WO2014122385A1 - Web of multilayer material made from cellular foam and textile fibres and associated production method - Google Patents

Web of multilayer material made from cellular foam and textile fibres and associated production method Download PDF

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Publication number
WO2014122385A1
WO2014122385A1 PCT/FR2014/050187 FR2014050187W WO2014122385A1 WO 2014122385 A1 WO2014122385 A1 WO 2014122385A1 FR 2014050187 W FR2014050187 W FR 2014050187W WO 2014122385 A1 WO2014122385 A1 WO 2014122385A1
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Prior art keywords
foam
layer
felt
fibers
multilayer material
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Application number
PCT/FR2014/050187
Other languages
French (fr)
Inventor
Richard PAPIN
Original Assignee
Société D'innovation De Recyclage Textiles Et Matériaux Alvéolaires "Innortex"
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Publication of WO2014122385A1 publication Critical patent/WO2014122385A1/en

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • B32B5/08Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer the fibres or filaments of a layer being of different substances, e.g. conjugate fibres, mixture of different fibres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • B32B5/022Non-woven fabric
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/18Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by features of a layer of foamed material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/22Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
    • B32B5/24Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
    • B32B5/245Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer another layer next to it being a foam layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2250/00Layers arrangement
    • B32B2250/22All layers being foamed
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2250/00Layers arrangement
    • B32B2250/40Symmetrical or sandwich layers, e.g. ABA, ABCBA, ABCCBA
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/02Synthetic macromolecular fibres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/02Synthetic macromolecular fibres
    • B32B2262/0253Polyolefin fibres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/02Synthetic macromolecular fibres
    • B32B2262/0276Polyester fibres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/02Synthetic macromolecular fibres
    • B32B2262/0276Polyester fibres
    • B32B2262/0284Polyethylene terephthalate [PET] or polybutylene terephthalate [PBT]
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/12Conjugate fibres, e.g. core/sheath or side-by-side
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2266/00Composition of foam
    • B32B2266/02Organic
    • B32B2266/0207Materials belonging to B32B25/00
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2266/00Composition of foam
    • B32B2266/02Organic
    • B32B2266/0214Materials belonging to B32B27/00
    • B32B2266/0278Polyurethane
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/10Properties of the layers or laminate having particular acoustical properties
    • B32B2307/102Insulating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/30Properties of the layers or laminate having particular thermal properties
    • B32B2307/304Insulating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/50Properties of the layers or laminate having particular mechanical properties
    • B32B2307/544Torsion strength; Torsion stiffness
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/72Density
    • B32B2307/722Non-uniform density
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2479/00Furniture

Definitions

  • the present invention relates to the field of multilayer materials based on foam and textile, and their method of manufacture.
  • the present invention relates to the recycling of materials resulting from the recovery of production falls, or the recovery of bedding elements, such as mattresses, or furniture elements, such as upholstery elements, seats, armchairs, sofas or the like, based on cellular foam and / or textile.
  • the recycling of such elements is complex because it must integrate both the recycling of the "foam” part and that of the "textile” part, generally constituting the envelope of the foam-based elements.
  • An object of the present invention is therefore to propose the simultaneous recycling of these two categories of elements, by the manufacture of a material integrating both cellular foam waste and textile waste.
  • Another object of the invention is to provide a multilayer material incorporating both cellular foam waste and textile waste.
  • Sheets of foamed foam material are already known comprising agglomerates of foam, pieces of foam larger or smaller, interconnected by thermoplastic fibers.
  • Felt layers containing agglomerates of textile fibers and of thermoplastic fibers bonding textile fibers to one another are also known.
  • the present invention relates to a strip of multilayer material based on cellular foam characterized in that it comprises at least two adjacent layers:
  • a first flexible layer referred to as a foam layer
  • a foam layer formed of an agglomerate of foam pieces, of polyurethane or latex type, and of thermoplastic fibers, and possibly of textile fibers, the pieces of cellular foam forming the majority weight component at least one second layer, called a felt layer, which is stiffer than the foam layer and which contains a mixture of foam, textile fibers and thermoplastic fibers, the textile fibers being the majority weight component of said foam layer; felt layer,
  • said at least one adjacent foam layer and at least one felt layer being (thermo) bonded together by means of the thermoplastic fibers present in each of the two adjacent layers and flush with the surface of each of them.
  • the assembly of the layer (s) of foam and the (or) layer (s) of felt between them does not require the introduction of an adhesive film or glue between them.
  • the combination of these two types of layers namely the assembly of a layer of foam and a layer of felt, has the advantage of combining the flexibility of the foam layer with the relative greater rigidity of the layer of felt.
  • the foam layer is very light. Despite this lightness (low density), its combination with a felt layer gives it interesting properties, including improved performance of loss of height and hardness during dynamic fatigue tests.
  • the density of the cellular foam layer is advantageously less than 100 kg / m 3 , preferably less than 80 kg / m 3 , and more preferably less than 60 kg / m 3 .
  • the felt layer advantageously has a grammage higher than 300 g / m 2 and less than 1500g / m 2, preferably between 500 and 1000 g / m 2.
  • the second layer is of lesser thickness than the first layer, called the foam layer, in order to provide rigidity to said web of material without reducing the overall flexibility provided by the foam layer.
  • the foam layer may for example be of a thickness of between 20 mm and 500 mm, more preferably between 30 mm and 240 mm.
  • the thickness of the felt layer may be between 2 mm and 50 mm and preferably between 8 mm and 30 mm.
  • textile fiber is preferably meant cotton or viscose fibers, as frequently encountered in bedding or upholstery furniture or seat components but any other textile fiber is usable in the process according to the present invention.
  • the strip of multilayer material comprises at least two superimposed layers, one being a layer of foam and the other a layer of felt.
  • the strip of multilayer material comprises at least three superimposed layers, one being at least one layer of foam disposed between at least two layers of felt.
  • the strip of multilayer material may comprise at least one layer of felt disposed longitudinally within a layer of foam, preferably in a corrugated or sinusoidal arrangement inside the layer. of foam, in particular for stiffening said foam layer.
  • thermoplastic fibers used for the thermo-bonding between the constituents of the foam layer between the constituents of the felt layer, and between the different layers: felt and foam thus formed are preferably polypropylene fibers or polyester fibers, such as polyethylene terephthalate (PET) fibers or poly (lactic acid) (PLA) fibers, or a combination of these fibers.
  • PET polyethylene terephthalate
  • PLA poly (lactic acid)
  • thermoplastic fibers are polyester fibers
  • the latter are preferably fibers of two-component type comprising a core housed in a sheath (peripheral envelope), the core having a softening point or higher melting than respectively the point of softening or melting of the sheath.
  • a bi-component polyester fiber having a softening or melting point sheath of about 100 to about 180 ° C and a softening or melting point core of greater than 200 ° C is suitable as a heat-setting fiber in the present invention.
  • the felt layer comprises a weight proportion of foam pieces of between 2 and 25%, preferably between 5 and 20%, more preferably between 6 and 10%.
  • the foam layer comprises a weight proportion of textile fibers of between 0 and 30%, preferably between 5 and 30%, more preferably between 5 and 25%.
  • the proportion of thermoforming thermoplastic fibers may be equal or different in the different layers, preferably the at least one layer of foam and the at least one layer of felt comprise a proportion by weight of thermoplastic fibers of between 5% and 35%, preferably between 10% and 30%.
  • the strips of multilayer material according to the invention can be configured and assembled according to an assembly in which said strips of multilayer material are arranged side by side, transversely or longitudinally, and are (thermally) bonded together by means of said thermoplastic fibers present in each of the at least two layers forming said adjacent strips and flush on the edge of each of them.
  • the present invention also relates to a method of continuously manufacturing strips of multilayer material as described above. This process comprises the following successive steps:
  • grinding pieces of foam to the desired size preferably of size between 5 and 30 mm, preferably between 8 and 25 mm, more preferably between 10 and 20 mm; ii - elimination of the finest pieces of foam, namely less than 5 mm, preferably less than 2 mm;
  • grinding the pieces of foam is meant both the shredding of larger pieces but also the cutting to achieve fragments of more regular shapes by means for example of rotary scissors. These clean cuts can influence the quality of the foam layer.
