WO2015135424A1 - Composition pesticide et procédé de lutte contre les organismes nuisibles - Google Patents

Composition pesticide et procédé de lutte contre les organismes nuisibles Download PDF

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Publication number
WO2015135424A1
WO2015135424A1 PCT/CN2015/073294 CN2015073294W WO2015135424A1 WO 2015135424 A1 WO2015135424 A1 WO 2015135424A1 CN 2015073294 W CN2015073294 W CN 2015073294W WO 2015135424 A1 WO2015135424 A1 WO 2015135424A1
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Prior art keywords
active ingredient
cyhalothrin
pesticidal composition
pest
plant
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PCT/CN2015/073294
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English (en)
Chinese (zh)
Inventor
李成应
布里斯托詹姆斯.T
罗昌炎
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江苏龙灯化学有限公司
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Publication of WO2015135424A1 publication Critical patent/WO2015135424A1/fr

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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/54—1,3-Diazines; Hydrogenated 1,3-diazines
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests

Definitions

  • the present invention relates to a pesticidal composition comprising flufenicol and lambda-cyhalothrin; and more particularly to a method of controlling pests.
  • Chemical control is an important means of preventing and controlling pests in agriculture. However, at present, it is sometimes impossible to effectively prevent the cause due to poor effects such as pests, survival characteristics, living environment, and the like.
  • pests such as Lepidoptera, Coleoptera, Diptera, Homoptera, Hemiptera, Hymenoptera, Thysanoptera, Arachnida, and Nematodes
  • conventional chemicals are used for prevention and control. It has become increasingly difficult. Therefore, in order to effectively prevent pests that cannot be prevented or prevented from being difficult, a new means and method are sought.
  • Hummer whitefly, aphid, scale insect, cotton red bollworm, cotton bollworm, cabbage caterpillar, rapeseed meal, rapeseed, red spider, bridgeworm, cotton blind, tea mites, tea caterpillar, tea orange Pests such as rice, wheat, cotton, citrus leaf moth Pests. If the corresponding measures are not taken for the pests, it will affect the growth of the crops. Insecticides are mainly used to control agricultural pests and municipal hygiene pests.
  • Flumazepam is developed by the Japanese Pesticide Company and belongs to a class of new quinazoline (m-diazabenzene) insecticides. Flumazepam is generally applied as a water-dispersible granule. Its mechanism of action is to stop the pests from feeding and starvation, thereby preventing plant tissues from suffering more damage and limiting the spread of some important diseases. At present, it is mainly used to control whiteflies, mites and scale insects on vegetables, fruit trees and tea leaves.
  • Lambda-Cyhalothrin chemical name: 3-(2-chloro-3,3,3-trifluoropropenyl) -2,2-Dimethylcyclopropanecarboxylic acid ⁇ -cyano-3-phenoxybenzyl ester, the molecular structure of which is:
  • Lacy-cyhalothrin is a pyrethroid insecticide and acaricide; it is mainly caused by contact and stomach toxicity; the mechanism of action is to inhibit the transmission of insect axons, and to avoid, knock down and poison the insects.
  • cotton bollworm and cotton bollworm can also be used to control a variety of surface and public health pests.
  • a typical need in the field of pest control is the need to reduce the dose rate of the active ingredient and to reduce or avoid adverse environmental or toxicological effects while still allowing effective pest control.
  • a pest control agent that combines knockdown activity and prolonged control time, ie, rapid action and long-acting action.
  • the object of the present invention is to solve the above technical problems and to provide a pesticidal composition which comprises fluorine
  • a pesticidal composition which comprises fluorine
  • the combination of praziquan and lambda-cyhalothrin makes the obtained composition have a gain effect on the control effect, and expands the insecticidal spectrum, improves the rapid action and long-acting effect of pest control, and delays the drug resistance. produce.
  • a pesticidal composition including
  • the first active ingredient flufenicol
  • Second active ingredient lambda-cyhalothrin
  • the first active ingredient fipronil and the second active ingredient cyhalothrin are in a ratio of 1:100-100:1 by weight.
  • the first active ingredient fipronil and the second active ingredient cyhalothrin are 1:50 to 50:1 by weight.
  • the first active ingredient fipronil and the second active ingredient cyhalothrin are 1:25-25:1 by weight.
  • the first active ingredient flufenicol and the second active ingredient cyhalothrin are 1:10 to 10:1 by weight.
  • a pesticidal composition comprising a first active ingredient, flubenzuron, and a second active ingredient, cyhalothrin, said first active ingredient flufenicol and a second active ingredient, cyhalothrin
  • the total weight is from 5% to 90% by weight of the composition.
  • a pesticidal composition comprising a first active ingredient, flubenzuron, and a second active ingredient, cyhalothrin, the first active ingredient flufenicol and a second active ingredient, cyhalothrin
  • the composition comprises from 10% to 80% by weight.
  • a pesticidal composition comprising a first active ingredient, flubenzuron and a second active ingredient, cyhalothrin, a total of the first active ingredient flufenicol and a second active ingredient, cyhalothrin
  • the composition comprises from 20% to 60% by weight.
