WO2015137808A1 - Improved low pressure 2-k handheld spray gun - Google Patents

Improved low pressure 2-k handheld spray gun Download PDF

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Publication number
WO2015137808A1
WO2015137808A1 PCT/NL2015/050155 NL2015050155W WO2015137808A1 WO 2015137808 A1 WO2015137808 A1 WO 2015137808A1 NL 2015050155 W NL2015050155 W NL 2015050155W WO 2015137808 A1 WO2015137808 A1 WO 2015137808A1
Authority
WO
WIPO (PCT)
Prior art keywords
fluid
nozzle
spray gun
adhesive
pressure
Prior art date
Application number
PCT/NL2015/050155
Other languages
French (fr)
Inventor
Rudolph Frank DE BLOCK
Antonius Wilhelmus Zaarbelink
Original Assignee
Saba Dinxperlo B.V.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Saba Dinxperlo B.V. filed Critical Saba Dinxperlo B.V.
Priority to CN201580020634.6A priority Critical patent/CN106232240A/en
Priority to PL15715482T priority patent/PL3116654T3/en
Priority to EP15715482.4A priority patent/EP3116654B1/en
Priority to CA2942295A priority patent/CA2942295C/en
Publication of WO2015137808A1 publication Critical patent/WO2015137808A1/en
Priority to US15/261,524 priority patent/US10384219B2/en

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05BSPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
    • B05B7/00Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas
    • B05B7/02Spray pistols; Apparatus for discharge
    • B05B7/08Spray pistols; Apparatus for discharge with separate outlet orifices, e.g. to form parallel jets, i.e. the axis of the jets being parallel, to form intersecting jets, i.e. the axis of the jets converging but not necessarily intersecting at a point
    • B05B7/0807Spray pistols; Apparatus for discharge with separate outlet orifices, e.g. to form parallel jets, i.e. the axis of the jets being parallel, to form intersecting jets, i.e. the axis of the jets converging but not necessarily intersecting at a point to form intersecting jets
    • B05B7/0846Spray pistols; Apparatus for discharge with separate outlet orifices, e.g. to form parallel jets, i.e. the axis of the jets being parallel, to form intersecting jets, i.e. the axis of the jets converging but not necessarily intersecting at a point to form intersecting jets with jets being only jets constituted by a liquid or a mixture containing a liquid
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05BSPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
    • B05B12/00Arrangements for controlling delivery; Arrangements for controlling the spray area
    • B05B12/002Manually-actuated controlling means, e.g. push buttons, levers or triggers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05BSPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
    • B05B7/00Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas
    • B05B7/02Spray pistols; Apparatus for discharge
    • B05B7/04Spray pistols; Apparatus for discharge with arrangements for mixing liquids or other fluent materials before discharge
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05BSPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
    • B05B7/00Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas
    • B05B7/02Spray pistols; Apparatus for discharge
    • B05B7/08Spray pistols; Apparatus for discharge with separate outlet orifices, e.g. to form parallel jets, i.e. the axis of the jets being parallel, to form intersecting jets, i.e. the axis of the jets converging but not necessarily intersecting at a point
    • B05B7/0807Spray pistols; Apparatus for discharge with separate outlet orifices, e.g. to form parallel jets, i.e. the axis of the jets being parallel, to form intersecting jets, i.e. the axis of the jets converging but not necessarily intersecting at a point to form intersecting jets
    • B05B7/0815Spray pistols; Apparatus for discharge with separate outlet orifices, e.g. to form parallel jets, i.e. the axis of the jets being parallel, to form intersecting jets, i.e. the axis of the jets converging but not necessarily intersecting at a point to form intersecting jets with at least one gas jet intersecting a jet constituted by a liquid or a mixture containing a liquid for controlling the shape of the latter
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05BSPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
    • B05B7/00Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas
    • B05B7/02Spray pistols; Apparatus for discharge
    • B05B7/12Spray pistols; Apparatus for discharge designed to control volume of flow, e.g. with adjustable passages
