WO2015089795A1 - Lubricating oil having antioxidant additive - Google Patents
Lubricating oil having antioxidant additive Download PDFInfo
- Publication number
- WO2015089795A1 WO2015089795A1 PCT/CN2013/089977 CN2013089977W WO2015089795A1 WO 2015089795 A1 WO2015089795 A1 WO 2015089795A1 CN 2013089977 W CN2013089977 W CN 2013089977W WO 2015089795 A1 WO2015089795 A1 WO 2015089795A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- parts
- lubricating oil
- antioxidant additive
- antioxidant
- polyacrylate
- Prior art date
Links
- 239000010687 lubricating oil Substances 0.000 title claims abstract description 28
- 239000003963 antioxidant agent Substances 0.000 title claims abstract description 21
- -1 diaryl sulfide Chemical compound 0.000 claims abstract description 22
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Natural products C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims abstract description 11
- 229920000058 polyacrylate Polymers 0.000 claims abstract description 11
- 229920000642 polymer Polymers 0.000 claims abstract description 11
- 239000002199 base oil Substances 0.000 claims abstract description 9
- 229920001577 copolymer Polymers 0.000 claims abstract description 9
- 229920005862 polyol Polymers 0.000 claims abstract description 8
- 150000003077 polyols Chemical class 0.000 claims abstract description 8
- 238000002156 mixing Methods 0.000 claims abstract description 3
- 229920002675 Polyoxyl Polymers 0.000 claims description 2
- 239000004615 ingredient Substances 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 12
- 230000003078 antioxidant effect Effects 0.000 abstract description 2
- 239000002270 dispersing agent Substances 0.000 abstract description 2
- 238000003756 stirring Methods 0.000 description 9
- 230000003647 oxidation Effects 0.000 description 6
- 238000007254 oxidation reaction Methods 0.000 description 6
- 239000000654 additive Substances 0.000 description 5
- 230000003064 anti-oxidating effect Effects 0.000 description 5
- 238000001514 detection method Methods 0.000 description 5
- 239000000446 fuel Substances 0.000 description 5
- 239000002828 fuel tank Substances 0.000 description 5
- 239000003921 oil Substances 0.000 description 4
- 150000002978 peroxides Chemical class 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 238000005299 abrasion Methods 0.000 description 2
- 235000006708 antioxidants Nutrition 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 230000006866 deterioration Effects 0.000 description 2
- 239000000314 lubricant Substances 0.000 description 2
- 238000005461 lubrication Methods 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 1
- 230000003254 anti-foaming effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000003502 gasoline Substances 0.000 description 1
- 229910052734 helium Inorganic materials 0.000 description 1
- 239000001307 helium Substances 0.000 description 1
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 230000001050 lubricating effect Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000010705 motor oil Substances 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 238000009877 rendering Methods 0.000 description 1
- 239000010802 sludge Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M161/00—Lubricating compositions characterised by the additive being a mixture of a macromolecular compound and a non-macromolecular compound, each of these compounds being essential
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
- C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
- C10M2205/024—Propene
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/08—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type
- C10M2209/084—Acrylate; Methacrylate
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/08—Thiols; Sulfides; Polysulfides; Mercaptals
- C10M2219/082—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms
- C10M2219/086—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms containing sulfur atoms bound to carbon atoms of six-membered aromatic rings
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/04—Detergent property or dispersant property
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/10—Inhibition of oxidation, e.g. anti-oxidants
Definitions
- the present invention relates to a lubricating oil, and more particularly to a lubricating oil having an antioxidant additive. Background technique
- the lubricating oil As the lubricating oil is affected by operating temperature, metal catalysis, combustion products and helium during use, it will gradually lose its antioxidant activity, cause oxidative deterioration, and make the oil clean, dispersible and abrasion resistant. Suffering from rapid damage, increased viscosity, formation of paint films, deposits, etc., which can cause serious damage to engine components.
- the object of the present invention is to provide a lubricating oil with an anti-oxidant additive, which has a very obvious anti-oxidation effect on the engine oil, and can ensure the lubricating effect of the lubricating oil for a long time, and prolongs the problem existing in the above technology. Oil change interval.
- Another object of the present invention is to provide a lubricating oil having an antioxidant additive which is easy to produce and which can effectively reduce the manufacturing cost, thereby providing the consumer with an inexpensive and stable product.
- the present invention has been achieved in accordance with the following scheme.
- a lubricating oil having an antioxidant additive characterized in that the antioxidant additive is prepared by mixing the following components in a weight ratio (the ratios described below are weight ratios unless otherwise specified):
- Ethylene-propylene copolymer 10-20 parts
- Diaryl sulfide 5-10 parts
- Styrene ester polymer 5-8 parts
- the preparation method is as follows: the above base oil, ethylene-propylene copolymer, polyacrylate, polydecyloxypolyol and styrene ester polymer are uniformly mixed and heated to 30 ° C for 30 minutes, and diaryl sulfide is added. Stirring was continued and the temperature was raised to 55 ° C - 70 ° C, stirred for 120 minutes, and filtered to obtain the product.
- diaryl sulfide is an antioxidant additive, preferably in an amount of from 7 to 10 parts.
- the polyacrylate preferably in an amount of from 7 to 8 parts.
- the polyalkoxy polyol preferably in an amount of from 6 to 7 parts.
- the styrene ester polymer is preferably used in an amount of 5-6 parts.
- the formula used in the invention combines the anti-oxidation additive with the viscosity index improver, the dispersant and the like organically, and comprehensively exerts the effect, thereby improving the anti-wear and anti-pressure and oxidation resistance of the lubricating oil, and the lubricating oil It has a good cleaning effect and good anti-foaming effect.
- the preparation of the invention is simple and practical, the preparation cost is low, the service life of the lubricating oil can be effectively extended, and the lubrication effect is improved.
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Lubricants (AREA)
Abstract
Description
Claims
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PCT/CN2013/089977 WO2015089795A1 (en) | 2013-12-19 | 2013-12-19 | Lubricating oil having antioxidant additive |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PCT/CN2013/089977 WO2015089795A1 (en) | 2013-12-19 | 2013-12-19 | Lubricating oil having antioxidant additive |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2015089795A1 true WO2015089795A1 (en) | 2015-06-25 |
Family
ID=53401975
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/CN2013/089977 WO2015089795A1 (en) | 2013-12-19 | 2013-12-19 | Lubricating oil having antioxidant additive |
Country Status (1)
Country | Link |
---|---|
WO (1) | WO2015089795A1 (en) |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102443474A (en) * | 2010-10-12 | 2012-05-09 | 天津市公博科技开发有限公司 | Compound additive for engine oil |
CN102443458A (en) * | 2010-10-11 | 2012-05-09 | 天津市公博科技开发有限公司 | Composite additive used in engine lubricating oil |
CN102533409A (en) * | 2010-12-31 | 2012-07-04 | 中国石油化工股份有限公司 | Lubricating oil composition for motorcycle shock absorber |
-
2013
- 2013-12-19 WO PCT/CN2013/089977 patent/WO2015089795A1/en active Application Filing
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102443458A (en) * | 2010-10-11 | 2012-05-09 | 天津市公博科技开发有限公司 | Composite additive used in engine lubricating oil |
CN102443474A (en) * | 2010-10-12 | 2012-05-09 | 天津市公博科技开发有限公司 | Compound additive for engine oil |
CN102533409A (en) * | 2010-12-31 | 2012-07-04 | 中国石油化工股份有限公司 | Lubricating oil composition for motorcycle shock absorber |
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