  • the pesticidal composition according to the present invention further comprises a surfactant and/or a extender.
  • the pesticidal composition of the present invention can be formulated into any dosage form that is agriculturally acceptable.
  • the insecticidal composition is in the form of an emulsifiable concentrate, a suspending agent, a seed treatment agent, a water-dispersible granule, a wettable powder, a suspoemulsion, an aerosol, an aqueous emulsion, a microcapsule suspension, Microcapsule suspension-suspension, ultra-low volume liquid, microemulsion.
  • the present invention provides a pesticidal composition of the present invention for use in the prevention or control of pests. use.
  • the insecticidal composition is used for controlling Bemisia tabaci, Thrips tabaci, rice planthopper, beet armyworm, yellow stripe, scale insect, cotton bollworm, cotton bollworm, cabbage caterpillar, cabbage tube , rapeseed, spider mites, bridge worms, cotton blind mites, tea mites, tea caterpillars, tea orange mites, leaf mites, citrus leaf moth, citrus cotton mites, citrus leaf mites, citrus leaf miner, rust mites, peach small Carnivorous insects and pears.
  • the present invention provides a method for preventing or controlling a pest, which comprises applying the pesticidal composition of the present invention to a target useful plant, a target pest or an environment thereof, and a propagation material of the target useful plant.
  • the plant propagation material is seedlings, rhizomes, seedlings, cuttings or seeds.
  • a method for protecting crops from harmful organisms comprising cropping a pesticidal composition comprising a first active ingredient, flufenicol and a second active ingredient, with a target useful plant, a target pest or an environment thereof, and a target useful plant Breeding material contact.
  • a method for protecting crops against pest infestation comprises separately, sequentially or simultaneously administering a first active ingredient, flufenicol, and a second active ingredient, cyhalothrin.
  • each of the first active ingredient flufenicol and the second active ingredient cyhalothrin is in the form of a formulated composition.
  • a method of protecting a plant seed comprising contacting the seed with an effective amount of the pesticidal composition of the present invention prior to sowing and/or after germination.
  • a seed treated with the pesticidal composition of the present invention is
  • the present inventors have found that the combination of the first active ingredient flufenicol and the second active ingredient, cyhalothrin, not only provides an additive effect on the insecticidal spectrum, but also achieves a surprising synergistic effect.
  • insecticidal effect means that the insecticidal effect of the active ingredient combination of the present invention is greater than the sum of the effects of the respective active ingredients, or that the effect is superadditive.
  • the present invention provides an insecticidal composition
  • a first active ingredient fipronil
  • a second active ingredient lambda cyhalothrin.
  • the present invention provides a pesticidal composition, wherein the first active ingredient fipronil and the second active ingredient lambda-cyhalothrin have a weight ratio of 1:100-100:1, preferably 1:50-50: 1, still more preferably 1:25-25:1, more preferably 1:10-10:1.
  • the total amount of active ingredient in the compositions of the invention can be selected based on the particular factors to achieve the desired effect.
  • the factors are, for example, a dosage form, a subject to be administered, an administration method, and the like.
  • the first active ingredient flufenicol and the second active ingredient lambda cyhalothrin together comprise from 5% to 90%, preferably from 10% to 80%, more preferably from 20% to 60% by weight of the composition.
  • compositions of the present invention may optionally comprise an agronomically acceptable surfactant or extender.
  • the term "filler” refers to a natural or synthetic organic or inorganic compound which may be combined or combined with the active ingredient to make it easier to apply to a subject, such as a plant, crop or grass. Therefore, the filler is preferably inert and at least agriculturally acceptable.
  • the filler may be a solid or a liquid.
  • Suitable solid carriers are: for example, vegetable powders (eg soy flour, starch, cereal flour, wood flour, bark flour, sawdust, walnut shell flour, bran, cellulose powder, coconut shell, corn cob and tobacco stem) Granules, residues after extracting plant extracts, etc.), clays (such as kaolin, bentonite, acid china clay, etc.), talc.
  • Silica such as diatomaceous earth, silica sand, mica, hydrous silicic acid, calcium silicate), activated carbon, natural minerals (pumice, attapulgite and zeolite), fired diatomaceous earth, sand, plastic media, etc.
  • inorganic mineral powders such as potassium chloride, calcium carbonate, and calcium phosphate
  • chemical fertilizers such as ammonium sulfate, ammonium phosphate, urea, and green ammonium, and soil fertilizers.
  • the substances may be used singly or in combination of two or more.
  • Suitable liquid carriers can be selected from the group consisting of water, alcohols (eg methanol, ethanol, isopropanol, butanol, ethylene glycol, etc.), ketones (eg acetone, methyl ethyl ketone, diisobutyl) Ketones, cyclohexanone, etc.), ethers (such as diethyl ether, dioxane, methylcellulose, tetrahydrofuran, etc.), aliphatic hydrocarbons (such as kerosene, mineral oil, etc.), aromatic hydrocarbons (for example) Benzene, toluene, xylene, mineral spirits, alkylnaphthalenes, chlorinated aromatic hydrocarbons, chlorinated aliphatic hydrocarbons, chlorobenzene, etc.), halogenated hydrocarbons, amides, sulfones, dimethyl sulfoxide, minerals and vegetable oils, Animal oil, etc.
