WO2015174692A1 - Combustible solide comprenant une masse algale contenant de l'huile et un additif pour combustible, et son procédé de production - Google Patents

Combustible solide comprenant une masse algale contenant de l'huile et un additif pour combustible, et son procédé de production Download PDF

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Publication number
WO2015174692A1
WO2015174692A1 PCT/KR2015/004635 KR2015004635W WO2015174692A1 WO 2015174692 A1 WO2015174692 A1 WO 2015174692A1 KR 2015004635 W KR2015004635 W KR 2015004635W WO 2015174692 A1 WO2015174692 A1 WO 2015174692A1
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WO
WIPO (PCT)
Prior art keywords
solid fuel
fuel
oil
algimass
fuel additive
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Application number
PCT/KR2015/004635
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English (en)
Korean (ko)
Inventor
박승민
나봉갑
최중부
Original Assignee
알펫 주식회사
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Application filed by 알펫 주식회사 filed Critical 알펫 주식회사
Publication of WO2015174692A1 publication Critical patent/WO2015174692A1/fr

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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L5/00—Solid fuels
    • C10L5/40—Solid fuels essentially based on materials of non-mineral origin
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L10/00—Use of additives to fuels or fires for particular purposes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L5/00—Solid fuels
    • C10L5/40—Solid fuels essentially based on materials of non-mineral origin
    • C10L5/44—Solid fuels essentially based on materials of non-mineral origin on vegetable substances
    • C10L5/445—Agricultural waste, e.g. corn crops, grass clippings, nut shells or oil pressing residues
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00—Technologies for the production of fuel of non-fossil origin
    • Y02E50/10—Biofuels, e.g. bio-diesel
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00—Technologies for the production of fuel of non-fossil origin
    • Y02E50/30—Fuel from waste, e.g. synthetic alcohol or diesel
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry
    • Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock

