WO2015041763A1 - Method and structure for reducing the propagation of cracks in epitaxial films formed on semiconductor wafers - Google Patents

Method and structure for reducing the propagation of cracks in epitaxial films formed on semiconductor wafers Download PDF

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Publication number
WO2015041763A1
WO2015041763A1 PCT/US2014/049708 US2014049708W WO2015041763A1 WO 2015041763 A1 WO2015041763 A1 WO 2015041763A1 US 2014049708 W US2014049708 W US 2014049708W WO 2015041763 A1 WO2015041763 A1 WO 2015041763A1
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Prior art keywords
epitaxial film
wafer
silicon
outer peripheral
semiconductor wafer
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PCT/US2014/049708
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French (fr)
Inventor
Kelly P. Ip
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Raytheon Co
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Raytheon Co
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    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10P—GENERIC PROCESSES OR APPARATUS FOR THE MANUFACTURE OR TREATMENT OF DEVICES COVERED BY CLASS H10
    • H10P14/00—Formation of materials, e.g. in the shape of layers or pillars
    • H10P14/20—Formation of materials, e.g. in the shape of layers or pillars of semiconductor materials
    • H10P14/34—Deposited materials, e.g. layers
    • H10P14/3402—Deposited materials, e.g. layers characterised by the chemical composition
    • H10P14/3414—Deposited materials, e.g. layers characterised by the chemical composition being group IIIA-VIA materials
    • H10P14/3416—Nitrides
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10P—GENERIC PROCESSES OR APPARATUS FOR THE MANUFACTURE OR TREATMENT OF DEVICES COVERED BY CLASS H10
    • H10P90/00—Preparation of wafers not covered by a single main group of this subclass, e.g. wafer reinforcement
    • C—CHEMISTRY; METALLURGY
    • C30—CRYSTAL GROWTH
    • C30B—SINGLE-CRYSTAL GROWTH; UNIDIRECTIONAL SOLIDIFICATION OF EUTECTIC MATERIAL OR UNIDIRECTIONAL DEMIXING OF EUTECTOID MATERIAL; REFINING BY ZONE-MELTING OF MATERIAL; PRODUCTION OF A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; SINGLE CRYSTALS OR HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; AFTER-TREATMENT OF SINGLE CRYSTALS OR A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; APPARATUS THEREFOR
    • C30B29/00—Single crystals or homogeneous polycrystalline material with defined structure characterised by the material or by their shape
    • C30B29/10—Inorganic compounds or compositions
    • C30B29/40—AIIIBV compounds wherein A is B, Al, Ga, In or Tl and B is N, P, As, Sb or Bi
    • C30B29/403—AIII-nitrides
    • C—CHEMISTRY; METALLURGY
    • C30—CRYSTAL GROWTH
    • C30B—SINGLE-CRYSTAL GROWTH; UNIDIRECTIONAL SOLIDIFICATION OF EUTECTIC MATERIAL OR UNIDIRECTIONAL DEMIXING OF EUTECTOID MATERIAL; REFINING BY ZONE-MELTING OF MATERIAL; PRODUCTION OF A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; SINGLE CRYSTALS OR HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; AFTER-TREATMENT OF SINGLE CRYSTALS OR A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; APPARATUS THEREFOR
    • C30B33/00—After-treatment of single crystals or homogeneous polycrystalline material with defined structure
    • C30B33/08—Etching
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
    • H10D62/00—Semiconductor bodies, or regions thereof, of devices having potential barriers
    • H10D62/80—Semiconductor bodies, or regions thereof, of devices having potential barriers characterised by the materials
    • H10D62/85—Semiconductor bodies, or regions thereof, of devices having potential barriers characterised by the materials being Group III-V materials, e.g. GaAs
    • H10D62/8503—Nitride Group III-V materials, e.g. AlN or GaN
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10P—GENERIC PROCESSES OR APPARATUS FOR THE MANUFACTURE OR TREATMENT OF DEVICES COVERED BY CLASS H10
    • H10P50/00—Etching of wafers, substrates or parts of devices
    • H10P50/60—Wet etching
    • H10P50/64—Wet etching of semiconductor materials
    • H10P50/642—Chemical etching
    • H10P50/646—Chemical etching of Group III-V materials
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10P—GENERIC PROCESSES OR APPARATUS FOR THE MANUFACTURE OR TREATMENT OF DEVICES COVERED BY CLASS H10
    • H10P50/00—Etching of wafers, substrates or parts of devices
    • H10P50/69—Etching of wafers, substrates or parts of devices using masks for semiconductor materials
    • H10P50/691—Etching of wafers, substrates or parts of devices using masks for semiconductor materials for Group V materials or Group III-V materials
    • H10P50/693—Etching of wafers, substrates or parts of devices using masks for semiconductor materials for Group V materials or Group III-V materials characterised by their size, orientation, disposition, behaviour or shape, in horizontal or vertical plane
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10P—GENERIC PROCESSES OR APPARATUS FOR THE MANUFACTURE OR TREATMENT OF DEVICES COVERED BY CLASS H10
    • H10P90/00—Preparation of wafers not covered by a single main group of this subclass, e.g. wafer reinforcement
    • H10P90/19—Preparing inhomogeneous wafers
    • H10P90/1904—Preparing vertically inhomogeneous wafers
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10P—GENERIC PROCESSES OR APPARATUS FOR THE MANUFACTURE OR TREATMENT OF DEVICES COVERED BY CLASS H10
    • H10P14/00—Formation of materials, e.g. in the shape of layers or pillars
    • H10P14/20—Formation of materials, e.g. in the shape of layers or pillars of semiconductor materials
    • H10P14/29—Formation of materials, e.g. in the shape of layers or pillars of semiconductor materials characterised by the substrates
    • H10P14/2926—Crystal orientations

