WO2016078995A1 - Compositions pesticides - Google Patents

Compositions pesticides Download PDF

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Publication number
WO2016078995A1
WO2016078995A1 PCT/EP2015/076388 EP2015076388W WO2016078995A1 WO 2016078995 A1 WO2016078995 A1 WO 2016078995A1 EP 2015076388 W EP2015076388 W EP 2015076388W WO 2016078995 A1 WO2016078995 A1 WO 2016078995A1
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WO
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Prior art keywords
compound
component
compositions
phenyl
chlorophenoxy
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PCT/EP2015/076388
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English (en)
Inventor
Frederik Menges
Markus Gewehr
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BASF Agro B.V.
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Publication of WO2016078995A1 publication Critical patent/WO2016078995A1/fr

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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • A01N43/647—Triazoles; Hydrogenated triazoles
    • A01N43/653—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles

Definitions

  • compositions comprising,
  • compositions comprising,
  • component I a compound selected from the following compounds 1-1 to 1-31 :
  • compound 1-1 2-[2-chloro-4-(4-chlorophenoxy)phenyl]-1 -(1 ,2,4-triazol-1 -yl)pent-3-yn-2-ol; compound I-2 1 -[2-chloro-4-(4-chlorophenoxy)phenyl]-1 -cyclopropyl-2-(1 ,2,4-triazol-1 - yl)ethanol;
  • compound I-8 1 -[2-[2-chloro-4-(4-chlorophenoxy)phenyl]-2-cyclopropyl-2-methoxy-ethyl]- 1 ,2,4-triazole;
  • compound 1-1 1 1 -[2-[4-(4-chlorophenoxy)-2-(trifluoromethyl)phenyl]-2-cyclopropyl-2-methoxy- ethyl]-1 ,2,4-triazole;
  • compound 1-13 1 -[2-[4-(4-chlorophenoxy)-2-(trifluoromethyl)phenyl]-2-methoxy-butyl]1 ,2,4- triazole;
  • compound 1-15 1 -[2-[4-(4-chlorophenoxy)-2-(trifluoromethyl)phenyl]-2-methoxy- pent-3-ynyl]-1 ,2,4-triazole; compound 1-16 2-[4
  • X is CI or F
  • the invention also relates to pesticidal compositions comprising, 1) as component I a compound selected from the compounds 1-1 to 1-31 as defined above; and 2) as component II a compound seleceted from (ll)-1 and (ll)-2 as defined above; and 3) as component III a further pesticide.
  • Component III is preferably a compound selected from the following groups A) to E): A) Respiration inhibitors
  • -Inhibitors of complex III at Q 0 site e. g. strobilurins: azoxystrobin (F-1 ), dimoxystrobin (F-2), fluoxastrobin (F-3), kresoxim-methyl (F-4), metominostrobin (F-5), orysastrobin (F-6), pyraclostrobin (F-7), trifloxystrobin (F-8), famoxadone (F-9), fenamidone (F-10);
  • azoxystrobin F-1
  • dimoxystrobin F-2
  • fluoxastrobin F-3
  • kresoxim-methyl F-4
  • metominostrobin F-5
  • orysastrobin F-6
  • pyraclostrobin F-7
  • trifloxystrobin F-8
  • F-9 famoxadone
  • F-10 fenamidone
  • -inhibitors of complex II e. g. carboxamides: benodanil (F-1 1 ), bixafen (F-12), boscalid (F-13), carboxin (F-14), fenfuram (F-15), fluopyram (F-16), flutolanil (F-17), fluxapyroxad (F-18), furametpyr (F-19), isopyrazam (F-20), mepronil (F-21 ), oxycarboxin (F-22), penthiopyrad (F-23), thifluzamide (F-24);
  • complex II e. g. carboxamides
  • benodanil F-1 1
  • bixafen F-12
  • boscalid F-13
  • carboxin F-14
  • fenfuram F-15
  • fluopyram F-16
  • flutolanil F-17
  • fluxapyroxad F-18
  • furametpyr F-19
  • isopyrazam F-20
  • mepronil F-21
  • C14 demethylase inhibitors (DMI fungicides): triazoles: azaconazole (F-25), bitertanol (F- 26), bromuconazole (F-27), cyproconazole (F-28), difenoconazole (F-29), diniconazole (F-30), epoxiconazole (F-31 ), fenbuconazole (F-32), fluquinconazole (F-33), flusilazole (F-34), flutriafol (F-35), hexaconazole (F-36), imibenconazole (F-37), ipconazole (F-38), metconazole (F-39), myclobutanil (F-40), oxpoconazole (F-41 ), penconazole (F-42), propiconazole (F-43), prothio- conazole (F-44), simeconazole (F-45), tebu
  • Delta14-reductase inhibitors dodemorph (F-57), fenpropimorph (F-58), tridemorph (F-59), fenpropidin (F-60), spiroxamine (F-61 );
  • phenylamides or acyl amino acid fungicides metalaxyl (F-63);
  • tubulin inhibitors such as benzimidazoles, thiophanates: benomyl (F-64), carbendazim (F- 65), fuberidazole (F-66), thiabendazole (F-67), thiophanate-methyl (F-68);
  • diethofencarb F-69
  • the invention furthermore relates to the use of the inventive compositions as pesticides in particular for controlling phytopathogenic fungi as detained herein and preparations or compositions comprising them.
  • the invention furthermore also relates to seed comprising the compositions.
  • the invention furthermore also relates to methods for controlling pests, in particular phytopathogenic fungi as detained herein, wherein the fungi or the materials, plants, the soil or seed to be protected from fungal attack are treated with an effective amount of a compositions according to the invention.
  • the invention furthermore also relates to processes for preparing the compositions according to the invention.
  • compositions which, at a reduced total amount of active compounds applied, show improved activity against important pests, in particular phythopathogenic fungi, in particular for certain indications. It was a further object to provide for compositions that are useful for the control of specific pathogens in specific important crops that are often susceptible to the attack of pathogens.
  • the compounds I can be obtained by various routes in analogy to prior art processes known (cf. J.Agric. Food Chem. (2009) 57, 4854-4860; EP 0 275 955 A1 ; DE 40 03 180 A1 ; EP 0 1 13 640 A2; EP 0 126 430 A2). Furthermore, compounds I (component I), its preparation and use in crop protection are described in WO 2013/007767
  • Compounds 1-1 to 1-31 used as component I in the inventive compositions are the following fungicidal compounds:
  • compound ⁇ 20 1 -[2-[2-chloro-4-(4-chlorophenoxy)phenyl]-2-methoxy-propyl]-1 ,2,4-triazole; compound ⁇ 21 1 -[2-[2-chloro-4-(4-chlorophenoxy)phenyl]-2-methoxy-butyl]-1 ,2,4-triazole; compound ⁇ 22 1 -[2-[2-chloro-4-(4-chlorophenoxy)phenyl]-2-methoxy-pentyl]-1 ,2,4-triazole; compound ⁇ 23 2-[2-chloro-4-(4-chlorophenoxy)phenyl]-1 ,1 ,1 -trifluoro-3-(1 ,2,4-triazol-1 - yl)propan-2-ol;
  • Compounds 1-1 to 1-31 comprise chiral centers and they are generally obtained in the form of racemates.
  • the R- and S-enantiomers of the compounds contained as component I in the compositions according to the invention can be separated and isolated in pure form with methods known by the skilled person, e.g. by using chiral HPLC. Suitable for use in the compositions are both the enantiomers and compositions thereof. Furthermore, said
  • components I can be present in different crystal modifications, which may differ in biological activity.
  • a racemic composition of the respective components I namely of compound 1-1 , I-2, I-3, I-4, I-5, I-6, I-7, I-8, I-9, 1-10, 1-1 1 , 1-12, 1-13, 1-14, 1-15, 1-16, 1-17, 1-18, I- 19, I-20, 1-21 , I-22, I-23, I-24, I-25, I-26, I-27, I-28, I-29, I-30 or 1-31 , respectively, is present.
  • the (R)-enantiomer of compound I- 3 is (R)-2-[4-(4-chlorophenoxy)-2-(trifluoromethyl)phenyl]-1 -(1 ,2,4-triazol-1 -yl)propan-2-ol;
  • the S- enantiomer of I-3 is (S)-2-[4-(4-chlorophenoxy)-2-(trifluoromethyl)phenyl]-1 -(1 ,2,4-triazol-1 - yl)propan-2-ol. This applies to the other compounds accordingly.
  • the respective compound 1-1 , I-2, I-3, I-4, I-5, I-6, I-7, I-8, I-9, 1-10, 1-1 1 , 1-12, 1-13, 1-14, 1-15, 1-16, 1-17, 1-18, 1-19, I-20, 1-21 , I-22, I-23, I-24, I-25, I-26, I-27, I-28, I-29, I-30 or 1-31 , respectively, is provided and used as (R)-enantiomer with an
  • the respective compound 1-1 , I-2, I-3, I-4, I-5, I-6, I-7, I-8, I-9, 1-10, 1-1 1 , 1-12, 1-13, 1-14, 1-15, 1-16, 1-17, 1-18, I- 19, I-20, 1-21 , I-22, I-23, I-24, I-25, I-26, I-27, I-28, I-29, I-30 or 1-31 , respectively, is provided and used as (S)-enantiomer with an enantiomeric excess (e.e.) of at least 40%, for example, at least 50%, 60%, 70% or 80%, preferably at least 90%, more preferably at least 95%, yet more preferably at least 98% and most preferably at least 99%.
  • component I is compound 1-1.
  • component I is compound I-2.
  • component I is compound I-3.
  • component I is compound I-4.
  • componen is compound I-5.
  • componen is compound
  • componen is compound I-7.
  • componen is compound I-8.
  • componen is compound I-9.
  • componen is compound 1-10.
  • componen is compound 1-11.
  • componen is compound 1-12.
  • componen is compound 1-13.
  • componen is compound 1-14.
  • componen is compound 1-15.
  • componen is compound 1-16.
  • component is compound 1-17.
  • component 1 is compound 1-18.
  • component 1 is compound 1-19.