  • alcohols e
  • compositions of the present invention may also comprise additional additional components such as surfactants.
  • Suitable surfactants are emulsifiers, dispersants or wetting agents having ionic or nonionic properties, or mixtures of these surfactants.
  • Suitable of these surfactants are fatty alcohol polyoxyethylene ethers, polyoxyethylene alkyl aryl ethers, polyoxyethylene higher fatty acid esters, polyoxyethylene alcohol or phenol phosphates, fatty acid esters of polyhydric alcohols, and alkane Sodium aryl sulfonate, naphthalene sulfonate polymer, lignosulfonate, polymeric comb-shaped branched copolymer, butyl naphthalene sulfonate, alkyl aryl sulfonate, sodium alkyl sulfosuccinate , polyglycerides such as fats and oils, fatty alcohols and ethylene oxide condensates, alkyl taurate salts
  • Suitable oligosaccharides or polymers are for example based on the individual ethylene monomers, acrylic acid, polyoxyethylene or polyoxypropylene or their combination with, for example, (poly)alcohols or (poly)amines.
  • a surfactant When one of the active compounds and/or one of the inert carriers is insoluble in water and when applied in water, a surfactant must be present. The proportion of surfactant is from 5% to 40% by weight of the composition of the invention.
  • the active compound can be combined with any solid or liquid additive conventionally used for formulation purposes.
  • the preparation of the present invention can be carried out by known means for at least one of the active ingredient and the following Mixing: solvent or diluent, emulsifier, dispersant, and / or binder or fixative, wetting agent, water repellent, if necessary, can also contain drier and colorant, stabilizer, pigment, defoaming Agents, preservatives, thickeners, water and other processing aids.
  • compositions of the present invention may be used as such or may be used in the form of their formulations or in the form in which they are prepared, depending on their respective physical and/or chemical properties.
  • An example of a dosage form for a premix composition is:
  • WP wettable powder
  • EW emulsion, water emulsion
  • Examples of dosage forms suitable for tank mix compositions are solutions, diluted emulsions, suspensions or mixtures and powders thereof.
  • the tank mix composition is one or more premix compositions containing different pesticides, and optionally further auxiliaries, diluted with a solvent such as water.
  • compositions of the present invention include not only ready-to-use compositions that can be applied to plants or seeds by suitable means, but also commercially available concentrates that must be diluted with water prior to administration.
  • compositions of the present invention may also be administered in combination with other active ingredients such as fungicides, bactericides, attractants, insecticides, acaricides, nematicides, growth regulators, herbicides, Safety agents, fertilizers or chemical pheromones.
  • active ingredients such as fungicides, bactericides, attractants, insecticides, acaricides, nematicides, growth regulators, herbicides, Safety agents, fertilizers or chemical pheromones.
  • the insecticidal composition of the invention has good plant compatibility and favorable constant temperature animal toxicity, and is suitable for controlling pests encountered in agriculture, forestry, storage products and materials, and health fields, especially insects and aphids. . They are active against normally sensitive and resistant species and are active for all or a single developmental stage.
  • Pests refers to any organism that can cause damage to the normal state of the plant.
  • Package Including: Lepidopteran pests include, for example, chilosuppressalis (walker), Tryporyzaincertulas (walker), cnaphalocrocismedinalis Guenee, hellullaundalis, and conogethespunctiferlis Papilioxuthus, pierisrapae crucivora, parnaraguttata, malacosoma Neustria testacea, lymantriadispar, hyphantriacunea, euproctissubflava , pathlodescontracus, helicoverplomigera, pink bollworm, trichoplusiani, mamestrabrassicae, spodopteraexigua, Spodoptera litura ( Spodopteralitura), Anoxophyesoranafasciata, Adoxophyeshonmai, Archipsfuscocureanus
  • Coleoptera pests include, for example, sitphilusoryzaelinne, Podagricomela nigricollis Che, S. zeamails, S. granarius, Cabbageleafbeetle, and small leafhoppers. (Daikon leaf beele), fleabeetle, Altica chalybea, phyllotretastriolata, Epitrixcucumeris, Ehirtipennis, E. fuscula, Aulacophoraindica (Gemlin), Phaedon cochleariae, etc.
  • Diptera pests include, for example, agromyzaoryzae, hydrelliagriseola, liriomyzatrifolii, chromatomyiahorticola, liriomyzabryoniae, gray fly (deliaplatura), deliaantiqua, ceratitiscapiatawiedgman, rhagoletispomonella, R. cingulata.
  • Hemipteran pests include, for example, megacoptapunctatissimum, eurydemarugosum, eysarcorislewisi, eysarcorisparvus, nezaraviridula, plautiastali, sylvestris Halymorphamista, cletuspunctiger, leptocorisachinensis, stephantispyrioides, and trigonotyluscoelestialium.
