WO2015118942A1 - Shielded wire - Google Patents

Shielded wire Download PDF

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WO2015118942A1
WO2015118942A1 PCT/JP2015/051381 JP2015051381W WO2015118942A1 WO 2015118942 A1 WO2015118942 A1 WO 2015118942A1 JP 2015051381 W JP2015051381 W JP 2015051381W WO 2015118942 A1 WO2015118942 A1 WO 2015118942A1
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Prior art keywords
wire
electric wire
shielded
shielded electric
plating film
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PCT/JP2015/051381
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French (fr)
Japanese (ja)
Inventor
亮真 上柿
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株式会社オートネットワーク技術研究所
住友電装株式会社
住友電気工業株式会社
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Publication of WO2015118942A1 publication Critical patent/WO2015118942A1/en

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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B1/00Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
    • H01B1/02Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of metals or alloys
    • H01B1/023Alloys based on aluminium
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/16Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
    • C23C18/1601Process or apparatus
    • C23C18/1633Process of electroless plating
    • C23C18/1635Composition of the substrate
    • C23C18/1637Composition of the substrate metallic substrate
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/16Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
    • C23C18/1601Process or apparatus
    • C23C18/1633Process of electroless plating
    • C23C18/1646Characteristics of the product obtained
    • C23C18/165Multilayered product
    • C23C18/1651Two or more layers only obtained by electroless plating
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/16Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
    • C23C18/1601Process or apparatus
    • C23C18/1633Process of electroless plating
    • C23C18/1646Characteristics of the product obtained
    • C23C18/165Multilayered product
    • C23C18/1653Two or more layers with at least one layer obtained by electroless plating and one layer obtained by electroplating
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D5/00Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
    • C25D5/10Electroplating with more than one layer of the same or of different metals
    • C25D5/12Electroplating with more than one layer of the same or of different metals at least one layer being of nickel or chromium
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D7/00Electroplating characterised by the article coated
    • C25D7/06Wires; Strips; Foils
    • C25D7/0607Wires
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B7/00Insulated conductors or cables characterised by their form
    • H01B7/17Protection against damage caused by external factors, e.g. sheaths or armouring
    • H01B7/28Protection against damage caused by moisture, corrosion, chemical attack or weather
    • H01B7/2813Protection against damage caused by electrical, chemical or water tree deterioration
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B11/00Communication cables or conductors
    • H01B11/02Cables with twisted pairs or quads
    • H01B11/06Cables with twisted pairs or quads with means for reducing effects of electromagnetic or electrostatic disturbances, e.g. screens
    • H01B11/10Screens specially adapted for reducing interference from external sources
    • H01B11/1033Screens specially adapted for reducing interference from external sources composed of a wire-braided conductor