  • component 1 is compound I-20.
  • component 1 is compound 1-21.
  • component 1 is compound I -22.
  • component 1 is compound I-23.
  • component 1 is compound I -24.
  • component 1 is compound I -25.
  • component 1 is compound I-26.
  • component 1 is compound I -27.
  • component 1 is compound I -28.
  • component 1 is compound I-29.
  • component 1 is compound I-30.
  • component 1 is compound 1-31.
  • component I is selected from compounds 1-1 , I-2, I-3, I-4, I-5, I-6, I-7, I-8, I-9, 1-1 1 , 1-13, 1-14, 1-15 and 1-16. According to a more particular embodiment of the present invention, component I is selected from compounds 1-1 , I-2, I-6 and I-8. According to another more particular embodiment of the present invention, component I is selected from compounds I-3, I-4, I-5, I-7, I-9, 1-1 1 , 1-13, 1-14, 1-15 and 1-16. According to still a further embodiment of the present invention, component I is selected from compounds 1-1 , I-2, I-3, I-4, I-5 and 1-13. According to still a further embodiment of the present invention, component I is selected from compounds 1-1 , I-4 and 1-13. According to still a further embodiment of the present invention, component I is selected from compounds I-3 and I-5.
  • component I is selected from compounds 1-17, 1-18, 1-19, I-20, 1-21 , I-22, I-23, I-24, I-25, I-26, I-27, I-28, I-29, I-30 and 1-31.
  • the component II is a compound of formula (II):
  • compositions can be found in e.g. in WO 201 1/070771 ; WO 2012/165499; WO 2012/169523 and WO 2014/061197.
  • X in component (II) is CI (also named compound (ll)-1 ).
  • X in component (II) is F (also named compound (ll)-2).
  • Compounds (ll)-1 and (ll)-2 comprise three chiral centers and they are generally obtained in the form of racemates or as diastereomer mixtures. Therefore, the compound (ll)-1 or (ll)-2, respectively, has various stereoisomers (enantiomers or diastereomers), and consists of a stereoisomer mixture or a single stereoisomer depending on its composition.
  • diastereomers/enantiomers of the compounds (II) can be separated and isolated in pure form, for example, on the basis of their different solubilities or by column chromatography. Using known methods, such uniform pairs of diastereomers can be used to obtain uniform
  • stereoisomers component II it is possible to use at least one of the stereoisomers component II in the inventove compositions. Furthermore, said components II can be present in different crystal modifications, which may differ in biological activity.
  • the active compounds F-1 to F-70, their preparation and their action against harmful fungi are mostly known (cf.: http://www.alanwood.net/pesticides/) and mainly commercially available. Commercially available active compounds can be found, for example, in The Pesticide Manual, 14th Edition, British Crop Protection Council (2006) and other publications.
  • inorganic acids examples include hydrohalic acids, such as hydrogen fluoride, hydrogen chloride, hydrogen bromide and hydrogen iodide, carbonic acid, sulfuric acid, phosphoric acid and nitric acid.
  • Suitable organic acids are, for example, formic acid and alkanoic acids, such as acetic acid, trifluoroacetic acid, trichloroacetic acid and propionic acid, and also glycolic acid, thiocyanic acid, lactic acid, succinic acid, citric acid, benzoic acid and other arylcarboxylic acids, cinnamic acid, oxalic acid, alkylsulfonic acids (sulfonic acids having straight-chain or branched alkyl radicals of 1 to 20 carbon atoms), arylsulfonic acids or aryldisulfonic acids (aromatic radicals, such as phenyl and naphthyl, which carry one or two sulfonic acid groups), alkylphosphonic acids (phosphonic acids having straight-chain or branched alkyl radicals with 1 to 20 carbon atoms), arylphosphonic acids or aryldiphosphonic acids (aromatic radicals, such as phenyl and naph
  • Suitable metal ions are in particular the ions of the elements of the second main group, in particular calcium and magnesium, of the third and fourth main group, in particular aluminum, tin and lead, and also of the elements of transition groups one to eight, in particular chromium, manganese, iron, cobalt, nickel, copper, zinc, and others. Particular preference is given to the metal ions of the elements of transition groups of the fourth period.
  • the metals can be present in the various valencies that they can assume.
  • compositions and their preferred uses are further described.
  • the use of the composition for controlling a particular phytopathogenic fungus is also meant to encompass the respective method for controlling the particular phytopathogenic fungi, wherein the fungi or the materials, plants, the soil or seed to be protected from fungal attack are treated with an effective amount of a composition as defined in that particular context.
  • the present invention relates to two-component compositions, i.e. compositions comprising component I, i.e in particular a compound selected from compounds I- 1 , I-2, I-3, I-4, I-5, I-6, I-7, I-8, I-9, 1-10, 1-1 1 , 1-12, 1-13, 1-14, 1-15, 1-16, 1-17, 1-18, 1-19, I-20, 1-21 , I-22, I-23, I-24, I-25, I-26, I-27, I-28, I-29, I-30 and 1-31 , or any group of compounds I detailled above, and component II selected from compounds (ll)-1 and (ll)-2.
  • component II selected from compounds (ll)-1 and (ll)-2.
  • the composition may, of course, contain any kind of additive or the like as detailled below in order to provide a formulation suitable for use in agriculture.
  • the weight ratio of component I to component II in the inventive compositions is preferably from 1000:1 to 1 :1000, more specifically 500:1 to 1 :500, particularly 100:1 to 1 :100.
  • the weight ratio of component I to component II generally depends from the properties of the active substances used and is usually in the range of from 1 :100 to 100:1 , frequently in the range of from 1 :50 to 50:1 , preferably in the range of from 1 :20 to 20:1 , particularly preferably in the range of from 1 :10 to 10:1 , in particular in the range of from 1 :3 to 3:1. It may also be preferable for the weight ratio to be in the range of from 1 :2 to 2: 1.
  • two-component compositions according to the invention may preferably have weight ratios of compound I versus compound II in the range of from 1000:1 to 1 :1 , often in the range of from 100:1 to 1 :1 , regularly in the range of from 50:1 to 1 :1 , preferably in the range of from 20:1 to 1 :1 , more preferably in the range of from 10:1 to 1 :1 , even more preferably in the range of from 4:1 to 1 :1 and in particular in the range of from 2:1 to 1 :1.
  • two-component compositions according to the invention may preferably have weight ratios of compound I versus compound II usually is in the range of from 1 :1 to 1000, often in the range of from 1:1 to 1 :100, regularly in the range of from 1:1 to 1 :50, preferably in the range of from 1:1 to 1 :20, more preferably in the range of from 1:1 to 1:10, even more preferably in the range of from 1:1 to 1:4 and in particular in the range of from 1:1 to 1:2.
  • compositions of the invention are compiled in Table B1 , wherein each row corresponds to one embodiment of the compositions according to the invention, i.e. one specific individualized composition. According to one specific aspect, these are binary compositions which each only contain these two components as active compounds. Furthermore, also every combination of the compositions individualized in this table represent embodiments of the present invention.
  • Table B1 Two-component compositions B1-1 to B1-62 comprising one component I and one component II, in particular binary compositions containing the respective component I and II as only active ingredients:
  • component II selected from compounds (ll)-1 and (ll)-2 compoI II compoI II
  • B1-21 1-21 (ll)-1 B1-42 1-11 (ll)-2 One embodiment of the invention relates to any one of compositions B1-1 to B1-62 wherein the weight ratio of component I to component II is from 1000:1 to 1 :1000.
  • One further embodiment of the invention relates to any one of compositions B1 -1 to B1 -62 wherein the weight ratio of component I to component II is from 500:1 to 1 :500.
  • One further embodiment of the invention relates to any one of compositions B1 -1 to B1 -62 wherein the weight ratio of component I to component II is from 100:1 to 1 : 100.
  • One further embodiment of the invention relates to any one of compositions B1 -1 to B1 -62 wherein the weight ratio of component I to component II is from 1 :100 to 100:1.
  • One further embodiment of the invention relates to any one of compositions B1 -1 to B1 -62 wherein the weight ratio of component I to component II is from 1 :50 to 50:1 .
  • One further embodiment of the invention relates to any one of compositions B1 -1 to B1 -62 wherein the weight ratio of component I to component II is from 1 :20 to 20:1 .
  • One further embodiment of the invention relates to any one of compositions B1 -1 to B1 -62 wherein the weight ratio of component I to component II is from 1 : 10 to 10:1 .
  • One further embodiment of the invention relates to any one of compositions B1 -1 to B1 -62 wherein the weight ratio of component I to component II is from 1 :3 to 3:1.
  • One further embodiment of the invention relates to any one of compositions B1 -1 to B1 -62 wherein the weight ratio of component I to component II is from 1 :2 to 2:1.
  • One further embodiment of the invention relates to any one of compositions B1 -1 to B1 -62 wherein the weight ratio of component I to component II is from 1000:1 to 1 :1 .
  • One further embodiment of the invention relates to any one of compositions B1 -1 to B1 -62 wherein the weight ratio of component I to component II is from 100:1 to 1 :1 .
  • One further embodiment of the invention relates to any one of compositions B1 -1 to B1 -62 wherein the weight ratio of component I to component II is from 50:1 to 1 :1.
  • One further embodiment of the invention relates to any one of compositions B1 -1 to B1 -62 wherein the weight ratio of component I to component II is from 20:1 to 1 :1.
  • One further embodiment of the invention relates to any one of compositions B1 -1 to B1 -62 wherein the weight ratio of component I to component II is from 10:1 to 1 :1.
  • One further embodiment of the invention relates to any one of compositions B1 -1 to B1 -62 wherein the weight ratio of component I to component II is from 4:1 to 1 :1.
  • One further embodiment of the invention relates to any one of compositions B1 -1 to B1 -62 wherein the weight ratio of component I to component II is from 2:1 to 1 :1.
  • One further embodiment of the invention relates to any one of compositions B1 -1 to B1 -62 wherein the weight ratio of component I to component II is from 1 :1 to 1000.
