WO2015089795A1 - Lubricating oil having antioxidant additive - Google Patents

Lubricating oil having antioxidant additive Download PDF

Info

Publication number
WO2015089795A1
WO2015089795A1 PCT/CN2013/089977 CN2013089977W WO2015089795A1 WO 2015089795 A1 WO2015089795 A1 WO 2015089795A1 CN 2013089977 W CN2013089977 W CN 2013089977W WO 2015089795 A1 WO2015089795 A1 WO 2015089795A1
Authority
WO
WIPO (PCT)
Prior art keywords
parts
lubricating oil
antioxidant additive
antioxidant
polyacrylate
Prior art date
Application number
PCT/CN2013/089977
Other languages
French (fr)
Chinese (zh)
Inventor
龚金凤
Original Assignee
龚金凤
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 龚金凤 filed Critical 龚金凤
Priority to PCT/CN2013/089977 priority Critical patent/WO2015089795A1/en
Publication of WO2015089795A1 publication Critical patent/WO2015089795A1/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M161/00Lubricating compositions characterised by the additive being a mixture of a macromolecular compound and a non-macromolecular compound, each of these compounds being essential
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/02Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
    • C10M2205/024Propene
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/02Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/08Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type
    • C10M2209/084Acrylate; Methacrylate
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/08Thiols; Sulfides; Polysulfides; Mercaptals
    • C10M2219/082Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms
    • C10M2219/086Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms containing sulfur atoms bound to carbon atoms of six-membered aromatic rings
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/04Detergent property or dispersant property
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/06Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/10Inhibition of oxidation, e.g. anti-oxidants

Definitions

  • the present invention relates to a lubricating oil, and more particularly to a lubricating oil having an antioxidant additive. Background technique
  • the lubricating oil As the lubricating oil is affected by operating temperature, metal catalysis, combustion products and helium during use, it will gradually lose its antioxidant activity, cause oxidative deterioration, and make the oil clean, dispersible and abrasion resistant. Suffering from rapid damage, increased viscosity, formation of paint films, deposits, etc., which can cause serious damage to engine components.
  • the object of the present invention is to provide a lubricating oil with an anti-oxidant additive, which has a very obvious anti-oxidation effect on the engine oil, and can ensure the lubricating effect of the lubricating oil for a long time, and prolongs the problem existing in the above technology. Oil change interval.
  • Another object of the present invention is to provide a lubricating oil having an antioxidant additive which is easy to produce and which can effectively reduce the manufacturing cost, thereby providing the consumer with an inexpensive and stable product.
  • the present invention has been achieved in accordance with the following scheme.
  • a lubricating oil having an antioxidant additive characterized in that the antioxidant additive is prepared by mixing the following components in a weight ratio (the ratios described below are weight ratios unless otherwise specified):
  • Ethylene-propylene copolymer 10-20 parts
  • Diaryl sulfide 5-10 parts
  • Styrene ester polymer 5-8 parts
  • the preparation method is as follows: the above base oil, ethylene-propylene copolymer, polyacrylate, polydecyloxypolyol and styrene ester polymer are uniformly mixed and heated to 30 ° C for 30 minutes, and diaryl sulfide is added. Stirring was continued and the temperature was raised to 55 ° C - 70 ° C, stirred for 120 minutes, and filtered to obtain the product.
  • diaryl sulfide is an antioxidant additive, preferably in an amount of from 7 to 10 parts.
  • the polyacrylate preferably in an amount of from 7 to 8 parts.
  • the polyalkoxy polyol preferably in an amount of from 6 to 7 parts.
  • the styrene ester polymer is preferably used in an amount of 5-6 parts.
  • the formula used in the invention combines the anti-oxidation additive with the viscosity index improver, the dispersant and the like organically, and comprehensively exerts the effect, thereby improving the anti-wear and anti-pressure and oxidation resistance of the lubricating oil, and the lubricating oil It has a good cleaning effect and good anti-foaming effect.
  • the preparation of the invention is simple and practical, the preparation cost is low, the service life of the lubricating oil can be effectively extended, and the lubrication effect is improved.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)

Abstract

A lubricating oil having an antioxidant additive, wherein the antioxidant additive is made by mixing the following components by weight percent: an ethylene-propylene copolymer of 10-20 parts; a diaryl sulfide of 5-10 parts; polyacrylate of 5-8 parts; a polyalkoxy polyol of 5-10 parts; a styrene ester polymer of 5-8 parts; and a base oil of 30-60 parts. By combining the components of the antioxidant additive, a viscosity index improver, and a dispersing agent together with one another, and working comprehensively, the wear-resistant, extreme pressure-resistant and antioxidant performance are improved, and the lubricating oil has a good detergency effect, and also a good blistering-resistance effect.

