WO2015076582A1

WO2015076582A1 - Triboelectrostatic separation method for material separation of abs and ps mixed waste plastic

Info

Publication number: WO2015076582A1
Application number: PCT/KR2014/011194
Authority: WO
Inventors: 전호석; 김병곤; 이은선
Original assignee: 한국지질자원연구원
Priority date: 2013-11-20
Filing date: 2014-11-20
Publication date: 2015-05-28
Also published as: KR101530003B1; CN105636703A; KR20150057544A; JP2016533264A; JP6370389B2

Abstract

The present invention relates to a triboelectrostatic separation method for material separation of acrylonitrile butadiene styrene (ABS) and polystyrene (PS) mixed waste plastic, and more preferably, the purpose thereof is to recycle ABS and PS mixed plastic by obtaining a result of ABS grade of 99.5% and recovery of 92.5% under an optimal test condition as a result of triboelectrostatic separation tests by applying one of PET, HIPS and ABS, which are charging materials effective for material separation of ABS and PS mixed waste plastic which is a sample to be tested, in order to recover ABS from the ABS and PS mixed waste plastic by applying triboelectrostatic separation.

Description

Friction-type electrostatic separation method for separating waste plastic material from ABS (ABS) and PS (PS)

More particularly, the present invention relates to a method for separating ABS and PS mixed waste plastic materials, and more particularly, to a method of separating ABS (Polystyrene) In order to recover ABS from plastics, ABS material, which is an effective charge material for separating the waste plastic material, was used to test the friction and charge type electrostatic screening. As a result, The recovery rate is 99.5% and 92.5%, respectively, so that the mixed plastic of ABS and PS can be recycled.

In general, plastics can be substituted for wood, metal, and other materials. They are light and hard, easy to process, and have excellent chemical properties such as corrosion resistance and insulation, and are widely used throughout life and industry. In recent years, the use of plastics has been steadily expanding due to the "second plastic revolution" that has arisen due to the recent introduction of various kinds of special plastics represented by engineering plastics and functional polymers.

Korea is the world's fourth largest producer of plastics after the US, Japan and Germany due to the development of the petrochemical industry. Consumption per capita is also eighth in the world, consuming about 100 kg of plastic per capita per year. Due to the economic characteristics such as various functional excellence and low cost, the amount of waste plastics is increasing. The amount of waste plastics was increased by 3,548,000 tons in 2003, 3,968,000 tons in 2005 and 4,254,000 tons in 2007. The recycling rate of waste plastics as of 2007 is about 39% and more than half Are processed by landfill or incineration.

Solid industrial wastes are generally incinerated and landfilled to be scaled down, but the incineration and reclamation of waste plastics are not only economical but also a macroscopic cause of environmental pollution. The incineration of waste plastics can use some heat energy, but it causes a lot of economic losses, and can cause environmental problems by releasing toxic gases such as dioxins and incinerator corrosion caused by hydrogen chloride. In addition, the landfill of waste plastics is not only a matter of securing landfill sites but also the harmful components can be eluted, which is bulky compared to the unit weight, which lowers the landfill efficiency and is physically and chemically stable. Therefore, The problem of remaining semi-permanently occurs.

Therefore, the government has implemented the EPR (Expendable Product Responsibility) system since January 2003. In the future, in order to regulate the incineration and landfill of waste plastics by law, it is urgent to develop recycling technology for plastic industry and environmental protection.

Plastics are not easily degraded and deteriorated compared to other materials, and recycling is one of the easiest materials if efficient sorting technology is developed. The technologies that can recycle waste plastic include energy recycling, chemical recycling, and material recycling. Considering the cheap characteristics of plastics, recycling of materials is considered to be the most efficient method.

However, the plastic material separation technology is the most important for recycling because the physical properties are greatly deteriorated if any other type of plastic is mixed. Currently, plastic recycling is mostly handled by repair, but research on the separation technology of waste plastics materials in each field has progressed actively and great progress is being made.

In general, physical selection methods that can recycle waste plastics include electrostatic sorting, dry / wet specific gravity sorting, floating sorting, color sorting, and spectroscopy.