Definitions

  • This disclosure relates generally to methods and structures for reducing the propagation of cracks in epitaxial films formed on semiconductor wafers and more particularly to methods for reducing the propagation of cracks in epitaxial films having a different crystallographic structure than the crystallographic structure of the
  • Group III-N epitaxial film growth on Si substrates tend to have high stress developed in the films, leading to crack formation at the edge of the epitaxial layers that may propagate further into interior regions of the epitaxial layer as a result of subsequent processing.
  • the wafers with the epitaxial layers are exposed to subsequent mechanical stress, such as electrostatic chucks, backside vacuum, and robotic vacuum handling, and thermal stresses, such as during thin film deposition and anneal, which can cause the cracks in the edges of the epitaxial film to propagate and degrade the epitaxial film and/or cause wafer breakage.
  • the epitaxial film has a different crystallographic structure than the crystallographic structure of the semiconductor wafer.
  • the wafer is silicon and the epitaxial film is a compound of nitrogen.
  • the wafer is silicon and the epitaxial film is a Group III-N material.
  • the wafer is silicon and the epitaxial film is a Gallium Nitride.
  • the silicon is ⁇ 111> silicon.
  • a method comprising: providing a semiconductor wafer with an epitaxial film thereon, the epitaxial film having outer peripheral regions with cracks therein; and selectively removing peripheral regions of the epitaxial film while leaving portions of the semiconductor wafer underlying the removed determined outer peripheral regions of the epitaxial film.
  • a semiconductor structure comprising: a semiconductor wafer, the wafer having an outer peripheral edge; and an epitaxial film disposed on and in direct contact with a central portion of the semiconductor wafer and being displaced a predetermined distance from the peripheral edge of the wafer.
  • FIGS. 1A- IE are diagrammatical cross sectional sketches, greatly exaggerated in scale, taken along a diameter of a circular semiconductor wafer, showing a method for reducing the propagation of cracks in epitaxial films formed on a surface of the
  • a structure 10 having a semiconductor wafer 12, here a ⁇ 1 1 1> silicon wafer having a diameter of here, for example, an eight inch diameter circular wafer is shown.
  • the wafer 12 has an epitaxial film 14, here a compound of nitrogen, for example a Group III-N film, such as GaN which may include layers of AlGaN, for example.
  • an epitaxial film 14 here a compound of nitrogen, for example a Group III-N film, such as GaN which may include layers of AlGaN, for example.
  • After obtaining the structure 10 having the wafer 10 and the epitaxial film 14 thereon is inspected for cracks in outer peripheral edges of the epitaxial film 12. These cracks may exist inwardly from the edges up to 5 mm (0.197 inches). The inspection is used to determine how from the edges the cracks have propagated into interior regions of the epitaxial film 14.
  • a protective layer 16 for the epitaxial layer 14 is formed over the upper surface of the epitaxial film 16.
  • the protection layer 16 may be for example, a dielectric such as Atomic Layer Deposited (ALD) A1 2 0 3 . It is noted that the use of the protective layer 16 is an optional step in the process.
  • the protective layer 16 is coated with a photoresist layer 18, for example, SPR-220 photoresist, and patterned, using any conventional photoresist layer 18, for example, SPR-220 photoresist, and patterned, using any conventional photoresist layer 18, for example, SPR-220 photoresist, and patterned, using any conventional photoresist layer 18, for example, SPR-220 photoresist, and patterned, using any conventional photoresist layer 18, for example, SPR-220 photoresist, and patterned, using any conventional
