WO2015055942A3 - Supported metal catalyst and use thereof for selective oxidation of glycerol - Google Patents

Supported metal catalyst and use thereof for selective oxidation of glycerol Download PDF

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Publication number
WO2015055942A3
WO2015055942A3 PCT/FR2014/052612 FR2014052612W WO2015055942A3 WO 2015055942 A3 WO2015055942 A3 WO 2015055942A3 FR 2014052612 W FR2014052612 W FR 2014052612W WO 2015055942 A3 WO2015055942 A3 WO 2015055942A3
Authority
WO
WIPO (PCT)
Prior art keywords
glycerol
metal catalyst
supported metal
selective oxidation
oxidation
Prior art date
Application number
PCT/FR2014/052612
Other languages
French (fr)
Other versions
WO2015055942A2 (en
Inventor
Mickaël CAPRON
Franck Dumeignil
Elzbieta SKRZYNSKA
Original Assignee
Pivert
Centre National De La Recherche Scientique (Cnrs)
Université Des Sciences Et Technologies De Lille 1
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Pivert, Centre National De La Recherche Scientique (Cnrs), Université Des Sciences Et Technologies De Lille 1 filed Critical Pivert
Priority to US15/027,395 priority Critical patent/US9745243B2/en
Priority to EP14796812.7A priority patent/EP3033322A2/en
Publication of WO2015055942A2 publication Critical patent/WO2015055942A2/en
Publication of WO2015055942A3 publication Critical patent/WO2015055942A3/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/23—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups
    • C07C51/235—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups of —CHO groups or primary alcohol groups

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)

Abstract

The invention relates to a method for oxidation of glycerol into glyceric acid which includes a step of treating glycerol with a supported metal catalyst in the presence of oxygen, said catalyst including platinum and a metal element selected from the group comprising tin, molybdenum, bismuth and a mixture thereof.
PCT/FR2014/052612 2013-10-15 2014-10-14 Supported metal catalyst and use thereof for selective oxidation of glycerol WO2015055942A2 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
US15/027,395 US9745243B2 (en) 2013-10-15 2014-10-14 Supported metal catalyst and use thereof for selective oxidation of glycerol
EP14796812.7A EP3033322A2 (en) 2013-10-15 2014-10-14 Supported metal catalyst and use thereof for selective oxidation of glycerol

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR1360029A FR3011838B1 (en) 2013-10-15 2013-10-15 SUPPORTED BIMETALLIC CATALYST AND USE THEREOF FOR SELECTIVE GLYCEROL OXIDATION
FR1360029 2013-10-15

Publications (2)

Publication Number Publication Date
WO2015055942A2 WO2015055942A2 (en) 2015-04-23
WO2015055942A3 true WO2015055942A3 (en) 2015-06-11

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/FR2014/052612 WO2015055942A2 (en) 2013-10-15 2014-10-14 Supported metal catalyst and use thereof for selective oxidation of glycerol

Country Status (4)

Country Link
US (1) US9745243B2 (en)
EP (1) EP3033322A2 (en)
FR (1) FR3011838B1 (en)
WO (1) WO2015055942A2 (en)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108911961B (en) * 2018-06-07 2021-09-24 广东石油化工学院 Method for preparing tartronic acid by catalytic oxidation of glycerin
CN113956149B (en) * 2020-07-21 2024-03-15 中国石油大学(华东) Separation method of glyceric acid product prepared by glycerol oxidation
CN113956150B (en) * 2020-07-21 2024-03-22 中国石油大学(华东) Preparation method of glyceric acid

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2332899A1 (en) * 2009-12-10 2011-06-15 Rigas Tehniska universitate The method for selective production of glyceric acid

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB8512230D0 (en) 1985-05-14 1985-06-19 Shell Internationale Researche Preparation of carboxylic acid salt
CN100588641C (en) 2008-02-02 2010-02-10 北京大学 Method for synthesizing lactic acid by using glycerol
CN101695657B (en) 2009-10-27 2012-10-10 北京大学 Method for producing lactic acid by using glycerin and special catalyst for production of lactic acid by using glycerin
US9085521B2 (en) 2011-03-30 2015-07-21 University Of Kansas Catalyst system and process for converting glycerol to lactic acid
FR2999571B1 (en) 2012-12-19 2015-02-27 Novance TRANSFORMATION OF GLYCEROL BY HETEROGENEOUS CATALYSIS

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2332899A1 (en) * 2009-12-10 2011-06-15 Rigas Tehniska universitate The method for selective production of glyceric acid

Non-Patent Citations (6)

* Cited by examiner, † Cited by third party
Title
BIANCHI C L ET AL: "Selective oxidation of glycerol with oxygen using mono and bimetallic catalysts based on Au, Pd and Pt metals", CATALYSIS TODAY, ELSEVIER, NL, vol. 102-103, 15 May 2005 (2005-05-15), pages 203 - 212, XP027834742, ISSN: 0920-5861, [retrieved on 20050515] *
DAN LIANG ET AL: "Bimetallic Pt Cu catalysts for glycerol oxidation with oxygen in a base-free aqueous solution", CATALYSIS COMMUNICATIONS, ELSEVIER SCIENCE, AMSTERDAM, NL, vol. 12, no. 12, 14 March 2011 (2011-03-14), pages 1059 - 1062, XP028092660, ISSN: 1566-7367, [retrieved on 20110322], DOI: 10.1016/J.CATCOM.2011.03.019 *
ELINA SPROGE ET AL: "Selective liquid phase oxidation of glycerol to glyceric acid over novel supported Pt catalysts", JOURNAL OF THE SERBIAN CHEMICAL SOCIETY, vol. 78, no. 9, 1 January 2013 (2013-01-01), pages 1359 - 1372, XP055180440, ISSN: 0352-5139, DOI: 10.2298/JSC121203037S *
GARCIA ET AL: "Chemoselective catalytic oxidation of glycerol with air on platinum metals", APPLIED CATALYSIS A: GENERAL, ELSEVIER SCIENCE, AMSTERDAM, NL, vol. 127, no. 1-2, 22 June 1995 (1995-06-22), pages 165 - 176, XP022245054, ISSN: 0926-860X, DOI: 10.1016/0926-860X(95)00048-8 *
KIMURA H ET AL: "SELECTIVE OXIDATION OF GLYCEROL ON A PLATINUM-BISMUTH CATALYST", APPLIED CATALYSIS A: GENERAL, ELSEVIER SCIENCE, AMSTERDAM, NL, vol. 96, no. 2, 26 March 1993 (1993-03-26), pages 217 - 228, XP001199682, ISSN: 0926-860X, DOI: 10.1016/0926-860X(90)80011-3 *
N. WORZ ET AL: "Platinum-Bismuth-Catalyzed Oxidation of Glycerol: Kinetics and the Origin of Selective Deactivation", JOURNAL OF PHYSICAL CHEMISTRY C, vol. 114, no. 2, 21 January 2010 (2010-01-21), pages 1164 - 1172, XP055180411, ISSN: 1932-7447, DOI: 10.1021/jp909412h *

Also Published As

Publication number Publication date
US20160272565A1 (en) 2016-09-22
WO2015055942A2 (en) 2015-04-23
EP3033322A2 (en) 2016-06-22
FR3011838A1 (en) 2015-04-17
US9745243B2 (en) 2017-08-29
FR3011838B1 (en) 2015-11-13

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