WO2014177424A3 - Process for preparing a heavy base oil - Google Patents

Process for preparing a heavy base oil Download PDF

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Publication number
WO2014177424A3
WO2014177424A3 PCT/EP2014/058144 EP2014058144W WO2014177424A3 WO 2014177424 A3 WO2014177424 A3 WO 2014177424A3 EP 2014058144 W EP2014058144 W EP 2014058144W WO 2014177424 A3 WO2014177424 A3 WO 2014177424A3
Authority
WO
WIPO (PCT)
Prior art keywords
ppmw
base oil
range
amount
heavy base
Prior art date
Application number
PCT/EP2014/058144
Other languages
French (fr)
Other versions
WO2014177424A2 (en
Inventor
Laurent Georges Huve
John Joseph Baric
Nariman Boumendjel
Jakob Willem Duininck
Godfried Johannes Aarts
Original Assignee
Shell Internationale Research Maatschappij B.V.
Shell Oil Company
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shell Internationale Research Maatschappij B.V., Shell Oil Company filed Critical Shell Internationale Research Maatschappij B.V.
Priority to KR1020157034081A priority Critical patent/KR20160003203A/en
Priority to EP14720073.7A priority patent/EP2992070A2/en
Priority to CN201480024800.5A priority patent/CN105209580B/en
Priority to RU2015151620A priority patent/RU2671862C2/en
Publication of WO2014177424A2 publication Critical patent/WO2014177424A2/en
Publication of WO2014177424A3 publication Critical patent/WO2014177424A3/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G67/00—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only
    • C10G67/02—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only plural serial stages only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G65/00—Treatment of hydrocarbon oils by two or more hydrotreatment processes only
    • C10G65/02—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only
    • C10G65/04—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including only refining steps
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/58—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins
    • C10G45/60—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used
    • C10G45/64—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used containing crystalline alumino-silicates, e.g. molecular sieves
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G65/00—Treatment of hydrocarbon oils by two or more hydrotreatment processes only
    • C10G65/02—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only
    • C10G65/04—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including only refining steps
    • C10G65/043—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including only refining steps at least one step being a change in the structural skeleton
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G65/00—Treatment of hydrocarbon oils by two or more hydrotreatment processes only
    • C10G65/02—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only
    • C10G65/04—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including only refining steps
    • C10G65/08—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including only refining steps at least one step being a hydrogenation of the aromatic hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G65/00—Treatment of hydrocarbon oils by two or more hydrotreatment processes only
    • C10G65/02—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only
    • C10G65/12—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including cracking steps and other hydrotreatment steps
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/201—Impurities
    • C10G2300/202—Heteroatoms content, i.e. S, N, O, P
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/10—Lubricating oil

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Catalysts (AREA)

Abstract

The invention provides a process for preparing a heavy base oil comprising the steps of: (a) providing a hydrocarbonaceous feedstock which contains at least 50% by weight of hydrocarbons boiling above 460 °C, nitrogen in amount in the range of from 800-2500 ppmw, and sulphur in an amount in the range of from 1.5-4.0 %wt ppmw; (b) hydrotreating the hydrocarbonaceous feedstock with a hydrotreating catalyst in the presence of a hydrogen- containing gas under hydrotreating conditions to obtain a hydrotreated product which contains nitrogen in an amount in the range of from 30-80 ppmw and sulphur in an amount in the range of from 200-450 ppmw; (c) removing at least 50% of the N¾ and ¾S which is present in the hydrotreated product as obtained in step (b); (d) catalytically dewaxing at least part of the hydrotreated product as obtained in step (c) with a dewaxing catalyst in the presence of a hydrogen- containing gas under catalytic dewaxing conditions to obtain a dewaxed product, which dewaxing catalyst comprises a Group VIII metal hydrogenation component, dealuminated aluminosilicate zeolite crystallites and a low acidity refractory oxide binder material which is essentially free of alumina; (e) hydrofinishing at least part of the dewaxed product as obtained in step (d) with a hydrofinishing catalyst in the presence of a hydrogen-containing gas under hydrofinishing conditions to obtain a heavy base oil; and (f) recovering the heavy base oil.
PCT/EP2014/058144 2013-05-02 2014-04-22 Process for preparing a heavy base oil WO2014177424A2 (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
KR1020157034081A KR20160003203A (en) 2013-05-02 2014-04-22 Process for preparing a heavy base oil
EP14720073.7A EP2992070A2 (en) 2013-05-02 2014-04-22 Process for preparing a heavy base oil
CN201480024800.5A CN105209580B (en) 2013-05-02 2014-04-22 The method for preparing weight base oil
RU2015151620A RU2671862C2 (en) 2013-05-02 2014-04-22 Process for preparing heavy base oil

