WO2014129839A1 - Film optique ayant une excellente fonction de blocage des rayons ultraviolets et plaque de polarisation comportant ce dernier - Google Patents

Film optique ayant une excellente fonction de blocage des rayons ultraviolets et plaque de polarisation comportant ce dernier Download PDF

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Publication number
WO2014129839A1
WO2014129839A1 PCT/KR2014/001415 KR2014001415W WO2014129839A1 WO 2014129839 A1 WO2014129839 A1 WO 2014129839A1 KR 2014001415 W KR2014001415 W KR 2014001415W WO 2014129839 A1 WO2014129839 A1 WO 2014129839A1
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WIPO (PCT)
Prior art keywords
optical film
absorber
film
acrylic resin
weight
Prior art date
Application number
PCT/KR2014/001415
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English (en)
Korean (ko)
Inventor
윤석일
곽상민
엄준근
박세정
이남정
이중훈
Original Assignee
주식회사 엘지화학
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Application filed by 주식회사 엘지화학 filed Critical 주식회사 엘지화학
Priority to CN201480000464.0A priority Critical patent/CN104303082B/zh
Priority to US14/359,686 priority patent/US20150022878A1/en
Publication of WO2014129839A1 publication Critical patent/WO2014129839A1/fr

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Classifications

    • G—PHYSICS
    • G02—OPTICS
    • G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/1333—Constructional arrangements; Manufacturing methods
    • G02F1/1335—Structural association of cells with optical devices, e.g. polarisers or reflectors
    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00—Optical elements other than lenses
    • G02B5/20—Filters
    • G02B5/208—Filters for use with infrared or ultraviolet radiation, e.g. for separating visible light from infrared and/or ultraviolet radiation
    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00—Optical elements other than lenses
    • G02B5/30—Polarising elements
    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00—Optical elements other than lenses
    • G02B5/30—Polarising elements
    • G02B5/3025—Polarisers, i.e. arrangements capable of producing a definite output polarisation state from an unpolarised input state
    • G02B5/3075—Polarisers, i.e. arrangements capable of producing a definite output polarisation state from an unpolarised input state for use in the UV
    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00—Optical elements other than lenses
    • G02B5/30—Polarising elements
    • G02B5/3083—Birefringent or phase retarding elements
    • G02B5/3091—Birefringent or phase retarding elements for use in the UV
    • G—PHYSICS
    • G02—OPTICS
    • G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/1333—Constructional arrangements; Manufacturing methods
    • G02F1/1335—Structural association of cells with optical devices, e.g. polarisers or reflectors
    • G02F1/133528—Polarisers

