WO2015192321A1 - Infrared ray low warming pigment composition and infrared ray low warming material - Google Patents

Infrared ray low warming pigment composition and infrared ray low warming material Download PDF

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Publication number
WO2015192321A1
WO2015192321A1 PCT/CN2014/080105 CN2014080105W WO2015192321A1 WO 2015192321 A1 WO2015192321 A1 WO 2015192321A1 CN 2014080105 W CN2014080105 W CN 2014080105W WO 2015192321 A1 WO2015192321 A1 WO 2015192321A1
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Prior art keywords
pigment
component
red
yellow
blue
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PCT/CN2014/080105
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French (fr)
Chinese (zh)
Inventor
苏文渊
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李耀辉
苏文渊
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Priority to PCT/CN2014/080105 priority Critical patent/WO2015192321A1/en
Publication of WO2015192321A1 publication Critical patent/WO2015192321A1/en

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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes

Definitions

  • the present invention relates to a pigment composition, and more particularly to an infrared low-temperature pigment composition and an infrared low-temperature material. Background technique
  • the vehicle seat is made of plastic material, such as polyvinyl chloride (PVC), polypropylene (PP), etc., and in order to reduce the staininess of the seat and the obvious degree of reflection, it is usually added to the plastic and easily used as a pigment.
  • Carbon black (car bon bl ac k). Although the use of carbon black can avoid dirt, it has the disadvantage of easily absorbing infrared rays and causing the seat to heat up rapidly.
  • various products with low temperature-increasing properties and cool feelings such as cool-feeling clothes, low-heating cushions, etc.
  • the raw material is added or added with a raw material having a cool feeling.
  • Raw materials with low temperature-increasing properties include pigments or other reagents in addition to the polymer materials used to make the substrate.
  • Japanese Patent Laid-Open No. 2002-249676 discloses a near-infrared reflective composite pigment comprising a near-infrared reflective and/or near-infrared penetrating pigment and a white pigment having good near-infrared reflectance, but it is required to be White pigment assisted;
  • Japanese Patent Laid-Open No. 2006- 24941 1 discloses a black pigment for infrared reflection, which is composed of a metal composite oxide such as iron or cobalt, and also has a good infrared reflectance, but the pigment needs to undergo a high-temperature firing process. Moreover, this document does not disclose that the pigment has an application effect of lowering the temperature rise.
  • the inventors attempted to select a plurality of readily available pigment components to be mixed to obtain an infrared low-temperature pigment composition, and the infrared low-temperature pigment composition can be made into an infrared low-temperature material with a substrate.
  • An object of the present invention is to provide an infrared low-temperature-increasing pigment composition which can reduce the temperature increase effect by absorbing infrared rays.
  • the infrared low-temperature pigment composition of the present invention comprises at least two pigment components selected from the group consisting of a red pigment component, a yellow pigment component, a blue pigment component, an orange pigment component, and a purple pigment component. , brown pigment component or white pigment component.
  • the red pigment component is selected from the group consisting of Pigment Red 122, Pigment Red 144, Pigment Red 149, Pigment Red 166, Pigment Red 181, Pigment Red 202, Pigment Red 214, Pigment Red 221, Pigment Red 242, Pigment Red 254, Pigment Red 262, or any combination of the foregoing.
  • the yellow pigment component is selected from the group consisting of Pigment Yellow 81 (pi grriEnt yel l ow 81), Pigment Yellow 83, Pigment Yellow 109, Pigment Yellow 110, Pigment Yellow 120, Pigment Yellow 128, Pigment Yellow 138, Pigment Yellow 147, Pigment Yellow 181, Pigment Yellow 183, Pigment Yellow 214 or any combination of the foregoing.
  • the blue pigment component is selected from the Pigment Blue 15 series (pigrriEnt bl ue 15 seri es, for example: Pigment Blue 15, Pigment Blue 15: 1, Pigment Blue 15: 2, Pigment Blue 15: 3, Pigment Blue 15: 4. Pigment Blue 15:6), Pigment Blue 16, Pigment Blue 60, Pigment Blue 80 or any combination of the foregoing.
  • the orange pigment component is selected from Pigment Orange 43 (Pigment Orange 43), Pigment Orange 61, Pigment Orange 64, Pigment Orange 68, Pigment Orange 72, or any combination of the foregoing.
  • the violet pigment component is selected from PighoEnt violet 19, Pigment Violet 37, Pigment Violet 23 or any combination of the foregoing.
  • the brown pigment component is Pigment browi 23 (pigment browi 23).
  • the white pigment component is pigment white 6 ( 0 ) These pigments are expressed according to the color index (col or i ndex) generic name.
  • Another object of the present invention is to provide an infrared low temperature heating material comprising the infrared low temperature heating pigment composition and a substrate, which has a low temperature rising effect after absorbing infrared rays, can effectively reduce the heat absorption degree of the material, and further reduce Light user discomfort and reduce unnecessary energy consumption.
  • the beneficial effect of the invention is that the infrared low-temperature pigment composition of the invention can reduce the temperature rising effect caused by absorbing infrared rays, and the infrared low-temperature heating material of the invention has low temperature-raising effect after absorbing infrared rays, and can effectively reduce the material.
  • the degree of heat absorption does not require the user to reduce the temperature of the material by consuming energy.
  • FIG. 1 is an infrared temperature elevation diagram illustrating the temperature rise of the black PVC film of Application Example 1, Comparative Application Example 1 and Comparative Application Example 2 after infrared irradiation, curve A shows the test result of Comparative Application Example 1, and curve B shows the comparative application example. 2 test results and curves (: indicates the test results of application example 1;
  • FIG. 2 is an infrared heating diagram illustrating the temperature rise of the black PVC film of Application Example 2 after infrared irradiation;
  • Fig. 3 is an infrared radiation diagram showing the temperature rise of the black PVC film of Application Example 3 after infrared irradiation. detailed description
  • the infrared low-temperature pigment composition of the present invention comprises at least two pigment components selected from the group consisting of a red pigment component, a yellow pigment component, a blue pigment component, an orange pigment component, and a purple pigment component. , brown pigment component or white pigment component.
  • the selection of the pigment components is based on the pigments indicated by the color index generic names listed above.
  • the pigment composition of the present invention can be selected according to the subsequent application, and the color of the pigment composition finally obtained can be any color.
  • the infrared low temperature pigment composition comprises a primary pigment component and an auxiliary pigment component.
