Classifications

• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
  • C10L1/00—Liquid carbonaceous fuels
  • C10L1/04—Liquid carbonaceous fuels essentially based on blends of hydrocarbons
• • C—CHEMISTRY; METALLURGY
  • C05—FERTILISERS; MANUFACTURE THEREOF
  • C05F—ORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
  • C05F9/00—Fertilisers from household or town refuse
  • C05F9/04—Biological compost
• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
  • C10B53/00—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form
  • C10B53/02—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form of cellulose-containing material
• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
  • C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
  • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
  • C10J3/58—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels combined with pre-distillation of the fuel
  • C10J3/60—Processes
  • C10J3/62—Processes with separate withdrawal of the distillation products
• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
  • C10J2300/00—Details of gasification processes
  • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
  • C10J2300/0913—Carbonaceous raw material
  • C10J2300/0916—Biomass
• • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
  • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
  • Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
  • Y02A40/00—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production
  • Y02A40/10—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in agriculture
  • Y02A40/20—Fertilizers of biological origin, e.g. guano or fertilizers made from animal corpses
• • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
  • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
  • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
  • Y02P20/00—Technologies relating to chemical industry
  • Y02P20/141—Feedstock
  • Y02P20/145—Feedstock the feedstock being materials of biological origin
• • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
  • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
  • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
  • Y02P30/00—Technologies relating to oil refining and petrochemical industry
  • Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock
• • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
  • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
  • Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
  • Y02W30/00—Technologies for solid waste management
  • Y02W30/40—Bio-organic fraction processing; Production of fertilisers from the organic fraction of waste or refuse

Definitions

• Patent No. 14/036,480 filed September 25, 2013, which is a continuation of U.S. Patent Application No. 13/189,709, filed July 25, 2011, the contents of which are incorporated by reference in their entirety.
• the present invention relates generally to carbon footprint reduction and to methods for effecting this reduction.
• the atmosphere is being presently overburdened by carbon emissions produced from fossil fuels.
• the burning of fossil fuels presently contributes to an annual release of 4 billion metric tons of carbon dioxide into the atmosphere and the injection of 2 billion metric tons of carbon dioxide into the world's oceans. It has been well documented that these carbon emissions negatively affect living organisms in the oceans as well as on land. It is desirable to minimize the impact of the fossil fuel emissions.
• carbon footprint of a conversion process is meant the emissions of greenhouse gases generated by the conversion process. It is generally expressed as amount of carbon dioxide equivalents per weight of produced product or produced energy. Carbon dioxide is the primary greenhouse gas considered, although any other greenhouse gases such as nitrogen oxide and methane falls under the category.
• the carbon footprint generally entails production and consumption of food, fuels, manufactured goods, and materials and services used in the conversion process.
• US Patent Publication 2010/0311157 which teaches the production of biofuels from algae as feedstock. The process is claimed to be carbon negative due to the high absorption of C0 2 by the algae.
• US Patent Publication 2010/0040510 discloses a multistage pressurized fluidized bed gasifier operating between 780°C and 1100°C that converts biomass to synthesis gas and biochar. The biochar is said to be capable of being added to soil. The formation of methane, gasoline-like volatiles such as BTX (benzene, toluene, and xylene) and tar is explicitly avoided. The gasifier is said to possibly produce carbon negative fuel.
• US Patent Publication 2008/0317657 discloses a system and method for sequestering carbon in the form of char created by gasifying biomass in an unspecified reactor vessel. A low heating value producer gas is a by-product of the process.
• US Patent Publication 2010/0311157 discloses a system and method for sequestering carbon in the form of char created by gasifying
• 2004/0111968 discusses pyrolyzing biomass to produce char and pyrolysis gases, which are steam reformed to hydrogen.
• the char is treated to become a carbon-based fertilizer.
• the present invention discloses a method for reducing the carbon footprint of any conversion process via the introduction of one or more external carbon negative processes which use renewable inputs.
• a method for reducing the carbon footprint of a conversion process includes (a) conducting an external carbon negative process having biomass as input and sequesterable carbon and one or both of renewable energy and renewable feedstock as outputs, and b) utilizing said renewable energy to at least partly power said conversion process and/or utilizing said renewable feedstock as input to said conversion process.