Description

一种具有抗氧添加剂的润滑油 技术领域  Lubricating oil with anti-oxidant additive
本发明涉及一种润滑油, 特别涉及一种具有抗氧添加剂的润滑油。 背景技术  The present invention relates to a lubricating oil, and more particularly to a lubricating oil having an antioxidant additive. Background technique
随着现代社会中车辆使用的增说加,发动机的技术迅速发展,这就对润滑油的 质量提出了更高的要求, 目前, 市场上存在的各种润滑油添加剂的使用, 主要是 改善润滑油的综合性能, 例如抗磨性、 抗氧化性、耐压性等等, 提高起到了一定 的作用。特别是抗腐抗氧剂,汽油发动机润滑书油的氧化安定性是极其重要的一项 控制指标。抗氧化剂有时称为氧化抑制剂; 它们提高组合物的抗氧化性并且可以 通过与过氧化物结合并改性过氧化物起作用, 以通过分解过氧化物, 或通过使 氧化催化剂变得惰性而使它们变得无害。 氧化变质可以通过润滑剂中 的淤渣、 金属表面上的清漆状沉积物以及通过粘度增加表现出来。  With the increase in the use of vehicles in modern society, the technology of the engine has developed rapidly, which puts higher demands on the quality of lubricating oil. At present, the use of various lubricating oil additives on the market mainly improves lubrication. The overall performance of the oil, such as abrasion resistance, oxidation resistance, pressure resistance, etc., has played a certain role. Especially for anti-corrosion antioxidants, the oxidation stability of gasoline engine lubricated book oil is an extremely important control indicator. Antioxidants are sometimes referred to as oxidation inhibitors; they increase the oxidation resistance of the composition and can act by binding to the peroxide and modifying the peroxide to decompose the peroxide, or by rendering the oxidation catalyst inert. Make them harmless. Oxidative deterioration can be manifested by sludge in the lubricant, varnish-like deposits on the metal surface, and by viscosity increase.
由于润滑油在使用过程中受操作温度、金属催化作用、燃烧产物及窜气等因 素的影响, 会逐渐丧失抗氧化活性, 发生氧化变质, 使油品的清净性、 分散性和 抗磨性等遭受快速的破坏, 粘度增加, 形成漆膜、沉积物等, 这会对发动机部件 造成严重的危害。  As the lubricating oil is affected by operating temperature, metal catalysis, combustion products and helium during use, it will gradually lose its antioxidant activity, cause oxidative deterioration, and make the oil clean, dispersible and abrasion resistant. Suffering from rapid damage, increased viscosity, formation of paint films, deposits, etc., which can cause serious damage to engine components.
目前,我国市场上有多种润滑油抗氧添加剂在推广和使用,但均不能达到理 想效果; 进口润滑油抗腐抗氧添加剂价格非常昂贵, 对于消费者来说, 额外增加 很多负担, 而且这些润滑油抗氧添加剂均存在使用周期短的缺陷。 发明内容  At present, there are many kinds of lubricating oil anti-oxidation additives in the market in China, but they can not achieve the desired effect; the imported lubricating oil anti-corrosion and anti-oxidation additives are very expensive, and for the consumers, there is an extra burden, and these Lubricating oil anti-oxidation additives have short defects in the use period. Summary of the invention
本发明的目的是针对上述技术中存在的问题,提供一种具有抗氧添加剂的润 滑油,该润滑油对发动机的机油具有非常明显的抗氧化效果, 并能长期保证润滑 油的润滑效果, 延长换油周期。  The object of the present invention is to provide a lubricating oil with an anti-oxidant additive, which has a very obvious anti-oxidation effect on the engine oil, and can ensure the lubricating effect of the lubricating oil for a long time, and prolongs the problem existing in the above technology. Oil change interval.
本发明的另一个目地是提供一种具有抗氧添加剂的润滑油,该润滑油便于生 产, 能够有效地降低制作成本, 从而为消费者提供廉价且性能稳定的产品。 为达到上述目地, 本发明是按照如下方案实现的。 Another object of the present invention is to provide a lubricating oil having an antioxidant additive which is easy to produce and which can effectively reduce the manufacturing cost, thereby providing the consumer with an inexpensive and stable product. In order to achieve the above object, the present invention has been achieved in accordance with the following scheme.
一种具有抗氧添加剂的润滑油,其特征在于该抗氧添加剂是由下列组方按照 重量比混合制成 (下文所述比例, 除了特别指定外, 均是重量比) :  A lubricating oil having an antioxidant additive, characterized in that the antioxidant additive is prepared by mixing the following components in a weight ratio (the ratios described below are weight ratios unless otherwise specified):
乙烯-丙烯共聚物, 10— 20份;  Ethylene-propylene copolymer, 10-20 parts;