  • the primary pigment component is selected from the red pigment component, the yellow pigment component, the blue pigment component, or any combination of the foregoing.
  • the auxiliary pigment component is selected from the orange pigment component, the violet pigment component, the brown pigment component, the white pigment component, or any combination of the foregoing.
  • the infrared low temperature pigment composition comprises a red pigment component, a yellow pigment component and a blue pigment component.
  • the red pigment component is selected from the group consisting of Pigment Red 1 22, Pigment Red 144, Pigment Red 149, Pigment Red 1 66, Pigment Red 1 81, Pigment Red 202, Pigment Red 214, Pigment Red 221, Pigment Red 242, Pigment Red 254, Pigment Red 262 or any combination of the foregoing.
  • the yellow pigment component is selected from the group consisting of Pigment Yellow 81, Pigment Yellow 83, Pigment Yellow 109, Pigment Yellow 1 10, Pigment Yellow 1 20, Pigment Yellow 1 28, Pigment Yellow 138, Pigment Yellow 147, Pigment Yellow 1 81 , Pigment Yellow 1 83, Pigment Yellow 214 or any combination of the foregoing.
  • the blue pigment component is selected from Pigment Blue 15 series (eg: Pigment Blue 15, Pigment Blue 15: 1, Pigment Blue 15: 2, Pigment Blue 15: 3, Pigment Blue 15: 4, Pigment Blue 15: 6), Pigment Blue 16, Pigment Blue 60. Pigment Blue 80 or any combination of the foregoing.
  • Pigment Blue 15 series eg: Pigment Blue 15, Pigment Blue 15: 1, Pigment Blue 15: 2, Pigment Blue 15: 3, Pigment Blue 15: 4, Pigment Blue 15: 6
  • Pigment Blue 16 Pigment Blue 60.
  • Pigment Blue 80 or any combination of the foregoing.
  • the total content of the pigment composition is 100 v ⁇ t ⁇ 1 ⁇ 2, the content of the red pigment component ranges from 11 to 50 wt%, and the content of the yellow pigment component ranges from 26 to 67 v ⁇ t. %, the content of the blue pigment component ranges from 13 to 47 wt ° / 3 ⁇ 4
  • the infrared low temperature rising material of the present invention comprises the infrared low temperature rising pigment composition and the substrate as described above.
  • the infrared low temperature heating material is prepared by adding the infrared low temperature pigment composition to a color masterbatch, a color paste or an ink, and then adding it to the substrate in an appropriate addition ratio.
  • the substrate is a polyvinyl chloride based substrate.
  • the infrared low temperature material is tested according to ASTM D803 and has a final stable temperature of 65-70 °C.
  • the infrared low temperature heating material further comprises an existing additive such as a plasticizer, a liquid stabilizer, a UV absorber, an antioxidant, a surfactant, a lubricant, a flame retardant or any combination of the foregoing.
  • an existing additive such as a plasticizer, a liquid stabilizer, a UV absorber, an antioxidant, a surfactant, a lubricant, a flame retardant or any combination of the foregoing.
  • the infrared low temperature heating material is suitable for most materials requiring low temperature increasing effects, for example, in general methods for automotive interior materials (such as plastics, plastic coating, fiber fabrics), automotive paints, baking varnishes, and paints for vehicles. , outdoor insulation paint, plastic building materials or paving materials (such as cement pavement).
  • the infrared low temperature heating material is suitable for use in black, gray or brown materials.
  • the invention is further described in the following examples, but it should be understood that these examples are for illustrative purposes only and are not to be construed as limiting.
  • the pigment compositions of Examples 1-6 were prepared by mixing according to the pigment types and content ratios in Table 1 below.
  • a total weight of the pigment composition of each of the examples is 100 wtQ / ⁇ 10
  • PVQ film Polyvinyl chloride
  • the PVC powder (S-60), the non-phthalate plasticizer, the calcium/zinc liquid stabilizer and the ultraviolet absorber are mixed in a weight ratio of 100:40:1.5:1 to obtain a PVC component.
  • Example 1 The pigment composition of Example 1 and the PVC powder were formulated into a color masterbatch (containing 25-35 v ⁇ t Q / pigment composition, the balance being PVC powder), and the color masterbatch was added to the above PVC component for color development ( containing 7-10 ⁇ t Q / masterbatch), to give a black PVC film E1.
  • a color masterbatch containing 25-35 v ⁇ t Q / pigment composition, the balance being PVC powder
  • the color masterbatch was added to the above PVC component for color development ( containing 7-10 ⁇ t Q / masterbatch), to give a black PVC film E1.
  • Application Example 2-6 differs from Application Example 1 in that the pigment composition of Example 1 was replaced with the pigment composition of Example 2-6, respectively, and the black PVC film E2-E6 was obtained by color development.
  • Comparative Application Example 1 differs from Application Example 1 in that the pigment composition of Example 1 was replaced with carbon black, and a carbon black PVC film C1 was obtained by color development.
  • Comparative Application Example 2 differs from Application Example 1 in that a commercially available pigment (IR bl ack, main The composition was pigment green 1 7 and pigment blue 1 5: 3) Substituting the pigment composition of Example 1 and developing a black PVC film C2.
  • a commercially available pigment IR bl ack, main The composition was pigment green 1 7 and pigment blue 1 5: 3
  • the infrared light (Phi I i ps PAR38 IR Red 1 50W 1 25-130V, wavelength range 600-1400 nn) and PVC film are irradiated for 60 minutes at a distance of 17 cm, and the infrared thermometer is used every 5 minutes.
  • the PVC film temperature of Application Example 1 and the comparative application examples was measured, and the results are shown in Fig. 1.
  • the temperature of the PVC film of Application Example 2-6 was measured, and the results of Application Example 2 and Application Example 3 are shown in Fig. 2 and Fig. 3, respectively.
  • Figure 1 shows a black PVC film E1 using the infrared low-temperature pigment composition of the present invention, which has a temperature of less than 65 ° C after 60 minutes of absorption of infrared rays (curve C of Figure 1);
  • Figure 2 shows the use of the infrared low-temperature pigment of the present invention.
  • the composition of the black PVC film E2, which absorbs infrared rays for 55 minutes, has a temperature of about 70 ° C;
  • Figure 3 shows a black PVC film E3 using the infrared low-temperature pigment composition of the present invention, which absorbs infrared rays for about 55 minutes.