• the conversion process includes one or more of electricity production, electrochemical reduction process, smelting, fossil fuel extraction, chemical refining, and/or chemical conversion processes.
• the renewable energy is selected from the group consisting of heat, combustible biovapors, combustible fuels and electricity.
• electricity is produced by combustion of one or both of combustible biovapors or renewable fuels obtained as output from the carbon negative process.
• the renewable feedstock comprises light hydrocarbons, C1-C5 light gases, or C6-C20 hydrocarbons.
• the sequesterable carbon is greater than 50% fixed carbon.
• the carbon footprint reduction is greater than 1%, or the carbon footprint reduction is greater than 10% .
• the sequesterable carbon is sequestered by use as a soil amendment, and/or the sequesterable carbon is sequestered by underground storage, and/or the sequesterable carbon is sequestered by addition to soil containing compost material.
• the sequesterable carbon is used for carbon offsets and/or the sequesterable carbon is used for carbon credits.
• the sequesterable carbon is reacted with oxygen, carbon dioxide, methane or steam to generate synthesis gas, which displaces fossil carbon, and for example, the synthesis gas is converted to combustible fuels, refinery stock or chemicals.
• At least one of the combustible fuels, refinery stock or chemicals is certified as carbon negative.
• the output of a plurality of carbon negative processes serve as input to the conversion process.
• the carbon negative process causes the conversion process to qualify for RINs (Renewable Identification Numbers).
• a system for reducing the carbon footprint of a conversion process includes (a) an external carbon negative system having biomass as input and sequesterable carbon and one or both of renewable energy and renewable feedstock as outputs to the conversion process; and b) a conversion process system directly coupled to the external carbon negative system for receiving one or more of said renewable energy as power in said conversion process system and said renewable feedstock as input to said conversion process.
• the size of the carbon negative system is adjustable.
• the carbon negative system produces biochar and bio vapors.
• a plurality of external carbon negative system are directly coupled into said conversion process.
• the plurality of external carbon negative systems communicate in parallel with said conversion process.
• the plurality of external carbon negative systems communicate in series with said conversion process.
• the carbon negative process utilizes a pyrolysis process with renewable feedstocks such as wood and grasses.
• the pyrolysis process produces a carbonaceous solid that can be sequestered in soil for an extended period.
• the pyrolysis produces energy, for example, in the form of heat, energy or renewable fuel, to render the process energy self-sufficient, producing energy to power the pyrolysis as well as energy to power an external conversion process.
• the pyrolysis produces combustible vapors, which are burned to produce electricity that can be used to power devices in the conversion process.
• the pyro lysis vapors are fed to a catalytic conversion process to produce renewable fuel or chemicals.
• the renewable fuel can serve as a carbon negative energy source for an external conversion process.
• the renewable chemicals can serve as carbon negative feedstock for an external energy process.
• a plurality of carbon negative process produce output in parallel, and this output is fed to a conversion process.
• the carbon negative processes are linked, such as drying and/or torrefaction, followed by pyrolysis, followed by gasification, and their output is collected and fed to the conversion process.
• a biofractioning process is the carbon negative process.
• FIG. 1 is a flow diagram illustrating an embodiment of a carbon positive conversion process, which takes an input and converts it into at least one of combustible fuels, chemicals, electricity or heat energy.
• FIG. 2 is an example of the effect of reducing the carbon footprint of a conversion process after implementation of the invention.
• FIG. 3 illustrates the effects of implementing the present invention upon application to a carbon positive conversion process showing that the carbon footprint of the conversion process is reversed upon invention implementation.
• FIG. 4 illustrates the effects of implementing the present invention upon application to a carbon negative conversion process showing that the carbon footprint of the conversion process is further diminished upon invention implementation.
• FIG. 5 is an embodiment of a negative carbon process module, which has biomass as input and as outputs, has a sequesterable carbon and at least one of combustible fuels, chemicals, electricity or heat energy.
• FIG. 6 is a block diagram illustrating an embodiment for inserting a carbon negative process module into a conversion process.
• FIG. 7 is a flow diagram illustrating how the output of a plurality of carbon negative process modules can serve as the input to a conversion process.