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP13166276.9 2013-05-02
EP13166276 2013-05-02

Publications (2)

Publication Number Publication Date
WO2014177424A2 WO2014177424A2 (en) 2014-11-06
WO2014177424A3 true WO2014177424A3 (en) 2015-01-08

Family

ID=48190394

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2014/058144 WO2014177424A2 (en) 2013-05-02 2014-04-22 Process for preparing a heavy base oil

Country Status (5)

Country Link
EP (1) EP2992070A2 (en)
KR (1) KR20160003203A (en)
CN (1) CN105209580B (en)
RU (1) RU2671862C2 (en)
WO (1) WO2014177424A2 (en)

Families Citing this family (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10550341B2 (en) * 2015-12-28 2020-02-04 Exxonmobil Research And Engineering Company Sequential deasphalting for base stock production
US10407630B2 (en) 2016-11-21 2019-09-10 Saudi Arabian Oil Company Process and system for conversion of crude oil to petrochemicals and fuel products integrating solvent deasphalting of vacuum residue
US10472574B2 (en) 2016-11-21 2019-11-12 Saudi Arabian Oil Company Process and system for conversion of crude oil to petrochemicals and fuel products integrating delayed coking of vacuum residue
US10487276B2 (en) 2016-11-21 2019-11-26 Saudi Arabian Oil Company Process and system for conversion of crude oil to petrochemicals and fuel products integrating vacuum residue hydroprocessing
US10487275B2 (en) * 2016-11-21 2019-11-26 Saudi Arabian Oil Company Process and system for conversion of crude oil to petrochemicals and fuel products integrating vacuum residue conditioning and base oil production
US10870807B2 (en) 2016-11-21 2020-12-22 Saudi Arabian Oil Company Process and system for conversion of crude oil to petrochemicals and fuel products integrating steam cracking, fluid catalytic cracking, and conversion of naphtha into chemical rich reformate
US10472579B2 (en) 2016-11-21 2019-11-12 Saudi Arabian Oil Company Process and system for conversion of crude oil to petrochemicals and fuel products integrating vacuum gas oil hydrocracking and steam cracking
US20180142167A1 (en) 2016-11-21 2018-05-24 Saudi Arabian Oil Company Process and system for conversion of crude oil to chemicals and fuel products integrating steam cracking and fluid catalytic cracking
US10619112B2 (en) 2016-11-21 2020-04-14 Saudi Arabian Oil Company Process and system for conversion of crude oil to petrochemicals and fuel products integrating vacuum gas oil hydrotreating and steam cracking
US10472580B2 (en) 2016-11-21 2019-11-12 Saudi Arabian Oil Company Process and system for conversion of crude oil to petrochemicals and fuel products integrating steam cracking and conversion of naphtha into chemical rich reformate
US10604709B2 (en) 2017-02-12 2020-03-31 Magēmā Technology LLC Multi-stage device and process for production of a low sulfur heavy marine fuel oil from distressed heavy fuel oil materials
US11788017B2 (en) 2017-02-12 2023-10-17 Magëmã Technology LLC Multi-stage process and device for reducing environmental contaminants in heavy marine fuel oil
US20180230389A1 (en) 2017-02-12 2018-08-16 Magēmā Technology, LLC Multi-Stage Process and Device for Reducing Environmental Contaminates in Heavy Marine Fuel Oil
EP3635076A1 (en) * 2017-06-07 2020-04-15 Exxonmobil Research And Engineering Company Production of diesel and base stocks from crude oil
US10696906B2 (en) 2017-09-29 2020-06-30 Marathon Petroleum Company Lp Tower bottoms coke catching device
US12000720B2 (en) 2018-09-10 2024-06-04 Marathon Petroleum Company Lp Product inventory monitoring
US11975316B2 (en) 2019-05-09 2024-05-07 Marathon Petroleum Company Lp Methods and reforming systems for re-dispersing platinum on reforming catalyst
CA3109606C (en) 2020-02-19 2022-12-06 Marathon Petroleum Company Lp Low sulfur fuel oil blends for paraffinic resid stability and associated methods
US11898109B2 (en) 2021-02-25 2024-02-13 Marathon Petroleum Company Lp Assemblies and methods for enhancing control of hydrotreating and fluid catalytic cracking (FCC) processes using spectroscopic analyzers
US20220268694A1 (en) 2021-02-25 2022-08-25 Marathon Petroleum Company Lp Methods and assemblies for determining and using standardized spectral responses for calibration of spectroscopic analyzers
US11905468B2 (en) 2021-02-25 2024-02-20 Marathon Petroleum Company Lp Assemblies and methods for enhancing control of fluid catalytic cracking (FCC) processes using spectroscopic analyzers
US11692141B2 (en) 2021-10-10 2023-07-04 Marathon Petroleum Company Lp Methods and systems for enhancing processing of hydrocarbons in a fluid catalytic cracking unit using a renewable additive
CA3188122A1 (en) 2022-01-31 2023-07-31 Marathon Petroleum Company Lp Systems and methods for reducing rendered fats pour point

