WO2016079043A1 - Compositions pesticides comprenant un composé triazole - Google Patents

Compositions pesticides comprenant un composé triazole Download PDF

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Publication number
WO2016079043A1
WO2016079043A1 PCT/EP2015/076663 EP2015076663W WO2016079043A1 WO 2016079043 A1 WO2016079043 A1 WO 2016079043A1 EP 2015076663 W EP2015076663 W EP 2015076663W WO 2016079043 A1 WO2016079043 A1 WO 2016079043A1
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Prior art keywords
phenyl
trifluoromethyl
chloro
compound
component
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PCT/EP2015/076663
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English (en)
Inventor
Florent MAZUIR
Annette SCHUSTER
Egon Haden
Frederik Menges
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BASF Agro B.V.
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Publication of WO2016079043A1 publication Critical patent/WO2016079043A1/fr

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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • A01N43/647—Triazoles; Hydrogenated triazoles
    • A01N43/653—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles

Definitions

  • Pesticidal compositions comprising a triazole compound
  • the present invention relates to pesticidal compositions and uses and methods for combatting harmful pests using the inventive compositions, such as phythopathogenic fungi and/or for the control of insects, acarids or nematodes. Furthermore, the present invention provides methods for improving the health of a plant using the inventive compositions.
  • compositions which, at a reduced total amount of active compounds applied, show improved activity against important harmful fungi, in particular for certain indications. It was a further object to provide for compositions that are useful for the control of specific pathogens in specific important crops that are often susceptible to the attack of pathogens.
  • the present invention relates to pesticidal compositions comprising,
  • component I a compound selected from the group consisting of the compounds 1-1 , I-2, I-3, I-4, I-5, I-6, I-7, I-8, I-9, 1-10, 1-1 1 , 1-12, 1-13, 1-14, 1-15, 1-16, 1-17, 1-18, 1-19, I-20, 1-21 , I- 22, I-23, I-24, I-25, I-26, I-27, I-28, I-29, I-30 and 1-31 , or the N-oxides or the agriculturally acceptable salts of each of the compounds; and 2) as component II a compound selected from the group consisting of the fungicidal compounds Azoxystrobin (F-1 ), Trifloxystrobin (F-2), Picoxystrobin (F-3), Pyraclostrobin (F- 4), Sedaxane (F-5), Penthiopyrad (F-6), Penflufen (F-7), Fluopyram (F-8), Fluxapyroxad (F- 9), Boscalid (F-1
  • component III a compound selected from the group consisting of the fungicidal compounds Azoxystrobin (F-1 ), Trifloxystrobin (F-2), Picoxystrobin (F-3), Pyraclostrobin (F-
  • the present invention relates, according to the second aspect, to compositions comprising, 1 ) as component I a compound selected from the group consisting of the compounds 1-1 , I-2, I-3, I-4, I-5, I-6, I-7, I-8, I-9, 1-10, 1-1 1 , 1-12, 1-13, 1-14, 1-15, 1-16, 1-17, 1-18, 1-19, I-20, 1-21 , I- 22, I-23, I-24, I-25, I-26, I-27, I-28, I-29, I-30 and 1-31 , or the N-oxides or the agriculturally acceptable salts of each of the compounds; and
  • component III a compound selected from the group consisting of the fungicidal compounds Azoxystrobin (F-1 ), Trifloxystrobin (F-2), Picoxystrobin (F-3), Pyraclostrobin (F- 4), Sedaxane (F-5), Penthiopyrad (F-6), Penflufen (F-7), Fluopyram (F-8), Fluxapyroxad (F- 9), Boscalid (F-10), Oxathiapiprolin (F-1 1 ), Metalaxyl (F-12), Metalaxyl-M (F-13), Ethaboxam (F-14), dimethomorph (F-15), Valifenalate(F-16), Cyproconazole (F-17), Difenoconazole (F- 18), Prothioconazole (F-19), Flutriafol (F-20), Thiabendazole (F-21 ), Ipconazole (F-22), Tebuconazole (F-23), Triadimenol (F-24), Tri