  • One further embodiment of the invention relates to any one of compositions B1 -1 to B1 -62 wherein the weight ratio of component I to component II is from 1 :1 to 1 :100.
  • One further embodiment of the invention relates to any one of compositions B1 -1 to B1 -62 wherein the weight ratio of component I to component II is from 1 :1 to 1 :50.
  • One further embodiment of the invention relates to any one of compositions B1 -1 to B1 -62 wherein the weight ratio of component I to component II is from 1 :1 to 1 :20.
  • One further embodiment of the invention relates to any one of compositions B1 -1 to B1 -62 wherein the weight ratio of component I to component II is from 1 :1 to 1 :10.
  • One further embodiment of the invention relates to any one of compositions B1 -1 to B1 -62 wherein the weight ratio of component I to component II is from 1 :1 to 1 :4.
  • One further embodiment of the invention relates to any one of compositions B1 -1 to B1 -62 wherein the weight ratio of component I to component II is from 1 :1 to 1 :2.
  • the present invention relates to pesticidal compositions comprising, 1 ) as component I a compound selected from the compounds 1-1 to 1-31 and the N- oxides and the agriculturally acceptable salts of each of the compounds, as defined above; and 2) as component II a compound selected from compounds (ll)-1 and (ll)-2 and the N-oxides and the agriculturally acceptable salts of each of the compounds, as defined above; and 3) as component III a compound preferably selected from the compounds F-1 to F-70 of groups A to E:
  • -Inhibitors of complex III at Q 0 site e. g. strobilurins: azoxystrobin (F-1 ), dimoxystrobin (F-2), fluoxastrobin (F-3), kresoxim-methyl (F-4), metominostrobin (F-5), orysastrobin (F-6), pyraclostrobin (F-7), trifloxystrobin (F-8), famoxadone (F-9), fenamidone (F-10);
  • azoxystrobin F-1
  • dimoxystrobin F-2
  • fluoxastrobin F-3
  • kresoxim-methyl F-4
  • metominostrobin F-5
  • orysastrobin F-6
  • pyraclostrobin F-7
  • trifloxystrobin F-8
  • F-9 famoxadone
  • F-10 fenamidone
  • -inhibitors of complex II e. g. carboxamides: benodanil (F-1 1 ), bixafen (F-12), boscalid (F-13), carboxin (F-14), fenfuram (F-15), fluopyram (F-16), flutolanil (F-17), fluxapyroxad (F-18), furametpyr (F-19), isopyrazam (F-20), mepronil (F-21 ), oxycarboxin (F-22), penthiopyrad (F-23), thifluzamide (F-24);
  • complex II e. g. carboxamides
  • benodanil F-1 1
  • bixafen F-12
  • boscalid F-13
  • carboxin F-14
  • fenfuram F-15
  • fluopyram F-16
  • flutolanil F-17
  • fluxapyroxad F-18
  • furametpyr F-19
  • isopyrazam F-20
  • mepronil F-21
  • C14 demethylase inhibitors (DMI fungicides): triazoles: azaconazole (F-25), bitertanol (F- 26), bromuconazole (F-27), cyproconazole (F-28), difenoconazole (F-29), diniconazole (F-30), epoxiconazole (F-31 ), fenbuconazole (F-32), fluquinconazole (F-33), flusilazole (F-34), flutriafol (F-35), hexaconazole (F-36), imibenconazole (F-37), ipconazole (F-38), metconazole (F-39), myclobutanil (F-40), oxpoconazole (F-41 ), penconazole (F-42), propiconazole (F-43), prothio- conazole (F-44), simeconazole (F-45), tebu
  • Delta14-reductase inhibitors dodemorph (F-57), fenpropimorph (F-58), tridemorph (F-59), fenpropidin (F-60), spiroxamine (F-61 ); Inhibitors of 3-keto reductase: fenhexamid (F-62);
  • phenylamides or acyl amino acid fungicides metalaxyl (F-63);
  • tubulin inhibitors such as benzimidazoles, thiophanates: benomyl (F-64), carbendazim (F- 65), fuberidazole (F-66), thiabendazole (F-67), thiophanate-methyl (F-68);
  • diethofencarb F-69
  • pesticides III of chemical nature described by their common names, their preparation and their biological activity e. g. against harmful fungi, pests or weed is known (cf.:
  • compositions may, of course, contain any kind of additive or the like as detained below in order to provide a formulation suitable for use in agriculture.
  • the weight ratio of component I to the 1 st further active compound (component II) depends on the properties of the active compounds in question and may particularly be 1000:1 to 1 :1000, specifically 500:1 to 1 :500. Preferably, it is in the range of from 1 :100 to 100:1 , preferably in the range of from 1 :50 to 50:1 and in particular in the range of from 1 :20 to 20:1. It may be preferable for the weight ratio to be in the region of from 1 :10 to 10:1 , preferably from 1 :3 to 3:1 , in particular from 1 :2 to 2:1.
  • the weight ratio of component I to the 2 nd further active compound (component III) may particularly be 1000:1 to 1 :1000, specifically 500:1 to 1 :500. It is preferably in the range of from 1 :100 to 100:1 , preferably in the range of from 1 :50 to 50:1 and in particular in the range of from 1 :20 to 20:1 . It may be preferable for the weight ratio to be in the region of from 1 :10 to 10:1 , preferably from 1 :3 to 3:1 , in particular from 1 :2 to 2:1.
  • the weight ratio of 1 st further active compound may particularly be 1000:1 to 1 :1000, specifically 500:1 to 1 :500. It is preferably in the range of from 1 :100 to 100:1 , preferably in the range of from 1 :50 to 50:1 and in particular in the range of from 1 :20 to 20:1 . It may be preferable for the weight ratio to be in the region of from 1 :10 to 10:1 ,
  • component II to 2 nd further active compound (component III) is preferably in the range of from 1 :100 to 100:1 , frequently in the range of from 1 :50 to 50:1 , preferably in the range of from 1 :20 to 20:1 , and in particular in the range of from 1 :10 to 10:1 . It may be preferable for the weight to be in the range of from 1 :3 to 3:1 , in particular from 1 :2 to 2:1.
  • bitertanol (F-26) triflumizole (F-53)
  • the present invention relates to any one of the compositions B1-1 to B1-62 further component III a compounds selecetd from F1 to F-70 detained above.
  • compositions of the invention are compiled in Table T1 , wherein each row corresponds to one embodiment of the compositions according to the invention, i.e. one specific individualized composition. According to one specific aspect, these are ternary compositions which each only contain these three components as active compounds.
  • compositions individualized in this table represent embodiments of the present invention.
  • Table T1 Three-component compositions T1 -1 to T1-420 comprising one component I, one component II and one component III, in particular ternary compositions containing the respective components I, II and III as only active ingredients:
  • component II selected from compounds (ll)-1 and (ll)-2 as described above
  • component III component III selected from F-1 to F-70 as defined above compoI II III compoI II III sition sition
  • compositions T1a-1 to T1a-140 correspond to compositions T1-1 to T1-140, with the difference, that component I is I-2 instead of 1-1.
  • compositions T1a-141 to T1a-280 correspond to compositions T1-141 to T1-280, with the difference, that component I is I-4 instead of I-3.
  • compositions T1a-281 to T1a-420 correspond to compositions T1-281 to T1-420, with the difference, that component I is I-6 instead of I-5.
  • compositions T1b-1 to T1b-140 correspond to compositions T1-1 to ⁇ -140, with the difference, that component I is I-7 instead of 1-1.
  • compositions T1 b-141 to T1b-280 correspond to compositions T1-141 to T1-280, with the difference, that component I is I-8 instead of I-3.
  • compositions T1b-281 to T1b-420 correspond to compositions T1-281 to T1-420, with the difference, that component I is I-9 instead of I-5.
  • compositions T1c-1 to T1c-140 correspond to compositions T1-1 to T1-140, with the difference, that component I is 1-10 instead of 1-1.
  • compositions T1c-141 to T1c-280 correspond to compositions T1-141 to T1-280, with the difference, that component I is 1-11 instead of I-3.
  • compositions T1c-281 to T1c-420 correspond to compositions T1-281 to T1-420, with the difference, that component I is 1-12 instead of I-5.
  • compositions T1d-1 to T1d-140 correspond to compositions T1-1 to T1-140, with the difference, that component I is 1-13 instead of 1-1.
  • compositions T1d-141 to T1d-280 correspond to compositions T1-141 to T1-280, with the difference, that component I is 1-14 instead of I-3.
  • compositions T1d-281 to T1d-420 correspond to compositions T1-281 to T1-420, with the difference, that component I is 1-15 instead of I-5.
  • compositions T1e-1 to T1e-140 correspond to compositions T1-1 to T1-140, with the difference, that component I is 1-16 instead of 1-1.
  • Compositions T1 e-141 to T1 e-280 correspond to compositions T1 -141 to T1-280, with the difference, that component I is 1-17 instead of I-3.
  • compositions T1 e-281 to T1 e-420 correspond to compositions T1 -281 to T1-420, with the difference, that component I is 1-18 instead of I-5.
  • compositions T1f-1 to T1 f-140 correspond to compositions T1 -1 to T1 -140, with the difference, that component I is 1-19 instead of 1-1.
  • compositions T1M41 to T1f-280 correspond to compositions T1-141 to T1 -280, with the difference, that component I is I-20 instead of I-3.
  • compositions T1f-281 to T1f-420 correspond to compositions T1-281 to T1 -420, with the difference, that component I is 1-21 instead of I-5.
  • compositions T1g-1 to T1 g-140 correspond to compositions T1-1 to T1 -140, with the difference, that component I is I-22 instead of 1-1.
  • compositions T1 g-141 to T1 g-280 correspond to compositions T1 -141 to T1-280, with the difference, that component I is I-23 instead of I-3.
  • compositions T1 g-281 to T1 g-420 correspond to compositions T1 -281 to T1-420, with the difference, that component I is I-24 instead of i-5.
  • compositions T1 h-1 to T1 h-140 correspond to compositions T1-1 to T1 -140, with the difference, that component I is I-25 instead of 1-1.
