WO2015108491A1 - Système et procédé pour améliorer l'efficacité d'élimination du co2 d'un courant de gaz naturel - Google Patents

Système et procédé pour améliorer l'efficacité d'élimination du co2 d'un courant de gaz naturel Download PDF

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Publication number
WO2015108491A1
WO2015108491A1 PCT/TH2014/000001 TH2014000001W WO2015108491A1 WO 2015108491 A1 WO2015108491 A1 WO 2015108491A1 TH 2014000001 W TH2014000001 W TH 2014000001W WO 2015108491 A1 WO2015108491 A1 WO 2015108491A1
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WO
WIPO (PCT)
Prior art keywords
membrane
separation unit
separation
gas
hydrocarbon gas
Prior art date
Application number
PCT/TH2014/000001
Other languages
English (en)
Inventor
Tassawuh POJANAVARAPHAN
Sakarin KHAISRI
Supakorn ATCHARIYAWUT
Kanokrot PHALAKORNKUL
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Ptt Public Company Limited
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Publication date
Application filed by Ptt Public Company Limited filed Critical Ptt Public Company Limited
Priority to PCT/TH2014/000001 priority Critical patent/WO2015108491A1/fr
Priority to SG11201601231UA priority patent/SG11201601231UA/en
Priority to AU2014377721A priority patent/AU2014377721B2/en
Publication of WO2015108491A1 publication Critical patent/WO2015108491A1/fr

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/22—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion
    • B01D53/225—Multiple stage diffusion
    • B01D53/226—Multiple stage diffusion in serial connexion
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/22—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion
    • B01D53/229—Integrated processes (Diffusion and at least one other process, e.g. adsorption, absorption)
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L3/00—Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
    • C10L3/06—Natural gas; Synthetic natural gas obtained by processes not covered by C10G, C10K3/02 or C10K3/04
    • C10L3/10—Working-up natural gas or synthetic natural gas
    • C10L3/101—Removal of contaminants
    • C10L3/102—Removal of contaminants of acid contaminants
    • C10L3/104—Carbon dioxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2256/00—Main component in the product gas stream after treatment
    • B01D2256/24—Hydrocarbons
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/50—Carbon oxides
    • B01D2257/504—Carbon dioxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/70—Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
    • B01D2257/702—Hydrocarbons
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/80—Water
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2325/00—Details relating to properties of membranes
    • B01D2325/38—Hydrophobic membranes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/002—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by condensation
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/40—Characteristics of the process deviating from typical ways of processing
    • C10G2300/4043—Limiting CO2 emissions
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2290/00—Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
    • C10L2290/06—Heat exchange, direct or indirect
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2290/00—Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
    • C10L2290/54—Specific separation steps for separating fractions, components or impurities during preparation or upgrading of a fuel
    • C10L2290/542—Adsorption of impurities during preparation or upgrading of a fuel
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2290/00—Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
    • C10L2290/54—Specific separation steps for separating fractions, components or impurities during preparation or upgrading of a fuel
    • C10L2290/547—Filtration for separating fractions, components or impurities during preparation or upgrading of a fuel
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2290/00—Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
    • C10L2290/54—Specific separation steps for separating fractions, components or impurities during preparation or upgrading of a fuel
    • C10L2290/548—Membrane- or permeation-treatment for separating fractions, components or impurities during preparation or upgrading of a fuel
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2290/00—Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
    • C10L2290/56—Specific details of the apparatus for preparation or upgrading of a fuel
    • C10L2290/562—Modular or modular elements containing apparatus
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2290/00—Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
    • C10L2290/58—Control or regulation of the fuel preparation of upgrading process
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2290/00—Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
    • C10L2290/60—Measuring or analysing fractions, components or impurities or process conditions during preparation or upgrading of a fuel
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
    • Y02C20/00—Capture or disposal of greenhouse gases
    • Y02C20/40—Capture or disposal of greenhouse gases of CO2
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry
    • Y02P30/40—Ethylene production