  • compositions comprising, 1 ) as component I a compound selected from the group consisting of the compounds 1-1 , I-2, I-3, I-4, I-5, I-6, I-7, I-8, I-9, 1-10, 1-1 1 , 1-12, 1-13, 1-14, 1-15, 1-16, 1-17, 1-18, 1-19, I-20, 1-21 , I- 22, I-23, I-24, I-25, I-26, I-27, I-28, I-29, I-30 and 1-31 , or the N-oxides orthe agriculturally acceptable salts of each of the compounds; and
  • component III a compound selected from the group consisting of the insecticidal compounds Fipronil (ln-1 ), 3-[benzoyl(methyl)amino]-N-[2-bromo-4-[1 ,2,2,2-tetrafluoro-1 - (trifluoromethyl)ethyl]-6-(trifluoromethyl)phenyl]-2-fluoro-benzamide (ln-2), 3-
  • the present invention relates to to pesticidal compositions comprising,
  • component I a compound selected from the group consisting of the compounds 1-1 , I-2, I-3, I-4, I-5, I-6, I-7, I-8, I-9, 1-10, 1-1 1 , 1-12, 1-13, 1-14, 1-15, 1-16, 1-17, 1-18, 1-19, I-20, 1-21 , I- 22, I-23, I-24, I-25, I-26, I-27, I-28, I-29, I-30 and 1-31 , or the N-oxides or the agriculturally acceptable salts of each of the compounds; and
  • the present invention relates to to pesticidal compositions comprising,
  • component I a compound selected from the group consisting of the compounds 1-1 , I-2, I-3, I-4, I-5, I-6, I-7, I-8, I-9, 1-10, 1-1 1 , 1-12, 1-13, 1-14, 1-15, 1-16, 1-17, 1-18, 1-19, I-20, 1-21 , I- 22, I-23, I-24, I-25, I-26, I-27, I-28, I-29, I-30 and 1-31 , or the N-oxides or the agriculturally acceptable salts of each of the compounds; and
  • insecticidal compound selected from the group consisting of (ln-10), (ln-1 1 ), (ln-12), (ln-13) and (ln-14), or the N-oxides or the agriculturally acceptable salts thereof.
  • the present invention relates to pesticidal compositions comprising,
  • component I a compound selected from the group consisting of the compounds 1-1 , I-2, I-3, I-4, I-5, I-6, I-7, I-8, I-9, 1-10, 1-1 1 , 1-12, 1-13, 1-14, 1-15, 1-16, 1-17, 1-18, 1-19, I-20, 1-21 , I- 22, I-23, I-24, I-25, I-26, I-27, I-28, I-29, I-30 and 1-31 , or the N-oxides or the agriculturally acceptable salts of each of the compounds; and
  • component III a compound selected from the group consisting of the fungicidal compounds (F-1 ), (F-2), (F-3), (F-4), (F-5), (F-6), (F-7), (F-8), (F-9), (F-10), (F-1 1 ), (F-12), (F- 13), (F-14), (F-15), (F-16), (F-17), (F-18), (F-19), (F-20), (F-21 ), (F-22), (F-23), (F-24), (F-25), (F-26), (F-27), (F-28), (F-29), (F-30), (F-31 ), (F-32), (F-33) and (F-34).
  • the present invention relates to pesticidal compositions comprising,
  • component I a compound selected from the group consisting of the compounds 1-1 , I-2, I-3, I-4, I-5, I-6, I-7, I-8, I-9, 1-10, 1-1 1 , 1-12, 1-13, 1-14, 1-15, 1-16, 1-17, 1-18, 1-19, I-20, 1-21 , I- 22, I-23, I-24, I-25, I-26, I-27, I-28, I-29, I-30 and 1-31 , or the N-oxides or the agriculturally acceptable salts of each of the compounds; and
  • component III a compound selected from the group consisting of the insecticidal compounds (ln-1 ), (ln-10), (ln-1 1 ), (ln-12), (ln-13), (ln-14), (ln-15), (ln-16), (ln-17), (ln-18), (ln-19), (ln-20), (ln-21 ), (ln-22), (ln-23), (ln-24), (ln-25), (ln-26), (ln-27), (ln-28), (ln-29), (In- 30), (ln-31 ), (ln-32), (ln-33), (ln-34) and (ln-35).
  • insecticidal compounds (ln-1 ), (ln-10), (ln-1 1 ), (ln-12), (ln-13), (ln-14), (ln-15), (ln-16), (ln-17), (ln-18), (ln-19), (ln-20), (ln-21 ), (ln-22), (ln-23
  • the components I, II and III used in the inventive compositions are further detailed and preferences and embodiments are outlined. Any of the embodiments and preferences given for a particular component can also be combined with any of the embdiments and preferences given for one or more further component/s of the inventive compositions.
  • the components I can be obtained by various routes in analogy to prior art processes known (cf. J.Agric. Food Chem. (2009) 57, 4854-4860; EP 0 275 955 A1 ; DE 40 03 180 A1 ; EP 0 1 13 640 A2; EP 0 126 430 A2).