  • compositions T1 h-141 to T1 h-280 correspond to compositions T1 -141 to T1-280, with the difference, that component I is I-26 instead of i-3.
  • compositions T1 h-281 to T1 h-420 correspond to compositions T1 -281 to T1-420, with the difference, that component I is I-27 instead of i-5.
  • compositions T1 i-1 to T1 i-140 correspond to compositions T1 -1 to T1-140, with the difference, that component I is I-28 instead of 1-1.
  • compositions T1 i-141 to T1 i-280 correspond to compositions T1 -141 to T1 -280, with the difference, that component I is I-29 instead of i-3.
  • compositions T1 i-281 to T1 i-420 correspond to compositions T1-281 to T1 -420, with the difference, that component I is I-30 instead of I-5.
  • compositions T1j-1 to T1 j-140 correspond to compositions T1 -1 to T1-140, with the difference, that component I is 1-31 instead of 1-1.
  • component I seceted from 1-1 to 1-31 , in particular selected from 1-1 , I-3 and I-5) with III (selected from F-1 to F-70) are novel.
  • the invention according to a further aspect relates to the novel pesticidal two- component compositions comprising, 1 ) as component I a compound selected from the compounds 1-1 to 1-31 and the N-oxides and the agriculturally acceptable salts of each of the compounds, as defined above; and 2) as component II a compound selected from compounds F-1 to F-70, and the N-oxides and the agriculturally acceptable salts of each of the compounds.
  • the weight ratio of component I to component II in these inventive compositions is preferably from 1000:1 to 1 :1000, more specifically 500:1 to 1 :500, particularly 100:1 to 1 :100.
  • the weight ratio of component I to component II generally depends from the properties of the active substances used and is usually in the range of from 1 :100 to 100:1 , frequently in the range of from 1 :50 to 50:1 , preferably in the range of from 1 :20 to 20:1 , particularly preferably in the range of from 1 :10 to 10:1 , in particular in the range of from 1 :3 to 3:1. It may also be preferable for the weight ratio to be in the range of from 1 :2 to 2:1.
  • said two-component compositions according to the invention may preferably have weight ratios of compound I versus compound II in the range of from 1000:1 to 1 :1 , often in the range of from 100:1 to 1 :1 , regularly in the range of from 50:1 to 1 :1 , preferably in the range of from 20:1 to 1 :1 , more preferably in the range of from 10:1 to 1 :1 , even more preferably in the range of from 4:1 to 1 :1 and in particular in the range of from 2:1 to 1 :1.
  • said two-component compositions according to the invention may preferably have weight ratios of compound I versus compound II usually is in the range of from 1 :1 to 1000, often in the range of from 1 :1 to 1 :100, regularly in the range of from 1 :1 to 1 :50, preferably in the range of from 1 :1 to 1 :20, more preferably in the range of from 1 :1 to 1 :10, even more preferably in the range of from 1 :1 to 1 :4 and in particular in the range of from 1 :1 to 1 :2.
  • compositions of this aspect of the invention are compiled in Table B2, wherein each row corresponds to one embodiment of the compositions according to the invention, i.e. one specific individualized composition. According to one specific aspect, these are binary compositions which each only contain these two components as active compounds. Furthermore, also every combination of the compositions individualized in this table represent embodiments of the present invention.
  • Table B2 Two-component compositions B2-1 to B2-210 comprising one component I and one component II, in particular binary compositions containing the respective component I and II as only active ingredients:
  • I component I selected from compounds 1-1 , I-3 and I-5
  • component II selected from compounds F-1 to F-70 compoI II compoI II compoI II sition sition sition sition
  • One embodiment of the invention relates to any one of compositions B2-1 to B2-210 wherein the weight ratio of component I to component II is from 1000:1 to 1 :1000.
  • One further embodiment of the invention relates to any one of compositions B2-1 to B2-210 wherein the weight ratio of component I to component II is from 500:1 to 1 :500.
  • One further embodiment of the invention relates to any one of compositions B2-1 to B2-210 wherein the weight ratio of component I to component II is from 100:1 to 1 : 100.
  • One further embodiment of the invention relates to any one of compositions B2-1 to B2-210 wherein the weight ratio of component I to component II is from 1 : 100 to 100:1.
  • One further embodiment of the invention relates to any one of compositions B2-1 to B2-210 wherein the weight ratio of component I to component II is from 1 :50 to 50:1 .
  • One further embodiment of the invention relates to any one of compositions B2-1 to B2-210 wherein the weight ratio of component I to component II is from 1 :20 to 20:1 .
  • One further embodiment of the invention relates to any one of compositions B2-1 to B2-210 wherein the weight ratio of component I to component II is from 1 : 10 to 10:1 .
  • One further embodiment of the invention relates to any one of compositions B2-1 to B2-210 wherein the weight ratio of component I to component II is from 1 :3 to 3:1.
  • One further embodiment of the invention relates to any one of compositions B2-1 to B2-210 wherein the weight ratio of component I to component II is from 1 :2 to 2:1.
  • One further embodiment of the invention relates to any one of compositions B2-1 to B2-210 wherein the weight ratio of component I to component II is from 1000:1 to 1 :1 .
  • One further embodiment of the invention relates to any one of compositions B2-1 to B2-210 wherein the weight ratio of component I to component II is from 100:1 to 1 :1 .
  • One further embodiment of the invention relates to any one of compositions B2-1 to B2-210 wherein the weight ratio of component I to component II is from 50:1 to 1 :1.
  • One further embodiment of the invention relates to any one of compositions B2-1 to B2-210 wherein the weight ratio of component I to component II is from 20:1 to 1 :1.
  • One further embodiment of the invention relates to any one of compositions B2-1 to B2-210 wherein the weight ratio of component I to component II is from 10:1 to 1 :1.
  • One further embodiment of the invention relates to any one of compositions B2-1 to B2-210 wherein the weight ratio of component I to component II is from 4:1 to 1 :1.
  • One further embodiment of the invention relates to any one of compositions B2-1 to B2-210 wherein the weight ratio of component I to component II is from 2:1 to 1 :1.
  • One further embodiment of the invention relates to any one of compositions B2-1 to B2-210 wherein the weight ratio of component I to component II is from 1 :1 to 1000.
  • One further embodiment of the invention relates to any one of compositions B2-1 to B2-210 wherein the weight ratio of component I to component II is from 1 :1 to 1 :100.
  • One further embodiment of the invention relates to any one of compositions B2-1 to B2-210 wherein the weight ratio of component I to component II is from 1 :1 to 1 :50.
  • One further embodiment of the invention relates to any one of compositions B2-1 to B2-210 wherein the weight ratio of component I to component II is from 1 :1 to 1 :20.
  • One further embodiment of the invention relates to any one of compositions B2-1 to B2-210 wherein the weight ratio of component I to component II is from 1 :1 to 1 :10.
  • One further embodiment of the invention relates to any one of compositions B2-1 to B2-210 wherein the weight ratio of component I to component II is from 1 :1 to 1 :4.
  • One further embodiment of the invention relates to any one of compositions B2-1 to B2-210 wherein the weight ratio of component I to component II is from 1 :1 to 1 :2.
  • the invention according to a further aspect relates to the novel pesticidal two-component compositions comprising, 1) as component I a compound selected from the compounds (ll)-1 and (ll)-2, and the N-oxides and the agriculturally acceptable salts of each of the compounds, as defined above; and 2) as component II a compound selected from compounds F-1 to F-70, and the N-oxides and the agriculturally acceptable salts of each of the compounds.
  • the weight ratio of component I to component II in these inventive compositions is preferably from 1000:1 to 1 :1000, more specifically 500:1 to 1 :500, particularly 100:1 to 1 :100.
  • the weight ratio of component I to component II generally depends from the properties of the active substances used and is usually in the range of from 1 :100 to 100:1 , frequently in the range of from 1 :50 to 50:1 , preferably in the range of from 1 :20 to 20:1 , particularly preferably in the range of from 1 :10 to 10:1 , in particular in the range of from 1 :3 to 3:1. It may also be preferable for the weight ratio to be in the range of from 1 :2 to 2:1.
  • said two-component compositions according to the invention may preferably have weight ratios of compound I versus compound II in the range of from 1000:1 to 1 :1 , often in the range of from 100:1 to 1 :1 , regularly in the range of from 50:1 to 1 :1 , preferably in the range of from 20:1 to 1 :1 , more preferably in the range of from 10:1 to 1 :1 , even more preferably in the range of from 4:1 to 1 :1 and in particular in the range of from 2:1 to 1 :1.
  • said two-component compositions according to the invention may preferably have weight ratios of compound I versus compound II usually is in the range of from 1 :1 to 1000, often in the range of from 1 :1 to 1 :100, regularly in the range of from 1 :1 to 1 :50, preferably in the range of from 1 :1 to 1 :20, more preferably in the range of from 1 :1 to 1 :10, even more preferably in the range of from 1 :1 to 1 :4 and in particular in the range of from 1 :1 to 1 :2.
  • compositions of this aspect of the invention are compiled in Table B2, wherein each row corresponds to one embodiment of the compositions according to the invention, i.e. one specific individualized composition. According to one specific aspect, these are binary compositions which each only contain these two components as active compounds. Furthermore, also every combination of the compositions individualized in this table represent embodiments of the present invention.
  • Table B2 Two-component compositions B3-1 to B3-140 comprising one component I and one component II, in particular binary compositions containing the respective component I and II as only active ingredients:
  • component II selected from compounds F-1 to F-70 compoI II compoI II compoI II sition sition sition sition
  • One embodiment of the invention relates to any one of compositions B3-1 to B3-140 wherein the weight ratio of component I to component II is from 1000:1 to 1 :1000.
  • One further embodiment of the invention relates to any one of compositions B3-1 to B3-140 wherein the weight ratio of component I to component II is from 500:1 to 1 :500.
  • One further embodiment of the invention relates to any one of compositions B3-1 to B3-140 wherein the weight ratio of component I to component II is from 100:1 to : 00.
  • One further embodiment of the invention relates to any one of compositions B3-1 to B3-140 wherein the weight ratio of component I to component II is from 1 :100 to 100:1.
