WO2016087945A3 - Strong conductive polymer microfiber and method of making the same - Google Patents

Strong conductive polymer microfiber and method of making the same Download PDF

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Publication number
WO2016087945A3
WO2016087945A3 PCT/IB2015/002467 IB2015002467W WO2016087945A3 WO 2016087945 A3 WO2016087945 A3 WO 2016087945A3 IB 2015002467 W IB2015002467 W IB 2015002467W WO 2016087945 A3 WO2016087945 A3 WO 2016087945A3
Authority
WO
WIPO (PCT)
Prior art keywords
conductive
fiber
pedot
doping
pss
Prior art date
Application number
PCT/IB2015/002467
Other languages
French (fr)
Other versions
WO2016087945A2 (en
Inventor
Jian Zhou
Er Qiang LI
Gilles LUBINEAU
Sigurdur T. THORODDSEN
Matthieu MULLE
Original Assignee
King Abdullah University Of Science And Technology
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by King Abdullah University Of Science And Technology filed Critical King Abdullah University Of Science And Technology
Priority to US15/525,005 priority Critical patent/US20170370024A1/en
Priority to EP15837134.4A priority patent/EP3227478A2/en
Publication of WO2016087945A2 publication Critical patent/WO2016087945A2/en
Publication of WO2016087945A3 publication Critical patent/WO2016087945A3/en

Links

Classifications

    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/58—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products
    • D01F6/74—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products from polycondensates of cyclic compounds, e.g. polyimides, polybenzimidazoles
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/88—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds
    • D01F6/94—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds of other polycondensation products
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D10/00—Physical treatment of artificial filaments or the like during manufacture, i.e. during a continuous production process before the filaments have been collected
    • D01D10/02—Heat treatment
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00—Formation of filaments, threads, or the like
    • D01D5/06—Wet spinning methods
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00—Formation of filaments, threads, or the like
    • D01D5/12—Stretch-spinning methods

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Artificial Filaments (AREA)
  • Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
  • Multicomponent Fibers (AREA)
  • Electroluminescent Light Sources (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Spinning Methods And Devices For Manufacturing Artificial Fibers (AREA)

Abstract

A method comprising: providing at least one first composition comprising at least one conjugated polymer and at least one solvent, wet spinning the at least one first composition to form at least one first fiber material, hot-drawing the at least one fiber to form at least one second fiber material. In lead embodiments, high-performance poly(3,4-ethylenedioxy- thiophene)/poly(styrenesulfonate) (PEDOT/PSS) conjugated polymer microfibers were fabricated via wet- spinning followed by hot-drawing. In these lead embodiments, due to the combined effects of the vertical hot-drawing process and doping/de-doping the microfibers with ethylene glycol (EG), a record electrical conductivity of 2804 S · cm-1 was achieved. This is believed to be a six-fold improvement over the best previously reported value for PEDOT/PSS fibers (467 S · cm-1) and a twofold improvement over the best values for conductive polymer films treated by EG de-doping (1418 S · cm-1). Moreover, these lead, highly conductive fibers experience a semiconductor-metal transition at 313 K. They also have superior mechanical properties with a Young's modulus up to 8.3 GPa, a tensile strength reaching 409.8 MPa and a large elongation before failure (21%). The most conductive fiber also demonstrates an extraordinary electrical performance during stretching/unstretching: the conductivity increased by 25% before the fiber rupture point with a maximum strain up to 21%. Simple fabrication of the semi-metallic, strong and stretchable wet-spun PEDOT/PSS microfibers can make them available for conductive smart electronics. A dramatic improvement in electrical conductivity is needed to make conductive polymer fibers viable candidates in applications such as flexible electrodes, conductive textiles, and fast-response sensors and actuators.
PCT/IB2015/002467 2014-12-03 2015-12-03 Semi-metallic, strong conductive polymer microfiber, method and fast response rate actuators and heating textiles WO2016087945A2 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
US15/525,005 US20170370024A1 (en) 2014-12-03 2015-12-03 Semi-metallic, strong conductive polymer microfiber, method and fast response rate actuators and heating textiles
EP15837134.4A EP3227478A2 (en) 2014-12-03 2015-12-03 Strong conductive polymer microfiber and method of making the same

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201462086885P 2014-12-03 2014-12-03
US62/086,885 2014-12-03

Publications (2)