  • Compounds 1-1 to 1-31 used as component I in the inventive compositions are the following fungicidal compounds:
  • compound 1-1 2-[2-chloro-4-(4-chlorophenoxy)phenyl]-1-(1 ,2,4-triazol-1 -yl)pent-3-yn-2-ol; compound I-2 1-[2-chloro-4-(4-chlorophenoxy)phenyl]-1-cyclopropyl-2-(1 ,2,4-triazol-1- yl)ethanol;
  • compound I-4 1-[4-(4-chlorophenoxy)-2-(trifluoromethyl)phenyl]-1-cyclopropyl-2-(1 ,2,4- triazol-1 -yl)ethanol; compound 1-5 2-[4-(4-chlorophenoxy)-2-(trifluoromethyl)phenyl]-3-methyl-1-(1 ,2,4-triazol-
  • compound I-8 1-[2-[2-chloro-4-(4-chlorophenoxy)phenyl]-2-cyclopropyl-2-methoxy-ethyl]- 1 ,2,4-triazole;
  • compound 1-1 1 1-[2-[4-(4-chlorophenoxy)-2-(trifluoromethyl)phenyl]-2-cyclopropyl-2- methoxy-ethyl]-1 ,2,4-triazole;
  • compound 1-13 1-[2-[4-(4-chlorophenoxy)-2-(trifluoromethyl)phenyl]-2-methoxy-butyl]1 ,2,4- triazole;
  • compound 1-17 2-[2-chloro-4-(4-chlorophenoxy)phenyl]-1-(1 ,2,4-triazol-1 -yl)propan-2-ol; compound 1-18 2-[2-chloro-4-(4-fluorophenoxy)phenyl]-1-(1 ,2,4-triazol-1 -yl)propan-2-ol; compound 1-19 2-[2-chloro-4-(4-chlorophenoxy)phenyl]-3-methyl-1 -(1 ,2,4-triazol-1-yl)butan-
  • compound I-20 1-[2-[2-chloro-4-(4-chlorophenoxy)phenyl]-2-methoxy-propyl]-1 ,2,4-triazole; compound 1-21 1-[2-[2-chloro-4-(4-chlorophenoxy)phenyl]-2-methoxy-butyl]-1 ,2,4-triazole; compound I-22 1-[2-[2-chloro-4-(4-chlorophenoxy)phenyl]-2-methoxy-pentyl]-1 ,2,4-triazole; compound I-23 2-[2-chloro-4-(4-chlorophenoxy)phenyl]-1 ,1 ,1 -trifluoro-3-(1 ,2,4-triazol-1 - yl)propan-2-ol;
  • compound I-25 2-[2-chloro-4-(4-chlorophenoxy)phenyl]-1-(1 ,2,4-triazol-1 -yl)pent-4-yn-2-ol; compound I-26 2-[2-chloro-4-(4-chlorophenoxy)phenyl]-1 -methoxy-3-(1 ,2,4-triazol-1 - yl)propan-2-ol;
  • compound I-28 2-[4-(4-chlorophenoxy)-2-(trifluoromethyl)phenyl]-1-(1 ,2,4-triazol-1- yl)pentan-2-ol; compound 1-29 2-[4-(4-fluorophenoxy)-2-(trifluoromethyl)phenyl]-1-(1 ,2,4-triazol-1- yl)propan-2-ol;
  • Compounds 1-1 to 1-31 comprise chiral centers and they are generally obtained in the form of racemates.
  • the R- and S- enantiomers of the compounds contained as component I in the compositions according to the invention can be separated and isolated in pure form with methods known by the skilled person, e.g. by using chiral HPLC. Suitable for use in the compositions are both the enantiomers and compositions thereof.
  • said components I can be present in different crystal modifications, which may differ in biological activity.
  • a racemic composition of the respective components I namely of compound 1-1 , I-2, I-3, I-4, I-5, I-6, I-7, I-8, I-9, 1-10, 1-1 1 , 1-12, 1-13, 1-14, 1-15, 1-16, 1-17, 1-18, 1-19, I-20, 1-21 , I-22, I-23, I-24, I-25, I-26, I-27, I-28, I-29, I-30 or 1-31 , respectively, is present.
  • the (R)-enantiomer of compound I-3 is (R)-2-[4-(4-chlorophenoxy)-2-(trifluoromethyl)phenyl]-1 -(1 ,2,4-triazol-1- yl)propan-2-ol;
  • the S-enantiomer of I-3 is (S)-2-[4-(4-chlorophenoxy)-2- (trifluoromethyl)phenyl]-1-(1 ,2,4-triazol-1-yl)propan-2-ol. This applies to the other compounds accordingly.