  • Homopteran pests include, for example, nephotettixcincticeps, laodelphaxstriatellus, nilaparvatalugens, sogatella furcifera, psyllapyrisuga, diaphorinatabaci, and tobacco powder Be (bemisiatabaci), locust (homoptera), apple aphid (eriosomalanigerum).
  • hymenoptera there are arachinasaefifinis, argepagana, formica japonica, and dryocsmuskuriphilus.
  • Thysanoptera pests such as Haplothrips Chinensis Priesner.
  • Arachnida pest For example, panonychus citri, Tetranychus cinnabarinus, panonychus ulmi, tetranychus urticae, tetranychus viennensis, and small needles Oligonychus ununguis) eotetranychus kankitus, brevipalus phoenicis, bryobia praetiosa, aceria tulipae, colomerus vitis, calacarus Carinatus), polyphagotarsonemus latus, rhizoglyphus rostochiensis, and the like.
  • Anoplura such as Damalinia spp., Haematopinus spp., Linognathus spp., Pediculus spp., Trichodectes spp. ).
  • Isopoda for example, Oniscus asellus, Armadilliudium vulgare, Porcellio scaber.
  • Diplopoda for example, Blaniulus guttulatus.
  • Chi lopoda for example, Geophilus carpophagus Scutigera spp.
  • Synphyla for example, Scutigerella immaculata.
  • Thysanura for example, Lepisma saccharina.
  • Collembola for example, the armed spiny worm (Onychiurus armatus).
  • Orthoptera for example, Acheta domesticus, Gryllotalpa spp., Locusta migratoriamigrator ioides, Melanoplus pp., Desert ⁇ (Schistocercagregaria) ).
  • Dermaptera for example, Forficula auricularia.
  • Isoptera (lsoptera), for example, Reticulitermes spp.
  • nematodes selected from root-knot nematodes, cyst-forming nematodes, stem nematodes, and leaf nematodes.
  • the following nematode soybeans, Heterodera, golbodera rostochiensis, melonogyne incognita, etc., in the dorylaimida, longidorus sp., and the like are preferred.
  • the insecticidal composition is used for controlling Bemisia tabaci, Thrips tabaci, rice planthopper, beet armyworm, yellow stripe, scale insect, cotton bollworm, cotton bollworm, cabbage caterpillar, cabbage tube , rapeseed, spider mites, bridge worms, cotton blind mites, tea mites, tea caterpillars, tea orange mites, leaf mites, citrus leaf moth, citrus cotton mites, citrus leaf mites, citrus leaf miner, rust mites, peach small Carnivorous insects and pears.
  • the meaning of the plants herein is to be understood as meaning all plants and plant populations.
  • Plants are plants obtainable by conventional breeding and preferred methods or by biotechnological and genetic engineering methods or by a combination of these methods.
  • the plants include transgenic plants, as well as plant varieties that are protected or unprotected by plant breeders' rights.
  • the meaning of a plant part is understood to mean all parts and organs of the plant above and below the ground, such as branches, leaves, flowers and roots, examples of which may be leaves, needles, leaves, stems, stems, flowers, fruit bodies, fruits. And seeds, as well as roots, tubers and rhizomes.
  • the plant parts also include harvested material as well as vegetative and generative propagation material such as cuttings, tubers, rhizomes, young shoots and seeds.
  • Useful plants which can be used in the protection of the present invention, as well as the application of the pesticidal composition according to the invention, include: cereal plants such as wheat, oats, barley, triticale and rye, as well as corn, sorghum and chestnut, rice; beets, such as sugar Beet or fodder beet; fruit, such as apple fruit, stone fruit, tree nut or soft fruit such as apple, pear, plum, peach, banana, almond, walnut, pistachio, cherry or berry, such as strawberry, or blackberry; Crops such as kidney beans, peas or soybeans; oil crops such as canola, mustard, olive, sunflower, ramie, cocoa or peanut; cucurbits such as pumpkin, zucchini, cucumber or melon; fiber plants such as cotton, flax, marijuana Or jute; citrus fruits such as oranges, lemons, grapefruits or oranges; vegetables such as spinach, lettuce, asparagus, cabbage, carrots, onions, tomatoes, red peppers, potatoes or
  • the present invention provides a method for preventing or controlling a pest, which comprises applying the pesticidal composition of the present invention to a target useful plant, a target pest or an environment thereof, and a propagation material of the target useful plant.
  • compositions of the invention are carried out directly by conventional treatment or by acting on their environment, habitat or storage area, such as impregnation, watering, spraying, misting, spreading, Spraying, fogging, spreading, foaming, coating, coating, drip irrigation, etc. to the leaves of plants (foliar application), the frequency and amount of application can be adjusted to adapt to the extent of damage by the pests .
  • compositions of the invention are also suitable for protecting plant propagation material such as seeds, fruits, tubers or nucleoli or plant cuttings from pests, particularly insects and mites.
  • the propagation material can be treated with the composition prior to application, such as seed dressing prior to sowing.
