WO2016078153A1 - Adhésif de type émulsion composite pour la fabrication de papier - Google Patents

Adhésif de type émulsion composite pour la fabrication de papier Download PDF

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Publication number
WO2016078153A1
WO2016078153A1 PCT/CN2014/092931 CN2014092931W WO2016078153A1 WO 2016078153 A1 WO2016078153 A1 WO 2016078153A1 CN 2014092931 W CN2014092931 W CN 2014092931W WO 2016078153 A1 WO2016078153 A1 WO 2016078153A1
Authority
WO
WIPO (PCT)
Prior art keywords
parts
papermaking
adhesive
composite emulsion
potassium persulfate
Prior art date
Application number
PCT/CN2014/092931
Other languages
English (en)
Chinese (zh)
Inventor
俞志红
Original Assignee
俞志红
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 俞志红 filed Critical 俞志红
Publication of WO2016078153A1 publication Critical patent/WO2016078153A1/fr

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/12—Polymerisation in non-solvents
    • C08F2/16—Aqueous medium
    • C08F2/22—Emulsion polymerisation
    • C08F2/24—Emulsion polymerisation with the aid of emulsifying agents
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F12/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F12/02—Monomers containing only one unsaturated aliphatic radical
    • C08F12/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F12/06—Hydrocarbons
    • C08F12/08—Styrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
    • C08F20/04—Acids, Metal salts or ammonium salts thereof
    • C08F20/06—Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
    • C08F20/10—Esters
    • C08F20/12—Esters of monohydric alcohols or phenols
    • C08F20/14—Methyl esters, e.g. methyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
    • C08F20/10—Esters
    • C08F20/12—Esters of monohydric alcohols or phenols
    • C08F20/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
    • C08F20/10—Esters
    • C08F20/12—Esters of monohydric alcohols or phenols
    • C08F20/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F20/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
    • C08F20/52—Amides or imides
    • C08F20/54—Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide
    • C08F20/56—Acrylamide; Methacrylamide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/28—Oxygen or compounds releasing free oxygen
    • C08F4/30—Inorganic compounds
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/26—Agents rendering paper transparent or translucent

Definitions

  • a composite emulsion binder for papermaking comprising 60-80 parts of methyl acrylate, 150-170 parts of butyl acrylate, 20-40 parts of methyl methacrylate, and 70-90 of styrene. Parts: acrylic acid, acrylamide (0.6:1) 50-70 parts, composite emulsifier 10-30 parts, potassium persulfate 2-8 parts, distilled water 1500-1900 parts.
  • Example 1 60 parts of methyl acrylate, 150 parts of butyl acrylate, 20 parts of methyl methacrylate, 70 parts of styrene, 50 parts of acrylic acid, acrylamide (0.6:1), 10 parts of composite emulsifier, persulfuric acid 2 parts of potassium and 1500 parts of distilled water.
  • Example 3 comprising 80 parts of methyl acrylate, 170 parts of butyl acrylate, methyl propyl 40 parts of methyl enoate, 90 parts of styrene, 70 parts of acrylic acid, acrylamide (0.6:1), 30 parts of complex emulsifier, 8 parts of potassium persulfate, and 1900 parts of distilled water.
  • the adhesive of the present invention has an appropriate viscosity and good stability, and the transparency, water absorption and tensile strength of the film are remarkably improved.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Adhesives Or Adhesive Processes (AREA)

Abstract

Cette invention concerne un adhésif de type émulsion composite pour la fabrication de papier, comprenant de 60 à 80 parties de méthacrylate, de 150 à 170 parties de butylacrylate, de 20 à 40 parties de méthacrylate de méthyle, de 70 à 90 parties de styrène, de 50 à 70 parties d'acide acrylique et d'acrylamide (0,6:1), de 10 à 30 parties d'un émulsifiant composite, de 2 à 8 parties de persulfate de potassium, et de 1500 à 1900 parties d'eau distillée. L'adhésif a une viscosité appropriée et une grande stabilité. La transparence, une capacité d'absorption de l'eau, et résistance à la traction de l'adhésif sont augmentées de manière significative.
PCT/CN2014/092931 2014-11-19 2014-12-03 Adhésif de type émulsion composite pour la fabrication de papier WO2016078153A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN201410665547.3 2014-11-19
CN201410665547 2014-11-19

Publications (1)

Publication Number Publication Date
WO2016078153A1 true WO2016078153A1 (fr) 2016-05-26

Family

ID=56013122

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/CN2014/092931 WO2016078153A1 (fr) 2014-11-19 2014-12-03 Adhésif de type émulsion composite pour la fabrication de papier

Country Status (1)

Country Link
WO (1) WO2016078153A1 (fr)

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101086148A (zh) * 2007-06-28 2007-12-12 上海东升新材料有限公司 纸用乳液干强剂及其制备方法
CN101177923A (zh) * 2007-11-30 2008-05-14 华南理工大学 一种造纸用苯丙乳液表面施胶剂及其合成方法
CN102444049A (zh) * 2010-10-15 2012-05-09 中国海洋石油总公司 一种乳液型纸张用助剂及其制备方法以及包含其的纸张
KR20120050071A (ko) * 2010-11-10 2012-05-18 정웅규 벽지용 점접착제 및 이를 도포하여 제조된 수용해성 점접착식 벽지
CN102816272A (zh) * 2012-08-31 2012-12-12 佛山市三水灏诚合成树脂有限公司 一种耐白电油苯乙烯-丙烯酸乳液、乳液光油及其制备方法

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101086148A (zh) * 2007-06-28 2007-12-12 上海东升新材料有限公司 纸用乳液干强剂及其制备方法
CN101177923A (zh) * 2007-11-30 2008-05-14 华南理工大学 一种造纸用苯丙乳液表面施胶剂及其合成方法
CN102444049A (zh) * 2010-10-15 2012-05-09 中国海洋石油总公司 一种乳液型纸张用助剂及其制备方法以及包含其的纸张
KR20120050071A (ko) * 2010-11-10 2012-05-18 정웅규 벽지용 점접착제 및 이를 도포하여 제조된 수용해성 점접착식 벽지
CN102816272A (zh) * 2012-08-31 2012-12-12 佛山市三水灏诚合成树脂有限公司 一种耐白电油苯乙烯-丙烯酸乳液、乳液光油及其制备方法

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
LI, RUSONG ET AL.: "The Preparation of a Self-Crosslinking Binder for Pigment Printing", JOURNAL OF HUAZHONG UNIVERSITY OF SCIENCE AND TECHNOLOGY, vol. 24, no. II, 31 August 1996 (1996-08-31), pages 131 - 133 *

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