二芳基硫化物, 5— 10份;  Diaryl sulfide, 5-10 parts;
聚丙烯酸酯; 5-8份;  Polyacrylate; 5-8 parts;
聚垸氧基多醇; 5— 10份;  Polyoxyl polyol; 5-10 parts;
苯乙烯酯聚合物, 5— 8份;  Styrene ester polymer, 5-8 parts;
基础油, 30— 60份。  Base oil, 30-60 parts.
制备方法是: 将上述基础油、 乙烯-丙烯共聚物、 聚丙烯酸酯、 聚垸氧基多 醇和苯乙烯酯聚合物、 混合均匀加温至 30°C搅拌 30分钟, 加入二芳基硫化物, 继续搅拌并升温至 55°C-70°C, 搅拌 120 分钟, 过滤后即得产品。  The preparation method is as follows: the above base oil, ethylene-propylene copolymer, polyacrylate, polydecyloxypolyol and styrene ester polymer are uniformly mixed and heated to 30 ° C for 30 minutes, and diaryl sulfide is added. Stirring was continued and the temperature was raised to 55 ° C - 70 ° C, stirred for 120 minutes, and filtered to obtain the product.
其中, 所述二芳基硫化物为抗氧添加剂, 其优选用量为 7— 10份。  Wherein the diaryl sulfide is an antioxidant additive, preferably in an amount of from 7 to 10 parts.
所述聚丙烯酸酯; 其优选用量为 7-8份。  The polyacrylate; preferably in an amount of from 7 to 8 parts.
所述聚烷氧基多醇; 其优选用量为 6— 7份。  The polyalkoxy polyol; preferably in an amount of from 6 to 7 parts.
所述苯乙烯酯聚合物, 其优选用量为 5— 6份。  The styrene ester polymer is preferably used in an amount of 5-6 parts.
本发明所采用的配方,将抗氧添加剂与粘度指数改进剂、分散剂等组份有机 的结合在一起, 综合发挥效力, 提高了润滑油抗磨和抗极压、 耐氧化性能, 使润 滑油的清净效果良好, 兼具有良好的抗起泡效果。  The formula used in the invention combines the anti-oxidation additive with the viscosity index improver, the dispersant and the like organically, and comprehensively exerts the effect, thereby improving the anti-wear and anti-pressure and oxidation resistance of the lubricating oil, and the lubricating oil It has a good cleaning effect and good anti-foaming effect.
且,本发明的制备简单实用,制备成本低,能够有效地延长润滑油使用寿命, 提高润滑效果。 具体实施方式  Moreover, the preparation of the invention is simple and practical, the preparation cost is low, the service life of the lubricating oil can be effectively extended, and the lubrication effect is improved. detailed description
下面通过实施例对本发明作进一步的说明。应当指出的是,对于本发明的具 体说明, 并不作为对发明的具体限定, 凡以近似方式实现的技术方案, 均与发明 的具体实施等同。  The invention is further illustrated by the following examples. It should be noted that the specific description of the present invention is not intended to limit the invention, and the technical solutions implemented in an approximate manner are equivalent to the specific embodiments of the invention.
同时需要说明的是,下文中的重量百分比虽然在不同的实施例中具有不同的 点, 但是这些点共同构成一个涵盖范围, 对于在此涵盖范围内的点, 均属于本发 明的保护范围。 【实施例 1】 。 It should be noted that the weight percentages below have different points in different embodiments, but these points together constitute a range of coverage, and the points within the scope of the present invention are all within the scope of the present invention. [Example 1].
将上述基础油 30份、 乙烯 -丙烯共聚物 10份、 聚丙烯酸酯 5份、 聚烷氧基多 醇 5份和苯乙烯酯聚合物 5份、 混合均匀加温至 30°C搅拌 30-40分钟, 加入二 芳基硫化物 5份, 继续搅拌并升温至 55°C-70°C, 搅拌 120分钟, 过滤后即得产 品  30 parts of the above base oil, 10 parts of ethylene-propylene copolymer, 5 parts of polyacrylate, 5 parts of polyalkoxy polyol and 5 parts of styrene ester polymer, uniformly mixed and heated to 30 ° C, stirred 30-40 Minutes, add 5 parts of diaryl sulfide, continue stirring and warm to 55 ° C -70 ° C, stir for 120 minutes, filter to obtain the product
使用时, 将本产品按 3— 4%重量百分比的比例加入至机动车油箱中即可。 使用中检测: 发动机噪音明显降低, 同时可节省燃油, 润滑油使用寿命提高 2倍 以上, 使用效果良好。  When using, add the product to the fuel tank of the motor vehicle in a proportion of 3-4% by weight. In-use detection: The engine noise is significantly reduced, and the fuel consumption is saved. The service life of the lubricating oil is more than 2 times, and the use effect is good.
【实施例 2】 。  [Example 2].
将上述基础油 60份、 乙烯 -丙烯共聚物 20份、 聚丙烯酸酯 8份、 聚烷氧基多 醇 10份和苯乙烯酯聚合物 8份、 混合均匀加温至 30°C搅拌 30-40分钟, 加入二 芳基硫化物 10份, 继续搅拌并升温至 55°C-70°C, 搅拌 120分钟, 过滤后即得 广品。  60 parts of the above base oil, 20 parts of ethylene-propylene copolymer, 8 parts of polyacrylate, 10 parts of polyalkoxy polyol and 8 parts of styrene ester polymer, uniformly mixed and heated to 30 ° C and stirred 30-40 Minutes, 10 parts of diaryl sulfide was added, stirring was continued and the temperature was raised to 55 ° C - 70 ° C, stirred for 120 minutes, and filtered to obtain a wide product.
