WO2014174416A3 - Dehydration of sugars on zeolites obtainable from an organotemplate-free synthetic process - Google Patents

Dehydration of sugars on zeolites obtainable from an organotemplate-free synthetic process Download PDF

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Publication number
WO2014174416A3
WO2014174416A3 PCT/IB2014/060805 IB2014060805W WO2014174416A3 WO 2014174416 A3 WO2014174416 A3 WO 2014174416A3 IB 2014060805 W IB2014060805 W IB 2014060805W WO 2014174416 A3 WO2014174416 A3 WO 2014174416A3
Authority
WO
WIPO (PCT)
Prior art keywords
organotemplate
dehydration
synthetic process
sugars
free synthetic
Prior art date
Application number
PCT/IB2014/060805
Other languages
French (fr)
Other versions
WO2014174416A2 (en
Inventor
Mathias Feyen
Ulrich Müller
Stefan Maurer
Martin Alexander BOHN
Bilge Yilmaz
Takashi Tatsumi
Weiping Zhang
Dirk De Vos
Hermann Gies
Xinhe Bao
Feng-Shou Xiao
Yokoi TOSHIYUKI
Original Assignee
Basf Se
Tokyo Institute Of Technology
Basf (China) Company Limited
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Se, Tokyo Institute Of Technology, Basf (China) Company Limited filed Critical Basf Se
Publication of WO2014174416A2 publication Critical patent/WO2014174416A2/en
Publication of WO2014174416A3 publication Critical patent/WO2014174416A3/en

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/90—Regeneration or reactivation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7049—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing rare earth elements, titanium, zirconium, hafnium, zinc, cadmium, mercury, gallium, indium, thallium, tin or lead
    • B01J29/7057—Zeolite Beta
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/06—Washing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00—Regeneration or reactivation of catalysts, in general
    • B01J38/02—Heat treatment
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/026—After-treatment
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/06—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/46—Other types characterised by their X-ray diffraction pattern and their defined composition
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/16—After treatment, characterised by the effect to be obtained to increase the Si/Al ratio; Dealumination
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/37—Acid treatment
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Geology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)

Abstract

A method of dehydration of at least one compound (A) comprising, in the chain form, -at least one hydroxyl group and -at least one carbonyl functionality selected from the group consisting of aldehyde (CHO), ke- tone (CO) and carboxylic acid (COOH) and mixtures thereof,in the presence of at least one zeolite which is (a) obtainable from an organotemplate-free synthetic process and (b) isomorphously substituted comprising silicon, aluminum and at least one further metal wherein the at least one further metal is selected from the group consisting of the elements of Group 3 to 14 in Period 4 to 6and mixtures thereof.
PCT/IB2014/060805 2013-04-22 2014-04-17 Dehydration of sugars on zeolites obtainable from an organotemplate-free synthetic process WO2014174416A2 (en)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US201361814358P 2013-04-22 2013-04-22
EPPCT/CN2013/074508 2013-04-22
CN2013074508 2013-04-22
US61/814358 2013-04-22

Publications (2)

Publication Number Publication Date
WO2014174416A2 WO2014174416A2 (en) 2014-10-30
WO2014174416A3 true WO2014174416A3 (en) 2015-03-12

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/IB2014/060805 WO2014174416A2 (en) 2013-04-22 2014-04-17 Dehydration of sugars on zeolites obtainable from an organotemplate-free synthetic process

Country Status (1)

Country Link
WO (1) WO2014174416A2 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109590020B (en) * 2018-12-27 2021-08-24 桂林理工大学 Preparation method of microporous-mesoporous composite molecular sieve denitration catalyst

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105793341A (en) 2013-12-06 2016-07-20 巴斯夫欧洲公司 Softener composition which contains tetrahydrofuran derivatives and 1,2-cyclohexane dicarboxylic acid esters
WO2016128917A1 (en) 2015-02-12 2016-08-18 Basf Se Process for the preparation of a dealuminated zeolitic material having the bea framework structure

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1294088A (en) * 1999-10-22 2001-05-09 英特卫普有限公司 Aluminium silicate compsns. and its prepn. process and application
CN1302691A (en) * 2000-12-22 2001-07-11 刘希尧 Zeolite molecular sieve containing rare-earth heteroatoms with MOR structure and its synthesis process
CN1524788A (en) * 2003-02-28 2004-09-01 中国石油化工股份有限公司 Synthesizing method for MOR zeolite comprising zinc
WO2007146636A1 (en) * 2006-06-06 2007-12-21 Wisconsin Alumni Research Foundation Catalytic process for producing furan derivatives from carbohydrates in a biphasic reactor
WO2010146156A1 (en) * 2009-06-18 2010-12-23 Basf Se Organotemplate-free synthetic process for the production of a zeolitic material
CN101962194A (en) * 2010-09-07 2011-02-02 浙江大学 Method for preparing ZSM-34 and heteroatomic substitution molecular sieve thereof by direct synthesis method
CN101962193A (en) * 2010-09-07 2011-02-02 浙江大学 Method for preparing ZSM-34 and heteroatom substituted molecular sieve thereof by using crystal seed synthesis method
CN102066258A (en) * 2008-07-11 2011-05-18 南方化学股份公司 Method for production of crystalline, zeolite-like gallo-aluminium silicates
WO2011157839A1 (en) * 2010-06-18 2011-12-22 Basf Se Organotemplate-free synthetic process for the production of a zeolitic material of the lev-type structure

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1294088A (en) * 1999-10-22 2001-05-09 英特卫普有限公司 Aluminium silicate compsns. and its prepn. process and application
CN1302691A (en) * 2000-12-22 2001-07-11 刘希尧 Zeolite molecular sieve containing rare-earth heteroatoms with MOR structure and its synthesis process
CN1524788A (en) * 2003-02-28 2004-09-01 中国石油化工股份有限公司 Synthesizing method for MOR zeolite comprising zinc
WO2007146636A1 (en) * 2006-06-06 2007-12-21 Wisconsin Alumni Research Foundation Catalytic process for producing furan derivatives from carbohydrates in a biphasic reactor
CN102066258A (en) * 2008-07-11 2011-05-18 南方化学股份公司 Method for production of crystalline, zeolite-like gallo-aluminium silicates
WO2010146156A1 (en) * 2009-06-18 2010-12-23 Basf Se Organotemplate-free synthetic process for the production of a zeolitic material
WO2011157839A1 (en) * 2010-06-18 2011-12-22 Basf Se Organotemplate-free synthetic process for the production of a zeolitic material of the lev-type structure
CN101962194A (en) * 2010-09-07 2011-02-02 浙江大学 Method for preparing ZSM-34 and heteroatomic substitution molecular sieve thereof by direct synthesis method
CN101962193A (en) * 2010-09-07 2011-02-02 浙江大学 Method for preparing ZSM-34 and heteroatom substituted molecular sieve thereof by using crystal seed synthesis method

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109590020B (en) * 2018-12-27 2021-08-24 桂林理工大学 Preparation method of microporous-mesoporous composite molecular sieve denitration catalyst

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