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05BSPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
    • B05B7/00Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas
    • B05B7/02Spray pistols; Apparatus for discharge
    • B05B7/12Spray pistols; Apparatus for discharge designed to control volume of flow, e.g. with adjustable passages
    • B05B7/1209Spray pistols; Apparatus for discharge designed to control volume of flow, e.g. with adjustable passages the controlling means for each liquid or other fluent material being manual and interdependent
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05BSPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
    • B05B9/00Spraying apparatus for discharge of liquids or other fluent material, without essentially mixing with gas or vapour
    • B05B9/01Spray pistols, discharge devices
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29BPREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B7/00Mixing; Kneading
    • B29B7/74Mixing; Kneading using other mixers or combinations of mixers, e.g. of dissimilar mixers ; Plant
    • B29B7/7404Mixing devices specially adapted for foamable substances
    • B29B7/7409Mixing devices specially adapted for foamable substances with supply of gas
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29BPREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B7/00Mixing; Kneading
    • B29B7/74Mixing; Kneading using other mixers or combinations of mixers, e.g. of dissimilar mixers ; Plant
    • B29B7/7438Mixing guns, i.e. hand-held mixing units having dispensing means
    • B29B7/7452Mixing guns, i.e. hand-held mixing units having dispensing means for mixing components by spraying them into each other; for mixing by intersecting sheets
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J107/00Adhesives based on natural rubber
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J109/00Adhesives based on homopolymers or copolymers of conjugated diene hydrocarbons
    • C09J109/06Copolymers with styrene
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J111/00Adhesives based on homopolymers or copolymers of chloroprene
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J123/00Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers
    • C09J123/02Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers not modified by chemical after-treatment
    • C09J123/04Homopolymers or copolymers of ethene
    • C09J123/08Copolymers of ethene
    • C09J123/0846Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
    • C09J123/0853Vinylacetate
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J125/00Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Adhesives based on derivatives of such polymers
    • C09J125/02Homopolymers or copolymers of hydrocarbons
    • C09J125/04Homopolymers or copolymers of styrene
    • C09J125/08Copolymers of styrene
    • C09J125/10Copolymers of styrene with conjugated dienes
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J131/00Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid, or of a haloformic acid; Adhesives based on derivatives of such polymers
    • C09J131/02Homopolymers or copolymers of esters of monocarboxylic acids
    • C09J131/04Homopolymers or copolymers of vinyl acetate
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J133/00Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
    • C09J133/04Homopolymers or copolymers of esters
    • C09J133/06Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C09J133/08Homopolymers or copolymers of acrylic acid esters
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J175/00Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
    • C09J175/04Polyurethanes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05BSPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
    • B05B7/00Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas
    • B05B7/24Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas with means, e.g. a container, for supplying liquid or other fluent material to a discharge device
    • B05B7/2489Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas with means, e.g. a container, for supplying liquid or other fluent material to a discharge device an atomising fluid, e.g. a gas, being supplied to the discharge device
    • B05B7/2497Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas with means, e.g. a container, for supplying liquid or other fluent material to a discharge device an atomising fluid, e.g. a gas, being supplied to the discharge device several liquids from different sources being supplied to the discharge device