  • the respective compound 1-1 , I-2, I-3, I-4, I-5, I-6, I-7, I-8, I-9, 1-10, 1-1 1 , 1-12, 1-13, 1-14, 1-15, 1-16, 1-17, 1-18, 1-19, I-20, 1-21 , I-22, I-23, I-24, I-25, I- 26, I-27, I-28, I-29, I-30 or 1-31 , respectively, is provided and used as (R)-enantiomer with an enantiomeric excess (e.e.) of at least 40%, for example, at least 50%, 60%, 70% or 80%, preferably at least 90%, more preferably at least 95%, yet more preferably at least 98% and most preferably at least 99%.
  • an enantiomeric excess e.e.
  • the respective compound 1-1 , I-2, I-3, I-4, I-5, I-6, I-7, I-8, I-9, 1-10, 1-1 1 , 1-12, 1-13, 1-14, 1-15, 1-16, 1-17, 1-18, 1-19, I-20, 1-21 , I-22, I-23, I-24, I-25, I-26, I-27, I-28, I-29, I-30 or 1-31 , respectively, is provided and used as (S)-enantiomer with an enantiomeric excess (e.e.) of at least 40%, for example, at least 50%, 60%, 70% or 80%, preferably at least 90%, more preferably at least 95%, yet more preferably at least 98% and most preferably at least 99%.
  • an enantiomeric excess e.e.
  • component I is compound 1-1 .
  • component I is compound I-2.
  • component I is compound I-3.
  • component I is compound I-4.
  • component I is compound I-5.
  • o he nvention componen I is compound 1-6.
  • o he nvention componen I is compound 1-7.
  • o he nvention componen I is compound 1-8.
  • o he nvention componen I is compound 1-9.
  • o he nvention componen I is compound 1-10.
  • o he nvention componen I is compound 1-1 1.
  • o he nvention componen I is compound 1-12.
  • o he nvention componen I is compound 1-13.
  • o he nvention componen I is compound 1-14.
  • o he nvention componen I is compound 1-15.
  • o he nvention componen I is compound 1-16.
  • component is compound I- 17.
  • o he nvention componen I is compound 1-18.
  • o he nvention componen I is compound 1-19.
  • o he nvention componen I is compound I-20.
  • o he nvention componen I is compound 1-21.
  • o he nvention componen I is compound I-22.
  • o he nvention componen I is compound I-23.
  • o he nvention componen I is compound I-24.
  • o he nvention componen I is compound I-25.
  • o he nvention componen I is compound I-26.
  • o he nvention componen I is compound I-27.
  • o he nvention componen I is compound I-28.
  • o he nvention componen I is compound I-29.
  • o he nvention componen I is compound I-30.
  • o he nvention componen I is compound 1-31.
  • component I is selected from compounds 1-1 , I-2, I-3, I-4, I-5, I-6, I-7, I-8, I-9, 1-1 1 , 1-13, 1-14, 1-15 and 1-16. According to a more particular embodiment of the present invention, component I is selected from compounds 1-1 , I-2, I-6 and I-8. According to another more particular embodiment of the present invention, component I is selected from compounds I-3, I-4, I-5, I-7, I-9, 1-1 1 , 1-13, I- 14, 1-15 and 1-16. According to still a further embodiment of the present invention, component I is selected from compounds 1-1 , I-2, I-3, I-4, I-5 and 1-13. According to still a further embodiment of the present invention, component I is selected from compounds 1-1 , I-4 and I- 13. According to still a further embodiment of the present invention, component I is selected from compounds I-3 and I-5.
  • component I is selected from compounds 1-17, 1-18, 1-19, I-20, 1-21 , I-22, I-23, I-24, I-25, I-26, I-27, I-28, I-29, I-30 and 1-31.