  • the mixture is more homogeneous, the arrangements of the pieces between them are more precise and can contribute to a better coefficient of expansion, and a better behavior of the material in terms of loss of height and hardness.
  • Foam webs and felt webs may be formed by a needling process, or advantageously by a process known as "air lay” in which the fibers are positioned and oriented with air (for example, machine “air lay” of the manufacturer LAROCHE).
  • This "air lay” method is preferred because it does not require mechanical intervention within the material, in contrast to the needling process using needles to place the fibers in the desired orientation.
  • the formation of the web of felt takes place continuously, and the mixture of the components of the foam layer is deposited continuously on said web of previously formed felt before passing through the oven and compression.
  • the foamed materials and textiles used are derived from the recycling of bedding elements, such as mattresses, or upholstered furniture upholstery elements, such as seats.
  • Recycling means both the dismantling of mattresses or furniture or the recycling of manufacturing scrap. These recycled products used for the production of strips of multilayer material according to the invention can be reused for the realization of new upholstery or bedding materials.
  • spring-type springs for the mattress may be inserted.
  • FIG. 1 is a sectional diagram of a strip of multilayer material according to the first embodiment of the invention. invention;
  • Figure 2 is a sectional diagram of a strip of multilayer material according to the second embodiment of the invention;
  • Figure 3 is a sectional diagram of a strip of multilayer material according to the third embodiment of the invention;
  • FIG. 4 schematizes the method of continuous manufacture of strips of multilayer materials according to the invention;
  • Figure 5 is a sectional diagram of a variant of the second embodiment of multilayer strips according to the invention;
  • FIG. 6 is a diagram illustrating the method of producing the multilayer strip of FIG. 5.
  • the strip of multilayer material (1; 1 1; 21) consists of at least one layer 2 of cellular foam, and at least one layer felt 3; 3A, 3B; 3C.
  • the layer called felt layer 3 consists of an agglomerate, that is to say here a mixture as homogeneous as possible pieces of cellular foam, textile fibers and thermoplastic fibers.
  • textile fibers are the majority weight component.
  • the layer 2 is an agglomerate, as homogeneous as possible mixture of pieces of foam, thermoplastic fibers and optionally textile fibers.
  • the pieces of cellular foam constitute the majority weight component of this layer of foam 2.
  • the strip of multilayer material according to the invention can be presented in three different main aspects:
  • a felt layer 3 and a foam layer 2 are superimposed and adhere to one another by means of the thermoplastic thermo-forming fibers contained in each of said layers to form the multilayer strip 1 1 ;
  • At least one layer of foam 2 is interposed between two layers of felt 3A and 3B, the layers being bonded together by means of the thermoplastic fibers of thermobonding to form the multilayer strip 1 1;
  • the multilayer strip 21 comprises a layer of foam 2 enclosing within it one or more layers of felt 3C arranged (for example) , as schematized in this figure 3, sinusoidally in the heart of said foam layer.
  • Figure 4 the method of manufacturing a multilayer strip 1 1 having a layer of foam 2 disposed between two layers of felt 3A and 3B, that is to say according to the second embodiment of embodiment of the invention.
  • the starting materials of the felt layers are textile fibers, in particular frayed textile fibers from production residues or post-consumer products, for example bedding, agglomerated with a polyester-type thermolating fiber.
  • the felt layer also incorporates pieces of foam, the whole is mixed, applied to an "air lay" type machine to form a sheet of felt which, after passing through an oven (such as the oven 6 of FIG. ), is compressed for the purpose of stabilizing the material, and after cooling into rolls 4A and 4B.
  • a first felt layer coming from the roll 4B is positioned on the conveyor 10 of the "air lay" type machine and will constitute the lower layer of felt 3B of the strip of multilayer material 1 1 final.
  • the foam layer is made continuously on said lower felt layer 3B after mixing, thermo-forming fibers 7 with foam pieces 12 in a hopper 8, the mixture being spread on the lower felt layer 3B.
  • a layer of felt 3A (top felt layer) from a second roll 4A is applied over the foam layer 5 thus formed.
  • thermoling fibers 7 can be softened to bind, on the one hand, to the other components of the foam layer and, on the other hand, to the layers of felt 3A lower and upper 3B between which it is positioned.
  • a compression is preferably applied at the time of passage through the oven 6 when the assembly is still hot to form a strip of multilayer material 1 1 according to the invention.
  • springs 9 can be positioned in the thickness of the foam layer 2 to form the strip of multilayer material 31 shown in FIG. 5.
  • These springs 9 can be in the form of a spring plate inserted into the mixture of foam and fibers before compression; they may be plastic springs or steel-type metal springs. In the latter case, the metal springs are first integrated in a non-woven bag which allows them to be associated with each other to form a plate, that is to say a set of poly-springs.
  • constituents used for the different layers of felt and foam may be:
  • the textile fibers are advantageously derived from recycling of bedding material for example which comprises both textile fibers and cellular foam.
  • the textile fiber mixture also contains a fraction of reduced size foam flakes during the fraying phase.
  • a hygienization phase can be implemented prior to the use of these materials.
  • added polyester thermoloading fibers represent a proportion by weight of between 5 and 35%, preferably between 10% and 30% of the total weight of the felt layer and between 5 and 35%, preferably between 10 and 30%; % of the total mass of the foam layer.
  • the thermolating fiber is preferably a bi-component polyester fiber composed of a core and a shell called sheath.
  • the sheath melts at a temperature close to 1 10 ° C while the core can withstand temperatures of about 200 ° C.
  • the softening of the sheath thus makes it possible to ensure the sticky power, also called the thermoliant, of these fibers.
  • these fibers Preferably, these fibers have a linear weight between 2.2 and 20 decitex and a length of between 15 and 60 mm approximately.
  • the foam layer is an agglomerate of flakes of polyurethane foam or latex which may be derived from the production residues of a foam plant or plant using these materials, or from material from post-furnishing products. consumption for example.
  • foam flakes are prepared by a grinding process, for example by means of a knife mill, equipped with a grid with 15 mm round or square holes. This grinding makes it possible to obtain a size of flakes or pieces of approximately 15 mm, the fine particles being thus eliminated.
  • the foam layer 2 may, for example, have a thickness of between 20 mm and 250 mm. Its density may advantageously be between 20 and 50 kg / m 3 approximately, depending on the degree of compression.
  • the layer (s) of felt can (wind) have a thickness of between 2 mm and 50 mm, preferably between 8 and 30 mm for use in bedding or furniture, with a basis weight of between 300 g / m 2 and 1000 g / m 2 .
  • a strip of multilayer material is prepared according to the method described above.
  • the different layers are composed as follows:
  • the foam layers consist of 80% by weight of an agglomerate of recycled polyurethane foam pieces from dismantled mattresses, mixed with 20% of low-melt polyester bicomponent fibers (hot-melt sheath at 110 ° C. - Manufacturer Far Eastern) (fibers of 32 mm length, 4 denier).
  • the densities of the three foam layers A, B and C manufactured are summarized in Table 1.
  • This felt layer comprises an agglomerate of recycled textile fibers (75% by weight), recycled foam (5% by weight) and 20% by weight of the same two-component polyester fibers as those used for the foam layers of the samples. comparative.
  • the foam A it is the addition of the felt layer which allows to pass the threshold of the 25% loss of hardness.
  • the combination, according to the invention, of a layer of foam with a layer of felt thus makes it possible to obtain interesting mechanical properties, in particular for use in the field of bedding.
  • the content of volatile organic compounds of this multilayer material was measured according to ISO 16000 methods (-3, -6, -9, -1 1) on a sample of 1 m 2 of multilayer material with a total thickness of 50 mm.
  • the volume of the emitting chamber is 1 m 3 with a charge rate of 1 m 2 / m 3 and a renewal of air of 0.5 m 3 / h.
  • the incoming air is dried over activated silica gel and filtered by means of a VOC filter.
  • the samples taken on 200/400 carbon tube and DNPH 300/150 silica tube are analyzed by GC-MS (VOC) and HPLC (Aldehydes).
  • the sample volume at 3 and 28 days is 90 liters at 60 l / h.
  • the value of the average density calculated is of 49.75 Kg / m 3 . This value is close to that of polyurethane panels (of the order of 40 Kg / m 3 ), rock wool (of the order of 40 Kg / m 3 ) and cellulose wadding medium density (from the order of 55 Kg / m 3 ) (see Table 3). Stabi! dj.mens ion nej I
  • the thermal conductivity of the wet or dry sample was also measured by the guarded hot plate method, which is one of the most widely used steady-state measurement methods.
  • the thermal conductivity measured on dry material (stabilized at 10 ° C) is 0.03563 W / mK and the thermal conductivity on a wet material (stabilized at 50% relative humidity and at 20 ° C) is 0.3593 W / mK.
  • thermal conductivity of the wet material or the dry material are very small. These thermal conductivity values are close to those of expanded polystyrene, polyester, glass wool, cellulose wadding in bulk or panel or sheep wool (see Table 4).
  • the acoustic absorption performance of the material is also very good.
  • the absorption coefficient is greater than 0.8 from 800 Hertz, which is comparable to values obtained with commonly used acoustic materials (mineral wool, foam).
  • the multilayer material according to the present invention has properties very close to those of rockwool, cellulose wadding and wood fiber.
  • a use of the multilayer material according to the invention in the fields of thermal and acoustic insulation can thus be envisaged.

