WO2015050592A2 - Panneau de revêtement pour chambre de combustion de turbine à gaz - Google Patents

Panneau de revêtement pour chambre de combustion de turbine à gaz Download PDF

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Publication number
WO2015050592A2
WO2015050592A2 PCT/US2014/042130 US2014042130W WO2015050592A2 WO 2015050592 A2 WO2015050592 A2 WO 2015050592A2 US 2014042130 W US2014042130 W US 2014042130W WO 2015050592 A2 WO2015050592 A2 WO 2015050592A2
Authority
WO
WIPO (PCT)
Prior art keywords
liner panel
hemi
combustor
recited
liner
Prior art date
Application number
PCT/US2014/042130
Other languages
English (en)
Other versions
WO2015050592A3 (fr
Inventor
Christopher Drake
Frank J. Cunha
Stanislav KOSTKA
Original Assignee
United Technologies Corporation
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by United Technologies Corporation filed Critical United Technologies Corporation
Priority to EP14850876.5A priority Critical patent/EP3008388A4/fr
Priority to US14/897,725 priority patent/US20160123592A1/en
Publication of WO2015050592A2 publication Critical patent/WO2015050592A2/fr
Publication of WO2015050592A3 publication Critical patent/WO2015050592A3/fr

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Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23RGENERATING COMBUSTION PRODUCTS OF HIGH PRESSURE OR HIGH VELOCITY, e.g. GAS-TURBINE COMBUSTION CHAMBERS
    • F23R3/00Continuous combustion chambers using liquid or gaseous fuel
    • F23R3/002Wall structures
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23RGENERATING COMBUSTION PRODUCTS OF HIGH PRESSURE OR HIGH VELOCITY, e.g. GAS-TURBINE COMBUSTION CHAMBERS
    • F23R3/00Continuous combustion chambers using liquid or gaseous fuel
    • F23R3/005Combined with pressure or heat exchangers
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23RGENERATING COMBUSTION PRODUCTS OF HIGH PRESSURE OR HIGH VELOCITY, e.g. GAS-TURBINE COMBUSTION CHAMBERS
    • F23R3/00Continuous combustion chambers using liquid or gaseous fuel
    • F23R3/007Continuous combustion chambers using liquid or gaseous fuel constructed mainly of ceramic components
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23RGENERATING COMBUSTION PRODUCTS OF HIGH PRESSURE OR HIGH VELOCITY, e.g. GAS-TURBINE COMBUSTION CHAMBERS
    • F23R3/00Continuous combustion chambers using liquid or gaseous fuel
    • F23R3/02Continuous combustion chambers using liquid or gaseous fuel characterised by the air-flow or gas-flow configuration
    • F23R3/04Air inlet arrangements
    • F23R3/06Arrangement of apertures along the flame tube
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23RGENERATING COMBUSTION PRODUCTS OF HIGH PRESSURE OR HIGH VELOCITY, e.g. GAS-TURBINE COMBUSTION CHAMBERS
    • F23R2900/00Special features of, or arrangements for continuous combustion chambers; Combustion processes therefor
    • F23R2900/03041Effusion cooled combustion chamber walls or domes
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23RGENERATING COMBUSTION PRODUCTS OF HIGH PRESSURE OR HIGH VELOCITY, e.g. GAS-TURBINE COMBUSTION CHAMBERS
    • F23R2900/00Special features of, or arrangements for continuous combustion chambers; Combustion processes therefor
    • F23R2900/03044Impingement cooled combustion chamber walls or subassemblies
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23RGENERATING COMBUSTION PRODUCTS OF HIGH PRESSURE OR HIGH VELOCITY, e.g. GAS-TURBINE COMBUSTION CHAMBERS
    • F23R2900/00Special features of, or arrangements for continuous combustion chambers; Combustion processes therefor
    • F23R2900/03045Convection cooled combustion chamber walls provided with turbolators or means for creating turbulences to increase cooling
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02TCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
    • Y02T50/00Aeronautics or air transport
    • Y02T50/60Efficient propulsion technologies, e.g. for aircraft