Definitions

  • the present invention relates to an optical film and a polarizing plate including the same, and more particularly to an acrylic optical film having an excellent UV blocking function and a polarizing plate including the same.
  • a polarizing plate used in an image display device such as a liquid crystal display device generally uses a triacetyl cellulose film (hereinafter, TAC film) as a protective film for protecting a polyvinyl alcohol polarizer.
  • TAC film triacetyl cellulose film
  • the TAC film does not have sufficient heat and moisture resistance, and when used under high temperature or high humidity, the TAC film has a problem in that polarization plate characteristics such as polarization degree and color are degraded due to film deformation. Therefore, in recent years, a method of using a transparent acrylic resin film having excellent moisture resistance and heat resistance instead of the TAC film has been proposed as a material of the polarizer protective film.
  • the technique which prevents a polarizer from being degraded by an ultraviolet-ray by adding a ultraviolet absorber to such an acryl-type film to have ultraviolet absorption performance was also proposed.
  • a benzotriazol compound or a benzophenone compound, a cyano acrylate compound, a salicylic acid compound, etc. may be used as the ultraviolet absorber.
  • the ultraviolet absorbents are mostly decomposed during high temperature processing, not only the UV absorbing ability is lowered, but also the yellowing of the resin and the film due to thermal decomposition of the ultraviolet absorber.
  • the ultraviolet absorbers are added to the acrylic resin, the glass transition temperature is significantly lowered compared to the resin composition before the addition, and thus the heat resistance may be degraded, or the optical properties of the optical film may be adversely affected.
  • the present invention is to solve the above problems, to provide an acrylic optical film and a polarizing plate including the same that can effectively block ultraviolet rays without adversely affecting the physical properties of the optical film.
  • the present invention is an acrylic resin having a glass transition temperature of 120 °C or more, including an alkyl (meth) acrylate repeating unit and a styrene repeating unit; And it provides an optical film comprising a UV absorber 1% pyrolysis temperature is 2.5 times or more than the glass transition temperature of the acrylic resin.
  • the UV absorber is preferably included in an amount of 0.1 to 5 parts by weight based on 100 parts by weight of the acrylic resin.
  • the UV absorber may be a triazine UV absorber, it is preferable that the 1% pyrolysis temperature is about 300 to 400 °C.
  • the optical film of the present invention preferably has a light transmittance of 5% or less with respect to a 380 nm wavelength measured in terms of a film thickness of 40 ⁇ m, and a variation in b value of the optical film is preferably 0.5 or less.
  • the present invention provides a polarizing plate including at least one or more optical films of the present invention.
  • the optical film of the present invention uses a UV absorber having a high 1% pyrolysis temperature, there is almost no thermal decomposition of the UV absorber even in a high temperature process such as pelletizing a resin or stretching a film. The yellowing phenomenon can be effectively suppressed and the transparency of the film can be maintained high.
  • the optical film of the present invention not only has an excellent UV blocking effect, but also has a high light transmittance in the visible light region, and also has excellent heat resistance.
  • the inventors of the present invention have repeatedly studied to develop an optical film having excellent UV blocking effect and excellent physical properties such as transparency, color, and durability, and have thus developed the optical film of the present invention.
  • the optical film of the present invention has (1) a glass transition temperature of 120 ° C. or more, an acrylic resin containing an alkyl (meth) acrylate-based repeating unit and a styrene-based repeating unit, and (2) a 1% pyrolysis temperature of the acrylic resin. It contains a UV absorber that is at least 2.5 times the glass transition temperature.
  • the optical film of this invention uses acrylic resin whose glass transition temperature is 120 degreeC or more, Preferably it is 120 degreeC-200 degreeC, More preferably, it is 120 degreeC-140 degreeC as a base material. This is because when the glass transition temperature of the acrylic resin is lower than 120 ° C., the heat resistance of the film may be inferior, and the polarizing plate whip phenomenon may occur after the polarizing plate lamination, or the durability may be deteriorated.
  • the said acrylic resin is copolymer resin containing an alkyl (meth) acrylate type repeating unit and a styrene type repeating unit.
  • the alkyl (meth) acrylate means both alkyl acrylate and alkyl methacrylate, but is not limited thereto, in view of optical transparency, compatibility, processability and productivity, the alkyl (meth) acrylate It is preferable that carbon number of the alkyl group of is about 1-10, It is more preferable that it is about 1-4 carbon atoms, It is more preferable that it is a methyl group or an ethyl group.
  • the alkyl (meth) acrylate may be methyl acrylate, ethyl acrylate, methyl methacrylate, ethyl methacrylate, and the like, and methyl methacrylate is particularly preferred.
  • the content of the alkyl (meth) acrylate repeating unit is about 50 to 99.9 parts by weight, preferably 70 to 99 parts by weight, more preferably about 97 to 99.9 parts by weight based on 100 parts by weight of the copolymer resin. desirable. This is because excellent retardation characteristics and optical characteristics can be obtained when the content of the alkyl (meth) acrylate repeating unit is in the above range.