• FIG. 8 shows a mass balance for an embodiment of a carbon negative process module with 1.0 ton of biomass as input and 0.25 ton sequesterable char and 0.75 ton biovapors and light gases as output as well as C02 equivalents distribution.
• FIG. 9 is an embodiment of a carbon negative process module with more detailed possibilities for biovapor conversion and biochar processing.
• Fig. 10 illustrates carbon balance considerations in determining the carbon negativity aspects of an embodiment carbon negative module.
• Fig. 11 illustrates an embodiment of the invention in which a negative carbon conversion process is inserted inside a negative carbon conversion process to produce a different type of sequesterable carbon after a different type of biomass is co-fed to the conversion process. Net result is reduction in carbon footprint of the initial carbon negative process.
• Embodiments of the invention are directed toward methods for reducing the carbon footprint of any conversion processes, in particular industrial conversion processes having significant carbon positive emissions.
• a conversion process is defined as a process that uses energy to take a physical input and convert it into at least one of combustible fuels, chemicals, electricity or heat energy. The latter are referred to as useful products.
• a conversion process necessarily has two inputs: a physical input and an energy input.
• the physical input is of non-renewable source and the energy input is derived from fossil fuels.
• the energy input to the conversion process may be electricity or heat energy or other form of energy, such as electrochemical or nuclear, needed to perform the conversion.
• FIG. 1 is a flow diagram illustrating an embodiment of a production module containing a carbon positive conversion process. Shown is a carbon positive production module 50 comprising an input 100, and conversion process 200.
• Both input 100 and conversion process 200 have positive carbon footprints, meaning that carbon dioxide was released/generated to produce them, so that the output of production module is carbon positive.
• Possible outputs of conversion module are combustible fuels 210, chemicals 220, electricity 230 and heat energy 240.
• the input 100 can be any substance, of renewable or non-renewable source, carbon containing or not, which is fed to conversion process 200.
• Embodiments of input 100 include unprocessed ore, raw feedstock, and raw chemicals. The full nature of the embodiments of input 100 will become evident from disclosure of embodiments of conversion process 200.
• Conversion process 200 may be applied to chemical and industrial processes that use energy to effect a physical or chemical transformation in feedstock material to a different substance or substances.
• the conversion process may be applied on its own, or as part of a larger process.
• Embodiments of particularly high carbon footprint conversion processes include smelting processes which transform ores to metals, as in lead, steel or copper smelting; electrochemical reduction processes from the oxides to metals, as in aluminum oxide reduction to aluminum metal in the Bessemer process, and pyroprocessing methods which use heat to combine materials, such as clay, sand, or cement, or steelmaking processes using oxygen. Processes involving physical formation of a substance are included.
• Processes involving change of the physical state of a substance such as liquefaction of gases, gas scrubbing, drying using supercritical means, and freeze-drying are also included. Processes involving changes in size of a given substance, as in communition processes, are covered.
• Electrolytic processes include plating processes which deposit a material on an electrode, including gilding, anodization, and electrowinning, as well as electrotyping, electro-etching, electro-engraving, electropolishing, electrophoretic and electroseparation processes. Processes using electric arc furnaces are included.
• metal fabrication processes involving casting, stamping, machining by large and small machines, forging such as wrought iron forging in furnaces, soldering, metal cutting, metal polishing, processes which harden or render metals more ductile, die making.
• molding processes such as compression molding and blow molding.
• Cleaning processes such as sandblasting, water jet blasting, hot air blasting, and liquid blasting processes are also included.
• Physical and chemical separation processes including various forms of distillation such as vacuum and steam distillation, solvent extraction processes such as organic solvent extraction and supercritical extraction, and flotation separation processes are included.
• Chemical processes involving the conversion of one chemical into another are covered. Examples of these numerous chemical processes include chemical petroleum or large molecule cracking processes, alkylating processes, benzene functionalization processes, and processes using Friedel-Crafts chemistry. Also included are processes that utilize polymerization reactions, benzene functionalization reactions, Diels- Alders reactions, olefin metathesis reactions, transesterifcation reactions, soap making chemistry, amide formation reactions, carbonylation reactions, and acidification and alkali reactions.