  • the active ingredient can also be applied to the seed (coating) by soaking the nucleoli in the liquid composition or coating the nucleolus with a solid composition.
  • the composition can also be applied to the application site when the propagation material is applied, for example, within the seed ditch during sowing.
  • plant propagation material is understood to mean all parts of the plant capable of reproduction, such as seeds, as well as plant material such as cuttings or tubers (for example potatoes). Therefore, the plant parts used in this article include plant reproduction. material. Mention may be made, for example, of seeds (in the narrow sense), roots, fruits, tubers, bulbs, rhizomes and plant parts. Germinated plants and effective plants to be inhibited after germination from the soil or after emergence are also mentioned. Young plants can be protected by whole or partial treatment by dipping prior to transplantation.
  • Plant parts and subsequently grown plant organs are any part of a plant produced by plant propagation material such as seeds. Plant parts, plant organs and plants can also benefit from protecting plants from plant diseases by applying the compositions to plant propagation materials. Certain plant parts and certain subsequently grown plant organs can also be considered as plant propagation material, which can itself be applied (or treated) with the composition; thus plants produced from treated plant parts and treated plant organs, Other plant parts and other plant parts may also benefit from protecting the plant from plant pests by applying the composition to certain plant parts and certain plant organs.
  • the active ingredient can also be applied to the seed by successively impregnating the tubers or grains with a liquid preparation of the respective active ingredients, or by coating with a combined wet or dry preparation (coating) ).
  • compositions of the invention are applied to the seed in their own right or in a suitable dosage form.
  • the seed is treated in a steady state such that the treatment does not cause any damage.
  • the treatment of the seed can usually be carried out at any time between harvesting and sowing. It must generally be noted during seed treatment that the amount of the composition of the invention applied to the seed and/or the amount of other additives is selected so as not to affect the germination of the seed or to damage the resulting plant.
  • compositions of the present invention are particularly advantageous for treating plant propagation material, particularly seeds of rice, canola, cotton, wheat, barley, soybean, corn, peanuts.
  • a method of protecting a seed comprising contacting the seed with a synergistically effective amount of a pesticidal composition of the present invention prior to sowing and/or after germination.
  • a seed treated with the pesticidal composition of the present invention is
  • compositions of the invention can be applied to the environment, habitat or storage area in which the plants are grown.
  • the environment and habitat of plant growth refer to a support capable of rooting and growing crops, such as soil, water, etc.
  • Specific raw materials can be used, for example, sand, pumice, vermiculite, diatomaceous earth, agar, gelatin, High molecular substances, asbestos, wood chips, bark, etc. Soil is preferred.
  • a method of applying a medicament to the soil for example, diluting the liquid medicament in water or undiluting the root applied directly to the root of the plant or the method of growing the farm, and spreading the granule into the root of the plant or in the field of the nursery
  • powder, water-dispersible granules, etc. are sprayed into the soil and mixed with the soil as a whole.
  • the powder and the water-dispersible granules are diluted and sprayed in the planting hole and the seeding ditch. The method of sowing, etc.
  • the treatment of the present invention may also produce a super-additive effect of improving plant growth, increasing tolerance to high or low temperatures, increasing tolerance to drought or salinity to water or soil, and increasing flowering. Quality, making harvesting easier, accelerating maturity, increasing harvesting yield, improving the quality of harvested products and/or improving their nutritional value and improving harvesting Storage stability of the product and / or its processing properties.
  • the dose can even be reduced, in particular when applying an inert matrix When it is asbestos or pearl rock;
  • the pesticidal composition of the present invention comprises the application of the first active ingredient and the second active ingredient separately, sequentially or simultaneously.
  • any of the technical features of any embodiment or embodiment of the present invention may be independently combined with any other embodiment of the present invention. That is, one or more of the technical features of any of the embodiments of the present invention can be recombined with any other technical features. Technical features formed by recombining such technical features are disclosed herein, as specifically recited herein.
  • flubenzuron has good control effect on whitefly, aphid and scale insect. After mixed with lambda-cyhalothrin, it can effectively prevent rice planthopper, thrips and cotton red bell. Insects, Helicoverpa armigera, Pieris rapae, Brassica campestris, Brassica campestris, Red spider, Bridge worm, Cotton scorpion, Tea scorpion, Tea caterpillar, Tea orange stalk, Leaf stalk, Citrus leaf moth, Orange stalk, Citrus leaf stalk Main pests such as citrus leaf miner, rust mites, peach small heartworm and pear small heartworm;
  • the wettable powder of the present invention is obtained by mixing the active ingredients, various auxiliaries, fillers and the like in proportions of the formulation and pulverizing them by an ultrafine pulverizer.
  • the original drug, the solvent and the emulsifier are added together to dissolve into a uniform oil phase; the water-soluble component and water are mixed to prepare an aqueous phase; and the oil phase is mixed with the water phase under high-speed stirring to obtain the present invention.
  • Water emulsion Water emulsion.
  • the active ingredient, the dispersing agent, the wetting agent, the disintegrating agent and the filler are uniformly mixed according to the formulation ratio, and are pulverized into a wettable powder by a jet stream, and then added with a certain amount of water to be mixed and granulated.
