WO2015052325A1 - Capture de dioxyde de carbone - Google Patents

Capture de dioxyde de carbone Download PDF

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Publication number
WO2015052325A1
WO2015052325A1 PCT/EP2014/071800 EP2014071800W WO2015052325A1 WO 2015052325 A1 WO2015052325 A1 WO 2015052325A1 EP 2014071800 W EP2014071800 W EP 2014071800W WO 2015052325 A1 WO2015052325 A1 WO 2015052325A1
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WO
WIPO (PCT)
Prior art keywords
solution
sodium bicarbonate
carbon dioxide
sodium carbonate
gas
Prior art date
Application number
PCT/EP2014/071800
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English (en)
Inventor
Norbert Schmidbauer
Svein Knudsen
Original Assignee
Nilu - Stiftelsen Norsk Institutt For Luftforskning
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from GB201318044A external-priority patent/GB201318044D0/en
Application filed by Nilu - Stiftelsen Norsk Institutt For Luftforskning filed Critical Nilu - Stiftelsen Norsk Institutt For Luftforskning
Publication of WO2015052325A1 publication Critical patent/WO2015052325A1/fr

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/46—Removing components of defined structure
    • B01D53/62—Carbon oxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2251/00—Reactants
    • B01D2251/30—Alkali metal compounds
    • B01D2251/304—Alkali metal compounds of sodium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2251/00—Reactants
    • B01D2251/60—Inorganic bases or salts
    • B01D2251/606—Carbonates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/50—Carbon oxides
    • B01D2257/504—Carbon dioxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2258/00—Sources of waste gases
    • B01D2258/02—Other waste gases
    • B01D2258/0283—Flue gases
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/20—Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
    • Y02C20/00—Capture or disposal of greenhouse gases
    • Y02C20/40—Capture or disposal of greenhouse gases of CO2