  • the styrene-based repeating unit means a repeating unit derived from a substituted or unsubstituted styrene monomer, for example, from ⁇ -methyl styrene, p-methyl methacrylate, vinyl toluene, t-butyl styrene It may be a derived repeating unit. Among these, ⁇ -methyl styrene is particularly preferable.
  • the content of the styrene-based repeating unit is preferably about 0.1 to 10 parts by weight, preferably about 0.1 to 5 parts by weight, more preferably about 0.1 to 3 parts by weight based on 100 parts by weight of the copolymer resin. This is because excellent retardation characteristics and optical characteristics can be obtained when the content of the styrenic repeating unit is in the above range.
  • the acrylic resin has an imide-based repeating unit, a vinyl cyanide-based repeating unit, a 3- to 6-membered heterocyclic unit substituted with at least one carbonyl group and / or an aromatic ring to improve heat resistance ( It may further include a meth) acrylate-based repeat unit.
  • the imide-based repeating unit may include repeating units derived from maleimide, for example, maleimide substituted with an alkyl group having 1 to 10 carbon atoms or maleimide substituted with an aryl group having 6 to 12 carbon atoms. And repeating units derived from cyclohexyl maleade, phenyl maleimide, and the like.
  • the content of the imide-based repeating unit may be about 1 to 30 parts by weight, preferably about 5 to 20 parts by weight, and more preferably about 8 to 15 parts by weight based on 100 parts by weight of the copolymer resin.
  • the vinyl cyanide-based repeating unit may be, for example, repeating units derived from acrylonitrile.
  • the content of the vinyl cyanide repeating unit may be about 1 to 30 parts by weight, preferably about 5 to 20 parts by weight, and more preferably about 8 to 15 parts by weight based on 100 parts by weight of the copolymer resin.
  • Examples of the (meth) acrylate-based repeating unit having the aromatic ring include repeating units derived from (meth) acrylate containing an aromatic ring having 6 to 12 carbon atoms, and specifically, phenyl ( Meth) acrylate, benzyl (meth) acrylate, and the like.
  • the content of the (meth) acrylate-based repeating unit having the aromatic ring may be about 1 to 50 parts by weight, preferably about 5 to 30 parts by weight, and more preferably about 5 to 10 parts by weight based on 100 parts by weight of the acrylic resin. Can be.
  • specific examples of the 3 to 6 membered heterocyclic repeating unit substituted with the at least one carbonyl group may include a lactone ring unit.
  • the content of the 3 to 6 membered heterocyclic repeating unit substituted with at least one carbonyl group is about 10 to 50 parts by weight, preferably about 20 to 40 parts by weight, more preferably 25 to 100 parts by weight of the copolymer resin. It is preferable that it is about 35 weight part.
  • the acrylic resin of the present invention may be a compounding resin in which another resin is blended in the copolymer resin including the repeating units.
  • the resin that can be blended into the acrylic resin of the present invention for example, an aromatic resin having a carbonate portion in the main chain can be used.
  • the aromatic resin having a carbonate portion in the main chain may be a polycarbonate resin
  • the aromatic resin and an acrylic resin having a carbonate portion in the main chain may be mixed in a weight ratio of 0.1: 100 ⁇ 10: 100, preferably It may be mixed in a weight ratio of 0.5: 100 to 8: 100, and more preferably in a weight ratio of 1: 100 to 5: 100.
  • the UV absorber is 1% pyrolysis temperature is 2.5 times or more, preferably 2.5 to 5.0 times, more preferably 2.5 to 3.0 times the glass transition temperature of the acrylic resin used as the base material. Do. When the 1% pyrolysis temperature of the UV absorber is less than 2.5 times the glass transition temperature of the acrylic resin, the casting roll may be contaminated while a migration phenomenon occurs in which the UV absorber escapes to the outside of the film during film processing.
  • the 1% pyrolysis temperature of the UV absorber is preferably about 300 ° C to 400 ° C. In consideration of contamination resistance and optical properties, it is most preferable that the 1% pyrolysis temperature of the UV absorber is within the above numerical range.
  • the 1% pyrolysis temperature of the UV absorber is a value measured using TGA equipment of TA Co., when the temperature is raised at a rate of 10 °C per minute in a nitrogen atmosphere, the weight of the UV absorber is reduced by 1% compared to the initial weight It means the temperature when.
  • Triazine-based UV absorbers usable in the present invention include, but are not limited to, Tinuvin 460 from BASF, LA F70 from ADEKA, and the like.
  • the UV absorber is preferably about 0.1 to 5 parts by weight, more preferably about 0.1 to 4 parts by weight based on 100 parts by weight of the acrylic resin. This is because when the content of the UV absorber satisfies the above range, both the optical properties and the UV blocking effect of the film are excellent.
  • the manufacturing method of the optical film of this invention as mentioned above is not specifically limited,
  • acrylic resin, additives, such as a UV absorber and another polymerizing agent are fully mixed by arbitrary suitable mixing methods, and a thermoplastic resin composition is prepared. After manufacturing, it may be produced by film molding.
  • the thermoplastic resin composition may be prepared by, for example, pre-blending the film raw material with any suitable mixer such as an omni mixer and then extruding and kneading the obtained mixture.