  • the water-dispersible granules of the present invention are obtained by dry sieving.
  • microemulsion of the present invention is obtained by mixing and stirring the above components to a uniformly transparent liquid.
  • the wettable powder of the present invention is obtained by mixing the active ingredients, various auxiliaries, fillers and the like in proportions of the formulation and pulverizing them by an ultrafine pulverizer.
  • the above components of the disodium disodium, modified calcium lignosulfonate, xanthan gum, bentonite, glycerin, water, etc. are uniformly mixed in proportion and sand-milled to prepare a suspension agent.
  • the oil phase containing the first active ingredient flufenicol is added to a suspending agent containing the second active ingredient cyhalothrin to obtain a suspoemulsion.
  • the olefin is obtained in an oil phase; the aqueous phase is uniformly mixed according to the components in the formulation; the oil phase is added to the aqueous phase under stirring to obtain an aqueous emulsion.
  • the above combinations are mixed in proportion, ground, and pulverized to prepare a wettable powder.
  • the milled active ingredient is uniformly applied to the carrier wetted with polyethylene glycol in a mixer. In this way, dust-free coated granules can be obtained.
  • the above components are mixed in proportion, ground and pulverized to prepare a wettable powder.
  • the active ingredient is mixed with the auxiliaries and ground and the mixture is moistened with water.
  • the mixture was extruded and then dried in a stream of air.
  • the acid monoester disodium, the modified lignosulfonate calcium, the xanthan gum, the bentonite, the glycerin, the water and the like are uniformly mixed in proportion and sand-milled to prepare a suspension.
  • An oil phase containing the second active ingredient lambda cyhalothrin is added to the suspension containing the first active ingredient to obtain a suspoemulsion.
  • the above components are uniformly mixed in proportion and prepared by sanding Into a suspending agent.
  • the oil phase containing the second active ingredient cyhalothrin is added to a suspension containing the first active ingredient flubenzuron to obtain a suspoemulsion.
  • Fluroxypyrazine 50% Second active ingredient cyhalothrin 2% SOLVESSO TM 200 10% Ethoxylated castor oil 4% Fatty alcohol polyoxyethylene ether sulfosuccinate monosodium disodium 10% Modified calcium lignosulfonate 5% Xanthan gum 0.5% Bentonite 1% Glycerol 5% Defoamer 0.6% water make up to 100%
  • the above components are uniformly mixed in proportion and prepared by sanding Into a suspending agent.
  • An oil phase containing the second active ingredient cyhalothrin is added to a suspension containing the first active ingredient flubenzuron to obtain a suspoemulsion.
  • the above components are mixed and stirred to a uniformly transparent liquid to obtain the emulsifiable concentrate of the present invention.
  • the plurality polymethylene polyphenyl polyisocyanate (the PAPI), the second active ingredient cyhalothrin 200 is (TM) and an oil phase formed by SOLVESSO added (TM) 4913 aqueous solution in ATLOX, to form an emulsion.
  • the catalyst was then heated and kept warm at 50 ° C for 2 hours. After cooling, a microcapsule containing the second active ingredient is obtained.
  • ATLOX TM 4913 dispersant LFH, antifoaming agent, urea, the first active ingredient flufenicol and water are uniformly mixed in proportion and sanded to prepare a suspension.
  • microcapsule containing the second active ingredient cyhalothrin is added to the aqueous suspension of the first active ingredient flufenicol, and stirred uniformly to obtain the microcapsule suspension-suspending agent of the present invention.
  • Fluroxypyrazine 5% Second active ingredient cyhalothrin 50% SOLVESSO TM 200 20% Ethoxylated castor oil 5% Fatty alcohol polyoxyethylene ether sulfosuccinate monosodium disodium 10% Modified sodium lignosulfonate 5% Xanthan gum 0.5% Glycerol 5% Polyvinylpyrrolidone (PVP-K30) 1% Defoamer 0.6% water make up to 100%
  • the second active ingredient, cyhalothrin is dissolved in SOLVESSO TM 200, and ethoxylated castor oil is added to obtain a emulsifiable concentrate containing the second active ingredient, cyhalothrin; the first active ingredient flufenicol , fatty alcohol polyoxyethylene ether sulfosuccinate monosodium disodium, modified lignosulfonate calcium, xanthan gum, glycerol, polyvinylpyrrolidone, water and other components are uniformly mixed in proportion and sand Grinding, prepared as a suspension.
  • the oil phase containing the second active ingredient lambda cyhalothrin is added to the suspension seed coating agent containing the first active ingredient to obtain the suspension seed coating agent of the present invention.
  • the antifreeze propylene glycol, the diluent SOLVESSO TM 100 is mixed, and the first active ingredient flufenicol and the second active ingredient cyhalothrin are added under stirring; a surfactant is added thereto, and a pulverizing device is passed under stirring.
  • the colloid mill is pulverized, and the colloid-milled suspension is passed through an ultrafine pulverizer. The cycle is repeated until the particle diameter of the solid particles is ⁇ 2 um.