使用时, 将本产品按 3— 4%重量百分比的比例加入至机动车油箱中即可。 使用中检测: 发动机噪音明显降低, 同时可节省燃油, 润滑油使用寿命提高 2倍 以上, 使用效果良好。  When using, add the product to the fuel tank of the motor vehicle in a proportion of 3-4% by weight. In-use detection: The engine noise is significantly reduced, and the fuel consumption is saved. The service life of the lubricating oil is more than 2 times, and the use effect is good.
【实施例 3】  [Embodiment 3]
将上述基础油 40份、 乙烯 -丙烯共聚物 10份、 聚丙烯酸酯 7份、 聚垸氧基多 醇 6份和苯乙烯酯聚合物 5份、 混合均匀加温至 30°C搅拌 30-40分钟, 加入二 芳基硫化物 7份, 继续搅拌并升温至 55°C-70°C, 搅拌 120分钟, 过滤后即得产 品。  40 parts of the above base oil, 10 parts of ethylene-propylene copolymer, 7 parts of polyacrylate, 6 parts of polydecyloxypolyol and 5 parts of styrene ester polymer, uniformly mixed and heated to 30 ° C and stirred 30-40 Minutes, 7 parts of diaryl sulfide were added, stirring was continued and the temperature was raised to 55 ° C - 70 ° C, stirred for 120 minutes, and filtered to obtain the product.
使用时, 将本产品按 3— 4%重量百分比的比例加入至机动车油箱中即可。 使用中检测: 发动机噪音明显降低, 同时可节省燃油, 润滑油使用寿命提高 2倍 以上, 使用效果良好。  When using, add the product to the fuel tank of the motor vehicle in a proportion of 3-4% by weight. In-use detection: The engine noise is significantly reduced, and the fuel consumption is saved. The service life of the lubricating oil is more than 2 times, and the use effect is good.
【实施例 4】  [Embodiment 4]
将上述基础油 50份、 乙烯 -丙烯共聚物 15份、 聚丙烯酸酯 8份、 聚垸氧基多 醇 7份和苯乙烯酯聚合物 6份、 混合均匀加温至 30°C搅拌 30-40分钟, 加入二 芳基硫化物 10份, 继续搅拌并升温至 55°C-70°C, 搅拌 120分钟, 过滤后即得 广 -in口口口0 使用时, 将本产品按 3— 4 %重量百分比的比例加入至机动车油箱中即可。 使用中检测: 发动机噪音明显降低, 同时可节省燃油, 润滑油使用寿命提高 2倍 以上, 使用效果良好。 50 parts of the above base oil, 15 parts of ethylene-propylene copolymer, 8 parts of polyacrylate, 7 parts of polydecyloxy polyol and 6 parts of styrene ester polymer, uniformly mixed and heated to 30 ° C and stirred 30-40 Minutes, add 10 parts of diaryl sulfide, continue to stir and heat to 55 ° C -70 ° C, stir for 120 minutes, after filtration, you will get wide - in mouth mouth 0 When using, add the product to the fuel tank of the motor vehicle in a proportion of 3-4% by weight. In-use detection: Engine noise is significantly reduced, fuel can be saved at the same time, the service life of the lubricant is increased by more than 2 times, and the use effect is good.
【实施例 5】 。  [Example 5].
将上述基础油 50份、 乙烯 -丙烯共聚物 12份、 聚丙烯酸酯 7份、 聚垸氧基多 醇 6份和苯乙烯酯聚合物 6份、 混合均匀加温至 30°C搅拌 30-40分钟, 加入二 芳基硫化物 8份, 继续搅拌并升温至 55 °C-70°C, 搅拌 120分钟, 过滤后即得产 品  50 parts of the above base oil, 12 parts of ethylene-propylene copolymer, 7 parts of polyacrylate, 6 parts of polydecyloxypolyol and 6 parts of styrene ester polymer, uniformly mixed and heated to 30 ° C and stirred 30-40 Minutes, add 8 parts of diaryl sulfide, continue stirring and warm to 55 °C-70 °C, stir for 120 minutes, filter to obtain the product
使用时, 将本产品按 3— 4 %重量百分比的比例加入至机动车油箱中即可。 使用中检测: 发动机噪音明显降低, 同时可节省燃油, 润滑油使用寿命提高 2倍 以上, 使用效果良好。  When using, add the product to the fuel tank of the motor vehicle in a proportion of 3-4% by weight. In-use detection: The engine noise is significantly reduced, and the fuel consumption is saved. The service life of the lubricating oil is more than 2 times, and the use effect is good.
总之, 以上所述, 仅仅是对本发明实施的具体描述, 并不代表本发明所实施 的所有方式。在本发明目的及技术方案的基础上所做的等同变化及修饰,均在发 明的保护范围内。  In conclusion, the above description is only a specific description of the implementation of the invention, and does not represent all the embodiments of the invention. Equivalent changes and modifications made on the basis of the objects and technical solutions of the present invention are within the scope of the invention.