Definitions

  • the present disclosure relates to a gas turbine engine and, more particularly, to a combustor section therefor.
  • Gas turbine engines such as those that power modern commercial and military aircraft, generally include a compressor section to pressurize an airflow, a combustor section to burn a hydrocarbon fuel in the presence of the pressurized air, and a turbine section to extract energy from the resultant combustion gases.
  • Advanced engine cycles require the combustor section to operate at high compressor exit temperatures. A survey of typical flight envelopes often reveals that high compressor exit temperatures exist with reduced supply pressure at high altitude. These operational conditions result in relatively high convection and radiation high heat loads.
  • a liner panel is provided for a combustor of a gas turbine engine according to one disclosed non-limiting embodiment of the present disclosure.
  • This liner panel includes a multiple of heat transfer augmentors. At least one of the multiple of heat transfer augmentors includes a depression. The depression includes an entrance to at least one passage through the liner panel.
  • the entrance to the at least one passage through the liner panel may be displaced from a surface of the liner panel.
  • the at least one passage may be an effusion flow passage.
  • the depression may be a hemi-spherical depression.
  • the entrance may be within the hemi-spherical depression.
  • the entrance may be centered within the hemi-spherical depression.
  • the at least one passage may define an angle through the liner panel.
  • at least one of the multiple of impingement flow passages may be directed between the hemi-spherical protuberance
  • a liner panel is provided for a combustor of a gas turbine engine according to another disclosed non-limiting embodiment of the present disclosure.
  • This liner panel includes a multiple of heat transfer augmentors.
  • a subset of the multiple of heat transfer augmentors includes a hemi-spherical protuberance with a hemi-spherical depression.
  • the hemi-spherical depression includes an entrance to at least one passage through the liner panel.
  • the entrance to the at least one passage through the liner panel may be displaced from a surface of the liner panel.
  • the at least one passage may be an effusion flow passage.
  • the entrance may be centered within a hemi-spherical depression.
  • At least one of the multiple of impingement flow passages may be directed between the hemi-spherical protuberance.
  • the at least one passage may define an angle through the liner panel.
  • a combustor of a gas turbine engine is provided according to another disclosed non-limiting embodiment of the present disclosure.
  • This combustor includes a shell with a multiple of impingement flow passages.
  • the combustor also includes a liner panel mounted to the shell.
  • the liner panel includes a multiple of heat transfer augmentors which extend from a cold side thereof toward the shell.
  • At least one of the multiple of heat transfer augmentors includes a hemi-spherical protuberance with a hemi-spherical depression.
  • the hemi- spherical depression includes an entrance to at least one passage through the liner panel.
  • a plurality of studs may extend from a cold side of the liner panel.
  • At least one of the multiple of impingement flow passages may be directed between the hemi-spherical protuberance.
  • the effusion flow passage may define an angle through the liner panel.
  • At least one of said multiple of impingement flow passages may direct an impingement jet between a subset of said multiple of heat transfer augmentors then over and into said a hemi-spherical depression of said hemi-spherical protuberance.
  • FIG. 1 is a schematic cross-section of an example gas turbine engine architecture
  • FIG. 2 is a schematic cross-section of another example gas turbine engine architecture
  • FIG. 3 is an expanded longitudinal schematic sectional view of a combustor section according to one non-limiting embodiment that may be used with the example gas turbine engine architectures shown in FIGS. 1 and 2;
  • FIG. 4 is an expanded perspective view of a liner panel array from a cold side
  • FIG. 5 is a perspective partial longitudinal sectional view of the combustor section
  • FIG. 6 is an exploded view of a liner assembly of the combustor
  • FIG. 7 is a cold side view of a combustor liner panel with a multiple of heat transfer augmentors according to one disclosed non-limiting embodiment
  • FIG. 8 is a sectional view of the multiple of heat transfer augmentors of FIG.
  • FIG. 1 schematically illustrates a gas turbine engine 20.
  • the gas turbine engine 20 is disclosed herein as a two-spool turbo fan that generally incorporates a fan section 22, a compressor section 24, a combustor section 26 and a turbine section 28.
  • alternative engine architectures 200 might include an augmentor section 12, an exhaust duct section 14 and a nozzle section 16 in addition to the fan section 22', compressor section 24', combustor section 26' and turbine section 28' among other systems or features.
