WO2015059170A1 - Composition - Google Patents

Composition Download PDF

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Publication number
WO2015059170A1
WO2015059170A1 PCT/EP2014/072608 EP2014072608W WO2015059170A1 WO 2015059170 A1 WO2015059170 A1 WO 2015059170A1 EP 2014072608 W EP2014072608 W EP 2014072608W WO 2015059170 A1 WO2015059170 A1 WO 2015059170A1
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WO
WIPO (PCT)
Prior art keywords
particles
composition according
acrylate
composition
base
Prior art date
Application number
PCT/EP2014/072608
Other languages
French (fr)
Inventor
Nicholas BALLARD
Stefan Antonius Franciscus BON
Abid IFTIKHAR
Ezat Khoshdel
Original Assignee
Unilever Plc
Unilever N.V.
Conopco, Inc., D/B/A Unilever
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Unilever Plc, Unilever N.V., Conopco, Inc., D/B/A Unilever filed Critical Unilever Plc
Priority to EP14787170.1A priority Critical patent/EP3060307A1/en
Priority to JP2016549631A priority patent/JP2016534154A/en
Priority to CN201480056662.9A priority patent/CN105682744A/en
Priority to US15/029,711 priority patent/US20160243020A1/en
Publication of WO2015059170A1 publication Critical patent/WO2015059170A1/en

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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • A61K8/8152—Homopolymers or copolymers of esters, e.g. (meth)acrylic acid esters; Compositions of derivatives of such polymers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/0241—Containing particulates characterized by their shape and/or structure
    • A61K8/0279—Porous; Hollow
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/0241—Containing particulates characterized by their shape and/or structure
    • A61K8/0283—Matrix particles
    • A61K8/0287—Matrix particles the particulate containing a solid-in-solid dispersion
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04—Dispersions; Emulsions
    • A61K8/046—Aerosols; Foams
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/31—Hydrocarbons
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/37—Esters of carboxylic acids
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73—Polysaccharides
    • A61K8/731—Cellulose; Quaternized cellulose derivatives
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8105—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • A61K8/8117—Homopolymers or copolymers of aromatic olefines, e.g. polystyrene; Compositions of derivatives of such polymers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/02—Preparations for cleaning the hair
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/41—Particular ingredients further characterized by their size
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/41—Particular ingredients further characterized by their size
    • A61K2800/412—Microsized, i.e. having sizes between 0.1 and 100 microns

Definitions

  • the present invention relates to a dry shampoo.
  • Dry shampoos are compositions for cleansing the hair without washing with water.
  • the product provides a suitable product to provide a clean feel and look on days when perhaps there is no opportunity, either through lack of time or lack of available water, to wash the hair.
  • XP002683579 Database accession no. 1669958 discloses a dry shampoo comprising aluminium starch octenylsuccinate, silica and glycerine.
  • the composition also comprises butylenes glycol.
  • the present invention provides a dry shampoo composition
  • a dry shampoo composition comprising a base and propellant, wherein the base comprises sebum absorber particles, said particles comprising acrylate cross-polymer, polydivinyl benzene polymers or or hydrohobically modified polysaccharide derivatives, and wherein the particles are insoluble in water.
  • the composition comprises substantially no alcohol. More preferably the composition comprises substantially no ethanol. More preferably, the composition comprises from 0 to 2% wt., most preferably 0 to 1 % wt. of the composition alcohol. More preferably, the composition comprises from 0 to 2% wt., more preferably from 0 to 1 % wt. of the composition ethanol.
  • the base comprises from 5 to 20% wt. of the composition.
  • the base comprises from 2 to 75% wt of the base sebum absorber.
  • the particles are preferably crosslinked, preferably at a level of 20 - 90 %, more preferably 50 - 90 %, most preferably 80 -90 %.
  • the particles comprise styrene/polydivinylbenzene copolymer.
  • the particles comprise hydrophobic acrylate, for example, methyl acrylate, ethyl acrylate, butyl acrylate, ethyl hexyl acrylate, octyl acrylate, decyl acrylate, lauryl acrylate, hexadecyl acrylate and octadecyl acrylate.
  • hydrophobic acrylate for example, methyl acrylate, ethyl acrylate, butyl acrylate, ethyl hexyl acrylate, octyl acrylate, decyl acrylate, lauryl acrylate, hexadecyl acrylate and octadecyl acrylate.
  • the particles may comprise a hydrohobically modified polysaccharide derivative.
  • Preferred hydrohobically modified polysaccharide derivatives are hydrophobically modified cellulose derivatives.
  • a preferred derivative is triacetate.
  • An even more preferred cellulose derivative is cellulose acetate Butyrate, available from, from example, Eastman.
  • the sebum absorbers have an average particle size d(0.5) as measured using a Malvern (DLS) Mastersizer 2000 from 2 to 120 microns, more preferably from 5 to 90 microns.
  • Preferred particles include Spheromers CA6 ex. Microbeads AS, SunPPMA- COCO130, SunPPMA-COCO170, SunPPMA-P and SunPPMA-PH ex. Sunjin Chemicals, and the Celluflows C-25 and TA-25 ex. JNC Corporation.
  • the dry shampoo comprises anoil which is preferably present at from 0.1 to 5% wt. of the base.
  • the oil is isopropyl myristate, benzyl alcohol, PPG-3 benzyl ether myristate.
  • the most preferred is isopropyl myristate.
  • the dry shampoo comprises propylene glycol.
  • any propylene glycol is present at from 0.5 to 5% wt. of the base.
  • the propylene glycol reduces or prevents white residues being deposited on the hair. This is particularly problematic for users with dark hair.
  • the composition of the invention also comprises a propellant to suspend the base immediately before mixing and to facilitate its egress from its container.
  • the composition is stored in a pressurised container.
  • the container is an aerosol canister. More preferably, the container is an un-lacquered aerosol canister.
  • Suitable propellants are well known in the art and include butane, isobutene and propane.
  • a virgin hair switch was treated with the control by way of applying sebum directly to the switch.
  • the switch was then treated with a dry shampoo composition comprising one of the test particles and the particles then removed with a magnet. The amount of sebum remaining was then measured as a percentage of that which was applied.
  • EXAMPLE 3 Porous particles comprising styrene/divinyl benzene and optionally acrylate were prepared by suspension polymerization in a 1 L reactor equipped with a
  • formulations for dry shampoos comprising particles. They are made by standard processes and comprise any of the particles described herein.
  • the data shows that the styrene/divinyl benzene and lauryl methacrylate (1 :0.3) particles are superior to starch for sebum removal.
  • Volume is not just a style preference but also a measure for cleansing. The more volume returned the greater the cleansing efficacy.

