WO2014096530A1 - Method for manufacturing an electrolytic cell for use in an electrolysis process and electrolytic cell - Google Patents
Method for manufacturing an electrolytic cell for use in an electrolysis process and electrolytic cell Download PDFInfo
- Publication number
- WO2014096530A1 WO2014096530A1 PCT/FI2013/051155 FI2013051155W WO2014096530A1 WO 2014096530 A1 WO2014096530 A1 WO 2014096530A1 FI 2013051155 W FI2013051155 W FI 2013051155W WO 2014096530 A1 WO2014096530 A1 WO 2014096530A1
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- WO
- WIPO (PCT)
- Prior art keywords
- container unit
- inner space
- cathodes
- anodes
- end wall
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C7/00—Constructional parts, or assemblies thereof, of cells; Servicing or operating of cells
Definitions
- the invention relates to a method for manufacturing an electrolytic cell for corrosive electrolyte and for use in an electrolysis process such as for a process for electrowinning or electrorefining of metals as defined in the preamble of independent claim 1.
- the invention also relates to an electrolytic cell for corrosive electrolyte and for use in an electrolysis process such as for a process for electrowinning or electrorefining of metals as defined in the preamble of independent claim 11.
- Metal refers in this context for example but not limited to copper, nickel, zinc, lead, and silver.
- a container unit is in this context meant a container that is in the form of a separate unit having an inner space limited by a bottom, a first side wall extending from a first side edge of the bottom, a second side wall extending from a second side edge of the bottom, a first end wall extending from a first end edge of the bottom, and a second end wall extending from a second end edge of the bottom.
- a container unit of this type is for example presented in publication US 5,066,379.
- US 5,066,379 presents a container formed of polymer concrete in which minerals such as copper are purified in an electrolytic process.
- the container includes a bottom and end and side walls for containing a corrosive electrolyte, such as, a sulphuric or hydrochloric acid solution.
- An overflow box is integrally formed in a first formation extending vertically along one end wall of the cell and an overflow pipe is molded into the first formation and extends from the overflow box outwardly of the cell.
- a vertical covered inlet channel or cast-in pipe is provided at the opposite end of the container and extends from its upper to its lower end.
- a problem with electrolytic cells is that they are expensive to manufacture and expensive to transport and install because of their large size.
- the object of the invention is to provide an electrolytic cell that is economical to manufacture, transport and install.
- the method comprises a step for providing a container unit having an inner space limited by a bottom, a first side wall extending from a first side edge of the bottom, a second side wall extending from a second side edge of the bottom, a first end wall extending from a first end edge of the bottom, and a second end wall extending from a second end edge of the bottom.
- the method comprises additionally a step for providing a support member designed and dimensioned to extend at least partly in the inner space of the container unit between the first end wall of the container unit and the second end wall of the container unit.
- the method comprises additionally a step for arranging the support member at least partly in the inner space of the container unit between the first end wall of the container unit and the second end wall of the container unit to divide the inner space of the container unit into a first part for a first row of anodes and cathodes in alternating order and into a second part for a second row of anodes and cathodes in alternating order.
- the electrolytic cell of the invention is correspondingly characterized by the definitions of independent claim 11.
- the electrolytic cell comprises a container unit having an inner space limited by a bottom, a first side wall extending from a first side edge of the bottom, a second side wall extending from a second side edge of the bottom, a first end wall extending from a first end edge of the bottom, and a second end wall extending from a second end edge of the bottom.
- the electrolytic cell comprises a support member arranged at least partly in the inner space of the container unit between the first end wall of the container unit and the second end wall of the container unit to divide the inner space of the container unit into a first part for a first row of anodes and cathodes in alternating order and into a part for a second row of anodes and cathodes in alternating order.
- the invention is based on providing a support member and dividing the inner space of the container unit into a first part for a first row of anodes and cathodes in alternating order and into a part for a second row of anodes and cathodes in alternating order.
- the metal producing capacity is increased relative to the production, transport and installation costs of the electrolytic cell in comparison to an electrolytic cell according to the prior art.