Definitions

  • the present disclosure relates to a method and apparatus for capture of carbon dioxide (C0 2 ).
  • C0 2 carbon dioxide
  • capture of C0 2 from combustion gases such as flue gases.
  • US 7727374 discloses a system using a sodium hydroxide ion solution to capture carbon dioxide, which reacts with the sodium hydroxide to form sodium bicarbonate in solution.
  • This sodium hydroxide ion solution is produced by electrolysis, along with the addition of acid.
  • the sodium bicarbonate is extracted from the water using heated precipitation. This process is energy intensive and the electrolysis process produces potentially hazardous waste products in the form of chlorine gas and also hydrogen gas.
  • the disclosure provides a method of treatment of combustion gases for carbon dioxide capture comprising: (i) providing a solution of sodium bicarbonate and sodium carbonate in water; (ii) contacting the solution with a gas mixture, the gas mixture including carbon dioxide, such that carbon dioxide dissolves in water and reacts with hydroxide ions in the solution to form bicarbonate ions; (iii) continuing step (ii) until sodium bicarbonate precipitates out of the solution as a solid; (iv) removing the solid sodium bicarbonate; and (v) heating the sodium bicarbonate to form sodium carbonate, water and carbon dioxide; wherein during steps (i) to (iv) the sodium bicarbonate concentration in the solution is maintained at 80% or more of saturation levels.
  • solubility of sodium bicarbonate in water which is 96 g/l at 20 °C
  • solubility of sodium carbonate in water which is 215 g/l at 20 °C.
  • This difference in solubility means that, with an appropriate amount of sodium carbonate in solution, solid sodium bicarbonate will result when sufficient carbon dioxide is added to the solution.
  • One mole of dissolved carbon dioxide reacting with this sodium carbonate / sodium bicarbonate solution will result in precipitation of two moles of sodium bicarbonate.
  • One mole of sodium carbonate needs to be added to renew the solution.
  • the sodium carbonate may be obtained from the calcination of the two moles of precipitated sodium bicarbonate, resulting in a closed loop of involved chemicals for the preferred embodiments of the invention.
  • a significant advantage with the proposed method is the effective mixing of gas and liquid to facilitate the absorption of C0 2 in the liquid. If solid bed or scrubbers are used, as in some prior art techniques, the relative slow reaction rate of the C0 2 reaction with the OH " ions results in large and expensive size equipment and low capture rates. In the proposed method, a long residence time and a high reactant volume compensate the slow reaction. In preferred embodiments the method may advantageously make use of a new contactor where gas is introduced via a mixer- injector that creates large numbers of small bubbles of gas in the solution. An advantage of such a contactor is the ability to work with precipitating systems, where scrubbers have a problem.
  • the introduction of the bubbles in the absorbent is done with an aspirating turbine, also known as an aerator, one type being manufactured by Heinrich Frings GmbH & Co. KG under the trademark "Friborator”, through a manifold where combustion gas is fed into the manifold and ejected into the absorbent as bubbles or by using ultrasonic devices and the like.
  • an aspirating turbine also known as an aerator, one type being manufactured by Heinrich Frings GmbH & Co. KG under the trademark "Friborator”
  • combustion gas is introduced in this way will revitalize processes with slow reaction kinetics, such as: carbonate processes, slow amines and amino acid methods.
  • the reaction forms solids that precipitate from the liquid. This enables the process only to treat the solids and not the reactant liquid.
  • the reactant is preferably recycled as discussed further below.
  • the recycling process involves shifting the reactant between phases from liquid to solid and back to liquid. As noted above, carrying out the reaction in solution makes the whole mass available for reaction and not only the surface. Soiling of surfaces is not a problem since the solids are dissolved and reformed and pollutants in the system will not stick to the surfaces.
  • Other gasses and particles in the gas may be absorbed by the liquid: NO x , metals and particles will to some extent form solids that will precipitate, but will not be re- dissolved in the carbonate resolver and can therefore be separated from the reactant.
  • Sodium bicarbonate is safe and easy to handle. It can be easily transported or stored. The calcination process can therefore be centralized for small sources e.g. capture on ships with calcination in harbours.
  • the calcination is done by: (v) heating the sodium bicarbonate to form sodium carbonate, water (generally as water vapour) and carbon dioxide.
  • the carbon dioxide may be captured for storage, sequestration or used as an ingredient in industrial processes such as methanol production.
  • the method includes: (vi) capturing and, optionally, drying the carbon dioxide and (vii) recycling the sodium carbonate into the sodium carbonate solution used in (i).
  • the water can also optionally be recycled.
  • This sequence of steps creates a closed or partially closed loop for the sodium carbonate required in the process, which is hence not consumed but instead can be continuously recycled to a full or partial extent.
  • the method does not require any addition of sodium compounds, such as sodium carbonate or sodium hydroxide to maintain the working solution.
  • the process does not include the addition of such sodium compounds.
  • the only necessary inputs to the process when it is in steady state are the combustion gases and the heat (or energy) required for thermal decomposition of the sodium bicarbonate.
  • the heat required can be minimised by recovering heat from the system after the reaction, although of course there will always be some losses so some extra heat input is always required.
  • this extra heat can be obtained from the combustion gases.
  • the sodium carbonate solution can be regenerated by the recycled sodium carbonate.
  • the water can advantageously also be re-used in the sodium carbonate solution, and although this is a lesser advantage since water is more abundant than sodium carbonate it is nonetheless a useful feature, especially when pure water is not readily available, for example on board a ship. This provides considerable additional advantages compared to the process proposed in US 7727374, which involves the use of a solution with sodium hydroxide solution to capture carbon dioxide, but involves continued consumption of raw materials and energy, rather than allowing for an efficient recycling system.
  • the sodium bicarbonate may be treated in a drier to remove excess moisture.