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Veterinary Medicine (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Dispersion Chemistry (AREA)
  • Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Mathematical Physics (AREA)
  • Emergency Medicine (AREA)
  • Cosmetics (AREA)

Abstract

Dry shampoo compositioncomprising a base and propellant, wherein the base comprises sebum absorber particles, said particles comprising acrylate cross- polymer, polydivinyl benzene polymers or or hydrohobically modified polysaccharide derivatives, wherein the particles are insoluble in water.

Description

COMPOSITION
The present invention relates to a dry shampoo.
Dry shampoos are compositions for cleansing the hair without washing with water. The product provides a suitable product to provide a clean feel and look on days when perhaps there is no opportunity, either through lack of time or lack of available water, to wash the hair.
Database GNPD [Online] Mintel November 201 1 (201 1 -1 1 ) "Instant Dry
Shampoo" XP002683579 Database accession no. 1669958 discloses a dry shampoo comprising aluminium starch octenylsuccinate, silica and glycerine. The composition also comprises butylenes glycol.
Database GNPD [Online] Mintel February 201 1 (2012-02) "Instant Dry Shampoo" XP002683580 Database accession no. 1727707 discloses a dry shampoo comprising aluminium starch octenylsuccinate, silica and glycerine. The composition also comprises butylenes glycol.
Despite the prior art there remains a need for improved dry shampoos. In particular there is a need for dry shampoos to provide sebum removal, i.e.
cleansing of the hair and also to provide volume to the hair. We have surprisingly found that an improved dry shampoo can be formulated with synthetic particles. The particles are applied to the hair in the usual manner and removed by applying a comb or brush through the hair. The consumer is provided with a simple yet effective means for cleaning the hair on a non-wash day. Accordingly, and in a first aspect, the present invention provides a dry shampoo composition comprising a base and propellant, wherein the base comprises sebum absorber particles, said particles comprising acrylate cross-polymer, polydivinyl benzene polymers or or hydrohobically modified polysaccharide derivatives, and wherein the particles are insoluble in water.
Preferably, the composition comprises substantially no alcohol. More preferably the composition comprises substantially no ethanol. More preferably, the composition comprises from 0 to 2% wt., most preferably 0 to 1 % wt. of the composition alcohol. More preferably, the composition comprises from 0 to 2% wt., more preferably from 0 to 1 % wt. of the composition ethanol.
Preferably, the base comprises from 5 to 20% wt. of the composition. Preferably, the base comprises from 2 to 75% wt of the base sebum absorber.
The particles are preferably crosslinked, preferably at a level of 20 - 90 %, more preferably 50 - 90 %, most preferably 80 -90 %. Preferably, the particles comprise styrene/polydivinylbenzene copolymer.
More preferably, the particles comprise hydrophobic acrylate, for example, methyl acrylate, ethyl acrylate, butyl acrylate, ethyl hexyl acrylate, octyl acrylate, decyl acrylate, lauryl acrylate, hexadecyl acrylate and octadecyl acrylate.
The particles may comprise a hydrohobically modified polysaccharide derivative. Preferred hydrohobically modified polysaccharide derivatives are hydrophobically modified cellulose derivatives. A preferred derivative is triacetate. An even more preferred cellulose derivative is cellulose acetate Butyrate, available from, from example, Eastman. Preferably, the sebum absorbers have an average particle size d(0.5) as measured using a Malvern (DLS) Mastersizer 2000 from 2 to 120 microns, more preferably from 5 to 90 microns. Preferred particles include Spheromers CA6 ex. Microbeads AS, SunPPMA- COCO130, SunPPMA-COCO170, SunPPMA-P and SunPPMA-PH ex. Sunjin Chemicals, and the Celluflows C-25 and TA-25 ex. JNC Corporation.
Preferably, the dry shampoo comprises anoil which is preferably present at from 0.1 to 5% wt. of the base.
Preferably, the oil is isopropyl myristate, benzyl alcohol, PPG-3 benzyl ether myristate. The most preferred is isopropyl myristate. Preferably, the dry shampoo comprises propylene glycol. Preferably any propylene glycol is present at from 0.5 to 5% wt. of the base.