  • the fan section 22 drives air along a bypass flowpath while the compressor section 24 drives air along a core flowpath for compression and communication into the combustor section 26 then expansion through the turbine section 28.
  • turbofan in the disclosed non-limiting embodiment, it should be understood that the concepts described herein are not limited to use with turbofans as the teachings may be applied to other types of turbine engines such as a turbojets, turboshafts, and three-spool (plus fan) turbofans wherein an intermediate spool includes an intermediate pressure compressor (“IPC") between a low pressure compressor (“LPC”) and a high pressure compressor (“HPC”), and an intermediate pressure turbine (“IPT”) between a high pressure turbine (“HPT”) and a low pressure turbine (“LPT”).
  • IPC intermediate pressure compressor
  • LPC low pressure compressor
  • HPC high pressure compressor
  • IPT intermediate pressure turbine
  • the engine 20 generally includes a low spool 30 and a high spool 32 mounted for rotation about an engine central longitudinal axis A relative to an engine static structure 36 via several bearing structures 38.
  • the low spool 30 generally includes an inner shaft 40 that interconnects a fan 42, a low pressure compressor (“LPC”) 44 and a low pressure turbine (“LPT”) 46.
  • the inner shaft 40 drives the fan 42 directly or through a geared architecture 48 to drive the fan 42 at a lower speed than the low spool 30.
  • An exemplary reduction transmission is an epicyclic transmission, namely a planetary or star gear system.
  • the high spool 32 includes an outer shaft 50 that interconnects a high pressure compressor (“HPC”) 52 and a high pressure turbine (“HPT”) 54.
  • a combustor 56 is arranged between the high pressure compressor 52 and the high pressure turbine 54.
  • the inner shaft 40 and the outer shaft 50 are concentric and rotate about the engine central longitudinal axis A which is collinear with their longitudinal axes.
  • the gas turbine engine 20 is a high-bypass geared aircraft engine.
  • the gas turbine engine 20 bypass ratio is greater than about six (6:1).
  • the geared architecture 48 can include an epicyclic gear train, such as a planetary gear system or other gear system.
  • the example epicyclic gear train has a gear reduction ratio of greater than about 2.3, and in another example is greater than about 2.5:1.
  • the geared turbofan enables operation of the low spool 30 at higher speeds which can increase the operational efficiency of the LPC 44 and LPT 46 and render increased pressure in a fewer number of stages.
  • a pressure ratio associated with the LPT 46 is pressure measured prior to the inlet of the LPT 46 as related to the pressure at the outlet of the LPT 46 prior to an exhaust nozzle of the gas turbine engine 20.
  • the bypass ratio of the gas turbine engine 20 is greater than about ten (10:1)
  • the fan diameter is significantly larger than that of the LPC 44
  • the LPT 46 has a pressure ratio that is greater than about five (5:1). It should be understood, however, that the above parameters are only exemplary of one embodiment of a geared architecture engine and that the present disclosure is applicable to other gas turbine engines including direct drive turbofans.
  • a significant amount of thrust is provided by the bypass flow path due to the high bypass ratio.
  • the fan section 22 of the gas turbine engine 20 is designed for a particular flight condition - typically cruise at about 0.8 Mach and about 35,000 feet. This flight condition, with the gas turbine engine 20 at its best fuel consumption, is also known as bucket cruise Thrust Specific Fuel Consumption (TSFC).
  • TSFC Thrust Specific Fuel Consumption
  • Fan Pressure Ratio is the pressure ratio across a blade of the fan section 22 without the use of a Fan Exit Guide Vane system.
  • the low Fan Pressure Ratio according to one non-limiting embodiment of the example gas turbine engine 20 is less than 1.45.
  • Low Corrected Fan Tip Speed is the actual fan tip speed divided by an industry standard temperature correction of ("Tram" / 518.7) 0'5 .
  • the Low Corrected Fan Tip Speed according to one non-limiting embodiment of the example gas turbine engine 20 is less than about 1150 fps (351 m/s).
  • the combustor section 26 generally includes a combustor 56 with an outer combustor liner assembly 60, an inner combustor liner assembly 62 and a diffuser case module 64.
  • the outer combustor liner assembly 60 and the inner combustor liner assembly 62 are spaced apart such that a combustion chamber 66 is defined therebetween.
  • the combustion chamber 66 is generally annular in shape.
  • the outer combustor liner assembly 60 is spaced radially inward from an outer diffuser case 64-0 of the diffuser case module 64 to define an outer annular plenum 76.
  • the inner combustor liner assembly 62 is spaced radially outward from an inner diffuser case 64- I of the diffuser case module 64 to define an inner annular plenum 78. It should be understood that although a particular combustor is illustrated, other combustor types with various combustor liner arrangements will also benefit herefrom. It should be further understood that the disclosed cooling flow paths are but an illustrated embodiment and should not be limited only thereto.