- One reason for this is that if more anodes and cathodes producing capacity can fit into one container unit, the specific production cost of the container unit is reduced.
- the relative transportation and installation costs are lowered due to fewer transportation movements and fewer installation activities for the specified production capacity.
- the container unit has the following dimensions: The width of the container unit is between 2.5 and 2.6 m, the height of the container unit is between 1.7 and 1.8 m, and the length of the container unit is between 5.6 and 6.0 m.
- the width of the container unit is between 2.5 and 2.6 m
- the height of the container unit is between 1.7 and 1.8 m
- the length of the container unit is between 5.6 and 6.0 m.
- Figure 1 shows an electrolytic cell according to a first embodiment
- FIG. 1 shows the electrolytic cell shown in figure 1 as seen from above
- Figure 3 shows the electrolytic cell shown in figure 1 as seen from one end
- Figure 4 shows the electrolytic cell shown in figure 1 as seen from the other end
- Figure 5 shows the electrolytic cell shown in figure 1 as cut along line B - B in figure
- Figure 6 shows the electrolytic cell shown in figure 1 as cut along line A - A in figure 5
- Figure 7 shows an electrolytic cell according to a second embodiment
- Figure 8 shows the electrolytic cell shown in figure 7 as seen from above
- Figure 9 shows the electrolytic cell shown in figure 7 as seen from one end
- Figure 10 shows the electrolytic cell shown in figure 7 as seen from the other end
- Figure 11 shows the electrolytic cell shown in figure 7 as cut along line B - B in figure 8
- Figure 12 shows the electrolytic cell shown in figure 7 as cut along line A - A in figure
- Figure 13 shows an electrolytic cell according to a third embodiment
- Figure 14 shows the electrolytic cell shown in figure 13 as seen from above
- Figure 15 shows the electrolytic cell shown in figure 13 as seen from one end
- Figure 16 shows the electrolytic cell shown in figure 13 as seen from the other end
- Figure 17 shows the electrolytic cell shown in figure 13 as cut along line B - B in figure
- Figure 18 shows the electrolytic cell shown in figure 13 as cut along line A - A in figure 17, and
- Figure 19 shows an electrolytic cell according to the second embodiment shown in figures 7 to 12 where in the first part is arranged a first row of anodes and cathodes in alternating order.
- the invention relates to a method for manufacturing an electrolytic cell for corrosive electrolyte and for use in an electrolysis process such as for a process for electrowinning or electrorefining of metals and to an electrolytic cell for corrosive electrolyte and for use in an electrolysis process such as for a process for electrowinning or electrorefining of metals.
- the method comprises a first providing step for providing a container unit 1 having an inner space (not marked with a reference numeral) limited by a bottom 2, a first side wall 3 extending from a first side edge 4 of the bottom 2, a second side wall 5 extending from a second side edge 6 of the bottom 2, a first end wall 7 extending from a first end edge 8 of the bottom 2, and a second end wall 9 extending from a second end edge 10 of the bottom 2.
- the method comprises additionally a second providing step for providing a support member 11 designed and dimensioned to extend at least partly inside the inner space of the container unit 1 between the first end wall 7 of the container unit 1 and the second end wall 9 of the container unit 1.
- the method comprises additionally an arranging step for arranging the support member 11 at least partly inside the inner space of the container unit 1 between the first end wall 7 of the container unit 1 and the second end wall 9 of the container unit 1 to divide the inner space of the container unit 1 into a first part 12 for a first row of anodes and cathodes 20 in alternating order and into a second part 13 for a second row of anodes and cathodes (not shown in the figures) in alternating order.
- the method may additionally comprise a third providing step for providing an additional support member (not shown in the figures) designed and dimensioned to extend at least partly inside the inner space of the container unit 1 between the first end wall 7 of the container unit 1 and the second end wall 9 of the container unit 1 and an additional arranging step for arranging such additional support member at least partly inside the inner space of the container unit 1 between the first end wall 7 of the container unit 1 and the second end wall 9 of the container unit 1 to divide the inner space of the container unit 1 in addition to a first part 12 and in addition to a second part 13 additionally into a third part(not shown in the figures) for a third row of anodes and cathodes (not shown in the figures) in alternating order.
