one or more radicals R 9 , or a combination of these systems; two or more of these substituents R may together also form a ring system with a total of five or six ring members; wherein R 2 to R 9 are defined as in claim 1;
und wobei das organische Molekül über Reste, die polymerisierbare funktionelle Einheiten tragen, die mit sich selbst homopolymerisiert oder mit anderen Monomeren copolymiersiert werden können, als Polymer mit Wiederholungseinheiten nach den Formeln 8 und/oder 9 erhalten wird and wherein the organic molecule is obtained via residues carrying polymerizable functional units which can be homopolymerized with themselves or copolymerized with other monomers, as a polymer having repeating units of the formulas 8 and / or 9
Figure imgf000099_0001
Figure imgf000099_0001
Formel 8 Formel 9 mit Formula 8 Formula 9 with
gewellte Linie = Position, über die die Linkergruppe L1 oder L2 an das organische Molekül gebunden ist; wavy line = position via which the linker group L 1 or L 2 is bonded to the organic molecule;
L1 und L2 = gleiche oder verschiedene Linkergruppen, aufweisend zwischen 0 bis 20 Kohlenstoffatome; oder aufweisend eine Form -C(=0)0; L 1 and L 2 = same or different linker groups, having between 0 to 20 carbon atoms; or having a form -C (= 0) 0;
und wobei insbesondere L1 und L2 = -X-L3 mit X = O oder S; and wherein in particular L 1 and L 2 = -XL 3 with X = O or S;
L3 = eine weitere Linkergruppe ausgewählt aus der Gruppe aus einersubstituierten und unsubstituierten Alkylengruppe (linear, verzweigt oder cyclisch) und einer substituierten und unsubstituierten Arylengruppe, wobei auch Kombinationen möglich sind. L 3 = another linker group selected from the group consisting of a substituted and unsubstituted alkylene group (linear, branched or cyclic) and a substituted and unsubstituted arylene group, wherein combinations are also possible.
9. Verwendung eines organischen Moleküls nach einem oder mehreren der Ansprüche 1 bis 8 als lumineszierender Emitter und/oder als Hostmaterial und/oder als Elektronentransportmaterial und/oder als Lochinjektionsmaterial und/oder als Lochblockiermaterial in einem optoelektronischen Bauelement. 9. Use of an organic molecule according to one or more of claims 1 to 8 as a luminescent emitter and / or as a host material and / or as an electron transport material and / or as a hole injection material and / or as a hole blocking material in an optoelectronic component.
10. Verwendung nach Anspruch 9, wobei das optoelektronische Bauelement ausgewählt ist aus der Gruppe bestehend aus: 10. Use according to claim 9, wherein the optoelectronic component is selected from the group consisting of:
• organischen lichtemittierenden Dioden (OLEDs), • lichtemittierenden elektrochemischen Zellen, Organic light-emitting diodes (OLEDs), Light-emitting electrochemical cells,
• OLED-Sensoren, insbesondere in nicht hermetisch nach außen abgeschirmten Gas- und Dampf-Sensoren,  OLED sensors, especially in non-hermetically shielded gas and vapor sensors,
• organischen Dioden,  Organic diodes,
• organischen Solarzellen,  • organic solar cells,
• organischen Transistoren,  Organic transistors,
• organischen Feldeffekttransistoren,  Organic field effect transistors,
• organischen Lasern und  • organic lasers and
• Down-Konversions-Elementen.  • Down conversion elements.
1 1 . Verwendung nach Anspruch 9 oder 10, wobei der Anteil des organischen Moleküls am Emitter 1 % bis 99 % beträgt. 1 1. Use according to claim 9 or 10, wherein the proportion of the organic molecule at the emitter is 1% to 99%.
12. Verwendung nach Anspruch 9 bis 1 1 , wobei die Konzentration des organischen Moleküls als Emitter in optischen Licht emittierenden Bauelementen, insbesondere in OLEDs, zwischen 5 % und 80 % beträgt. 12. Use according to claim 9 to 1 1, wherein the concentration of the organic molecule as an emitter in optical light-emitting components, in particular in OLEDs, between 5% and 80%.