  • the combustor liner assemblies 60, 62 contain the combustion products for direction toward the turbine section 28.
  • Each combustor liner assembly 60, 62 generally includes a respective support shell 68, 70 which supports one or more liner panels 72, 74 mounted to a hot side of the respective support shell 68, 70.
  • Each of the liner panels 72, 74 may be generally rectilinear and manufactured of, for example, a nickel based super alloy, ceramic or other temperature resistant material and are arranged to form a liner array.
  • the liner array includes a multiple of forward liner panels 72A and a multiple of aft liner panels 72B that are circumferentially staggered to line the hot side of the outer shell 68 (also shown in FIG. 4).
  • a multiple of forward liner panels 74A and a multiple of aft liner panels 74B are circumferentially staggered to line the hot side of the inner shell 70.
  • the combustor 56 further includes a forward assembly 80 immediately downstream of the compressor section 24 to receive compressed airflow therefrom.
  • the forward assembly 80 generally includes an annular hood 82, a bulkhead assembly 84, a multiple of fuel nozzles 86 (one shown) and a multiple of fuel nozzle guides 90 (one shown).
  • Each of the fuel nozzle guides 90 is circumferentially aligned with one of the hood ports 94 to project through the bulkhead assembly 84.
  • Each bulkhead assembly 84 includes a bulkhead support shell 96 secured to the combustor liner assemblies 60, 62, and a multiple of circumferentially distributed bulkhead liner panels 98 secured to the bulkhead support shell 96 around the central opening 92.
  • the annular hood 82 extends radially between, and is secured to, the forwardmost ends of the combustor liner assemblies 60, 62.
  • the annular hood 82 includes a multiple of circumferentially distributed hood ports 94 that accommodate the respective fuel nozzle 86 and introduce air into the forward end of the combustion chamber 66 through the central opening 92.
  • Each fuel nozzle 86 may be secured to the diffuser case module 64 and project through one of the hood ports 94 and through the central opening 92 within the respective fuel nozzle guide 90.
  • the forward assembly 80 introduces core combustion air into the forward section of the combustion chamber 66 while the remainder enters the outer annular plenum 76 and the inner annular plenum 78.
  • the multiple of fuel nozzles 86 and adjacent structure generate a blended fuel-air mixture that supports stable combustion in the combustion chamber 66.
  • the NGVs 54A are static engine components which direct core airflow combustion gases onto the turbine blades of the first turbine rotor in the turbine section 28 to facilitate the conversion of pressure energy into kinetic energy.
  • the core airflow combustion gases are also accelerated by the NGVs 54A because of their convergent shape and are typically given a "spin” or a “swirl” in the direction of turbine rotor rotation.
  • the turbine rotor blades absorb this energy to drive the turbine rotor at high speed.
  • a multiple of studs 100 extend from the liner panels 72, 74 so as to permit the liner panels 72, 74 to be mounted to their respective support shells 68, 70 with fasteners 102 such as nuts (shown in FIG. 5). That is, the studs 100 project rigidly from the liner panels 72, 74 and through the respective support shells 68, 70 to receive the fasteners 102 at a threaded distal end section thereof.
  • a multiple of cooling impingement passages 104 penetrate through the support shells 68, 70 to allow air from the respective annular plenums 76, 78 to enter cavities 106A, 106B (also shown in FIG. 6) formed in the combustor liner assemblies 60, 62 between the respective support shells 68, 70 and liner panels 72, 74.
  • the cooling impingement passages 104 are generally normal to the surface of the liner panels 72, 74.
  • the air in the cavities 106 A, 106B provides cold side impingement cooling of the liner panels 72, 74 that is generally defined herein as heat removal via internal convection.
  • a multiple of effusion passages 108 penetrate through each of the liner panels 72, 74.
  • the geometry of the passages e.g., diameter, shape, density, surface angle, incidence angle, etc.
  • the combination of impingement passages 104 and effusion passages 108 may be referred to as an Impingement Film Floatwall (IFF) assembly.
  • IFF Impingement Film Floatwall
  • the effusion passages 108 allow the air to pass from the cavities 106 A, 106B defined in part by a cold side 110 of the liner panels 72, 74 to a hot side 112 of the liner panels 72, 74 and thereby facilitate the formation of thin, cool, insulating blanket or film of cooling air along the hot side 112.
  • the effusion passages 108 are generally more numerous than the impingement passages 104 to promote the development of film cooling along the hot side 112 to sheath the liner panels 72, 74.