Definitions

  • the present invention relates to a shielded electric wire.
  • shielded wires are used in places where countermeasures against electromagnetic noise are required in automobiles and electrical equipment.
  • the shielded electric wire has a core part that transmits electrical signals and the like, and a shield layer that covers the outer periphery of the core part. Intrusion of electromagnetic noise from the outside to the core part, and electromagnetic noise from the core part to the outside The radiation can be suppressed by the shield layer.
  • the shield layer for example, a braided shield layer formed by braiding metal strands is known.
  • Patent Document 1 describes a shielded electric wire having a shield layer configured by braiding a metal-coated fiber formed by forming a metal film on the outer periphery of a heat-resistant fiber.
  • the shield layer using the metal-coated fiber as in Patent Document 1 has a problem that it is liable to cause a connection failure when connected to the ground wire.
  • the present invention has been made in view of such a background, and intends to provide a shielded electric wire that is inexpensive and lightweight and has excellent shielding performance.
  • One aspect of the present invention is a core portion including a covered electric wire having a conductor and an insulating material coated around the conductor; A braided shield layer covering the outer periphery of the core part, comprising a plurality of strands knitted,
  • the element wire is a shielded electric wire characterized in that an Al wire or an Al alloy wire is used as a base material, and a plating film made of a metal that is harder to be oxidized than Al is provided on the surface.
  • the shielded electric wire has a braided shield layer formed by braiding a plurality of strands and covering the outer periphery of the core portion.
  • the said strand is comprised by using Al wire or Al alloy wire as a base material, and has the plating film which consists of a metal which is hard to oxidize than Al on the surface. Therefore, it is possible to prevent the Al 2 O 3 film from being formed on the surface of the base material.
  • the said plating film is comprised from the metal which is harder to oxidize than Al, it can suppress that the oxide film which is a nonconductor is formed on the surface of the said strand.
  • the element wire can reduce the AC resistance in the high frequency region as compared with the conventional element wire not having a plating film.
  • the said braided shield layer improves the shielding performance with respect to the electromagnetic noise of a high frequency area
  • the said strand uses the Al wire or Al alloy wire for the said base material, it is cheap and lightweight compared with the strand which consists of Cu or Cu alloy.
  • the shielded electric wire is inexpensive and lightweight and has excellent shielding performance.
  • FIG. 1 is a cross-sectional view taken along line II-II in FIG. 1. Sectional drawing of the strand in Example 1.
  • FIG. FIG. 3 is an explanatory diagram of measurement of an induced noise amount in the first embodiment.
  • Sectional drawing equivalent to FIG. 2 of the 2-core shielded electric wire which has a core part provided with two covered electric wires.
  • Sectional drawing equivalent to FIG. 2 of the 3 core shielded electric wire which has a core part provided with the three covered electric wires.
  • Sectional drawing equivalent to FIG. 2 of the 4-core shielded electric wire which has a core part provided with four covered electric wires.
  • the shielded wire may be configured as a power line that transmits a relatively large current such as operating power, or may be configured as a signal line that transmits a relatively small current such as a control signal.
  • the said shielded electric wire may be comprised as a single core shielded electric wire which has one said covered electric wire, and may be comprised as a multi-core shielded electric wire which has two or more said covered electric wires.
  • the conductor used for the said covered electric wire it is using the metal wire which has the outstanding electrical conductivity, such as Cu wire, Cu alloy wire, Sn (tin) plating Cu alloy wire, Al wire, and Al alloy wire, for example. it can.
  • the conductor may be composed of a single metal wire, or may be composed of a stranded wire in which a large number of the metal wires are twisted together.
  • the insulating material used for the covered electric wire a conventionally known material can be used as the insulating material for the electric wire. From the viewpoints of insulation and manufacturability, a crosslinked polyethylene resin or a crosslinked polyvinyl chloride resin is often used as the insulating material.
  • the element wire constituting the braided shield layer is composed of an Al wire or an Al alloy wire as a base material, and has a plating film made of a metal that is harder to be oxidized than Al on the surface.
  • the metal used for the plating film include metals having a higher standard oxidation-reduction potential than Al, such as Au (gold), Ag (silver), Cu (copper), Ni (nickel), and Sn (tin). Can be used. From the viewpoint of cost and conductivity, the plating film is preferably made of Sn.
  • the thickness of the said plating film is 1 micrometer or more.
  • the shielding performance in the high frequency region can be sufficiently improved.
  • the thickness of the plating film is less than 1 ⁇ m, the durability of the plating film may be insufficient depending on the application. That is, for example, when used as an automobile wire harness, the plating film may be worn away by vibration or bending, and the plating film may be easily peeled off.
  • the plating film is peeled off from the base material, an Al 2 O 3 film is formed on the surface of the base material, resulting in a decrease in shielding performance.
  • the thickness of the plating film is preferably 1 ⁇ m or more.
  • an intermediate film may be provided between the plating film and the base material as necessary.
  • an intermediate film what has the effect
  • a Zn plating film, a Ni plating film, or the like can be used as the intermediate film.
  • the shielded electric wire having the above-described configuration can improve the shielding characteristics in a frequency region of 1 MHz or more as compared with a shielded electric wire using a bare wire having no plating film on the surface. Therefore, the shielded electric wire is suitable for applications that need to reduce electromagnetic noise in a frequency region of 1 MHz or higher. Such applications include, for example, automobile wire harnesses.
  • the shielded electric wire 1 includes a core portion 2 and a braided shield layer 3 that covers the outer periphery 22 of the core portion 2.
  • the core part 2 is composed of a single covered electric wire 21 having a conductor 211 and an insulating material 212 covered around the conductor 211.
  • the braided shield layer 3 is configured by braiding a plurality of strands 31.