  • the water removed from the sodium bicarbonate may optionally be recovered and recycled into the sodium carbonate solution.
  • the carbon dioxide may be treated in a drier to recover water before the carbon dioxide is processed further.
  • the water thus obtained may optionally be recovered and recycled into the sodium carbonate solution.
  • the heating at step (v) may be at a temperature of 70 °C to 250 °C.
  • the sodium bicarbonate is heated at a temperature in the range 150 °C to 210 °C, for example a temperature close to 160 °C or a temperature close to 200 °C.
  • the products of step (v) will be at an elevated temperature.
  • the method may include heat exchange between some or all processes including heat generation and consumption for example heat exchange between the products of step (v) and the sodium bicarbonate that is to be heated in step (v). This can pre-heat the sodium bicarbonate, which reduces the energy required for step (v). For example heat from the sodium carbonate may be recovered to pre-heat the sodium bicarbonate.
  • the carbon dioxide obtained from step (v) is preferably compressed for storage.
  • the carbon dioxide can be stored for future use, transported elsewhere, or used locally for sequestration as an ingredient in industrial processes.
  • the concentration of the sodium bicarbonate solution is controlled so that it is close to saturation.
  • the solution may be maintained at 90% or more of saturation levels, preferably at 95% or more.
  • the concentration may be at about fully saturated for sodium bicarbonate.
  • the process is most effective when the concentration is as close to saturation as possible.
  • Sodium carbonate is preferably continually added to the solution (either as a solid or as a solution) as the reaction with carbon dioxide precipitates out sodium bicarbonate and 'removes' reactants from the solution. In preferred embodiments, this sodium carbonate is recycled from the sodium carbonate produced by the heating in step (v). It will be understood that the solubility of sodium carbonate (and sodium bicarbonate) will vary with temperature. The temperature of the solution may be monitored and the amount of sodium carbonate controlled accordingly in order to maintain a concentration at the chosen saturation level.
  • the sodium carbonate solution is at a temperature of at least 15 °C, more preferably at least 20 °C.
  • the temperature may be up to about 70 °C and preferably it is not higher than 70 °C.
  • a catalyst may be included in the solution in order to accelerate the chemical reactions.
  • C0 2 uptake and release is accelerated by carbonic anhydrase.
  • a stabilised carbonic anhydrase or functional equivalent thereof is added to the solution to accelerate those reactions.
  • the flue gas will be effectively mixed with the reactants in the solution.
  • the absorption of gas in liquids is in general described by Henry's law.
  • an injector/mixer device is used to introduce the gas mixture into the reactant solution.
  • the injector/mixer preferably generates sufficient gas/liquid surfaces such as large numbers of small gas bubbles in the solution. This maximise the surface area of contact between the gas and the liquid, which maximises the speed of dissolution and hence increases the speed of the carbon dioxide capture process.
  • the mixing can be done with a Friborator or other aerator. Replenishment of the reactant solution can be done within this process.
  • the preferred embodiment will be designed to obtain sufficient resident time for absorption and reactions to take place.
  • the embodiment may need a precipitation zone.
  • the heating/calcination step (v) may be performed under pressure. This results in the carbon dioxide being produced at an elevated pressure and reduced compression is therefore required to bring the carbon dioxide to the required pressure for storage and/or transport.
  • An elevated pressure can be achieved by carrying out the heating step in a pressure container and using the transformation of the solid sodium bicarbonate into sodium carbonate, water and gaseous carbon dioxide to generate an increased pressure.
  • the whole process can be pressurised and may, for example, operate at the pressure of the system that provides the incoming gas mixture. When an increased pressure is used then the temperature of the heating step can be adjusted accordingly.
  • the gas mixture is an exhaust/flue gas, which may be from industrial processes, power plants, or combustion processes, for example from an internal combustion engine.
  • the heating at step (v) preferably uses the heat of the exhaust and/or waste heat from the engine. This further reduces the energy required by the process, since the main energy input at step (v) can make use of what would otherwise be waste heat.
  • the system may also be operated under pressure by using the exhaust gas pressure.
  • the invention provides an apparatus for treatment of exhaust gases for carbon dioxide capture, the apparatus comprising: a reaction vessel containing a solution of sodium bicarbonate and sodium carbonate in water; a gas delivery device for contacting the solution with a combustion gas mixture, the gas mixture including carbon dioxide, such that carbon dioxide will react with the hydroxide ions in the solution and form bicarbonate ions, wherein the gas delivery device is arranged for continuous delivery of gas so that as a result of the reaction sodium bicarbonate precipitates out of the solution as a solid; and a heater for heating the sodium bicarbonate in order to form sodium carbonate, water and carbon dioxide.
  • the gas delivery device may be a gas injector for bubbling the gas mixture through the solution in the reaction vessel.
  • Very effective devices are aerator products called Friborator produced by Heinrich Frings GmbH & Co. KG of Bonn, Germany. These devices come in various configurations that can be adapted to the containers and volumes that are to be processed.
  • the gas delivery device may optionally mix the solution with the gas by movement of the solution through a mixer- injector, for example a Venturi mixer-injector such as that described in US 5863128.
  • the gas delivery device is preferably connected to a supply for the gas mixture, for example it may be connected to an exhaust system in order to receive a gas mixture in the form of exhaust gases.
  • the gas mixture that emerges from the solution with depleted carbon dioxide content may be removed from the reaction vessel via an outlet, for example an outlet in a headspace of the reaction vessel. This gas may subsequently be treated further or vented to atmosphere.
  • the apparatus may include a sediment or slurry extraction device for removing the sodium bicarbonate sediment from the reaction vessel.