  • Film cooling as defined herein is the introduction of a relatively cooler air at one or more discrete locations along a surface exposed to a high temperature environment to protect that surface in the region of the air injection as well as downstream thereof.
  • a multiple of dilution passages 116 may penetrate through both the respective support shells 68, 70 and liner panels 72, 74 along a common axis D (see FIG. 5).
  • the dilution passages 116 are located downstream of the forward assembly 80 to quench the hot combustion gases within the combustion chamber 66 by direct supply of cooling air from the respective annular plenums 76, 78.
  • Tl is a temperature in front of the fan section 22; T2 is a temperature at the leading edge of the fan 42; T2.5 is the temperature between the LPC 44 and the HPC 52; T3 is the temperature aft of the HPC 52; T4 is the temperature in the combustion chamber 66; T4.5 is the temperature between the HPT 54 and the LPT 46; and T5 is the temperature aft of the LPT 46 (see FIG. 1).
  • a multiple of heat transfer augmentors 118 extend from the cold side 110 of each liner panel 72, 74 to increase heat transfer.
  • the support shells 68, 70 and liner panels 72, 74 may be manufactured via an additive manufacturing process that facilitates incorporation of the relatively small heat transfer augmentors 118 as well as the cooling impingement passages 104, the effusion passages 108, the dilution passages 116 and or other features.
  • One additive manufacturing process includes powder bed metallurgy in which layers of powder alloy such as nickel, cobalt, or other material is sequentially build-up by systems from, for example, Concept Laser of Lichtenfels, DE and EOS of Kunststoff, DE, e.g. direct metal laser sintering or electron beam melting.
  • each of the multiple of heat transfer augmentors 118 defines a hemi-spherical protuberance 120 which flanks a valley 122 defined by the cold side 110 of each liner panel 72, 74.
  • the valley 122 is defined by a subset of four (4) hemi-spherical protuberances 120; however, other geometries will also benefit herefrom.
  • Each hemi-spherical protuberance 120 includes a hemi-spherical depression 124 with an entrance 126 to a respective effusion passage 108. That is, the hemi-spherical depressions 124 are recesses defined in the respective hemi-spherical protuberances 120 to facilitate capture and direction of air into each of the effusion passages 108.
  • the hemi-spherical depression 124 is offset from the cold side 110 of each liner panel 72, 74.
  • the entrance 126 may be displaced from an exit 128 of the effusion passages 108 such that the effusion passage 108 defines an angle through each liner panel 72, 74 (see FIG. 8). That is, the effusion passage 108 need not be perpendicular through each liner panel 72, 74.
  • the multiple of cooling impingement passages 104 penetrate through the support shells 68, 70 to allow air within the respective annular plenums 76, 78 to impinge onto the respective valley 122. That is, impingement air from the multiple of cooling passages 104 may be directed between the hemi- spherical protuberances 120 such that the impingement air will tabulate and cause a pressure increase.
  • the pressure drop causes the impingement air to navigate into the hemi-spherical depression 124, thence into the effusion passage 108 and into the combustor chamber 66.
  • the entrance 126 to the effusion passages 108 is raised from the flat cold side 110 of the liner panel 72, 74 by the respective protuberance in which it is defined, and surrounded by the bowl of the hemi-spherical depression 124 to form a tortious path for the navigation of cooling air thereto. This tortuous path increases the time for convective heat transfer, and increases cooling effectiveness.
  • the effusion passages 108 are through the relatively thicker portion of the liner panel 72, 74, which thereby provides additional surface area for effusion cooling effectiveness.
  • Cooling effectiveness of the liner panel 72, 74 may depend on a number of factors, one of which is the heat transfer coefficient. This heat transfer coefficient depicts how well heat is transferred from the liner panel 72, 74 to the cooling air. As the liner panel 72, 74 surface area increases on account of the protuberances 120 and depressions 124, this coefficient increases due to a greater ability to transfer heat to the cooling air. Turbulation of the air also increases this heat transfer.
  • the multiple of heat transfer augmentors 118 increase surface area, promote turbulence, increase thermal efficiency, and facilitate film cooling as the spent impingement flow is directed towards the effusion passages 108 (see FIG. 8).
  • the heat transfer relies primarily on the surface heat transfer augmentors 118 and the attributes thereof. In general, flow transition from the stagnation impingement flow to turbulence follows the mechanism associated with turbulence creation through unstable Tollmien-Schiliting waves, three-dimensional instability, then by vortex breakdown in a cascading process which leads to intense flow fluctuations and energy exchange or high heat transfer.

