Classifications

• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
  • C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
  • C08L9/06—Copolymers with styrene
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
  • C08C19/00—Chemical modification of rubber
  • C08C19/25—Incorporating silicon atoms into the molecule
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
  • C08C19/00—Chemical modification of rubber
  • C08C19/30—Addition of a reagent which reacts with a hetero atom or a group containing hetero atoms of the macromolecule
  • C08C19/42—Addition of a reagent which reacts with a hetero atom or a group containing hetero atoms of the macromolecule reacting with metals or metal-containing groups
  • C08C19/44—Addition of a reagent which reacts with a hetero atom or a group containing hetero atoms of the macromolecule reacting with metals or metal-containing groups of polymers containing metal atoms exclusively at one or both ends of the skeleton
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
  • C08L15/00—Compositions of rubber derivatives
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
  • C08L2205/00—Polymer mixtures characterised by other features
  • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group

Definitions

• the present invention relates to a diene elastomer modified with an alkoxysilane group, optionally partially or completely hydrolysed, carrying, where appropriate, another function capable of interacting with a reinforcing filler within a rubber composition.
• the present invention also relates to a reinforced rubber composition, usable especially for the manufacture of tires, comprising this elastomer.
• patent EP 0 992 537 describes a rubber composition which comprises an extended elastomer modified at the end of the chain by an alkoxysilane function and bearing at the other end or along its chain one or more amine functional groups. Furthermore, it has also been proposed to improve the properties of the rubber compositions by using end-functionalized elastomers with alkoxysilane functional groups carrying an amine group, whether in a black, silica or hybrid mixture.
• WO 2009133068 A1 a functionalized diene elastomer consisting essentially of the coupled species of an elastomer having, within the chain, a group carrying an alkoxysilane function and an amine function, the atom of silicon of this group linking the two parts of the chain of the diene elastomer.
• This functionalized elastomer gives the composition containing the improved mechanical and dynamic properties, including improved hysteresis, while maintaining a satisfactory raw implementation, in particular for use in tread tire. It is a constant concern of the designers of materials intended for the manufacture of tires to improve the compromises in the mechanical and dynamic properties of the rubber compositions in order to improve the performance of the tire containing them, without penalizing the stages of its manufacture.
• a functionalized diene elastomer composed of a diene elastomer functionalized at one end of the chain by a silanol function and, to a certain extent, a diene elastomer coupled or star-labeled to tin base.
• This elastomer gives a rubber composition containing it hysteresis and processing properties quite satisfactory and acceptable for use in a tire, while having a significantly improved cold flow resistance.
• the technical problem to be solved by the invention is to further improve the compromise of hysteresis property and implementation of a rubber composition for application in pneumatic, without penalizing its manufacture or properties of the elastomer contained in this composition, especially its resistance to cold creep.
• a predominantly coupled diene elastomer of specific composition including in particular certain proportions of star species and obtained by reaction with a trialkoxysilane compound or not carrying another function capable of interacting with a reinforcing filler, gives the rubber compositions containing it a remarkable and unexpected improvement in the compromise implemented at raw / hysteresis, while preserving a satisfactory cold flow of the elastomer.
• the subject of the invention is therefore a modified diene elastomer based on a) of at least 55% by weight relative to the total weight of the modified diene elastomer, of species coupled by a functional group carrying a function of formula -SiOR, in which R is a hydrogen atom or an alkyl radical having 1 to 10 carbon atoms, and possibly another function capable of to interact with a reinforcing filler, the group being bonded to the two branches of the diene elastomer via the silicon atom, b) from 5% by weight to 30% by weight relative to the total weight of the modified diene elastomer, of star-shaped species having three elastomeric branches connected to the same silicon atom belonging to a functional group which may or may not carry another function capable of interacting with a reinforcing filler, c) of a lower level or equal to 15% by weight relative to the total weight of the modified diene elastomer, of species functionalized at the chain end by a
• the invention also relates to a process for synthesizing said modified diene elastomer.
• Another object of the invention is a reinforced rubber composition based at least on a reinforcing filler and an elastomeric matrix comprising at least said modified diene elastomer.
• any range of values designated by the expression "between a and b" represents the range of values from more than a to less than b (i.e. terminals a and b excluded) while any range of values designated by the term “from a to b” means the range from a to b (i.e., including the strict limits a and b).
• iene elastomer is understood to mean a diene elastomer which comprises a functional group comprising at least one silicon atom and optionally a function capable of interacting with a reinforcing filler, and which is derived from the modification by means of a functionalization agent of the trialkoxysilane type, which may or may not carry another function capable of interacting with a reinforcing filler. It is generally an elastomer obtained by reaction of a living diene elastomer resulting from the anionic polymerization step on the functionalization agent in question.
• the diene elastomer is functionalized at the end or end of the chain.
• the diene elastomer is coupled or functionalized in the middle of the chain, as opposed to the position "at the end of the chain” and although the grouping is not precisely in the middle of the elastomeric chain.
• the silicon atom of this group links the two branches of the chain of the diene elastomer.
• the diene elastomer When the group is central to which three chains or elastomer branches are bonded forming a star structure of the elastomer, it will be said that the diene elastomer is starred.
• the silicon atom of this group binds the three branches of the diene elastomer modified with one another.
• the subject of the invention is a modified diene elastomer composed of species a), b), c) and d) in the proportions indicated above.
• the modified diene elastomer preferably comprises at least 10% by weight relative to the total weight of the modified diene elastomer of said star species b).
• the modified diene elastomer comprises at most 25%, more preferably at most 20% by weight relative to the total weight of the modified diene elastomer of said star species b).
• the modified diene elastomer preferably comprises a level strictly greater than 0% by weight and less than 10% by weight, relative to the total weight of the modified diene elastomer of said non-functional species. d).
• the modified diene elastomer preferably comprises a level greater than or equal to 65%, or even greater than or equal to 70%, by weight relative to the total weight of the modified diene elastomer of said coupled species. at).
• the modified diene elastomer preferably comprises a content of less than or equal to 10% by weight, relative to the total weight of the modified diene elastomer of said species functionalized at the end of the chain. vs).
• the preferential aspects concerning species a), b), c) and d) are combinable with one another.