Claims

权 利 要 求 书 claims
1、 一种具有抗氧添加剂的润滑油, 其特征在于该抗氧添加剂是由下列组方 按照重量比混合制成: 1. A lubricating oil with an antioxidant additive, characterized in that the antioxidant additive is made by mixing the following ingredients in a weight ratio:
乙烯-丙烯共聚物, 10— 20份; Ethylene-propylene copolymer, 10-20 parts;
二芳基硫化物, 5— 10份; Diaryl sulfide, 5-10 parts;
聚丙烯酸酯; 5-8份; Polyacrylate; 5-8 parts;
聚烷氧基多醇; 5— 10份; Polyalkoxy polyol; 5-10 parts;
苯乙烯酯聚合物, 5— 8份; Styrene ester polymer, 5-8 parts;
基础油, 30— 60份。 Base oil, 30-60 parts.
2、 如权利要求 1所述的具有抗氧添加剂的润滑油, 其特征在于所述二芳基 硫化物为抗氧添加剂, 其优选用量为 7— 10份。 2. The lubricating oil with an antioxidant additive as claimed in claim 1, characterized in that the diaryl sulfide is an antioxidant additive, and its preferred dosage is 7-10 parts.
3、 如权利要求 1所述的具有抗氧添加剂的润滑油, 其特征在于所述聚丙烯 酸酯; 其优选用量为 7-8份。 3. The lubricating oil with antioxidant additive as claimed in claim 1, characterized in that the polyacrylate is preferably used in an amount of 7-8 parts.
4、 如权利要求 1所述的具有抗氧添加剂的润滑油, 其特征在于所述聚垸氧 基多醇; 其优选用量为 6— 7份。 4. The lubricating oil with antioxidant additive as claimed in claim 1, characterized in that the polyoxyl polyol has a preferred dosage of 6-7 parts.
5、 如权利要求 1所述的具有抗氧添加剂的润滑油, 其特征在于所述苯乙烯 酯聚合物, 其优选用量为 5— 6份。 5. The lubricating oil with an antioxidant additive as claimed in claim 1, characterized in that the preferred dosage of the styrene ester polymer is 5-6 parts.
PCT/CN2013/089977 2013-12-19 2013-12-19 Lubricating oil having antioxidant additive WO2015089795A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
PCT/CN2013/089977 WO2015089795A1 (en) 2013-12-19 2013-12-19 Lubricating oil having antioxidant additive