Definitions

  • the present invention is in the field of low pres- sure limited overspray handheld aerosol spray gun for spray ⁇ ing a two-component adhesive, a method for spraying a two- component adhesive and a two-component adhesive obtainable by said method.
  • Airless spraying involves using pressure to force a fluid to be sprayed through a small orifice. Airless spray equipment is often operated at higher pressures than air- spray- or air assisted- spray equipment. Operating pressures of airless spray systems are typically up to 50.000 kPa (-500 bar) . Air-spray uses pressurized air to spray adhesives. Op- erating pressures are typically up to 1600 kPa (-16 bar) . In view of operating pressure, and in view of adhesives used, air-spray and airless spray methods are at least difficult to combine. Methods and products for applying a layer of adhe ⁇ sive onto a surface wherein the method comprises spraying the adhesive airlessly are known in the prior art. Likewise air pressurized products and methods are known.
  • a measure that could reduce an amount of adhesive in the air is to actively remove air borne adhesive by suc ⁇ tion/ventilation. Apart from the energy and equipment costs such may also involves heating/cooling fresh air being supplied. Furthermore, it also determines a selection of a phys ⁇ ical location of spraying to a location where active ventila- tion is provided; typically spraying can not be performed at any given location, e.g. where a surface to be sprayed is lo ⁇ cated. In other words, such is unwanted.
  • Another issue with airless systems is a phenomenon called tailoring. At the edge of a spraying pattern a relatively larger amount of adhesive is deposited. If the adhe ⁇ sive is colored, which is typically the case, such can be ob- served as a thicker or more intense colored line. A distribu ⁇ tion of adhesive is not even over the surface, e.g. in terms of amount of adhesive per unit surface, which is unwanted.
  • the adhesive is not homogeneously distributed over a surface to which the spray is applied. Typically there is much more adhesive at the cen ⁇ ter of the surface compared to the edges thereof. Also a lot of overspray, beyond the edges, is present.
  • pressurized air systems are as follows. It is noted that pressurized air itself also con- tributes considerably to costs of applying adhesive, espe ⁇ cially if more complex equipment is needed. Also, prior art methods typically make use of rather complicated equipment, especially air assisted spray equipment. Such systems are ra ⁇ ther voluminous, complex and costly.
  • the prior art equipment is typically (somewhat) dif ⁇ ficult to handle, e.g. in terms of relocating, and replacing feed stock. Also, in view of complexity, such systems are at a certain distance from a location where the adhesive is be ⁇ ing applied; inherently such involves some further risks, e.g. clogging of tubing, less control at the location of ap ⁇ plication, etc.
  • DE 33 360 53 A recites a 2-component spray gun with two spray heads, in which the main component is atomised by the airless spray method and the hardener com- ponent is atomised by the compressed-air spray method.
  • a high pressure is used to spray the two components.
  • US 4,928,884 A recites a fluid assist airless spray nozzle for spraying a plural component spray system with a nozzle plate having an airless discharge orifice located therein for spraying a first component of the plural compo ⁇ nent system as, for instance, a resin component.
  • a first flu- id discharge orifice is located on one side of the airless discharge orifice and a second fluid discharge orifice is lo ⁇ cated on the other.
  • Outboard of the first fluid discharge or ⁇ ifice is a first gas discharge orifice and outboard of the second fluid discharge orifice is a second gas discharge ori ⁇ fice.
  • the system is considered rather complicated, having various of the above risks, such as airborne particles, and typically not providing an adequate spray pattern.
  • handheld spray gun which overcomes one or more of the above disadvantages, without jeopardizing functionality and ad ⁇ vantages .
  • the present invention relates to an improved low pressure 2-K handheld spray gun according to claim 1.
  • an adhesive is provided in amount of 80-97 wt . % of a first fluid and 3-20 wt . % of a second fluid, the wt . percentage calculated on a combined first and second flu ⁇ id.
  • the first fluid and second fluid are provided through separate fluid passage ways and mixed when airborne.
  • the first and second fluids are typically present in an external container or the like.
  • an external container is on connection with the spray gun by means of a tubing or the like, which tubing is connected to the spray gun by means of a connector, such as a plug, a screw, etc.
  • the first and second fluids are sprayed through a nozzle, which nozzle is preferably removable.
  • a nozzle may be replaced in order to be in line with requirements.
  • the first and second fluid passage ways are con- trolled by a mechanism for opening and closing of the passage way of each fluid to the nozzle.
  • a trigger is provided for simultaneous control of the mechanisms; as such a person holding the spray gun can control application of the adhesive (components) by using the trigger for opening and closing.
  • a first removable nozzle tip attached to the first nozzle is provid- ed, which first nozzle tip has a slit incorporated therein.
  • the present invention provides a solution to one or more of the above mentioned problems, and in particu ⁇ lar an amount of airborne adhesive not being applied to a surface is virtually absent.
  • the present invention relates in a first aspect to a handheld spray gun according to claim 1.
  • the second nozzle is directed such that the second fluid in ⁇ timately mixes with the first fluid at a distance of 1-10 cm of the first nozzle, preferably 2-7 cm.
  • a distance may vary somewhat. The distance is preferably not too large, as mixing is than not optimal and overspray increases. A similar argument holds for a too small distance.
  • the first nozzle has an opening with a first area, preferably a circular opening
  • the second nozzle has an opening with a second area, preferably a circular opening, wherein a ratio between the first area and the second area (first ar- ea:second area) e[0.2:5], preferably e[0.33:3.5], more pref ⁇ erably e[0.45:2.5], such as e[0.66:1.5].