Definitions

  • the present invention relates to a system and a process for enhancing efficiency of
  • CPP Central Processing Platform
  • WHP Wellhead platform
  • the capacity of the CPP was designed based on flow rate, size of gas reservoirs, C0 2 content in feed natural gas and in methane rich product stream which will be forwarded to Onshore Facilities (OF locating at on-shore location, via sub-sea pipeline or other forms/condition of transport, while the purpose of WHP is primarily to provide the suspension point and pressure seals for casing strings.
  • the current natural gas recovery technology involves a separation unit with pressure and temperature control for removing contaminants including sands, water condensate, and other liquid contaminants installed at CPP.
  • CN 102636002 disclosed a low-temperature method for removing C0 2 in natural gas.
  • the method comprising a step of: compressing the natural gas, dehydrating, drying and pre- cooling the natural gas, freezing the natural gas, and freezing the C0 2 into a solid state and attaching so as to remove the C0 2 from the natural gas.
  • the method comprising a refrigeration system, a compressor and a dehydrating and drying tower, a pre-cooling heat exchanger and a freezing heat exchanger, an inlet of the natural gas compressor is used as the inlet of the natural gas and an outlet of the natural gas compressor is communicated with the other end of a heat exchange coil pipe in the pre-cooling heat exchanger through the dehydrating and drying tower; and the other end of the heat exchange coil pipe is communicated with one end of a shell side of the freezing heat exchanger and the other end of the shell side of the freezing heat exchanger is used as a discharging end of the liquefied natural gas.
  • WO2010080752 disclosed a method for recovering a natural gas contaminated with high levels of carbon dioxide.
  • a gas containing methane and carbon dioxide is extracted from a reservoir containing natural gas, where carbon dioxide comprises greater than 40 vol.% of the extracted gas.
  • the extracted gas is scrubbed with a wash effective to produce a washed extracted gas containing less carbon dioxide than the extracted gas and at least 20 vol.% carbon dioxide.
  • the washed extracted gas is oxidized with an oxygen containing gas in the presence of a partial oxidation catalyst to produce an oxidation product gas containing hydrogen, carbon monoxide, and carbon dioxide.
  • the oxidation product gas is then utilized to produce a liquid methanol product.
  • WO2005032702 disclosed a method of separating or concentrating hydrocarbon- containing gas mixtures such as hydrogen from hydrocarbons, carbon dioxide from hydrocarbons, nitrogen from hydrocarbons, and hydrocarbons from one another using a selectively permeable membrane.
  • the method is well suited to separate hydrocarbon- containing mixtures such as those generated by petroleum refining industries, petrochemical industries, natural gas processing, and the like.
  • the membranes exhibit extremely good resistance to plasticization by hydrocarbon components in the gas mixture under practical industrial process conditions.
  • US2006042463 disclosed a method and a system for sweetening a raw natural gas feed stream using a multi-stage membrane separation process, and in embodiments a two-stage membrane separation process.
  • the method and system also include use of a gas turbine which operates with an impure fuel gas stream (such as in the sense of having a relatively high C0 2 and H2S acid gas contaminant content) as derived from a permeate gas stream obtained in at least the second stage of a membrane separation process, or later stages if more than two stages are employed.
  • the gas turbine is coupled with an electrical generator, which generates electrical power that drives a compressor for the second stage (or higher) of the membrane separation process, as well as other process equipment associated therewith, such as air coolers and process pumps.
  • the gas turbine can be coupled mechanically to the compressor employed.
  • the power generated by the turbine generator combination can be exported to a local power grid.
  • the turbine generator is a micro-turbine generator (MTG) which can advantageously be used in applications where space is limited, such as an offshore platform or other oil/gas production facility or on board a floating vessel.
  • JPS6443329 disclosed a method for separating gas employing two types of membranes wherein a mixed gas composed of any of H2, C0 2 and CO gases and a gas of volatile hydrocarbons is allowed to pass through a first-step membrane module and a second- step membrane module through which high boiling-point components in the volatile hydrocarbon gas pass faster than methane. Subsequently, H2, C0 2 and CO is separated from the resulting mixed gas by allowing the gas of H2, C0 2 and CO to pass faster than the volatile hydrocarbon gas components.
  • US2007214957 disclosed an invention relates to gas separation, in particular to separation of C0 2 from C0 2 -rich liquids, particularly from C0 2 absorption liquids used in the removal of C0 2 from off-gases or product flows, such as natural gas or synthesis gas.
  • C0 2 is separated from a C0 2 -rich liquid by a method comprising a step wherein, under elevated pressure, said liquid is contacted with a membrane based on polyacetylene substituted with trimethylsilyl groups such that the pressure across the membrane is at least 1 bar and that at least a part of the C0 2 is transported from the liquid through the membrane.
  • the system for the separation or removal of carbon dioxide comprises an apparatus for a selective separation of carbon dioxide (C0 2 ) from flue gas - typically exhaust gases, syngas or natural gas streams - using one or more so-called C0 2 reverse selective membrane(s) in the first separation unit to enrich a feed gas stream which contains carbon dioxide with C0 2 and by separating other constituents of the gas stream.
  • C0 2 carbon dioxide