  • the element wire 31 has an Al wire as a base material 311, and has a plating film 312 made of Sn that is less oxidized than Al on the surface.
  • the configuration of the shielded electric wire 1 will be described in detail.
  • the covered electric wire 21 is made by forming a Cu wire having a cross-sectional area of 3 mm 2 as a conductor 211 and extruding an insulating material 212 around the conductor 211.
  • the braided shield layer 3 is formed in a unit of a bundle of strands 32 in which three strands 31 are arranged side by side.
  • the braided shield layer 3 of this example has 24 pairs of strands 32.
  • each strand bundle 32 is knitted while being wound around the outer periphery 22 of the core portion 2 in a spiral shape.
  • the twisting pitch of the strand bundle 32 that is, the distance that the strand bundle 32 travels in the longitudinal direction of the core portion 2 when the strand bundle 32 makes a spiral turn around the outer periphery 22 of the core portion 2 is 20 mm.
  • the strand 31 has an Al wire with a diameter of 0.18 mm as a base material 311 and has a plating film 312 made of Sn on the surface.
  • an intermediate film 313 made of Ni formed by plating is provided between the base material 311 and the plating film 312.
  • the thickness of the plating film 312 in the shielded electric wire 1 of this example is 1 ⁇ m.
  • the plating film 312 and the intermediate film 313 are formed by a conventionally known method.
  • the shielding performance was evaluated using the shielded electric wire 1 configured as described above.
  • the evaluation method will be described below.
  • the shielded electric wire 1 was placed in a straight line, one end 11 thereof was connected to the output terminal 41 of the network analyzer 4, and the other end 12 was connected to the 50 ⁇ termination resistor 5. Further, the noise induction wire 6 was arranged in parallel with the shielded electric wire 1, and one end 61 thereof was connected to the input terminal 42 of the network analyzer 4. The other end 62 of the noise induction wire 6 was opened.
  • the AC signal generated from the network analyzer 4 was input to the noise induction wire 6 and the frequency of the AC signal was swept between 300 kHz and 3 GHz.
  • inductive noise derived from the AC signal was generated in the shielded electric wire 1, and the intensity of the reflected signal reflected from the shielded electric wire 1 toward the output terminal 41 was measured by the network analyzer 4.
  • the intensity ratio of the reflected signal with respect to the AC signal was calculated using the intensity of the obtained reflected signal and the intensity of the AC signal input to the noise induction line 6, and the value was used as the amount of induced noise.
  • a comparative electric wire consisting only of the core portion 2 without the braided shield layer 3 was prepared separately, and the amount of induction noise of the comparative electric wire was calculated by the same method as described above. And the difference of the induction noise amount of the shielded electric wire 1 and the induction noise amount of the comparison electric wire obtained when the frequency of the AC signal was 10 MHz was obtained. As a result, the shielded electric wire 1 was able to reduce the amount of induced noise for a 10 MHz AC signal by 50 dB compared to the comparative electric wire.
  • Example 2 This example is an example of the shielded electric wire 1 using the wire 31 in which the thickness of the plating film 312 is changed from 1 ⁇ m to 2 ⁇ m.
  • the shielded electric wire 1 was produced in the same manner as in Example 1 except that the film thickness of the plating film 312 was changed.
  • the shielded electric wire 1 of this example was able to reduce the amount of induced noise with respect to an AC signal of 10 MHz by 51 dB compared to the comparative electric wire.
  • This example is an example of the shielded electric wire 1 using an annealed copper wire having a diameter of 0.18 mm.
  • a shielded electric wire 1 was produced in the same manner as in Example 1 except that the annealed copper wire was used as the element wire 31.
  • the shielded electric wire 1 of this example was able to reduce the amount of induction noise for an AC signal of 10 MHz by 55 dB compared to the comparative electric wire.
  • This example is an example of the shielded electric wire 1 using an Al wire having a diameter of 0.18 mm. That is, the shielded electric wire 1 of the present example includes the braided shield layer 3 having the base wire 311 itself in a state before the plating film 312 is formed on the surface as the element wire 31. Others are the same as in the first embodiment.
  • the shielded electric wire 1 of this example was able to reduce the amount of induced noise for an AC signal of 10 MHz by 38 dB compared to the comparative electric wire.
  • the shielded wire 1 using the wire 31 having the plated film 312 made of Sn on the surface is a comparative wire that does not have the braided shield layer 3.
  • the amount of induced noise for an AC signal of 10 MHz could be reduced by 50 to 51 dB.
  • This value is equivalent to the shielded electric wire 1 (Comparative Example 1) using a conventional annealed copper wire, and it can be seen that the shielded electric wires 1 of Example 1 and Example 2 have excellent shielding performance in a high frequency region. .
  • Comparative Example 2 when an Al wire that does not form the plating film 312 on the surface is used as the element wire 31, compared to a comparative electric wire that does not have the braided shield layer 3, The amount of induced noise is reduced by 38 dB. From the above results, the shielded electric wire 1 of Comparative Example 2 using the Al wire without forming the plating film 312 on the surface as the element wire 31 is inferior in shielding performance in the high frequency region as compared with the shielded electric wires 1 of Examples 1 and 2. I understand that.
  • Example 1 and Example 2 showed the example of the single core shielded electric wire 1 which has the one covered electric wire 21 in the core part 2, the covered electric wire 21 of the core part 2 is suitably used according to a use. You may increase the number.
  • FIG. 5 shows an example of a two-core shielded electric wire 102 having two covered electric wires 21.
  • FIG. 6 shows an example of a three-core shielded electric wire 103 having three covered electric wires 21.
  • FIG. 7 shows an example of a four-core shielded electric wire 104 having four covered electric wires 21.
  • the same reference numerals as those used in FIGS. 1 and 2 represent the same components as in the first embodiment.
  • Example 1 and Example 2 showed the example of the shielded electric wire 1 with the braided shield layer 3 exposed on the surface, the sheath covering the outer periphery 33 (see FIG. 2) of the braided shield layer 3 as necessary.
  • a part may be provided.
  • a sheath part can be comprised from the material which has insulation, such as a crosslinked polyethylene resin and a crosslinked vinyl chloride resin, for example.