Definitions

  • renewable energy is being discussed as the most realistic and influential alternative that can simultaneously solve the future energy shortage problem and the greenhouse gas environmental problem.
  • the Fukushima nuclear power plant accident caused by the Great East Japan Earthquake has emphasized the necessity of developing renewable energy, which is clean energy.
  • Microalgae are photosynthetic aquatic single-celled organisms commonly called phytoplankton. There are more than 220,000 kinds of microalgae, and if only water, sunlight and carbon dioxide are supplied, photosynthesis is possible and unlimited growth is possible, and mass production is possible for a short time in various environments, and useful substances such as carbohydrates, proteins and unsaturated fatty acids It is a rich eco-friendly resource.
  • the solid fuel according to the present invention preferably comprises 20 to 50% by weight of Algemass including oil and 50 to 80% by weight of fuel additive.
  • the present invention comprises the steps of drying the algimass including oil; Putting the fuel additive into the crusher, crushing, drying and pulverizing; Grinding the dried and sterilized fuel additive; Mixing the fuel additive and the algimass comprising the oil; And it provides a method for producing a solid fuel comprising the step of molding a mixture of algimass and fuel additives including the oil.
  • the ash formed by burning the solid fuel including the algimass including the oil and the fuel additive according to the present invention is rich in nitrogen, phosphorus and potassium, etc. can be used as a raw material of the fertilizer.
  • the solid fuel according to the present invention includes 5 to 50% by weight of algimass and oil and 50 to 95% by weight of the fuel additive.
  • Microalgae contain fats and fatty acids as coatings, storage products, metabolites and energy sources.
  • Algae mass (algae mass) used in the present invention is produced by harvesting and drying the above-mentioned algae refers to the algae containing the oil in the dried state as a step before extracting the oil (oil) contained in the algae.
  • the solid fuel according to the present invention may be prepared by mixing an algemass and a fuel additive including an oil.
  • the fuel additives include wood pellets, rice bran, rice straw, rice husk, barley straw, corn stalk, sugar cane, bio ethanol residue, methanol residue, coffee shell, peanut shell, sunflower seed, sunflower seed shell, bamboo and low calorie coal.
  • wood pellets wood pellets, rice bran, rice straw, rice husk, barley straw, corn stalk, sugar cane, bio ethanol residue, methanol residue, coffee shell, peanut shell, sunflower seed, sunflower seed shell, bamboo and low calorie coal.
  • One kind or a mixture of two or more kinds selected from the group consisting of can be used.
  • low calorie coal refers to coal having a calorie of 3,800 kcal / kg to 4,000 kcal / kg or less.
  • the fuel additive may be used one or a mixture of two or more selected from the group consisting of charcoal, charcoal, loess, mud and low-calorie coal.
  • an excipient may be glue, starch and the like, but is not limited thereto.
  • Wood pellets, rice bran, rice straw, rice husk, barley straw, corn stalk, sugar cane, bio ethanol residue, methanol residue, coffee shell, peanut shell, sunflower seed, sunflower seed shell, bamboo, charcoal, charcoal, ocher and mud And low calorie coal is preferably pulverized and used.
  • the ash produced by the combustion is rich in nitrogen, phosphorus, potassium, and the like and can be used as a raw material of fertilizer.
  • the fuel additive is placed in a crusher, crushed, dried and sterilized.
  • the pulverized fuel additive is preferably dried and sterilized for about 2 to 5 minutes at a temperature of 150 ⁇ 200 °C in a drum type dryer.
  • the dried and sterilized fuel additive is ground to 10 mm or less.
  • the algimass containing the oil and the fuel additive are mixed to the above-mentioned content.
  • the mixture of the algimass and the fuel additive including the oil is molded and the molding size is adjusted according to the use. For example, in the case of power plant mixing, it can be molded 2 to 20 times more than wood pellets.
  • the solid fuel is produced by molding for 2 to 5 minutes at a pressure of 300 ⁇ 900 kgf / cm 2 at a temperature of 150 ⁇ 180 °C.
  • Cooled solid fuel should be stored in a silo tank for easy storage, loading and transportation.
  • the shape of the solid fuel according to the present invention may be pellet-shaped, perforated disk shape, almond shape, granule shape, pillow shape or finger shape.
  • Solid fuel was prepared in the same manner as in Example 1 except that rice husks were used instead of wood pellets.
  • Solid fuel was prepared in the same manner as in Example 1 except that the cornstalk was used instead of the wood pellets.
  • Solid fuel was prepared in the same manner as in Example 19 except that 100 g of charcoal and starch were used instead of wood pellets.
  • a solid fuel was prepared in the same manner as in Example 19 except that 100 g of loess and starch was used instead of wood pellets.
  • a solid fuel was prepared in the same manner as in Example 37, except that rice bran was used instead of wood pellets.
  • a solid fuel was prepared in the same manner as in Example 37, except that rice husks were used instead of wood pellets.
  • a solid fuel was prepared in the same manner as in Example 37, except that barley straw was used instead of wood pellets.