• a conversion process as specified above using fossil fuels will generally have a positive carbon footprint. Any of these processes may benefit from the current invention, by coupling the carbon positive footprint process with a carbon negative process, to reduce the carbon footprint of the output. In some cases, the footprint may be so relatively high among comparable other conversion processes as to classify the process as energy intensive. It is particularly for those processes that the present invention demonstrates its utmost utility.
• Implementation of the present invention will serve the purpose of reducing the carbon footprint by virtue of the introduction of a carbon negative process into an energy intensive fossil fuel based conversion process.
• the effect will be to reduce the footprint as shown in Fig. 2, although in some embodiments the reduction will so significant as to actually render the process overall carbon negative.
• Fig. 3 which illustrates the effect of reversing the carbon footprint from positive to negative.
• the invention can also be applied to a carbon negative process, in order to render it even more negative. This is illustrated by Fig. 4.
• the effect of reducing the carbon footprint of a given process will be termed 'carbon remediation' in the present context.
• the present invention will reduce carbon footprint for any conversion process by more than 1%, and preferably by more than 5%, and most preferably by more than 10%. It may qualify a conversion process for RIN (renewable identification number) credits.
• Carbon remediation of a conversion process or production module may be achieved by coupling a carbon negative module to the conversion process.
• a carbon negative module contains a process that converts a renewable input such as biomass into useful products and in the process sequesters carbon. Due to the carbon fixing of biomass that absorbs large quantities of carbon dioxide, biomass is a highly carbon negative input into the process.
• An embodiment of a carbon negative module 60 is shown in Fig. 5.
• a renewable input 300 such as biomass is directed to carbon negative process 350, which produces a carbonaceous sequesterable co-product 375 (often termed biochar).
• an energy input is required for the conversion of the biomass.
• Sequesterable carbon is considered to have a very low footprint, and can be considered to have a 'zero' carbon footprint.
• the carbon negative process produces one or more of renewable energy or renewable feedstock that can be used in subsequent conversion processes.
• Outputs from module can include at least one of combustible chemicals 310, chemicals 320, electricity 330 and heat energy 340.
• the sequesterable nature of the product 375 enables carbon negativity for module 60.
• the overall process is carbon negative as long as the highly carbon negative biomass input outweighs the carbon positive external energy sources that are inputs to the carbon negative process 350.
• the carbon impact of the energy input can be reduced by using a renewable resource (discussed in greater detail below).
• Sequesterable carbon is characterized by its recalcitrance to microbial
• sequesterable carbon will exhibit less than 20% microbial decomposition after residence in soil for one year. In other embodiments, a sequesterable carbon will exhibit less than 10% or less than 5% microbial decomposition after residence in soil for one year. In many instances, sequesterable carbon will demonstrate resistance to microbial decomposition for significantly longer times, such as more than 5 years or more than 10 years, or more than 20 years, or more than 50 years.
• Examples of possible carbon negative processes include thermochemical pyrolysis of biomass, bioenergy production with carbon capture and oil production using algae.
• the form of carbon capture is gaseous C0 2 and algae oil is liquid hydrocarbon (displacing fossil emitted C0 2 ).
• FIG. 8 An embodiment of the carbon negative module 50 is shown in Fig. 8. This is a mass and energy balanced process. 1 ton of biomass is introduced into a pyrolysis process, which converts it to 0.75 ton of bio vapors and light gases and 0.25 ton of biochar. Bio vapors include lower molecular weight oxygenated and hydrocarbon compounds generated by the decomposition of biomass. 7.5 mm BTU is net generated and is capable of being sent to a conversion process, such as a smelting process. This energy represents a renewable displacement of 500 kg of C0 2 , which would have been obtained from combustion of natural gas.
• the carbon remediation may be effected by a more complex process than that depicted in Fig. 8.
• Fig. 9 illustrates an embodiment of a carbon negative process containing a wide variety of components. The components for this process have been previously disclosed in US Patent 5,568,493 and US Patent 8,430,937, which are incorporated in their entirety by reference.
• biomass 405 is inputted into pyrolysis process 420 to concurrently produce combustible fuels and chemicals 495 and sequesterable carbon 425.
• Biomass 405 is pretreated in operation 410 prior to being subjected to the pyrolysis process 420.
• the conversion process produces sequesterable carbon 425 and volatile gas streams 423, e.g., containing biovapors and light gases.