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Turbine Rotor Nozzle Sealing (AREA)

Abstract

On décrit un panneau de revêtement pour chambre de combustion de turbine à gaz. Le panneau de revêtement comprend de multiples concentrateurs de flux de transfert de chaleur. Au moins l'un des multiples concentrateurs de flux de transfert de chaleur comprend une dépression présentant une entrée d'au moins un passage traversant le panneau de revêtement.
PCT/US2014/042130 2013-06-14 2014-06-12 Panneau de revêtement pour chambre de combustion de turbine à gaz WO2015050592A2 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
EP14850876.5A EP3008388A4 (fr) 2013-06-14 2014-06-12 Panneau de revêtement pour chambre de combustion de turbine à gaz
US14/897,725 US20160123592A1 (en) 2013-06-14 2014-06-12 Gas turbine engine combustor liner panel

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US201361835153P 2013-06-14 2013-06-14
US61/835,153 2013-06-14
US201361865912P 2013-08-14 2013-08-14
US61/865,912 2013-08-14

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Publication Number Publication Date
WO2015050592A2 true WO2015050592A2 (fr) 2015-04-09
WO2015050592A3 WO2015050592A3 (fr) 2015-06-11

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US (1) US20160123592A1 (fr)
EP (1) EP3008388A4 (fr)
WO (1) WO2015050592A2 (fr)

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