[Prior Art Literature]

1. Lee, Sung-Kyu et al., 2010: Development of waste plastic recycling and eco-friendly production system, Disaster Prevention Research, 12 (2), pp.110-120, Disaster Prevention Research Institute, Seoul, Korea.

2. Jung, H. et al., 2010: Development of Electrostatic Separation Technique for Soft PVC from Medical Plastic Waste, J. of Korea Society of Waste Management, 27 (2), pp.159-164

3. Domestic registered patent No. 10-0835992 (filed on February 22, 2007)

4. Domestic Registration No. 10-0809117 (filing date: February 26, 2007)

5. Domestic registered patent No. 10-0848478 (filed on February 26, 2007)

6. Domestic registered patent No. 10-0836003 (filed on March 15, 2007)

7. Domestic Patent Publication No. 10-2013-0095921 (filed on February 21, 2012)

In the present invention, the material separation of waste plastics mixed with ABS (Acrylonitrile Butadiene Styrene) and PS (Polystyrene) is performed by applying a friction-type electrostatic separation method capable of separating all materials regardless of conductive materials and nonconductive materials .

Especially, it is aimed to establish material separation technology that can increase the recycling of mixed waste plastics by screening technology which shows efficiency of ABS recovery and quality of 90% and 99% respectively, focusing on recovering ABS with high demand and high price. .

BRIEF DESCRIPTION OF THE DRAWINGS The above and other objects, features and advantages of the present invention will be more apparent from the following detailed description taken in conjunction with the accompanying drawings, in which: FIG.

The friction lowering type electrostatic separation method for separating ABS and PS mixed waste plastic material according to the present invention is a method for separating ABS and PS mixed waste plastic materials from each other by colliding and rubbing particles on different particles and particles or on the surface of a charging device, When particles are brought into contact with different particles or on the surface of a charging device when the electrons move in the direction in which the fermi levels of the two materials are equal to each other, (+) Or negatively charged (+), and the particles charged with the opposite polarity are passed through the electric field in which a high voltage is applied. -) electrode while the negatively charged particles are moved to the positive (+) electrode to be separated.

That is, the charged material for material separation for recovering ABS from waste plastics mixed with ABS (Acrylonitrile Butadiene Styrene) and PS (Polystyrene) by applying the friction lowering type electrostatic separation is composed of any one of PET, HIPS and ABS do.

As mentioned above, when waste plastics are recycled, it is difficult to recycle materials because the material properties are deteriorated if various types of plastics are mixed. Therefore, it is necessary to separate them by using a material separation technique. In particular, in the case of ABS resin, which is in increasing demand in various fields such as automobiles and electric / electronic industries, the production amount is increasing, and a considerable amount of waste plastic is generated.

Accordingly, in the present invention, by applying the friction lowering type electrostatic separation method, it is possible to produce the charge and charge characteristics of a charged material suitable for separating waste plastic material mixed with ABS and PS recovered from waste household appliances, It is possible to charge the particles with different polarities through the contact between the particles or between the particles and the surface of the charging device so that they can be easily separated electrostatically.

FIG. 1 is a schematic view showing a triboelectrification process of particles according to the present invention. Specifically, FIG. 1 (a) shows charging by contact between the particles and the surface of the charging device, FIG. 1 .

FIG. 2 is a schematic view showing a vertical reciprocating type charging device used for charging sequence ABS and PS charging sequence and charging characteristics, and a conventional (PTFE, PVC, PP, HDPE, PET, HIPS, ABS, POM and Nylon) 2 (b) is a bottom view, and FIG. 2 (c) is a perspective view showing a Faraday cage for measuring a charge polarity and a charging amount. FIG. 2 )to be.

Figure 3 is a schematic flow diagram according to the present invention.

4 is a graph showing the results of charge characteristics test according to the present invention.

5 is a graph showing a screening efficiency according to the charged material according to the present invention.

6 is a graph showing the effect of the voltage strength of the electrode according to the present invention on the quality and recovery efficiency of ABS and PS mixed plastics.