  • pesticides II and III of chemical nature described by their common names, their preparation and their biological activity e. g. against harmful fungi, pests or weed is known (cf.: http://www.alanwood.net/pesticides/); these substances are commercially available and known, for example, from the references below:
  • azoxystrobin methyl 2- ⁇ 2-[6-(2-cyano-1 -vinylpenta-1 ,3-dienyloxy)pyrimidin-4-yloxy]phenyl ⁇ -3- methoxyacrylate (EP 382 375); trifloxystrobin, methyl (E)-methoxyimino- ⁇ (E)-a-[1-(a,a,a- trifluoro-m-tolyl)ethylideneaminooxy]-o-tolyl ⁇ acetate (EP 460 575); picoxystrobin, methyl 3- methoxy-2-[2-(6-trifluoromethylpyridin-2-yloxymethyl)phenyl]acrylate (EP 278 595); pyraclo- strobin, methyl /V-[2-[1-(4-chlorophenyl)-1 H-pyrazol-3-yloxymethyl]phenyl ⁇ (/V-methoxy)carba- mate (WO 96/01256);
  • the compounds used in the compositions of the present invention may be capable of forming salts or adducts with inorganic or organic acids or with metal ions, in particular salts with inorganic acids or N-oxides. Also the use of said compounds as salt and/or N-oxide in the inventive compositions is encompassed by the present invention.
  • inorganic acids examples include hydrohalic acids, such as hydrogen fluoride, hydrogen chloride, hydrogen bromide and hydrogen iodide, carbonic acid, sulfuric acid, phosphoric acid and nitric acid.
  • Suitable organic acids are, for example, formic acid and alkanoic acids, such as acetic acid, trifluoroacetic acid, trichloroacetic acid and propionic acid, and also glycolic acid, thiocyanic acid, lactic acid, succinic acid, citric acid, benzoic acid and other arylcarboxylic acids, cinnamic acid, oxalic acid, alkylsulfonic acids (sulfonic acids having straight-chain or branched alkyl radicals of 1 to 20 carbon atoms), arylsulfonic acids or aryldisulfonic acids (aromatic radicals, such as phenyl and naphthyl, which carry one or two sulfonic acid groups), alkylphosphonic acids (phosphonic acids having straight-chain or branched alkyl radicals with 1 to 20 carbon atoms), arylphosphonic acids or aryldiphosphonic acids (aromatic radicals, such as phenyl and naph
  • Suitable metal ions are in particular the ions of the elements of the second main group, in particular calcium and magnesium, of the third and fourth main group, in particular aluminum, tin and lead, and also of the elements of transition groups one to eight, in particular chromium, manganese, iron, cobalt, nickel, copper, zinc, and others.
  • N-oxide includes any compound used in the compositions of the present invention which has at least one tertiary nitrogen atom that is oxidized to an N- oxide moiety.
  • N-oxides of compounds of the present invention can in particular be prepared by oxidizing a ring nitrogen atom(s) of a heterocyclic ring with a suitable oxidizing agent, such as peroxo carboxylic acids or other peroxides. The person skilled in the art knows if and in which positions N-oxides may be formed.
  • each row corresponds to one embodiment of the compositions according to the invention, i.e. one specifically individualized composition with the name of the respective composition given in the first column of the respective row in the table (e.g. T1 -3).
  • said compositions are ternary compositions, containing onle these three components given in the respective row of the table as active compounds.
  • every combination of the compositions individualized in the tables represent embodiments of the present invention.
  • compositions comprising,
  • component I a compound selected from the group consisting of the compounds 1-1 , I-2, I-3, I-4, I-5, I-6, I-7, I-8, I-9, 1-10, 1-1 1 , 1-12, 1-13, 1-14, 1-15, 1-16, 1-17, 1-18, 1-19, I-20, 1-21 , I- 22, I-23, I-24, I-25, I-26, I-27, I-28, I-29, I-30 and 1-31 ; and
  • components II and III compounds independently selected from the group consisting of the fungicidal compounds (F-1 ), (F-2), (F-3), (F-4), (F-5), (F-6), (F-7), (F-8), (F- 9), (F-10), (F-1 1 ), (F-12), (F-13), (F-14), (F-15), (F-16), (F-17), (F-18), (F-19), Flutriafol (F- 20), (F-21 ), (F-22), (F-23), (F-24), (F-25), (F-26), (F-27), (F-28), (F-29), (F-30), (F-31 ), (F-32), (F-33) and (F-34), (wherein components II and III are different active ingredients.
  • component II is selected from the fungicidal compounds Azoxystrobin (F-1 ), Trifloxystrobin (F-2), Picoxystrobin (F-3) and Pyraclostrobin (F-4), and component III is selected from from the fungicidal compounds Sedaxane (F-5), Penthiopyrad (F-6), Penflufen (F-7), Fluopyram (F-8), Fluxapyroxad (F-9), Boscalid (F-10), Oxathiapiprolin (F-1 1 ), Metalaxyl (F-12), Metalaxyl-M (F-13), Ethaboxam (F-14), dimethomorph (F-15), Valifenalate(F-16), Cyproconazole (F-17), Difenoconazole (F-18), Prothioconazole (F-19), Flutriafol (F-20), Thiabendazole (F-21 ), Ipconazole (F-22), Tebuconazole (F-23), Triadadax
  • component II is (F-1) and component III is selected from from the fungicidal compounds (F-5), (F-11), (F-12), (F-13), (F-15) and (F- 21).