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  • Metallurgy (AREA)
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Abstract

A shielded wire (1) has a core portion (2), and a braided shield layer (3) which covers the outer periphery of the core portion (2). The core portion (2) is provided with a coated wire (21) which has a conductor (211) and insulating material (212) that covers the perimeter of the conductor (211). The braided shield layer (3) is configured so that a plurality of strands (31) are woven thereinto. The strands (31) each comprise Al wire or Al alloy wire as base material (311), and each have, on the surface thereof, a plating coating (312) comprising a metal that is less susceptible to oxidation than Al.

Description

シールド電線Shielded wire
 本発明は、シールド電線に関する。 The present invention relates to a shielded electric wire.
 例えば自動車や電気機器等において、電磁ノイズ対策が必要な箇所には、シールド電線が用いられている。シールド電線は、電気信号等を伝達するコア部と、コア部の外周を被覆するシールド層とを有しており、外部からコア部への電磁ノイズの侵入や、コア部から外部への電磁ノイズの放射をシールド層により抑制することができるよう構成されている。シールド層としては、例えば、金属素線を編み込んで形成した編組シールド層が知られている。 For example, shielded wires are used in places where countermeasures against electromagnetic noise are required in automobiles and electrical equipment. The shielded electric wire has a core part that transmits electrical signals and the like, and a shield layer that covers the outer periphery of the core part. Intrusion of electromagnetic noise from the outside to the core part, and electromagnetic noise from the core part to the outside The radiation can be suppressed by the shield layer. As the shield layer, for example, a braided shield layer formed by braiding metal strands is known.
 従来、シールド層に用いられる金属素線には、導電性や加工性の観点から、CuやCu合金よりなる線材が用いられている。近年では、シールド電線全体を軽量化するため、より軽量な素線よりなるシールド層が望まれている。例えば特許文献1には、耐熱性繊維の外周に金属膜を形成してなる金属皮膜繊維を編組加工して構成されるシールド層を有するシールド電線が記載されている。 Conventionally, a wire made of Cu or a Cu alloy has been used as a metal wire used for a shield layer from the viewpoint of conductivity and workability. In recent years, in order to reduce the weight of the entire shielded electric wire, a shield layer made of a lighter strand is desired. For example, Patent Document 1 describes a shielded electric wire having a shield layer configured by braiding a metal-coated fiber formed by forming a metal film on the outer periphery of a heat-resistant fiber.
特開2013-110053号公報JP 2013-110053 A
 しかしながら、特許文献1のように金属被覆繊維を用いたシールド層は、アース線との接続に当たって接続不良を起こしやすいという問題がある。 However, the shield layer using the metal-coated fiber as in Patent Document 1 has a problem that it is liable to cause a connection failure when connected to the ground wire.
 一方、Cu(銅)に比べて軽量かつ安価である、Al(アルミニウム)やAl合金よりなる素線をシールド層に採用することが検討されている。AlやAl合金より構成された素線は、アース線との電気的な接続が容易であるため、上述のような接続不良の問題を回避することができる。しかしながら、Alは比較的酸化されやすい性質を有するため、不導体であるAl23の皮膜が表面に不可避的に形成される。このAl23皮膜の存在により、AlやAl合金より構成された素線は、表皮効果の影響が顕著となる高周波領域において交流抵抗が大きくなる。それ故、高周波領域の電磁ノイズに対するシールド性能が低下するという問題がある。 On the other hand, it has been studied to employ a strand made of Al (aluminum) or an Al alloy, which is lighter and cheaper than Cu (copper), for the shield layer. Since the element wire made of Al or Al alloy is easily electrically connected to the ground wire, the above-described problem of poor connection can be avoided. However, since Al has the property of being relatively easily oxidized, a film of Al 2 O 3 which is a nonconductor is inevitably formed on the surface. Due to the presence of the Al 2 O 3 film, the wire composed of Al or Al alloy has a high AC resistance in a high frequency region where the influence of the skin effect becomes significant. Therefore, there is a problem that the shielding performance against electromagnetic noise in the high frequency region is lowered.
 本発明は、かかる背景に鑑みてなされたものであり、安価かつ軽量であり、優れたシールド性能を有するシールド電線を提供しようとするものである。 The present invention has been made in view of such a background, and intends to provide a shielded electric wire that is inexpensive and lightweight and has excellent shielding performance.
 本発明の一態様は、導体と該導体の周囲に被覆された絶縁材とを有する被覆電線を備えたコア部と、
 複数の素線を編み込んでなり、上記コア部の外周を覆う編組シールド層とを有し、
 上記素線は、Al線またはAl合金線を基材として構成され、Alよりも酸化されにくい金属からなるめっき膜を表面に有していることを特徴とするシールド電線にある。
One aspect of the present invention is a core portion including a covered electric wire having a conductor and an insulating material coated around the conductor;
A braided shield layer covering the outer periphery of the core part, comprising a plurality of strands knitted,
The element wire is a shielded electric wire characterized in that an Al wire or an Al alloy wire is used as a base material, and a plating film made of a metal that is harder to be oxidized than Al is provided on the surface.
 上記シールド電線は、複数の素線を編み込んでなり、上記コア部の外周を覆う上記編組シールド層を有している。また、上記素線は、Al線またはAl合金線を基材として構成され、Alよりも酸化されにくい金属からなるめっき膜を表面に有している。そのため、上記基材の表面にAl23皮膜が形成されることを防止できる。また、上記めっき膜がAlよりも酸化されにくい金属から構成されているため、不導体である酸化皮膜が上記素線の表面に形成されることを抑制できる。これらの結果、上記素線は、めっき膜を有しない従来の素線に比べて高周波領域における交流抵抗を低減することができる。そして、上記編組シールド層は、上記素線を用いることにより高周波領域の電磁ノイズに対するシールド性能が向上し、優れたシールド性能を有する。 The shielded electric wire has a braided shield layer formed by braiding a plurality of strands and covering the outer periphery of the core portion. Moreover, the said strand is comprised by using Al wire or Al alloy wire as a base material, and has the plating film which consists of a metal which is hard to oxidize than Al on the surface. Therefore, it is possible to prevent the Al 2 O 3 film from being formed on the surface of the base material. Moreover, since the said plating film is comprised from the metal which is harder to oxidize than Al, it can suppress that the oxide film which is a nonconductor is formed on the surface of the said strand. As a result, the element wire can reduce the AC resistance in the high frequency region as compared with the conventional element wire not having a plating film. And the said braided shield layer improves the shielding performance with respect to the electromagnetic noise of a high frequency area | region by using the said strand, and has the outstanding shielding performance.