- a third providing step for providing an additional support member (not shown in the figures) designed and dimensioned to extend at least partly inside the inner space of the container unit 1 between the first end wall 7 of the container unit 1 and the second end wall 9 of the container unit 1
- an additional arranging step for arranging such additional support member at least
- Figures 1 to 6 show an electrolytic cell manufactured according to a first embodiment of the method.
- a support member 11 in the form of a prefabricated partition member designed and dimensioned to extend in the inner space of the container unit 1 between the first end wall 7 and the second end wall 9 of the container unit 1 and the bottom 2 of the container unit 1 is provided in the second providing step.
- the arranging step comprises arranging said prefabricated partition member in the inner space of the container unit 1, and attaching the prefabricated partition member to the end walls of the container unit 1 and to the bottom 2 of the container unit 1 to divide the inner space of the container unit 1 into a first part 12 and into a second part 13 such that the first part 12 forms a first sub-inner space for a first row of anodes and cathodes 20 in alternating order, and such that the second part 13 forms a second sub-inner space that is separated from the first sub-inner space and that is for a second row of anodes and cathodes in alternating order.
- the first sub-inner space can be separated by the prefabricated partition member from the second sub-inner space so that electrolyte is prevented from flowing between the first sub-inner space and the second sub-inner space.
- Figures 7 to 12 show an electrolytic cell manufactured according to a second embodiment of the method.
- the second providing step comprises providing a support member 11 in the form of a prefabricated partition member designed and dimensioned to extend in the inner space of the container unit 1 between the first end wall 7 and the second end wall 9 of the container unit 1 and the bottom 2 of the container unit 1 and having at least one opening 14 allowing electrolyte to freely mix between the first sub-inner space and the second sub-inner space.
- the arranging step comprises arranging said prefabricated partition member in the inner space of the container unit 1, and attaching the prefabricated partition member to the end walls of the container unit 1 and to the bottom 2 of the container unit 1 to divide the inner space of the container unit 1 into a first part 12 and into a second part 13 such that the first part 12 forms a first sub-inner space for a first row of anodes and cathodes 20 in alternating order, and such that the second part 13 forms a second sub-inner space that is separated from the first sub-inner space and that is for a second row of anodes and cathodes in alternating order.
- Said at least one opening 14 can be formed in the edge of the prefabricated partition member, as is the case in the embodiment shown in figures 7 to 12. Alternatively said at least one opening 14 can be surrounded by material of the prefabricated partition member.
- Figures 13 to 18 show an electrolytic cell manufactured according to a third embodiment of the method.
- the second providing step comprises providing a support member 11 in the form of a prefabricated beam designed and dimensioned to extend in the inner space of the container unit 1 between the first end wall 7 and the second end wall 9 of the container unit 1 and allowing electrolyte to freely mix between the first part 12 and the second part 13.
- the arranging step comprises arranging said prefabricated beam in the inner space of the container unit 1, and attaching the prefabricated beam to the first end wall 7 and to the second end wall 9 of the container unit 1 to divide the inner space of the container unit 1 into a first part 12 for a first row of anodes and cathodes 20 in alternating order and into a second part 13 for a second row of anodes and cathodes in alternating order.
- the first part 12 for a first row of anodes and cathodes 20 in alternating order and the second part 13 for a second row of anodes and cathodes in alternating order formed in the method have preferably, but not necessarily, the same dimensions and form.
- the method comprises preferably, but not necessarily, arranging the support member 11 in the arranging step so that the first row of anodes and cathodes 20 to be arranged in alternating order in the first part 12 and second row of anodes and cathodes to be arranged in alternating order in the second part 13 will be parallel as is the case in the embodiments shown in the figures.