  • photolithographic process or etch bead removal process to leave a portion of the photoresist 18 over the interior portions of the epitaxial film 14 and remove portions of the photoresist 18 from regions about the outer edge peripheral regions 20 of the epitaxial film 14 where the cracks in the epitaxial film 14 were determined to exist, as shown in FIG. 1C. It is understood that if the protective layer 16 is not used, the photoresist layer 18 would be deposited directly to the surface of the epitaxial layer 14 and the
  • a shadow mask can be used to expose the edge of the wafer.
  • the surface of the structure shown in FIG. 1C is plasma etched in chlorine-based chemistry to remove portions of the protective layer 16 and underlying portions of the epitaxial film 14 exposed by the photoresist layer 18. It is noted that to insure complete removal of the exposed portions of the epitaxial film 16, the etch process may remove a small upper exposed surface portion of the wafer 12. Thus, the process selectively removes the determined outer peripheral edge regions of the epitaxial film while leaving portions of the semiconductor wafer underlying the removed determined outer peripheral regions of the epitaxial film.
  • a semiconductor structure FIG.
  • the method may include one or more of the following features either independently or in combination with another feature including: wherein the epitaxial film has a different crystallographic structure than the
  • the wafer is silicon and the epitaxial film is a compound of nitrogen; wherein the wafer is silicon and the epitaxial film is a Group III-N material; wherein the wafer is silicon and the epitaxial film is Gallium Nitride, Indium Gallium Nitride, Aluminum Nitride or Aluminum Indium
  • the method according to the disclosure includes: providing a semiconductor wafer with an epitaxial film thereon, the epitaxial film having outer peripheral regions with cracks therein;
  • the method may include one or more of the following features either independently or in combination with another feature including: wherein the epitaxial film has a different crystallographic structure than the crystallographic structure of the semiconductor wafer; wherein the wafer is silicon and the epitaxial film is a compound of nitrogen; wherein the wafer is silicon and the epitaxial film is a Group III-N material;
  • the wafer is silicon and the epitaxial film is Gallium Nitride, Indium Gallium Nitride, Aluminum Nitride or Aluminum Indium Gallium Nitride; or wherein the silicon has a ⁇ l l l> silicon.
  • a semiconductor structure includes: a semiconductor wafer, the wafer having an outer peripheral edge; an epitaxial film disposed on and in direct contact with a central portion of the semiconductor wafer and being displaced a predetermined distance from the peripheral edge of the wafer.
  • the semiconductor structure may include one or more of the following features either independently or in combination with another feature including: wherein the epitaxial film has a different crystallographic structure than the crystallographic structure of the semiconductor wafer; wherein the wafer is silicon and the epitaxial film is a compound of nitrogen; wherein the wafer is silicon and the epitaxial film is a Group III-N material; wherein the wafer is silicon and the epitaxial film is Gallium Nitride, Indium Gallium Nitride, Aluminum Nitride or Aluminum Indium Gallium Nitride; wherein the silicon has a ⁇ 1 1 1> silicon.

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  • Chemical & Material Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Recrystallisation Techniques (AREA)
  • Chemical Vapour Deposition (AREA)

Abstract

A method for reducing the effects of cracks in an epitaxial film. The method includes: providing a semiconductor wafer with an epitaxial film thereon; inspecting the epitaxial film to determine outer peripheral edge regions of the epitaxial film having cracks therein; and selectively removing the determined outer peripheral edge regions of the epitaxial film while leaving portions of the semiconductor wafer underlying the removed determined outer peripheral regions of the epitaxial film.