  • One further embodiment of the invention relates to any one of compositions B3-1 to B3-140 wherein the weight ratio of component I to component II is from 1 :50 to 50:1 .
  • One further embodiment of the invention relates to any one of compositions B3-1 to B3-140 wherein the weight ratio of component I to component II is from 1 :20 to 20:1 .
  • One further embodiment of the invention relates to any one of compositions B3-1 to B3-140 wherein the weight ratio of component I to component II is from 1 : 10 to 10:1 .
  • One further embodiment of the invention relates to any one of compositions B3-1 to B3-140 wherein the weight ratio of component I to component II is from 1 :3 to 3:1.
  • One further embodiment of the invention relates to any one of compositions B3-1 to B3-140 wherein the weight ratio of component I to component II is from 1 :2 to 2:1.
  • One further embodiment of the invention relates to any one of compositions B3-1 to B3-140 wherein the weight ratio of component I to component II is from 1000:1 to 1 :1 .
  • One further embodiment of the invention relates to any one of compositions B3-1 to B3-140 wherein the weight ratio of component I to component II is from 100:1 to 1 :1 .
  • One further embodiment of the invention relates to any one of compositions B3-1 to B3-140 wherein the weight ratio of component I to component II is from 50:1 to 1 :1.
  • One further embodiment of the invention relates to any one of compositions B3-1 to B3-140 wherein the weight ratio of component I to component II is from 20:1 to 1 :1.
  • One further embodiment of the invention relates to any one of compositions B3-1 to B3-140 wherein the weight ratio of component I to component II is from 10:1 to 1 :1.
  • One further embodiment of the invention relates to any one of compositions B3-1 to B3-140 wherein the weight ratio of component I to component II is from 4:1 to 1 :1.
  • One further embodiment of the invention relates to any one of compositions B3-1 to B3-140 wherein the weight ratio of component I to component II is from 2:1 to 1 :1.
  • One further embodiment of the invention relates to any one of compositions B3-1 to B3 -140 wherein the weight ratio of component I to component II is from 1 :1 to 1000.
  • One further embodiment of the invention relates to any one of compositions B3-1 to B3 -140 wherein the weight ratio of component I to component II is from 1 :1 to 1 :100.
  • One further embodiment of the invention relates to any one of compositions B3-1 to B3 -140 wherein the weight ratio of component I to component II is from 1 :1 to 1 :50.
  • One further embodiment of the invention relates to any one of compositions B3-1 to B3 -140 wherein the weight ratio of component I to component II is from 1 :1 to 1 :20.
  • One further embodiment of the invention relates to any one of compositions B3-1 to B3 -140 wherein the weight ratio of component I to component II is from 1 :1 to 1 :10.
  • One further embodiment of the invention relates to any one of compositions B3-1 to B3 -140 wherein the weight ratio of component I to component II is from 1 :1 to 1 :4.
  • One further embodiment of the invention relates to any one of compositions B3-1 to B3 -140 wherein the weight ratio of component I to component II is from 1 :1 to 1 :2.
  • mixtures and compositions according to the invention are suitable as fungicides. They are distinguished by an outstanding effectiveness against a broad spectrum of phytopathogenic fungi, including soil-borne fungi, which derive especially from the classes of the
  • Zygomycetes Ascomycetes, Basidiomycetes and Deuteromycetes (syn. Fungi imperfecti). Some are systemically effective and they can be used in crop protection as foliar fungicides, fungicides for seed dressing and soil fungicides. Moreover, they are suitable for controlling harmful fungi, which inter alia occur in wood or roots of plants.
  • the mixtures and compositions according to the invention are particularly important in the control of a multitude of phytopathogenic fungi on various cultivated plants, such as cereals, e. g. wheat, rye, barley, triticale, oats or rice; beet, e. g. sugar beet or fodder beet; fruits, such as pomes, stone fruits or soft fruits, e. g.
  • cereals e. g. wheat, rye, barley, triticale, oats or rice
  • beet e. g. sugar beet or fodder beet
  • fruits such as pomes, stone fruits or soft fruits, e. g.
  • inventive mixtures and compositions are used for controlling a multitude of fungi on field crops, such as potatoes sugar beets, tobacco, wheat, rye, barley, oats, rice, corn, cotton, soybeans, rape, legumes, sunflowers, coffee or sugar cane; fruits; vines; ornamentals; or vegetables, such as cucumbers, tomatoes, beans or squashes.
  • field crops such as potatoes sugar beets, tobacco, wheat, rye, barley, oats, rice, corn, cotton, soybeans, rape, legumes, sunflowers, coffee or sugar cane; fruits; vines; ornamentals; or vegetables, such as cucumbers, tomatoes, beans or squashes.
  • plant propagation material is to be understood to denote all the generative parts of the plant such as seeds and vegetative plant material such as cuttings and tubers (e. g. potatoes), which can be used for the multiplication of the plant. This includes seeds, roots, fruits, tubers, bulbs, rhizomes, shoots, sprouts and other parts of plants, including seedlings and young plants, which are to be transplanted after germination or after emergence from soil. These young plants may also be protected before transplantation by a total or partial treatment by immersion or pouring.
  • treatment of plant propagation materials with the inventive combination of component I and component II and compositions thereof, respectively, is used for controlling a multitude of fungi on cereals, such as wheat, rye, barley and oats; rice, corn, cotton and soybeans.
  • cultiva plants is to be understood as including plants which have been modified by breeding, mutagenesis or genetic engineering including but not limiting to agricultural biotech products on the market or in development (cf. http://cera-gmc.org/, see GM crop database therein).
  • Genetically modified plants are plants, which genetic material has been so modified by the use of recombinant DNA techniques that under natural circumstances cannot readily be obtained by cross breeding, mutations or natural recombination.
  • one or more genes have been integrated into the genetic material of a genetically modified plant in order to improve certain properties of the plant.
  • Such genetic modifications also include but are not limited to targeted post-translational modification of protein(s), oligo- or polypeptides e. g.
  • HPPD hydroxyphenyl- pyruvate dioxygenase
  • ALS acetolactate synthase
  • EPSPS enolpyruvylshikimate-3-phosphate synthase
  • GS glutamine synthetase
  • glufosinate see e. g. EP-A
  • cultivated plants have been rendered tolerant to herbicides by conventional methods of breeding (mutagenesis), e. g. Clearfield ® summer rape (Canola, BASF SE, Germany) being tolerant to imidazolinones, e. g. imazamox.
  • Genetic engineering methods have been used to render cultivated plants such as soybean, cotton, corn, beets and rape, tolerant to herbicides such as glyphosate and glufosinate, some of which are commercially available under the trade names RoundupReady ® (glyphosate-tolerant, Monsanto, U.S.A.) and LibertyLink ® (glufosinate- tolerant, Bayer CropScience, Germany).
  • plants are also covered that are by the use of recombinant DNA techniques capable to synthesize one or more insecticidal proteins, especially those known from the bacterial genus Bacillus, particularly from Bacillus thuringiensis, such as ⁇ -endotoxins, e. g. CrylA(b), CrylA(c), CrylF, CrylF(a2), CryllA(b), CrylllA, CrylllB(bl) or Cry9c; vegetative insecticidal proteins (VIP), e. g. VIP1 , VIP2, VIP3 or VIP3A; insecticidal proteins of bacteria colonizing nematodes, e. g. Photorhabdus spp.
  • VIP1 , VIP2, VIP3 or VIP3A vegetative insecticidal proteins
  • toxins produced by animals such as scorpion toxins, arachnid toxins, wasp toxins, or other insect-specific neurotoxins
  • toxins produced by fungi such Streptomycetes toxins, plant lectins, such as pea or barley lectins; agglutinins
  • proteinase inhibitors such as trypsin inhibitors, serine protease inhibitors, patatin, cystatin or papain inhibitors
  • ribosome-inactivating proteins (RIP) such as ricin, maize-RIP, abrin, luffin, saporin or bryodin
  • steroid metabolism enzymes such as 3-hydro- xysteroid oxidase, ecdysteroid-IDP-glycosyl-transferase, cholesterol oxidases, ecdysone inhibitors or HMG-CoA-reductase
  • ion channel blockers such as blockers
  • these insecticidal proteins or toxins are to be understood expressly also as pre-toxins, hybrid proteins, truncated or otherwise modified proteins.
  • Hybrid proteins are characterized by a new combination of protein domains, (see, e. g. WO 02/015701 ).
  • Further examples of such toxins or genetically modified plants capable of synthesizing such toxins are disclosed, e. g., in EP-A 374 753, WO 93/007278, WO 95/34656, EP-A 427 529, EP-A 451 878, WO 03/18810 und WO 03/52073.
  • the methods for producing such genetically modified plants are generally known to the person skilled in the art and are described, e. g.
  • insecticidal proteins contained in the genetically modified plants impart to the plants producing these proteins tolerance to harmful pests from all taxonomic groups of arthropods, especially to beetles (Coeloptera), two-winged insects (Diptera), and moths (Lepidoptera) and to nematodes (Nematoda).
  • Genetically modified plants capable to synthesize one or more insecticidal proteins are, e.
  • WO 03/018810 MON 863 from Monsanto Europe S.A., Belgium (corn cultivars producing the Cry3Bb1 toxin), IPC 531 from Monsanto Europe S.A., Belgium (cotton cultivars producing a modified version of the CrylAc toxin) and 1507 from Pioneer Overseas Corporation, Belgium (corn cultivars producing the Cry1 F toxin and PAT enzyme).
  • plants are also covered that are by the use of recombinant DNA techniques capable to synthesize one or more proteins to increase the resistance or tolerance of those plants to bacterial, viral or fungal pathogens. Examples of such proteins are the so-called "pathogenesis-related proteins" (PR proteins, see, e. g.
  • EP-A 392 225 plant disease resistance genes (e. g. potato cultivars, which express resistance genes acting against Phytophthora infestans derived from the mexican wild potato Solanum bulbocastanum) or T4-lysozym (e. g. potato cultivars capable of synthesizing these proteins with increased resistance against bacteria such as Erwinia amylvora).
