WO2015133996A1 - Low voc composition to remove grafitti - Google Patents
Low voc composition to remove grafitti Download PDFInfo
- Publication number
- WO2015133996A1 WO2015133996A1 PCT/US2014/020192 US2014020192W WO2015133996A1 WO 2015133996 A1 WO2015133996 A1 WO 2015133996A1 US 2014020192 W US2014020192 W US 2014020192W WO 2015133996 A1 WO2015133996 A1 WO 2015133996A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- percent
- composition
- graffiti
- glycol ether
- remove
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 55
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims abstract description 36
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims abstract description 25
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 18
- 239000003205 fragrance Substances 0.000 claims abstract description 12
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000008367 deionised water Substances 0.000 claims description 17
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims description 5
- IPKKHRVROFYTEK-UHFFFAOYSA-N dipentyl phthalate Chemical compound CCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCC IPKKHRVROFYTEK-UHFFFAOYSA-N 0.000 claims description 5
- 239000013008 thixotropic agent Substances 0.000 claims description 4
- OAYXUHPQHDHDDZ-UHFFFAOYSA-N 2-(2-butoxyethoxy)ethanol Chemical compound CCCCOCCOCCO OAYXUHPQHDHDDZ-UHFFFAOYSA-N 0.000 claims description 2
- 229910021641 deionized water Inorganic materials 0.000 claims 4
- 239000003795 chemical substances by application Substances 0.000 claims 1
- PAAZPARNPHGIKF-UHFFFAOYSA-N 1,2-dibromoethane Chemical compound BrCCBr PAAZPARNPHGIKF-UHFFFAOYSA-N 0.000 abstract description 3
- 239000012855 volatile organic compound Substances 0.000 description 16
- 238000009472 formulation Methods 0.000 description 15
- 239000000976 ink Substances 0.000 description 7
- 239000000463 material Substances 0.000 description 7
- 239000000243 solution Substances 0.000 description 7
- 238000004140 cleaning Methods 0.000 description 5
- 239000000758 substrate Substances 0.000 description 5
- 239000003973 paint Substances 0.000 description 4
- 239000004744 fabric Substances 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 210000003298 dental enamel Anatomy 0.000 description 2
- 239000000975 dye Substances 0.000 description 2
- 239000003550 marker Substances 0.000 description 2
- 241000385654 Gymnothorax tile Species 0.000 description 1
- 229920004142 LEXAN™ Polymers 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- 235000008331 Pinus X rigitaeda Nutrition 0.000 description 1
- 235000011613 Pinus brutia Nutrition 0.000 description 1
- 241000018646 Pinus brutia Species 0.000 description 1
- 229920005372 Plexiglas® Polymers 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 229920006397 acrylic thermoplastic Polymers 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 239000011449 brick Substances 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 229910021485 fumed silica Inorganic materials 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000002905 metal composite material Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 239000008213 purified water Substances 0.000 description 1
- 239000000565 sealant Substances 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 230000003381 solubilizing effect Effects 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
- ISXSCDLOGDJUNJ-UHFFFAOYSA-N tert-butyl prop-2-enoate Chemical compound CC(C)(C)OC(=O)C=C ISXSCDLOGDJUNJ-UHFFFAOYSA-N 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/26—Organic compounds containing oxygen
- C11D7/265—Carboxylic acids or salts thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D9/00—Chemical paint or ink removers
- C09D9/005—Chemical paint or ink removers containing organic solvents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/50—Perfumes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/26—Organic compounds containing oxygen
- C11D7/263—Ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/26—Organic compounds containing oxygen
- C11D7/264—Aldehydes; Ketones; Acetals or ketals
Definitions
- compositions to remove paint and enamel, acrylic, primer, and sealant from surfaces such as carpets, cloth, leather and suede, hard surfaces such as street signs, tile and brick to restore them as closely as possible to a clean condition are provided.
- Porous surfaces such as those of carpets, clothing, automobile seats, and certain metal and metal composites, and other hard surfaces such as tile, vinyl, and plastics can be marked with paint or ink in the form of graffiti, Permanent marker inks, and printers inks, enamel and acrylics, and highlighters can be used. Note that this composition will not harm Lexan® or Plexiglass®,
- compositions are limited both in the range of their effectiveness, and also as to how efficient they really are for their intended purpose. If one intends to remove a graffito, he is likely to find a nearly-equal number of formulations to buy for the purpose. In addition, some of the stains and deposits are usually only partially removed after application of market-available cleaners, and with risk to the material being cleaned. On the consumer market today, for example, there Motsenbocker Low VOC Composition To Remove Graffiti is no known composition which will remove marking pen dye from a white tablecloth. The present invention will.