Abstract

A web of multilayer material (11) made from cellular foam characterised in that it comprises at least two adjacent layers: -at least one first flexible layer, called the foam layer (2), formed from an agglomerate of pieces of polyurethane or latex foam, and thermoplastic fibres, and optionally textile fibres, the pieces of cellular foam forming the majority component by weight of said foam layer, -at least one second layer, called the felt layer (3A, 3B), which is more rigid than the foam layer (2), containing a mixture of foam, textile fibres and thermoplastic fibres, the textile fibres being the majority component by weight of said felt layer, said adjacent at least one foam layer and at least one felt layer being (thermo)bonded together by means of the thermoplastic fibres present in each of the two adjacent layers and flush with the surface of each of them. The invention also concerns the method of producing the web of multilayer material.

Description

BANDE DE MATERIAU MULTICOUCHE A BASE DE MOUSSE ALVEOLAIRE ET DE FIBRES TEXTILES ET PROCEDE DE FABRICATION ASSOCIE  BAND OF MULTILAYER MATERIAL BASED ON ALVEOLAR FOAM AND TEXTILE FIBERS AND METHOD OF MANUFACTURING THE SAME
La présente invention concerne le domaine des matériaux multicouches à base de mousse et de textile, ainsi que leur procédé de fabrication. The present invention relates to the field of multilayer materials based on foam and textile, and their method of manufacture.
Plus particulièrement, la présente invention concerne le recyclage de matériaux issus de la récupération de chutes de production, ou de la récupération d'éléments de literie, tels que des matelas, ou d'éléments d'ameublement, tels que des éléments de rembourrage, de sièges, fauteuils, canapés ou assimilés, à base de mousse alvéolaire et/ou de textile. Le recyclage de tels éléments est complexe car il doit intégrer à la fois le recyclage de la partie « mousse » et celui de la partie « textile », constituant généralement l'enveloppe des éléments à base de mousse. More particularly, the present invention relates to the recycling of materials resulting from the recovery of production falls, or the recovery of bedding elements, such as mattresses, or furniture elements, such as upholstery elements, seats, armchairs, sofas or the like, based on cellular foam and / or textile. The recycling of such elements is complex because it must integrate both the recycling of the "foam" part and that of the "textile" part, generally constituting the envelope of the foam-based elements.
Dans le recyclage des matériaux issus de matelas ou d'élément de rembourrage de mobilier, on procède généralement à un démantèlement des différents éléments constitutifs de la literie ou des éléments de garnissage de mobilier rembourré, puis un déchiquetage des éléments à base de mousse ainsi qu'un effilochage des éléments textiles. Le tri de ces différents constituants est une opération longue et fastidieuse. Un but de la présente invention est donc de proposer le recyclage simultané de ces deux catégories d'éléments, par la fabrication d'un matériau intégrant à la fois les déchets de mousse alvéolaire et les déchets de textile. In the recycling of materials from mattresses or furniture upholstery, the various elements of bedding or upholstered furniture upholstery are generally dismantled, followed by shredding of the foam-based elements. a fraying of the textile elements. The sorting of these different constituents is a long and tedious operation. An object of the present invention is therefore to propose the simultaneous recycling of these two categories of elements, by the manufacture of a material integrating both cellular foam waste and textile waste.
Un autre but de l'invention est de proposer un matériau multicouche intégrant à la fois des déchets de mousse alvéolaire et des déchets de textile. On connaît déjà des bandes de matériau à base de mousse alvéolaire comprenant des agglomérats de mousse, de morceaux de mousse plus ou moins gros, liés entre eux par des fibres thermoplastiques. On connaît par ailleurs la réalisation de couches de feutre renfermant des agglomérats de fibres textiles et de fibres thermoplastiques liant les fibres textiles entre elles. La présente invention concerne une bande de matériau multicouche à base de mousse alvéolaire caractérisée en ce qu'elle comprend au moins deux couches adjacentes : Another object of the invention is to provide a multilayer material incorporating both cellular foam waste and textile waste. Sheets of foamed foam material are already known comprising agglomerates of foam, pieces of foam larger or smaller, interconnected by thermoplastic fibers. Felt layers containing agglomerates of textile fibers and of thermoplastic fibers bonding textile fibers to one another are also known. The present invention relates to a strip of multilayer material based on cellular foam characterized in that it comprises at least two adjacent layers:
- au moins une première couche souple, dénommée couche de mousse, formée d'un agglomérat de morceaux de mousse, de type polyuréthane ou latex, et de fibres thermoplastiques, et éventuellement de fibres textiles, les morceaux de mousse alvéolaire formant le composant pondéral majoritaire de ladite couche de mousse, - au moins une seconde couche, dénommée couche de feutre, plus rigide que la couche de mousse, renfermant un mélange de mousse, de fibres textiles et de fibres thermoplastiques, les fibres textiles étant le composant pondéral majoritaire de ladite couche de feutre, at least a first flexible layer, referred to as a foam layer, formed of an agglomerate of foam pieces, of polyurethane or latex type, and of thermoplastic fibers, and possibly of textile fibers, the pieces of cellular foam forming the majority weight component at least one second layer, called a felt layer, which is stiffer than the foam layer and which contains a mixture of foam, textile fibers and thermoplastic fibers, the textile fibers being the majority weight component of said foam layer; felt layer,
lesdites au moins une couche de mousse et au moins une couche de feutre adjacentes étant (thermo)liées entre elles au moyen des fibres thermoplastiques présentes dans chacune des deux couches adjacentes et affleurant à la surface de chacune d'elles. L'assemblage de la (ou des) couche(s) de mousse et de la (ou des) couche(s) de feutres entre elles, ne nécessite pas l'introduction d'un film adhésif ni de colle entre celles-ci. La combinaison de ces deux types de couche, à savoir l'assemblage d'une couche de mousse et d'une couche de feutre, présente l'avantage de combiner la souplesse de la couche de mousse avec la relative plus grande rigidité de la couche de feutre. En outre, la couche de mousse est très légère. En dépit de cette légèreté (faible masse volumique), sa combinaison avec une couche de feutre lui confère des propriétés intéressantes, notamment une amélioration des performances de perte de hauteur et de dureté lors des tests de fatigue dynamique. said at least one adjacent foam layer and at least one felt layer being (thermo) bonded together by means of the thermoplastic fibers present in each of the two adjacent layers and flush with the surface of each of them. The assembly of the layer (s) of foam and the (or) layer (s) of felt between them, does not require the introduction of an adhesive film or glue between them. The combination of these two types of layers, namely the assembly of a layer of foam and a layer of felt, has the advantage of combining the flexibility of the foam layer with the relative greater rigidity of the layer of felt. In addition, the foam layer is very light. Despite this lightness (low density), its combination with a felt layer gives it interesting properties, including improved performance of loss of height and hardness during dynamic fatigue tests.
La masse volumique de la couche de mousse alvéolaire est avantageusement inférieure à 100 kg/m3, de préférence inférieure à 80 kg/m3, et de préférence encore inférieure à 60 kg/m3. La couche de feutre présente avantageusement un grammage supérieur à 300 g/m2 et inférieur à 1500g/m2, de préférence compris entre 500 et 1000 g/m2. The density of the cellular foam layer is advantageously less than 100 kg / m 3 , preferably less than 80 kg / m 3 , and more preferably less than 60 kg / m 3 . The felt layer advantageously has a grammage higher than 300 g / m 2 and less than 1500g / m 2, preferably between 500 and 1000 g / m 2.
De manière avantageuse, la seconde couche, dénommée couche de feutre, est de moindre épaisseur que la première couche, dite couche de mousse, en vue d'apporter rigidité à ladite bande de matériau sans réduire la souplesse générale apportée par la couche de mousse. La couche de mousse peut par exemple être d'une épaisseur comprise entre 20 mm et 500 mm, de préférence encore entre 30 mm et 240 mm. L'épaisseur de la couche de feutre peut être comprise entre 2 mm et 50 mm et de préférence entre 8 mm et 30 mm. Advantageously, the second layer, called the felt layer, is of lesser thickness than the first layer, called the foam layer, in order to provide rigidity to said web of material without reducing the overall flexibility provided by the foam layer. The foam layer may for example be of a thickness of between 20 mm and 500 mm, more preferably between 30 mm and 240 mm. The thickness of the felt layer may be between 2 mm and 50 mm and preferably between 8 mm and 30 mm.
Par fibre textile on entend, de préférence, des fibres en coton ou en viscose, telles que rencontrées fréquemment dans les composants de literie ou de rembourrage de mobilier ou de siège mais toute autre fibre textile est utilisable dans le procédé selon la présente invention. By textile fiber is preferably meant cotton or viscose fibers, as frequently encountered in bedding or upholstery furniture or seat components but any other textile fiber is usable in the process according to the present invention.
Selon un premier mode de réalisation de l'invention, la bande de matériau multicouche comprend au moins deux couches superposées, l'une étant une couche de mousse et l'autre une couche de feutre. According to a first embodiment of the invention, the strip of multilayer material comprises at least two superimposed layers, one being a layer of foam and the other a layer of felt.
Selon un second mode de réalisation de l'invention, la bande de matériau multicouche comprend au moins trois couches superposées, l'une étant au moins une couche de mousse disposée entre au moins deux couches de feutre. Selon un troisième mode de réalisation de l'invention, la bande de matériau multicouche peut comprendre au moins une couche de feutre disposée longitudinalement au sein d'une couche de mousse, de préférence selon un agencement ondulé ou sinusoïdal à l'intérieur de la couche de mousse, en vue notamment de la rigidification de ladite couche de mousse. According to a second embodiment of the invention, the strip of multilayer material comprises at least three superimposed layers, one being at least one layer of foam disposed between at least two layers of felt. According to a third embodiment of the invention, the strip of multilayer material may comprise at least one layer of felt disposed longitudinally within a layer of foam, preferably in a corrugated or sinusoidal arrangement inside the layer. of foam, in particular for stiffening said foam layer.