  • the feed gas stream is separated in the first separation unit by C02 -reverse-selective separation into a C0 2 -lean gas stream and a C0 2 -enriched gas stream.
  • the C0 2 -enriched gas stream is fed to a second separation unit which is a C0 2 - selective separation unit.
  • the second separation results in a purified C0 2 -rich gas stream and a remaining C0 2 -lean gas stream. Accordingly, an alternative system and process for removal of C0 2 from natural hydrocarbon gas stream is desirable.
  • the invention disclosed a system for enhancing efficiency in removal C0 2 from natural hydrocarbon gas stream.
  • the system predominantly employs membrane separation technique for removal of C0 2 from hydrocarbon gas and liquids.
  • the system comprising a first separation unit installed at a wellhead, such as Wellhead Platform (WHP) and a second separation unit installed at a Central Processing Platform (CPP).
  • WHP Wellhead Platform
  • CPP Central Processing Platform
  • the first separation unit of which is installed at the WHP comprising a sand separator, a heat exchanger, a cooler, a gas/liquid separator, a coalescer, and a first membrane unit.
  • the second separation unit of which is installed at the CPP comprising a separator and coalescer, an adsorbent guard bed, a heater, a particle filter and a second membrane unit.
  • the first separation unit is configured to partially remove C0 2 and other contaminants from hydrocarbon gas and liquid as well as preconditioning the hydrocarbon gas and liquid to attain the properties and characteristics to meet the specification set by the second separation unit located at the CPP in order that the hydrocarbon gas and liquid which has been treated by the first separation unit may be transferred for further processing to the second separation unit and wherein the said hydrocarbon gas and liquid has already attained specific properties and characteristics acceptable for further processing by the second separation unit.
  • the invention disclosed a process for enhancing efficiency in removal of C0 2 from natural hydrocarbon gas stream, in particular those natural hydrocarbon gas stream with high level of C0 2 withdrawn from high C0 2 gas reservoir.
  • the processing comprising a step of: i) withdrawing natural hydrocarbon gas and liquid, ii) feeding the said hydrocarbon gas and liquid obtained in i) to a first separation cycle via a first separation unit located at the wellhead, iii) feeding the treated natural gas stream obtained in ii) to a second separation cycle via a second separation unit located at the CPP.
  • FIG. 1 shows schematic illustration of a system for enhancing efficiency in removal C0 2 from natural hydrocarbon gas stream according to the principle of the present invention
  • FIG. 2 shows diagram representation of a first separation unit and its process flow at the WHP according to the principle of the present invention
  • FIG. 3 shows diagram representation of a second separation unit and its process flow at the CPP according to the principle of the present invention
  • FIG. 4 shows schematic exemplary representation of the membrane unit of the first separation unit of the present invention.
  • FIG. 5 shows schematic representation of removal of C0 2 using a membrane of the membrane unit of the first separation unit of the present invention.
  • the present invention disclosed a system and a process for enhancing efficiency in removal of C0 2 from natural hydrocarbon gas stream.
  • the invention disclosed a system for enhancing efficiency in removal C0 2 from natural hydrocarbon gas stream.
  • the system predominantly employs membrane separation technique for removal of C0 2 from hydrocarbon gas and liquids.
  • the system comprising a first separation unit installed at a wellhead, such as WHP or a sub-sea wellhead and a second separation unit installed at a CPP.
  • the first separation unit installed at the wellhead comprising a sand separator, a heat exchanger, a cooler, a gas/liquid separator, a coalescer, and a first membrane unit.
  • the second separation unit which is installed at the CPP comprising a separator and coalescer, an adsorbent guard bed, a heater, a particle filter and a second membrane unit.
  • the first separation unit is configured to partially remove C0 2 and other contaminants from hydrocarbon gas and liquid as well as pre-conditioning the hydrocarbon gas and liquid to attain the properties and characteristics to meet the specification set by the second separation unit located at the CPP in order that the hydrocarbon gas and liquid which has been treated by the first separation unit may be transferred for further processing to the second separation unit and wherein the said hydrocarbon gas and liquid has already attained specific properties and characteristics acceptable for further processing by the second separation unit.
  • the invention disclosed a process for enhancing efficiency in removal of C0 2 from natural hydrocarbon gas stream, in particular those natural hydrocarbon gas stream with high level of C0 2 withdrawn from high C0 2 gas reservoir.
  • the processing comprising a step of: i) withdrawing natural hydrocarbon gas and liquid, ii) feeding the said hydrocarbon gas and liquid obtained in i) to a first separation cycle via a first separation unit located at the wellhead, iii) feeding the treated natural gas stream obtained in ii) to a second separation cycle via a second separation unit located at the CPP.
  • the invention disclosed a system for enhancing removal of C0 2 from natural hydrocarbon gas stream, in particular, those natural hydrocarbon gas with high C0 2 content withdrawn from gas reservoirs which produce natural hydrocarbon gas with high C0 2 level.
  • the system comprising a first separation unit installed at the wellhead, such as WHP or a sub-sea wellhead and a second separation unit installed at the CPP.
  • the sysm may further comprising an Onshore Facilities configured to receive treated natural gas from the second separation unit at the CPP.