• the volatile gas streams 423 are transformed to commercial grade fuels 495 via separation and blending processes 480 and 490, respectively, which can also produce saleable chemicals 481 and 491.
• An optional fuel conversion process 470 converts the volatile gas streams to renewable fuel components 473, which can contain for example acetylene, benzene, toluene and xylenes.
• the sequesterable char 425 may partly be converted to synthesis gas via syngas production step 450.
• the synthesis gas can have numerous uses, including conversion to fuels and fuel precursors via process 460, and utilization in energy production or chemical production 455.
• Synthesis gas production process 450 can receive input from: (i) biochar processing 430, (ii) external sources of hydrogen, carbon or oxygen 431 , (iii) recycled carbon monoxide or carbon dioxide from process 460, or (iv) recycled gases after the separation process 482.
• biochar 425 may be sequestered in underground storage product 434.
• the biochar may also be mixed with compost to yield sequestered product 433.
• Direct utilization of the biochar as a soil amendment is also possible, since the residence time of biochar in soil is in the order of millennia. The latter has been determined from the persistence of biochar as a soil enhancement agent in Amazonian soil terra preta.
• Biochar 425 may also be upgraded via different techniques and sold as a soil fertilizer 439 to enhance soil growth.
• biochar 425 may optionally be processed prior to being sold directly for various end uses such as activated charcoal, gas purifier, coal purifier and water purifier. Further detail of the biochar processing and sequestration can be found in US. Pat. No. ,430,937, which is incorporated in its entirety by reference.
• the commercial grade negative carbon fuels 495 arise from the concurrent production of pyrolysis-derived renewable fuels and sequesterable biochar.
• the carbon negative module of Fig. 5 is necessarily carbon negative due to the presence of the biochar. Even with the addition of external energy, selection of appropriate energy inputs and recycling of the various outputs of the carbon negative process back into the process also results in a carbon negative process.
• Fig. 6 shows a carbon negative module 60 coupled to a production module 50 via energy distributor 75.
• Distributor 75 can comprise a simple tubing with a tee configuration.
• Energy distributor 75 distributes energy 74 that comes from the carbon negative module.
• energy 74 can include pyrolysis energy (heat), heat generated by burning of pyrolysis gases, or electricity production as a result of burning of pyrolysis gases.
• the energy distributer 75 directs energy, e.g., combustion energy 76 generated from the carbon negative module, to the production module.
• the combustion energy 76 serves as a source of energy used to supplement or decrease the energy needs of conversion process in the production module. Part of the energy generated by carbon negative module can be diverted (shown as energy 77) to self-energize the carbon negative process, thus further improving carbon negativity of the process by reducing external input energy needs.
• the carbon negative module can produce useful outputs in the form of carbon negative chemicals, combustible fuels or other forms of materials.
• This output is shown in Fig. 6 as feedstock 79 for the production module.
• Feedstock 79 can comprise light hydrocarbons, C1-C5 light gases, or C6-C20 hydrocarbons.
• the feedstock can be used for the generation of heat or electricity that is used in a conversion process, such as smelting or electrochemical reduction processes or any process requiring heat or electricity as part of the conversion process or as energy to drive the conversion process.
• Feedstock can also be embodied in a production module involving a chemical conversion process, such as conversion of benzene to benzoic acid in a benzene formylation process.
• a chemical conversion process such as conversion of benzene to benzoic acid in a benzene formylation process.
• Other exemplary feedstocks from pyrolysis of biomass include acetylene, toluene, xylene and acetic acid, all of which are feedstocks for a variety of chemical production processes.
• toluene can be used as a precursor to benzene and in oxidation reactions to yield benzaldehyde and benzoic acid, two important intermediates in chemistry.
• Acetic acid is a useful reagent for the formation of acetaldehyde, and acetylene can be used as a feedstock with alcohols, hydrogen cyanide, hydrogen chloride, or carboxylic acids to give vinyl compounds and with carbon monoxide to give acrylic acid.
• Production module 50 may have additional inputs 80, of renewable or non-renewable form, that allows the conversion process to perform the conversion.
• the carbon negative module is coupled to the production module.
