WO2014071671A1 - Nanometer polypropylene composition - Google Patents
Nanometer polypropylene composition Download PDFInfo
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- WO2014071671A1 WO2014071671A1 PCT/CN2012/087483 CN2012087483W WO2014071671A1 WO 2014071671 A1 WO2014071671 A1 WO 2014071671A1 CN 2012087483 W CN2012087483 W CN 2012087483W WO 2014071671 A1 WO2014071671 A1 WO 2014071671A1
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- polypropylene composition
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L53/02—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Definitions
- the invention belongs to the field of polypropylene technology, and in particular to an improved nano-polypropylene composition.
- Polypropylene has high crystallinity and regular structure, and thus has excellent mechanical properties. However, at room temperature and low temperature, the impact strength is poor due to the high degree of molecular structure regularity. The most outstanding property of polypropylene is its resistance to bending fatigue. Polypropylene has good heat resistance, and the product can be sterilized at a temperature above 10CTC, and it is not deformed at 150 °C under the condition of no external force. The embrittlement temperature is -35 ° C, embrittlement occurs below -35 ° C, and the cold resistance is not as good as polyethylene. Polypropylene has good chemical stability, and it is stable to various other chemicals except for concentrated sulfuric acid and concentrated nitric acid.
- polypropylene has excellent high-frequency insulation properties, and since it hardly absorbs water, the insulation properties are not affected by humidity. It has a high dielectric constant and can be used to make heated electrical insulation products as temperature rises. It also has a high breakdown voltage and is suitable for use as an electrical accessory. It has good resistance to voltage and arc resistance, but it has high static electricity and is easily aged in contact with copper.
- Polypropylene is very sensitive to ultraviolet light, and the addition of zinc oxide, dilauryl thiodipropionate, carbon black or the like can improve its aging resistance.
- Conventional general-purpose PP has many disadvantages such as low strength, large shrinkage, easy warpage, temperature resistance, chemical resistance and poor light stability.
- the traditional PP also has good transparency and low price. It is mainly used in some daily household items, especially for subsequent modified granulation. Summary of the invention
- the present invention provides an improved nano-polypropylene composition which balances mechanical properties, chemical properties, thermal properties and photostability energy, and satisfies the long-term resistance of furniture products in special occasions indoors and outdoors. UV light, no discoloration and aging resistance.
- nano-polypropylene composition composed of base material and compounding agent by mass
- the base material is PP K7726: 60 parts, PP K8303: 6 parts, PP T30S: 15 parts, SBS YH-792: 9 parts
- the improved nano-polypropylene composition provided by the invention has low temperature resistance, no aging at minus 40 ° C, no breakage; high temperature resistance, no deformation at 65 ° C; outdoor use up to three years of anti-UV three-level standard; Strength standard: Tensile strength 28/MPa, elongation at break of 435%, bending strength of 26, cantilever notched impact strength at room temperature 610J/N, -40°C 238J/N; molding shrinkage rate of 13% or less; heat distortion temperature of 1.82 map/c 115 ° C.
- the nano-polypropylene composition is composed of a base material and a compounding agent by mass, the base material is PP (polypropylene) K7726: 60 parts (Yanshan Petrochemical), PP K8303: 6 parts (Yanshan Petrochemical), PP T30S: 15 (Qilu Petrochemical), SBS YH-792: 9 parts (Yueyang Petrochemical); Formulation: Butyl rubber: 0.2 parts, Barium sulfate: 8 parts, aluminate coupling agent (Hangzhou Jessica Chemical Co., Ltd.) : 0.7 parts, light stabilizer 628 (Shanxi Institute of Chemical Industry): 0.12 parts, antioxidant 1010 (BASF): 0.1 parts, antioxidant DLTP (Foshan Yubang Chemical Co., Ltd.): 0.2 parts, stearic acid Calcium (CaSt): 0.08 parts, light stabilizer GW-480 (Beijing Additives Research Institute): 0.09 parts, according to product color requirements, you can also add
- the preparation process is as follows: The above materials are mixed in proportion, thermally dehumidified at 110 ° C for 60 minutes, and the amount of feed per minute is controlled to 7000 g by an extruder, air-cooled to room temperature, parallel pelletized, and finally sealed.