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/CN2013/089977 WO2015089795A1 (en) 2013-12-19 2013-12-19 Lubricating oil having antioxidant additive

Publications (1)

Publication Number Publication Date
WO2015089795A1 true WO2015089795A1 (en) 2015-06-25

Family

ID=53401975

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/CN2013/089977 WO2015089795A1 (en) 2013-12-19 2013-12-19 Lubricating oil having antioxidant additive

Country Status (1)

Country Link
WO (1) WO2015089795A1 (en)

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102443474A (en) * 2010-10-12 2012-05-09 天津市公博科技开发有限公司 Compound additive for engine oil
CN102443458A (en) * 2010-10-11 2012-05-09 天津市公博科技开发有限公司 Composite additive used in engine lubricating oil
CN102533409A (en) * 2010-12-31 2012-07-04 中国石油化工股份有限公司 Lubricating oil composition for motorcycle shock absorber

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102443458A (en) * 2010-10-11 2012-05-09 天津市公博科技开发有限公司 Composite additive used in engine lubricating oil
CN102443474A (en) * 2010-10-12 2012-05-09 天津市公博科技开发有限公司 Compound additive for engine oil
CN102533409A (en) * 2010-12-31 2012-07-04 中国石油化工股份有限公司 Lubricating oil composition for motorcycle shock absorber

Similar Documents

Publication Publication Date Title
WO2013049976A1 (en) Anti-burn engine oil and preparation method thereof
JP2005502764A (en) Diesel fuel, its production and use
KR20140109853A (en) Lubricant composition for marine engine
CN109517634B (en) Gasoline additive, composition thereof and gasoline composition
CN102041113A (en) Novel diesel additive component
CN103421555B (en) Gasoline composite additive and preparation method and application thereof
CA3155740A1 (en) Compositions and methods and uses relating thereto
CN112094671A (en) Alcohol-based fuel antioxidant and anticorrosive composite additive and preparation method thereof
CN104087381B (en) A kind of two n-pentyl ether diesel engine oil compositions
CN103450955B (en) Low-sulfur diesel oil additive composition, and preparation method and application of same
CN104087373B (en) A kind of washing oil fuel delivery engine oil base oil
CN103695050B (en) Vehicle methanol gasoline composite additive
CN110408454B (en) Additive for improving engine power
WO2015089795A1 (en) Lubricating oil having antioxidant additive
CN101665732B (en) Cleaning dispersant for gasoline
CN101935575B (en) Low-emission diesel engine lubricating oil composite
CN116376622A (en) Coal-based engine oil and application thereof
JP6955332B2 (en) Lubricating oil composition
KR20160044306A (en) Diesel Engine Oil Composition for Improving Fuel Efficiency and Endurance Performance
CN108018111A (en) A kind of heavy load CNG natural gas engines machine oil complexing agent and its preparation method and application
CN1891795B (en) Petrol additive
CN114717041A (en) Diesel engine oil composition with long oil change period
CN103450957B (en) Bioenzyme-containing gasoline composite additive as well as preparation method and application for same
CN113072987A (en) Vehicle and ship additive applied to coal-based biofuel and preparation method thereof
CN103740450A (en) Synthetic gas engine oil and preparation method thereof

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 13899375

Country of ref document: EP

Kind code of ref document: A1

NENP Non-entry into the national phase

Ref country code: DE

122 Ep: pct application non-entry in european phase

Ref document number: 13899375

Country of ref document: EP

Kind code of ref document: A1

32PN Ep: public notification in the ep bulletin as address of the adressee cannot be established

Free format text: NOTING OF LOSS OF RIGHTS PURSUANT TO RULE 112(1) EPC (EPO FORM 1205A DATED 17.11.2016)

122 Ep: pct application non-entry in european phase

Ref document number: 13899375

Country of ref document: EP

Kind code of ref document: A1