  • FIG. 1 shows schematic illustration of an embodiment of a system 100 for enhancing efficiency in removal C0 2 from natural hydrocarbon gas stream according to the principle of the present invention.
  • the system (100) comprising a Wellhead Platform (WHP) 105, a Central Processing Platform (CPP) 1 10 located at offshore location and an Onshore Facilities (OF) 1 15 locating at on-shore location.
  • WHP 105, the CPP 1 10 and the OF 1 15 are connected via pipeline.
  • the WHP 105 comprising a first separation unit 120 configured to process hydrocarbon gas and liquid with high C0 2 content withdrawn from a gas reservoir or multiple reservoirs and to lower the C0 2 content and other contaminants from the said hydrocarbon gas and liquid prior to delivering the said hydrocarbon gas and liquid with targeted lowered C0 2 content to the CPP 110.
  • the CPP 1 10 comprising a second separation unit 125 configured to receive from the first separation unit 120 natural gas stream of which has been treated to lower C0 2 content and with controlled pressure, temperature and flow rate by the first separation unit 120. More specifically, the first separation unit 120 is configured to lower or remove or partially remove C0 2 from hydrocarbon gas and liquid with high C0 2 content, i.e. the hydrocarbon gas and liquid having the C0 2 content in the range of 70-90 mole% as well as to pre-conditioning the hydrocarbon gas and liquid to meet other operating specifications and capacities of the second separation unit 125.
  • the CPP 1 10 transfers the treated natural gas stream which has been treated by both the first separation unit 120 and the second separation unit 125 to OF 1 15 via pipeline.
  • OF1 15 is not an essential element of the present invention as it plays no technical role interm of removal of C0 2 from the natural gas stream according to the principle of the present invention, but simply receive the natural gas which has been treated by the first separation unit 120 and the second separation unit 125.
  • the trated natural gas may be store on site or transfer to other processing facilities or vessels.
  • it is also not essential that the transferring of the treated natural gas from the first separation unit 120 and the second separation unit 125 to OF1 15 is limited to only via pipeline.
  • the treated natural gas may be transferred to OF1 15 via other means such as a gas transport vessel.
  • pre-conditioning refers to adjustment of properties and characteristics of the hydrocarbon gas and liquid including its C0 2 level as well as other contaminants, flow rate, pressure, temperature to meet the operating specification and capacity of the second separation unit 125 located at the CPP 1 10.
  • the properties and characteristics of hydrocarbon gas including natural gas from different wells/reservoirs and different regions can be varied. It is very typical for hydrocarbon gas especially natural gas in Asia to be derived from smaller size wells/reservoirs and often with higher C0 2 level, which can be as high as 90 mole%.
  • the application of the pre-conditioning using the first separation unit 120 at WHP 105 also made it possible for the feed natural gas to be further processed by the existing conventional CPP without requiring any modifications to the original design and configuration or operating specification and the CPP 1 10 can also continue to receive feed gas having normal level of C0 2 withdrawn from reservoirs with lower or normal range of C0 2 , i.e. 50 mole% and lower.
  • the first separation unit 120 is installed at WHP 105 located on offshore location and is configured to process hydrocarbon gas and liquid withdrawn from smaller gas reservoir, or multiple smaller reservoirs with high C0 2 content wherein the C0 2 content is as high as 90 mole% to treat the hydrocarbon gas and liquid prior to feeding the resulting hydrocarbon mixture to the second separation unit 125 installed at the CPP 1 10.
  • the first separation unit 120 comprising a sand separator 130, a heat exchanger 135, a cooler 140, a gas/liquid separator 145, a coalescer 150, and a first membrane unit 155 connected in a series.
  • the sand separator 130, the heat exchanger 135, the cooler 140, the gas/liquid separator 145, the coalescer 150 are installed before the first membrane unit 155.
  • the hydrocarbon gas and liquid with high C0 2 content is fed into the sand separator 130 to remove sand, sediment or any other solid particles.
  • the characteristics and configuration and mechanism of the sand separator 130 may be of any known configurations which can serve the purposes.
  • the sand, sediment or any other solid particles having particle size greater than 0.3 micron are removed at this step.
  • the hydrocarbon gas and liquid which sand, sediment and other solid particles have been removed or partially removed are then passed through to the heat exchanger 135 to reduce the temperature of the hydrocarbon gas and liquid to a required level, preferably to be below 45°C using any known kinds and forms of any heat exchange mediums including waste gas stream, air, water, etc. and heat exchanger of any known configurations.
  • the hydrocarbon gas and liquid which have passed through the heat exchanger 135 are then passed into the cooler 140 and subsequently entered the gas/liquid separator 145.
  • the gas/liquid separator 145 may also be of any known separators.
  • the saturated hydrocarbon gas which exits the gas/liquid separator 145 is then fed into the coalescer 150 to remove water vapor, condensate and hydrocarbon liquids contaminants after which the resultant hydrocarbon gas is then fed into the first membrane unit 155 to obtain the resulting hydrocarbon mixture of which to be fed into the second separation unit 125 located at the CPP 1 10 for further processing to further remove C0 2 and other contaminants.
  • the first membrane unit 155 other non-desired permeate gasses are separated and then fed or re-circulated back into the heat exchanger 135 prior to being disposed of or released to a flare.