  • the openings are relatively small, such as 0.28-0.8 mm for the first nozzle, and 0.35-1.0 mm for the second nozzle.
  • the openings preferably have an annular form. It has also been found that the ratio of surface areas of the openings of the two nozzles is within the above mentioned ranges, despite the first fluid being provided in much larger quantities, compared to the second fluid.
  • the present handheld spray gun is capable of withstanding a first fluid pressure of 200-800 kPa (2-8 Bar) , preferably at 250-400 kPa, more preferably at 275- 350 kPa.
  • the first fluid is provided at a relatively low pressure. It has been found that, in combination with the nozzle and noz ⁇ zle tip, such a pressure provides a very good spray pattern, e.g. in terms of quantity provided per unit surface area, in terms of overspray, in terms of mixing, in terms of tailor ⁇ ing, in terms of amount of airborne particles, etc.
  • the pres ⁇ sure used is also relatively safe for employees using the present spray gun.
  • the present handheld spray gun is capable of withstanding a second fluid pressure of 10-100 kPa (0.1-1.0 Bar), preferably at 12-40 kPa, more preferably at 20-30 kPa.
  • a second fluid pressure of 10-100 kPa (0.1-1.0 Bar), preferably at 12-40 kPa, more preferably at 20-30 kPa.
  • the pressures used are surprisingly low and can be provided with e.g. a simple ring tubing for pressurized air, a container having pressurized air, etc.
  • the amount of air used is esti ⁇ mated to be about 1-10% compared to prior art air spray guns.
  • the second fluid itself is pressurized as well, comparable to the first fluid, but at a lower pressure, typically at a pressure of 15-100 kPa (0.15-1.0 Bar), prefer- ably at 20-50 kPa, more preferably at 25-35 kPa.
  • a spray pattern can be adjusted easily, such as by adjusting a pressure. Also a mixing ratio between first and second flu ⁇ id can be adjusted easily.
  • the present invention relates to a system for spraying a two-component adhesive comprising an aerosol spray gun according to any of the preceding claims,
  • (A) a means for providing an airless pressure of 200-800 kPa to the first fluid
  • (B) a means for providing an air pressure of 10-100 kPa to the second fluid.
  • the present invention relates to a method of spraying a two component adhesive comprising a first and second fluid.
  • the method comprises the steps of providing an aerosol spray gun according to any of claims 1-5 or a system according to claim 6.
  • the first fluid relates to a first component of a two component adhesive. It is preferably selected from a pol- chloroprene dispersion, polyurethane dispersion, polyacry- late dispersion, vinylacetate-ethylene dispersion, ethylene- vinylacetate dispersion, natural rubber dispersion, styrene- butadiene-styrene copolymer dispersion, styrene-butadiene rubber dispersion, and combinations thereof.
  • the first compo ⁇ nent is preferably provided at a pressure of 200-800 kPa (2-6 Bar) , preferably at 250-400 kPa, more preferably at 275-350 kPa.
  • the second fluid relates to a second component of a two component adhesive.
  • the second fluid is preferably an ac ⁇ tivator. It is preferably selected from a salt of a multiva ⁇ lent metal such as zinc, aluminum or calcium; or an acid solution, such as selected from citric acid, formic acid, ace ⁇ tic acid, lactic acid and mineral acid having a pH below 5, preferably below 4.5, most preferably below 4, and combina ⁇ tions thereof.
  • the second component is preferably provided at a pressure of 150-500 kPa (0.15-0.5 Bar), preferably at 200- 400 kPa, more preferably at 250-300 kPa.
  • a next step relates to applying the combined fluids as an adhesive to a surface.
  • the viscosi ⁇ ties of the first- and second- fluids are in the range of 0.2 mPa*s to 10 Pa*s at 25°C. It has been found that for intimate mixing, obtaining a good spray pattern, reducing overspray, etc. these viscosities suit particularly well.
  • a pressure for spraying is provided by one or more selected from: positive displacement pumps, such as double diaphragm pumps or piston pumps; pressurized systems such as pressure tanks; and, grav ⁇ ity feed feeding systems.
  • the present method is for applying >90 wt . % of adhesive as provided to a surface, preferably > 95 wt.%, such as >98 wt . % .
  • An amount of overspray (loss) and an amount of adhesive applied (yield) is measured according to DIN 13966 (September 2003), specifically part 1 thereof. If boundary conditions are optimized almost 100,0 wt.% is provided to an intended surface. As such the present method reduces overspray and provides further advantages, as men ⁇ tioned .
  • An amount of overspray (loss) and an amount of adhe ⁇ sive applied (yield) is measured according to DIN 13966, spe ⁇ cifically part 1 thereof.
  • the present invention relates to a use of the present spray gun or system for one or more of limiting use of air by more than 50%, limiting overspray to less than 10 wt.%, improving mixing of first and second fluid to more than 90%, improving homogeneity of a sprayed layer to more than 90%, enlarging a width of a spray pattern by more than 20%, limiting an amount of adhesive per unit sprayed area to less than 80%, and limiting tailing to less than 10%.
  • the present invention relates to an adhesive layer, such as obtainable by a method according to the invention, amongst others having an improved homogene ⁇ ity to more than 90%.
  • Figure 1 relates to a spray gun.
  • Figure 2 relates to a spray gun add on.
  • Figure 1 relates to a spray gun 100.
  • various elements of an example of the present spray gun can be seen.
  • an input regulator for air 20 is shown.
  • a handle 60 for opening and closing is provided.
  • an opening and closing mechanism 30 for air and a material needle 40 for adhesive is shown.
  • an air hose to activator switch 50 is shown. Fur- ther the elements 1-5 of present claim 1 have been identified in the figure.
  • Figures 2a-c relate to a spray gun add on 95.
  • the add-on is for providing air pressure to a second component of the adhe ⁇ sive to be applied.
  • Fig. 2a shows the assembled activator switch, whereas fig. 2b. shows construction of the switch.
  • Fig. 3c shows a worked open version of the add on 95. Further the elements 1-7 of present claim 1 have been identified in the figure.