Description

METHOD AND STRUCTURE FOR REDUCING THE
PROPAGATION OF CRACKS IN EPITAXIAL FILMS FORMED ON
SEMICONDUCTOR WAFERS
TECHNICAL FIELD
[0001] This disclosure relates generally to methods and structures for reducing the propagation of cracks in epitaxial films formed on semiconductor wafers and more particularly to methods for reducing the propagation of cracks in epitaxial films having a different crystallographic structure than the crystallographic structure of the
semiconductor wafer.
BACKGROUND
[0002] As is known in the art, Group III-N epitaxial film growth on Si substrates tend to have high stress developed in the films, leading to crack formation at the edge of the epitaxial layers that may propagate further into interior regions of the epitaxial layer as a result of subsequent processing. During fabrication, the wafers with the epitaxial layers are exposed to subsequent mechanical stress, such as electrostatic chucks, backside vacuum, and robotic vacuum handling, and thermal stresses, such as during thin film deposition and anneal, which can cause the cracks in the edges of the epitaxial film to propagate and degrade the epitaxial film and/or cause wafer breakage.
SUMMARY
[0003] In accordance with the present disclosure, a method is provided comprising:
providing a semiconductor wafer with an epitaxial film thereon; inspecting the epitaxial film to determine outer peripheral edge regions of the epitaxial film having cracks therein; and selectively removing the determined outer peripheral edge regions of the epitaxial film while leaving portions of the semiconductor wafer underlying the removed determined outer peripheral regions of the epitaxial film.
[0004] In one embodiment, the epitaxial film has a different crystallographic structure than the crystallographic structure of the semiconductor wafer.
[0005] In one embodiment, the wafer is silicon and the epitaxial film is a compound of nitrogen. [0006] In one embodiment, the wafer is silicon and the epitaxial film is a Group III-N material.
[0007] In one embodiment, the wafer is silicon and the epitaxial film is a Gallium Nitride. [0008] In one embodiment, the silicon is <111> silicon.
[0009] In one embodiment a method is provided comprising: providing a semiconductor wafer with an epitaxial film thereon, the epitaxial film having outer peripheral regions with cracks therein; and selectively removing peripheral regions of the epitaxial film while leaving portions of the semiconductor wafer underlying the removed determined outer peripheral regions of the epitaxial film.
[0010] In one embodiment, a semiconductor structure is provided, comprising: a semiconductor wafer, the wafer having an outer peripheral edge; and an epitaxial film disposed on and in direct contact with a central portion of the semiconductor wafer and being displaced a predetermined distance from the peripheral edge of the wafer.
[0011] With such method, the cracked edges of III-N epitaxial films are removed from the Si substrates. As a result, the edge cracks are eliminated and no longer propagate through the epitaxial film during subsequent processing.
[0012] The details of one or more embodiments of the disclosure are set forth in the accompanying drawings and the description below. Other features, objects, and
advantages of the disclosure will be apparent from the description and drawings, and from the claims.
DESCRIPTION OF DRAWINGS
[0013] FIGS. 1A- IE are diagrammatical cross sectional sketches, greatly exaggerated in scale, taken along a diameter of a circular semiconductor wafer, showing a method for reducing the propagation of cracks in epitaxial films formed on a surface of the
semiconductor wafer according to the disclosure. [0014] Like reference symbols in the various drawings indicate like elements.
DETAILED DESCRIPTION
[0015] Referring now to FIG. 1A, a structure 10 having a semiconductor wafer 12, here a <1 1 1> silicon wafer having a diameter of here, for example, an eight inch diameter circular wafer is shown. The wafer 12 has an epitaxial film 14, here a compound of nitrogen, for example a Group III-N film, such as GaN which may include layers of AlGaN, for example. After obtaining the structure 10 having the wafer 10 and the epitaxial film 14 thereon is inspected for cracks in outer peripheral edges of the epitaxial film 12. These cracks may exist inwardly from the edges up to 5 mm (0.197 inches). The inspection is used to determine how from the edges the cracks have propagated into interior regions of the epitaxial film 14. Once this is determined, a protective layer 16 (FIG. IB) for the epitaxial layer 14 is formed over the upper surface of the epitaxial film 16. The protection layer 16 may be for example, a dielectric such as Atomic Layer Deposited (ALD) A1203. It is noted that the use of the protective layer 16 is an optional step in the process.
[0016] Next, referring to FIG. 1C, the protective layer 16 is coated with a photoresist layer 18, for example, SPR-220 photoresist, and patterned, using any conventional