  • the key function of the first separation unit 120 is to pre-conditioning the hydrocarbon gas and liquid including removal of C0 2 at the wellhead to attain a C0 2 level as well as other characteristics to be within the range that will meet the operating specification of the second separation unit 125 located at the CPP 1 10 or the operating specification of the conventional pre-existing C0 2 removal system at the CPP 1 10.
  • the pre-conditioning of the hydrocarbon gas and liquid having high C0 2 content at the first separation unit 120 enable the hydrocarbon gas which has been treated by the first separation unit 120 to be fed as feed gas to the second separator unit 125 of which has been designed and calibrated to treat hydrocarbon gas and liquid with specific level of C0 2 as well as other specific characteristics without requiring modification of the current design and operating system of the existing processing system at the CPP 1 10.
  • the first separation unit 120 may further comprising any other known elements, separators of which may be strategically placed along the above described processing flow to remove different contaminants at different steps of the processing flow.
  • the first separation unit 120 may comprise more than one or multiple units of first membrane units 155, wherein each first membrane unit 155 is configured to function in term of removing C0 2 equally, independently or in compliment to one another to achieve the set target, i.e. the level of C0 2 content, flow rate, pressure and temperature of the hydrocarbon gas acceptable for further processing by the second separator unit 125 located at CPP 1 10.
  • the flow rate, pressure and temperature of the feed hydrocarbon gas and liquid at the first separator unit 120 are monitored and controlled by a controller 161 of which could be a computerized controller or manually operated controller communicates or links to the first separation unit 120 such as the feed hydrocarbon gas and liquid are fed into the second separation unit 125 under controlled pressure, temperature and flow rate.
  • the operating pressure and temperature at the first separation unit 120 are 25-65 bar and 40- 100°C, respectively. It will be appreciated by a skilled person in the art that application of - l i
  • the system according to the present invention allows opportunities to exploit natural hydrocarbon gas with high C0 2 , which usually sealed off at the well because it is unfit for processing by the existing processing system installed at the CPP 1 10.
  • the current invention would, therefore, present opportinities for increasing productivity of natural gas as natural gas with high C0 2 content can now be processed.
  • the system according to the present invention requires no modification to the current processing system, the system according to the present invention not only avoid the cost of modification of the current processing system [which would be far more costly than application of the present invention], the existing processing system will also be able to continue handling of hydrocarbon gas and liquid having normal range of C0 2 content.
  • the system 100 for enhancing efficiency in removal C0 2 from natural hydrocarbon gas stream with high C0 2 content comprising a Wellhead Platform (WHP) 105 located on offshore location, a Central Processing Platform (CPP) 1 10 located at offshore location and may further comprising an Onshore Facility (OF) 115 located at on-shore location.
  • the CPP 1 10 comprising a second separation unit 125 configured to receive from the first separation unit 120 natural gas stream of which has been treated by the first separation unit 120.
  • the second separation unit 125 comprising a separator and coalescer unit 160, an adsorbent guard bed 165, a heater 170, a particle filter 175, and a second membrane unit 180. It is possible for the second separation unit 125 to also comprising a separate controller rather sharing the same controller 161 with the first separation unit 120.
  • the application of the separator and coalescer unit 160, the adsorbent guard bed 165, the heater 170, the particle filter 175, and the second membrane unit 180 at the CPP 110 are known.
  • traditional membranes cannot stand against liquid and heavy hydrocarbon components contained in the gas stream.
  • traditional membrane at the membrane unit at the CPP1 10 is cellulosic, polysulfone and polyimide-based membrane which has relatively short life span and susceptible to damages or reduction in efficiencies upon contacting with water, natural gas liquids, heavy hydrocarbons and C0 2 gas.
  • the traditional membrane often undergoes plasticization known as "C0 2 induced plasticization" resulting in a reduction in separation efficiencies during operation.
  • the Adsorbent Guard Bed 165 is, therefore, required as a pre-treatment unit at the CPP 1 10 to cut-off heavy hydrocarbon and other components such as water from the feed natural gas.
  • the heater 170 is configured to superheat and control the temperature of the membrane restricting any water from entering the second membrane unit 180.
  • the features and characteristics and components of the second separation unit 125 are known. Therefore, these elements will not be described.
  • the second separation unit 125 at the CPP 1 10 receives from the first separation unit 120, hydrocarbon gas which has been pre-treated to meet its operating specification. It should be noted, however, that the configuration and components of the first separation unit 120 at the WHP 105 are designed based on the availability of limited footprint and power supply.
  • the Adsorbent Guard Bed 165 which is a crucial component of the conventional system for removal of C0 2 from natural gas stream and of which covers more than 50% of CPP1 10 designed footprint is no longer a necessity at the first separation unit 120 of the present invention. Therefore, it is possible to attain a more compact overall footprint at the WHP 105 than that of the CPP 1 10. This, once again, proves that the system 100 for enhancing efficiency in removal C0 2 from natural hydrocarbon gas stream according to the principle of the present invention is more flexible in removal of C0 2 from natural hydrocarbon gas stream.