• diene elastomer is meant according to the invention any homopolymer obtained by polymerization of a conjugated diene monomer having from 4 to 12 carbon atoms, or any block copolymer, random, sequential or microsequenced, obtained by copolymerization of one or more dienes conjugated to one another or to one or more vinylaromatic compounds having 8 to 20 carbon atoms.
• copolymers these contain from 20% to 99% by weight of diene units, and from 1% to 80% by weight of vinylaromatic units.
• conjugated dienes 1,3-butadiene, 2-methyl-1,3-butadiene, 2,3-di (C 1 -C 5 alkyl) -1,3-butadienes, such as, for example, 2,3-dimethyl-1,3-butadiene, 2,3-diethyl-1,3-butadiene, 2-methyl-3-ethyl-1,3-butadiene, 2-methyl-3-isopropyl-1 , 3-butadiene, aryl-1,3-butadiene, 1,3-pentadiene, 2,4-hexadiene, etc.
• Suitable vinyl aromatic compounds are, for example, styrene, ortho-, meta-, para-methylstyrene, the commercial "vinyl-toluene" mixture, para-tert-butylstyrene, methoxystyrenes, chlorostyrenes, vinylmesitylene, divinylbenzene, vinylnaphthalene, etc.
• the diene elastomer is chosen from polybutadienes, butadiene-styrene copolymers, butadiene-styrene-isoprene copolymers, styrene-isoprene copolymers, butadiene-isoprene copolymers and synthetic polyisoprene.
• the diene elastomer is a butadiene-styrene copolymer.
• the modified diene elastomer has no other function than that comprising the silicon atom directly bonded to the elastomeric chain.
• the modified diene elastomer also comprises another function capable of interacting with a reinforcing filler, this function being carried by the group containing the silicon atom.
• This variants do not exclude the fact that the function comprising the silicon atom directly bonded to the elastomeric chain interacts in a privileged manner with the reinforcing filler.
• "Group” or “function capable of interacting with a reinforcing filler” means any group or function capable of forming, within a composition of rubber reinforced by means of a filler, a physical or chemical bond with said charge. This interaction can be established for example by means of covalent, hydrogen, ionic and / or electrostatic bonds between said function and functions present on charges.
• the term "function capable of interacting with a reinforcing filler” preferably means functional groups comprising at least one heteroatom selected from among N, S, O and P. Examples of primary and secondary amines are exemplified by these functions. or tertiary, cyclic or otherwise, isocyanates, imines, cyano, thiols, carboxylates, epoxides, primary, secondary or tertiary phosphines.
• secondary or tertiary amine functional groups mention may be made of amines substituted with C 1 -C 10 alkyl radicals, preferably C 1 -C 4 alkyl radicals, more preferably methyl or ethyl radicals, or else cyclic amines forming a heterocycle containing a nitrogen atom and at least one carbon atom, preferably from 2 to 6 carbon atoms.
• a carboxylate function mention may be made of acrylates or methacrylates. Such a function is preferably a methacrylate.
• epoxy As an epoxide function, mention may be made of epoxy or glycidyloxy groups.
• phosphines substituted with C 1 -C 10 alkyl radicals preferably C 1 -C 4 alkyl radicals, more preferentially methyl or ethyl radicals, or diphenylphosphine radicals.
• C 1 -C 10 alkyl radicals preferably C 1 -C 4 alkyl radicals, more preferentially methyl or ethyl radicals, or diphenylphosphine radicals.
• metylphosphino-, dimethylphosphino-, ethylphosphino-, diethylphosphino, ethylmethylphosphino- and diphenylphosphino- groups are suitable.
• the other function capable of interacting with a reinforcing filler is directly related to the silicon atom itself directly linked to the diene elastomer.
• the other function capable of interacting with a reinforcing filler and the silicon atom directly bonded to the diene elastomer are linked via a spacer group which can be a atom or group of atoms.
• the spacer group may be a divalent hydrocarbon radical, linear or branched, aliphatic C1-C18, saturated or unsaturated, cyclic or not, or a divalent aromatic hydrocarbon radical C6-C18 and may contain one or more aromatic radicals and / or a or more heteroatoms.
• the hydrocarbon radical may optionally be substituted.
• the spacer group is a divalent hydrocarbon radical, linear or branched, C1-C10 aliphatic, more preferably a linear aliphatic divalent hydrocarbon radical in the form of C6, more preferably still the linear divalent C3 hydrocarbon radical.
• the other function capable of interacting with a reinforcing filler is a tertiary amine, more particularly a diethylamino or dimethylamino group; -.
• the spacer group is a C1-C6 linear hydrocarbon radical, more preferably the C3 linear hydrocarbon radical.
• R is a hydrogen atom or an alkyl radical having 1 to 4 carbon atoms, preferably methyl or ethyl.
• the diene elastomer is a butadiene-styrene copolymer.
• the modified diene elastomer according to the invention may be prepared according to a process that includes modifying the elastomer by reacting a living diene elastomer with a trialkoxysilane agent that may or may not carry another function capable of interacting with a reinforcing filler, known to those skilled in the art to react with a piece of living elastomeric chain.
• the process can be continuous or discontinuous.
• Such a synthesis method comprises the following steps:
• a functionalizing agent non-polymerizable, trialkoxysilane type, the alkoxy functional groups being hydrolysable or not silanol function, optionally carrying another function capable of interacting with a reinforcing filler, said functionalizing agent end-chain binding to at least one living chain of the elastomer by its silicon atom.
• a polymerization initiator any known monofunctional anionic initiator can be used. However, an initiator containing an alkali metal such as lithium is used in a preferred manner. Suitable organolithium initiators include those having a carbon-lithium bond and a nitrogen-lithium bond.
• Representative compounds are aliphatic organoliths such as ethyllithium, n-butyllithium (n-BuLi), isobutyl lithium, lithium amides obtained from a cyclic secondary amine, such as pyrrolidine and hexamethyleneimine.
• aliphatic organoliths such as ethyllithium, n-butyllithium (n-BuLi), isobutyl lithium, lithium amides obtained from a cyclic secondary amine, such as pyrrolidine and hexamethyleneimine.