7 is a graph showing the effect of the position of the separator according to the present invention on the sorting efficiency.

8 is a graph showing the effect of the charging time on the sorting efficiency according to the present invention.

9 is a graph showing the screening efficiency according to the ratio of the mixed waste plastic according to the present invention.

10 is a graph showing the influence of the relative humidity according to the present invention on the sorting efficiency in the separation of materials of mixed waste plastics.

11 is a cross-sectional view of a bench scale frictional charge electrostatic screening apparatus used in the present invention.

DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS Hereinafter, preferred embodiments of a friction charge type electrostatic separation method for separating ABS and PS mixed waste plastic materials according to the present invention will be described in detail with reference to the accompanying drawings.

The friction-type electrostatic separation method for separating waste plastics mixed with ABS and PS according to the present invention is a method of separating waste plastic mixed with ABS and PS according to the present invention by charging them with different polarity through contact between different particles and particles or contact between particles and a surface of a charging device, It is a way to separate it by miracle.

FIG. 1 shows a triboelectrification process of particles, wherein (a) shows charging by contact between the particles and the surface of the charging device, and (b) shows charging phenomenon due to contact between particles and particles.

As can be seen from FIG. 1, when particles collide and rub against different particles and particles or on the surface of a charging device, the Fermi level (Fermi level) of the two materials due to the difference in work function -level) are equal to each other. After the particles come into contact with each other or between the different particles or the surface of the charging device, when the particles are separated from the surface again, an excess or deficiency of electrons occurs and the particles are charged with negative (-) or positive (+).

The positive (+) charged particles move to the negative (-) electrode while the negative (-) charged particles move to the positive +) Electrode to be separated.

Hereinafter, the separated sample and the experimental method will be described in detail.

1) Samples and Experimental Methods

The sample used in the present invention is waste plastics made of a mixture of ABS and PS, which are plastics of waste household appliances obtained from Sejong Co., ABS and PS are six general-purpose plastics, with production and demand of about 145,000 tons and 330,000 tons respectively for ABS and about 640,000 tons and 200,000 tons for PS, respectively, About 2.3 times, demand is about 1.6 times higher. In addition, the price of ABS PS is about 300-500 USD / ton compared to other synthetic resin. ABS of 1,891 USD / ton and PS 1,686 USD / ton in 2012 are more expensive than PS by 200 USD / ton. ABS and PS are excellent in moldability, impact resistance, chemical resistance, heat resistance, mechanical strength and electrical insulation, high resin strength, thermal stability, adhesiveness and paintability, and are used for office equipment, automobile parts and electronic parts . In the case of double ABS, it is widely used in automobile parts, electronic parts, etc., and its production is rapidly increasing not only in domestic but also in the world.

FIG. 2 shows a schematic view of a vertical reciprocating type charging device used for studying the charging sequence and charge characteristics of waste plastic ABS and PS and a conventional (PTFE, PVC, PP, HDPE, PET, , Nylon). In order to select a charged substance, the object samples ABS and PS are first cut by a cutting mill (not shown in the drawing) And the particle size was adjusted to 1 to 6 mm by a sieve (1 mm).

The samples with controlled particle size were put into various types of stocks and rubbed and collided by a vertical reciprocating charger, and the charge polarity and charge amount were measured with a Faraday cage shown in FIG. 2 (c). On the basis of this, a charged material for friction separation and electrostatic separation for the separation of ABS and PS mixed waste plastic materials was selected.

FIG. 3 shows a process chart of the experiment according to the present invention. First, the ABS and PS waste plastic as the target samples are crushed and sized at a size of 1 to 6 mm by a cutting mill and a sieve, 1: 1. The particle-size-adjusted samples were charged to the bottom of an ABS material, charged by friction and collision by a vertical reciprocating charger, and then separated and transported to different high-voltage electric fields. In addition, optimum conditions for selection and separation efficiency were verified by changing the experimental conditions such as the voltage of the electrode, the position of the separator, and the humidity.