  • component II is (F-4), and
  • component III is selected from from the fungicidal compounds (F-5), (F-7), (F-8), (F-11), (F- 12), (F-13), (F-14), (F-15), (F-22), (F-27), (F-28), (F-32) and (F-34), more specifically component III is selected from (F-5), (F-7), (F-8), (F-11), (F-12), (F-13), (F-14), (F-15), (F-22), (F-32) and (F-34).
  • any of said compositions are ternary compositions that contain components I, II and III as only active ingredients.
  • compositions according to the invention are individualized.
  • Table T1 Three-component compositions comprising one component I ("I"), one component II (“II”) and one component III ("III"), in particular ternary compositions containing the respective components I, II and III as only active ingredients.
  • component II is selected from the fungicidal compounds Sedaxane (F-5), Penthiopyrad (F-6), Penflufen (F-7), Fluopyram (F-8), Fluxapyroxad (F-9) and Boscalid (F-10), and component III is selected from the fungicidal compounds
  • Triticonazole F-27
  • Fludioxinil F-28
  • Carboxin F-29
  • Silthiofarm F-30
  • Ziram F-31
  • Thiram F-32
  • Carbendazim F-33
  • Thiophanate-methyl F-34
  • component II is (F-8), and component III is selected from the fungicidal compounds (F-12), (F-13), (F-15), (F-19), (F-22), (F-27) and (F-34).
  • component II is Fluxapyroxad (F-9) and
  • component III is selected from the fungicidal compounds (F-1 1 ), (F-12), (F-13), (F-14), (F- 15), (F-21 ), (F-22), (F-26), (F-27), (F-28), (F-30), (F-32) and (F-34), in particular, component III is selected from (F-1 1 ), (F-12), (F-13), (F-14), (F-15), (F-21 ), (F-22), (F-26), (F-30), (F-32) and (F-34).
  • component II is Boscalid (F-10) and component III is selected from the fungicidal compounds (F-1 1 ), (F-12), (F-13), (F-14), (F-15), (F-21 ), (F- 22), (F-26), (F-27), (F-28), (F-30), (F-32) and (F-34).
  • Table T2 Three-component compositions comprising one component I ("I"), one component II (“II”) and one component III ("III"), in particular ternary compositions containing the respective components I, II and III as only active ingredients.
  • component II is selected from the fungicidal compounds Oxathiapiprolin (F-1 1 ), Metalaxyl (F-12), Metalaxyl-M (F-13), Ethaboxam (F-14), dimethomorph (F-15) and Valifenalate(F-16), and component III is selected from the fungicidal compounds Cyproconazole (F-17), Difenoconazole (F-18), Prothioconazole (F-19), Flutriafol (F-20), Thiabendazole (F-21 ), Ipconazole (F-22), Tebuconazole (F-23), Triadimenol (F-24), Prochloraz (F-25), Fluquinconazole (F-26), Triticonazole (F-27), Fludioxinil (F-28), Carboxin (F-29), Silthiofarm (F-30), Ziram (F-31 ), Thiram (F-32), Carbendazim (F-33) and Thio
  • component II is selected from the fungicidal compounds (F-12), -M (F-13), (F-14) and (F-15), and component III is selected from the fungicidal compounds (F-19), (F-22), (F-25), (F-27), (F-28), (F-32) and (F-34).
  • Table T3 Three-component compositions comprising one component I ("I"), one component II (“II”) and one component III ("III"), in particular ternary compositions containing the respective components I, II and III as only active ingredients.
  • T3-83 1-1 F-15 F-27 T3-122 I-3 F-1 1 F-30 T3-161 I-3 F-13 F-33
  • T3-31 1 I-5 F-16 F-21 T3-317 I-5 F-16 F-27 T3-323 I-5 F-16 F-33
  • component II is selected from the fungicidal compounds Cyproconazole (F-17), Difenoconazole (F-18), Prothioconazole (F-19), Flutriafol (F-20), Thiabendazole (F-21 ), Ipconazole (F-22), Tebuconazole (F-23), Triadimenol (F-24), Prochloraz (F-25), Fluquinconazole (F-26) and Triticonazole (F-27), and component III is selected from the fungicidal compounds Fludioxinil (F-28), Carboxin (F-29), Silthiofarm (F- 30), Ziram (F-31 ), Thiram (F-32), Carbendazim (F-33) and Thiophanate-methyl (F-34).