13. Optoelektronisches Bauelement, aufweisend ein organisches Molekül nach einem oder mehreren der Ansprüche 1 bis 8, insbesondere ausgeformt als ein Bauelement ausgewählt aus der Gruppe bestehend aus organischer lichtemittierender Diode (OLED), Lichtemittierender elektrochemischer Zelle, OLED-Sensor, insbesondere in nicht hermetisch nach außen abgeschirmten Gas- und Dampf-Sensoren, organischer Diode, organischer Solarzelle, organischem Transistor, organischem Feldeffekttransistor, organischem Laser und Down-Konversion-Element. 13. An optoelectronic component, comprising an organic molecule according to one or more of claims 1 to 8, in particular formed as a component selected from the group consisting of organic light emitting diode (OLED), light emitting electrochemical cell, OLED sensor, in particular in non-hermetic externally shielded gas and vapor sensors, organic diode, organic solar cell, organic transistor, organic field effect transistor, organic laser and down-conversion element.
14. Optoelektronisches Bauelement nach Anspruch 13, aufweisend ein Substrat, eine Anode und eine Kathode, wobei die Anode und die Kathode auf das Substrat aufgebracht sind, und mindestens eine lichtemittierende Schicht, welche zwischen Anode und Kathode angeordnet ist und die ein organisches Molekül nach einem oder mehreren der Ansprüche 1 bis 8 enthält. 14. An optoelectronic component according to claim 13, comprising a substrate, an anode and a cathode, wherein the anode and the cathode are applied to the substrate, and at least one light-emitting layer, which is arranged between anode and cathode and which is an organic molecule according to one or more of claims 1 to 8.
15. Optoelektronisches Bauelement nach Anspruch 13 oder 14, in dem die lichtemittierende Schicht mindestens ein Hostmaterial aufweist, wobei insbesondere der angeregte Singulettzustand (Si) und/oder der angeregte Triplettzustand (T-i) des mindestens einen Hostmaterials höher ist als der angeregte Singulettzustand (Si) und/oder der angeregte Triplettzustand (Τ-ι) des organischen Moleküls nach einem oder mehreren der Ansprüche 1 bis 8. 15. Optoelectronic component according to claim 13 or 14, in which the light-emitting layer has at least one host material, wherein in particular the excited singlet state (Si) and / or the excited triplet state (Ti) of the at least one host material is higher than the excited singlet state (Si) and / or the excited one Triplet state (Τ-ι) of the organic molecule according to one or more of claims 1 to 8.
16. Optoelektronisches Bauelement nach Anspruch 13 bis 15, wobei mindestens ein Hostmaterial aus einem Material gemäß einem oder mehreren der Ansprüche 1 bis 8 besteht. 16. Optoelectronic component according to claim 13 to 15, wherein at least one host material consists of a material according to one or more of claims 1 to 8.
17. Optoelektronisches Bauelement nach Anspruch 13 bis 16, wobei die lichtemittierende Schicht fluoreszente oder phosphoreszente Materialien aufweist und wobei die Materialien der lichtemittierenden Schicht organische Moleküle gemäß einem oder mehreren der Ansprüche 1 bis 8 sind. 17. The optoelectronic component according to claim 13, wherein the light-emitting layer has fluorescent or phosphorescent materials, and wherein the materials of the light-emitting layer are organic molecules according to one or more of claims 1 to 8.
18. Optoelektronisches Bauelement nach Anspruch 13 bis 17, in dem ein Molekül gemäß nach einem oder mehreren der Ansprüche 1 bis 8 und ein funktionelles Material einen Exciplex bilden. 18. An optoelectronic component according to claim 13 to 17, in which form a molecule according to one or more of claims 1 to 8 and a functional material an exciplex.
19. Optoelektronisches Bauelement nach Anspruch 13 bis 18, wobei die Emission durch thermisch aktivierte verzögerte Fluoreszenz (TADF) charakterisiert ist. 19. The optoelectronic component according to claim 13 to 18, wherein the emission is characterized by thermally activated delayed fluorescence (TADF).
20. Optoelektronisches Bauelement nach Anspruch 13, in dem ein organisches Molekül gemäß einem oder mehreren der Ansprüche 1 bis 8 in einer Ladungstransportschicht verwendet wird. 20. The optoelectronic component according to claim 13, in which an organic molecule according to one or more of claims 1 to 8 is used in a charge transport layer.
21 . Verfahren zur Herstellung eines optoelektronischen Bauelements, wobei ein organisches Molekül nach einem oder mehreren der Ansprüche 1 bis 8 verwendet wird. 21. Process for producing an optoelectronic component, wherein an organic molecule according to one or more of claims 1 to 8 is used.
22. Verfahren nach Anspruch 21 , wobei die Verarbeitung des organischen Moleküls mittels eines Vakuumverdampfungsverfahrens oder aus einer Lösung erfolgt. 22. The method of claim 21, wherein the processing of the organic molecule is carried out by a vacuum evaporation method or from a solution.
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