  • the wettable powder of the present invention is obtained by mixing the active ingredients, various auxiliaries, fillers and the like in proportions of the formulation and pulverizing them by an ultrafine pulverizer.
  • the components of the active component, the dispersing agent and the wetting agent are uniformly mixed according to the formulation ratio, and after grinding and/or high-speed shearing, corn oil is added to obtain an oil suspensioning agent.
  • the first active ingredient flufenicol and the second active ingredient, cyhalothrin, are uniformly mixed in proportion.
  • the ratio in the above embodiment is a weight ratio of one hundred.
  • the inventors conducted a large number of tests and effect analysis on the different ratios of flufenicol and cyhalothrin through a large number of screening tests, and found that the new compound insecticide obtained within a certain ratio range
  • the agent has a gain effect, not just a simple addition of the two agents, and is specifically described by the following embodiments.
  • a combination of indoor virulence determination and insecticidal test is adopted, firstly, the indoor toxicity test is used to determine the co-toxicity coefficient (CTC) of the two agents after being compounded in a certain ratio, and CTC ⁇ 80 is resistant.
  • Test method The compound pesticide reagents in the above examples were diluted into five series of concentrations, respectively, and placed in a beaker for use. Then, the leaves of the same size that have not been contacted with any agent are soaked in the prepared liquid for 5s, then taken out, naturally dried, placed in the insect box, and then the test larva is attached. Breeding at 25 °C, each treatment was repeated 3 times, the number of test insects used per repetition was 20, and a blank control was set at the same time. The number of dead insects was checked at 72 hours, the mortality and corrected mortality were calculated, and the virulence regression equation was obtained. And calculate the LC 50 value. If the control mortality is greater than 10%, it is considered an invalid test. Calculated as follows:
  • Mortality (%) (number of live insects before drug - number of live insects) / number of live insects before drug *100
  • the test insect corrected mortality rate was converted into probability value (y), the treatment concentration ( ⁇ g/ml) was converted into logarithmic value (x), and the virulence regression equation was obtained by least squares method, and thus each medicament was calculated. value.
  • the co-toxicity coefficient CTC was calculated. The calculation formula is as follows (with flufenicol as a standard drug, its virulence index is 100):
  • Measured virulence index (ATI) (standard drug LC 50 / test agent LC 50 ) ⁇ 100
  • Theoretical virulence index (TTI) A ATI ⁇ percentage of A in the mixture + B ATI ⁇ percentage of B in the mixture
  • CTC (mixture ATI / mixture TTI) ⁇ 100
  • Test 1 Determination of indoor virulence of citrus aphids
  • Test 2 Results of indoor virulence test on beet armyworm
  • the indoor virulence test results of rice planthopper, thrips, whitefly, and red spider also showed that flufenicol and lambda-cypermethrin inhibit rice planthopper and alfalfa.
  • the ratio of horse, whitefly, and red spider was in the range of 1:100-100:1, the co-toxicity coefficient was greater than 120, indicating that the mixing of the two in this range showed a gain effect.
  • X is the kill rate when active compound A is used in an amount of m g/ha or at a concentration of m ppm, expressed as a percentage of the untreated control
  • Y is the kill rate when using the active compound B in an amount of n g/ha or a concentration of n ppm, expressed as a percentage of the untreated control
  • E is the killing rate when active ingredients A and B are used in amounts of m and n g/ha or at concentrations of m and n ppm, expressed as a percentage of the untreated control,
  • the lethal effect of the composition is superadditive, i.e., there is a synergistic effect.
  • the actually observed kill rate must exceed the value of the expected kill rate value (E) calculated using the above formula.
  • the test was carried out as follows: The test site was in Jiaxing, Zhejiang, and the time was in early March. The potted citrus test was carried out for 3 years. Before the spraying, 200 insects were inoculated with cotton aphid. Spray treatment 2 days after inoculation. According to the front and back of the wetted leaves, 3 citrus seedlings were treated each. Six days after the drug, 25 leaves were taken in the laboratory to investigate the number of adults on the leaves with binoculars, and the population reduction rate and control effect were calculated. The formula is as follows:
  • Test 4 Efficacy test for controlling beet armyworm
  • the test was carried out as follows: The test site was in Jiaxing, Zhejiang, and the time was in early March. Potted cotton test was used. Before the spraying, 200 insects were inoculated into beet armyworms. Spray treatment 2 days after inoculation. According to the front and back of the wetted blade, 3 cotton plants were treated each. Six days after the drug, 25 leaves were taken in the laboratory to investigate the number of adults on the leaves with binoculars, and the population reduction rate and control effect were calculated. The formula is as follows:
  • Sand 1 Rotating soil 1 Prepare experimental soil, 200 g of soil was placed in each 300 ml plastic container, and sprayed at a prescribed concentration of the drug. Ten larvae of yellow-striped fleas were placed in each container, and after standing at a constant temperature of 25 ° C in the dark, the soil was dispersed after the required time, and the number of larvae survived was counted to obtain mortality.