  • component II is (F-19) and component III is selected from the fungicidal compounds (F-28) and (F-34), in particular component III is (F- 34).
  • component II is (F-22) and component III is (F-34).
  • component II is (F-23) and component III is selected from the fungicidal compounds (F-28) and (F-29), in particular (F-29).
  • component II is (F-27) and component III is (F-29).
  • Table T4 Three-component compositions comprising one component I ("I"), one component II (“II”) and one component III ("III"), in particular ternary compositions containing the respective components I, II and III as only active ingredients.
  • T4-61 1-1 F-25 F-32 T4-100 I-3 F-20 F-29 T4-139 I-3 F-25 F-33
  • T4-62 1-1 F-25 F-33 T4-101 I-3 F-20 F-30 T4-140 I-3 F-25 F-34
  • component II is the fungicidal compound Fludioxinil (F-28) and component III is selected from the fungicidal compounds Carboxin (F-29),
  • component II is compound (F-30) and
  • component III is selected from the fungicidal compounds (F-29), (F-31 ), (F-32), (F-33) and (F-34).
  • component II is (F-29)
  • component III is selected from the fungicidal compounds (F-31 ), (F-32), (F-33) and (F-34).
  • Table T5 Three-component compositions comprising one component I ("I"), one component II (“II”) and one component III ("III"), in particular ternary compositions containing the respective components I, II and III as only active ingredients.
  • compositions comprising,
  • component I a compound selected from the group consisting of the compounds 1-1 , I-2, I-3, I-4, I-5, I-6, I-7, I-8, I-9, 1-10, 1-1 1 , 1-12, 1-13, 1-14, 1-15, 1-16, 1-17, 1-18, 1-19, I-20, 1-21 , I-
  • component III a compound selected from the group consisting of the fungicidal compounds Azoxystrobin (F-1 ), Trifloxystrobin (F-2), Picoxystrobin (F-3), Pyraclostrobin (F- 4), Sedaxane (F-5), Penthiopyrad (F-6), Penflufen (F-7), Fluopyram (F-8), Fluxapyroxad (F- 9), Boscalid (F-10), Oxathiapiprolin (F-1 1 ), Metalaxyl (F-12), Metalaxyl-M (F-13), Ethaboxam (F-14), dimethomorph (F-15), Valifenalate(F-16), Cyproconazole (F-17), Difenoconazole (F- 18), Prothioconazole (F-19), Flutriafol (F-20), Thiabendazole (F-21 ), Ipconazole (F-22), Tebuconazole (F-23), Triadimenol (F-24), Tri
  • Triticonazole F-27
  • Fludioxinil F-28
  • Carboxin F-29
  • Silthiofarm F-30
  • Ziram F-31
  • Thiram F-32
  • Carbendazim F-33
  • Thiophanate-methyl F-34
  • component II is selected from the insecticidal compounds (ln-1 ), (ln-15), (ln-16), (ln-17), (ln-18), (ln-19), (ln-20), (ln-21 ), (ln-22), (ln-23), (ln-24), (ln-25), (ln-26), (ln-27), (ln-28), (ln-29), (ln-30), (ln-31 ), (ln-32), (ln-33) and (ln-34); and component III is selected from the fungicidal compounds (F-1 ), (F-2), (F-3), (F-4), (F-5), (F-6), (F-7), (F-8), (F-9), (F-10), (F-1 1 ), (F-12), (F-13), (F-14), (F-15), (F-16), (F-17), (F-18), (F-19), (F-20), (F-21 ), (F-22), (F-23), (F-24), (F-25), (F-F-34); and
  • component II is (ln-1 ), and component III is selected from the fungicidal compounds (F-8), (F-12), (F-13), (F-15), (F-22), (F-27), (F-28), (F-30) and (F-34).
  • component II is selected from the insecticidal compounds (ln-15), (ln-16) and (ln-19); and component III is selected from the fungicidal compounds (F-8), (F-12), (F-13), (F-15), (F-22), (F-27), (F-28), (F-30) and (F- 34).
  • component II is (ln-20); and component III is selected from the fungicidal compounds (F-1 ), (F-2), (F-4), (F-6), (F-8), (F- 9), (F-10), (F-12), (F-13), (F-15), (F-18), (F-19), (F-22), (F-23), (F-27), (F-28), (F-30) and (F- 34).