  • plant disease resistance genes e. g. potato cultivars, which express resistance genes acting against Phytophthora infestans derived from the mexican wild potato Solanum bulbocastanum
  • T4-lysozym e. g. potato cultivars capable of synthesizing these proteins with increased resistance against bacteria such as Erwinia amylvora.
  • the methods for producing such genetically modified plants are generally known to the person skilled in the art and are described, e. g. in the publications mentioned above.
  • plants are also covered that are by the use of recombinant DNA techniques capable to synthesize one or more proteins to increase the productivity (e. g. bio mass production, grain yield, starch content, oil content or protein content), tolerance to drought, salinity or other growth-limiting environmental factors or tolerance to pests and fungal, bacterial or viral pathogens of those plants.
  • productivity e. g. bio mass production, grain yield, starch content, oil content or protein content
  • plants are also covered that contain by the use of recombinant DNA techniques a modified amount of substances of content or new substances of content, specifically to improve human or animal nutrition, e. g. oil crops that produce health-promoting long-chain omega-3 fatty acids or unsaturated omega-9 fatty acids (e. g. Nexera ® rape, DOW Agro Sciences, Canada).
  • plants are also covered that contain by the use of recombinant DNA techniques a modified amount of substances of content or new substances of content, specifically to improve raw material production, e. g. potatoes that produce increased amounts of amylopectin (e. g. Amflora ® potato, BASF SE, Germany).
  • a modified amount of substances of content or new substances of content specifically to improve raw material production, e. g. potatoes that produce increased amounts of amylopectin (e. g. Amflora ® potato, BASF SE, Germany).
  • inventive mixtures and compositions are particularly suitable for controlling the following plant diseases:
  • Albugo spp. white rust
  • vegetables e. g. A. Candida
  • sunflowers e. g. A. tragopogonis
  • Alternaria spp. Alternaria leaf spot) on vegetables, rape (A. brassicola or brassicae), sugar beets (A. tenuis), fruits, rice, soybeans, potatoes (e. g. A. solanior A.
  • alternata tomatoes (e. g. A. solanior A. alternata) and wheat; Aphanomyces spp. on sugar beets and vegetables; Ascochyta spp. on cereals and vegetables, e. g. A. tritici (anthracnose) on wheat and A. hordei on barley; Bipolaris and Drechslera spp. (teleomorph: Cochliobolus spp.) on corn (e. g. D. maydis), cereals (e. g. B. sorokiniana: spot blotch), rice (e. g. B.
  • Ceratocystis (syn. Ophiostoma) spp. (rot or wilt) on broad-leaved trees and evergreens, e. g. C. ulmi (Dutch elm disease) on elms; Cercospora spp. (Cercospora leaf spots) on corn, rice, sugar beets (e. g. C. beticola), sugar cane, vegetables, coffee, soybeans (e. g. C. sojina or C. kikuchii) and rice; Cladosporium spp. on tomatoes (e. g. C. fulvum: leaf mold) and cereals, e. g. C. herbarum (black ear) on wheat; Claviceps purpurea (ergot) on cereals; Cochlioboius
  • anamorph Helminthosporium of Bipolaris
  • spp. leaf spots
  • corn C. carbonum
  • cereals e. g. C. sativus, anamorph: B. sorokiniana
  • rice e. g. C. miyabeanus, anamorph: H.
  • teleomorph Nectria or Neonectria spp.
  • fruit trees canker or young vine decline
  • teleomorph Nectria or Neonectria spp.
  • fruit trees canker or young vine decline
  • teleomorph Nectria or Neonectria spp.
  • vines e. g. C. liriodendri, teleomorph: Neonectria liriodendri: Black Foot Disease
  • Dematophora teleomorph: Rosellinia necatrix (root and stem rot) on soybeans
  • Diaporthe spp. e. g. D. phaseolorum (damping off) on soybeans
  • Drechslera sertraolorum
  • Phaeomoniella chlamydospora (earlier Phaeoacremonium chlamydosporum)
  • Drechslera, teleomorph Cochlioboius) on corn, cereals and rice; Hemileia spp., e. g. H. vastatrix (coffee leaf rust) on coffee; Isariopsis clavispora (syn. Cladosporium vitis) on vines; Macrophomina phaseolina (syn. phaseoli) (root and stem rot) on soybeans and cotton; Microdochium (syn. Fusarium) nivale (pink snow mold) on cereals (e. g. wheat or barley); Microsphaera diffusa (powdery mildew) on soybeans; Monilinia spp., e. g. M.
  • Phakopsora pachyrhizi and P. meibomiae (soybean rust) on soybeans; Phialophora spp. e. g. on vines (e. g. P. tracheiphila and P. tetraspora) and soybeans (e. g. P. gregata: stem rot); Phoma lingam (root and stem rot) on rape and cabbage and P. betae (root rot, leaf spot and damping-off) on sugar beets; Phomopsis spp. on sunflowers, vines (e. g. P. viticola: can and leaf spot) and soybeans (e. g. stem rot: P.
  • phaseoli, teleomorph Diaporthe phaseolorum
  • Physoderma maydis brown spots
  • Phytophthora spp. wilt, root, leaf, fruit and stem root
  • various plants such as paprika and cucurbits (e. g. P. capsici), soybeans (e. g. P. megasperma, syn. P. sojae), potatoes and tomatoes (e. g. P. infestans: late blight) and broad- leaved trees (e. g. P. ramorum: sudden oak death);
  • Plasmodiophora brassicae club root
  • cabbage rape, radish and other plants
  • Plasmopara spp. e. g.
  • P. viticola grapevine downy mildew
  • Podosphaera spp. podosphaera spp.
  • Polymyxa spp. e. g. on cereals, such as barley and wheat (P. graminis) and sugar beets (P. betae) and thereby transmitted viral diseases
  • Pseudocercosporelia herpotrichoides eyespot, teleomorph: Tapesia yallundae
  • Drechslera tritici-repentis (tan spot) on wheat or P. feres (net blotch) on barley; Pyricularia spp., e. g. P. oryzae (teleomorph: Magnaporthe grisea, rice blast) on rice and P. grisea on turf and cereals; Pythium spp. (damping-off) on turf, rice, corn, wheat, cotton, rape, sunflowers, soybeans, sugar beets, vegetables and various other plants (e. g. P. ultimum or P. aphani- dermatum); Ramularia spp., e. g. R.
  • collo-cygni amularia leaf spots, Physiological leaf spots
  • R. beticola on sugar beets
  • Rhizoctonia spp. on cotton, rice, potatoes, turf, corn, rape, potatoes, sugar beets, vegetables and various other plants, e. g. R. solani (root and stem rot) on soybeans, R. solani (sheath blight) on rice or R.
  • Leptosphaeria [syn. Phaeosphaeria] nodorum) on wheat; Synchytrium endobioticum on potatoes (potato wart disease); Taphrina spp., e. g. T. deformans (leaf curl disease) on peaches and T. pruni (plum pocket) on plums; Thielaviopsis spp. (black root rot) on tobacco, pome fruits, vegetables, soybeans and cotton, e. g. T basicola (syn. Chalara elegans); Tilletia spp. (common bunt or stinking smut) on cereals, such as e. g. T. tritici (syn. T.
  • corn smut corn smut
  • sugar cane a sugar cane
  • Venturia spp. scab
  • apples e. g. V. inaequalis
  • pears a verticillium spp. (wilt) on various plants, such as fruits and ornamentals, vines, soft fruits, vegetables and field crops, e. g. V. dahliae on strawberries, rape, potatoes and tomatoes.
  • mixtures and compositions of the present invention are effective against plant pathogens in speciality crops such as vine, fruits, hop, vegetables and tabacco - see above list.
  • the method of treatment according to the invention can also be used in the field of protecting stored products or harvest against attack of fungi and microorganisms.
  • the term "stored products” is understood to denote natural substances of plant or animal origin and their processed forms, which have been taken from the natural life cycle and for which long-term protection is desired.
  • Stored products of crop plant origin such as plants or parts thereof, for example stalks, leafs, tubers, seeds, fruits or grains, can be protected in the freshly harvested state or in processed form, such as pre-dried, moistened, comminuted, ground, pressed or roasted, which process is also known as post-harvest treatment.
  • Also falling under the definition of stored products is timber, whether in the form of crude timber, such as construction timber, electricity pylons and barriers, or in the form of finished articles, such as furniture or objects made from wood.
  • Stored products of animal origin are hides, leather, furs, hairs and the like. The combinations according the present invention can prevent
  • stored products is understood to denote natural substances of plant origin and their processed forms, more preferably fruits and their processed forms, such as pomes, stone fruits, soft fruits and citrus fruits and their processed forms.
  • Plant propagation materials may be treated with the mixtures and compositions of the invention prophylactically either at or before planting or transplanting.
  • the invention also relates to agrochemical compositions comprising an auxiliary and one component I and a component II according to the invention.
  • An agrochemical composition comprises a fungicidally effective amount of a component I and a component II.
  • effective amount denotes an amount of the composition or of the components I and II, which is sufficient for controlling harmful fungi on cultivated plants or in the protection of materials and which does not result in a substantial damage to the treated plants. Such an amount can vary in a broad range and is dependent on various factors, such as the fungal species to be controlled, the treated cultivated plant or material, the climatic conditions and the specific component I and II used.
  • compositions e. g. solutions, emulsions, suspensions, dusts, powders, pastes, granules, pressings, capsules, and mixtures thereof.
  • composition types are suspensions (e. g. SC, OD, FS), emulsifiable concentrates (e. g. EC), emulsions (e. g. EW, EO, ES, ME), capsules (e. g. CS, ZC), pastes, pastilles, wettable powders or dusts (e. g. WP, SP, WS, DP, DS), pressings (e. g.
  • compositions types are defined in the "Catalogue of pesticide formulation types and international coding system", Technical
  • compositions are prepared in a known manner, such as described by Mollet and
  • Suitable auxiliaries are solvents, liquid carriers, solid carriers or fillers, surfactants, dispersants, emulsifiers, wetters, adjuvants, solubilizers, penetration enhancers, protective colloids, adhesion agents, thickeners, humectants, repellents, attractants, feeding stimulants, compatibilizers, bactericides, anti-freezing agents, anti-foaming agents, colorants, tackifiers and binders.