- compositions are objectionable from an environmental standpoint.
- This composition is water-based, and is environmentally acceptable.
- the composition is available in a 3% Volatile Organic Compound (VOC) configuration and will perform surface
- a composition according to this invention specifically designed to attack and remove graffiti is water-based and comprises, in addition to water, Glycol Ether EB S Acetone, DBE, Acetic acid, and a small amount of fragrance.
- This composition is surprisingly effective for the removal of pen and grease pencil stains attached to flat surfaces. !Vfotsenbocker Low VOC Composition To Remove Graffiti
- This formulation represents a paradigm shift away from traditional cleaners. All cleaners in the market today clean specified substrates, e.g. tile cleaner, bathroom cleaner, floor cleaner, carpet cleaner, pre-wash; this formulation attacks specific stain types, for ANY substrate. Cleaners in today's market are basically just soap and water. This VOC-compiiant formulation works better than non-VOC-formulations in the market, remaining safe for the environment, safe for the individual, and safe for any surface.
- Gleaning graffiti from a wide range of substrate materials from deposits and stains is an aqueous solution of water, Glycol Ether EB, Acetone, DBE, Acetic acid, and a small amount of fragrance. This solution is
- biodegradable, low-VOC 3% VOC content
- VOC 3% VOC content
- the components of the solution are benign, and if left in place will eause no damage to the substrate (soiled) material to which the solution is applied, nc)r to persons who come in contact with it,
- the modified formulation to be described can be directly applied to many troublesome graffiti marks and left there. The stain quickly
- an amount of thixotropic agent equal to 5.2 percent by weight can be added to each of the formulae, substituting for an equal amount of de-onized water.
- cellulose and fumed silica make excellent thickeners for these
Abstract
A Low-VOC, water-based graffiti cleaner containing water, Glycol Ether EB, Acetone, DBE, Acetic acid, and a small amount of fragrance. The VOC content of this composition is less than or equal to 15.5%.
Description
Motsenbocker Low VOC Composition To Remove Graffiti
FIELD OF THE INVENTION
Compositions to remove paint and enamel, acrylic, primer, and sealant from surfaces such as carpets, cloth, leather and suede, hard surfaces such as street signs, tile and brick to restore them as closely as possible to a clean condition.
BACKGROUND OF THE INVENTION
Porous surfaces, such as those of carpets, clothing, automobile seats, and certain metal and metal composites, and other hard surfaces such as tile, vinyl, and plastics can be marked with paint or ink in the form of graffiti, Permanent marker inks, and printers inks, enamel and acrylics, and highlighters can be used. Note that this composition will not harm Lexan® or Plexiglass®,
The above recitation exemplifies a broad range of materials which need to be cleaned from a broad range of deposits and stains, In
response to this need, an equally wide range of cleaning compositions already exists in the market,
Generally speaking, commercial compositions are limited both in the range of their effectiveness, and also as to how efficient they really are for their intended purpose. If one intends to remove a graffito, he is likely to find a nearly-equal number of formulations to buy for the purpose. In addition, some of the stains and deposits are usually only partially removed after application of market-available cleaners, and with risk to the material being cleaned. On the consumer market today, for example, there
Motsenbocker Low VOC Composition To Remove Graffiti is no known composition which will remove marking pen dye from a white tablecloth. The present invention will.
Furthermore, many existing compositions are objectionable from an environmental standpoint. This composition is water-based, and is environmentally acceptable. The composition is available in a 3% Volatile Organic Compound (VOC) configuration and will perform surface
cleaning.
It is an object of this invention to provide a water-based
environmentally acceptable, biodegradable cleaning composition which can be used to remove graffiti. Any residue of these compositions which might remain on the surface, or in the fabric underlying it, will not adversely affect the user or the surface to which it was applied. It has proved to be a considerable surprise to observe how many types of really difficult stains and deposits these compositions can remove, with little or no remaining evidence that there ever had been a stain or a deposit, or that the
composition ever had been applied, all without damage to the material being cleaned.
BRIEF DESCRIPTION OF THE INVENTION
A composition according to this invention specifically designed to attack and remove graffiti is water-based and comprises, in addition to water, Glycol Ether EBS Acetone, DBE, Acetic acid, and a small amount of fragrance. This composition is surprisingly effective for the removal of pen and grease pencil stains attached to flat surfaces.