 また、上記素線は、上記基材にAl線またはAl合金線を用いているため、CuやCu合金よりなる素線に比べて安価かつ軽量である。 Moreover, since the said strand uses the Al wire or Al alloy wire for the said base material, it is cheap and lightweight compared with the strand which consists of Cu or Cu alloy.
 以上のように、上記シールド電線は、安価かつ軽量であり、優れたシールド性能を有する。 As described above, the shielded electric wire is inexpensive and lightweight and has excellent shielding performance.
実施例1における、シールド電線の側面図。The side view of the shielded electric wire in Example 1. FIG. 図1のII-II線矢視断面図。FIG. 2 is a cross-sectional view taken along line II-II in FIG. 1. 実施例1における、素線の断面図。Sectional drawing of the strand in Example 1. FIG. 実施例1における、誘導ノイズ量の測定の説明図。FIG. 3 is an explanatory diagram of measurement of an induced noise amount in the first embodiment. 2本の被覆電線を備えたコア部を有する2芯シールド電線の、図2に相当する断面図。Sectional drawing equivalent to FIG. 2 of the 2-core shielded electric wire which has a core part provided with two covered electric wires. 3本の被覆電線を備えたコア部を有する3芯シールド電線の、図2に相当する断面図。Sectional drawing equivalent to FIG. 2 of the 3 core shielded electric wire which has a core part provided with the three covered electric wires. 4本の被覆電線を備えたコア部を有する4芯シールド電線の、図2に相当する断面図。Sectional drawing equivalent to FIG. 2 of the 4-core shielded electric wire which has a core part provided with four covered electric wires.
 上記シールド電線は、動作用電力等の比較的大きい電流を伝達する電力線として構成されていても良く、制御信号等の比較的小さい電流を伝達する信号線として構成されていても良い。また、上記シールド電線は、1本の上記被覆電線を有する単芯シールド電線として構成されていても良く、2本以上の上記被覆電線を有する多芯シールド電線として構成されていても良い。 The shielded wire may be configured as a power line that transmits a relatively large current such as operating power, or may be configured as a signal line that transmits a relatively small current such as a control signal. Moreover, the said shielded electric wire may be comprised as a single core shielded electric wire which has one said covered electric wire, and may be comprised as a multi-core shielded electric wire which has two or more said covered electric wires.
 上記被覆電線に用いられる導体としては、例えば、Cu線、Cu合金線、Sn(スズ)めっきCu合金線、Al線及びAl合金線等の、優れた電気伝導性を有する金属線を用いることができる。また、上記導体は、1本の上記金属線から構成されていても良く、多数の上記金属線が撚り合わされた撚線から構成されていても良い。 As a conductor used for the said covered electric wire, it is using the metal wire which has the outstanding electrical conductivity, such as Cu wire, Cu alloy wire, Sn (tin) plating Cu alloy wire, Al wire, and Al alloy wire, for example. it can. The conductor may be composed of a single metal wire, or may be composed of a stranded wire in which a large number of the metal wires are twisted together.
 また、上記被覆電線に用いられる絶縁材としては、電線用の絶縁材として従来公知の材料を用いることができる。絶縁性や製造性等の観点からは、上記絶縁材として、架橋ポリエチレン系樹脂や架橋ポリ塩化ビニル樹脂が用いられることが多い。 In addition, as the insulating material used for the covered electric wire, a conventionally known material can be used as the insulating material for the electric wire. From the viewpoints of insulation and manufacturability, a crosslinked polyethylene resin or a crosslinked polyvinyl chloride resin is often used as the insulating material.
 上記編組シールド層を構成する上記素線は、Al線またはAl合金線を基材として構成され、Alよりも酸化されにくい金属からなるめっき膜を表面に有している。上記めっき膜に用いられる金属としては、例えば、Au(金)、Ag(銀)、Cu(銅)、Ni(ニッケル)、Sn(スズ)等の、Alよりも標準酸化還元電位が高い金属を用いることができる。コスト及び導電性の観点から、上記めっき膜はSnから構成されていることが好ましい。 The element wire constituting the braided shield layer is composed of an Al wire or an Al alloy wire as a base material, and has a plating film made of a metal that is harder to be oxidized than Al on the surface. Examples of the metal used for the plating film include metals having a higher standard oxidation-reduction potential than Al, such as Au (gold), Ag (silver), Cu (copper), Ni (nickel), and Sn (tin). Can be used. From the viewpoint of cost and conductivity, the plating film is preferably made of Sn.
 また、上記めっき膜の厚みは1μm以上であることが好ましい。この場合には、高周波領域におけるシールド性能を十分に向上させることができる。上記めっき膜の厚みが1μm未満の場合には、用途によってはめっき膜の耐久性が不十分となるおそれがある。すなわち、例えば自動車用ワイヤーハーネスとして用いる場合は、振動や屈曲によって上記めっき膜の摩耗等が発生し、上記めっき膜が剥がれ易くなるおそれがある。上記めっき膜が上記基材から剥がれると、上記基材の表面にAl23皮膜が形成され、シールド性能の低下を招く。上記めっき膜の耐久性を高め、上述のような問題を抑制する観点から、上記めっき膜の厚みを1μm以上とすることが好ましい。 Moreover, it is preferable that the thickness of the said plating film is 1 micrometer or more. In this case, the shielding performance in the high frequency region can be sufficiently improved. When the thickness of the plating film is less than 1 μm, the durability of the plating film may be insufficient depending on the application. That is, for example, when used as an automobile wire harness, the plating film may be worn away by vibration or bending, and the plating film may be easily peeled off. When the plating film is peeled off from the base material, an Al 2 O 3 film is formed on the surface of the base material, resulting in a decrease in shielding performance. From the viewpoint of enhancing the durability of the plating film and suppressing the above-described problems, the thickness of the plating film is preferably 1 μm or more.
 また、上記めっき膜と上記基材との間に、必要に応じて中間膜を設けてもよい。中間膜としては、例えば、上記めっき膜と上記基材との密着性を向上させる作用を有するものを用いることができる。例えば、中間膜としては、Znめっき膜やNiめっき膜等を用いることができる。 Further, an intermediate film may be provided between the plating film and the base material as necessary. As an intermediate film, what has the effect | action which improves the adhesiveness of the said plating film and the said base material can be used, for example. For example, a Zn plating film, a Ni plating film, or the like can be used as the intermediate film.
 上記シールド電線は、上述の構成を有することにより、表面にめっき膜を有さない素線を用いたシールド電線に比べて、1MHz以上の周波数領域におけるシールド特性を向上させることができる。それ故、上記シールド電線は、1MHz以上の周波数領域における電磁ノイズを低減する必要がある用途に好適である。このような用途としては、例えば、自動車用ワイヤーハーネス等がある。 The shielded electric wire having the above-described configuration can improve the shielding characteristics in a frequency region of 1 MHz or more as compared with a shielded electric wire using a bare wire having no plating film on the surface. Therefore, the shielded electric wire is suitable for applications that need to reduce electromagnetic noise in a frequency region of 1 MHz or higher. Such applications include, for example, automobile wire harnesses.