  • Solid fuel was prepared in the same manner as in Example 37, except that corn cob was used instead of wood pellets.
  • Solid fuel was prepared in the same manner as in Example 37, except that sugar cane bags were used instead of wood pellets.
  • a solid fuel was prepared in the same manner as in Example 37, except that methanol residue was used instead of the wood pellets.
  • a solid fuel was prepared in the same manner as in Example 37 except that the coffee shell was used instead of the wood pellet.
  • a solid fuel was prepared in the same manner as in Example 37 except that the peanut shell was used instead of the wood pellet.
  • a solid fuel was prepared in the same manner as in Example 37, except that sunflower seeds were used instead of wood pellets.
  • a solid fuel was prepared in the same manner as in Example 37, except that sunflower seed shells were used instead of wood pellets.
  • Solid fuel was prepared in the same manner as in Example 37, except that bamboo was used instead of wood pellets.
  • Solid fuel was prepared in the same manner as in Example 37 except that 100 g of charcoal and starch were used instead of wood pellets.
  • Solid fuel was prepared in the same manner as in Example 37, except that 100 g of charcoal and starch were used instead of wood pellets.
  • Solid fuel was prepared in the same manner as in Example 37, except that 100 g of loess and starch was used instead of wood pellets.
  • Solid fuel was prepared in the same manner as in Example 37, except that 100 g of clay and starch were used instead of wood pellets.
  • a solid fuel was prepared in the same manner as in Example 37 except that a mixture of 400 g of wood pellets and 400 g of rice bran was used instead of the wood pellets.
  • a solid fuel was prepared in the same manner as in Example 37, except that a mixture of 200 g of wood pellets, 300 g of chaff and 300 g of rice bran was used instead of the wood pellets.
  • a solid fuel was prepared in the same manner as in Example 37, except that a mixture of wood pellets 200g, barley straw 200g, rice husk 200g and rice bran 200g was used instead of wood pellets.
  • a solid fuel was prepared in the same manner as in Example 37, except that a mixture of wood pellets 200g, barley straw 100g, rice hull 100g, bioethanol 100g and rice bran 200g was used instead of wood pellets.
  • a solid fuel was prepared in the same manner as in Example 37, except that a mixture of wood pellets 200g, barley straw 200g, rice husk 200g, bioethanol 100g and rice bran 200g was used instead of wood pellets.
  • a solid fuel was prepared in the same manner as in Example 37, except that wood pellets 200g, barley straw 100g, rice husk 100g, bioethanol 100g, coffee skin 100g and rice bran 200g mixture was used.
  • Solid fuel was prepared in the same manner as in Example 37 except that wood pellets 500g and rice bran 300g, rice straw 300g, rice husk 300g, barley straw 400g, corn cob 400g, sunflower seed 200g, charcoal 500g and starch 100g Was prepared.
  • rice bran 300g, rice straw 300g, rice husk 300g, barley straw 400g, corn cob 400g, sunflower seeds 200g, charcoal 500g and 100g of starch 100g was used in the same manner as in Example 37 to prepare a solid fuel.
  • a solid fuel was prepared in the same manner as in Example 37, except that a straw straw 300g, barley straw 300g, sugar cane 300g, peanut shell 300g, sunflower seeds 300g, charcoal 500g and 100g of starch instead of wood pellets.
  • a solid fuel was prepared in the same manner as in Example 37, except that a mixture of rice bran 300g, rice straw 300g, rice husk 300g, barley straw 300g, sunflower seed shell 300g, bamboo 300g, charcoal 500g and starch 100g instead of wood pellets.
  • a solid fuel was prepared in the same manner as in Example 37, except that 300g of rice bran, 300g of rice straw, 300g of sugar cane, 300g of coffee beans, 300g of sunflower seeds, 300g of bamboo, charcoal 400g, charcoal 500g, and 100g of starch were used instead of wood pellets. Prepared.
  • Wood pellets 200g, rice bran 300g, rice straw 300g, chaff 300g, barley straw 300g, coffee shell 200g, peanut shell 200g, sunflower seed 300g, bamboo 300g, charcoal 200g, charcoal 500g and 100g starch instead of wood pellets In the same manner as in Example 37, a solid fuel was prepared.
  • a solid fuel was prepared in the same manner as in Example 1 except that 300 g of wood pellets was used.
  • a solid fuel was prepared in the same manner as in Example 1 except that 900 g of wood pellets was used.
  • a solid fuel was prepared in the same manner as in Example 1 except that 1 kg of wood pellets was used.
  • the solid fuels prepared in Examples 1 to 68 were measured by using a bomb type passive calorimeter, and the calorific value was determined by calculating the kcal for 1 kg of the sample, and the results are shown in Table 1 below.
  • Example 1 Example 2
  • Example 3 Example 4
  • Example 5 Calorific Value (kcal / kg) 5,561 5,755 5,675 5,933 5,364
  • Example 6 Example 7
  • Example 8 Example 9
  • Example 10 Calorific Value (kcal / kg) 5,223 5,565 5,235 5,173 5,334
  • Example 11 Example 12
  • Example 13 Example 14
  • Example 15 Calorific Value (kcal / kg) 5,574 5,644 5,975 5,924 5,644
  • Example 16 Example 17
  • Example 18 Example 19
  • Example 20 Calorific Value (kcal / kg) 5,134 5,651 5,975 5,253 5,355
  • Example 21 Example 22
  • Example 23 Example 24
  • Example 25 Calorific Value (kcal / kg) 5,511 5,762 5,575 5,883 5,219
  • Example 26 Example 27
  • Example 28 Example 29
  • Example 30 Calorific Value (kcal / kg) 5,366 5,915 5,165 5,835 5,543
  • Example 31 Example 32