  • the results of the application examples 4-6 are similar to the application examples 2 - 3; the application examples 1 - 6 are significantly more than the temperature of the application of the carbon black PVC film C1 (greater than 100 ° C, as shown in Figure 1 Curve A) and the temperature of the black PVC film C2 prepared by using the commercially available pigment of Comparative Example 2 (higher than 78 ° C, as shown by curve B in FIG. 1 ) are low, which proves that the infrared low-temperature pigment composition of the present invention can reduce the absorption of infrared rays. The resulting warming effect.
  • the infrared low-temperature pigment composition of the present invention can reduce the temperature rising effect caused by absorbing infrared rays, and the infrared low-temperature heating material of the invention has low temperature-raising effect after absorbing infrared rays, and can effectively reduce the heat absorption degree of the material. The user does not need to consume energy to lower the temperature of the material.

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

An infrared ray low warming pigment composition comprises at least two pigment components selected from the group consisting of a red pigment component, a yellow pigment component, a blue pigment component, an orange pigment component, a purple pigment component, a brown pigment component and a white pigment component. The infrared ray low warming pigment composition can effectively reduce the warming effect resulting from infrared ray absorption. Also provided is an infrared ray low warming material, comprising the infrared ray low warming pigment composition and a substrate material. The infrared ray low warming material is low in warming effect subsequent to infrared ray absorption, which can effectively reduce the degree of heat absorption of the infrared ray low warming material.

Description

红外线低升温颜料组成物及红外线低升温材料 技术领域  Infrared low temperature heating pigment composition and infrared low temperature heating material
本发明涉及一种颜料组成物 ，特别是涉及一种红外线低升温颜料 组成物 ， 以及一种红外线低升温材料。 背景技术  The present invention relates to a pigment composition, and more particularly to an infrared low-temperature pigment composition and an infrared low-temperature material. Background technique
一般车辆座椅为塑料材质 ，例如聚氯乙烯（PVC)、 聚丙烯（PP)等 ， 且为了減少座椅的脏污及反光的明显程度 ，通常会在塑料中添加容易 取得且供作为颜料的碳黑（car bon bl ac k)。 碳黑的使用虽然可以避免 脏污 ，但其缺点是易吸收红外线而导致座椅快速升温。 近年来 ，随着 天气日益炎热 ， 各种具备低升温性质及凉爽感觉的商品（例如凉感衣 物、 低升温坐垫等）也不断地被开发 ， 而此类商品一般是通过使用具 备低升温性质的原料或者添加具有凉感的原料而制成。 具备低升温性 质的原料除了供制作基材的高分子材料外 ， 尚包含颜料、 或其他试剂 o  Generally, the vehicle seat is made of plastic material, such as polyvinyl chloride (PVC), polypropylene (PP), etc., and in order to reduce the staininess of the seat and the obvious degree of reflection, it is usually added to the plastic and easily used as a pigment. Carbon black (car bon bl ac k). Although the use of carbon black can avoid dirt, it has the disadvantage of easily absorbing infrared rays and causing the seat to heat up rapidly. In recent years, as the weather has become increasingly hot, various products with low temperature-increasing properties and cool feelings (such as cool-feeling clothes, low-heating cushions, etc.) have been continuously developed, and such products are generally used by using low-temperature-raising properties. The raw material is added or added with a raw material having a cool feeling. Raw materials with low temperature-increasing properties include pigments or other reagents in addition to the polymer materials used to make the substrate.
日本专利特开 2002- 249676公开一种近红外线反射性复合颜料 ， 包含一近红外线反射性及 /或近红外线穿透性颜料及一白色颜料 ， 具 有良好的近红外线反射率 ，但其需以该白色颜料辅助 ； 日本专利特开 2006- 24941 1 公开一种红外线反射用黑色颜料 ， 由铁、 钴等金属复合 氧化物构成 ，也具有良好的红外线反射率 ，但该颜料需经过高温烧制 过程 ， 且该文献未公开该颜料具有降低升温的应用效果。  Japanese Patent Laid-Open No. 2002-249676 discloses a near-infrared reflective composite pigment comprising a near-infrared reflective and/or near-infrared penetrating pigment and a white pigment having good near-infrared reflectance, but it is required to be White pigment assisted; Japanese Patent Laid-Open No. 2006- 24941 1 discloses a black pigment for infrared reflection, which is composed of a metal composite oxide such as iron or cobalt, and also has a good infrared reflectance, but the pigment needs to undergo a high-temperature firing process. Moreover, this document does not disclose that the pigment has an application effect of lowering the temperature rise.
由上述可知 ， 以往使用碳黑或前述复合颜料仍存有许多问题 ，实 有开发一种容易取得且不需辅助的红外线低升温颜料组成物的需求。 发明内容  From the above, it has been found that there have been many problems in the conventional use of carbon black or the above-mentioned composite pigment, and there has been a demand for developing an infrared low-temperature pigment composition which is easy to obtain and which does not require assistance. Summary of the invention
鉴于前述的问题 ，发明人尝试选择多种容易取得的颜料组分加以 混合 ，以得到红外线低升温颜料组成物 ，且该红外线低升温颜料组成 物能与基材制成红外线低升温材料。  In view of the foregoing problems, the inventors attempted to select a plurality of readily available pigment components to be mixed to obtain an infrared low-temperature pigment composition, and the infrared low-temperature pigment composition can be made into an infrared low-temperature material with a substrate.