- the general-purpose polypropylene modified nano-polypropylene combines the tensile strength, elongation at break, bending strength, impact strength and heat distortion temperature of the toughened polypropylene and the reinforced polypropylene.
- the local weak parts will not be broken due to external stress and other factors.
- nano-polypropylene also has a certain heat resistance, and does not cause a decrease in strength and softening due to excessive temperature.
- the ingredients added to our blended ingredients make the product not to be exposed to dust and prolonged sunlight in outdoor and severe weather conditions, resulting in product cleaning difficulties and aging and color changes. And the improvement of nano-polypropylene burning speed is more than 5 times slower than other polypropylene, and the safety is improved.
Abstract
A nanometer polypropylene composition is formed by basic materials and compounding agents in part by mass. The basic materials comprise 60 parts of PP K7726, 6 parts of PP K8303, 15 parts of PP T30S, and 9 parts of SBS YH-792. The compounding agents comprise 0.2 part of butyl rubber, 8 parts of barium sulfate, 0.7 part of aluminic acid ester coupling agents, 0.12 part of light stabilizer GW-628, 0.1 part of antioxidant 1010, 0.2 part of antioxidant DLTP, 0.08 part of calcium stearate (CaSt), and 0.09 part of light stabilizer GW-480. The modified nanometer polypropylene composition is low-temperature-resistant, does not age at the temperature of minus 40 degrees centigrade, does not crack, is high-temperature-resistant, does not deform at the temperature of 65 degrees centigrade, and reaches the anti-ultraviolet level-3 standard when the composition is used outdoors within two years.
Description
纳米聚丙烯组合物 技术领域 Nano-polypropylene composition
本发明属于聚丙烯技术领域， 尤其涉及一种改进的纳米聚丙烯组合物。 The invention belongs to the field of polypropylene technology, and in particular to an improved nano-polypropylene composition.
背景技术 Background technique
聚丙烯的结晶度高， 结构规整， 因而具有优良的力学性能。 但在室温和低温下， 由 于本身的分子结构规整度高， 所以冲击强度较差。 聚丙烯最突出的性能就是抗弯曲疲劳 性。聚丙烯具有良好的耐热性， 制品能在 10CTC以上温度进行消毒灭菌， 在不受外力的条 件下， 150°C也不变形。 脆化温度为 -35°C， 在低于 -35°C会发生脆化， 耐寒性不如聚乙烯。 聚丙烯的化学稳定性很好， 除能被浓硫酸、 浓硝酸侵蚀外， 对其它各种化学试剂都比较 稳定； 但低分子量的脂肪烃、 芳香烃和氯化烃等能使聚丙烯软化和溶胀， 同时它的化学 稳定性随结晶度的增加还有所提高， 所以聚丙烯适合制作各种化工管道和配件， 防腐蚀 效果良好。 聚丙烯的高频绝缘性能优良， 由于它几乎不吸水， 故绝缘性能不受湿度的影 响。 它有较高的介电系数， 且随温度的上升， 可以用来制作受热的电气绝缘制品。 它的 击穿电压也很高， 适合用作电气配件等。 抗电压、 耐电弧性好， 但静电度高， 与铜接触 易老化。 聚丙烯对紫外线很敏感， 加入氧化锌、 硫代二丙酸二月桂酯、 碳黑或类似的乳 白填料等可以改善其耐老化性能。传统通用级的 PP存在很多缺点，如强度低，收縮率大， 易翘曲， 耐温差， 耐化学性和光稳定性差等诸多缺陷。 但传统的 PP也有透明性好， 价格 低廉的有点， 主要应用在一些大众的日常用品上， 特别是可进行后续的改性造粒加工。 发明内容 Polypropylene has high crystallinity and regular structure, and thus has excellent mechanical properties. However, at room temperature and low temperature, the impact strength is poor due to the high degree of molecular structure regularity. The most outstanding property of polypropylene is its resistance to bending fatigue. Polypropylene has good heat resistance, and the product can be sterilized at a temperature above 10CTC, and it is not deformed at 150 °C under the condition of no external force. The embrittlement temperature is -35 ° C, embrittlement occurs below -35 ° C, and the cold resistance is not as good as polyethylene. Polypropylene has good chemical stability, and it is stable to various other chemicals except for concentrated sulfuric acid and concentrated nitric acid. However, low molecular weight aliphatic hydrocarbons, aromatic hydrocarbons