Les fibres thermoplastiques servant à la thermo-liaison entre les constituants de la couche de mousse entre les constituants de la couche de feutre, et entre les différentes couches : feutre et mousse ainsi formées, sont de préférence des fibres de polypropylène ou des fibres polyester, telles que des fibres de polyéthylène téréphtalate (PET) ou des fibres de poly(acide lactique) (PLA), ou une combinaison de ces fibres. The thermoplastic fibers used for the thermo-bonding between the constituents of the foam layer between the constituents of the felt layer, and between the different layers: felt and foam thus formed, are preferably polypropylene fibers or polyester fibers, such as polyethylene terephthalate (PET) fibers or poly (lactic acid) (PLA) fibers, or a combination of these fibers.
Lorsque les fibres thermoplastiques sont des fibres polyester, ces dernières sont de préférence des fibres de type bi-composant comprenant une âme logée dans une gaine (enveloppe périphérique), l'âme présentant un point de ramollissement ou de fusion plus élevé que respectivement le point de ramollissement ou de fusion de la gaine. Par exemple, une fibre bi-composante polyester présentant une gaine à point de ramollissement ou de fusion compris entre 100 et 180°C environ et une âme à point de ramollissement ou de fusion supérieur à 200°C, est appropriée comme fibre thermoliante dans la présente invention. When the thermoplastic fibers are polyester fibers, the latter are preferably fibers of two-component type comprising a core housed in a sheath (peripheral envelope), the core having a softening point or higher melting than respectively the point of softening or melting of the sheath. For example, a bi-component polyester fiber having a softening or melting point sheath of about 100 to about 180 ° C and a softening or melting point core of greater than 200 ° C is suitable as a heat-setting fiber in the present invention.
De manière avantageuse, la couche de feutre comprend une proportion pondérale en morceaux de mousse comprise entre 2 et 25 %, de préférence entre 5 et 20 %, de préférence encore entre 6 et 10 %. Advantageously, the felt layer comprises a weight proportion of foam pieces of between 2 and 25%, preferably between 5 and 20%, more preferably between 6 and 10%.
De manière avantageuse, la couche de mousse comprend une proportion pondérale en fibres textiles comprise entre 0 et 30 %, de préférence entre 5 et 30 %, de préférence encore entre 5 et 25 %. La proportion en fibres thermoplastiques thermoliantes peut être égale ou différente dans les différentes couches, de préférence la au moins une couche de mousse et la au moins une couche de feutre comprennent une proportion pondérale en fibres thermoplastiques comprise entre 5 % et 35 %, de préférence entre 10 % et 30 %. Les bandes de matériau multicouche selon l'invention peuvent être configurées et assemblées selon un ensemble dans lequel lesdites bandes de matériau multicouche sont disposées côte à côte, transversalement ou longitudinalement, et sont (thermo)liées entre elles au moyen des dites fibres thermoplastiques présentes dans chacune des au moins deux couches composant les dites bandes adjacentes et affleurant sur la tranche de chacune d'elles. Advantageously, the foam layer comprises a weight proportion of textile fibers of between 0 and 30%, preferably between 5 and 30%, more preferably between 5 and 25%. The proportion of thermoforming thermoplastic fibers may be equal or different in the different layers, preferably the at least one layer of foam and the at least one layer of felt comprise a proportion by weight of thermoplastic fibers of between 5% and 35%, preferably between 10% and 30%. The strips of multilayer material according to the invention can be configured and assembled according to an assembly in which said strips of multilayer material are arranged side by side, transversely or longitudinally, and are (thermally) bonded together by means of said thermoplastic fibers present in each of the at least two layers forming said adjacent strips and flush on the edge of each of them.
Des proportions pondérales en fibres thermoliantes minimales de 5 % sont préférées pour une bonne liaison des bandes multicouches juxtaposées. La présente invention concerne également un procédé de fabrication en continu de bandes de matériau multicouche telles que décrites ci-dessus. Ce procédé comprend les étapes successives suivantes: Weight ratios of minimum thermoforming fibers of 5% are preferred for good bonding of the multilayer strips juxtaposed. The present invention also relates to a method of continuously manufacturing strips of multilayer material as described above. This process comprises the following successive steps:
i - broyage de morceaux de mousse à la dimension souhaitée, de préférence de taille comprise entre 5 et 30 mm, de préférence entre 8 et 25 mm, de préférence encore entre 10 et 20 mm ; ii - élimination des morceaux de mousse les plus fins, à savoir inférieurs à 5 mm, de préférence inférieurs à 2 mm ; grinding pieces of foam to the desired size, preferably of size between 5 and 30 mm, preferably between 8 and 25 mm, more preferably between 10 and 20 mm; ii - elimination of the finest pieces of foam, namely less than 5 mm, preferably less than 2 mm;
iii- déchiquetage et effilochage de morceaux textiles pour produire des fibres textiles ; iv- mélange des morceaux de mousse, des fibres textiles et des fibres thermoplastiques selon les proportions pondérales requises pour former séparément au moins une nappe de mousse et au moins une nappe de feutre ; iii- shredding and fraying of textile pieces to produce textile fibers; iv- mixing pieces of foam, textile fibers and thermoplastic fibers according to the weight proportions required to separately form at least one foam sheet and at least one felt sheet;
v- assemblage des dites nappes de mousse et de feutre par passage dans un four pour réaliser le ramollissement des fibres thermoplastiques présentes au sein des dites nappes, et ainsi la thermo liaison de nappes adjacentes, v- assembly of said plies of foam and felt by passing through an oven to achieve the softening of the thermoplastic fibers present within said plies, and thus the thermo-bonding of adjacent plies,
le passage dans le four étant accompagné et/ou suivi d'une opération de compression de l'assemblage desdites nappes ; the passage through the furnace being accompanied and / or followed by an operation of compressing the assembly of said plies;
vi- refroidissement de la bande de matériau multicouche ainsi réalisée. vi- cooling of the strip of multilayer material thus produced.
La compression "à chaud" renforce l'adhésion des matériaux entre eux et des couches entre elles. Ceci apporte, en outre, à la bande de matériau finie une tenue en sollicitation de fatigue statique ou dynamique. "Hot" compression strengthens the adhesion of materials between them and layers between them. This additionally provides the finished material web with static or dynamic fatigue stress resistance.
Par broyage des morceaux de mousse, on entend à la fois le déchiquetage de morceaux de taille plus importante mais également la découpe pour réaliser des fragments de formes plus régulières au moyen par exemple de ciseaux rotatifs. Ces coupes propres peuvent influencer la qualité de la couche de mousse. Le mélange est plus homogène, les dispositions des morceaux entre eux sont plus précises et permettent de contribuer à un meilleur coefficient de foisonnement, et à une meilleure tenue du matériau en terme de perte de hauteur et de dureté. By grinding the pieces of foam is meant both the shredding of larger pieces but also the cutting to achieve fragments of more regular shapes by means for example of rotary scissors. These clean cuts can influence the quality of the foam layer. The mixture is more homogeneous, the arrangements of the pieces between them are more precise and can contribute to a better coefficient of expansion, and a better behavior of the material in terms of loss of height and hardness.
La formation des nappes de mousse et des nappes de feutre peut s'effectuer par un procédé d'aiguilletage, ou de manière avantageuse par un procédé, appelé "air lay" dans lequel on positionne et on oriente les fibres avec de l'air (par exemple, machine "air lay" du fabricant LAROCHE). Ce procédé "air lay" est préféré car il ne nécessite pas d'intervention mécanique au sein du matériau au contraire du procédé d'aiguilletage mettant en œuvre des aiguilles pour placer les fibres selon l'orientation souhaitée. Foam webs and felt webs may be formed by a needling process, or advantageously by a process known as "air lay" in which the fibers are positioned and oriented with air ( for example, machine "air lay" of the manufacturer LAROCHE). This "air lay" method is preferred because it does not require mechanical intervention within the material, in contrast to the needling process using needles to place the fibers in the desired orientation.
De préférence, la formation de la nappe de feutre a lieu en continu, et le mélange des composants de la couche de mousse est déposé en continu sur ladite nappe de feutre formée précédemment avant le passage dans le four et la compression. Preferably, the formation of the web of felt takes place continuously, and the mixture of the components of the foam layer is deposited continuously on said web of previously formed felt before passing through the oven and compression.
De manière avantageuse, les matériaux mousses et textiles utilisés sont issus du recyclage d'éléments de literie, tels que des matelas, ou d'éléments de garnissage de mobiliers rembourrés, tels que sièges. Advantageously, the foamed materials and textiles used are derived from the recycling of bedding elements, such as mattresses, or upholstered furniture upholstery elements, such as seats.