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Nozzles (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)

Abstract

The present invention is in the field of low pressure limited overspray handheld aerosol spray gun for spraying a two-component adhesive, a method for spraying a two-component adhesive and a two-component adhesive obtainable by said method. In manufacturing of larger objects, such as matrasses and furniture, adhesives are often applied to fix parts of the large object together. Most adhesives are applied using either air-spray equipment or air-assisted spray equipment.

Description

Title Improved low pressure 2-K handheld spray gun FIELD OF THE INVENTION
The present invention is in the field of low pres- sure limited overspray handheld aerosol spray gun for spray¬ ing a two-component adhesive, a method for spraying a two- component adhesive and a two-component adhesive obtainable by said method.
BACKGROUND OF THE INVENTION
In manufacturing of larger objects, such as matrasses and furniture, adhesives are often applied to fix parts of the large object together. Most adhesives are applied using either air-spray equipment or air-assisted spray equipment.
Airless spraying involves using pressure to force a fluid to be sprayed through a small orifice. Airless spray equipment is often operated at higher pressures than air- spray- or air assisted- spray equipment. Operating pressures of airless spray systems are typically up to 50.000 kPa (-500 bar) . Air-spray uses pressurized air to spray adhesives. Op- erating pressures are typically up to 1600 kPa (-16 bar) . In view of operating pressure, and in view of adhesives used, air-spray and airless spray methods are at least difficult to combine. Methods and products for applying a layer of adhe¬ sive onto a surface wherein the method comprises spraying the adhesive airlessly are known in the prior art. Likewise air pressurized products and methods are known.
Prior art methods and spray guns, and especially air-assisted spray equipment, suffer from a phenomenon called overspray. It is noted that spraying inherently relates to having an adhesive to be air borne. Under ideal circumstanc¬ es, using e.g. a dedicated and sophisticated fully automated equipment, which may have one spray gun or a series of paral¬ lel spray guns, at a fixed distance from a surface to be sprayed an amount of overspray may be limited to less than about 10% of a total amount of adhesive applied. As the sprayed material relates to an adhesive an end result is that eventually all items close by and typically a surrounding en¬ vironment is covered with a layer of adhesive. More serious is that in view of labor conditions employees are exposed to air-borne adhesives. Of course the overspray is also a waste of materials per se.
A measure that could reduce an amount of adhesive in the air is to actively remove air borne adhesive by suc¬ tion/ventilation. Apart from the energy and equipment costs such may also involves heating/cooling fresh air being supplied. Furthermore, it also determines a selection of a phys¬ ical location of spraying to a location where active ventila- tion is provided; typically spraying can not be performed at any given location, e.g. where a surface to be sprayed is lo¬ cated. In other words, such is unwanted.
It is noted when the spray gun is handheld the situ¬ ation is much worse, especially in terms of amount of over- spray. Under ideal circumstances, e.g. a fixed distance be¬ tween the spray gun and object to be sprayed, a fixed pres¬ sure, etc. less than 20% overspray (in relation to a total amount applied) is obtainable. In practice more than 30% of the amount applied is over sprayed, and typically more than 40%.
Another issue with airless systems is a phenomenon called tailoring. At the edge of a spraying pattern a relatively larger amount of adhesive is deposited. If the adhe¬ sive is colored, which is typically the case, such can be ob- served as a thicker or more intense colored line. A distribu¬ tion of adhesive is not even over the surface, e.g. in terms of amount of adhesive per unit surface, which is unwanted.
In case of an air-spray system the adhesive is not homogeneously distributed over a surface to which the spray is applied. Typically there is much more adhesive at the cen¬ ter of the surface compared to the edges thereof. Also a lot of overspray, beyond the edges, is present.
For two-component adhesives good mixing of the two components may be an issue as well. Mixing does not only re- late to intimately combining the two components, but also to securing a required ratio of components in the mixed adhe¬ sive. Typically one component is provided in a relatively large amount and the other in a relatively small amount. Such is even more complex if a relatively large area needs to be covered with an adhesive.
Other disadvantages for pressurized air systems are as follows. It is noted that pressurized air itself also con- tributes considerably to costs of applying adhesive, espe¬ cially if more complex equipment is needed. Also, prior art methods typically make use of rather complicated equipment, especially air assisted spray equipment. Such systems are ra¬ ther voluminous, complex and costly.
As an amount of adhesive to be applied at a given moment in prior art systems is typically much smaller than a content of a container there is a risk that the component may clog, block a tube, etc. Such requires cleaning of the equip¬ ment .
The prior art equipment is typically (somewhat) dif¬ ficult to handle, e.g. in terms of relocating, and replacing feed stock. Also, in view of complexity, such systems are at a certain distance from a location where the adhesive is be¬ ing applied; inherently such involves some further risks, e.g. clogging of tubing, less control at the location of ap¬ plication, etc.
In an example DE 33 360 53 A recites a 2-component spray gun with two spray heads, in which the main component is atomised by the airless spray method and the hardener com- ponent is atomised by the compressed-air spray method. A high pressure is used to spray the two components. As a result airborne particles are formed which spread throughout a given location of application and a spray pattern is not well controlled .