- the method comprises preferably, but not necessarily, arranging the support member 11 in the arranging step so that the support member 11 and the first side wall 3 of the container unit 1 will form a first supporting arrangement (not marked with a reference numeral) in the first part 12 for indirect or direct support of the hanger bars or similar of the anodes and cathodes to be arranged in alternating order in the first part 12, and so that the support member 11 and the second side wall 5 of the container unit 1 will form a second supporting arrangement (not marked with a reference numeral) in the second part 13 for indirect or direct support of the hanger bars or similar of the anodes and cathodes to be arranged in alternating order in the second part 13.
- the first providing step comprises providing a container unit 1 made of polymer concrete, concrete lined with glass fibre or entirely from glass fibre or polymeric material.
- the second providing step comprises providing a prefabricated partition member made of polymer concrete, concrete lined with glass fibre or entirely from glass fibre or polymeric material.
- the method comprises preferably, but not necessarily, providing in the first providing step a container unit 1 made of polymer concrete, concrete lined with glass fibre or entirely from glass fibre or polymeric material, and providing in the second providing step a prefabricated partition member made of polymer concrete, concrete lined with glass fibre or entirely from glass fibre or polymeric material.
- the method comprises preferably, but not necessarily, providing in the first providing step a container unit 1 having the following dimensions:
- the width of the container unit 1 being between 2 and 3m, preferably between 2.5 and 2.6 m
- the height of the container unit 1 being between 1 and 2 m, preferably between 1.7 and 1.8 m
- the length of the container unit 1 being between 4 and 12 m, preferably between 5.6 and 6.0 m
- the first providing step includes providing two container units 1 having the following dimensions:
- each of said two container units 1 being between 2.5 and 2.6 m
- each of said two container units 1 being between 1.7 and 1.8 m
- each of said two container units 1 being between 5.6 and 6.0 m
- This preferred embodiment of the method includes a packing step for packing said two container units 1 in one 40 foot shipping container, preferably in a 40 foot high cube shipping container so that said two container units 1 each lie on one of their side walls (3 or 5 inside the shipping container.
- the method comprises preferably, but not necessarily, providing the electrolytic cell with a common inlet 15 for feeding electrolyte to both the first part 12 and the second part 13.
- the method comprises preferably, but not necessarily, providing in the first providing step a container unit 1 comprising a first overflow bowl 16 for the first part 12 and a second overflow bowl 17 for the second part 13.
- the first providing step comprises preferably, but not necessarily, providing a container unit 1 provided with supports 18 for walking bridges (not shown in the figures) to be placed between the electrolytic cells in the tankhouse where the electrolytic cell are used.
- the method can comprise a step for providing at least one of the support member 11, the first side wall 3 and the second side wall 5 with a busbar arrangement 19 for supplying electrical energy to the anodes and cathodes.
- the electrolytic cell comprises a container unit 1 having an inner space limited by a bottom 2, a first side wall 3 extending from a first side edge 4 of the bottom 2, a second side wall 5 extending from a second side edge 6 of the bottom 2, a first end wall 7 extending from a first end edge 8 of the bottom 2, and a second end wall 9 extending from a second end edge 10 of the bottom 2.
- the electrolytic cell comprises a support member 11 arranged at least partly in the inner space of the container unit 1 between the first end wall 7 of the container unit 1 and the second end wall 9 of the container unit 1 to divide the inner space of the container unit 1 into a first part 12 for a first row of anodes and cathodes 20 in alternating order and into a second part 13 for a second row of anodes and cathodes (not shown in the figures) in alternating order.
- the support member 11 can be in the form of a prefabricated support member 11 that is arranged at least partly in the inner space of the container unit 1 between the first end wall 7 and the second end wall 9 of the container unit 1.
- the electrolytic cell may additionally comprise an additional support member (not shown in the figures) designed and dimensioned to extend at least partly inside the inner space of the container unit 1 between the first end wall 7 of the container unit 1 and the second end wall 9 of the container unit 1 and such additional support member may be arranged at least partly inside the inner space of the container unit 1 between the first end wall 7 of the container unit 1 and the second end wall 9 of the container unit 1 to divide the inner space of the container unit 1 in addition to a first part 12 and in addition to a second part 13 additionally into a third part (not shown in the figures) for a third row of anodes and cathodes (not shown in the figures) in alternating order.