• the polymerization is preferably carried out in the presence of an inert hydrocarbon solvent which may be for example an aliphatic or alicyclic hydrocarbon such as pentane, hexane, heptane, isooctane, cyclohexane, methylcyclohexane or a hydrocarbon aromatic such as benzene, toluene, xylene.
• an inert hydrocarbon solvent which may be for example an aliphatic or alicyclic hydrocarbon such as pentane, hexane, heptane, isooctane, cyclohexane, methylcyclohexane or a hydrocarbon aromatic such as benzene, toluene, xylene.
• the polymerization can be carried out continuously or discontinuously, in dispersion or in solution.
• the polymerization is generally carried out at a temperature of between 20 ° C. and 150 ° C. and preferably in the region of 30 ° C. to 110 ° C.
• the diene elastomer may have any microstructure which is a function of the polymerization conditions used.
• the elastomer may be block, random, sequenced, microsequential, etc.
• the microstructure of this elastomer may be determined by the presence or absence of a modifying and / or randomizing agent and the amounts of modifying agent and / or or randomizing used.
• the living diene elastomer resulting from the polymerization is then modified to prepare the modified diene elastomer according to the invention by reaction with the functionalization agent.
• the reaction time between the living diene elastomer resulting from the polymerization and the functionalizing agent may be between 10 seconds and 2 hours. Those skilled in the art will be able to determine the operating conditions of the modification reaction to result in the composition of the desired modified diene elastomer.
• the modified diene elastomer according to the invention is obtained by mixing at least two diene elastomers of the same nature, modified with the same functionalizing agent, and having a different composition, in order to obtain the referred in cash coupled, starred, functionalized at the end of the chain and not functional.
• the non-functional species ratio in the mixture may be adjusted by adding a non-functional diene elastomer whose polymerization is stopped, for example by addition of methanol, and which does not undergo a modification step directly to the mixture or to each diene elastomer before mixing.
• the modified diene elastomers of different composition of the mixture are respectively obtained by carrying out the modification step by varying the molar ratio of the functionalization agent to the polymerization initiator.
• a ratio ranging from 0.40 to 0.75 preferably from 0.45 to 0.65 and even more preferentially from 0.45 to 0.55
• a ratio ranging from 0.15 to 0.40, preferably from 0.20 to 0.35, even more preferentially from 0.30 to 0.35 stellate species (3 branches) are predominantly formed.
• a ratio greater than or equal to 0.75 preferably greater than 1, the functionalized species at the end of the chain are predominantly formed.
• At least two modified diene elastomers of different composition are prepared, the elastomer being before modification of the same nature (identical microstructure and macrostructure) with the same functionalization agent, the proportions of which are varied according to FIG. majority target species.
• the level of non-functional elastomer is adjusted to about 8%.
• the composition of the modified diene elastomers is determined, for example, by the high resolution SEC technique.
• the proportion of each elastomer in the mixture can then be easily evaluated by the skilled person to achieve the target rate of each species in the modified diene elastomer according to the invention.
• the mixing of these elastomers can be carried out in an inert solvent, for example an aliphatic or alicyclic hydrocarbon such as pentane, hexane, heptane, isooctane, cyclohexane or an aromatic hydrocarbon such as benzene or toluene.
• xylene which may be the same as the polymerization solvent.
• the mixing will then be carried out at a temperature of between 20 ° C. and 120 ° C. and preferably in the region of 30 ° C. to 90 ° C.
• elastomers of different compositions can be synthesized preferably batchwise in a stirred reactor, supposed perfectly stirred according to the skilled person, in a manner known per se.
• the inventors have also developed an innovative process making it possible to prepare the modified elastomer according to the invention continuously whereas until now the control of the distributions of species could only be envisaged in batch mode.
• the polymerization and modification steps by the functionalization agent take place on the same continuous production line.
• the step of modifying the diene elastomer proceeds continuously in a functionalization device, by contacting the living diene elastomer carrying an active site obtained after polymerization with a non-polymerizable functionalization agent comprising ( a) if appropriate, a function capable of interacting with a reinforcing filler and (b) a trialkoxysilane group, the alkoxy radical, which may or may not be hydrolysable, having 1 to 10 carbon atoms,
• A represents the functionalising agent
• PLi represents a living elastomeric chain
• PA represents the functionalized elastomer at the end of the chain
• P2A represents the coupled elastomer
• P3A represents the stellate elastomer with three branches
• k 1 , k 2 and k 3 are the kinetic constants respectively of the reactions R 1, R 2 and R 3 (expressed in (m 3 / mol) s -1 ),
• [PA] is the end-functionalized elastomer concentration (expressed in mol / m 3 ),
• [P 2 A] is the concentration of coupled elastomer (expressed in mol / m 3 ),
• [P3A] is the concentration of three-branched star elastomer (expressed in mol / m 3 ),
• P is the adimensional parameter of resistance to dispersion
• ⁇ 1 is the residence time defined as the ratio reactor volume / total volume flow, preferably equal to at least 0.1 minute and at most 10 minutes, more preferably at most 5 minutes,
• t is the time variable of the residence time distribution.
• a functionalization device which is a combination of the device (i) and a device with at least one stirred continuous reactor, having a residence time distribution characterized by the following equation: e Eq 2
• ⁇ 2 is the residence time defined as the ratio reactor volume / total volume flow, preferably between 0 and 60 minutes, more preferably between 5 and 50 minutes,
• t is the time variable of the residence time distribution
• P is the adimensional parameter of resistance to dispersion as defined in the bibliography "Villermeaux, J; Engineering of the chemical reaction; 1993 ". It is preferably greater than 6.9, more preferably greater than or equal to 9.6, or even greater than or equal to 12. P is not limited by a maximum value within the scope of the invention. He can tend towards infinity. If it tends to infinity, then the device in which the operation takes place behaves like an ideal reactor with a piston type flow.
• One of the essential elements of the invention lies in the choice of this functionalizing agent to correspond to the kinetic model of the operation defined above with a ratio of kinetic constants, denoted K, greater than 1.
• This ratio K is greater than 1, preferably greater than or equal to 10, or even greater than or equal to 100. Below this value of 1, the distribution of the different species results in a modified elastomer whose use in reinforced rubber composition results in processing and hysteresis properties which are not always optimized for satisfactory use in tire treads. There is no upper limit to K. Those skilled in the art will understand that the larger K is, the more the reaction is managed by the molar ratio of functionalizing agent to polymerization initiator. When this value goes to infinity, the process is quantitative and stoichiometric.