  • Suitable solvents and liquid carriers are water and organic solvents, such as mineral oil fractions of medium to high boiling point, e. g. kerosene, diesel oil; oils of vegetable or animal origin; aliphatic, cyclic and aromatic hydrocarbons, e. g. toluene, paraffin,
  • tetrahydronaphthalene alkylated naphthalenes
  • alcohols e. g. ethanol, propanol, butanol, benzyl alcohol, cyclohexanol
  • glycols DMSO; ketones, e. g. cyclohexanone; esters, e. g.
  • lactates carbonates, fatty acid esters, gamma-butyrolactone; fatty acids; phosphonates;
  • amines e. g. N-methylpyrrolidone, fatty acid dimethylamides; and mixtures thereof.
  • Suitable solid carriers or fillers are mineral earths, e. g. silicates, silica gels, talc, kaolins, limestone, lime, chalk, clays, dolomite, diatomaceous earth, bentonite, calcium sulfate, magnesium sulfate, magnesium oxide; polysaccharides, e. g. cellulose, starch; fertilizers, e. g. ammonium sulfate, ammonium phosphate, ammonium nitrate, ureas; products of vegetable origin, e. g. cereal meal, tree bark meal, wood meal, nutshell meal, and mixtures thereof.
  • mineral earths e. g. silicates, silica gels, talc, kaolins, limestone, lime, chalk, clays, dolomite, diatomaceous earth, bentonite, calcium sulfate, magnesium sulfate, magnesium oxide
  • polysaccharides e. g. cellulose, star
  • Suitable surfactants are surface-active compounds, such as anionic, cationic, nonionic and amphoteric surfactants, block polymers, polyelectrolytes, and mixtures thereof. Such surfactants can be used as emulsifier, dispersant, solubilizer, wetter, penetration enhancer, protective colloid, or adjuvant. Examples of surfactants are listed in McCutcheon's, Vol.1 : Emulsifiers & Detergents, McCutcheon's Directories, Glen Rock, USA, 2008 (International Ed. or North American Ed.).
  • Suitable anionic surfactants are alkali, alkaline earth or ammonium salts of sulfonates, sulfates, phosphates, carboxylates, and mixtures thereof.
  • sulfonates are alkylarylsulfonates, diphenylsulfonates, alpha-olefin sulfonates, lignin sulfonates, sulfonates of fatty acids and oils, sulfonates of ethoxylated alkylphenols, sulfonates of alkoxylated arylphenols, sulfonates of condensed naphthalenes, sulfonates of dodecyl- and tridecylbenzenes, sulfonates of naphthalenes and alkylnaphthalenes, sulfosuccinates or sulfosuccinamates.
  • Examples of sulfates are sulfates of fatty acids and oils, of ethoxylated alkylphenols, of alcohols, of ethoxylated alcohols, or of fatty acid esters.
  • Examples of phosphates are phosphate esters.
  • Examples of carboxylates are alkyl carboxylates, and carboxylated alcohol or alkylphenol ethoxylates.
  • Suitable nonionic surfactants are alkoxylates, N-subsituted fatty acid amides, amine oxides, esters, sugar-based surfactants, polymeric surfactants, and mixtures thereof.
  • alkoxylates are compounds such as alcohols, alkylphenols, amines, amides, arylphenols, fatty acids or fatty acid esters which have been alkoxylated with 1 to 50 equivalents.
  • Ethylene oxide and/or propylene oxide may be employed for the alkoxylation, preferably ethylene oxide.
  • N-subsititued fatty acid amides are fatty acid glucamides or fatty acid
  • esters are fatty acid esters, glycerol esters or monoglycerides.
  • sugar-based surfactants are sorbitans, ethoxylated sorbitans, sucrose and glucose esters or alkylpolyglucosides.
  • polymeric surfactants are home- or copolymers of vinylpyrrolidone, vinylalcohols, or vinylacetate.
  • Suitable cationic surfactants are quaternary surfactants, for example quaternary ammonium compounds with one or two hydrophobic groups, or salts of long-chain primary amines.
  • Suitable amphoteric surfactants are alkylbetains and imidazolines.
  • Suitable block polymers are block polymers of the A-B or A-B-A type comprising blocks of polyethylene oxide and polypropylene oxide, or of the A-B-C type comprising alkanol, polyethylene oxide and polypropylene oxide.
  • Suitable polyelectrolytes are polyacids or polybases. Examples of polyacids are alkali salts of polyacrylic acid or polyacid comb polymers. Examples of polybases are polyvinyl amines or polyethylene amines.
  • Suitable adjuvants are compounds, which have a negligible or even no pesticidal activity themselves, and which improve the biological performance of the component I on the target.
  • examples are surfactants, mineral or vegetable oils, and other auxiliaries. Further examples are listed by Knowles, Adjuvants and additives, Agrow Reports DS256, T&F Informa UK, 2006, chapter 5.
  • Suitable thickeners are polysaccharides (e. g. xanthan gum, carboxymethyl cellulose), inorganic clays (organically modified or unmodified), polycarboxylates, and silicates.
  • Suitable bactericides are bronopol and isothiazolinone derivatives such as alkylisothiazolinones and benzisothiazolinones.
  • Suitable anti-freezing agents are ethylene glycol, propylene glycol, urea and glycerin.
  • Suitable anti-foaming agents are silicones, long chain alcohols, and salts of fatty acids.
  • Suitable colorants are pigments of low water solubility and water- soluble dyes.
  • examples are inorganic colorants (e. g. iron oxide, titan oxide, iron
  • Suitable tackifiers or binders are polyvinyl pyrrolidones, polyvinyl acetates, polyvinyl alcohols, polyacrylates, biological or synthetic waxes, and cellulose ethers.
  • composition types and their preparation are (wherein active substances denote component I and component II):
  • Water-soluble concentrates (SL, LS) 10-60 wt% active substances and 5-15 wt% wetting agent (e. g. alcohol alkoxylates) are dissolved in water and/or in a water-soluble solvent (e. g. alcohols) ad 100 wt%.
  • the active substance dissolves upon dilution with water.
  • emulsifiers e. g. calcium dodecylbenzenesulfonate and castor oil ethoxylate
  • water-insoluble organic solvent e. g. aromatic hydrocarbon
  • Emulsions (EW, EO, ES)
  • emulsifiers e. g. calcium dodecylbenzenesulfonate and castor oil ethoxylate
  • 20-40 wt% water-insoluble organic solvent e. g. aromatic hydrocarbon
  • This mixture is introduced into water ad 100 wt% by means of an emulsifying machine and made into a homogeneous emulsion. Dilution with water gives an emulsion.
  • active substances are comminuted with addition of 2-10 wt% dispersants and wetting agents (e. g. sodium lignosulfonate and alcohol ethoxylate), 0.1 -2 wt% thickener (e. g. xanthan gum) and ad water ad 100 wt% to give a fine active substance suspension. Dilution with water gives a stable suspension of the active substance.
  • dispersants and wetting agents e. g. sodium lignosulfonate and alcohol ethoxylate
  • 0.1 -2 wt% thickener e. g. xanthan gum
  • ad water ad 100 wt%
  • active substances are ground finely with addition of dispersants and wetting agents (e. g. sodium lignosulfonate and alcohol ethoxylate) ad 100 wt% and prepared as water- dispersible or water-soluble granules by means of technical appliances (e. g. extrusion, spray tower, fluidized bed). Dilution with water gives a stable dispersion or solution of the active substance.
  • dispersants and wetting agents e. g. sodium lignosulfonate and alcohol ethoxylate
  • active substances are ground in a rotor-stator mill with addition of 1-5 wt% dispersants (e. g. sodium lignosulfonate), 1 -3 wt% wetting agents (e. g. alcohol ethoxylate) and solid carrier (e. g. silica gel) ad 100 wt%. Dilution with water gives a stable dispersion or solution of the active substance.
  • dispersants e. g. sodium lignosulfonate
  • wetting agents e. g. alcohol ethoxylate
  • solid carrier e. g. silica gel
  • active substances are comminuted with addition of 3-10 wt% dispersants (e. g. sodium lignosulfonate), 1 -5 wt% thickener (e. g. carboxymethyl cellulose) and water ad 100 wt% to give a fine suspension of the active substance. Dilution with water gives a stable suspension of the active substance.
  • dispersants e. g. sodium lignosulfonate
  • 1 -5 wt% thickener e. g. carboxymethyl cellulose
  • 5-20 wt% active substances are added to 5-30 wt% organic solvent blend (e. g. fatty acid dimethylamide and cyclohexanone), 10-25 wt% surfactant blend (e. g. alcohol ethoxylate and arylphenol ethoxylate), and water ad 100 wt%. This mixture is stirred for 1 h to produce spontaneously a thermodynamically stable microemulsion.
  • organic solvent blend e. g. fatty acid dimethylamide and cyclohexanone
  • surfactant blend e. g. alcohol ethoxylate and arylphenol ethoxylate
  • An oil phase comprising 5-50 wt% active substances, 0-40 wt% water insoluble organic solvent (e. g. aromatic hydrocarbon), 2-15 wt% acrylic monomers (e. g. methylmethacrylate, methacrylic acid and a di- or triacrylate) are dispersed into an aqueous solution of a protective colloid (e. g. polyvinyl alcohol). Radical polymerization initiated by a radical initiator results in the formation of poly(meth)acrylate microcapsules.
  • an oil phase comprising 5-50 wt% of active substances, 0-40 wt% water insoluble organic solvent (e. g. aromatic hydrocarbon), and an isocyanate monomer (e. g. diphenylmethene-4,4'-diisocyanatae) are dispersed into an aqueous solution of a protective colloid (e. g. polyvinyl alcohol).
  • a polyamine e. g.
  • hexamethylenediamine results in the formation of polyurea microcapsules.
  • the monomers amount to 1 -10 wt%.
  • the wt% relate to the total CS composition.