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Solid Fuels And Fuel-Associated Substances (AREA)

Abstract

Cette invention concerne un combustible solide comprenant une masse algale contenant de l'huile, et un additif pour combustible, et qui présente une excellente énergie thermique de combustion, et est ainsi capable de remplacer les combustibles d'origine fossile. Le combustible solide, selon l'invention, est doué de photosynthèse et de prolifération illimitée, et est respectueux de l'environnement tout en ayant une excellente énergie thermique par le biais d'une réutilisation des déchets agricoles, par utilisation d'une masse algale contenant de l'huile, qui peut être produite en masse en un temps court dans divers environnements, et l'additif pour combustible.
PCT/KR2015/004635 2014-05-10 2015-05-08 Combustible solide comprenant une masse algale contenant de l'huile et un additif pour combustible, et son procédé de production WO2015174692A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
KR10-2014-0056018 2014-05-10
KR1020140056018A KR101445254B1 (ko) 2014-05-10 2014-05-10 오일을 포함한 앨지매스와 연료첨가제를 포함하는 고체연료 및 이의 제조 방법

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WO2015174692A1 true WO2015174692A1 (fr) 2015-11-19

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109097134A (zh) * 2018-07-09 2018-12-28 安徽冠建新能源科技有限公司 一种提高燃烧时间的生物质粒配比及其制备工艺
CN109135781A (zh) * 2018-08-25 2019-01-04 西盟昌轩炭业有限责任公司 一种环保型机制木炭的制备方法
CN109135863A (zh) * 2018-08-06 2019-01-04 佛山领新信息科技有限公司 一种新能源燃料及其制备方法

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101605288B1 (ko) * 2015-02-23 2016-03-21 오석재 연료 펠릿
KR102571583B1 (ko) * 2023-01-02 2023-08-28 주식회사 올바른생각 커피찌꺼기를 이용한 가공품 제조 방법

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KR20090095631A (ko) * 2006-12-01 2009-09-09 노쓰 캐롤라이나 스테이트 유니버시티 바이오매스를 연료로 변환하는 방법
KR20120024631A (ko) * 2009-05-26 2012-03-14 아메리칸 펠레트 서플라이 엘엘씨 압축 바이오매스로부터의 펠렛 및 브리켓
KR20120054973A (ko) * 2010-11-22 2012-05-31 한국에너지기술연구원 2 단계 열분해에 의한 미세조류로부터의 지질 회수 방법
US20130004904A1 (en) * 2010-01-28 2013-01-03 Creative Co. Ltd. Solid fuel
KR20130085374A (ko) * 2010-05-28 2013-07-29 솔라짐, 인코포레이티드 맞춤 오일을 포함하는 식품 조성물

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KR20090095631A (ko) * 2006-12-01 2009-09-09 노쓰 캐롤라이나 스테이트 유니버시티 바이오매스를 연료로 변환하는 방법
KR20120024631A (ko) * 2009-05-26 2012-03-14 아메리칸 펠레트 서플라이 엘엘씨 압축 바이오매스로부터의 펠렛 및 브리켓
US20130004904A1 (en) * 2010-01-28 2013-01-03 Creative Co. Ltd. Solid fuel
KR20130085374A (ko) * 2010-05-28 2013-07-29 솔라짐, 인코포레이티드 맞춤 오일을 포함하는 식품 조성물
KR20120054973A (ko) * 2010-11-22 2012-05-31 한국에너지기술연구원 2 단계 열분해에 의한 미세조류로부터의 지질 회수 방법

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109097134A (zh) * 2018-07-09 2018-12-28 安徽冠建新能源科技有限公司 一种提高燃烧时间的生物质粒配比及其制备工艺
CN109135863A (zh) * 2018-08-06 2019-01-04 佛山领新信息科技有限公司 一种新能源燃料及其制备方法
CN109135781A (zh) * 2018-08-25 2019-01-04 西盟昌轩炭业有限责任公司 一种环保型机制木炭的制备方法

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