US 4,928,884 A recites a fluid assist airless spray nozzle for spraying a plural component spray system with a nozzle plate having an airless discharge orifice located therein for spraying a first component of the plural compo¬ nent system as, for instance, a resin component. A first flu- id discharge orifice is located on one side of the airless discharge orifice and a second fluid discharge orifice is lo¬ cated on the other. Outboard of the first fluid discharge or¬ ifice is a first gas discharge orifice and outboard of the second fluid discharge orifice is a second gas discharge ori¬ fice. The system is considered rather complicated, having various of the above risks, such as airborne particles, and typically not providing an adequate spray pattern.
In view of the disadvantages of the prior art sys¬ tems there is a need for an improved low pressure 2-K
handheld spray gun which overcomes one or more of the above disadvantages, without jeopardizing functionality and ad¬ vantages .
SUMMARY OF THE INVENTION
The present invention relates to an improved low pressure 2-K handheld spray gun according to claim 1.
Therein an adhesive is provided in amount of 80-97 wt . % of a first fluid and 3-20 wt . % of a second fluid, the wt . percentage calculated on a combined first and second flu¬ id. The first fluid and second fluid are provided through separate fluid passage ways and mixed when airborne. The first and second fluids are typically present in an external container or the like. Typically an external container is on connection with the spray gun by means of a tubing or the like, which tubing is connected to the spray gun by means of a connector, such as a plug, a screw, etc.
The first and second fluids are sprayed through a nozzle, which nozzle is preferably removable. For instance in view of an adhesive provided, and amount of adhesive provid¬ ed, a ratio of first and second fluid provided, a spray pat¬ tern to be provided, etc. a nozzle may be replaced in order to be in line with requirements.
The first and second fluid passage ways are con- trolled by a mechanism for opening and closing of the passage way of each fluid to the nozzle. A trigger is provided for simultaneous control of the mechanisms; as such a person holding the spray gun can control application of the adhesive (components) by using the trigger for opening and closing.
It has been found that using airless pressure can not solve all of the above problems. Especially mixing of components and spray pattern are difficult to control. Sur¬ prisingly if only the second component is sprayed using a re- duced air pressure, in combination with an airless spraying of the first component, full control is achieved. Thereto a third fluid passage way for providing air is provided. Also a chamber wherein the second and third passage ways enter and from which access to the second nozzle is provided. The cham¬ ber preferably has a cross section which is 0.9-10 times a cross section of the second (or third) passage way.
In order to further optimize a spray pattern a first removable nozzle tip attached to the first nozzle is provid- ed, which first nozzle tip has a slit incorporated therein.
Thereby the present invention provides a solution to one or more of the above mentioned problems, and in particu¬ lar an amount of airborne adhesive not being applied to a surface is virtually absent.
Advantages of the present description are detailed throughout the description.
DETAILED DESCRIPTION OF THE INVENTION
The present invention relates in a first aspect to a handheld spray gun according to claim 1.
In an example of the present handheld spray gun the second nozzle is directed such that the second fluid in¬ timately mixes with the first fluid at a distance of 1-10 cm of the first nozzle, preferably 2-7 cm. Is has been found that in order to reduce overspray and have a good mixing the first and second fluid mix at a certain distance from the top. Depending on a pressure applied, and to a ratio of the pressures, as well as on the nozzles provided, a distance may vary somewhat. The distance is preferably not too large, as mixing is than not optimal and overspray increases. A similar argument holds for a too small distance.
In an example of the present handheld spray gun the first nozzle has an opening with a first area, preferably a circular opening, wherein the second nozzle has an opening with a second area, preferably a circular opening, wherein a ratio between the first area and the second area (first ar- ea:second area) e[0.2:5], preferably e[0.33:3.5], more pref¬ erably e[0.45:2.5], such as e[0.66:1.5]. It has been found that the openings are relatively small, such as 0.28-0.8 mm for the first nozzle, and 0.35-1.0 mm for the second nozzle. The openings preferably have an annular form. It has also been found that the ratio of surface areas of the openings of the two nozzles is within the above mentioned ranges, despite the first fluid being provided in much larger quantities, compared to the second fluid.
In an example of the present handheld spray gun is capable of withstanding a first fluid pressure of 200-800 kPa (2-8 Bar) , preferably at 250-400 kPa, more preferably at 275- 350 kPa. In other words, compared to other airless systems, the first fluid is provided at a relatively low pressure. It has been found that, in combination with the nozzle and noz¬ zle tip, such a pressure provides a very good spray pattern, e.g. in terms of quantity provided per unit surface area, in terms of overspray, in terms of mixing, in terms of tailor¬ ing, in terms of amount of airborne particles, etc. The pres¬ sure used is also relatively safe for employees using the present spray gun.