!Vfotsenbocker Low VOC Composition To Remove Graffiti
This formulation represents a paradigm shift away from traditional cleaners. All cleaners in the market today clean specified substrates, e.g. tile cleaner, bathroom cleaner, floor cleaner, carpet cleaner, pre-wash; this formulation attacks specific stain types, for ANY substrate. Cleaners in today's market are basically just soap and water. This VOC-compiiant formulation works better than non-VOC-formulations in the market, remaining safe for the environment, safe for the individual, and safe for any surface.
Motsenbocker Low VOC Composition To Remove Graffiti
DETAILED DESCRIPTION OF THE INVENTION
The basic formulation of this invention, itself useful for cleaning
Gleaning graffiti from a wide range of substrate materials from deposits and stains is an aqueous solution of water, Glycol Ether EB, Acetone, DBE, Acetic acid, and a small amount of fragrance. This solution is
biodegradable, low-VOC ( 3% VOC content ) and is applicable to a wide range of materials without damaging them. It is best to wash it out after the solution has done its work-it does leave a small but usually
unobjectionable deposit. The components of the solution are benign, and if left in place will eause no damage to the substrate (soiled) material to which the solution is applied, nc)r to persons who come in contact with it,
The combination of components used herein appears to function synergistically, by mechanisms which are not fully understood at this time. What has become apparent is that the total composition functions to a degree of effectiveness much greater than already-known compositions useful for the intended purposes, and that elimination of any of the components greatly reduces the effectiveness of the composition, U.S. Pat, No. 5,484,487 to otsenboeker teaches the application process for the present invention.
As a preliminary observation, it should be noted that purified water (either distilled, de-ionized or softened), is preferred. If it is used, the solution will be clear. If water is used which is not purified, then the solution is likely to be cloudy and sometimes less acceptable to the user. However, some users might actually prefer a cloudy or milky composition.
Motsenbocker Low VOC Composition To Remove Graffiti
Use of tap water will usually result in this.
Some paints and deposits are more resistant to the basic
formulation, usually because their dyes or other colorizers must be attended to either by decolorizing them, or by solubilizing them. Examples of these materials are fluid inks such as fountain pen inks, marker inks, and ball point inks. These are notoriously difficult to remove without damage to cloth, with the use of cleaning solutions generally available in a
household, and with the skill and knowledge of the householder.
Especially this is the situation where water-based formulations are needed. This invention provides excellent results without recourse to aromatic or petroleum solvents.
This is a 100% biodegradeable, water-based product designed to break the stain's bond with the underlying substrate, i.e. paint slides off the painted surface.
The modified formulation to be described can be directly applied to many troublesome graffiti marks and left there. The stain quickly
disappears. There will be no damage to any surfaces.
The presently preferred basic formulation is as follows:
C . Numbgrs
Glycol ether EB 11 1 -76-2
Glycol ether EB and DPNP 11 1 ~76~2
Acetone 67-64-1
DBE - Dl Base Ester 11 19-40-0
Acetic acid 64-19-17
Motsenbocker Low VOC Composition To Remove Graffiti
De-ionized water 7732-18-5
Fragrance / Pine (Chemia) 29163
In all the the formulations and guidelines given below, at least one substance from each group must be included.
As a variation of the below formulae, an amount of thixotropic agent equal to 5.2 percent by weight can be added to each of the formulae, substituting for an equal amount of de-onized water. As an example, cellulose and fumed silica make excellent thickeners for these
compositions.
15.5% VOC Formulation percentages
a. De-ionized water 53.7
b. Glycol ether EB 15.5
c. Acetone 13.6
d. DBE - Dl Base Ester 16.4
e. Acetic acid 0.3
f. Fragrance 0.5
100.0
7.25% VOC Formulation .perce afles , ,A
a. De-ionized water 53.7
b.Glyeol ether EB 7.25
Glycol ether DB 7.25
c. Acetone 13.6
d. DBE - Di Base Ester 16.4
fvlotsenbocker Low VOC Composition To Remove Graffiti e. Acetic acid 0.3
f. Fragrance 0,5
100.0
7.25% VOC Formulation percentages,,-,!!
a. De-ionized water 53,7
b. Glycol ether EB 7.25
Glycol ether DPNP 7,25
c. Acetone 13.6
d. DBE - Dl Base Ester 16.4
e. Acetic acid 0.3
f. Fragrance 0.5
100.0
Variable Range VOC Formulation percentages
a. De-ionized water (varying)
b. Glycol ether EB 0 - 14
Glycol ether DPNP 1 - 15.5
c. Acetone 13.6
d. DBE - Dl Base Ester 16.4
e. Acetic acid 0.3
f. Fragrance 0.5
100.0
This invention is not to be limited to the embodiments described in
Motsenbocker Low VOC Composition To Remove Graffiti the description which are given by way of example and not of limitation, but only in accordance with the scope of the appended claims.