2) Experimental results

end. Charge characteristic

For the separation of ABS and PS mixed waste plastics, a charging characteristic study was carried out to select charged materials which can charge the specimens to opposite polarities. The specimens were put into a single state in different materials (PTFE, PVC, PP, HDPE, PET, HIPS, ABS, POM and Nylon) with different work function values and charging sequences. After charging, the charge polarity and charge amount were measured using a Faraday cage. Experiments were conducted under the conditions of relative humidity and temperature of less than 40% and room temperature (25 ℃), respectively, and rotational speed and residence time were adjusted to 270 rpm and 2 min.

4 shows the results of the charge characteristics test. The work function values of ABS and PS were lower than those of PTFE, PVC, PP and HDPE, respectively, and higher than POM and Nylon. On the other hand, in the case of PET (Polyethylene Terephthalate), HIPS (High Impact Poly Polystyrene) and ABS, ABS and PS are charged with opposite polarities. At this time, ABS and PS, which are the same material as the target sample, charge the object sample in the opposite direction because the work function differs due to the chemical composition of the plastic inner structure and additives even though the same material is used. Therefore, it is confirmed that ABS, HIPS and PET materials can charge the waste plastics mixed ABS and PS, which are the target samples, with the opposite polarity.

Therefore, the present invention confirms the sorting efficiency according to the charged substance for selecting the optimum charged substance, and the result is shown in FIG. The charged material is made of PTFE, HDPE, and PP for comparison with PET, HIPS, and ABS, in which ABS and PS can charge the mixed waste plastic with the opposite polarity. FIG. 5 shows the quality and recoverability of ABS according to charged materials using mixed waste plastic having a ratio of ABS and PS of 1: 1. In the case of PTFE, HDPE and PP charged with the same polarity, the recovery rate is high, but the grade is lower than 60%. When considering the mixing ratio of mixed waste plastic is 1: 1, . On the other hand, in the case of PET, HIPS and ABS, the recovery rate of 90% or more and the durability of 80% or more can be observed. Among them, And 92.5%, respectively. Therefore, in the present invention, separation characteristic study was performed by selecting ABS as a charged substance.

B) Influence of voltage strength

FIG. 6 is a graph showing changes in electrode voltage intensity from 5 kV to 25 kV at a charging time of 30 seconds, a position of 2 cm in the positive electrode direction and a relative humidity of 30% And the effect on recovery efficiency. As the intensity of the voltage increases, the quality and recoverability of the ABS increases and exhibits high sorting efficiency. At 5 kV with low voltage, the quality and recovery rate were the lowest at 92.5% and 69.3%, respectively. However, as the voltage intensity increased, the quality and recovery rate increased and increased to 99.5% and 92.5% at 20kV. At the peak voltage of 25 kV according to the present invention, the quality and recovering rate were the highest at 99.9% and 93.75%, respectively, but showed no significant difference from the value at 20 kV and showed similar sorting efficiency. Therefore, when the energy efficiency and screening efficiency are taken into consideration, it was found that the voltage of 20 kV is effective in recovering ABS from waste plastics mixed with ABS and PS.

As shown in the graph of FIG. 6, the charge amount of the charged particles is very weak in nC / g unit, and a high electric energy is required to increase the separation efficiency. Because it is necessary.

C) Influence of separation position

The charge amount of the sample is influenced by factors such as the work function value of the particle, the temperature, and the charge time. Because of this, the charged amount of each charged particle is different, so the speed and distance to move to the electrode when separated in the electric field are different. Therefore, by moving the position of the separator in the electric field, a suitable condition showing high sorting efficiency can be obtained.

FIG. 7 is a graph illustrating the effect of the position of the separator on the sorting efficiency. The voltage was measured at a voltage of 20 kV, a relative humidity of 30%, and a charging time of 30 seconds. The separator was positioned at 6 cm The experiment was carried out at 2 cm intervals. As the position of the separator moved from both electrodes to the negative electrode, the ABS grade was 99.9% at 6 cm in the negative pole direction and 99.5% and 98.2% at 2 cm and 6 cm in the positive pole direction, respectively Although not shown, the recovery rate increases to 76.2%, 92.5% and 98.2% at each point.