In an example of the present handheld spray gun is capable of withstanding a second fluid pressure of 10-100 kPa (0.1-1.0 Bar), preferably at 12-40 kPa, more preferably at 20-30 kPa. Despite the pressure being provided with air, the pressures used are surprisingly low and can be provided with e.g. a simple ring tubing for pressurized air, a container having pressurized air, etc. The amount of air used is esti¬ mated to be about 1-10% compared to prior art air spray guns. It is noted that the second fluid itself is pressurized as well, comparable to the first fluid, but at a lower pressure, typically at a pressure of 15-100 kPa (0.15-1.0 Bar), prefer- ably at 20-50 kPa, more preferably at 25-35 kPa.
It is noted that with the present adaptable nozzles a spray pattern can be adjusted easily, such as by adjusting a pressure. Also a mixing ratio between first and second flu¬ id can be adjusted easily.
In a second aspect the present invention relates to a system for spraying a two-component adhesive comprising an aerosol spray gun according to any of the preceding claims,
(A) a means for providing an airless pressure of 200-800 kPa to the first fluid, and
(B) a means for providing an air pressure of 10-100 kPa to the second fluid.
In a third aspect the present invention relates to a method of spraying a two component adhesive comprising a first and second fluid. The method comprises the steps of providing an aerosol spray gun according to any of claims 1-5 or a system according to claim 6.
The first fluid relates to a first component of a two component adhesive. It is preferably selected from a pol- ychloroprene dispersion, polyurethane dispersion, polyacry- late dispersion, vinylacetate-ethylene dispersion, ethylene- vinylacetate dispersion, natural rubber dispersion, styrene- butadiene-styrene copolymer dispersion, styrene-butadiene rubber dispersion, and combinations thereof. The first compo¬ nent is preferably provided at a pressure of 200-800 kPa (2-6 Bar) , preferably at 250-400 kPa, more preferably at 275-350 kPa.
The second fluid relates to a second component of a two component adhesive. The second fluid is preferably an ac¬ tivator. It is preferably selected from a salt of a multiva¬ lent metal such as zinc, aluminum or calcium; or an acid solution, such as selected from citric acid, formic acid, ace¬ tic acid, lactic acid and mineral acid having a pH below 5, preferably below 4.5, most preferably below 4, and combina¬ tions thereof. The second component is preferably provided at a pressure of 150-500 kPa (0.15-0.5 Bar), preferably at 200- 400 kPa, more preferably at 250-300 kPa.
A next step relates to applying the combined fluids as an adhesive to a surface.
In an example of the present method the viscosi¬ ties of the first- and second- fluids are in the range of 0.2 mPa*s to 10 Pa*s at 25°C. It has been found that for intimate mixing, obtaining a good spray pattern, reducing overspray, etc. these viscosities suit particularly well.
In an example of the present method a pressure for spraying is provided by one or more selected from: positive displacement pumps, such as double diaphragm pumps or piston pumps; pressurized systems such as pressure tanks; and, grav¬ ity feed feeding systems.
In an example the present method is for applying >90 wt . % of adhesive as provided to a surface, preferably > 95 wt.%, such as >98 wt . % . An amount of overspray (loss) and an amount of adhesive applied (yield) is measured according to DIN 13966 (September 2003), specifically part 1 thereof. If boundary conditions are optimized almost 100,0 wt.% is provided to an intended surface. As such the present method reduces overspray and provides further advantages, as men¬ tioned .
An amount of overspray (loss) and an amount of adhe¬ sive applied (yield) is measured according to DIN 13966, spe¬ cifically part 1 thereof.
In a fourth aspect the present invention relates to a use of the present spray gun or system for one or more of limiting use of air by more than 50%, limiting overspray to less than 10 wt.%, improving mixing of first and second fluid to more than 90%, improving homogeneity of a sprayed layer to more than 90%, enlarging a width of a spray pattern by more than 20%, limiting an amount of adhesive per unit sprayed area to less than 80%, and limiting tailing to less than 10%.
In a fifth aspect the present invention relates to an adhesive layer, such as obtainable by a method according to the invention, amongst others having an improved homogene¬ ity to more than 90%.
The invention is further detailed by the accompanying figures and examples, which are exemplary and explanatory of nature and are not limiting the scope of the invention. To the person skilled in the art it may be clear that many variants, being obvious or not, may be conceivable falling within the scope of protection, defined by the present claims .
SUMMARY OF FIGURES
Figure 1 relates to a spray gun.
Figure 2 relates to a spray gun add on. DE TAILED DESCRIPTION OF FIGURES
10 Main Body of spray gun
20 Air input regulator
30 Opening and closing mechanism
40 Material needle
70 Nipple
80 Airless nozzle
81 Slit
90 Swivel
95 Spray gun add on
1 first and second connection
2 first nozzle and second nozzle
3 separate fluid passage ways
4 first and second mechanism for opening and closing
5 trigger for simultaneous control of the mechanisms
6 third fluid passage way
7 chamber
Figure 1 relates to a spray gun 100. Therein various elements of an example of the present spray gun can be seen. For instance an input regulator for air 20 is shown. Also a handle 60 for opening and closing is provided. Part 10 re¬ lates to a main body. Further an opening and closing mechanism 30 for air and a material needle 40 for adhesive is shown. Also an air hose to activator switch 50 is shown. Fur- ther the elements 1-5 of present claim 1 have been identified in the figure.
Figures 2a-c relate to a spray gun add on 95. The add-on is for providing air pressure to a second component of the adhe¬ sive to be applied. Fig. 2a shows the assembled activator switch, whereas fig. 2b. shows construction of the switch.
Fig. 3c shows a worked open version of the add on 95. Further the elements 1-7 of present claim 1 have been identified in the figure.
It should be appreciated that for commercial appli- cation it may be preferable to use one or more variations of the present system, which would similar be to the ones dis¬ closed in the present application and are within the spirit of the invention.