  • the sediment extraction device may for example be a conveyor such as a belt conveyor or screw conveyor.
  • the sodium bicarbonate sediment may be treated in a drier or in a filtering device to remove excess moisture.
  • the drier may be arranged to recover water for recycling into the sodium carbonate solution.
  • the heater is arranged to heat the sodium bicarbonate to a temperature of 70 °C or above, for example a temperature in the range 70 °C to 250 °C. Waste heat from the combustion gas may be used to provide some or all of the heat for the heater. This reduces energy consumption.
  • the carbon dioxide may be captured in gaseous form and optionally the apparatus includes a compressor for compressing the carbon dioxide.
  • the heater may also act to dry the sodium carbonate if necessary.
  • a gas drier may be included in order to remove moisture from the carbon dioxide.
  • the calcination process may also be done in a sodium bicarbonate slurry preferably under pressure. This will reduce the energy consumption due to less production of water vapour and a higher concentration of C0 2 in the headspace.
  • the apparatus includes a sodium carbonate recycling system for recycling the sodium carbonate into the reactant solution.
  • the recycling system could include a mechanism for transporting the sodium carbonate from the heater to the reaction vessel.
  • the sodium carbonate recycling system may dissolve the sodium carbonate in water, which preferably includes water recovered from the heater and/or driers.
  • the apparatus includes a control device for controlling the concentration in the reaction chamber.
  • the concentration may be controlled such that the sodium bicarbonate concentration in the solution is maintained at 80% or more of saturation levels, optionally at 90% or at 95% of saturation levels.
  • the control device may be connected with the sodium carbonate recycling system so that it can control the rate of recycling of sodium carbonate into the solution in the reaction chamber and thereby control the concentration of the solution.
  • the flue gas will be effectively mixed with the reactants in the solution.
  • the absorption of gas in liquids is governed by Henry's law.
  • the mixing may be done with a Friborator or other suitable mixer device.
  • the fluid comes from the reactant embodiment. Replenishment of the reactant solution can be done within this process.
  • the embodiment will be designed to obtain sufficient resident time for absorption and reaction to take place.
  • a Friborator will need between 10 and 100 m 2 to distribute the flue gas as bubbles.
  • a flue gas from a power plant with a C0 2 concentration of 14% one ton of C0 2 could be captured per hour, resulting in precipitation of 3.8 tons of sodium bicarbonate.
  • the preferred embodiment may include a precipitation zone.
  • the heater may include a pressure container so that the heating can be carried out under pressure.
  • the whole apparatus may be pressurised and may, for example, operate at the pressure of the system that provides the incoming gas mixture.
  • the apparatus may be installed on a vehicle for treating its exhaust gases, and the invention hence extends to a vehicle fitted with the apparatus, for example the apparatus may be installed on a ship.
  • the heater preferably uses heat from the exhaust and/or waste heat from the engine.
  • the heater may hence include a heat exchanger for taking heat from the exhaust and/or from the engine coolant.
  • the method of the first aspect is considered novel and inventive without step (v) and without reference to the saturation level for the solution.
  • the invention provides a method of treatment of combustion gases for carbon dioxide capture comprising: (i) providing a solution of sodium bicarbonate and sodium carbonate in water; (ii) contacting the solution with a combustion gas mixture, the gas mixture including carbon dioxide, such that carbon dioxide reacts with hydroxide ions in the solution to form
  • a yet further aspect provides an apparatus for treatment of exhaust gases for carbon dioxide capture, the apparatus comprising: a reaction vessel containing a solution of sodium bicarbonate and sodium carbonate in water; and a gas delivery device for contacting the solution with a combustion gas mixture, the gas mixture including carbon dioxide, such that carbon dioxide will react with the hydroxide ions in the solution and form bicarbonate ions, wherein the gas delivery device is arranged for continuous delivery of gas so that as a result of the reaction sodium bicarbonate precipitates out of the solution as a solid.
  • the initial capture of carbon dioxide from a gas mixture occurs in a absorber/reaction chamber.
  • the reaction chamber contains a mixture of sodium bicarbonate (NaHC0 3 ) and sodium carbonate (Na 2 C0 3 ) in solution.
  • the solution will contain sodium ions, HC0 3 " ions, C0 3 2" ions and OH " ions together with physically solved C0 2 in equilibrium with carbonic acid.
  • the HC0 3 " ion concentration will be kept close to saturation of sodium bicarbonate.
  • the main reactions will be dissolution of C0 2 in water followed by reaction with OH " ions.
  • C0 2 from the flue gas dissolves into the solution and reacts with OH " forming HC0 3 " which falls out as sediment (sodium bicarbonate).
  • the chamber is continuously fed with solved sodium carbonate at a rate that is equimolar with the C0 2 reaction rate.
  • NaHC0 3 sediment preprocessing The sediment or slurry is extracted from the reaction chamber and excess water may be removed from the sediment.
  • Carbonate (Na 2 C0 3 ) dissolver Dissolving sodium carbonate in water for recycling into the reaction chamber.
  • the starting solution is prepared by adding sodium bicarbonate and sodium carbonate to water until the bicarbonate concentration is close to the saturation point of sodium bicarbonate.
  • the sodium carbonate is added in order to increase the number of hydroxyl ions and carbonate ions.
  • Starting with sodium bicarbonate provides additional advantages as well since it allows a better pH control of the solution. A pure sodium carbonate solution is more aggressive to materials due to its high pH value. Once the sodium bicarbonate is in the solution it is much easier to control the pH of the reaction liquid.
  • concentration in the reaction chamber is controlled, so that it is always close to saturation of sodium bicarbonate. This ensures that carbon dioxide is efficiently reacted and precipitated as sodium bicarbonate. In the sediment preprosessing and the reclaiming process, water can be recycled.
  • the heating in the stripper and reclaimer at (3) will typically be at a temperature in the range 70 °C to 250 °C, for example at a temperature that is close to 160 °C.
  • Other features of the process and the apparatus that carries out the process can be as described above.