• the functionalization agent in accordance with the invention may carry a silanol-functional alkoxysilane function or a non-hydrolysable alkoxysilane function, and possibly another function capable of interacting with a reinforcing filler, both functions being directly related to each other or via a spacer group.
• the other function capable of interacting with a reinforcing filler and the spacer group are as defined above.
• the functionalization agent may be represented by the following formula 1: GOLD'
• - R is a divalent aliphatic hydrocarbon radical, saturated or unsaturated, cyclic or not, C1-C18, aromatic C6-C18, preferably a divalent hydrocarbon radical, linear or branched, aliphatic C1-C10, more preferably a hydrocarbon radical divalent linear C1-C6 aliphatic, more preferably still linear hydrocarbon radical C 3 .
• X is a hydrogen atom or a function capable of interacting with a reinforcing filler
• R 'radicals substituted or unsubstituted, identical or different, represent a C1-C10 or Ci-Cs, preferably an alkyl group Ci-C 4, more preferably methyl and ethyl.
• the function likely to interact with a reinforcing filler is as defined above.
• the function likely to interact with a reinforcing filler is a primary amine, protected or not, secondary, protected or not, or tertiary.
• the nitrogen atom may then be substituted with two identical or different groups, which may be a trialkyl silyl radical, the alkyl group having 1 to 4 carbon atoms, or a C 1 -C 10 alkyl radical, preferably C 1 -C alkyl. -C4, more preferably a methyl or ethyl radical, or both nitrogen substituents form with it a heterocycle containing a nitrogen atom and at least one carbon atom, preferably from 2 to 6 carbon atoms,
• functionalizing agents include (N, N-dialkylaminopropyl) trialkoxysilanes, (N-alkylaminopropyl) trialkoxysilanes, the secondary amine function of which is protected by a trialkyl silyl group and aminopropyltnalkoxysilanes, the primary amine function of which is protected by two trialkyl silyl groups.
• the functionalizing agent may be chosen from 3- (N, N-dimethylaminopropyl) trimethoxysilane, 3- (N, N-dimethylaminopropyl) triethoxysilane, 3- (N, N-diethylaminopropyl) trimethoxysilane, 3- (N, N-diethylaminopropyl) triethoxysilane, 3- (N, N-dipropylaminopropyl) trimethoxysilane, 3- (N, N-dipropylaminopropyl) triethoxysilane, 3- (N, N-dibutylaminopropyl) trimethoxysilane, 3- (N N- (dibutylaminopropyl) triethoxysilane, 3- (N, N-dipentylaminopropyl) trimethoxysilane, 3- (N, N-dipentylaminopropyl) triethoxysilane, 3- (
• the coupling agent is 3- (N, N-dimethylaminopropyl) trimethoxysilane.
• the functionalization agent may be chosen from 3- (N, N-methyltrimethylsilylaminopropyl) trimethoxysilane,
• the coupling agent is 3- (N, N-methyltrimethylsilylaminopropyl) trimethoxysilane.
• the functionalising agent may be chosen from 3- (N, N-bistrimethylsilylaminopropyl) trimethoxysilane and 3- (N, N-) bistriméthylsilylaminopropyl) triethoxysilane.
• the coupling agent is 3- (N, N-bisthymethylsilylaminopropyl) thmethoxysilane.
• the function capable of interacting with a reinforcing filler is an isocyanate function.
• the functionalizing agent may be chosen from 3- (isocyanatopropyl) trimethoxysilane and 3- (isocyanatopropyl) triethoxysilane.
• the function capable of interacting with a reinforcing filler is an imine function.
• the functionalizing agent may be chosen from N- (1,3-dimethylbutylidene) -3- (trimethoxysilyl) -1-propanamine, N- (1,3-dimethylbutylidene) -3- (triethoxysilyl) -1 propanamine, N- (1,3-methylethylidene) -3- (trimethoxysilyl) -1-propanamine, N- (1,3-methylethylidene) -3- (triethoxysilyl) -1-propanamine, N-ethylidene- 3-
• the function capable of interacting with a reinforcing filler is a cyano function.
• the functionalizing agent may be chosen from 3- (cyanopropyl) trimethoxysilane and 3- (cyanopropyl) triethoxysilane.
• the function capable of interacting with a reinforcing filler is a thiol function, protected or not.
• thiol function protected or not.
• the functionalizing agent may be chosen from (S-trimethylsilylmercaptopropyl) trimethoxysilane, (S-trimethylsilylmercaptopropyl) triethoxysilane, and (S-tert-butyl) butyldimethylsilylmercaptopropyl) trimethoxysilane, (S-tert-butyldimethylsilylmercaptopropyl) triethoxysilane.
• the function capable of interacting with a reinforcing filler is a carboxylate function.
• a carboxylate function mention may be made of acrylates or methacrylates. Such a function is preferably a methacrylate.
• the functionalizing agent may be chosen from 3- (methacryloyloxypropyl) trimethoxysilane, and 3-
• the function capable of interacting with a reinforcing filler is an epoxide function.
• the functionalizing agent may be chosen from 2- (glycidyloxyethyl) trimethoxysilane, 2- (glycidyloxyethyl) triethoxysilane, 3- (glycidyloxypropyl) trimethoxysilane, 3- (glycidyloxypropyl) triethoxysilane, 2- (3,4 epoxycyclohexyl) ethyltrimethoxysilane, 2- (3,4-epoxycyclohexyl) ethyltriethoxysilane.
• the function capable of interacting with a reinforcing filler is a primary phosphine function, protected or not, secondary, protected or not, or tertiary.
• the functionalizing agent may be chosen from 3- (P, P-bistrimethylsilylphosphinopropyl) trimethoxysilane, the 3-
• the synthesis process may be continued by a step of deprotection of the primary or secondary amine. This step is implemented after the modification reaction.
• This deprotection step may have the effect of hydrolyzing all or part of the hydrolyzable alkoxysilane functions of the modified diene elastomer to transform them into silanol functions.