In a composition according to the invention the propylene glycol reduces or prevents white residues being deposited on the hair. This is particularly problematic for users with dark hair.
The composition of the invention also comprises a propellant to suspend the base immediately before mixing and to facilitate its egress from its container. The composition is stored in a pressurised container. Preferably, the container is an aerosol canister. More preferably, the container is an un-lacquered aerosol canister.
Suitable propellants are well known in the art and include butane, isobutene and propane. EXAMPLE 1
A virgin hair switch was treated with the control by way of applying sebum directly to the switch.
The switch was then treated with a dry shampoo composition comprising one of the test particles and the particles then removed with a magnet. The amount of sebum remaining was then measured as a percentage of that which was applied.
EXAMPLE 2
Spheromers CA6 ex. Microbeads AS,
SunPPMA-COCO130, SunPPMA-COCO170, SunPPMA-P and SunPPMA-PH ex. Sunjin Chemicals,
Celluflows C-25 and TA-25 ex. JNC Corporation,
Styrene/Divinyl benzene
Styrene/Divinyl benzene and lauryl methacrylate (1 :0.1 )
Styrene/Divinyl benzene and 2-ethylhexyl metacrylate (1 :0.1 )
Styrene/Divinyl benzene and butyl acrylate (1 :0.1 )
Styrene/Divinyl benzene and lauryl methacrylate (1 :0.3)
EXAMPLE 3 Porous particles comprising styrene/divinyl benzene and optionally acrylate were prepared by suspension polymerization in a 1 L reactor equipped with a
mechanical stirrer and nitrogen inlet according to the recipes shown in Table 1 . The heterogeneous reaction mixture was degassed for half an hour whilst being stirred at 500 rpm. The nitrogen source was then raised above the solution and the stirring rate was dropped to 350 rpm. The reaction was allowed to proceed for 18 h at 70 °C. The resulting porous particles were collected by filtration and washed by distilled water and ethanol. The particles were then left in 1 L of acetone solution stirring overnight to completely remove any linear polymer. The final product was filtered again and dried in vacuo for 24 hours at 60 °C.
Table 1
Figure imgf000006_0001
EXAMPLE 4
The following are formulations for dry shampoos comprising particles. They are made by standard processes and comprise any of the particles described herein.
Figure imgf000006_0002
EXAMPLE 5
Demonstrating the efficacy of styrene/divinyl benzene and lauryl methacrylate (1 :0.3) particles in sebum removal and volume generation.
Sebum Removal
Figure imgf000007_0001
Containing styrene/divinyl benzene and lauryl methacrylate (1 :0.3) particles instead of aluminium starch octenyl succinate.
The data shows that the styrene/divinyl benzene and lauryl methacrylate (1 :0.3) particles are superior to starch for sebum removal.
Volume
Volume is not just a style preference but also a measure for cleansing. The more volume returned the greater the cleansing efficacy.
Front Volume Side Volume Average Volume mm2 mm2 Volume mm2 %
Control 12187.144 10373.923 1 1280.5335 100
Sebum 3904.388 2428.708 3166.548 28.07091
DS 4954.91 3674.479 4314.6945 38.24903 control
Inventive 8496.415 7974.322 8235.3685 73.00513 DS The data again shows that styrene/divinyl benzene and lauryl methacrylate (1 :0.3) particles are superior to starch.
EXAMPLE 6
Demonstrating the efficacy of SunPPMA-PH particles in sebum removal and volume generation.
Sebum Removal
Figure imgf000008_0001
Containing SunPMMA PH particles instead of aluminium starch octenyl succinate. Volume
Figure imgf000008_0002
EXAMPLE 7
Demonstrating the efficacy of Celluflow C25 particles in sebum removal and volume generation. Sebum Removal
Figure imgf000009_0001
Containing Celluflow C25 particles instead of aluminium starch octenyl succinate.
Volume
Figure imgf000009_0002
EXAMPLE 8
Demonstrating the efficacy of *Celluflow TA25 particles in sebum removal and volume generation.
Sebum Removal
Comparative DS Inventive DS*
Before DS application 100% 100%
After DS application 25% 28% Volume
Front Volume Side Volume Average Volume mm2 mm2 Volume mm2 %
Control 12187.144 10373.923 1 1280.5335 100
Sebum 3904.388 2428.708 3166.548 28.07091
DS 4954.91 3674.479 4314.6945 38.24903 control
Celluflow 8377.1 19 7587.96 7982.5395 70.76385 TA-25