  • suitable mixer such as an omni mixer and then extruding and kneading the obtained mixture.
  • the mixer used for extrusion kneading is not specifically limited,
  • any suitable mixers such as an extruder, such as a single screw extruder and a twin screw extruder, and a pressurized kneader, can be used.
  • film forming may be performed by any suitable film forming method well known in the art, such as, for example, solution casting (solution casting), melt extrusion, calendering, extrusion molding, and the like. Solution casting or melt extrusion is preferred.
  • Aromatic hydrocarbons such as benzene, toluene, xylene; Aliphatic hydrocarbons such as cyclohexane and decalin; Esters such as ethyl acetate and butyl acetate; Ketones such as acetone, methyl ethyl ketone and methyl isobutyl ketone; Alcohols such as methanol, ethanol, isopropanol, butanol, isobutanol, methyl cellosolve, ethyl cellosolve and butyl cellosolve; Ethers such as tetrahydrofuran and dioxane; Halogenated hydrocarbons such as dichloromethane, chloroform and carbon tetrachloride; Dimethylformamide; Dimethyl sulfoxide etc. are mentioned. These solvents may be used alone or in combination of two or more thereof.
  • Molding temperature becomes like this.
  • it is 150-350 degree
  • a T-die method As said melt extrusion method, a T-die method, an inflation method, etc. are mentioned, for example.
  • a T-die When forming a film by the said T-die method, a T-die is attached to the front-end
  • the optical film of the present invention may be either an unstretched film or a stretched film.
  • a stretched film it may be a uniaxial stretched film or a biaxially stretched film
  • a biaxially stretched film it may be either a simultaneous biaxially stretched film or a successive biaxially stretched film.
  • biaxial stretching the mechanical strength is improved and the film performance is improved.
  • when blended with other thermoplastic resin to the acrylic resin it is possible to suppress the increase in the phase difference by stretching to maintain optical isotropy.
  • the stretching is (Tg-30 ° C) to (Tg + 100 ° C), more preferably (Tg-20 ° C) to (Tg + 80 ° C) when the glass transition temperature of the resin composition is Tg. It is preferably carried out in the temperature range of. If the stretching temperature is lower than (Tg-30 ° C), a sufficient draw ratio may not be obtained. If the stretching temperature is higher than (Tg + 100 ° C), the resin composition may flow (flow), which may prevent stable stretching. have.
  • the draw ratio is preferably 1.1 to 25 times, more preferably about 1.3 to 10 times as defined by the area ratio. It is because physical property improvement effects, such as toughness, are the most preferable when draw ratio is in the said numerical range.
  • the stretching speed is preferably 10 to 20,000% / min, more preferably 100 to 10,000% / min in one direction.
  • the stretching speed is less than 10% / min, the time taken to obtain a sufficient stretching ratio may be long, and the productivity may deteriorate.
  • the stretching speed exceeds 20,000% / min, there is a fear that breakage of the stretched film occurs.
  • the optical film of this invention can further perform heat processing (annealing) after the above extending
  • the heat treatment condition is not particularly limited and may be appropriately adjusted according to the desired physical properties.
  • the optical film of the present invention prepared by the method as described above has a very excellent UV blocking effect with a light transmittance of 5% or less for the wavelength of 380nm measured in terms of film thickness of 40 ⁇ m.
  • the optical film of the said invention is excellent in a color sense with the change rate of b value being 0.5 or less.
  • the optical film of the present invention is excellent in optical properties with a light transmittance of 92% or more in the visible light region.
  • the optical film of the present invention is attached to one or both sides of the polarizer can be usefully used as a polarizing plate protective film.
  • the polarizer and the optical film of the present invention is coated with an adhesive on the surface of the film or polarizer using a roll coater, gravure coater, bar coater, knife coater or capillary coater, etc. It may be carried out by a method of laminating by heating or pressing at room temperature.
  • adhesive adhesives used in the art, for example, polyvinyl alcohol-based adhesives, polyurethane-based adhesives, acrylic adhesives and the like can be used without limitation.
  • optical film of the present invention can be applied to various displays such as a liquid crystal display, a plasma display, an electroluminescent device.
  • 1% pyrolysis temperature measured using TGA of TA.
  • the poly (N-cyclohexylmaleimide-co-methylmethacrylate-co- ⁇ methyl-styrene) resin has N-cyclohexylmarimide content of 6.0 wt% and ⁇ methyl-styrene content of 2.0 wt% according to NMR analysis. Was%.
  • the raw material pellets prepared above were vacuum dried and melted with an extruder at 250 ° C., passed through a T-die of a coat hanger type, and a film having a thickness of 200 ⁇ m was passed through a chrome plating casting roll and a drying roll. Prepared.
  • This film was used to prepare a biaxially stretched film having a thickness of 40 ⁇ m at a ratio of twice each of the films in the MD and TD directions at 130 to 135 ° C. using an experimental film stretching equipment.
  • the light transmittance and b value for the 380 nm wavelength of the film and the degree of migration in the process of film formation were measured and shown in Table 1 below.
  • the film was exposed to 1000 ° C. under 0.6 W / m 2 condition at 60 ° C. in an At2000 UV2000 apparatus, and then the light transmittance and b value were measured.