Par recyclage, on entend à la fois le démantèlement de matelas ou de mobilier ou encore le recyclage de chutes de fabrication. Ces produits recyclés servant à la réalisation de bandes de matériau multicouche selon l'invention peuvent être réutilisés pour la réalisation de nouveaux matériaux de rembourrage ou de literie. A cet effet, en variante, lors du dépôt du mélange des composants de la couche de mousse, peuvent être insérés des ressorts de type ressorts pour matelas. La bande de matériau multicouche, de préférence selon le second mode de réalisation de l'invention, à savoir deux couches de feutre entourant une couche de mousse, elle-même enfermant des éléments ressorts, constitue ainsi une bande de matériau complète pouvant être utilisée directement comme élément de rembourrage dans l'ameublement (âme de matelas par exemple). Elle présente l'avantage de pouvoir être réalisée en continu au moyen du procédé de fabrication selon l'invention. Recycling means both the dismantling of mattresses or furniture or the recycling of manufacturing scrap. These recycled products used for the production of strips of multilayer material according to the invention can be reused for the realization of new upholstery or bedding materials. For this purpose, alternatively, during the deposition of the mixture of the components of the foam layer, spring-type springs for the mattress may be inserted. The strip of multilayer material, preferably according to the second embodiment of the invention, namely two layers of felt surrounding a layer of foam, itself enclosing spring elements, thus constitutes a strip of complete material that can be used directly. as a cushioning element in furniture (mattress core for example). It has the advantage of being able to be carried out continuously by means of the manufacturing method according to the invention.
Les bandes de matériau multicouche, selon l'invention ainsi que l'ensemble de bandes décrites précédemment et préparées selon le procédé décrit ci-dessus, trouvent une utilisation intéressante en tant qu'isolant phonique et/ou thermique ou encore en tant que matériau de rembourrage. The strips of multilayer material, according to the invention as well as the set of strips described above and prepared according to the method described above, find an interesting use as a sound and / or thermal insulator or as a material of padding.
L'invention sera bien comprise à la lecture de la description suivante d'exemples de réalisation, en référence aux dessins annexés dans lesquels : la figure 1 est un schéma en coupe d'une bande de matériau multicouche selon le premier mode de réalisation de l'invention ; la figure 2 est un schéma en coupe d'une bande de matériau multicouche selon le deuxième mode de réalisation de l'invention ; la figure 3 est un schéma en coupe d'une bande de matériau multicouche selon le troisième mode de réalisation de l'invention ; la figure 4 schématise le procédé de fabrication continue de bandes de matériaux multicouches selon l'invention ; la figure 5 est un schéma en coupe d'une variante du second mode de réalisation de bandes multicouches selon l'invention ; la figure 6 est un schéma illustrant le procédé de réalisation de la bande multicouche de la figure 5. The invention will be better understood on reading the following description of exemplary embodiments, with reference to the appended drawings in which: FIG. 1 is a sectional diagram of a strip of multilayer material according to the first embodiment of the invention. invention; Figure 2 is a sectional diagram of a strip of multilayer material according to the second embodiment of the invention; Figure 3 is a sectional diagram of a strip of multilayer material according to the third embodiment of the invention; FIG. 4 schematizes the method of continuous manufacture of strips of multilayer materials according to the invention; Figure 5 is a sectional diagram of a variant of the second embodiment of multilayer strips according to the invention; FIG. 6 is a diagram illustrating the method of producing the multilayer strip of FIG. 5.
En se référant aux figures 1 , 2 et 3, la bande de matériau multicouche (1 ; 1 1 ; 21 ), selon l'invention, se compose d'au moins une couche 2 de mousse alvéolaire, et d'au moins une couche de feutre 3 ; 3A, 3B ; 3C. With reference to FIGS. 1, 2 and 3, the strip of multilayer material (1; 1 1; 21) according to the invention consists of at least one layer 2 of cellular foam, and at least one layer felt 3; 3A, 3B; 3C.
La couche dénommée couche de feutre 3 se compose d'un agglomérat, c'est-à-dire ici un mélange le plus homogène possible de morceaux de mousse alvéolaires, de fibres textiles et de fibres thermoplastiques. Dans cette couche de feutre, les fibres textiles sont le composant pondéral majoritaire. The layer called felt layer 3 consists of an agglomerate, that is to say here a mixture as homogeneous as possible pieces of cellular foam, textile fibers and thermoplastic fibers. In this layer of felt, textile fibers are the majority weight component.
La couche 2, dite de mousse, est un agglomérat, mélange le plus homogène possible, de morceaux de mousse, de fibres thermoplastiques et éventuellement de fibres textiles. Les morceaux de mousse alvéolaire constituent le composant pondéral majoritaire de cette couche de mousse 2. The layer 2, called foam, is an agglomerate, as homogeneous as possible mixture of pieces of foam, thermoplastic fibers and optionally textile fibers. The pieces of cellular foam constitute the majority weight component of this layer of foam 2.
La bande de matériau multicouche, selon l'invention, peut se présenter sous trois aspects principaux différents : The strip of multilayer material according to the invention can be presented in three different main aspects:
- selon un premier mode de réalisation (schématisé sur la figure 1 ), une couche de feutre 3 et une couche de mousse 2 sont superposées et adhèrent entre elles au moyen des fibres thermoplastiques thermoliantes contenues dans chacune desdites couches pour former la bande multicouche 1 1 ;  according to a first embodiment (shown diagrammatically in FIG. 1), a felt layer 3 and a foam layer 2 are superimposed and adhere to one another by means of the thermoplastic thermo-forming fibers contained in each of said layers to form the multilayer strip 1 1 ;
- selon un second mode de réalisation (schématisé sur la figure 2), au moins une couche de mousse 2 est interposée entre deux couches de feutre 3A et 3B, les couches étant liées entre elles au moyen des fibres thermoplastiques de thermoliaison pour former la bande multicouche 1 1 ; according to a second embodiment (shown diagrammatically in FIG. 2), at least one layer of foam 2 is interposed between two layers of felt 3A and 3B, the layers being bonded together by means of the thermoplastic fibers of thermobonding to form the multilayer strip 1 1;
- selon un troisième mode de réalisation de l'invention (schématisé sur la figure 3), la bande multicouche 21 comporte une couche de mousse 2 renfermant en son sein une ou plusieurs couche(s) de feutre 3C disposée(s), par exemple, comme schématisé sur cette figure 3, de manière sinusoïdale au cœur de ladite couche de mousse.  according to a third embodiment of the invention (shown diagrammatically in FIG. 3), the multilayer strip 21 comprises a layer of foam 2 enclosing within it one or more layers of felt 3C arranged (for example) , as schematized in this figure 3, sinusoidally in the heart of said foam layer.
A titre d'exemple est schématisé sur la figure 4 le procédé de fabrication d'une bande multicouche 1 1 comportant une couche de mousse 2 disposée entre deux couches de feutre 3A et 3B, c'est-à-dire selon le second mode de réalisation de l'invention. By way of example is shown schematically in Figure 4 the method of manufacturing a multilayer strip 1 1 having a layer of foam 2 disposed between two layers of felt 3A and 3B, that is to say according to the second embodiment of embodiment of the invention.
Les matériaux de départ des couches de feutre sont des fibres textiles, notamment des fibres textiles effilochées en provenance de résidus de production ou de produits post-consommation, literie par exemple, agglomérées avec une fibre thermoliante de type polyester. La couche de feutre intègre également des morceaux de mousse, l'ensemble est mélangé, appliqué sur une machine de type "air lay" pour former une nappe de feutre qui, après passage dans un four (tel que le four 6 de la figure 4), est comprimée à des fins de stabilisation de la matière, et après refroidissement mis sous forme de rouleaux 4A et 4B. The starting materials of the felt layers are textile fibers, in particular frayed textile fibers from production residues or post-consumer products, for example bedding, agglomerated with a polyester-type thermolating fiber. The felt layer also incorporates pieces of foam, the whole is mixed, applied to an "air lay" type machine to form a sheet of felt which, after passing through an oven (such as the oven 6 of FIG. ), is compressed for the purpose of stabilizing the material, and after cooling into rolls 4A and 4B.
Pour la réalisation du procédé en continu, tel que schématisé sur la figure 4, une première couche de feutre issue du rouleau 4B est positionnée sur le convoyeur 10 de la machine de type "air lay" et constituera la couche inférieure de feutre 3B de la bande de matériau multicouche 1 1 finale. La couche de mousse est réalisée en continu sur ladite couche de feutre inférieure 3B après mélange, des fibres thermoliantes 7 avec des morceaux de mousse alvéolaires 12 dans une trémie 8, le mélange 5 étant étalé sur la couche de feutre 3B inférieure. Puis une couche de feutre 3A (couche de feutre supérieure) issue d'un second rouleau 4A est appliquée au-dessus de la couche de mousse 5 ainsi formée. For the realization of the continuous process, as shown diagrammatically in FIG. 4, a first felt layer coming from the roll 4B is positioned on the conveyor 10 of the "air lay" type machine and will constitute the lower layer of felt 3B of the strip of multilayer material 1 1 final. The foam layer is made continuously on said lower felt layer 3B after mixing, thermo-forming fibers 7 with foam pieces 12 in a hopper 8, the mixture being spread on the lower felt layer 3B. Then a layer of felt 3A (top felt layer) from a second roll 4A is applied over the foam layer 5 thus formed.
L'ensemble passe ensuite dans le four 6 pour être réchauffé afin de permettre aux fibres thermoliantes 7 d'être ramollies pour se lier, d'une part, aux autres composants de la couche de mousse et, d'autre part, aux couches de feutre 3A inférieure et 3B supérieure entre lesquelles elle est positionnée. Une compression est, de préférence, appliquée au moment du passage dans le four 6 lorsque l'ensemble est encore chaud pour former une bande de matériau multicouche 1 1 selon l'invention. Selon une variante de ce procédé présentée sur la figure 6, des ressorts 9 peuvent être positionnés dans l'épaisseur de la couche de mousse 2 pour former la bande de matériau multicouche 31 présentée sur la figure 5. Ces ressorts 9 peuvent être sous la forme d'une plaque de ressorts insérée au sein du mélange 5 de mousse et de fibres avant compression ; il peut s'agir de ressorts en matière plastique ou de ressorts métalliques de type acier. Dans ce dernier cas, les ressorts métalliques sont d'abord intégrés dans une poche en non tissé qui permet de les associer entre eux pour former une plaque, c'est-à-dire un ensemble de poly-ressorts. The assembly then passes into the oven 6 to be heated in order to allow the thermoling fibers 7 to be softened to bind, on the one hand, to the other components of the foam layer and, on the other hand, to the layers of felt 3A lower and upper 3B between which it is positioned. A compression is preferably applied at the time of passage through the oven 6 when the assembly is still hot to form a strip of multilayer material 1 1 according to the invention. According to a variant of this method shown in FIG. 6, springs 9 can be positioned in the thickness of the foam layer 2 to form the strip of multilayer material 31 shown in FIG. 5. These springs 9 can be in the form of a spring plate inserted into the mixture of foam and fibers before compression; they may be plastic springs or steel-type metal springs. In the latter case, the metal springs are first integrated in a non-woven bag which allows them to be associated with each other to form a plate, that is to say a set of poly-springs.