photolithographic process or etch bead removal process, to leave a portion of the photoresist 18 over the interior portions of the epitaxial film 14 and remove portions of the photoresist 18 from regions about the outer edge peripheral regions 20 of the epitaxial film 14 where the cracks in the epitaxial film 14 were determined to exist, as shown in FIG. 1C. It is understood that if the protective layer 16 is not used, the photoresist layer 18 would be deposited directly to the surface of the epitaxial layer 14 and the
photolithographically processed as described above. Alternatively, a shadow mask can be used to expose the edge of the wafer.
[0017] Next, and referring to FIG. ID, the surface of the structure shown in FIG. 1C is plasma etched in chlorine-based chemistry to remove portions of the protective layer 16 and underlying portions of the epitaxial film 14 exposed by the photoresist layer 18. It is noted that to insure complete removal of the exposed portions of the epitaxial film 16, the etch process may remove a small upper exposed surface portion of the wafer 12. Thus, the process selectively removes the determined outer peripheral edge regions of the epitaxial film while leaving portions of the semiconductor wafer underlying the removed determined outer peripheral regions of the epitaxial film. Thus, a semiconductor structure (FIG. I E) is provided having the semiconductor wafer 12 having an outer peripheral edge; and the epitaxial film 14 disposed on and in direct contact with a central portion of the semiconductor wafer 12 and being displaced a predetermined distance from the peripheral edge of the wafer 12. The resulting structure, shown in FIG. I E, with the edge cracks now removed from the outer peripheral edge portions of the epitaxial layer is now ready for further processing.
[0018] It should now be appreciated a method according to the disclosure includes:
providing a semiconductor wafer with an epitaxial film thereon; inspecting the epitaxial film to determine outer peripheral edge regions of the epitaxial film having cracks therein; and selectively removing the determined outer peripheral edge regions of the epitaxial film while leaving portions of the semiconductor wafer underlying the removed determined outer peripheral regions of the epitaxial film. The method may include one or more of the following features either independently or in combination with another feature including: wherein the epitaxial film has a different crystallographic structure than the
crystallographic structure of the semiconductor wafer; wherein the wafer is silicon and the epitaxial film is a compound of nitrogen; wherein the wafer is silicon and the epitaxial film is a Group III-N material; wherein the wafer is silicon and the epitaxial film is Gallium Nitride, Indium Gallium Nitride, Aluminum Nitride or Aluminum Indium
Gallium Nitride; or wherein the silicon has a <1 1 1> silicon. Alternatively, the method according to the disclosure includes: providing a semiconductor wafer with an epitaxial film thereon, the epitaxial film having outer peripheral regions with cracks therein;
selectively removing peripheral regions of the epitaxial film while leaving portions of the semiconductor wafer underlying the removed determined outer peripheral regions of the epitaxial film. The method may include one or more of the following features either independently or in combination with another feature including: wherein the epitaxial film has a different crystallographic structure than the crystallographic structure of the semiconductor wafer; wherein the wafer is silicon and the epitaxial film is a compound of nitrogen; wherein the wafer is silicon and the epitaxial film is a Group III-N material;
wherein the wafer is silicon and the epitaxial film is Gallium Nitride, Indium Gallium Nitride, Aluminum Nitride or Aluminum Indium Gallium Nitride; or wherein the silicon has a <l l l> silicon.
[0019] It should now be appreciated a semiconductor structure according to the disclosure includes: a semiconductor wafer, the wafer having an outer peripheral edge; an epitaxial film disposed on and in direct contact with a central portion of the semiconductor wafer and being displaced a predetermined distance from the peripheral edge of the wafer. The semiconductor structure may include one or more of the following features either independently or in combination with another feature including: wherein the epitaxial film has a different crystallographic structure than the crystallographic structure of the semiconductor wafer; wherein the wafer is silicon and the epitaxial film is a compound of nitrogen; wherein the wafer is silicon and the epitaxial film is a Group III-N material; wherein the wafer is silicon and the epitaxial film is Gallium Nitride, Indium Gallium Nitride, Aluminum Nitride or Aluminum Indium Gallium Nitride; wherein the silicon has a <1 1 1> silicon.
[0020] A number of embodiments of the disclosure have been described. Nevertheless, it will be understood that various modifications may be made without departing from the spirit and scope of the disclosure. Accordingly, other embodiments are within the scope of the following claims.