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  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Nonlinear Science (AREA)
  • Mathematical Physics (AREA)
  • Chemical & Material Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Polarising Elements (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)

Abstract

La présente invention se rapporte à un film optique qui comprend une résine acrylique présentant une température de transition vitreuse égale ou supérieure à 120 °C et contenant des unités répétitives à base de (méth)acrylate d'alkyle et des unités répétitives à base de styrène ; et un agent absorbant les ultraviolets, la température de pyrolyse de 1 % étant égale ou supérieure à 2,5 fois la température de transition vitreuse de la résine acrylique. La présente invention se rapporte également à une plaque de polarisation qui comprend le film.
PCT/KR2014/001415 2013-02-21 2014-02-21 Film optique ayant une excellente fonction de blocage des rayons ultraviolets et plaque de polarisation comportant ce dernier WO2014129839A1 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
CN201480000464.0A CN104303082B (zh) 2013-02-21 2014-02-21 具有优异的紫外阻隔效果的光学膜和包括该光学膜的偏光板
US14/359,686 US20150022878A1 (en) 2013-02-21 2014-02-21 Optical film having excellant uv blocking effect and polarizing plate comprising the same

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
KR10-2013-0018781 2013-02-21
KR1020130018781A KR101629064B1 (ko) 2013-02-21 2013-02-21 자외선 차단 기능이 우수한 광학 필름 및 이를 포함하는 편광판

Publications (1)

Publication Number Publication Date
WO2014129839A1 true WO2014129839A1 (fr) 2014-08-28

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PCT/KR2014/001415 WO2014129839A1 (fr) 2013-02-21 2014-02-21 Film optique ayant une excellente fonction de blocage des rayons ultraviolets et plaque de polarisation comportant ce dernier

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Country Link
US (1) US20150022878A1 (fr)
KR (1) KR101629064B1 (fr)
CN (1) CN104303082B (fr)
TW (1) TWI495650B (fr)
WO (1) WO2014129839A1 (fr)

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US10613260B2 (en) 2014-11-11 2020-04-07 Samsung Sdi Co., Ltd. Window film for display and display device including same
JP2016224182A (ja) * 2015-05-28 2016-12-28 日東電工株式会社 偏光板および液晶表示装置
JP2017088728A (ja) * 2015-11-10 2017-05-25 株式会社カネカ 光学フィルム、偏光板、および画像表示装置

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KR20090075624A (ko) * 2008-01-03 2009-07-08 주식회사 엘지화학 광학 필름, 편광자 보호 필름, 이를 이용한 편광판, 및 이를 이용한 화상 표시 장치
JP2009161744A (ja) * 2007-12-11 2009-07-23 Kaneka Corp 熱可塑性樹脂組成物、光学用フィルムおよび偏光子保護フィルム
JP2010044314A (ja) * 2008-08-18 2010-02-25 Nippon Zeon Co Ltd 光学部材用保護フィルムおよび偏光板
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KR101226343B1 (ko) * 2005-03-31 2013-01-24 닛토덴코 가부시키가이샤 편광자 보호 필름, 편광판, 및 화상 표시 장치
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JP5439075B2 (ja) * 2009-07-21 2014-03-12 太陽ホールディングス株式会社 光硬化性樹脂組成物
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JP2009161744A (ja) * 2007-12-11 2009-07-23 Kaneka Corp 熱可塑性樹脂組成物、光学用フィルムおよび偏光子保護フィルム
KR20090075624A (ko) * 2008-01-03 2009-07-08 주식회사 엘지화학 광학 필름, 편광자 보호 필름, 이를 이용한 편광판, 및 이를 이용한 화상 표시 장치
JP2010044314A (ja) * 2008-08-18 2010-02-25 Nippon Zeon Co Ltd 光学部材用保護フィルムおよび偏光板
JP2012082304A (ja) * 2010-10-08 2012-04-26 Kaneka Corp 光学用フィルム
JP2012082358A (ja) * 2010-10-14 2012-04-26 Kaneka Corp 光学用フィルム

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Publication number Publication date
CN104303082B (zh) 2017-04-26
KR101629064B1 (ko) 2016-06-21
US20150022878A1 (en) 2015-01-22
CN104303082A (zh) 2015-01-21
KR20140104820A (ko) 2014-08-29
TW201437238A (zh) 2014-10-01
TWI495650B (zh) 2015-08-11

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