(実施例1)
 上記シールド電線の実施例を、図1~図4を用いて説明する。図1及び図2に示すように、シールド電線1は、コア部2と、コア部2の外周22を覆う編組シールド層3とを有している。コア部2は、導体211と、導体211の周囲に被覆された絶縁材212とを有する1本の被覆電線21より構成されている。編組シールド層3は、複数の素線31を編み込んで構成されている。図2及び図3に示すように、素線31は、Al線を基材311として構成され、Alよりも酸化されにくいSnからなるめっき膜312を表面に有している。以下、シールド電線1の構成を詳説する。
Example 1
An example of the shielded wire will be described with reference to FIGS. As shown in FIGS. 1 and 2, the shielded electric wire 1 includes a core portion 2 and a braided shield layer 3 that covers the outer periphery 22 of the core portion 2. The core part 2 is composed of a single covered electric wire 21 having a conductor 211 and an insulating material 212 covered around the conductor 211. The braided shield layer 3 is configured by braiding a plurality of strands 31. As shown in FIGS. 2 and 3, the element wire 31 has an Al wire as a base material 311, and has a plating film 312 made of Sn that is less oxidized than Al on the surface. Hereinafter, the configuration of the shielded electric wire 1 will be described in detail.
 被覆電線21は、断面積3mm2のCu線を導体211とし、その周囲に絶縁材212を押出成形して作製されている。 The covered electric wire 21 is made by forming a Cu wire having a cross-sectional area of 3 mm 2 as a conductor 211 and extruding an insulating material 212 around the conductor 211.
 編組シールド層3は、図2に示すように、3本の素線31を互いに並べてなる素線束32を単位として形成されている。本例の編組シールド層3は、24組の素線束32を有している。図には示さないが、各々の素線束32は、コア部2の外周22をらせん状に巻き回されながら編み込まれている。本例においては、素線束32の撚りピッチ、すなわち素線束32がコア部2の外周22をらせん状に一回転したときにコア部2の長手方向に進む距離は20mmである。 As shown in FIG. 2, the braided shield layer 3 is formed in a unit of a bundle of strands 32 in which three strands 31 are arranged side by side. The braided shield layer 3 of this example has 24 pairs of strands 32. Although not shown in the drawing, each strand bundle 32 is knitted while being wound around the outer periphery 22 of the core portion 2 in a spiral shape. In this example, the twisting pitch of the strand bundle 32, that is, the distance that the strand bundle 32 travels in the longitudinal direction of the core portion 2 when the strand bundle 32 makes a spiral turn around the outer periphery 22 of the core portion 2 is 20 mm.
 図3に示すように、素線31は、直径0.18mmのAl線を基材311とし、表面にSnよりなるめっき膜312を有している。また、基材311とめっき膜312との間には、めっき処理により形成されたNiよりなる中間膜313が設けられている。本例のシールド電線1におけるめっき膜312の厚みは1μmである。なお、めっき膜312及び中間膜313は、従来公知の方法により形成されている。 As shown in FIG. 3, the strand 31 has an Al wire with a diameter of 0.18 mm as a base material 311 and has a plating film 312 made of Sn on the surface. In addition, an intermediate film 313 made of Ni formed by plating is provided between the base material 311 and the plating film 312. The thickness of the plating film 312 in the shielded electric wire 1 of this example is 1 μm. The plating film 312 and the intermediate film 313 are formed by a conventionally known method.
 本例においては、上述のように構成したシールド電線1を用いて、シールド性能の評価を行った。以下に、評価方法を説明する。 In this example, the shielding performance was evaluated using the shielded electric wire 1 configured as described above. The evaluation method will be described below.
<シールド性能評価>
 図4に示すように、シールド電線1をまっすぐに伸ばして配置し、その一端11をネットワークアナライザ4の出力端子41に接続すると共に、他端12を50Ωの終端抵抗5に接続した。また、シールド電線1と平行にノイズ誘導線6を配置し、その一端61をネットワークアナライザ4の入力端子42に接続した。なお、ノイズ誘導線6の他端62は開放とした。
<Shield performance evaluation>
As shown in FIG. 4, the shielded electric wire 1 was placed in a straight line, one end 11 thereof was connected to the output terminal 41 of the network analyzer 4, and the other end 12 was connected to the 50 Ω termination resistor 5. Further, the noise induction wire 6 was arranged in parallel with the shielded electric wire 1, and one end 61 thereof was connected to the input terminal 42 of the network analyzer 4. The other end 62 of the noise induction wire 6 was opened.
 次いで、ネットワークアナライザ4から発生させた交流信号をノイズ誘導線6に入力し、交流信号の周波数を300kHz~3GHzの間で掃引した。これにより、交流信号に由来する誘導ノイズをシールド電線1に発生させると共に、シールド電線1から出力端子41側に反射した反射信号の強度をネットワークアナライザ4により測定した。得られた反射信号の強度及びノイズ誘導線6に入力した交流信号の強度を用いて交流信号に対する反射信号の強度比を算出し、その値を誘導ノイズ量とした。 Next, the AC signal generated from the network analyzer 4 was input to the noise induction wire 6 and the frequency of the AC signal was swept between 300 kHz and 3 GHz. Thereby, inductive noise derived from the AC signal was generated in the shielded electric wire 1, and the intensity of the reflected signal reflected from the shielded electric wire 1 toward the output terminal 41 was measured by the network analyzer 4. The intensity ratio of the reflected signal with respect to the AC signal was calculated using the intensity of the obtained reflected signal and the intensity of the AC signal input to the noise induction line 6, and the value was used as the amount of induced noise.
 また、編組シールド層3を設けず、コア部2のみからなる比較用電線を別途準備し、上記と同様の方法により比較用電線の誘導ノイズ量を算出した。そして、交流信号の周波数が10MHzであるときに得られた、シールド電線1の誘導ノイズ量と比較用電線の誘導ノイズ量との差を求めた。以上の結果、シールド電線1は、比較用電線に比べて、10MHzの交流信号に対する誘導ノイズ量を50dB低減することができた。 Further, a comparative electric wire consisting only of the core portion 2 without the braided shield layer 3 was prepared separately, and the amount of induction noise of the comparative electric wire was calculated by the same method as described above. And the difference of the induction noise amount of the shielded electric wire 1 and the induction noise amount of the comparison electric wire obtained when the frequency of the AC signal was 10 MHz was obtained. As a result, the shielded electric wire 1 was able to reduce the amount of induced noise for a 10 MHz AC signal by 50 dB compared to the comparative electric wire.
(実施例2)
 本例は、めっき膜312の膜厚を1μmから2μmに変更した素線31を用いたシールド電線1の例である。本例においては、めっき膜312の膜厚を変更した以外は、実施例1と同様にシールド電線1を作製した。
(Example 2)