  • the system 100 for enhancing efficiency in removal C0 2 from natural hydrocarbon gas stream will be able to process natural hydrocarbon gas from different wells with variable C0 2 content. That is, wherein natural hydrocarbon gas with normal range of C0 2 content, i.e. at 40 to 50 mole% may be processed by the second separator unit 125 and wherein natural hydrocarbon gas with high level of C0 2 content, i.e. in excess of 50 mole% to as high as 90 mole%, may be processed by the fist separator unit 120 combined with the second separator unit 125 of the present system 100 for enhancing efficiency in removal C0 2 from natural hydrocarbon gas stream.
  • FIG. 4-5 show an exemplary schematic representation of the first membrane unit 155 and the functioning of the membrane according to the principle of the present invention wherein the first membrane unit 155 is configured to remove C0 2 from the hydrocarbon gas stream. Permeate gas generated in this step is discharged by the membrane unit 155 and recirculate to the heat exchanger 135 prior to being disposed of or release to a flare.
  • the first membrane unit 155 at the first separation unit 120 comprising a plurality of membrane modules 190 and inside each membrane module 190 there are disposed a plurality of semipermeable fluid separation membranes 156 configured to influence separation of gaseous mixture through solution -diffusion transport mechanism, wherein the hydrocarbon gas mixture is brought into contact with the said semi-permeable fluid separation membranes 156 under predetermined pressure such that a portion of C0 2 is selectively dissolved and diffused through the semi-permeable fluid separation membranes 156 resulting in enriched fraction of C0 2 on one side of the semi-permeable fluid separation membranes 156 and depleted fraction of C0 2 remains on the other side of the semi-permeable fluid separation membranes 156 as shown in FIG. 5.
  • the semi-permeable fluid separation membrane 156 used in an embodiment of the present invention is a fluid separation membrane made from composite membrane, preferably derived from a class of semi-crystalline engineered thermoplastics with outstanding thermal and chemical resistance capacity.
  • the semi-permeable fluid separation membrane 156 is an asymmetrical membrane selected from flat sheet membrane, tube membrane or hollow fiber membrane.
  • the semi-permeable fluid separation membrane 156 comprising a functional ized ultra-thin selective layer formed from a dense hydrophobic, oleophobic or amphiphobic and C0 2 selective layer 157 arranged on a bed of micro-porous substrate 158 to offer optimum resistant to water, natural gas liquids, hydrogen sulfide and heavy hydrocarbon.
  • the membrane unit 155 comprising a plurality of membrane modules 190 disposed within the said first membrane unit 155.
  • Each membrane module 190 at one end communicates to a feeding pipeline so as to receive feed gas [after having been treated by the coalesce 150] being fed into the first membrane unit 155, while connect to another pipeline at another end so as to discharge treated natural gas [product gas] out of the membrane unit 155.
  • the number of membrane modules 190 and the configuration of their arrangement could be tailored differently to suitable the volumetric flow of the feed gas and the available footprint at the wellhead.
  • the said plurality of membrane modules 190 are arranged as two or more groups in which each group comprising of a plurality of membrane modules 190 and each membrane module 190 in each group while connected to its respective feeding pipe share a common main pipe 191 delivering the feed gas into the first membrane unit 155.
  • each group of membrane modules 190 able to process the feed gas independently from one another. This allows a better and more convenience maintenance because any one group of the membrane modules 190 may be shut down for maintenance or repair while the remaining groups continue to process the feed gas. Consequently, it can reduce down-time of the system and would not substantially affect gas product output should shutting down of any one group of the membrane modules 190 is needed.
  • first membrane unit 155 While it is possible to provide the first membrane unit 155 with only a single group of a plurality of membrane modules 190 and each individual module may be selectively shut down in similar manner as with shutting down of a group of membrane modules 190, it is less preferred because it could affect the product output per time unit. Further, as mentioned earlier providing a multiple units of the first membrane units 155 is also possible and that each membrane unit may comprise a single or multiple groups of membrane module 190 are also possible. Accordingly, selective shutting down of the entire membrane unit 155 among the multiple units thereof or shutting down of only one specific group of a plurality of membrane modules 190 among the multiple groups thereof or shutting down of one specific module among a single group for maintenance would be all possible without completely shutting down of the entire system.
  • each membrane module 190 disposed inside each membrane module 190 are multiple semipermeable fluid separation membranes 156 configured to influence separation of gaseous mixture through solution -diffusion transport mechanism, wherein the hydrocarbon gas mixture is brought into contact with the said semi-permeable fluid separation membrane 156 under predetermined pressure such that a portion of C0 2 is selectively dissolved and diffused through the semi-permeable fluid separation membrane 156 resulting in enriched fraction of C0 2 on one side of the semi-permeable fluid separation membrane 156 and depleted fraction of C0 2 remains on the other side of the semi-permeable fluid separation membrane 156 as shown in FIG. 5.
  • first membrane unit 155 can also be applied to wellhead platform or any other types of wellhead such as sub-sea wellhead.