- an additional support member (not shown in the figures) designed and dimensioned to extend at least partly inside the inner space of the container unit 1 between the first end wall 7 of the container unit 1 and the second end wall 9 of the container unit 1 and such additional support member may be arranged at least partly inside the inner space of the container unit 1 between the first end wall 7 of the container unit 1
- Figures 1 to 6 show an electrolytic cell according to a first embodiment.
- the support member 11 is in the form of a prefabricated partition member designed and dimensioned to extend in the inner space of the container unit 1 between the first end wall 7 of the container unit 1 and the second end wall 9 of the container unit 1 and the bottom 2 of the container unit 1.
- Said prefabricated partition member is in this first embodiment of the electrolytic cell arranged in the inner space of the container unit 1 and is attached to the first end wall 7 of the container unit 1 and to the second end wall 9 of the container unit 1 and to the bottom 2 of the container unit 1 to divide the inner space of the container unit 1 into a first part 12 in the form of a first sub-inner space for a first row of anodes and cathodes 20 in alternating order and into a second part 13 in the form of a second sub-inner space for a second row of anodes and cathodes in alternating order.
- the first sub-inner space can be separated by the prefabricated partition member from the second sub-inner space so that electrolyte is prevented from flowing between the first sub-inner space and the second sub-inner space.
- Figures 7 to 12 show an electrolytic cell according to a second embodiment.
- the support member 11 is in the form of a prefabricated partition member designed and dimensioned to extend in the inner space of the container unit 1 between the first end wall 7 and the second end wall 9 of the container unit 1 and the bottom 2 of the container unit 1.
- the prefabricated partition member has at least one opening 14 allowing electrolyte to freely mix between the first sub-inner space and the second sub-inner space.
- Said prefabricated partition member is in this second embodiment arranged in the inner space of the container unit 1 and is attached to the first end wall 7 of the container unit 1 and to the second end wall 9 of the container unit 1 and to the bottom 2 of the container unit 1 to divide the inner space of the container unit 1 into a first part 12 in the form of a first sub-inner space for a first row of anodes and cathodes 20 in alternating order and into a second part 13 in the form of a second sub-inner space for a second row of anodes and cathodes in alternating order.
- Figures 13 to 18 show an electrolytic cell according to a third embodiment.
- the support member 11 is in the form of a prefabricated beam member designed and dimensioned to extend in the inner space of the container unit 1 between the first end wall 7 and the second end wall 9 of the container unit 1.
- Said prefabricated beam member is arranged in the inner space of the container unit 1 and is attached to the end walls of the container unit 1 to divide the inner space of the container unit 1 into a first part 12 for a first row of anodes and cathodes 20 in alternating order and into a second part 13 for a second row of anodes and cathodes in alternating order.
- the support member 11 is preferably, but not necessarily, arranged so that the first row of anodes and cathodes 20 to be arranged in alternating order in the first part 12 and second row of anodes and cathodes to be arranged in alternating order in the second part
- the support member 11 is preferably, but not necessarily, arranged so that the support member 11 and the first side wall 3 of the container unit 1 forms a first supporting arrangement in the first part 12 for indirect or direct support of the hanger bars or similar of the anodes and cathodes in the first row of anodes and cathodes 20 to be arranged in alternating order in the first part 12, and so that the support member 11 and the second side wall 5 of the container unit 1 forms a second supporting arrangement in the second part 13 for indirect or direct support of the hanger bars or similar of the anodes and cathodes in the second row of anodes and cathodes to be arranged in alternating order in the second part 13.
- the container unit 1 is preferably, but not necessarily, made of polymer concrete, concrete lined with glass fibre or entirely from glass fibre or polymeric material.
- the support member 11 is preferably, but not necessarily, made of polymer concrete, concrete lined with glass fibre or entirely from glass fibre or polymeric material.
- the container unit 1 is preferably, but not necessarily, made of polymer concrete, concrete lined with glass fibre or entirely from glass fibre or polymeric material, and the support member 11 being made of polymer concrete, concrete lined with glass fibre or entirely from glass fibre or polymeric material.