Publication Number Publication Date
WO2016087945A2 WO2016087945A2 (en) 2016-06-09
WO2016087945A3 true WO2016087945A3 (en) 2016-07-28

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/IB2015/002467 WO2016087945A2 (en) 2014-12-03 2015-12-03 Semi-metallic, strong conductive polymer microfiber, method and fast response rate actuators and heating textiles

Country Status (3)

Country Link
US (1) US20170370024A1 (en)
EP (1) EP3227478A2 (en)
WO (1) WO2016087945A2 (en)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111556911B (en) 2017-11-06 2022-12-23 阿卜杜拉国王科技大学 Method and apparatus for preparing copolymer-wrapped nanotube fibers
CZ309078B6 (en) * 2018-05-28 2022-01-19 Contipro A.S. Device and method of producing nano- and / or microfibrous layers with increased thickness uniformity
US11877517B2 (en) * 2019-03-05 2024-01-16 North Carolina State University Flexible piezo-composite sensors and transducers
US11180867B2 (en) 2019-03-20 2021-11-23 University Of Kentucky Research Foundation Continuous wet-spinning process for the fabrication of PEDOT:PSS fibers with high electrical conductivity, thermal conductivity and Young's modulus
CN110085436B (en) * 2019-04-21 2021-08-06 北京工业大学 Preparation method of graphene/poly (ethylenedioxythiophene) composite fiber assembly
CN113217313B (en) * 2021-04-22 2022-05-17 北京航空航天大学杭州创新研究院 Response actuating device, preparation method and application
CN115437232A (en) * 2021-06-01 2022-12-06 卡西欧计算机株式会社 Exterior member, case, and timepiece
CN113701929B (en) * 2021-09-16 2022-06-14 湖南大学 SBCs-GaN micro-LED-based flexible pressure visualization sensor and preparation method thereof
CN114108132B (en) * 2021-11-17 2024-05-10 江苏大学 Preparation method of high-strength high-conductivity PEDOT fiber
CN114561718B (en) * 2022-02-28 2023-06-16 中国科学技术大学 Composite fiber material, preparation method thereof and high-stretchability fibrous supercapacitor
CN115434036A (en) * 2022-09-20 2022-12-06 江苏大学 Preparation method of spiral-structure conductive polymer fiber artificial muscle

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2004042743A1 (en) * 2002-10-30 2004-05-21 Santa Fe Science & Technology, Inc. Spinning, doping, dedoping and redoping polyaniline fiber
CN102677223B (en) * 2011-03-08 2013-12-18 北京服装学院 Wet spinning method for multi-color conductive polymer-based composite conductive fiber

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7132630B2 (en) 2002-12-02 2006-11-07 Sante Fe Science And Technology, Llc Resistive heating using polyaniline fiber
JP4945756B2 (en) 2004-08-31 2012-06-06 国立大学法人山梨大学 Polymer film or fiber deformation method and polymer actuator
JP5135757B2 (en) 2006-01-13 2013-02-06 日産自動車株式会社 Sensors and actuators using fabric made of conductive polymer
JP5256454B2 (en) 2006-02-28 2013-08-07 国立大学法人山梨大学 Method for treating conductive polymer
JP4894420B2 (en) 2006-03-16 2012-03-14 日産自動車株式会社 Ventilation variable fabric, sound-absorbing material, vehicle parts

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2004042743A1 (en) * 2002-10-30 2004-05-21 Santa Fe Science & Technology, Inc. Spinning, doping, dedoping and redoping polyaniline fiber
CN102677223B (en) * 2011-03-08 2013-12-18 北京服装学院 Wet spinning method for multi-color conductive polymer-based composite conductive fiber

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
ROUHOLLAH JALILI ET AL: "One-Step Wet-Spinning Process of Poly(3,4-ethylenedioxythiophene):Poly(styrenesulfonate) Fibers and the Origin of Higher Electrical Conductivity", ADVANCED FUNCTIONAL MATERIALS, vol. 21, no. 17, 18 July 2011 (2011-07-18), pages 3363 - 3370, XP055006193, ISSN: 1616-301X, DOI: 10.1002/adfm.201100785 *

Also Published As

Publication number Publication date
WO2016087945A2 (en) 2016-06-09
EP3227478A2 (en) 2017-10-11
US20170370024A1 (en) 2017-12-28

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