• the synthesis process may be continued by a thiol deprotection step.
• This step is implemented after the modification reaction.
• This deprotection step may have the effect of hydrolyzing all or part of the hydrolyzable alkoxysilane functions of the modified diene elastomer to transform them into silanol functions.
• the synthesis process may be continued by a step of deprotection of the phosphine.
• This step is implemented after the modification reaction.
• This deprotection step may have the effect of hydrolyzing all or part of the hydrolyzable alkoxysilane functions of the modified diene elastomer to transform them into silanol functions.
• the synthesis process may comprise a step of hydrolysis of the hydrolyzable alkoxysilane functions, by adding a acidic, basic or neutral compound as described in EP 2 266 819 A1
• the hydrolysable functions are then converted into silanol function.
• the method of synthesis of the modified diene elastomer according to the invention can be continued in a manner known per se by the recovery steps of the modified elastomer.
• these steps comprise a stripping step in order to recover the elastomer from the previous steps in dry form.
• This stripping step may have the effect of hydrolyzing all or part of the hydrolyzable alkoxysilane functions of the modified diene elastomer to turn them into silanol functions.
• at least 50 to 70 mol% of the functions can thus be hydrolysed.
• the invention also relates to a reinforced rubber composition based on at least one reinforcing filler and an elastomeric matrix comprising at least one modified diene elastomer according to the invention.
• the elastomeric matrix may comprise up to 100 phr of modified diene elastomer according to the invention.
• modified diene elastomer according to the invention also means any mixture of at least two modified elastomers according to the invention.
• the elastomer matrix may also comprise at least one diene elastomer different from said modified diene elastomer according to the invention.
• This or these diene elastomers different from the modified diene elastomer according to the invention may be chosen from the diene elastomers conventionally used in tires, such as natural rubber or a synthetic elastomer, or another functionalized, coupled or star-shaped elastomer.
• This or these different diene elastomers of said modified diene elastomer according to the invention can then be present from 1 to 70 parts by weight per 100 parts of modified diene elastomer according to the invention.
• the matrix consists solely of this modified diene elastomer according to the present invention.
• a reinforcing filler it is possible to use any type known for its ability to reinforce a rubber composition that can be used for the manufacture of tires, for example carbon black, a reinforcing inorganic filler such as silica with which it is associated with known a coupling agent, or a mixture of these two types of charge.
• the reinforcing filler is predominantly other than carbon black, more preferably it comprises more than 50% by weight of the total weight of the filler, of one or more fillers other than black.
• carbon especially a reinforcing inorganic filler such as silica, or it consists exclusively of such a filler.
• carbon black when carbon black is also present, it may be used at a level of less than 20 phr, more preferably less than 10 phr (for example between 0.5 and 20 phr, in particular from 1 to 10 phr).
• the total reinforcing filler content is between 10 and 200 phr, more preferably between 30 and 150 phr, the optimum being in a known manner different according to the particular applications targeted.
• Suitable carbon blacks are all carbon blacks, used individually or in the form of mixtures, especially blacks conventionally used in tires or their treads (so-called pneumatic grade blacks). These carbon blacks can be used in the isolated state, as commercially available, or in any other form, for example as a carrier for some of the rubber additives used.
• any other inorganic or inorganic filler irrespective of its color and origin (natural or synthetic), capable of reinforcing on its own, without any other means than an intermediate coupling agent, must be understood to mean any other inorganic or inorganic filler.
• rubber composition for use in the manufacture of tires; such a charge is generally characterized, in known manner, by the presence of hydroxyl groups (OH) on its surface.
• Suitable reinforcing inorganic fillers are in particular mineral fillers of the siliceous type, preferentially silica (SiO 2).
• the silica used may be any reinforcing silica known to those skilled in the art, in particular any precipitated or fumed silica having a BET surface and a CTAB specific surface both less than 450 m 2 / g, preferably from 30 to 400 m 2 / g, especially between 60 and 300 m 2 / g. Mention may also be made of mineral fillers of the aluminous type, in particular alumina (Al 2 O 3) or aluminum (oxide) hydroxides, or reinforcing titanium oxides, for example described in US 6,610,261 and US 6,747,087.
• Reinforcing fillers of another nature are also suitable as reinforcing fillers, provided that these reinforcing fillers are covered with a siliceous layer, or else comprise at their surface functional sites, in particular hydroxyl sites, which require use of a coupling agent to establish the bond between the filler and the elastomer.
• a coupling agent to establish the bond between the filler and the elastomer.
• reinforcing filler is present indifferent, whether in the form of powder, microbeads, granules, or beads.
• reinforcing inorganic filler is also understood to mean mixtures of different reinforcing fillers, in particular highly dispersible silicas as described above.
• silica When the silica is present in the composition as a reinforcing filler, it is possible to use as coupling agents organosilanes, especially polysulfurized alkoxysilanes or mercaptosilanes, or at least bifunctional polyorganosiloxanes.
• organosilanes especially polysulfurized alkoxysilanes or mercaptosilanes, or at least bifunctional polyorganosiloxanes.
• Silica / elastomer bonding agents in particular, have been described in a large number of documents, the best known of which are bifunctional alkoxysilanes such as polysulfurized alkoxysilanes.
• the level of coupling agent is advantageously less than 20 phr, it being understood that it is generally desirable to use as little as possible. Its rate is preferably between 0.5 and 12 phr.
• the presence of the coupling agent depends on that of the load reinforcing inorganic. Its rate is easily adjusted by the skilled person according to the rate of this charge; it is typically of the order of 0.5% to 15% by weight relative to the amount of reinforcing inorganic filler.
• the rubber compositions in accordance with the invention may also contain, in addition to the coupling agents, coupling activators, charge-recovery agents or, more generally, processing aid agents which can be used in a known manner, thanks to to improve the dispersion of the filler in the rubber matrix and to lower the viscosity of the compositions, to improve their ability to use in the green state, these agents being, for example, hydrolysable silanes such as alkylalkoxysilanes, polyols, polyethers, primary, secondary or tertiary amines, hydroxylated or hydrolyzable polyorganosiloxanes.
• these agents being, for example, hydrolysable silanes such as alkylalkoxysilanes, polyols, polyethers, primary, secondary or tertiary amines, hydroxylated or hydrolyzable polyorganosiloxanes.