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20040144691A1 (en) * 2001-06-07 2004-07-29 Gerard Benard Process to prepare a base oil from slack-wax
EP1997868A1 (en) * 2007-05-30 2008-12-03 Shell Internationale Researchmaatschappij B.V. Process for producing a naphthenic base oil
US20090166252A1 (en) * 2007-12-28 2009-07-02 Michel Daage Process for preparing lube basestocks having superior low temperature properties at high VI

Family Cites Families (4)

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MY125670A (en) * 1995-06-13 2006-08-30 Shell Int Research Catalytic dewaxing process and catalyst composition
CZ297084B6 (en) * 1996-07-16 2006-09-13 Chevron U. S. A. Inc. Process for producing lubricating oil base stock
US7282137B2 (en) * 2002-10-08 2007-10-16 Exxonmobil Research And Engineering Company Process for preparing basestocks having high VI
CN1317368C (en) * 2004-03-31 2007-05-23 中国石油化工股份有限公司 Method for preparing lubricating oil base oil

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20040144691A1 (en) * 2001-06-07 2004-07-29 Gerard Benard Process to prepare a base oil from slack-wax
EP1997868A1 (en) * 2007-05-30 2008-12-03 Shell Internationale Researchmaatschappij B.V. Process for producing a naphthenic base oil
US20090166252A1 (en) * 2007-12-28 2009-07-02 Michel Daage Process for preparing lube basestocks having superior low temperature properties at high VI

Also Published As

Publication number Publication date
CN105209580B (en) 2018-06-08
RU2015151620A3 (en) 2018-03-19
WO2014177424A2 (en) 2014-11-06
CN105209580A (en) 2015-12-30
KR20160003203A (en) 2016-01-08
RU2671862C2 (en) 2018-11-07
RU2015151620A (en) 2017-06-07
EP2992070A2 (en) 2016-03-09

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