A titre d'exemples, les constituants utilisés pour les différentes couches de feutre et de mousse peuvent être : By way of examples, the constituents used for the different layers of felt and foam may be:
- des fibres textiles, des fibres en viscose et/ou coton de longueur variant entre 10 mm et 80 mm. Ici les fibres textiles sont avantageusement issues de recyclage de matériau de literie par exemple qui comporte à la fois des fibres textiles et de la mousse alvéolaire. Dans ce cas, il se peut que le mélange des fibres textiles renferme également une fraction de flocons de mousse de taille réduite lors de la phase d'effilochage. Une phase d'hygiénisation peut être mise en œuvre préalablement à l'utilisation de ces matériaux. - des fibres de thermoliaison en polyester ajoutées représentent une proportion pondérale comprise entre 5 et 35 %, de préférence entre 10 % et 30 % de la masse totale de la couche de feutre et comprise entre 5 et 35 %, de préférence entre 10 et 30 % de la masse totale de la couche de mousse. La fibre thermoliante est, de préférence, une fibre bi-composante en polyester composée d'une âme et d'une enveloppe appelée gaine. La gaine fond à température voisine de 1 10°C alors que l'âme peut résister jusqu'à des températures de 200°C environ. Le ramollissement de la gaine permet donc d'assurer le pouvoir collant, appelé encore du thermoliant, de ces fibres. De préférence, ces fibres présentent un poids linéique entre 2,2 et 20 decitex et une longueur comprise entre 15 et 60 mm environ. - la couche de mousse est un agglomérat de flocons de mousse polyuréthane ou latex qui peuvent être issus de résidus de production d'usine de fabrication de mousse ou d'usine utilisant ces matériaux, ou bien de matière provenant de produits d'ameublement post-consommation par exemple. Dans ce dernier cas, une phase d'hygiénisation est mise en œuvre préalablement à l'utilisation de ces flocons de mousse. Ces flocons de mousse sont préparés par un procédé de broyage, par exemple au moyen d'un broyeur à couteaux, équipé d'une grille à trous ronds ou carrés de 15 mm. Ce broyage permet d'obtenir une taille de flocons ou morceaux d'environ 15 mm, les particules fines étant ainsi éliminées. - textile fibers, viscose fibers and / or cotton of length ranging between 10 mm and 80 mm. Here the textile fibers are advantageously derived from recycling of bedding material for example which comprises both textile fibers and cellular foam. In this case, it may be that the textile fiber mixture also contains a fraction of reduced size foam flakes during the fraying phase. A hygienization phase can be implemented prior to the use of these materials. added polyester thermoloading fibers represent a proportion by weight of between 5 and 35%, preferably between 10% and 30% of the total weight of the felt layer and between 5 and 35%, preferably between 10 and 30%; % of the total mass of the foam layer. The thermolating fiber is preferably a bi-component polyester fiber composed of a core and a shell called sheath. The sheath melts at a temperature close to 1 10 ° C while the core can withstand temperatures of about 200 ° C. The softening of the sheath thus makes it possible to ensure the sticky power, also called the thermoliant, of these fibers. Preferably, these fibers have a linear weight between 2.2 and 20 decitex and a length of between 15 and 60 mm approximately. the foam layer is an agglomerate of flakes of polyurethane foam or latex which may be derived from the production residues of a foam plant or plant using these materials, or from material from post-furnishing products. consumption for example. In the latter case, a hygienization phase is implemented prior to the use of these foam flakes. These foam flakes are prepared by a grinding process, for example by means of a knife mill, equipped with a grid with 15 mm round or square holes. This grinding makes it possible to obtain a size of flakes or pieces of approximately 15 mm, the fine particles being thus eliminated.
Après la phase de nappage et de thermoliaison, la couche de mousse 2 peut, par exemple, présenter une épaisseur comprise entre 20 mm et 250 mm. Sa masse volumique peut avantageusement être comprise entre 20 et 50 kg/m3 environ, selon le degré de compression. La ou les couche(s) de feutre peut(vent) présenter une épaisseur pouvant aller entre 2 mm et 50 mm, de préférence entre 8 et 30 mm pour une utilisation en literie ou ameublement, avec un grammage compris entre 300 g/m2 et 1000 g/m2. After the coating and thermolysis phase, the foam layer 2 may, for example, have a thickness of between 20 mm and 250 mm. Its density may advantageously be between 20 and 50 kg / m 3 approximately, depending on the degree of compression. The layer (s) of felt can (wind) have a thickness of between 2 mm and 50 mm, preferably between 8 and 30 mm for use in bedding or furniture, with a basis weight of between 300 g / m 2 and 1000 g / m 2 .
Des exemples de réalisation et des résultats de caractérisations physico-chimiques sont présentés ci-après. Exemplary embodiments and results of physicochemical characterizations are presented below.
Exemple 1 Example 1
Une bande de matériau multicouche est préparée selon le procédé décrit ci-dessus. Les différentes couches sont composées comme suit : A strip of multilayer material is prepared according to the method described above. The different layers are composed as follows:
- échantillons comparatifs : les couches de mousse sont constituées de 80 % en masse d'un agglomérat de morceaux de mousse alvéolaire polyuréthane recyclée en provenance de matelas démantelés, mélangés à 20 % de fibres bicomposant polyester low melt (gaine thermofusible à 1 10°C - Fabricant Far Eastern) (fibres de longueur de 32 mm, 4 denier). Différentes densités de mousse sont préparées correspondant à des compressions plus ou moins importantes de la nappe lors du passage dans le four (T° = 170°C) selon une opération continue sur un convoyeur à une vitesse moyenne d'environ 1 ,2 m/min. Les masses volumiques des trois couches de mousse A, B et C fabriquées sont regroupées dans le tableau 1. - un échantillon selon l'invention combine une couche de mousse A de 12 cm d'épaisseur présentant une masse volumique de 25 Kg/m3, et une couche de feutre d'épaisseur e = 10 mm et de grammage de 800 g/m2. Comparative samples: the foam layers consist of 80% by weight of an agglomerate of recycled polyurethane foam pieces from dismantled mattresses, mixed with 20% of low-melt polyester bicomponent fibers (hot-melt sheath at 110 ° C. - Manufacturer Far Eastern) (fibers of 32 mm length, 4 denier). Different densities of foam are prepared corresponding to more or less significant compressions of the web during the passage in the oven (T ° = 170 ° C) according to a continuous operation on a conveyor at an average speed of about 1.2 m. min. The densities of the three foam layers A, B and C manufactured are summarized in Table 1. a sample according to the invention combines a 12 cm thick layer of foam A having a density of 25 kg / m 3 , and a layer of felt of thickness e = 10 mm and a weight of 800 g / m 2 .
Cette couche de feutre comprend un agglomérat de fibres textiles recyclées (75 % en poids), de mousse recyclée (5 % en poids) et 20 % en poids des mêmes fibres bicomposant en polyester que celles mises en œuvre pour les couches de mousse des échantillons comparatifs. This felt layer comprises an agglomerate of recycled textile fibers (75% by weight), recycled foam (5% by weight) and 20% by weight of the same two-component polyester fibers as those used for the foam layers of the samples. comparative.
Dans un objectif de réutilisation d'une telle bande (mousse + feutre) dans le domaine de la literie, des tests de fatigue dynamique selon la norme IS03385 ont été réalisés. Les résultats de ces tests sont regroupés dans le tableau 1 . Tests de fatigue dynamique selon la norme ISO 3385 In order to reuse such a band (foam + felt) in the field of bedding, dynamic fatigue tests according to the IS03385 standard have been carried out. The results of these tests are summarized in Table 1. Dynamic fatigue tests according to ISO 3385
Figure imgf000013_0001
Figure imgf000013_0001
Tableau 1 On note que la présence de feutre associé à la couche de mousse de 25 Kg/m3 a un effet bénéfique sur la perte d'épaisseur de cette dernière en réduisant cette perte de plus de 8 mm, c'est-à-dire d'un tiers. Table 1 It is noted that the presence of felt associated with the foam layer of 25 kg / m 3 has a beneficial effect on the loss of thickness of the latter by reducing this loss by more than 8 mm, that is to say say of a third.
En ce qui concerne la perte de dureté, la norme ISO 3385 qui impose, pour un usage du matériau en literie, une perte de dureté inférieure ou égale à 25 % est respectée pour les mousses B et C. Regarding the loss of hardness, the ISO 3385 standard which imposes, for use of bedding material, a hardness loss of less than or equal to 25% is observed for foams B and C.
Pour la mousse A c'est l'ajout de la couche de feutre qui permet de passer le seuil des 25 % de perte de dureté. La combinaison, selon l'invention, d'une couche de mousse avec une couche de feutre permet donc d'obtenir des propriétés mécaniques intéressantes, notamment pour une utilisation dans le domaine de la literie. For the foam A it is the addition of the felt layer which allows to pass the threshold of the 25% loss of hardness. The combination, according to the invention, of a layer of foam with a layer of felt thus makes it possible to obtain interesting mechanical properties, in particular for use in the field of bedding.
Exemple 2 Example 2
Une bande de matériau multicouche, préparée selon le même procédé que l'exemple 1 , combine une couche de mousse A de 30 mm d'épaisseur présentant une masse volumique de 25 Kg/m3 entourée de deux couches de feutre d'épaisseur e = 10 mm et de grammage de 800 g/m2. La teneur en composés organiques volatils de ce matériau multicouche a été mesurée selon les méthodes ISO 16000 (-3, -6, -9, -1 1 ) sur un échantillon de 1 m2 de matériau multicouche d'épaisseur totale de 50 mm. A strip of multilayer material, prepared according to the same method as Example 1, combines a layer of foam A 30 mm thick having a density of 25 Kg / m 3 surrounded by two layers of thick felt e = 10 mm and weight of 800 g / m 2 . The content of volatile organic compounds of this multilayer material was measured according to ISO 16000 methods (-3, -6, -9, -1 1) on a sample of 1 m 2 of multilayer material with a total thickness of 50 mm.