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Environmental & Geological Engineering (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Treating Waste Gases (AREA)
  • Gas Separation By Absorption (AREA)

Abstract

L'invention concerne un procédé de traitement de gaz d'échappement pour une capture de dioxyde de carbone, qui consiste à mettre en contact un mélange de gaz de combustion comprenant du dioxyde de carbone avec une solution de bicarbonate de sodium et de carbonate de sodium dans l'eau, de telle sorte que le dioxyde de carbone réagit avec des ions hydroxydes dans la solution pour former des ions de bicarbonate ; poursuivre la mise en contact jusqu'à ce que le bicarbonate de sodium précipite à partir de la solution sous forme solide ; retirer le bicarbonate de sodium solide ; et (v) chauffer le bicarbonate de sodium pour former du carbonate de sodium, de l'eau et du dioxyde de carbone ; pendant les étapes (i) à (iv), la concentration de bicarbonate de sodium dans la solution étant maintenue à 90 % ou plus des niveaux de saturation. Avantageusement, le procédé peut être réalisé dans une boucle de recyclage en continu dans laquelle le bicarbonate de sodium est fractionné par la chaleur en carbonate de sodium, eau et dioxyde de carbone, et le carbonate de sodium est recyclé dans la solution. Le dioxyde de carbone peut être comprimé et stocké.
PCT/EP2014/071800 2013-10-11 2014-10-10 Capture de dioxyde de carbone WO2015052325A1 (fr)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
NO20131355 2013-10-11
GB1318044.3 2013-10-11
NO20131355 2013-10-11
GB201318044A GB201318044D0 (en) 2013-10-11 2013-10-11 Capture of carbon dioxide

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WO2015052325A1 true WO2015052325A1 (fr) 2015-04-16