The reason for this is that the amount of ABS and PS recovered varies depending on the difference in the amount of particles and the position of the separator. In the case of PS with relatively high charging efficiency, the recovery of PS is hardly affected by the change of the position of the separator. However, as the position of the separator is shifted from the positive electrode to the negative electrode, ABS increases the recovery zone of the charged ABS, . Therefore, the most effective at 2 ㎝ in the direction of the anode when the quality and recovery rate were taken into consideration. The recovery rate was 99.5% and the recovery rate was 92.5%.

D) Influence of charging time

8 is a graph illustrating the effect of the charge time on the sorting efficiency. The charge time was increased from 10 seconds to 60 seconds with the voltage of 20 kV, the relative humidity of 30%, and the position of the separator in the positive direction of 2 cm. Experimental results show that the ABS quality and recovering rate are increased up to 30 seconds of charge time. However, when the charge time is longer than this, it is found that critical charge time is reached because there is almost no change in the sorting efficiency.

The reason for the increase in the sorting efficiency as the charging time becomes longer is that as the charging time becomes longer, the frequency of friction or collision between the particles or between charged particles and particles in the charged material increases, . On the other hand, if the charge time was more than 30 seconds, there was no significant change in the sorting efficiency because the charge time of 30 seconds served as a critical point to provide sufficient charge for sorting the sample. Therefore, in this study, the separation test was carried out under the optimal test conditions for 30 seconds of charging time. The results of the tests were 99.5% and 92.5%, respectively.

D) Effect of mixing ratio

In order to observe the mixing ratios showing the optimum sorting efficiency, the samples used in the experiment according to the present invention were obtained by collecting the PS and ABS waste plastic materials from the waste household appliances, : 9, 3: 7, 5: 5, 7: 3. The experimental parameters were 20 kV, 30% relative humidity, 2 cm in the position of the separator, and the charging time was fixed at 30 seconds.

9 shows the screening efficiency according to the ratio of mixed waste plastics. As the amount of ABS increases, the recovery rate decreases but the grade increases. When ABS and PS ratio is 1: 9. The quality and recovery rate were 95.4% and 96.8%, respectively. However, when the ratio of ABS was increased to 99.5%, 92.5% and 7: 3 respectively at 5: 5, the product quality increased to 99.4% and 82.8% .

As the amount of ABS increases, the reason for the increase in the durability is that when the ratio is 1: 9, the charging of the mixed waste plastic is not performed well due to the friction and collision between the relatively large amount of PS, This is because the greater the chance of friction and collision between the target samples, the more efficient charging is achieved. On the other hand, the recovery rate tends to decrease as the amount of ABS increases. This is because, as mentioned above, when the amount of ABS increases, the efficiency of charging decreases due to friction and collision between ABS. If the charge efficiency is reduced, particles that are not charged or weakly charged can not move to the ABS recovery zone and are discharged to the recovery zone of the PS, thereby reducing the recovery rate of the ABS.

Therefore, the highest selectivity was obtained at the ratio of ABS and PS of 5: 5, which shows the quality and recovery rate of 99.5% and 92.5%, respectively, in the mixed waste plastics.

E) Influence of relative humidity

FIG. 10 shows the effect of relative humidity on the sorting efficiency in the separation of mixed waste plastic materials. The selectivity for recovering ABS in mixed waste plastics was observed under the conditions of supply voltage strength 20 kV, position of the separator 2 cm in the direction of the anode, and charging time 30 sec. Experimental results show that ABS up to 40% has no significant effect on the durability and recovery rate of ABS. However, it can be seen that the relative humidity and the recovery rate of ABS are greatly reduced when the relative humidity is increased.

When the relative humidity was the lowest 20%, the quality and recoverability of ABS were the highest at 99.9% and 92.9%, respectively, and even when the relative humidity increased to 40%, 98.7% and 90.1% did not show any significant difference. However, when the relative humidity is higher than 40%, the screening efficiency is significantly lowered, and when the relative humidity is at the highest 70%, the quality and recovery rate are reduced to 70.6% and 48.6%, respectively.