This example is an example of the shielded electric wire 1 using the wire 31 in which the thickness of the plating film 312 is changed from 1 μm to 2 μm. In this example, the shielded electric wire 1 was produced in the same manner as in Example 1 except that the film thickness of the plating film 312 was changed.
 また、実施例1と同様に、シールド電線1及び比較用電線を用いて、誘導ノイズ量の測定を行い、両者の差を求めた。以上の結果、本例のシールド電線1は、比較用電線に比べて、10MHzの交流信号に対する誘導ノイズ量を51dB低減することができた。 Further, similarly to Example 1, the amount of induction noise was measured using the shielded electric wire 1 and the comparative electric wire, and the difference between the two was determined. As a result, the shielded electric wire 1 of this example was able to reduce the amount of induced noise with respect to an AC signal of 10 MHz by 51 dB compared to the comparative electric wire.
(比較例1)
 本例は、直径0.18mmの軟銅線を用いたシールド電線1の例である。本例においては、上記軟銅線を素線31として用いた以外は、実施例1と同様にシールド電線1を作製した。
(Comparative Example 1)
This example is an example of the shielded electric wire 1 using an annealed copper wire having a diameter of 0.18 mm. In this example, a shielded electric wire 1 was produced in the same manner as in Example 1 except that the annealed copper wire was used as the element wire 31.
 また、実施例1と同様に、シールド電線1及び比較用電線を用いて、誘導ノイズ量の測定を行い、両者の差を求めた。以上の結果、本例のシールド電線1は、比較用電線に比べて、10MHzの交流信号に対する誘導ノイズ量を55dB低減することができた。 Further, similarly to Example 1, the amount of induction noise was measured using the shielded electric wire 1 and the comparative electric wire, and the difference between the two was determined. As a result, the shielded electric wire 1 of this example was able to reduce the amount of induction noise for an AC signal of 10 MHz by 55 dB compared to the comparative electric wire.
(比較例2)
 本例は、直径0.18mmのAl線を用いたシールド電線1の例である。すなわち、本例のシールド電線1は、表面にめっき膜312が形成される前の状態の基材311そのものを素線31とする編組シールド層3を有している。その他は実施例1と同様である。
(Comparative Example 2)
This example is an example of the shielded electric wire 1 using an Al wire having a diameter of 0.18 mm. That is, the shielded electric wire 1 of the present example includes the braided shield layer 3 having the base wire 311 itself in a state before the plating film 312 is formed on the surface as the element wire 31. Others are the same as in the first embodiment.
 また、実施例1と同様に、シールド電線1及び比較用電線を用いて、誘導ノイズ量の測定を行い、両者の差を求めた。以上の結果、本例のシールド電線1は、比較用電線に比べて、10MHzの交流信号に対する誘導ノイズ量を38dB低減することができた。 Further, similarly to Example 1, the amount of induction noise was measured using the shielded electric wire 1 and the comparative electric wire, and the difference between the two was determined. As a result, the shielded electric wire 1 of this example was able to reduce the amount of induced noise for an AC signal of 10 MHz by 38 dB compared to the comparative electric wire.
 実施例1~2及び比較例1~2より知られるように、表面にSnよりなるめっき膜312を有する素線31を用いたシールド電線1は、編組シールド層3を有さない比較用電線に比べて、10MHzの交流信号に対する誘導ノイズ量を50~51dB低減することができた。この値は、従来の軟銅線を用いたシールド電線1(比較例1)と同等の値であり、実施例1及び実施例2のシールド電線1が高周波領域において優れたシールド性能を有することがわかる。 As is known from Examples 1 and 2 and Comparative Examples 1 and 2, the shielded wire 1 using the wire 31 having the plated film 312 made of Sn on the surface is a comparative wire that does not have the braided shield layer 3. In comparison, the amount of induced noise for an AC signal of 10 MHz could be reduced by 50 to 51 dB. This value is equivalent to the shielded electric wire 1 (Comparative Example 1) using a conventional annealed copper wire, and it can be seen that the shielded electric wires 1 of Example 1 and Example 2 have excellent shielding performance in a high frequency region. .
 一方、比較例2のように、表面にめっき膜312を形成しないAl線を素線31として用いた場合には、編組シールド層3を有さない比較用電線に比べて、10MHzの交流信号に対する誘導ノイズ量が38dB小さくなった。以上の結果から、表面にめっき膜312を形成しないAl線を素線31として用いた比較例2のシールド電線1は、実施例1~2のシールド電線1に比べて高周波領域におけるシールド性能が劣ることがわかる。 On the other hand, as in Comparative Example 2, when an Al wire that does not form the plating film 312 on the surface is used as the element wire 31, compared to a comparative electric wire that does not have the braided shield layer 3, The amount of induced noise is reduced by 38 dB. From the above results, the shielded electric wire 1 of Comparative Example 2 using the Al wire without forming the plating film 312 on the surface as the element wire 31 is inferior in shielding performance in the high frequency region as compared with the shielded electric wires 1 of Examples 1 and 2. I understand that.
 なお、実施例1及び実施例2には、コア部2に1本の被覆電線21を有する単芯シールド電線1の例を示したが、コア部2の被覆電線21は、用途に応じて適宜数を増やしても良い。例えば図5には、2本の被覆電線21を有する2芯シールド電線102の例を示す。また、図6には、3本の被覆電線21を有する3芯シールド電線103の例を示す。また、図7には、4本の被覆電線21を有する4芯シールド電線104の例を示す。なお、図5~図7において用いた符号のうち、図1及び図2において用いた符号と同一の符号は、実施例1と同様の構成要素等を表す。 In addition, although Example 1 and Example 2 showed the example of the single core shielded electric wire 1 which has the one covered electric wire 21 in the core part 2, the covered electric wire 21 of the core part 2 is suitably used according to a use. You may increase the number. For example, FIG. 5 shows an example of a two-core shielded electric wire 102 having two covered electric wires 21. FIG. 6 shows an example of a three-core shielded electric wire 103 having three covered electric wires 21. FIG. 7 shows an example of a four-core shielded electric wire 104 having four covered electric wires 21. Of the reference numerals used in FIGS. 5 to 7, the same reference numerals as those used in FIGS. 1 and 2 represent the same components as in the first embodiment.
 また、実施例1及び実施例2には編組シールド層3が表面に露出したシールド電線1の例を示したが、必要に応じて編組シールド層3の外周33(図2参照)を被覆するシース部を設けてもよい。シース部は、例えば、架橋ポリエチレン樹脂や架橋塩化ビニル樹脂等の、絶縁性を有する材料より構成することができる。 Moreover, although Example 1 and Example 2 showed the example of the shielded electric wire 1 with the braided shield layer 3 exposed on the surface, the sheath covering the outer periphery 33 (see FIG. 2) of the braided shield layer 3 as necessary. A part may be provided. A sheath part can be comprised from the material which has insulation, such as a crosslinked polyethylene resin and a crosslinked vinyl chloride resin, for example.