- the container unit 1 has preferably, but not necessarily, the following dimensions:
- the width of the container unit 1 being between 2 and 3m, preferably between 2.5 and 2.6 m
- the height of the container unit 1 being between 1 and 2 m, preferably between 1.7 and 1.8 m
- the length of the container unit 1 being between 4 and 12 m, preferably 5.6 and 6.0 m
- the electrolytic cell has preferably, but not necessarily, a common inlet 15 for feeding electrolyte to both the first part 12 and the second part 13.
- the container unit 1 comprises preferably, but not necessarily, a first overflow bowl 16 for the first part 12 and a second overflow bowl 17 for the second part 13.
- the container unit 1 comprises preferably, but not necessarily, supports 18 for walking bridges (not shown in the figures) to be placed between the electrolytic cells in the tankhouse where the electrolytic cell are used.
- At least one of the support member 11, the first side wall 3 and the second side wall 5 may be provided with a busbar arrangement 19 for supplying electrical energy to the anodes and cathodes.
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Electrolytic Production Of Metals (AREA)
Abstract
Description
Claims
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201380066332.3A CN104884679A (en) | 2012-12-21 | 2013-12-11 | Method for manufacturing an electrolytic cell for use in an electrolysis process and electrolytic cell |
| AU2013366337A AU2013366337B2 (en) | 2012-12-21 | 2013-12-11 | Method for manufacturing an electrolytic cell for use in an electrolysis process and electrolytic cell |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FI20126368A FI125834B (en) | 2012-12-21 | 2012-12-21 | Method for making an electrolytic cell for use in an electrolytic process and electrolytic cell |
| FI20126368 | 2012-12-21 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO2014096530A1 true WO2014096530A1 (en) | 2014-06-26 |
Family
ID=50977664
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/FI2013/051155 Ceased WO2014096530A1 (en) | 2012-12-21 | 2013-12-11 | Method for manufacturing an electrolytic cell for use in an electrolysis process and electrolytic cell |
Country Status (4)
| Country | Link |
|---|---|
| CN (1) | CN104884679A (en) |
| AU (1) | AU2013366337B2 (en) |
| FI (1) | FI125834B (en) |
| WO (1) | WO2014096530A1 (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3682809A (en) * | 1970-02-24 | 1972-08-08 | Kennecott Copper Corp | Electrolytic cell constructed for high circulation and uniform flow of electrolyte |
| US4134806A (en) * | 1973-01-29 | 1979-01-16 | Diamond Shamrock Technologies, S.A. | Metal anodes with reduced anodic surface and high current density and their use in electrowinning processes with low cathodic current density |
| EP2351874A2 (en) * | 2008-10-30 | 2011-08-03 | Novel Composites Technologies S.A. | Modular array of containers for electrowinning or electrorefining |
-
2012
- 2012-12-21 FI FI20126368A patent/FI125834B/en not_active IP Right Cessation
-
2013
- 2013-12-11 CN CN201380066332.3A patent/CN104884679A/en active Pending
- 2013-12-11 WO PCT/FI2013/051155 patent/WO2014096530A1/en not_active Ceased
- 2013-12-11 AU AU2013366337A patent/AU2013366337B2/en not_active Ceased
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3682809A (en) * | 1970-02-24 | 1972-08-08 | Kennecott Copper Corp | Electrolytic cell constructed for high circulation and uniform flow of electrolyte |
| US4134806A (en) * | 1973-01-29 | 1979-01-16 | Diamond Shamrock Technologies, S.A. | Metal anodes with reduced anodic surface and high current density and their use in electrowinning processes with low cathodic current density |
| EP2351874A2 (en) * | 2008-10-30 | 2011-08-03 | Novel Composites Technologies S.A. | Modular array of containers for electrowinning or electrorefining |
Also Published As
| Publication number | Publication date |
|---|---|
| AU2013366337A1 (en) | 2015-07-02 |
| CN104884679A (en) | 2015-09-02 |
| FI125834B (en) | 2016-03-15 |
| FI20126368L (en) | 2014-06-22 |
| AU2013366337B2 (en) | 2017-01-12 |
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