Claims

1. Low pressure limited overspray handheld aerosol spray gun for spraying a two-component adhesive comprising 80-97 wt . % of a first fluid and 3-20 wt . % of a second fluid, the wt . percentage calculated on a combined first and second fluid, comprising
(a) a first and second connection (1) for supply of the first and second fluid, respectively,
(b) a first nozzle and a second nozzle (2),
(c) a separate fluid passage (3) way for the first and second fluid between the connection and nozzle, respectively,
(d) a first and second mechanism (4) for opening and closing of the passage way of each fluid to the nozzle,
(e) a trigger (5) for simultaneous control of the mechanisms,
(f) a third fluid passage way (6) for providing air,
(g) a chamber (7) wherein the second and third passage ways enter and from which access to the second nozzle is pro¬ vided, and
(h) a first removable nozzle tip attached to the first noz¬ zle, characterized in that the first nozzle tip has a slit (81) incorporated therein.
2. Aerosol gun according to claim 1, wherein the second nozzle is directed such that the second fluid inti¬ mately mixes with the first fluid at a distance of 1-10 cm of the first nozzle.
3. Aerosol spray gun according to any of the preced¬ ing claims, wherein the first nozzle has an opening with a first area, wherein the second nozzle has an opening with a second area, wherein a ratio between the first area and the second area (first area:second area) e [0.2:5] .
4. Aerosol spray gun according to any of the preced¬ ing claims, capable of withstanding a first fluid pressure of 200-800 kPa (2-8 Bar) , and
capable of withstanding a second fluid pressure of 12-100 kPa (0.12-1.0 Bar) .
5. System for spraying a two-component adhesive comprising an aerosol spray gun according to any of the preced- ing claims,
(A) a means for providing an airless pressure of 200-800 kPa to the first fluid, and
(B) a means for providing an air pressure of 10-100 kPa to the second fluid.
6. Method of spraying a two component adhesive com¬ prising a first and second fluid comprising the steps of
providing an aerosol spray gun according to any of claims 1-4 or a system according to claim 5,
providing a first fluid selected from a polychloro- prene dispersion, polyurethane dispersion, polyacrylate dis¬ persion, vinylacetate-ethylene dispersion, ethylene- vinylacetate dispersion, natural rubber dispersion, styrene- butadiene-styrene copolymer dispersion, styrene-butadiene rubber dispersion, and combinations thereof, at a pressure of 200-800 kPa (2-8 Bar) ,
providing a second fluid which is an activator, and combinations thereof, at a pressure of 15-50 kPa (0.15-0.5 Bar) , and
applying the combined fluids as an adhesive to a surface .
7. Method according to claim 6, wherein the viscosities of the first- and second- fluids are in the range of 0.2 mPa*s to 10 Pa*s at 25°C.
8. Method according to claim 6 or 7, wherein pressure for spraying is provided by one or more selected from: positive displacement pumps, pressurized systems, and gravity feed feeding systems.
9. Method according to any of claims 6-8, for apply- ing >90 wt . % of adhesive as provided to a surface.
10. Use of an aerosol spray gun according to any of claims 1-4 or a system according to claim 5, for one or more of limiting use of air by more than 50%, limiting overspray to less than 10 wt.%, improving mixing of first and second fluid to more than 90%, improving homogeneity of a sprayed layer to more than 90%, enlarging a width of a spray pattern by more than 20%, limiting an amount of adhesive per unit sprayed area to less than 80%, and limiting tailing to less than 10%.
11. An adhesive layer obtained by a method according to any of claims 6-10, having a > 95% reduced overspray and an improved homogeneity to more than 90%.
PCT/NL2015/050155 2014-03-12 2015-03-12 Improved low pressure 2-k handheld spray gun WO2015137808A1 (en)

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PL15715482T PL3116654T3 (en) 2014-03-12 2015-03-12 Improved low pressure two-component handheld spray gun
EP15715482.4A EP3116654B1 (en) 2014-03-12 2015-03-12 Improved low pressure two-component handheld spray gun
CA2942295A CA2942295C (en) 2014-03-12 2015-03-12 Improved low pressure 2-k handheld spray gun
US15/261,524 US10384219B2 (en) 2014-03-12 2016-09-09 Low pressure 2-K handheld spray gun

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US9821332B2 (en) 2014-07-31 2017-11-21 Steven E. Adams Two component airless adhesive spray gun and method of use
US10155887B2 (en) 2015-04-21 2018-12-18 Worthen Industries Two component sprayable adhesive additive and method of use
US10384219B2 (en) 2014-03-12 2019-08-20 Strongbond B.V. Low pressure 2-K handheld spray gun
EP3628695A1 (en) 2018-09-27 2020-04-01 Covestro Deutschland AG Dispersion adhesives
EP3628711A1 (en) 2018-09-27 2020-04-01 Covestro Deutschland AG Dispersion adhesives
EP3789448A1 (en) 2019-09-04 2021-03-10 Covestro Deutschland AG Dispersion adhesives
EP3835334A1 (en) 2019-12-10 2021-06-16 Covestro Deutschland AG Use of dispersion adhesives for foam adhesion
US11059062B2 (en) 2014-02-19 2021-07-13 Worthen Industries Airless adhesive spray gun and method of use
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Publication number Priority date Publication date Assignee Title
US11059062B2 (en) 2014-02-19 2021-07-13 Worthen Industries Airless adhesive spray gun and method of use
US10384219B2 (en) 2014-03-12 2019-08-20 Strongbond B.V. Low pressure 2-K handheld spray gun
US9821332B2 (en) 2014-07-31 2017-11-21 Steven E. Adams Two component airless adhesive spray gun and method of use
US10040079B2 (en) 2014-07-31 2018-08-07 Steven E. Adams Two component airless adhesive spray gun and method of use
US10155887B2 (en) 2015-04-21 2018-12-18 Worthen Industries Two component sprayable adhesive additive and method of use
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EP3628695A1 (en) 2018-09-27 2020-04-01 Covestro Deutschland AG Dispersion adhesives
EP3789448A1 (en) 2019-09-04 2021-03-10 Covestro Deutschland AG Dispersion adhesives
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EP3835334A1 (en) 2019-12-10 2021-06-16 Covestro Deutschland AG Use of dispersion adhesives for foam adhesion
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WO2022157075A1 (en) 2021-01-19 2022-07-28 Covestro Deutschland Ag Storage-stable 1k spray adhesives based on polyurethane dispersions

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CA2942295A1 (en) 2015-09-17
EP3116654A1 (en) 2017-01-18
US10384219B2 (en) 2019-08-20
EP3116654B1 (en) 2019-10-30
CA2942295C (en) 2020-03-24
NL2012409A (en) 2015-11-19
PL3116654T3 (en) 2020-05-18
NL2012409B1 (en) 2015-11-26
CN106232240A (en) 2016-12-14
US20160375450A1 (en) 2016-12-29

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