Claims

1 . Dry shampoo composition comprising a base and propellant, wherein the base comprises sebum absorber particles, said particles comprising acrylate cross-polymer, polydivinyl benzene polymers or hydrophobically modified polysaccharide derivatives, wherein the particles are insoluble in water.
2. Composition according to claim 1 wherein the base comprises from 5 to 20% wt. of the composition.
3. Composition according to any preceding claim wherein the base comprises from 2 to 75% wt base sebum absorber.
4. Composition according to any preceding claim wherein the sebum absorber comprises particles of average particle size from 20 to 120 micrometer.
5. Composition as claimed in any preceding claim, wherein the particles are crosslinked at a level of preferably 20 - 90 %, more preferably 50 - 90, most preferably 80 -90 %.
6. Composition according to any preceding claim wherein the particles
comprise styrene/polydivinylbenzene copolymer.
7. Composition according to any preceding claim wherein the acrylate is a
hydrophobically modified (meth)acrylate.
8. Composition according to claim 7 wherein the (meth)acrylate is alkyl
methacrylate wherein alkyl means having from 1 to 22 carbons.
9. Composition according to any of claims 1 to 5, wherein the particles are selected from the group consisting of divinylbenzene, lauryl methacrylate, 2- ethylhexyl methacrylate, butyl acrylate and mixtures thereof.
10. Composition according to any one of claims 1 to 5, wherein the
hydrohobically modified polysaccharide derivatives are hydrophobically modified cellulose derivatives.
1 1 . Composition according to claim 10, wherein the hydrophobically modified cellulose derivative is selected from cellulose triacetate and cellulose acetate butyrate.
12. Composition according to any preceding claim comprising from 0.1 to 5% wt. oil.
13. Composition according to claim 1 1 wherein the oil is isopropyl myristate.
PCT/EP2014/072608 2013-10-22 2014-10-22 Composition WO2015059170A1 (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
EP14787170.1A EP3060307A1 (en) 2013-10-22 2014-10-22 Composition
JP2016549631A JP2016534154A (en) 2013-10-22 2014-10-22 Composition
CN201480056662.9A CN105682744A (en) 2013-10-22 2014-10-22 Composition
US15/029,711 US20160243020A1 (en) 2013-10-22 2014-10-22 Composition

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP13189643.3 2013-10-22
EP13189643 2013-10-22

Publications (1)

Publication Number Publication Date
WO2015059170A1 true WO2015059170A1 (en) 2015-04-30

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Country Status (5)

Country Link
US (1) US20160243020A1 (en)
EP (1) EP3060307A1 (en)
JP (1) JP2016534154A (en)
CN (1) CN105682744A (en)
WO (1) WO2015059170A1 (en)

Cited By (1)

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EP3763350A1 (en) * 2019-07-12 2021-01-13 Kao Corporation Dry shampoo with low residue staining properties

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Publication number Priority date Publication date Assignee Title
KR101922471B1 (en) 2017-03-21 2018-11-27 코스맥스 주식회사 Dry Shampoo Composition without white cast

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"Database", accession no. 669958
"Database", accession no. 727707
ANONYMOUS: "GNPD - Detox Dry Shampoo", 1 March 2013 (2013-03-01), XP055106227, Retrieved from the Internet <URL:http://www.gnpd.com/sinatra/recordpage/2022808/from_search/f1E1O5Wlnd/> [retrieved on 20140307] *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3763350A1 (en) * 2019-07-12 2021-01-13 Kao Corporation Dry shampoo with low residue staining properties

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US20160243020A1 (en) 2016-08-25
JP2016534154A (en) 2016-11-04
CN105682744A (en) 2016-06-15

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