• the rubber compositions according to the invention may also contain reinforcing organic fillers which may replace all or part of the carbon blacks or other reinforcing fillers described above.
• reinforcing organic fillers that may be mentioned are functionalized polyvinyl organic fillers as described in applications WO-A-2006/069792, WO-A-2006/069793, WO-A-2008/003434 and WO-A- 2008/003435.
• the rubber compositions in accordance with the invention may also comprise all or part of the usual additives normally used in elastomer compositions intended for the manufacture of tires, for example pigments, protective agents such as anti-ozone waxes, chemical antioxidants, anti-oxidants, anti-fatigue agents, reinforcing or plasticizing resins, acceptors (for example phenolic novolak resin) or methylene donors (for example HMT or H3M) as described, for example, in the application WO 02/10269, a crosslinking system based on either sulfur, or sulfur and / or peroxide donors and / or bismaleimides, vulcanization accelerators, vulcanization activators, adhesion promoters such as compounds based on cobalt, plasticizing agents, preferably non-aromatic or very weakly aromatic selected from the group consisting of naphthenic, paraffinic, MES oils, TDAE oils, ethers plasticizers, ester plasticizers, hydrocarbon resins having a high Tg, preferably greater
• the invention also relates to a process for preparing a rubber composition as described above.
• composition is manufactured in appropriate mixers, using two successive preparation phases well known to those skilled in the art: a first phase of work or thermomechanical mixing (so-called “nonproductive” phase) at high temperature, up to a maximum of maximum temperature between 1 10 ° C and 190 ° C, preferably between 130 ° C and 180 ° C, followed by a second phase of mechanical work (so-called “productive” phase) to a lower temperature, typically lower at 110 ° C, for example between 40 ° C and 100 ° C, finishing phase during which the crosslinking system is incorporated.
• the process according to the invention for preparing a rubber composition according to the invention comprises at least the following steps:
• thermomechanical working time (sometimes referred to as a "non-productive" phase) of the constituents basis of the rubber composition, with the exception of the crosslinking system and optionally an adhesion promoter, by intimately incorporating, by kneading into one or more steps, the elastomer matrix comprising the diene elastomer modified according to the invention, ingredients of the composition, then
• the process for preparing the rubber composition comprises the steps for preparing the modified diene elastomer according to the invention as described above according to its various synthetic methods.
• the final composition thus obtained can then be calendered, for example in the form of a sheet, a plate or extruded, for example to form a rubber profile usable as a semi-finished rubber product for the tire.
• the invention also relates to a semi-finished rubber product comprising a reinforced rubber composition according to the invention.
• the invention also relates to a tire of which at least one of its constituent elements is a semi-finished rubber product comprising a reinforced rubber composition according to the invention. Due to the improvement of the hysteresis / implementation compromise which characterizes a reinforced rubber composition according to the invention, it will be noted that such a composition may constitute any semi-finished product of the tire, and more particularly the tread, decreasing thus its rolling resistance.
• the SEC (Size Exclusion Chromatography) technique separates macromolecules in solution according to their size through columns filled with a porous gel.
• the macromolecules are separated according to their hydrodynamic volume, the larger ones being eluted first.
• the conventional SEC allows to apprehend the distribution of the molar masses of a polymer.
• Ip Mw / Mn
• the equipment used is a chromatographic chain "WATERS alliance".
• the elution solvent is either tetrahydrofuran or tetrahydrofuran + 1 vol% diisopropylamine + 1 vol% triethylamine, the flow rate is 1 ml. min “1 , the system temperature of 35 ° C and the analysis time of 30 min
• a set of two WATERS columns, with the trade name" STYRAGEL HT6E ", is used
• the injected volume of the sample solution The detector is a differential refractometer "WATERS 2410" and the chromatographic data exploitation software is the "WATERS EMPOWER" system.
• the calculated average molar masses relate to a calibration curve produced for SBRs with the following microstructure: 25% by mass of styrene type units, 23% by mass of type 1, 2 and 50% by mass units of 1,4-trans type units. .
• the high resolution SEC technique is used to determine the mass percentages of the different chain populations present in a polymer sample.
• the equipment used is a chromatographic chain "WATERS alliance 2695".
• the elution solvent is tetrahydrofuran, the flow rate of 0.2 ml. min- 1 , the system temperature of 35 ° C.
• a set of three identical columns in series is used (Shodex, length 300 mm, diameter 8 mm) The number of theoretical plates in the set of columns is greater than 22,000.
• the injected volume of the solution of the polymer sample is 50 ⁇
• the detector is a differential refractometer "WATERS 2414" and the chromatographic data exploitation software is the "WATERS EMPOWER" system.
• the calculated molar masses relate to a calibration curve produced for SBRs with the following microstructure: 25% by mass of styrene type units, 23% by mass of type 1, 2 and 50% by mass units of type 1, 4-trans units.
• NIR Near infrared spectroscopy
• the acquisition of the spectrum is carried out in transmission mode between 4000 and 6200 cm “1 with a resolution of 2 cm “ 1 , using a Bruker Tensor 37 Fourier transform infrared near-infrared spectrometer equipped with a cooled InGaAs detector. by Peltier effect.
• An oscillatory consistometer is used as described in ASTM D-1646.
• the Mooney plasticity measurement is carried out according to the following principle: the elastomer (or the raw composition (ie before firing)) is molded in a cylindrical chamber heated to 100 ° C. After one minute preheating, the rotor turns within the test sample at 2 tr.min "1 and the torque used for maintaining this movement after 4 minutes of rotation is measured.
• the inherent viscosity is determined by measuring the flow time t of the polymer solution and the flow time fo of toluene in a capillary tube.
• the die has a diameter of 6.35 mm, a thickness of 0.5 mm and is located at the bottom and the center of a cylindrical cut-out cut of 52 mm in diameter.
• tan ⁇ max are measured on a viscoanalyzer (Metravib VA4000), according to the ASTM D 5992-96 standard.
• the response of a sample of vulcanized composition (cylindrical specimen 2 mm thick and section 79 mm 2 ) subjected to sinusoidal stress in alternating simple shear at a frequency of 10 Hz is recorded under normal conditions. temperature (23 ° C) according to ASTM D 1349-99.