本发明的目的在于提供一种红外线低升温颜料组成物 ，可降低因 吸收红外线而造成的升温效果。 本发明红外线低升温颜料组成物包含至少两种颜料组分 ，该等颜 料组分是选自于红色颜料组分、 黄色颜料组分、 蓝色颜料组分、 橙色 颜料组分、 紫色颜料组分、 棕色颜料组分或白色颜料组分。 该红色颜 料组分是选自于颜料红 122 (pigment red 122)、 颜料红 144、 颜料 红 149、 颜料红 166、 颜料红 181、 颜料红 202、 颜料红 214、 颜料红 221、 颜料红 242、 颜料红 254、 颜料红 262或前述物质的任一组合。 该黄色颜料组分是选自于颜料黄 81 ( pi grriEnt yel l ow 81)、 颜料黄 83、 颜料黄 109、 颜料黄 110、 颜料黄 120、 颜料黄 128、 颜料黄 138、 颜料黄 147、 颜料黄 181、 颜料黄 183、 颜料黄 214或前述物质的任一 组合。 该蓝色颜料组分是选自于颜料蓝 15 系列（pigrriEnt bl ue 15 seri es ,例如 ：颜料蓝 15、 颜料蓝 15: 1、 颜料蓝 15: 2、 颜料蓝 15: 3、 颜料蓝 15: 4、 颜料蓝 15:6)、 颜料蓝 16、 颜料蓝 60、 颜料蓝 80或前 述物质的任一组合。 该橙色颜料组分是选自于颜料橙 43 (pigment orange 43), 颜料橙 61、 颜料橙 64、 颜料橙 68、 颜料橙 72或前述物 质的任一组合。 该紫色颜料组分是选自于颜料紫 19(pigrriEnt violet 19)、 颜料紫 37、 颜料紫 23或前述物质的任一组合。 该棕色颜料组分 是颜料棕 23 (pigment browi 23)。 该白色颜料组分是颜料白 6 (pigment white 6)0 该等颜料是依据颜色索引（ col or i ndex)通用名 称表示。 An object of the present invention is to provide an infrared low-temperature-increasing pigment composition which can reduce the temperature increase effect by absorbing infrared rays. The infrared low-temperature pigment composition of the present invention comprises at least two pigment components selected from the group consisting of a red pigment component, a yellow pigment component, a blue pigment component, an orange pigment component, and a purple pigment component. , brown pigment component or white pigment component. The red pigment component is selected from the group consisting of Pigment Red 122, Pigment Red 144, Pigment Red 149, Pigment Red 166, Pigment Red 181, Pigment Red 202, Pigment Red 214, Pigment Red 221, Pigment Red 242, Pigment Red 254, Pigment Red 262, or any combination of the foregoing. The yellow pigment component is selected from the group consisting of Pigment Yellow 81 (pi grriEnt yel l ow 81), Pigment Yellow 83, Pigment Yellow 109, Pigment Yellow 110, Pigment Yellow 120, Pigment Yellow 128, Pigment Yellow 138, Pigment Yellow 147, Pigment Yellow 181, Pigment Yellow 183, Pigment Yellow 214 or any combination of the foregoing. The blue pigment component is selected from the Pigment Blue 15 series (pigrriEnt bl ue 15 seri es, for example: Pigment Blue 15, Pigment Blue 15: 1, Pigment Blue 15: 2, Pigment Blue 15: 3, Pigment Blue 15: 4. Pigment Blue 15:6), Pigment Blue 16, Pigment Blue 60, Pigment Blue 80 or any combination of the foregoing. The orange pigment component is selected from Pigment Orange 43 (Pigment Orange 43), Pigment Orange 61, Pigment Orange 64, Pigment Orange 68, Pigment Orange 72, or any combination of the foregoing. The violet pigment component is selected from PighoEnt violet 19, Pigment Violet 37, Pigment Violet 23 or any combination of the foregoing. The brown pigment component is Pigment browi 23 (pigment browi 23). The white pigment component is pigment white 6 ( 0 ) These pigments are expressed according to the color index (col or i ndex) generic name.
虽然前述颜料组分皆属市售商品 ，但从未有人试图通过选择并混 合该等颜料组分以得到该红外线低升温颜料组成物 ，此概念应为前所 未有且不易思及 ，否则业界不会持续苦思开发新的颜料以解决前述问 题。  Although the aforementioned pigment components are commercially available, no one has attempted to obtain the infrared low-temperature pigment composition by selecting and mixing the pigment components. This concept should be unprecedented and unthinkable, otherwise the industry will not continue. I am thinking about developing new pigments to solve the aforementioned problems.
本发明的另一个目的在于提供一种红外线低升温材料 ，包含该红 外线低升温颜料组成物及基材 ， 其在吸收红外线后的升温效果较低 ， 能有效降低该材料的吸热程度 ，进而減轻使用者的不适 ，并減少不必 要的能源消耗。  Another object of the present invention is to provide an infrared low temperature heating material comprising the infrared low temperature heating pigment composition and a substrate, which has a low temperature rising effect after absorbing infrared rays, can effectively reduce the heat absorption degree of the material, and further reduce Light user discomfort and reduce unnecessary energy consumption.
本发明的有益的效果在于 ：本发明红外线低升温颜料组成物可降 低因吸收红外线而造成的升温效果 ，且本发明红外线低升温材料在吸 收红外线后的升温效果较低 ，能有效降低该材料的吸热程度 ，使用者 不需通过消耗能源来降低该材料的温度。 附图说明 The beneficial effect of the invention is that the infrared low-temperature pigment composition of the invention can reduce the temperature rising effect caused by absorbing infrared rays, and the infrared low-temperature heating material of the invention has low temperature-raising effect after absorbing infrared rays, and can effectively reduce the material. The degree of heat absorption does not require the user to reduce the temperature of the material by consuming energy. DRAWINGS
图 1是红外线升温图 ， 说明应用例 1、 比较应用例 1及比较应用 例 2的黑色 PVC胶片在红外线照射后的升温情形 ，曲线 A表示比较应 用例 1 的测试结果、 曲线 B表示比较应用例 2的测试结果及曲线（：表 示应用例 1 的测试结果 ；  1 is an infrared temperature elevation diagram illustrating the temperature rise of the black PVC film of Application Example 1, Comparative Application Example 1 and Comparative Application Example 2 after infrared irradiation, curve A shows the test result of Comparative Application Example 1, and curve B shows the comparative application example. 2 test results and curves (: indicates the test results of application example 1;
图 2是红外线升温图 ，说明应用例 2的黑色 PVC胶片在红外线照 射后的升温情形 ； 及  2 is an infrared heating diagram illustrating the temperature rise of the black PVC film of Application Example 2 after infrared irradiation;
图 3是红外线升温图 ，说明应用例 3的黑色 PVC胶片在红外线照 射后的升温情形。 具体实施方式  Fig. 3 is an infrared radiation diagram showing the temperature rise of the black PVC film of Application Example 3 after infrared irradiation. detailed description
下面结合附图及实施例对本发明进行详细说明。  The present invention will be described in detail below with reference to the accompanying drawings and embodiments.