  • Mortality (%) ⁇ 1 - (number of survival heads / number of insects) ⁇ X100
  • the theoretical value (%) of mortality is calculated by the "colby formula".
  • the test results show that the actual mortality rate (%) is higher than the theoretical value (%), indicating that the combination of flufenicol and cyhalothrin, used in soil treatment has a synergistic effect on the prevention and treatment of yellow stripe.
  • Test 6 Effect of seed treatment on beet armyworm
  • the required amount of liquid formulation is added to the Erlenmeyer flask. Shake the flask to distribute the liquid to the entire bottom of the vessel. Immediately thereafter, the required amount of seeds is added to the bottle. The flask was shaken vigorously by hand for about 1 minute so that all the seeds were covered with liquid. The contents of the flask were poured onto a drying rack and dried in an oven.
  • the same number of kernels were loaded into each jar and a certain amount of solid preparation was filled in each vial to obtain The required amount of 0.3 mg of active ingredient per seed.
  • the flask was placed on a roller and spun at 80 rpm for 3 minutes. The flask was shaken by hand to cause the seed sticking to the wall of the flask to fall, and then the flask was rotated in the opposite direction for 3 minutes.
  • the agent and the single agent of Formulation Example 1-22 were subjected to seed treatment at a prescribed concentration according to Procedures F1 and F2.
  • the treated corn seeds are then sown. Twenty-six days after sowing, the 5-8 cm long portion of the topmost leaf of the plant was placed in a glass beaker and infested with 10 newly hatched beet armyworm first instar larvae.
  • the beaker was covered with a lid and kept at 25 ° C and 60% relative atmospheric humidity for 16 hours per day. Evaluation was performed after infestation 3-5. The mortality rate was recorded after recording the number of larvae that survived on the grown plants.
  • Mortality (%) ⁇ 1 - (number of survival heads / number of insects) ⁇ X100
  • the theoretical value (%) of mortality is calculated by the "colby formula".
  • the test results show that the actual mortality rate (%) is higher than the theoretical value (%), indicating that the combination of flufenicol and cyhalothrin is used for seed treatment and has synergistic effect on the control of beet armyworm.

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  • Life Sciences & Earth Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • Agronomy & Crop Science (AREA)
  • Zoology (AREA)
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Abstract

La présente invention concerne une composition pesticide comprenant le pyrifluquinazon et la lambda-cyhalothrine, et concerne plus précisément un procédé de lutte contre les organismes nuisibles. La composition pesticide comprenant le pyrifluquinazon et la lambda-cyhalothrine a un rapport en poids de pyrifluquinazon/lambda-cyhalothrine de 1:100 à 100:1. L'invention concerne un procédé de prévention ou de lutte contre les organismes nuisibles : utilisant la composition pesticide sur une plante utile cible, un organisme nuisible cible ou un environnement de ce dernier, et un matériau reproducteur pour la plante utile cible. L'invention concerne un procédé pour protéger des graines de plante, consistant : à permettre à des graines d'être en contact avec une dose efficace de la composition pesticide de la présente invention, avant l'encensement et/ou après la germination. Une graine est administrée et traitée avec une dose efficace de la composition pesticide de la présente invention.
PCT/CN2015/073294 2014-03-11 2015-02-26 Composition pesticide et procédé de lutte contre les organismes nuisibles WO2015135424A1 (fr)

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CN106212489A (zh) * 2016-05-26 2016-12-14 盐城工学院 Pyrifluquinazon与双三氟虫脲复配组合物
CN110583636A (zh) * 2018-06-13 2019-12-20 江苏龙灯化学有限公司 一种适合农业使用的农药助剂及其用途
CN110122129A (zh) * 2019-04-15 2019-08-16 中国检验检疫科学研究院 一种植物产品有害生物复合处理方法

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CN1947514A (zh) * 2006-11-05 2007-04-18 深圳诺普信农化股份有限公司 含有氟虫腈和高效氯氟氰菊酯的具有协同增效作用的杀虫剂
WO2013107795A2 (fr) * 2012-01-17 2013-07-25 Syngenta Participations Ag Mélanges pesticides contenant des pyrrolidinediones spirohétérocycliques
CN103518769A (zh) * 2013-10-11 2014-01-22 江苏龙灯化学有限公司 一种杀虫组合物

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WO2006106798A1 (fr) * 2005-03-30 2006-10-12 Nihon Nohyaku Co., Ltd. Agent de lutte contre des animaux nuisibles et procédé d'utilisation de celui-ci

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Publication number Priority date Publication date Assignee Title
CN1947514A (zh) * 2006-11-05 2007-04-18 深圳诺普信农化股份有限公司 含有氟虫腈和高效氯氟氰菊酯的具有协同增效作用的杀虫剂
WO2013107795A2 (fr) * 2012-01-17 2013-07-25 Syngenta Participations Ag Mélanges pesticides contenant des pyrrolidinediones spirohétérocycliques
CN103518769A (zh) * 2013-10-11 2014-01-22 江苏龙灯化学有限公司 一种杀虫组合物

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