• a peak-to-peak deformation amplitude sweep of 0.1% to 50% (forward cycle) and then 50% to 0.1% (return cycle) is performed.
• the result exploited is the loss factor tan ⁇ .
• tan ⁇ max the maximum value of tan ⁇ observed (tan ⁇ max) is indicated. This value is representative of the hysteresis of the material and in this case the rolling resistance: the lower the value of tan ⁇ max, the lower the rolling resistance. Determination of the species distribution of a modified elastomer.
• the monomer conversion rate reaches 95%. This level is determined by weighing a dried extract at 140 ° C., under the reduced pressure of 200 mmHg. A control bottle (bottle no. 1) is stopped with an excess of methanol relative to lithium. The inherent viscosity "initial" was 0.66 dl g "1.
• the solutions are antioxidized by the addition of 0.4 parts per hundred parts of elastomer (phr) of 4,4'-methylene-bis-2,6-tert-butylphenol and 0 , 2 parts per hundred parts elastomer (phr) of N- (1,3-dimethylbutyl) -N'-phenyl-p-phenylenediamine.
• elastomer (phr) 4,4'-methylene-bis-2,6-tert-butylphenol and 0 , 2 parts per hundred parts elastomer (phr) of N- (1,3-dimethylbutyl) -N'-phenyl-p-phenylenediamine.
• the “final” inherent viscosities, the viscosity leaps defined as the ratios of the “final” inherent viscosities on the “initial” inherent viscosity as well as the mass percentages of the deactivated (P) chains, chain end functionalized chains (PA) in middle chain (P2A) and star (P3A) are shown in Table 1 below.
• the living diene elastomer is functionalized according to the reaction mechanism described above in the description.
• the kinetic model of integrated operation makes it possible to determine the distribution of the different species.
• the chains can be deactivated (P) during the polymerization step and / or functionalization.
• the final product is a mixture of deactivated elastomer (P), end-chain functionalized elastomer (PA), functionalized middle-chain elastomer (P2A) and star-shaped elastomer (P3A).
• Figure 1 represents the distribution of the species P, PA, P 2 A and P 3 A as a function of the molar ratio functionalizing agent / living polymer chains (PLi): simulated (lines) and measured (points).
• the monomer conversion rate reaches 95%. This level is determined by weighing a dried extract at 140 ° C., under the reduced pressure of 200 mmHg. 0.88 mL of a solution of 0.1 mol.L- 1 (N, N-dimethylaminopropyl) trimethoxysilane in methylcyclohexane are added to the living polymer solutions (0.48 molar eq. the remaining twenty-one bottles.
• the solutions are antioxidized by addition of 0.4 parts per hundred parts of elastomer (pce) of 4,4'-methylene-bis-2,6-tert-butylphenol and 0.2 part per cent elastomer (pce) of N- (1,3-dimethylbutyl) -N'-phenyl-p- phenylenediamine.
• the polymers thus treated are separated from their solution by drying at 60 ° C. under reduced pressure and nitrogen flow for 12 hours.
• the functionalization section consists of a kenics-type static mixer with 36 elements of 4 L and a stirred continuous reactor of volume 32.5 L, supposed to be perfectly agitated.
• the minimum residence time in agitated reactors is 20 minutes.
• N-Butyllithium (n-BuLi) is introduced in sufficient quantity to neutralize the protic impurities provided by the various constituents present in the line inlet. At the inlet of the reactor, 850 ⁇ of n-BuLi per 100 g of monomers are introduced.
• the different flow rates are calculated so that the average residence time in the reactor is 40 min.
• the temperature is maintained at 90 ° C.
• the conversion rate measured on a sample taken at the outlet of the reactor, is 92.6%.
• 3- (N, N-dimethylaminopropyl) trimethoxysilane dissolved in methylcyclohexane is added to the living polymer solution in different amounts (different molar ratios 3- (N, N-dimethylaminopropyl) trimethoxysilane / PLi ) to characterize the functionalization process.
• This solution is mixed in a static mixer consisting of 36 Kenics KMR type mixing elements and then passes through an empty tube, the total residence time in the tube being 3 minutes (static mixer + empty tube), and a continuous stirring reactor of 32 minutes. , 5 L, supposed perfectly stirred according to the man of the art, 40 minutes of residence time.
• the polymers are then subjected to an antioxidant treatment with addition of 0.4 phr 2,2'-methylene-bis (4-methyl-6-tert-butylphenol) and 0.2 phr of N- (1,3-dimethylbutyl) -N'-phenyl-p-phenylenediamine.
• the polymers thus treated are separated from their solution by a stripping operation with steam, and then dried on a roll tool at 100 ° C.
• the inherent viscosity jumps (SV) measured are shown in FIG. 3.
• the kinetic functionalization model described above is integrated, according to one skilled in the art, into a tubular reactor model (representative of the Kenics static mixer) followed a perfectly stirred continuous reactor (representative of the agitated reactor of functionalization) (Bibliography: Villermeaux, J. Chemical reaction engineering, 1993) and makes it possible to determine the distribution of PLi, P, PA, P 2 A and P species 3 A.
• wP, A is the mass fraction of the species PA, PLi, P; Mw is the weight average molecular weight; a is the parameter of the equation MHS (Mark Houwink Sakurada) and equal to 0.75 g, is a correction for star polymers, for example:
• the ratio of kinetic constants K is estimated by minimizing the differences SV experimental and calculated.
• the value of K is 10 ⁇ 1 as shown in Figure 3.
• the calculated SV is determined from the species distribution calculated by the kinetic model integrated into the tubular reactor models and perfectly stirred continuously (Figure 4).
• N-Butyllithium (n-BuLi) is introduced at the entry line in sufficient quantity to neutralize the protic impurities provided by the various constituents present in the line inlet. At the inlet of the reactor, 850 ⁇ of n-BuLi per 100 g of monomers are introduced.
• the different flow rates are calculated so that the average residence time in the reactor is 40 min.
• the temperature is maintained at 90 ° C.
• the conversion rate measured on a sample taken at the outlet of the reactor, is 92.6% and the inherent viscosity is 1.68 dL.g -1 .