本发明红外线低升温颜料组成物包含至少两种颜料组分 ，该等颜 料组分是选自于红色颜料组分、 黄色颜料组分、 蓝色颜料组分、 橙色 颜料组分、 紫色颜料组分、 棕色颜料组分或白色颜料组分。 该等颜料 组分的选择是参照上述所列举的通过颜色索引通用名称表示的颜料。 本发明颜料组成物可依据后续应用挑选适合的颜料组分 ，最终所制得 的颜料组成物的颜色可为任何颜色。  The infrared low-temperature pigment composition of the present invention comprises at least two pigment components selected from the group consisting of a red pigment component, a yellow pigment component, a blue pigment component, an orange pigment component, and a purple pigment component. , brown pigment component or white pigment component. The selection of the pigment components is based on the pigments indicated by the color index generic names listed above. The pigment composition of the present invention can be selected according to the subsequent application, and the color of the pigment composition finally obtained can be any color.
较佳地 ，该红外线低升温颜料组成物包含主要颜料组分及辅助颜 料组分。  Preferably, the infrared low temperature pigment composition comprises a primary pigment component and an auxiliary pigment component.
该主要颜料组分是选自于该红色颜料组分、 该黄色颜料组分、 该 蓝色颜料组分或前述物质的任一组合。 该辅助颜料组分选自于该橙色 颜料组分、 该紫色颜料组分、 该棕色颜料组分、 该白色颜料组分或前 述物质的任一组合。  The primary pigment component is selected from the red pigment component, the yellow pigment component, the blue pigment component, or any combination of the foregoing. The auxiliary pigment component is selected from the orange pigment component, the violet pigment component, the brown pigment component, the white pigment component, or any combination of the foregoing.
较佳地 ，该红外线低升温颜料组成物包含红色颜料组分、 黄色颜 料组分及蓝色颜料组分。  Preferably, the infrared low temperature pigment composition comprises a red pigment component, a yellow pigment component and a blue pigment component.
该红色颜料组分是选自于颜料红 1 22、 颜料红 144、 颜料红 149、 颜料红 1 66、 颜料红 1 81、 颜料红 202、 颜料红 214、 颜料红 221、 颜 料红 242、 颜料红 254、 颜料红 262或前述物质的任一组合。 该黄色 颜料组分是选自于颜料黄 81、 颜料黄 83、 颜料黄 1 09、 颜料黄 1 1 0、 颜料黄 1 20、 颜料黄 1 28、 颜料黄 138、 颜料黄 147、 颜料黄 1 81、 颜 料黄 1 83、 颜料黄 214或前述物质的任一组合。 该蓝色颜料组分是选 自于颜料蓝 15系列（例如 ： 颜料蓝 15、 颜料蓝 15: 1、 颜料蓝 15: 2、 颜料蓝 15: 3、 颜料蓝 15: 4、 颜料蓝 15: 6)、 颜料蓝 16、 颜料蓝 60、 颜料蓝 80或前述物质的任一组合。 The red pigment component is selected from the group consisting of Pigment Red 1 22, Pigment Red 144, Pigment Red 149, Pigment Red 1 66, Pigment Red 1 81, Pigment Red 202, Pigment Red 214, Pigment Red 221, Pigment Red 242, Pigment Red 254, Pigment Red 262 or any combination of the foregoing. The yellow pigment component is selected from the group consisting of Pigment Yellow 81, Pigment Yellow 83, Pigment Yellow 109, Pigment Yellow 1 10, Pigment Yellow 1 20, Pigment Yellow 1 28, Pigment Yellow 138, Pigment Yellow 147, Pigment Yellow 1 81 , Pigment Yellow 1 83, Pigment Yellow 214 or any combination of the foregoing. The blue pigment component is selected From Pigment Blue 15 series (eg: Pigment Blue 15, Pigment Blue 15: 1, Pigment Blue 15: 2, Pigment Blue 15: 3, Pigment Blue 15: 4, Pigment Blue 15: 6), Pigment Blue 16, Pigment Blue 60. Pigment Blue 80 or any combination of the foregoing.
较佳地 ， 基于该颜料组成物的总重为 100 v\t<½, 该红色颜料组分 的含量范围为 11-50 wt%, 该黄色颜料组分的含量范围为 26-67 v\t%, 该蓝色颜料组分的含量范围为 13-47 wt°/¾  Preferably, the total content of the pigment composition is 100 v\t<1⁄2, the content of the red pigment component ranges from 11 to 50 wt%, and the content of the yellow pigment component ranges from 26 to 67 v\t. %, the content of the blue pigment component ranges from 13 to 47 wt ° / 3⁄4
本发明红外线低升温材料包含如上所述的红外线低升温颜料组 成物及基材。  The infrared low temperature rising material of the present invention comprises the infrared low temperature rising pigment composition and the substrate as described above.
较佳地 ，该红外线低升温材料是通过将该红外线低升温颜料组成 物调制成色母、 色膏或油墨 ， 再依适当添加比例添加至基材中。  Preferably, the infrared low temperature heating material is prepared by adding the infrared low temperature pigment composition to a color masterbatch, a color paste or an ink, and then adding it to the substrate in an appropriate addition ratio.
较佳地 ， 该基材为聚氯乙烯系基材。  Preferably, the substrate is a polyvinyl chloride based substrate.
较佳地 ，该红外线低升温材料 ，依据 ASTMD 803测试 ，具有 65-70 °C的最终稳定温度。  Preferably, the infrared low temperature material is tested according to ASTM D803 and has a final stable temperature of 65-70 °C.
较佳地 ，该红外线低升温材料还包含现有的添加剂 ，例如塑化剂、 液体安定剂、 紫外线吸收剂、 抗氧化剂、 界面活性剂、 润滑剂、 阻燃 剂或前述物质的任一组合。  Preferably, the infrared low temperature heating material further comprises an existing additive such as a plasticizer, a liquid stabilizer, a UV absorber, an antioxidant, a surfactant, a lubricant, a flame retardant or any combination of the foregoing.
较佳地 ，该红外线低升温材料适用于大多数需要低升温效果的素 材中 ， 例如以一般方法应用于汽车内装材料（如塑料、 塑料涂布、 纤 维织物）、 汽车漆、 烤漆、 器械涂漆、 户外隔热漆、 塑料建材或铺面 材料 (如水泥路面)。  Preferably, the infrared low temperature heating material is suitable for most materials requiring low temperature increasing effects, for example, in general methods for automotive interior materials (such as plastics, plastic coating, fiber fabrics), automotive paints, baking varnishes, and paints for vehicles. , outdoor insulation paint, plastic building materials or paving materials (such as cement pavement).