  • component II is (ln-21 ), and component III is selected from the fungicidal compounds (F-4), (F-9), (F-10), (F-12), (F-15), (F-27) and (F-34).
  • component II is selected from the insecticidal compounds (ln-29) and (ln-30); and component I II is selected from the fungicidal compounds (F-4), (F-9), (F-10), (F-15), (F-18), (F-27) and (F-34).
  • Table T6 Three-component compositions comprising one component I ("I"), one component II (“II”) and one component III ("III"), in particular ternary compositions containing the respective components I, II and III as only active ingredients. compocompocompo ⁇
  • T6-250 1-1 ln-21 F-12
  • T6-290 1-1 ln-22 F-18
  • T6-330 1-1 ln-23 F-24
  • T6-280 1-1 ln-22 F-8
  • T6-320 1-1 ln-23 F-14
  • T6-360 1-1 ln-24 F-20
  • T6-370 1-1 ln-24 F-30
  • T6-410 1-1 ln-26 F-2
  • T6-450 1-1 ln-27 F-8
  • T6-380 1-1 ln-25 F-6
  • T6-420 1-1 ln-26 F-12
  • T6-460 1-1 ln-27 F-18
  • T6-394 1-1 ln-25 F-20
  • T6-434 1-1 ln-26 F-26
  • T6-474 1-1 ln-27 F-32
  • T6-404 1-1 ln-25 F-30
  • T6-444 1-1 ln-27 F-2
  • T6-484 1-1 ln-28 F-8
  • T6-500 1-1 ln-28 F-24
  • T6-540 1-1 ln-29 F-30
  • T6-580 1-1 ln-31 F-2
  • T6-503 1-1 ln-28 F-27
  • T6-543 1-1 ln-29 F-33
  • T6-583 1-1 ln-31 F-5
  • T6-642 1-1 ln-32 F-30
  • T6-682 1-1 ln-34 F-2
  • T6-722 I-3 ln-1 F-8
  • T6-880 I-3 ln-18 F-30
  • T6-920 I-3 ln-20 F-2
  • T6-960 I-3 ln-21 F-8

Abstract

La présente invention concerne des compositions pesticides et des utilisations et des procédés de lutte contre des animaux nuisibles à l'aide des compositions de l'invention, tels que des champignons phythopathogènes et/ou pour la lutte contre les insectes, les acariens ou les nématodes. En outre, la présente invention concerne des procédés pour améliorer la santé d'une plante à l'aide des compositions de l'invention.
PCT/EP2015/076663 2014-11-18 2015-11-16 Compositions pesticides comprenant un composé triazole WO2016079043A1 (fr)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106035380A (zh) * 2016-06-27 2016-10-26 中国烟草总公司郑州烟草研究院 含苯甲酰胺类、二硝基苯胺类杀菌剂和生防菌的菌药组合物、制剂及应用
US10512267B2 (en) 2013-07-08 2019-12-24 BASF Agro, B.V. Compositions comprising a triazole compound and a biopesticide
US10519122B2 (en) 2013-01-09 2019-12-31 BASF Agro B.V. Process for the preparation of substituted oxiranes and triazoles
WO2020120206A3 (fr) * 2018-12-11 2020-07-23 BASF Agro B.V. Procédé de lutte contre un champignon phytopathogène choisi parmi des espèces de phakopsora. du soja par des compositions comprenant du méfentrifluconazole
US11185078B2 (en) 2016-02-09 2021-11-30 Basf Se Mixtures and compositions comprising Paenibacillus strains or metabolites thereof and other biopesticides

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10519122B2 (en) 2013-01-09 2019-12-31 BASF Agro B.V. Process for the preparation of substituted oxiranes and triazoles
US10981883B2 (en) 2013-01-09 2021-04-20 BASF Agro B.V. Process for the preparation of substituted oxiranes and triazoles
US10512267B2 (en) 2013-07-08 2019-12-24 BASF Agro, B.V. Compositions comprising a triazole compound and a biopesticide
US11185078B2 (en) 2016-02-09 2021-11-30 Basf Se Mixtures and compositions comprising Paenibacillus strains or metabolites thereof and other biopesticides
CN106035380A (zh) * 2016-06-27 2016-10-26 中国烟草总公司郑州烟草研究院 含苯甲酰胺类、二硝基苯胺类杀菌剂和生防菌的菌药组合物、制剂及应用
WO2020120206A3 (fr) * 2018-12-11 2020-07-23 BASF Agro B.V. Procédé de lutte contre un champignon phytopathogène choisi parmi des espèces de phakopsora. du soja par des compositions comprenant du méfentrifluconazole

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