• the polymer is then subjected to an antioxidant treatment with the addition of 0.4 phr of 2,2'-methylene-bis (4-methyl-6-tert-butylphenol) and 0.2 phr of N- (1,3-dimethylbutyl) -N'-phenyl-p-phenylenediamine.
• the polymer thus treated is separated from its solution by a stripping operation with steam, and then dried on a roll tool at 100 ° C., to obtain the polymer 1 functionalized with 3- (N, N-dimethylaminopropyl) trimethoxysilane in the middle of the chain according to the invention.
• the inherent viscosity of this polymer 1 is 2.15 dLg -1 , the viscosity jump is 1.28 and the viscosity ML ( i + ) 100 ° C. is 72.0.
• Mn of the polymer, determined by the conventional SEC technique, is 145,000 gmol -1 and the polymolecularity index Ip is 1.72.
• the CF ( +6 ) 100 ° C cold flow of this elastomer is 0.452.
• the microstructure of this polymer is determined by the NIR method: the mass ratio of units 1, 2 is 24.1%, this ratio relating to the butadiene units. The mass content of styrene is 26.5%.
• N-Butyllithium (n-BuLi) is introduced at the entry line in sufficient quantity to neutralize the protic impurities provided by the various constituents present in the line inlet. At the reactor inlet, 845 ⁇ of n-BuLi per 100 g of monomers are introduced.
• the different flow rates are calculated so that the average residence time in the reactor is 40 min.
• the temperature is maintained at 90 ° C.
• the conversion rate measured on a sample taken at the outlet of the reactor, is 92.7% and the inherent viscosity is 1.66 dL.g -1 .
• the polymer is then subjected to an antioxidant treatment with addition of 0.4 phr of 2,2'-methylene-bis (4-methyl-6-tert-butylphenol) and 0.2 phr of N- (1,3-dimethylbutyl) ) -N'-phenyl-p-phenylenediamine.
• the polymer thus treated is separated from its solution by a stripping operation with steam, and then dried on a roll tool at 100 ° C., to obtain the polymer 2 functionalized with 3- (N, N-dimethylaminopropyl) trimethoxysilane in the middle of the chain according to the invention.
• the inherent viscosity of this polymer 2 is 2.12 dLg -1 , the viscosity jump is 1.28 and the viscosity ML ( i + ) 100 ° C. is 70.4.
• Mn of the polymer, determined by the conventional SEC technique, is 142,000 gmol -1 , the molecular weight and the polymolecularity index Ip is 1.73.
• the CF ( +6 ) 100 ° C cold flow of this elastomer is 0.614.
• microstructure of this polymer is determined by the NIR method: the mass ratio of units 1, 2 is 23.6%, this ratio relating to the butadiene units. The mass content of styrene is 26.6%.
• Preparation of polymer 3 Polymer functionalized with 3- (N, N-dimethylaminopropyl) trimethoxysilane in the middle of the chain
• N-Butyllithium (n-BuLi) is introduced at the entry line in sufficient quantity to neutralize the protic impurities provided by the various constituents present in the line inlet. At the reactor inlet, 840 ⁇ of n-BuLi per 100 g of monomers are introduced.
• the different flow rates are calculated so that the average residence time in the reactor is 40 min.
• the temperature is maintained at 90 ° C.
• the conversion rate, measured on a sample taken at the outlet of the reactor, is 93.5% and the inherent viscosity is 1.66 dL.g -1 .
• This living polymer solution is introduced continuously into a second stirred continuous reactor of 32.5 L, presumably perfectly stirred according to the man of the art, of 40 minutes of residence time in which 393 micromoles per 100 g of monomers of 3- (N, N-dimethylaminopropyl) trimethoxysilane in solution in methylcyclohexane are introduced continuously.
• the polymer is then subjected to an antioxidant treatment with addition of 0.4 phr of 2,2'-methylene-bis (4-methyl-6-tert-butylphenol) and 0.2 phr of N- (1,3-dimethylbutyl) ) -N'-phenyl-p-phenylenediamine.
• the polymer thus treated is separated from its solution by a stripping operation with steam and then dried on a roll tool at 100 ° C., to obtain the polymer 3 functionalized with 3- (N, N-dimethylaminopropyl) trimethoxysilane in the middle of the chain.
• the inherent viscosity of this polymer 3 is 2.14 dLg -1 , the viscosity jump is 1.29 and the viscosity ML ( i + ) 100 ° C. is 76.4.
• Mn of the polymer, determined by the conventional SEC technique, is 144,000 g mol -1 and the polymolecularity index I p is 1.80.
• the CF (i +6 ) 100 ° C cold flow of this elastomer is 0.216.
• the microstructure of this polymer is determined by the NIR method: the mass ratio of 1,2 units is 24.4%, this ratio relating to the butadiene units. The mass content of styrene is 27.0%.
• the modified diene elastomers synthesized previously are introduced into an 85 cm 3 Polylab internal mixer, filled to 70% and having an initial tank temperature of about 110.degree. Then, the reinforcing fillers, the coupling agent and then, after one to two minutes of mixing, the various other ingredients with the exception of the vulcanization system, are introduced into the mixer. Theromechanical work (non-productive phase) is then carried out in one step (total mixing time equal to about 5 minutes), until a maximum temperature of "fall” of 160 ° C. is reached. The mixture thus obtained is recovered, cooled and the vulcanization system (sulfur) is added to an external mixer (homo-finisher) at 25 ° C, mixing the whole (productive phase) for about 5 to 6 min.
• compositions thus obtained are then calendered either in the form of plates (thickness of 2 to 3 mm) or thin sheets of rubber for the measurement of their physical or mechanical properties.
• the rubber compositions are given in Table 4. The amounts are expressed in parts per 100 parts by weight of elastomer (phr).
• the elastomers 1 and 2 have Cold Flow values considered to be sufficiently low to limit the creep problems, while minimizing the value of tan ⁇ in the reinforced rubber composition, expressing a reduced hysteresis.
• the elastomer 3 has a cold flow value further reduced, but to the detriment of the hysteresis of the reinforced rubber composition containing it.
• the compromise cold creep elastomers - hysteresis of the rubber composition containing them is optimized and quite satisfactory for the elastomers 1 and 2 of the invention.

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