较佳地 ， 该红外线低升温材料适用黑色、 灰色或棕色的素材中。 本发明将就以下实施例作进一步说明 ，但应了解的是 ，该等实施 例仅为例示说明用 ， 而不应被解释为本发明实施的限制。  Preferably, the infrared low temperature heating material is suitable for use in black, gray or brown materials. The invention is further described in the following examples, but it should be understood that these examples are for illustrative purposes only and are not to be construed as limiting.
<实施例 >颜料组成物 <Examples> Pigment Compositions
[实施例 1-6] [Example 1-6]
依据下表 1 的颜料种类及含量比例进行混合 ， 以制得实施例 1-6 的颜料组成物。  The pigment compositions of Examples 1-6 were prepared by mixing according to the pigment types and content ratios in Table 1 below.
表 1  Table 1
实施例编号 各个颜料的组成 [含量（wtQ/T]  Example No. Composition of each pigment [Content (wtQ/T]
颜料黄 110 [60.0]  Pigment Yellow 110 [60.0]
1  1
颜料红 122 [17.5] 颜料蓝 60 [22.5] Pigment Red 122 [17.5] Pigment Blue 60 [22.5]
颜料橙 61 [56]  Pigment Orange 61 [56]
2  2
颜料蓝 60 [44]  Pigment Blue 60 [44]
颜料黄 110 [67]  Pigment Yellow 110 [67]
3  3
颜料紫 23 [33]  Pigment Violet 23 [33]
颜料黄 138 [55.0]  Pigment Yellow 138 [55.0]
4 颜料红 166 [32.0]  4 Pigment Red 166 [32.0]
颜料蓝 16 [13.0]  Pigment Blue 16 [13.0]
颜料黄 109 [52.0]  Pigment Yellow 109 [52.0]
5 颜料红 166 [25.0]  5 Pigment Red 166 [25.0]
颜料蓝 15:3 [23.0]  Pigment Blue 15:3 [23.0]
颜料黄 120 [52.0]  Pigment Yellow 120 [52.0]
6 颜料红 254 [28.0]  6 Pigment Red 254 [28.0]
颜料蓝 15:3 [20.0]  Pigment Blue 15:3 [20.0]
a以各个实施例的颜料组成物总重为 100 wtQ/ά十算 a total weight of the pigment composition of each of the examples is 100 wtQ / ά10
<应用例 >聚氯乙烯（ PVQ胶片 <Application example> Polyvinyl chloride (PVQ film)
[应用例 1] [Application Example 1]
将 PVC粉末（S-60)、 非邻苯二甲酸酯塑化剂、 钙 /锌液体安定剂 及紫外线吸收剂以 100： 40： 1.5： 1 的重量比例混合 ，得到一 PVC组 分。  The PVC powder (S-60), the non-phthalate plasticizer, the calcium/zinc liquid stabilizer and the ultraviolet absorber are mixed in a weight ratio of 100:40:1.5:1 to obtain a PVC component.
将实施例 1 的颜料组成物与该 PVC粉末配制成一色母（含 25-35 v\tQ/颜料组成物 ，其余为 PVC粉末） ，再将该色母加入上述 PVC组分中 展色（含 7-10 \tQ/色母） ， 得到一黑色 PVC胶片 E1。 The pigment composition of Example 1 and the PVC powder were formulated into a color masterbatch (containing 25-35 v\t Q / pigment composition, the balance being PVC powder), and the color masterbatch was added to the above PVC component for color development ( containing 7-10 \ t Q / masterbatch), to give a black PVC film E1.
[应用例 2-6] [Application Example 2-6]
应用例 2-6与应用例 1不同处在于分别以实施例 2-6的颜料组成 物取代实施例 1 的颜料组成物 ，并分别展色得到黑色 PVC胶片 E2-E6。  Application Example 2-6 differs from Application Example 1 in that the pigment composition of Example 1 was replaced with the pigment composition of Example 2-6, respectively, and the black PVC film E2-E6 was obtained by color development.
[比较应用例 1] [Comparative Application Example 1]
比较应用例 1与应用例 1不同处在于以碳黑取代实施例 1的颜料 组成物 ， 并展色得到一碳黑 PVC胶片 C1。  Comparative Application Example 1 differs from Application Example 1 in that the pigment composition of Example 1 was replaced with carbon black, and a carbon black PVC film C1 was obtained by color development.
[比较应用例 2] [Comparative Application Example 2]
比较应用例 2与应用例 1 不同处在于以市售颜料（IR bl ack , 主 要成分为颜料绿 1 7与颜料蓝 1 5: 3)取代实施例 1 的颜料组成物 ，并展 色得到一黑色 PVC胶片 C2。 Comparative Application Example 2 differs from Application Example 1 in that a commercially available pigment (IR bl ack, main The composition was pigment green 1 7 and pigment blue 1 5: 3) Substituting the pigment composition of Example 1 and developing a black PVC film C2.
<测试例 1 >红外线升温测试  <Test example 1 > Infrared heating test
依据美国材料试验学会（ASTM D4803 标准测试方法 ， 进行 PVC 材料升温测试 ， 简述如下 ：  According to the American Society for Testing and Materials (ASTM D4803 standard test method, the PVC material heating test is briefly described as follows:
在 21 °C , 以红外线灯（ Phi I i ps PAR38 I R Red 1 50W 1 25- 130V , 波长范围 600- 1400 nn)与 PVC胶片距离 1 7厘米照射 60分钟 ，并以红 外线温度计每隔 5分钟分别量测应用例 1与该等比较应用例的 PVC胶 片温度 ， 其结果如图 1所示。 分别量测应用例 2- 6的 PVC胶片温度 ， 其中应用例 2及应用例 3的结果分别如图 2及图 3所示。  At 21 °C, the infrared light (Phi I i ps PAR38 IR Red 1 50W 1 25-130V, wavelength range 600-1400 nn) and PVC film are irradiated for 60 minutes at a distance of 17 cm, and the infrared thermometer is used every 5 minutes. The PVC film temperature of Application Example 1 and the comparative application examples was measured, and the results are shown in Fig. 1. The temperature of the PVC film of Application Example 2-6 was measured, and the results of Application Example 2 and Application Example 3 are shown in Fig. 2 and Fig. 3, respectively.