Claims

WHAT IS CLAIMED IS:
1. A method comprising:
providing a semiconductor wafer with an epitaxial film thereon;
inspecting the epitaxial film to determine outer peripheral edge regions of the epitaxial film having cracks therein; and
selectively removing the determined outer peripheral edge regions of the epitaxial film while leaving portions of the semiconductor wafer underlying the removed determined outer peripheral regions of the epitaxial film.
2. The method recited in claim 1 wherein the epitaxial film has a different crystallographic structure than the crystallographic structure of the semiconductor wafer.
3. The method recited in claim 2 wherein the wafer is silicon and the epitaxial film is a compound of nitrogen.
4. The method recited in claim 2 wherein the wafer is silicon and the epitaxial film is a Group III-N material.
5. The method recited in claim 1 wherein the wafer is silicon and the epitaxial film is Gallium Nitride, Indium Gallium Nitride, Aluminum Nitride or Aluminum Indium Gallium Nitride.
6. The method recited in claim 5 wherein the silicon has a <11 1> silicon.
7. A method comprising:
providing a semiconductor wafer with an epitaxial film thereon, the epitaxial film having outer peripheral regions with cracks therein;
selectively removing peripheral regions of the epitaxial film while leaving portions of the semiconductor wafer underlying the removed determined outer peripheral regions of the epitaxial film.
8. The method recited in claim 7 wherein the epitaxial film has a different crystallographic structure than the crystallographic structure of the semiconductor wafer.
9. The method recited in claim 8 wherein the wafer is silicon and the epitaxial film is a compound of nitrogen.
10. The method recited in claim 8 wherein the wafer is silicon and the epitaxial film is a Group III-N material.
1 1. The method recited in claim 7 wherein the wafer is silicon and the epitaxial film is Gallium Nitride, Indium Gallium Nitride, Aluminum Nitride or Aluminum Indium Gallium Nitride.
12. The method recited in claim 1 1 wherein the silicon has a <1 1 1> silicon.
13. A semiconductor structure comprising:
a semiconductor wafer, the wafer having an outer peripheral edge;
an epitaxial film disposed on and in direct contact with a central portion of the semiconductor wafer and being displaced a predetermined distance from the peripheral edge of the wafer.
14. The semiconductor structure recited in claim 13 wherein the epitaxial film has a different crystallographic structure than the crystallographic structure of the
semiconductor wafer.
15. The semiconductor structure recited in claim 14 wherein the wafer is silicon and the epitaxial film is a compound of nitrogen.
16. The semiconductor structure recited in claim 14 wherein the wafer is silicon and the epitaxial film is a Group III-N material.
17. The semiconductor structure recited in claim 13 wherein the wafer is silicon and the epitaxial film is Gallium Nitride, Indium Gallium Nitride, Aluminum Nitride or Aluminum Indium Gallium Nitride.
18. The semiconductor structure recited in claim 17 wherein the silicon has a
<1 11> silicon.
PCT/US2014/049708 2013-09-20 2014-08-05 Method and structure for reducing the propagation of cracks in epitaxial films formed on semiconductor wafers Ceased WO2015041763A1 (en)

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Publication number Priority date Publication date Assignee Title
JP6261388B2 (en) * 2014-03-05 2018-01-17 信越半導体株式会社 Manufacturing method of semiconductor epitaxial wafer
US10199216B2 (en) * 2015-12-24 2019-02-05 Infineon Technologies Austria Ag Semiconductor wafer and method
CN115705995A (en) * 2021-08-04 2023-02-17 无锡华润微电子有限公司 Nitride epitaxial structure and preparation method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH09181349A (en) * 1995-12-27 1997-07-11 Mitsubishi Electric Corp Method for manufacturing semiconductor device
KR20120065606A (en) * 2010-12-13 2012-06-21 삼성엘이디 주식회사 Method of fabricating nitride semiconductor device using silicon wafer
EP2602810A1 (en) * 2011-12-05 2013-06-12 Samsung Electronics Co., Ltd. Silicon substrate, epitaxial structure including the same, and method of manufacturing the silicon substrate

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH09181349A (en) * 1995-12-27 1997-07-11 Mitsubishi Electric Corp Method for manufacturing semiconductor device
KR20120065606A (en) * 2010-12-13 2012-06-21 삼성엘이디 주식회사 Method of fabricating nitride semiconductor device using silicon wafer
EP2602810A1 (en) * 2011-12-05 2013-06-12 Samsung Electronics Co., Ltd. Silicon substrate, epitaxial structure including the same, and method of manufacturing the silicon substrate

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