Therefore, in order to increase the screening efficiency, it is understood that the relative humidity should be maintained at 40% or less. In the experiment of the present invention, the material separation test was performed under the optimum condition of 30% relative humidity. 99.5% and 92.5% respectively. The reason why the relative humidity affects the separation of ABS and PS mixed waste plastic material is that the higher the relative humidity is, the more the moisture in the air becomes friction and hinders the surface polarization between the particles, and even if the particles are charged, Thereby reducing the charge amount.

11 is a cross-sectional view of a bench scale frictional charge electrostatic screening apparatus used in the present invention. 11, the frictional charge electrostatic screening apparatus 200 includes an injection port 210 for supplying mixed particles of ABS and PS to the interior of the electrostatic screening apparatus 200 by friction, An air compressor 240 for injecting air to move the mixed particles to the pipe line and the cyclone charging device, the injected PS particles to the negative polarity, and the ABS particles to the A negative electrode plate 250 and a positive electrode plate 260 for separating and separating the ABS and PS particles according to the polarity, a separator 250 for separating ABS and PS particles, A power supply unit 280 for supplying electric power to the anode plate 250 and the anode plate 260, and a drop port 255 for dropping the charged PS particles and ABS particles, respectively, do.

The separator 270 includes a first recovery unit 272 for collecting the polarized ABS particles, a second recovery unit 276 for collecting the polarity-charged PS particles, And a third recovery table 274 for collecting mixed particles of the ABS particles and the PS particles. At this time, the separator 270 may have a single plate shape, but the two plates formed integrally with the recovery bases 272, 274, and 276 and extending in the direction of the drop hole 255 in the recovery basin may be triangular or trapezoidal So that the ABS particles and the PS particles can be easily collected at the respective times. At this time, the separator 270 is formed into a trapezoid by inclining to the negative electrode plate and the positive electrode plate about the vertex of the triangle formed by gathering the two plates extending from the recovered portion. In order to obtain the high quality ABS as described above, The plate extending in the direction of the negative electrode may be provided by moving the plate 6 cm in the direction of the negative electrode. In order to obtain the ABS with a high quality and a high recovery rate, the plate in the positive direction extending from the recovering direction may be provided by moving from 2 cm to 6 cm in the positive direction.

The frictional charge type electrostatic screening apparatus 200 used in the present invention further includes an air drying unit 290 for removing water from the air supplied from the air compressor 240 to the pipeline 220 and the cyclone charging apparatus 230 And an air flow meter 295 formed in a part of a connection pipe connecting the air compressor 240 and the injection port 210 and capable of adjusting the amount of air supplied from the air compressor 240 .

Although the present invention having been described above has been described with reference to a limited number of embodiments, it is to be understood that the present invention is not limited thereto and that various changes and modifications may be made without departing from the spirit and scope of the present invention by those skilled in the art. Various modifications and variations are possible within the scope of the appended claims.

Claims

Charged materials for separation of ABS from waste plastics mixed with ABS (Acrylonitrile Butadiene Styrene) and PS (Polystyrene) by applying electrostatic separation by friction type are polyethylene (PET) (polyethylene terephthalate), HIPS (high impact polystyrene) Wherein the waste plastics material is separated from the waste plastics material.
The method according to claim 1,

Wherein the voltage is 15 ~ 25 kV in sorting the charged materials. The method of claim 1, wherein the voltage is 15 ~ 25 kV.
The method according to claim 1,

In the apparatus for separating static electricity, the separator is disposed at a lower portion of a falling port where the charged waste plastics falls. In order to recover the ABS of high quality, the separator is moved by 6 cm in the direction of the negative electrode around the drop hole, And when the recovery rate is aimed, it is moved from 2 cm to 6 cm in the direction of the anode about the drop hole, and is provided.
The method according to claim 1,

Wherein the charging time is 20 to 40 seconds in the selection of the charged materials.
The method according to claim 1,

Wherein the relative humidity of the charged materials is 20 to 40%. The method of claim 1, wherein the relative humidity is 20 to 40%.
The method according to claim 1,

Wherein the recovery rate is decreased as the amount of ABS is increased, but the quality of the ABS is increased.