• the coupling of the two processes eliminates or reduces the energy required to make the carbon negative renewable resources available for a conversion process. For example, if a conversion process is located a significant distance from the carbon negative module, energy in the form of transportation is needed to bring the carbon negative renewable resources to the production cite.
• the sites for the carbon negative module and the production module can be advantageously closely located to one another, or co-located on a single site or even integrated into a single process. It is contemplated that certain output of the carbon negative process can be collected and stored to be used in a production process at a later date. Such storing and subsequent use can be carried out in close proximity to one another, so that significant addition carbon positive activities are not required for its transportation.
• the carbon negative module is directly coupled to the production module.
• 'directly coupled' it is meant that the two processes are in direct communication with one another, for example, by having piping or tubing that physically connects an output of the carbon negative process with the production module.
• the coupling can occur through an intermediary, such electric transmission lines or thermal heat transfer mechanisms, as being within the meaning of 'directly coupled'.
• the relative size of carbon negative module 60 to production module 50 determines the degree of carbon negativity and thus carbon remediation applied to the conversion process. If the carbon negative module is relatively small compared to a carbon positive module, then case A as shown in Fig. 2 will be realized. On other hand, if the carbon negative module is sufficiently negative, it can reverse the carbon footprint of a carbon positive production module, as shown in Fig. 3. Instead of one large carbon negative module, an embodiment may have a plurality of carbon negative modules, all feeding into a production module, as shown in Fig. 7. Fig. 7 is an example of a plurality of carbon negative processes producing output in parallel. The input to the production module may be either energy or feedstock as previously discussed. Production module 50 may have additional inputs 55, of renewable or non-renewable form, that allows the conversion process to perform the conversion.
• the term 'biomass' includes any material derived or readily obtained from plant or animal sources. Such material can include without limitation: (i) plant products such as bark, leaves, tree branches, tree stumps, hardwood chips, softwood chips, grape pumice, sugarcane bagasse, switchgrass; and (ii) pellet material such as grass, wood and hay pellets, crop products such as corn, wheat and kenaf. This term may also include seeds such as vegetable seeds, sunflower seeds, fruit seeds, and legume seeds.
• the term 'biomass' can also include: (i) waste products including animal manure such as poultry derived waste; (ii) commercial or recycled material including plastic, paper, paper pulp, cardboard, sawdust, timber residue, wood shavings and cloth; (iii) municipal waste including sewage waste; (iv) agricultural waste such as coconut shells, pecan shells, almond shells, coffee grounds; and (v) agricultural feed products such as rice straw, wheat straw, rice hulls, corn stover, corn straw, and corn cobs.
• waste products including animal manure such as poultry derived waste
• commercial or recycled material including plastic, paper, paper pulp, cardboard, sawdust, timber residue, wood shavings and cloth
• municipal waste including sewage waste
• agricultural waste such as coconut shells, pecan shells, almond shells, coffee grounds
• agricultural feed products such as rice straw, wheat straw, rice hulls, corn stover, corn straw, and corn cobs.
• Fig. 10 is a flow diagram illustrating possible carbon pathways from the point of view of carbon dioxide balance.
• Atmospheric carbon dioxide is the source of carbon for the photosynthetic process that outputs biomass. Energy is needed to collect and transport biomass, and the production of this energy leaves a carbon footprint. Other carbon footprints are left during the production of energy to effect the conversion of biomass into fuel and sequesterable carbon, energy for the separation and blending processes, and energy for biochar upgrading.
• the conversion process itself may release carbon dioxide.
• Sequestered carbon in soil may serve as a small source of carbon dioxide emission, depending on whether the carbon is mixed with compost.
• some carbon dioxide is removed from the atmosphere by sequestering carbon in soil.
• the output path represents the energy provided to a positive conversion process, which could be partly power said conversion process.
• Carbon remediation may also be effected onto an already existing carbon negative process, as demonstrated by Fig. 6.
• Conversion process 50 may comprise an already carbon negative process which then takes additional renewable energy from the distinct carbon negative module. This is illustrated in Fig. 4.
• the carbon negative module and the conversion process are the same process, and this demonstrated by Fig. 11.

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• 2014
  • 2014-12-23 CA CA2934919A patent/CA2934919A1/en not_active Abandoned
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