Claims (4)

  1.  導体と該導体の周囲に被覆された絶縁材とを有する被覆電線を備えたコア部と、
     複数の素線を編み込んでなり、上記コア部の外周を覆う編組シールド層とを有し、
     上記素線は、Al線またはAl合金線を基材として構成され、Alよりも酸化されにくい金属からなるめっき膜を表面に有していることを特徴とするシールド電線。
    A core portion including a covered electric wire having a conductor and an insulating material coated around the conductor;
    A braided shield layer covering the outer periphery of the core part, comprising a plurality of strands knitted,
    The above-mentioned elemental wire is constituted by using an Al wire or an Al alloy wire as a base material, and has a plating film made of a metal that is harder to be oxidized than Al on the surface.
  2.  上記めっき膜は、Snから構成されていることを特徴とする請求項1に記載のシールド電線。 The shielded wire according to claim 1, wherein the plated film is made of Sn.
  3.  上記めっき膜の厚みは1μm以上であることを特徴とする請求項1または2に記載のシールド電線。 The shielded wire according to claim 1 or 2, wherein the plating film has a thickness of 1 µm or more.
  4.  1MHz以上の周波数領域における電磁ノイズを低減するために用いられることを特徴とする請求項1~3のいずれか1項に記載のシールド電線。 The shielded electric wire according to any one of claims 1 to 3, wherein the shielded electric wire is used for reducing electromagnetic noise in a frequency region of 1 MHz or more.
PCT/JP2015/051381 2014-02-06 2015-01-20 Shielded wire WO2015118942A1 (en)

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CN106205792B (en) * 2016-06-24 2017-08-15 李星明 A kind of armouring aluminium alloy power cable
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Citations (2)

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Publication number Priority date Publication date Assignee Title
JPH08321220A (en) * 1995-05-24 1996-12-03 Furukawa Electric Co Ltd:The Multi-pair cable signal transmitting path
JP2003151380A (en) * 2001-11-09 2003-05-23 Mitsubishi Cable Ind Ltd Coaxial cable

Patent Citations (2)

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Publication number Priority date Publication date Assignee Title
JPH08321220A (en) * 1995-05-24 1996-12-03 Furukawa Electric Co Ltd:The Multi-pair cable signal transmitting path
JP2003151380A (en) * 2001-11-09 2003-05-23 Mitsubishi Cable Ind Ltd Coaxial cable

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