图 1 显示使用本发明红外线低升温颜料组成物的黑色 PVC胶片 E1 ,其吸收红外线 60分钟后的温度低于 65°C (如图 1 的曲线 C) ；图 2 显示使用本发明红外线低升温颜料组成物的黑色 PVC胶片 E2 ,其吸收 红外线 55分钟后的温度约为 70°C ； 图 3显示使用本发明红外线低升 温颜料组成物的黑色 PVC胶片 E3 , 其吸收红外线 55分钟后的温度约 为 65°C ；应用例 4- 6的结果旨与应用例 2- 3类似 ；应用例 1 - 6旨明显 较比较应用例 1碳黑 PVC胶片 C1 的温度（大于 1 00°C , 如图 1 的曲线 A)及比较应用例 2市售颜料制得的黑色 PVC胶片 C2的温度（大于 78 °C ,如图 1 的曲线 B)低 ，证明本发明红外线低升温颜料组成物可降低 因吸收红外线而造成的升温效果。  Figure 1 shows a black PVC film E1 using the infrared low-temperature pigment composition of the present invention, which has a temperature of less than 65 ° C after 60 minutes of absorption of infrared rays (curve C of Figure 1); Figure 2 shows the use of the infrared low-temperature pigment of the present invention. The composition of the black PVC film E2, which absorbs infrared rays for 55 minutes, has a temperature of about 70 ° C; Figure 3 shows a black PVC film E3 using the infrared low-temperature pigment composition of the present invention, which absorbs infrared rays for about 55 minutes. 65 ° C; the results of the application examples 4-6 are similar to the application examples 2 - 3; the application examples 1 - 6 are significantly more than the temperature of the application of the carbon black PVC film C1 (greater than 100 ° C, as shown in Figure 1 Curve A) and the temperature of the black PVC film C2 prepared by using the commercially available pigment of Comparative Example 2 (higher than 78 ° C, as shown by curve B in FIG. 1 ) are low, which proves that the infrared low-temperature pigment composition of the present invention can reduce the absorption of infrared rays. The resulting warming effect.
<测试例 2 >日晒升温测试  <Test Example 2 > Solar heating test
在 13时至 14时 ， 将比较应用例 1碳黑 PVC胶片 C1 制成的胶皮 及应用例 1 黑色 PVC胶片 E1 制成的胶皮（分别如图 4所示）置于户外 阳光直接曝晒处 ，每隔 5分钟分别量测两胶皮的温度 ，其结果分别如 下表 2所示 ： Between 13:00 and 14:00, the rubber made from the carbon black PVC film C1 of Application Example 1 and the rubber made of the black PVC film E1 of Application Example 1 (shown in Figure 4, respectively) are placed in direct sunlight exposure. The temperature of the two rubber sheets was measured every 5 minutes, and the results are shown in Table 2 below:
Figure imgf000007_0001
曝晒时间 C1制成的胶皮温度 E1制成的胶皮温度
Figure imgf000007_0001
Rubber temperature made by rubber temperature E1 made by exposure time C1
13: 00 28°C 28°C 13: 00 28°C 28°C
13: 05 39°C 32°C 13: 10 55°C 45°C 13: 05 39°C 32°C 13: 10 55 ° C 45 ° C
13： 1 5 62°C 52°C 13: 1 5 62°C 52°C
13: 20 73°C 53°C 13: 20 73°C 53°C
13: 25 76°C 56°C 13: 25 76°C 56°C
13: 30 80°C 60°C 13: 30 80 ° C 60 ° C
13: 35 81 °C 60°C 13: 35 81 °C 60 °C
13: 40 82°C 61 °C 13: 40 82°C 61 °C
13: 45 84°C 61 °C 13: 45 84°C 61 °C
13: 50 84°C 62°C 13: 50 84°C 62°C
13: 55 84°C 62°C 13: 55 84°C 62°C
14: 00 84°C 62°C 表 2 结果显示 ， Ε1 制成的胶皮在日晒过程中的升温速度明显较 C1 制成的胶皮低 ， 且在日晒 60分钟后的最终温度也明显较低 ， 证明 本发明红外线低升温颜料组成物可降低因日晒而造成的升温效果。 14: 00 84°C 62°C Table 2 The results show that the rubber produced by Ε1 has a lower heating rate during the sun exposure than the rubber made by C1, and the final temperature after 60 minutes of sun exposure is also significantly lower. It is proved that the infrared low-temperature pigment composition of the present invention can reduce the temperature rising effect caused by the sun exposure.
此外 ， 图 4结果显示 C1制成的胶皮呈现深红棕色 ， Ε1制成的胶 皮则呈现黑色。  In addition, the results in Figure 4 show that the rubber made of C1 is dark reddish brown, and the rubber made of Ε1 is black.
综上所述 ，本发明红外线低升温颜料组成物可降低因吸收红外线 而造成的升温效果 ，且本发明红外线低升温材料在吸收红外线后的升 温效果较低 ，能有效降低该材料的吸热程度 ，使用者不需通过消耗能 源来降低该材料的温度。  In summary, the infrared low-temperature pigment composition of the present invention can reduce the temperature rising effect caused by absorbing infrared rays, and the infrared low-temperature heating material of the invention has low temperature-raising effect after absorbing infrared rays, and can effectively reduce the heat absorption degree of the material. The user does not need to consume energy to lower the temperature of the material.
惟以上所述 ，仅为本发明的较佳实施例与具体例而已 ，当不能以 此限定本发明实施的范围 ，即大凡依本发明权利要求及发明说明内容 所作的简单的等效变化与修饰 ， 皆仍属本发明专利涵盖的范围内。  The above is only the preferred embodiments and the specific examples of the present invention, and the scope of the present invention is not limited thereto, that is, the simple equivalent changes and modifications made according to the claims and the description of the invention. , are still within the scope of the invention patent.