Le volume de la chambre d'émission est de 1 m3 avec un taux de charge de 1 m2/m3 et un renouvellement de l'air de 0,5 m3/h. L'air entrant est séché sur gel de silice activée et filtré au moyen d'un filtre COV. The volume of the emitting chamber is 1 m 3 with a charge rate of 1 m 2 / m 3 and a renewal of air of 0.5 m 3 / h. The incoming air is dried over activated silica gel and filtered by means of a VOC filter.
Les échantillons prélevés sur tube charbon 200/400 et tube silice DNPH 300/150 sont analysés par GC-MS (COV) et HPLC (Aldéhydes). Le volume de prélèvement à 3 et 28 jours est de 90 litres à 60 l/h. The samples taken on 200/400 carbon tube and DNPH 300/150 silica tube are analyzed by GC-MS (VOC) and HPLC (Aldehydes). The sample volume at 3 and 28 days is 90 liters at 60 l / h.
La teneur en COV de ce matériau multicouche est présentée dans le tableau 2 ci- dessous : Concentration μ9/η"ΐ A+ The VOC content of this multilayer material is shown in Table 2 below: Concentration μ9 / η "ΐ A +
COV Total <244 <1000  VOC Total <244 <1000
1 ,4-Dichlorobenzène nd <60  1,4-Dichlorobenzene nd <60
2-Butoxyéthanol nd <1000  2-Butoxyethanol nd <1000
Acétaldéhyde 1 ,56 <200  Acetaldehyde 1, 56 <200
Ethylbenzène nd <750  Ethylbenzene nd <750
Formaldéhyde 4,96 <10  Formaldehyde 4.96 <10
Styrène nd <250  Styrene nd <250
Tétrachloroéthylène nd <250  Tetrachlorethylene nd <250
Toluène <20 <300  Toluene <20 <300
Triméthylbenzène nd <1000  Trimethylbenzene nd <1000
Xylène nd <200 nd : non détecté  Xylene nd <200 nd: not detected
Tableau 2 Ces résultats montrent que le matériau multicouche, selon l'invention, présente des valeurs de COV Totaux très faibles (<250 microgrammes/m3), ce qui permet de le classer comme matériau A+ pour son étiquetage COV, c'est-à-dire en classe la plus élevée. Ceci démontre que le matériau multicouche, selon l'invention, ne comportant pas de colle ni d'adhésif entre la couche de mousse et les couches de feutre, permet d'obtenir un matériau à très faible taux en Composés Organiques Volatils. Table 2 These results show that the multilayer material according to the invention has very low total VOC values (<250 micrograms / m 3 ), which makes it possible to classify it as A + material for its VOC labeling, ie to say in the highest class. This demonstrates that the multilayer material according to the invention, comprising no glue or adhesive between the foam layer and the felt layers, makes it possible to obtain a material with a very low content of Volatile Organic Compounds.
Exemple 3 - Caractérisations physiques asse yq \ u.m i q ue ap a rente Example 3 - Physical Characterizations ase yq \ um i q ue ap a rente
Sur le même type de matériau préparé que celui de l'exemple 2, ont été réalisés des essais de caractérisation de la masse volumique apparente de ce matériau selon la norme EN 1602. On the same type of material prepared as that of Example 2, tests were carried out to characterize the apparent density of this material according to EN 1602.
Sur différentes éprouvettes, la valeur de la masse volumique moyenne calculée est de 49,75 Kg/m3. Cette valeur est proche de celle des panneaux de polyuréthane (de l'ordre de 40 Kg/m3), de la laine de roche (de l'ordre de 40 Kg/m3) et de la ouate de cellulose moyenne densité (de l'ordre de 55 Kg/m3) (voir tableau 3). Stabi ! jté dj.mens ion nej je On different test specimens, the value of the average density calculated is of 49.75 Kg / m 3 . This value is close to that of polyurethane panels (of the order of 40 Kg / m 3 ), rock wool (of the order of 40 Kg / m 3 ) and cellulose wadding medium density (from the order of 55 Kg / m 3 ) (see Table 3). Stabi! dj.mens ion nej I
Les tests de caractérisation de la stabilité dimensionnelle à différentes conditions de température et d'humidité ont été réalisés selon les normes EN 1604 et EN 1604/A1 . Trois éprouvettes (A, B et C) ont été mesurées après une succession de conditions climatiques comme indiquée ci-dessous : Characterization tests for dimensional stability under different temperature and humidity conditions were carried out according to EN 1604 and EN 1604 / A1. Three test pieces (A, B and C) were measured after a succession of climatic conditions as indicated below:
- 48 heures à 5°C (+2) et 15 % (+5) HR - 48 hours at 5 ° C (+2) and 15% (+5) HR
- 48 heures à 25°C (+2) et 50 % (+5) HR  - 48 hours at 25 ° C (+2) and 50% (+5) HR
- 48 heures à 50°C (+2) et 90 % (+5) HR  - 48 hours at 50 ° C (+2) and 90% (+5) HR
(HR = Humidité Relative) (RH = Relative Humidity)
Les résultats sont donnés dans le tableau 3 ci-après : The results are given in Table 3 below:
Figure imgf000016_0001
Figure imgf000016_0001
Tableau 3 Table 3
Les variations dimensionnelles (épaisseur, longueur et largeur) sont très faibles malgré les conditions de température et d'hygrométrie imposées. L'isolant est donc stable au cours du temps. Ç nductjyjté thermique The dimensional variations (thickness, length and width) are very small despite the temperature and hygrometry conditions imposed. The insulation is stable over time. Thermal nductjyjt
La conductivité thermique de l'échantillon sec ou humide a également été mesurée par la méthode de la plaque chaude gardée qui est une des méthodes de mesure en régime stationnaire la plus utilisée. The thermal conductivity of the wet or dry sample was also measured by the guarded hot plate method, which is one of the most widely used steady-state measurement methods.
La conductivité thermique mesurée sur matériau sec (stabilisée à 10°C) est de 0,03563 W/mK et la conductivité thermique sur un matériau humide (stabilisée à 50 % d'humidité relative et à 20°C) est de 0,3593 W/mK. The thermal conductivity measured on dry material (stabilized at 10 ° C) is 0.03563 W / mK and the thermal conductivity on a wet material (stabilized at 50% relative humidity and at 20 ° C) is 0.3593 W / mK.
La différence est donc très faible entre la conductivité thermique du matériau humide ou du matériau sec. Ces valeurs de conductivité thermique sont proches de celles du polystyrène expansé, du polyester, de la laine de verre, de la ouate de cellulose en vrac ou en panneau ou encore la laine de mouton (voir tableau 4). The difference is therefore very small between the thermal conductivity of the wet material or the dry material. These thermal conductivity values are close to those of expanded polystyrene, polyester, glass wool, cellulose wadding in bulk or panel or sheep wool (see Table 4).
Absorption acoustique Acoustic absorption
Les performances en absorption acoustique du matériau sont également très bonnes. Le coefficient d'absorption est supérieur à 0,8 à partir de 800 Hertz, ce qui est comparable à des valeurs obtenues avec les matériaux acoustiques couramment utilisés (laine minérale, mousse). The acoustic absorption performance of the material is also very good. The absorption coefficient is greater than 0.8 from 800 Hertz, which is comparable to values obtained with commonly used acoustic materials (mineral wool, foam).
Résjstançe.à.ja djffusjon àja.yapeur d)e_au Enfin des essais de résistance à la diffusion à la vapeur d'eau selon la norme NF EN 12086 après avoir placé les échantillons dans une salle climatisée à 23°C (+2) et 50 % (+ 5) d'humidité relative (HR) stipulé dans la norme pendant plusieurs semaines. Resuspension.to.ready already in use. (D) Finally, water vapor diffusion resistance tests according to standard NF EN 12086 after having placed the samples in an air-conditioned room at 23 ° C (+2) and 50% (+ 5) relative humidity (RH) stipulated in the standard for several weeks.
Pour les essais, les échantillons ont été placés dans les conditions suivantes : For the tests, the samples were placed under the following conditions:
- 23°C - 1 1/50 % HR (solution saturée en NaOH / salle régulée à 50 % HR) - 23°C - 54/80 % HR (avec une solution saturée en K2C03 / étuve à 80 % HR) - 23°C - 80/99,5 % HR (avec une solution saturée en K2S04 / étuve à 80 % HR) Les évolutions des masses des échantillons testés ont également été contrôlées tout au long des essais. Les échantillons ont perdu ou gagné à peine 1 % en masse au cours des trois mois d'essais. Les échantillons ne sont donc pas hydrophiles. - 23 ° C - 1 1/50% RH (saturated NaOH solution / room regulated at 50% RH) - 23 ° C - 54/80% RH (with a saturated solution in K 2 CO 3 / oven at 80% RH ) - 23 ° C - 80 / 99.5% RH (with a saturated solution in K 2 S0 4 / oven at 80% RH) The evolutions of the masses of the samples tested were also checked all throughout the tests. The samples lost or gained barely 1% in mass during the three months of tests. The samples are therefore not hydrophilic.
Les valeurs moyennes de résistance à la diffusion de la vapeur d'eau (μ, m2.h.Pa/mg) et de la perméabilité à la vapeur d'eau (δ, mg/m.h.Pa) ont été calculées pour les conditions suivantes : 23°C - 54/80 % HR et 23°C - 80/99,5 % HR et sont respectivement de -0,9 et 0,06. Ces valeurs sont très proches de celles obtenues pour la laine de roche, notamment (cf. tableau 4). L'ensemble des résultats des caractérisations physiques du matériau multicouche selon la présente invention ainsi que la comparaison avec d'autres isolants sont présentés dans le tableau récapitulatif 4 ci-après. The mean values of resistance to water vapor diffusion (μ, m 2 .h.Pa / mg) and water vapor permeability (δ, mg / mhPa) were calculated for the following conditions: : 23 ° C - 54/80% RH and 23 ° C - 80 / 99.5% RH and are respectively -0.9 and 0.06. These values are very close to those obtained for rockwool, in particular (see Table 4). The set of results of the physical characterizations of the multilayer material according to the present invention as well as the comparison with other insulators are presented in the summary table 4 below.
Figure imgf000019_0001
Figure imgf000019_0001
Tableau 4 Si l'on prend en compte les valeurs de masse volumique apparente et de conductivité thermique, on peut en déduire que le matériau multicouche selon la présente invention présente des propriétés très proches de celles de la laine de roche, de la ouate de cellulose et de la fibre de bois. If the values of apparent density and thermal conductivity are taken into account, it can be deduced that the multilayer material according to the present invention has properties very close to those of rockwool, cellulose wadding and wood fiber.
Une utilisation du matériau multicouche selon l'invention dans les domaines de l'isolation thermique et acoustique peut ainsi être envisagée. A use of the multilayer material according to the invention in the fields of thermal and acoustic insulation can thus be envisaged.