  • the present invention disclosed a process for removal of C0 2 from hydrocarbon gas and liquid, especially those with high C0 2 content, for example those with the C02 level in the range of 50 mole% and over or up to 90 mole%.
  • the process using the system 100 as described above.
  • the process for removing C0 2 from natural hydrocarbon gas and liquid stream using the system (100) according to present invention comprising subjecting the natural hydrocarbon gas and liquid to a first separation cycle to lower the C0 2 content and contaminants to achieve a targeted level thereof follows by subjecting the hydrocarbon gas obtained therefrom to a second separation cycle to further remove the C0 2 content and contaminant to a desired level.
  • the process comprising the following steps:
  • step ii) subjecting the hydrocarbon gas and liquid obtained in step i) to a first C0 2 and contaminant removal cycle by feeding the hydrocarbon gas and liquid with high C0 2 content of up to 90 mole% to the first separation unit 120 installed at the WHP 105 located at offshore location to remove or partially remove or lower the C0 2 content including contaminants to be within the range or level of the pre-set operating specification at the CPP 1 10;
  • step iii) subjecting the resultant saturated hydrocarbon gas obtained in step ii) with lowered C0 2 and contamination level to a second C0 2 and contaminant removal cycle using the second separation unit 125 installed at the CPP1 10 located at a remote offshore location to further remove C0 2 and contaminants from the hydrocarbon gas and to bring the C0 2 level down to the required level or to meet the required specifications; and
  • hydrocarbon gas and liquid with high C0 2 content are withdrawn from gas reservoir/well or multiple reservoirs/wells using any known techniques, methods and apparatuses. Hydrocarbon gas and liquid obtained therefrom with C0 2 content up to 90 mole% are then fed to the first separation unit 120 installed at the WHP 105 to remove, partially remove or lower the C0 2 content as well as other contaminants to be within the range or level corresponding to the pre-set operating specification at the CPP 1 10, preferably the C0 2 is lowered to be 50 mole% and under.
  • the initial removal of the C0 2 as well as other contaminants at the first separation unit 120 is carried out under controlled pressure, temperature, and flow rate of which are monitored and controlled by computerized controller 161 linked to the first separation unit 120.
  • the operating pressure and temperature, at the first separation unit 120 is 25-65 bar and 40-100°C, respectively.
  • the flow rate is variable according to the source of the natural gas. Of course, these specific parameters of operating pressure, temperature and flow rate may be readjusted or recalibrate or variable as needed.
  • the hydrocarbon gas and liquid are brought into contact with the membrane arranged inside each membrane module 190 of the first membrane unit 155 of the first separation unit 120.
  • Each membrane module 190 comprising a plurality of semi-permeable membrane 156 configured to influence separation of gaseous mixture through solution -diffusion transport mechanism.
  • the hydrocarbon gas mixture is brought into contact with the said semi-permeable membrane 156 under predetermined pressure such that a portion of C0 2 is selectively dissolved and diffused through the membrane resulting on enriched fraction of C0 2 on one side of the membrane and depleted fraction of C0 2 remains on the other side of the membrane.
  • the features and configurations of the membrane are as earlier described.
  • the features and configurations of the first separation unit 120 are as previously described.
  • the hydrocarbon gas and liquid may be subjected to treatment by one or more first membrane units 155 installed at the first separation unit 120 to bring the C0 2 content as well as other contaminants down to the level suitable and acceptable for further processing by the second separation unit 125.
  • the saturated natural gas stream obtained from step ii) having C0 2 level and other characteristics that are fit for further processing by the second separation unit 125 are then fed, under controlled pressure, temperature and flow rate, to the second separation unit 125 to further remove C0 2 and bring the C0 2 level down to meet the requirements or the industry specifications.
  • the hydrocarbon gas of which has been treated by the first separation unit 120 is once again subjected to further treatment by the second separation unit 125.
  • the obtained hydrocarbon gas or feed gas is fed to the separator and coalescer unit 160, the adsorbent guard bed 165, the heater 170, the particle filter 175, and the second membrane unit 180 in respective sequence at the CPP 1 10.
  • the resulting hydrocarbon gas obtained in step iii) is then delivered to the onshore facilities 1 15 via pipeline. Permeate gas generates from the process are released to a flare.
  • onshore facilities 1 15 is not an esstential element of the present invention. Accordingly the treated hydrocarbon gas obtained in step iii) may be delivered to other processing facilities and not necessary located on shore or to the onshore facilities 1 15 mentioned herein.
  • the system and process for enhancing efficiency in removal of C0 2 from natural hydrocarbon gas stream according to the principle of the present invention offer advantage in term of enabling utilization of hydrocarbon gas with high C0 2 content up to 90 mole% which usually left unutilized as the currently used system is unable to process hydrocarbon gas with such high C0 2 content.
  • the system and process according to the principle of the present invention is designed to also compatible with the existing operating specification and configuration so that no or only minimal modification to the existing separation system at the CPP is required to avoid cost relating to modification of the currently used system. Accordingly, the objective of the invention as set out above is considered to have been met.