Claims

权 利 要 求 书 Claim
1. 一种红外线低升温颜料组成物 ， 其特征在于 ： 其包含至少 两种颜料组分 ， 所述颜料组分是选自于红色颜料组分、 黄色颜料组 分、 蓝色颜料组分、 橙色颜料组分、 紫色颜料组分、 棕色颜料组分 或白色颜料组分 ， 该红色颜料组分是选自于颜料红 122、 颜料红 144 、 颜料红 149、 颜料红 166、 颜料红 181、 颜料红 202、 颜料红 214、 颜 料红 221、 颜料红 242、 颜料红 254、 颜料红 262或前述物质的任一组 合 ，该黄色颜料组分是选自于颜料黄 81、 颜料黄 83、 颜料黄 109、 颜 料黄 110、 颜料黄 120、 颜料黄 128、 颜料黄 138、 颜料黄 147、 颜料黄 181、 颜料黄 183、 颜料黄 214或前述物质的任一组合 ，该蓝色颜料组 分是选自于颜料蓝 15系列、 颜料蓝 16、 颜料蓝 60、 颜料蓝 80或前述 物质的任一组合 ， 该橙色颜料组分是选自于颜料橙 43、 颜料橙 61、 颜料橙 64、 颜料橙 68、 颜料橙 72或前述物质的任一组合 ， 该紫色颜 料组分是选自于颜料紫 19、 颜料紫 37、 颜料紫 23或前述物质的任一 组合 ，该棕色颜料组分是颜料棕 23 ,该白色颜料组分是颜料白 6 ,所 述颜料是依据颜色索引通用名称表示。 An infrared low-temperature pigment composition characterized in that it comprises at least two pigment components selected from the group consisting of a red pigment component, a yellow pigment component, a blue pigment component, and an orange a pigment component, a purple pigment component, a brown pigment component or a white pigment component, the red pigment component being selected from the group consisting of Pigment Red 122, Pigment Red 144, Pigment Red 149, Pigment Red 166, Pigment Red 181, Pigment Red 202, Pigment Red 214, Pigment Red 221, Pigment Red 242, Pigment Red 254, Pigment Red 262, or any combination of the foregoing, the yellow pigment component is selected from Pigment Yellow 81, Pigment Yellow 83, Pigment Yellow 109, Pigment Yellow 110, Pigment Yellow 120, Pigment Yellow 128, Pigment Yellow 138, Pigment Yellow 147, Pigment Yellow 181, Pigment Yellow 183, Pigment Yellow 214, or any combination of the foregoing, the blue pigment component being selected from the pigment Blue 15 series, Pigment Blue 16, Pigment Blue 60, Pigment Blue 80 or any combination of the foregoing, the orange pigment component is selected from Pigment Orange 43, Pigment Orange 61, Yan Orange 64, Pigment Orange 68, Pigment Orange 72, or any combination of the foregoing, the violet pigment component being selected from Pigment Violet 19, Pigment Violet 37, Pigment Violet 23, or any combination of the foregoing, the brown pigment set The fraction is Pigment Brown 23, the white pigment component is Pigment White 6, and the pigment is expressed according to the color index common name.
2. 根据权利要求 1所述的红外线低升温颜料组成物 ，其特征在 于 ： 其包含主要颜料组分及辅助颜料组分 ， 该主要颜料组分是选自 于该红色颜料组分、 该黄色颜料组分、 该蓝色颜料组分或前述物质 的任一组合 ， 该辅助颜料组分选自于该橙色颜料组分、 该紫色颜料 组分、 该棕色颜料组分、 该白色颜料组分或前述物质的任一组合。  2. The infrared low-temperature pigment composition according to claim 1, comprising: a main pigment component and an auxiliary pigment component, the main pigment component being selected from the red pigment component, the yellow pigment a component, the blue pigment component, or any combination of the foregoing, the auxiliary pigment component being selected from the orange pigment component, the violet pigment component, the brown pigment component, the white pigment component, or the foregoing Any combination of substances.
3. 根据权利要求 1所述的红外线低升温颜料组成物 ，其特征在 于 ： 其包含红色颜料组分、 黄色颜料组分及蓝色颜料组分 ， 该红色 颜料组分是选自于颜料红 122、 颜料红 144、 颜料红 149、 颜料红 166 、 颜料红 181、 颜料红 202、 颜料红 214、 颜料红 221、 颜料红 242、 颜 料红 254、 颜料红 262或前述物质的任一组合 ， 该黄色颜料组分是选 自于颜料黄 81、 颜料黄 83、 颜料黄 109、 颜料黄 110、 颜料黄 120、 颜 料黄 128、 颜料黄 138、 颜料黄 147、 颜料黄 181、 颜料黄 183、 颜料黄 214或前述物质的任一组合 ，该蓝色颜料组分是选自于颜料蓝 15系列 、 颜料蓝 16、 颜料蓝 60、 颜料蓝 80或前述物质的任一组合。 3. The infrared low-temperature pigment composition according to claim 1, comprising: a red pigment component, a yellow pigment component, and a blue pigment component, the red pigment component being selected from the pigment red 122 , Pigment Red 144, Pigment Red 149, Pigment Red 166, Pigment Red 181, Pigment Red 202, Pigment Red 214, Pigment Red 221, Pigment Red 242, Pigment Red 254, Pigment Red 262, or any combination of the foregoing, the yellow The pigment component is selected from the group consisting of Pigment Yellow 81, Pigment Yellow 83, Pigment Yellow 109, Pigment Yellow 110, Pigment Yellow 120, Pigment Yellow 128, Pigment Yellow 138, Pigment Yellow 147, Pigment Yellow 181, Pigment Yellow 183, Pigment Yellow 214 Or any combination of the foregoing, the blue pigment component is selected from the group consisting of Pigment Blue 15 Series, Pigment Blue 16, Pigment Blue 60, Pigment Blue 80, or any combination of the foregoing.
4. 根据权利要求 3所述的红外线低升温颜料组成物 ，其特征在 于 ：基于该颜料组成物的总重为 100 wt%,该红色颜料组分的含量范 围为 11-50 wt%, 该黄色颜料组分的含量范围为 26-67 vvt%, 该蓝色 颜料组分的含量范围为 13-47 vvt0/¾ The infrared low-temperature pigment composition according to claim 3, wherein the red pigment component has a content ranging from 11 to 50% by weight based on the total weight of the pigment composition of 100% by weight. The content of the pigment component ranges from 26 to 67 vvt%, and the content of the blue pigment component ranges from 13 to 47 vvt 0 /3⁄4
5. 一种红外线低升温材料 ，其特征在于 ：其包含如权利要求 1 至 4中任一权利要求所述的红外线低升温颜料组成物及基材。  An infrared low-temperature heating material comprising the infrared low-temperature pigment composition according to any one of claims 1 to 4 and a substrate.
6. 根据权利要求 5所述的红外线低升温材料 ，其特征在于 ：依 据 ASTM D4803测试 ， 其具有 65- 70°C的最终稳定温度。  The infrared low temperature rising material according to claim 5, which has a final stable temperature of 65 to 70 ° C according to ASTM D4803 test.
PCT/CN2014/080105 2014-06-17 2014-06-17 Infrared ray low warming pigment composition and infrared ray low warming material WO2015192321A1 (en)

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