Claims
1. A composition for removing graffiti from surfaces, consisting essentially of:
a. 53.7 percent deionized water;
b. 15.5 percent Glycol Ether EB;
c. 13.6 percent acetone;
d. 16.4 percent DBE;
e. 0,3 percent acetic acid; and
f. 0.5 percent fragrance.
2. A composition for removing graffiti from surfaces, consisting essentially of:
a. 53.7 percent deionized water;
b. 7.25 percent Glyeol Ether EB and
7.25 percent Glycol Ether DB;
c. 13.6 percent acetone;
d. 16.4 percent DBE;
e. 0.3 percent acetic acid; and
f. 0.5 percent fragrance.
3. A composition for removing graffiti from surfaces, consisting essentially of:
a. 53.7 percent deionized water;
b. 7.25 percent Glycol Ether EB and
7.25 percent Glycol Ether DPNP;
Motsenbocker Low VOC Composition To Remove Graffiti c. 13.6 percent acetone;
d. 16.4 percent DBE;
e. 0.3 percent acetic acid; and
f. 0.5 percent fragrance.
4. A composition for removing graffiti from surfaces, consisting essentially of:
a. a varying percentage deionized water;
b. 0 to 14 percent Glycol Ether EB and
1 to 15.5 percent Glycol Ether DPNP;
G. 13.6 percent acetone;
d. 16.4 percent DBE;
e. 0.3 percent acetic acid; and
f. 0.5 percent fragrance.
5. A composition for removing graffiti from surfaces, as in Claim 1 , where the amount of de-ionized water is replaced with 48.5 percent de- ionized water plus 5.2 percent thixotropic agent.
6. A composition for removing graffiti from surfaces, as in Claim 2, where the amount of de-ionized water is replaced with 48.5 percent de- ionized water plus 5.2 percent thixotropic agent.
7. A composition for removing graffiti from surfaces, as in Claim 3, where the amount of de-ionized water is replaced with 48.5 percent de- ionized water plus 5.2 percent thixotropic agent.
8. A composition for removing graffiti from surfaces, as in Claim 4, where the varying percentage of de-ionized water is replaced with a
Motsenbocker Low VOC Composition To Remove Graffiti reduced, varying percentage of de-ionized water plus 5,2 percent thsxoiropic agent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/US2014/020192 WO2015133996A1 (en) | 2014-03-04 | 2014-03-04 | Low voc composition to remove grafitti |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/US2014/020192 WO2015133996A1 (en) | 2014-03-04 | 2014-03-04 | Low voc composition to remove grafitti |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO2015133996A1 true WO2015133996A1 (en) | 2015-09-11 |
Family
ID=54055661
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/US2014/020192 WO2015133996A1 (en) | 2014-03-04 | 2014-03-04 | Low voc composition to remove grafitti |
Country Status (1)
| Country | Link |
|---|---|
| WO (1) | WO2015133996A1 (en) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5415800A (en) * | 1993-06-09 | 1995-05-16 | Motsenbocker; Gregg | Cleanser for releasing adherent deposits from surfaces |
| US20080317949A1 (en) * | 2007-06-19 | 2008-12-25 | Garry Edgington | Method for protecting substrates and removing contaminants from such substrates |
| WO2009137096A1 (en) * | 2008-05-09 | 2009-11-12 | Rhodia Inc. | Cleaning compositions incorporating green solvents and methods for use |
| US20120040880A1 (en) * | 2010-08-12 | 2012-02-16 | Segetis, Inc. | Carboxy ester ketal removal compositions, methods of manufacture, and uses thereof |
-
2014
- 2014-03-04 WO PCT/US2014/020192 patent/WO2015133996A1/en active Application Filing
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5415800A (en) * | 1993-06-09 | 1995-05-16 | Motsenbocker; Gregg | Cleanser for releasing adherent deposits from surfaces |
| US20080317949A1 (en) * | 2007-06-19 | 2008-12-25 | Garry Edgington | Method for protecting substrates and removing contaminants from such substrates |
| WO2009137096A1 (en) * | 2008-05-09 | 2009-11-12 | Rhodia Inc. | Cleaning compositions incorporating green solvents and methods for use |
| US20120040880A1 (en) * | 2010-08-12 | 2012-02-16 | Segetis, Inc. | Carboxy ester ketal removal compositions, methods of manufacture, and uses thereof |
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