  • Dustable powders (DP, DS)
  • active substances are ground finely and mixed intimately with solid carrier (e. g. finely divided kaolin) ad 100 wt%.
  • solid carrier e. g. finely divided kaolin
  • active substances are ground finely and associated with solid carrier (e. g. silicate) ad 100 wt%.
  • solid carrier e. g. silicate
  • Granulation is achieved by extrusion, spray-drying or fluidized bed.
  • organic solvent e. g. aromatic hydrocarbon
  • compositions types i) to xi) may optionally comprise further auxiliaries, such as 0.1 -1 wt% bactericides, 5-15 wt% anti-freezing agents, 0.1-1 wt% anti-foaming agents, and 0.1 -1 wt% colorants.
  • auxiliaries such as 0.1 -1 wt% bactericides, 5-15 wt% anti-freezing agents, 0.1-1 wt% anti-foaming agents, and 0.1 -1 wt% colorants.
  • the agrochemical compositions generally comprise between 0.01 and 95%, preferably between 0.1 and 90%, and in particular between 0.5 and 75%, by weight of active substances.
  • the active substances are employed in a purity of from 90% to 100%, preferably from 95% to 100% (according to NMR spectrum).
  • LS solutions for seed treatment
  • SE Suspoemulsions
  • FS flowable concentrates
  • DS powders for dry treatment
  • WS water-dispersible powders for slurry treatment
  • compositions in question give, after two-to-tenfold dilution, active substance concentrations of from 0.01 to 60% by weight, preferably from 0.1 to 40%, in the ready-to-use preparations.
  • Methods for applying or treating component I and component II and compositions thereof, respectively, onto plant propagation material, especially seeds include dressing, coating, pelleting, dusting, and soaking as well as in-furrow application methods.
  • component I and component II or the compositions thereof, respectively are applied on to the plant propagation material by a method such that germination is not induced, e. g. by seed dressing, pelleting, coating and dusting.
  • amounts of active substance of from 0.1 to 1000 g, preferably from 1 to 1000 g, more preferably from 1 to 100 g and most preferably from 5 to 100 g, per 100 kilogram of plant propagation material (preferably seed) are generally required.
  • the amount of active substance applied depends on the kind of application area and on the desired effect. Amounts customarily applied in the protection of materials are 0.001 g to 2 kg, preferably 0.005 g to 1 kg, of active substance per cubic meter of treated material.
  • oils, wetters, adjuvants, fertilizer, or micronutrients, and further pesticides may be added to the active substances or the compositions comprising them as premix or, if appropriate not until immediately prior to use (tank mix).
  • pesticides e. g. herbicides, insecticides, fungicides, growth regulators, safeners
  • These agents can be admixed with the compositions according to the invention in a weight ratio of 1 :100 to 100:1 , preferably 1 :10 to 10:1.
  • composition according to the invention usually from a predosage device, a knapsack sprayer, a spray tank, a spray plane, or an irrigation system.
  • a predosage device usually from a knapsack sprayer, a spray tank, a spray plane, or an irrigation system.
  • agrochemical composition is made up with water, buffer, and/or further auxiliaries to the desired application concentration and the ready-to-use spray liquor or the agrochemical composition according to the invention is thus obtained.
  • 20 to 2000 liters, preferably 50 to 400 liters, of the ready-to-use spray liquor are applied per hectare of agricultural useful area.
  • composition according to the invention such as parts of a kit or parts of a binary or ternary mixture may be mixed by the user himself in a spray tank or any other kind of vessel used for applications (e. g. seed treater drums, seed pelleting machinery, knapsack sprayer) and further auxiliaries may be added, if appropriate.
  • a spray tank or any other kind of vessel used for applications (e. g. seed treater drums, seed pelleting machinery, knapsack sprayer) and further auxiliaries may be added, if appropriate.
  • one embodiment of the invention is a kit for preparing a usable pesticidal composition, the kit comprising a) a composition comprising component 1) as defined herein and at least one auxiliary; and b) a composition comprising component 2) as defined herein and at least one auxiliary; and optionally c) a composition comprising at least one auxiliary and optionally a further active component 3) as defined herein.
  • the compound ratios are advantageously chosen so as to produce a synergistic effect.
  • the weight ratio of component I and component II generally depends from the properties of the active substances used, usually it is in the range of from 1 :100 to 100:1 , regularly in the range of from 1 :50 to 50:1 , preferably in the range of from 1 :20 to 20:1 , more preferably in the range of from 1 :10 to 10:1 , even more preferably in the range of from 1 :4 to 4:1 and in particular in the range of from 1 :2 to 2:1.
  • the weight ratio of component I versus component II usually is in the range of from 1000:1 to 1 :1 , often in the range of from 100:1 to 1 :1 , regularly in the range of from 50:1 to 1 :1 , preferably in the range of from 20:1 to 1 :1 , more preferably in the range of from 10:1 to 1 :1 , even more preferably in the range of from 4:1 to 1 :1 and in particular in the range of from 2:1 to 1 :1.
  • the weight ratio of component I versus component II usually is in the range of from 1 :1 to 1000, often in the range of from 1 :1 to 1 :100, regularly in the range of from 1 :1 to 1 :50, preferably in the range of from 1 :1 to 1 :20, more preferably in the range of from 1 :1 to 1 :10, even more preferably in the range of from 1 :1 to 1 :4 and in particular in the range of from 1 :1 to 1 :2.
  • the compound ratios are advantageously chosen so as to produce a synergistic effect.
  • the active compounds are prepared as a stock solution comprising 25 mg of active compound which is made up to 10 ml using a mixture of acetone and/or DMSO and the emulsifier Uniperol ® EL (wetting agent having an emulsifying and dispersing action based on ethoxylated alkylphenols) in a ratio by volume of solvent/emulsifier of 99:1 .
  • the mixture is then made up to 100 ml with water.
  • This stock solution is diluted with the solvent/em ulsifier/water mixture described to give the concentration of active compound stated below.
  • the visually determined percentages of infected leaf areas are converted into efficacies in % of the untreated control.
  • the efficacy (E) is calculated as follows using Abbot's formula:
  • a corresponds to the fungicidal infection of the treated plants in %
  • ⁇ corresponds to the fungicidal infection of the untreated (control) plants in %
  • An efficacy of 0 means that the infection level of the treated plants corresponds to that of the untreated control plants; an efficacy of 100 means that the treated plants were not infected.
  • y efficacy expressed in % of the untreated control, when using the active compound B at the concentration b.

Abstract

La présente invention concerne des compositions pesticides comprenant 1) comme composant I un composé choisi parmi les composés I-1 à I-31 tel que défini dans la description; et 2) comme composant II un composé choisi parmi les composés (II)-1 et (II)-2.
PCT/EP2015/076388 2014-11-21 2015-11-12 Compositions pesticides WO2016078995A1 (fr)

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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2018105663A1 (fr) * 2016-12-06 2018-06-14 株式会社クレハ Agent chimique agricole et horticole, procédé de lutte contre des maladies de plantes et produit de lutte contre des maladies de plantes
US10512267B2 (en) 2013-07-08 2019-12-24 BASF Agro, B.V. Compositions comprising a triazole compound and a biopesticide
US10519122B2 (en) 2013-01-09 2019-12-31 BASF Agro B.V. Process for the preparation of substituted oxiranes and triazoles
US10779536B2 (en) 2014-11-07 2020-09-22 Basf Se Pesticidal mixtures
US10905122B2 (en) 2016-03-16 2021-02-02 Basf Se Use of tetrazolinones for combating resistant phytopathogenic fungi on cereals
US10959431B2 (en) 2016-10-10 2021-03-30 Basf Se Pesticidal mixtures
US11241012B2 (en) 2016-03-16 2022-02-08 Basf Se Use of tetrazolinones for combating resistant phytopathogenic fungi on soybean
US11425909B2 (en) 2016-03-16 2022-08-30 Basf Se Use of tetrazolinones for combating resistant phytopathogenic fungi on fruits

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WO2011070771A1 (fr) * 2009-12-08 2011-06-16 Kureha Corporation Dérivés d'azole, leurs procédés de production, leur intermédiaire, agents à usage agricole et horticole
WO2014095994A1 (fr) * 2012-12-20 2014-06-26 Basf Se Compositions comprenant un composé triazole
WO2014095932A1 (fr) * 2012-12-20 2014-06-26 Basf Se Compositions comprenant un composé triazole

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2011070771A1 (fr) * 2009-12-08 2011-06-16 Kureha Corporation Dérivés d'azole, leurs procédés de production, leur intermédiaire, agents à usage agricole et horticole
WO2014095994A1 (fr) * 2012-12-20 2014-06-26 Basf Se Compositions comprenant un composé triazole
WO2014095932A1 (fr) * 2012-12-20 2014-06-26 Basf Se Compositions comprenant un composé triazole

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10519122B2 (en) 2013-01-09 2019-12-31 BASF Agro B.V. Process for the preparation of substituted oxiranes and triazoles
US10981883B2 (en) 2013-01-09 2021-04-20 BASF Agro B.V. Process for the preparation of substituted oxiranes and triazoles
US10512267B2 (en) 2013-07-08 2019-12-24 BASF Agro, B.V. Compositions comprising a triazole compound and a biopesticide
US10779536B2 (en) 2014-11-07 2020-09-22 Basf Se Pesticidal mixtures
US10905122B2 (en) 2016-03-16 2021-02-02 Basf Se Use of tetrazolinones for combating resistant phytopathogenic fungi on cereals
US11241012B2 (en) 2016-03-16 2022-02-08 Basf Se Use of tetrazolinones for combating resistant phytopathogenic fungi on soybean
US11425909B2 (en) 2016-03-16 2022-08-30 Basf Se Use of tetrazolinones for combating resistant phytopathogenic fungi on fruits
US10959431B2 (en) 2016-10-10 2021-03-30 Basf Se Pesticidal mixtures
WO2018105663A1 (fr) * 2016-12-06 2018-06-14 株式会社クレハ Agent chimique agricole et horticole, procédé de lutte contre des maladies de plantes et produit de lutte contre des maladies de plantes

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