Claims

REVENDICATIONS
1 . Bande de matériau multicouche à base de mousse alvéolaire caractérisée en ce qu'elle comprend au moins deux couches adjacentes : 1. Strip of multilayer material based on cellular foam characterized in that it comprises at least two adjacent layers:
- au moins une première couche souple, dénommée couche de mousse (2), formée d'un agglomérat de morceaux de mousse, de type polyuréthane ou latex, et de fibres thermoplastiques (7), et éventuellement de fibres textiles, les morceaux de mousse alvéolaire formant le composant pondéral majoritaire de ladite couche de mousse, - au moins une seconde couche, dénommée couche de feutre, plus rigide que la couche de mousse, renfermant un mélange de mousse, de fibres textiles et de fibres thermoplastiques, les fibres textiles étant le composant pondéral majoritaire de ladite couche de feutre, at least a first flexible layer, referred to as a foam layer (2), formed of an agglomerate of pieces of foam, of polyurethane or latex type, and of thermoplastic fibers (7), and optionally of textile fibers, the pieces of foam cellular membrane forming the majority weight component of said foam layer; - at least one second layer, referred to as a felt layer, which is stiffer than the foam layer and which contains a mixture of foam, textile fibers and thermoplastic fibers, the textile fibers being the majority weight component of said felt layer,
lesdites au moins une couche de mousse (2) et au moins une couche de feutre (3 ; 3A, 3B ; 3C) adjacentes étant (thermo)liées entre elles au moyen des fibres thermoplastiques présentes dans chacune des deux couches adjacentes et affleurant à la surface de chacune d'elles. said at least one layer of foam (2) and at least one adjacent layer of felt (3; 3A, 3B; 3C) being (thermo) bonded together by means of the thermoplastic fibers present in each of the two adjacent layers and flush with the surface of each of them.
2. Bande de matériau multicouche selon la revendication 1 caractérisée en ce que la seconde couche, dénommée couche de feutre, est de moindre épaisseur que la première couche, dite couche de mousse, en vue d'apporter rigidité à ladite bande de matériau sans réduire sa souplesse générale apportée par la couche de mousse (2). 2. strip of multilayer material according to claim 1 characterized in that the second layer, called felt layer, is of lesser thickness than the first layer, said layer of foam, to provide rigidity to said strip of material without reducing its general flexibility provided by the layer of foam (2).
3. Bande de matériau multicouche selon l'une quelconque des revendications 1 ou 2 caractérisée en ce qu'elle comprend au moins deux couches superposées l'une étant une couche de mousse (2) et l'autre une couche de feutre (3). 3. strip of multilayer material according to any one of claims 1 or 2 characterized in that it comprises at least two superposed layers one being a layer of foam (2) and the other a layer of felt (3) .
4. Bande de matériau multicouche selon l'une quelconque des revendications précédentes caractérisée en ce qu'elle comprend au moins trois couches superposées, l'une étant au moins une couche de mousse (2) disposée entre au moins deux couches de feutre (3A, 3B). 4. Strip of multilayer material according to any one of the preceding claims, characterized in that it comprises at least three superposed layers, one being at least one layer of foam (2) disposed between at least two layers of felt (3A , 3B).
5. Bande de matériau multicouche selon la revendication 1 caractérisée en ce qu'elle comprend au moins une couche de feutre (3C) disposée longitudinalement au sein d'une couche de mousse, de préférence selon un agencement ondulé ou sinusoïdal à l'intérieur de la couche de mousse (2), en vue notamment de la rigidification de ladite couche de mousse. 5. strip of multilayer material according to claim 1 characterized in that it comprises at least one layer of felt (3C) disposed longitudinally within a layer of foam, preferably in a corrugated or sinusoidal arrangement within the layer of foam (2), in particular for the purpose of stiffening said layer of foam.
6. Bande de matériau multicouche selon l'une quelconque des revendications précédentes caractérisée en ce que les fibres thermoplastiques (7) sont des fibres de polypropylène ou des fibres polyester, telles que des fibres de polyéthylène téréphtalate (PET) ou des fibres de poly(acide lactique) (PLA), ou une combinaison de ces fibres. 6. A strip of multilayer material according to any one of the preceding claims, characterized in that the thermoplastic fibers (7) are polypropylene fibers or polyester fibers, such as polyethylene terephthalate (PET) fibers or poly fibers ( lactic acid) (PLA), or a combination of these fibers.
7. Bande de matériau multicouche selon la revendication 6 caractérisée en ce que les fibres polyester sont des fibres de type bi-composant comprenant une âme logée dans une gaine, l'âme présentant un point de ramollissement ou de fusion plus élevé que respectivement le point de ramollissement ou de fusion de la gaine. 7. strip of multilayer material according to claim 6 characterized in that the polyester fibers are bi-component type fibers comprising a core housed in a sheath, the core having a softening or melting point higher than the point respectively softening or melting of the sheath.
8. Bande de matériau multicouche selon l'une quelconque des revendications précédentes, caractérisée en ce que la couche de feutre comprend une proportion pondérale en morceaux de mousse comprise entre 2 et 25 %, de préférence entre 5 et 20 %, de préférence encore entre 6 et 10 %. 8. strip of multilayer material according to any one of the preceding claims, characterized in that the felt layer comprises a weight proportion of foam pieces of between 2 and 25%, preferably between 5 and 20%, preferably between 6 and 10%.
9. Bande de matériau multicouche selon l'une quelconque des revendications précédentes, caractérisée en ce que la couche de mousse (2) comprend une proportion pondérale en fibres textiles comprise entre 0 et 30 %, de préférence entre 5 et 30 %, de préférence encore entre 5 et 25 %. 9. A strip of multilayer material according to any one of the preceding claims, characterized in that the foam layer (2) comprises a textile fiber weight proportion of between 0 and 30%, preferably between 5 and 30%, preferably still between 5 and 25%.
10. Bande de matériau multicouche selon l'une quelconque des revendications précédentes, caractérisée en ce que la au moins une couche de mousse (2) et la au moins une couche de feutre comprennent une proportion pondérale en fibres thermoplastiques (7) comprise entre 5 % et 35 %, de préférence entre 10 % et 30 %, la proportion en fibres thermoplastiques pouvant être égale ou différente dans les différentes couches. Multilayer material web according to one of the preceding claims, characterized in that the at least one layer of foam (2) and the at least one layer of felt comprise a proportion by weight of thermoplastic fibers (7) of between % and 35%, preferably between 10% and 30%, the proportion of thermoplastic fibers may be equal or different in the different layers.
1 1 . Ensemble de bandes de matériau multicouche caractérisé en ce que les dites bandes de matériau multicouche selon l'une quelconque des revendications précédentes sont disposées côte à côte, transversalement ou longitudinalement, et sont (thermo)liées entre elles au moyen des dites fibres thermoplastiques (7) présentes dans chacune des au moins deux couches composant les dites bandes adjacentes et affleurant sur la tranche de chacune d'elles. 1 1. Set of strips of multilayer material characterized in that said strips of multilayer material according to any one of the preceding claims are arranged side by side, transversely or longitudinally, and are (thermally) bonded together by means of said thermoplastic fibers (7). ) present in each of the at least two layers forming the said strips adjacent and flush on the edge of each.
12. Procédé de fabrication en continu de bandes de matériau multicouche selon l'une des revendications précédentes comprenant les étapes successives suivantes: 12. A method of continuous manufacture of strips of multilayer material according to one of the preceding claims comprising the following successive steps:
i - broyage de morceaux de mousse à la dimension souhaitée, de préférence de taille comprise entre 5 et 30 mm, de préférence entre 8 et 25 mm, de préférence encore entre 10 et 20 mm ; grinding pieces of foam to the desired size, preferably of size between 5 and 30 mm, preferably between 8 and 25 mm, more preferably between 10 and 20 mm;
ii - élimination des morceaux de mousse les plus fins, à savoir inférieurs à 5 mm, de préférence inférieurs à 2 mm ; ii - elimination of the finest pieces of foam, namely less than 5 mm, preferably less than 2 mm;
iii-déchiquetage et effilochage de morceaux textiles pour produire des fibres textiles ; iv- mélange des morceaux de mousse (12), des fibres textiles et des fibres thermoplastiques (7) selon les proportions pondérales requises pour former séparément au moins une nappe de mousse et au moins une nappe de feutre ; iii-shredding and fraying of textile pieces to produce textile fibers; iv- mixing pieces of foam (12), textile fibers and thermoplastic fibers (7) according to the weight proportions required to separately form at least one foam web and at least one felt web;
v- assemblage des dites nappes de mousse et de feutre par passage dans un four (6) pour réaliser le ramollissement des fibres thermoplastiques présentes au sein des dites nappes. et ainsi la thermo liaison de nappes adjacentes, v- assembly of said plies of foam and felt by passing through an oven (6) to achieve the softening of the thermoplastic fibers present within said plies. and thus the thermo binding of adjacent layers,
le passage dans le four étant accompagné et/ou suivi d'une opération de compression de l'assemblage desdites nappes the passage in the furnace being accompanied and / or followed by a compression operation of the assembly of said plies
vi- refroidissement de la bande de matériau multicouche ainsi réalisée. vi- cooling of the strip of multilayer material thus produced.
13. Procédé selon la revendication 12, caractérisé en ce que la formation de la nappe de feutre a lieu en continu, et en ce que le mélange des composants de la couche de mousse est déposé en continu sur ladite nappe de feutre (formée préalablement), avant le passage dans le four et la compression. Method according to claim 12, characterized in that the formation of the felt web takes place continuously, and in that the mixture of the components of the foam layer is continuously deposited on said felt web (previously formed). , before the passage in the oven and compression.
14. Procédé selon l'une quelconque des revendications 12 ou 13, caractérisé en ce que les matériaux mousses et textiles utilisés sont issus du recyclage d'éléments de literie, tels que des matelas, ou d'éléments de garnissage de mobiliers rembourrés, tels que sièges. 14. Method according to any one of claims 12 or 13, characterized in that the foamed materials and textiles used are derived from the recycling of bedding elements, such as mattresses, or padded furniture upholstery elements, such as than seats.
15. Procédé selon l'une quelconque des revendications 12 à 14, caractérisé en ce que lors du dépôt du mélange des composants de la couche de mousse sont insérés des ressorts de type ressorts pour matelas. 15. Method according to any one of claims 12 to 14, characterized in that during the deposition of the mixture of the components of the layer of foam are inserted spring-like springs for mattress.
16. Utilisation de bandes de matériau multicouche selon l'une quelconque des revendications 1 à 10, de l'ensemble de bandes selon la revendication 1 1 ou préparées selon le procédé des revendications 12 à 14 en tant qu'isolant phonique et/ou thermique. 16. Use of strips of multilayer material according to any one of 1 to 10, of the set of strips according to claim 1 1 or prepared according to the method of claims 12 to 14 as a sound insulator and / or thermal.
17. Utilisation de bandes de matériau multicouche selon l'une quelconque des revendications 1 à 10, de l'ensemble de bandes selon la revendication 1 1 ou préparées selon le procédé des revendications 12 à 15 en tant que matériau de rembourrage. 17. Use of strips of multilayer material according to any one of claims 1 to 10, the set of strips according to claim 1 1 or prepared according to the method of claims 12 to 15 as padding material.
PCT/FR2014/050187 2013-02-06 2014-02-03 Web of multilayer material made from cellular foam and textile fibres and associated production method WO2014122385A1 (en)

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FR1351027A FR3001657B1 (en) 2013-02-06 2013-02-06 BAND OF MULTILAYER MATERIAL BASED ON ALVEOLAR FOAM AND TEXTILE FIBERS AND METHOD OF MANUFACTURING THE SAME.
FR1351027 2013-02-06

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2017187024A1 (en) * 2016-04-29 2017-11-02 Ahlstrom-Munksjö Oyj Compostable lid intended to seal a capsule and a capsule sealed by the lid
CN114311862A (en) * 2021-12-30 2022-04-12 重庆再升科技股份有限公司 Low-density foam sound insulation medium and preparation method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1600096A2 (en) * 2004-05-26 2005-11-30 The Clorox Company Substrates incorporating foam
WO2009085679A1 (en) * 2007-12-28 2009-07-09 3M Innovative Properties Company Composite nonwoven fibrous webs and methods of making and using the same
DE102009043377A1 (en) * 2009-09-29 2011-04-07 F.S. Fehrer Automotive Gmbh Composite part comprises polyurethane-sandwich material with decorative surface containing a layer sequence with a decorative cover layer, first and second fiber-reinforced polyurethane-layer, and an intermediate layer made of plastic foam

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1600096A2 (en) * 2004-05-26 2005-11-30 The Clorox Company Substrates incorporating foam
WO2009085679A1 (en) * 2007-12-28 2009-07-09 3M Innovative Properties Company Composite nonwoven fibrous webs and methods of making and using the same
DE102009043377A1 (en) * 2009-09-29 2011-04-07 F.S. Fehrer Automotive Gmbh Composite part comprises polyurethane-sandwich material with decorative surface containing a layer sequence with a decorative cover layer, first and second fiber-reinforced polyurethane-layer, and an intermediate layer made of plastic foam

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2017187024A1 (en) * 2016-04-29 2017-11-02 Ahlstrom-Munksjö Oyj Compostable lid intended to seal a capsule and a capsule sealed by the lid
FR3050725A1 (en) * 2016-04-29 2017-11-03 Ahlstroem Oy COMPOSTABLE OPERATOR FOR CAPTURING CAPSULE AND CAPSULE OBSTRUCTED BY THE OPERCULE
CN109071103A (en) * 2016-04-29 2018-12-21 奥斯龙明士克公司 Compostability lid for seal capsule and the capsule by the lid sealing
US11794985B2 (en) 2016-04-29 2023-10-24 Ahlstrom Oyj Compostable lid intended to seal a capsule and a capsule sealed by the lid
CN114311862A (en) * 2021-12-30 2022-04-12 重庆再升科技股份有限公司 Low-density foam sound insulation medium and preparation method thereof

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