WO2015097270A3 - Redox flow battery that reversibly converts chemical energy into electricity - Google Patents

Redox flow battery that reversibly converts chemical energy into electricity Download PDF

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Publication number
WO2015097270A3
WO2015097270A3 PCT/EP2014/079282 EP2014079282W WO2015097270A3 WO 2015097270 A3 WO2015097270 A3 WO 2015097270A3 EP 2014079282 W EP2014079282 W EP 2014079282W WO 2015097270 A3 WO2015097270 A3 WO 2015097270A3
Authority
WO
WIPO (PCT)
Prior art keywords
flow
anolyte
catholyte
electricity
chemical energy
Prior art date
Application number
PCT/EP2014/079282
Other languages
French (fr)
Other versions
WO2015097270A2 (en
Inventor
Bertrand Pavageau
Philippe RIVOAL
Annie Colin
Stéphane HAMELET
Jean-Marie Tarascon
Original Assignee
Rhodia Operations
Universite de Bordeaux
Centre National De La Recherche Scientifique (C.N.R.S.)
Universite De Picardie Jules Verne
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rhodia Operations, Universite de Bordeaux, Centre National De La Recherche Scientifique (C.N.R.S.), Universite De Picardie Jules Verne filed Critical Rhodia Operations
Publication of WO2015097270A2 publication Critical patent/WO2015097270A2/en
Publication of WO2015097270A3 publication Critical patent/WO2015097270A3/en

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Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/24Grouping of fuel cells, e.g. stacking of fuel cells
    • H01M8/2459Comprising electrode layers with interposed electrolyte compartment with possible electrolyte supply or circulation
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/02Details
    • H01M8/0202Collectors; Separators, e.g. bipolar separators; Interconnectors
    • H01M8/0258Collectors; Separators, e.g. bipolar separators; Interconnectors characterised by the configuration of channels, e.g. by the flow field of the reactant or coolant
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/18Regenerative fuel cells, e.g. redox flow batteries or secondary fuel cells
    • H01M8/184Regeneration by electrochemical means
    • H01M8/188Regeneration by electrochemical means by recharging of redox couples containing fluids; Redox flow type batteries
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/04Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04082Arrangements for control of reactant parameters, e.g. pressure or concentration
    • H01M8/04186Arrangements for control of reactant parameters, e.g. pressure or concentration of liquid-charged or electrolyte-charged reactants
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/04Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04082Arrangements for control of reactant parameters, e.g. pressure or concentration
    • H01M8/04201Reactant storage and supply, e.g. means for feeding, pipes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/22Fuel cells in which the fuel is based on materials comprising carbon or oxygen or hydrogen and other elements; Fuel cells in which the fuel is based on materials comprising only elements other than carbon, oxygen or hydrogen
    • H01M8/225Fuel cells in which the fuel is based on materials comprising particulate active material in the form of a suspension, a dispersion, a fluidised bed or a paste
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/50Fuel cells

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Fuel Cell (AREA)

Abstract

The invention relates to a redox flow battery that can be used to convert chemical energy into electricity in a reversible manner, comprising: - an anolyte tank (1), containing species of a redox couple, - a catholyte tank (2), containing species of another redox couple, and - at least one electrochemical cell (10), in which a flow of anolyte (A) originating from and sent back to the anolyte tank circulates, in which a flow of catholyte (C) originating from and sent back to the catholyte tank circulates, and which is provided with two electrodes (13), which are respectively in contact with the flow of anolyte (A) and with the flow of catholyte (C), and which collect an electric charge/discharge current of the redox flow battery. The flow of anolyte and the flow of catholyte in the electrochemical cell are laminar, and, in the electrochemical cell, a laminar flow of electrolyte (E) also circulates which is inserted between the flow of anolyte (A) and the flow of catholyte (C) so as to form, at the same time, a first liquid-liquid interface between the flow of anolyte and the flow of electrolyte and a second liquid-liquid interface between the flow of catholyte and the flow of electrolyte.
PCT/EP2014/079282 2013-12-24 2014-12-23 "redox flow" battery that reversibly converts chemical energy into electricity WO2015097270A2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR1363539A FR3015777A1 (en) 2013-12-24 2013-12-24 BATTERY, REDOXFLOW, TRANSFORMING CHEMICAL ENERGY IN REVERSIBLE ELECTRICITY
FR1363539 2013-12-24

Publications (2)

Publication Number Publication Date
WO2015097270A2 WO2015097270A2 (en) 2015-07-02
WO2015097270A3 true WO2015097270A3 (en) 2015-08-27

Family

ID=50179846

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2014/079282 WO2015097270A2 (en) 2013-12-24 2014-12-23 "redox flow" battery that reversibly converts chemical energy into electricity

Country Status (2)

Country Link
FR (1) FR3015777A1 (en)
WO (1) WO2015097270A2 (en)

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20040058217A1 (en) * 2002-09-20 2004-03-25 Ohlsen Leroy J. Fuel cell systems having internal multistream laminar flow
JP2006351248A (en) * 2005-06-13 2006-12-28 Fuji Xerox Co Ltd Micro fluidic element for power conversion
US20110200848A1 (en) * 2008-06-12 2011-08-18 Massachusetts Institute Of Technology High energy density redox flow device
US20120070766A1 (en) * 2010-09-21 2012-03-22 Massachusetts Institute Of Technology Laminar flow fuel cell incorporating concentrated liquid oxidant
WO2012038843A1 (en) * 2010-09-22 2012-03-29 International Business Machines Corporation Electrochemically powered integrated circuit package
US20120189880A1 (en) * 2011-01-20 2012-07-26 International Business Machines Corporation Electrochemical power delivery voltage regulator

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20040058217A1 (en) * 2002-09-20 2004-03-25 Ohlsen Leroy J. Fuel cell systems having internal multistream laminar flow
JP2006351248A (en) * 2005-06-13 2006-12-28 Fuji Xerox Co Ltd Micro fluidic element for power conversion
US20110200848A1 (en) * 2008-06-12 2011-08-18 Massachusetts Institute Of Technology High energy density redox flow device
US20120070766A1 (en) * 2010-09-21 2012-03-22 Massachusetts Institute Of Technology Laminar flow fuel cell incorporating concentrated liquid oxidant
WO2012038843A1 (en) * 2010-09-22 2012-03-29 International Business Machines Corporation Electrochemically powered integrated circuit package
US20120189880A1 (en) * 2011-01-20 2012-07-26 International Business Machines Corporation Electrochemical power delivery voltage regulator

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
FERRIGNO R ET AL: "Membraneless Vanadium Redox Fuel Cell Using Laminar Flow", JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, ACS PUBLICATIONS, US, vol. 124, 15 October 2002 (2002-10-15), pages 12930 - 12931, XP002282850, ISSN: 0002-7863, DOI: 10.1021/JA020812Q *
JIN WOOK LEE ET AL: "Microfluidic redox battery", LAB ON A CHIP, vol. 13, no. 13, 10 May 2013 (2013-05-10), pages 2504 - 2507, XP055114576, ISSN: 1473-0197, DOI: 10.1039/c3lc50499a *
SEYED ALI MOUSAVI SHAEGH ET AL: "A review on membraneless laminar flow-based fuel cells", INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, vol. 36, no. 9, 8 March 2011 (2011-03-08), pages 5675 - 5694, XP055013762, ISSN: 0360-3199, DOI: 10.1016/j.ijhydene.2011.01.063 *

Also Published As

Publication number Publication date
FR3015777A1 (en) 2015-06-26
WO2015097270A2 (en) 2015-07-02

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