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2017175044A1 (fr) * 2016-04-05 2017-10-12 L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude Élimination sélective de k+ et de cl- de cendres de précipitateur électrostatique de chaudière de récupération dans un processus de pâte kraft
CN112619370A (zh) * 2020-12-01 2021-04-09 成都正升能源技术开发有限公司 一种二氧化碳驱油田伴生气回收装置及使用方法
CN115228259A (zh) * 2022-07-15 2022-10-25 江西新节氢能源科技有限公司 一种锅炉烟气中二氧化碳和蒸馏水的提取装置及提取方法
CN115282993A (zh) * 2022-09-28 2022-11-04 中国华电科工集团有限公司 一种co2再生催化剂及其制备方法和应用
WO2023087370A1 (fr) * 2021-11-17 2023-05-25 国家电投集团科学技术研究院有限公司 Procédé de capture de dioxyde de carbone pour la production d'hydrogène par électrolyse/pyrolyse étagée couplées

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JPH0338219A (ja) * 1989-07-03 1991-02-19 Chiyoda Corp 排ガスからの炭酸ガスの除去、回収方法
DE102009012104A1 (de) * 2009-03-06 2010-09-09 Herbert Sieger Vorrichtung und Verfahren zur Reduktion von Kohlendioxid
US20100254869A1 (en) * 2007-05-24 2010-10-07 Co2 Purification As Process for removal of carbon dioxide from combustion gases
CA2698275A1 (fr) * 2010-03-31 2011-09-30 Airborne Industrial Minerals, Inc. Methodes de nettoyage de gaz de cheminee
EP2631005A1 (fr) * 2010-10-18 2013-08-28 Wuhan Kaidi Electric Power Co. Ltd. Procédé et appareil pour capturer le dioxyde de carbone dans un gaz de combustion avec du carbonate de sodium activé
WO2013134879A1 (fr) * 2012-03-14 2013-09-19 Co2 Solutions Inc. Utilisation de dioxyde de carbone pour améliorer la production de composés à base de bicarbonates par voie enzymatique

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Publication number Priority date Publication date Assignee Title
JPH0338219A (ja) * 1989-07-03 1991-02-19 Chiyoda Corp 排ガスからの炭酸ガスの除去、回収方法
US20100254869A1 (en) * 2007-05-24 2010-10-07 Co2 Purification As Process for removal of carbon dioxide from combustion gases
DE102009012104A1 (de) * 2009-03-06 2010-09-09 Herbert Sieger Vorrichtung und Verfahren zur Reduktion von Kohlendioxid
CA2698275A1 (fr) * 2010-03-31 2011-09-30 Airborne Industrial Minerals, Inc. Methodes de nettoyage de gaz de cheminee
EP2631005A1 (fr) * 2010-10-18 2013-08-28 Wuhan Kaidi Electric Power Co. Ltd. Procédé et appareil pour capturer le dioxyde de carbone dans un gaz de combustion avec du carbonate de sodium activé
WO2013134879A1 (fr) * 2012-03-14 2013-09-19 Co2 Solutions Inc. Utilisation de dioxyde de carbone pour améliorer la production de composés à base de bicarbonates par voie enzymatique

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2017175044A1 (fr) * 2016-04-05 2017-10-12 L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude Élimination sélective de k+ et de cl- de cendres de précipitateur électrostatique de chaudière de récupération dans un processus de pâte kraft
CN112619370A (zh) * 2020-12-01 2021-04-09 成都正升能源技术开发有限公司 一种二氧化碳驱油田伴生气回收装置及使用方法
CN112619370B (zh) * 2020-12-01 2022-12-27 成都正升能源技术开发有限公司 一种二氧化碳驱油田伴生气回收装置及使用方法
WO2023087370A1 (fr) * 2021-11-17 2023-05-25 国家电投集团科学技术研究院有限公司 Procédé de capture de dioxyde de carbone pour la production d'hydrogène par électrolyse/pyrolyse étagée couplées
CN115228259A (zh) * 2022-07-15 2022-10-25 江西新节氢能源科技有限公司 一种锅炉烟气中二氧化碳和蒸馏水的提取装置及提取方法
CN115282993A (zh) * 2022-09-28 2022-11-04 中国华电科工集团有限公司 一种co2再生催化剂及其制备方法和应用
CN115282993B (zh) * 2022-09-28 2023-02-03 中国华电科工集团有限公司 再生催化剂及其制备方法和应用

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