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)

Abstract

L'invention concerne un système et un procédé pour éliminer le CO2 d'un courant gazeux et liquide d'hydrocarbure naturel. Le système comprend une première unité de séparation installée au niveau d'une tête de puits en communication avec un réservoir de gaz ou de multiples réservoirs de gaz, et située sur un site au large; une seconde unité de séparation installée sur une plate-forme de traitement centrale et située sur un site éloigné au large; une unité de commande informatisée liée auxdites première et seconde unités de séparation; et un équipement de rivage situé sur le rivage. La première unité de séparation est configurée pour traiter des hydrocarbures gazeux et liquides afin de réduire la teneur en CO2 et les contaminants avant d'alimenter la seconde unité de séparation en hydrocarbures gazeux et liquides ayant la teneur en CO2 et les contaminants ciblés, à pression, température et débit contrôlés, pour permettre à la seconde unité de séparation d'effectuer un nouveau traitement destiné à éliminer davantage de CO2 et de contaminants.
PCT/TH2014/000001 2014-01-20 2014-01-20 Système et procédé pour améliorer l'efficacité d'élimination du co2 d'un courant de gaz naturel WO2015108491A1 (fr)

Priority Applications (3)

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PCT/TH2014/000001 WO2015108491A1 (fr) 2014-01-20 2014-01-20 Système et procédé pour améliorer l'efficacité d'élimination du co2 d'un courant de gaz naturel
SG11201601231UA SG11201601231UA (en) 2014-01-20 2014-01-20 A system and a process for enhancing efficiency of co2 removal from natural gas stream
AU2014377721A AU2014377721B2 (en) 2014-01-20 2014-01-20 A system and a process for enhancing efficiency of CO2 removal from natural gas stream

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PCT/TH2014/000001 WO2015108491A1 (fr) 2014-01-20 2014-01-20 Système et procédé pour améliorer l'efficacité d'élimination du co2 d'un courant de gaz naturel

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CN114570152B (zh) * 2022-03-28 2023-12-19 南京诺令生物科技有限公司 一种分离与提纯低颗粒物气体的集成装置及其分离提纯方法

Citations (5)

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Publication number Priority date Publication date Assignee Title
US6128919A (en) * 1998-04-08 2000-10-10 Messer Griesheim Industries, Inc. Process for separating natural gas and carbon dioxide
US20100280288A1 (en) * 2009-01-07 2010-11-04 Mahendra Ladharam Joshi Method for recovering a natural gas contaminated with high levels of co2
WO2012153808A1 (fr) * 2011-05-11 2012-11-15 日立造船株式会社 Système de séparation de dioxyde de carbone
US20130043033A1 (en) * 2011-08-19 2013-02-21 Marathon Oil Canada Corporation Upgrading hydrocarbon material on offshore platforms
US20130142717A1 (en) * 2011-12-02 2013-06-06 Michael Siskin Offshore gas separation process

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6128919A (en) * 1998-04-08 2000-10-10 Messer Griesheim Industries, Inc. Process for separating natural gas and carbon dioxide
US20100280288A1 (en) * 2009-01-07 2010-11-04 Mahendra Ladharam Joshi Method for recovering a natural gas contaminated with high levels of co2
WO2012153808A1 (fr) * 2011-05-11 2012-11-15 日立造船株式会社 Système de séparation de dioxyde de carbone
US20130043033A1 (en) * 2011-08-19 2013-02-21 Marathon Oil Canada Corporation Upgrading hydrocarbon material on offshore platforms
US20130142717A1 (en) * 2011-12-02 2013-06-06 Michael Siskin Offshore gas separation process

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