and chlorinated hydrocarbons can soften polypropylene and Swelling, and its chemical stability is also improved with the increase of crystallinity, so polypropylene is suitable for making various chemical pipes and fittings with good anti-corrosion effect. Polypropylene has excellent high-frequency insulation properties, and since it hardly absorbs water, the insulation properties are not affected by humidity. It has a high dielectric constant and can be used to make heated electrical insulation products as temperature rises. It also has a high breakdown voltage and is suitable for use as an electrical accessory. It has good resistance to voltage and arc resistance, but it has high static electricity and is easily aged in contact with copper. Polypropylene is very sensitive to ultraviolet light, and the addition of zinc oxide, dilauryl thiodipropionate, carbon black or the like can improve its aging resistance. Conventional general-purpose PP has many disadvantages such as low strength, large shrinkage, easy warpage, temperature resistance, chemical resistance and poor light stability. However, the traditional PP also has good transparency and low price. It is mainly used in some daily household items, especially for subsequent modified granulation. Summary of the invention
解决的技术问题： 本发明提供一种改进的纳米聚丙烯组合物， 该组合物平衡了机械 性能、 化学性能、 热性能和光稳定性能， 满足了家具产品在室内外特殊场合应用过程中， 长期耐紫外线光照， 不变色耐老化。 Technical Problem to be Solved: The present invention provides an improved nano-polypropylene composition which balances mechanical properties, chemical properties, thermal properties and photostability energy, and satisfies the long-term resistance of furniture products in special occasions indoors and outdoors. UV light, no discoloration and aging resistance.
技术方案：纳米聚丙烯组合物， 按质量份由基料和配剂组成， 所述基料为 PP K7726: 60份， PP K8303: 6份、 PP T30S: 15份、 SBS YH-792: 9份; 配剂为： 丁基橡胶： 0.2 份， 硫酸钡： 8份、 铝酸酯偶联剂： 0.7份， 光稳定剂 GW-628: 0.12份、 抗氧剂 1010: 0.1份、 抗氧剂 DLTP: 0.2份， 硬脂酸钙（CaSt): 0.08份， 光稳定剂 GW-480: 0.09份。 Technical solution: nano-polypropylene composition, composed of base material and compounding agent by mass, the base material is PP K7726: 60 parts, PP K8303: 6 parts, PP T30S: 15 parts, SBS YH-792: 9 parts Formulation: butyl rubber: 0.2 parts, barium sulfate: 8 parts, aluminate coupling agent: 0.7 parts, light stabilizer GW-628: 0.12 parts, antioxidant 1010: 0.1 parts, antioxidant DLTP : 0.2 parts, calcium stearate (CaSt): 0.08 parts, light stabilizer GW-480: 0.09 parts.
还包括钛白粉 R902: 1份、 红粉： 0.0045份、 黄粉： 0.0095份或炭黑： 0.0023份。 有益效果： 本发明提供的改进的纳米聚丙烯组合物， 耐低温， 零下 40°C不老化， 不 断裂； 耐高温， 零上 65°C不变形； 户外使用达到两年内抗紫外线三级标准； 强度标准：
拉伸强度 28/MPa， 断裂延伸率 435%， 弯曲强度 26， 悬臂梁缺口冲击强度常温 610J/N、 -40°C238J/N; 成型收縮率 13%以下； 热变形温度 1.82map/c须达 115°C。 Also included are titanium dioxide R902: 1 part, red powder: 0.0045 parts, yellow powder: 0.0095 parts or carbon black: 0.0023 parts. Advantageous Effects: The improved nano-polypropylene composition provided by the invention has low temperature resistance, no aging at minus 40 ° C, no breakage; high temperature resistance, no deformation at 65 ° C; outdoor use up to three years of anti-UV three-level standard; Strength standard: Tensile strength 28/MPa, elongation at break of 435%, bending strength of 26, cantilever notched impact strength at room temperature 610J/N, -40°C 238J/N; molding shrinkage rate of 13% or less; heat distortion temperature of 1.82 map/c 115 ° C.
具体实施方式 detailed description
实施例 1 Example 1
纳米聚丙烯组合物， 按质量份由基料和配剂组成， 所述基料为 PP (聚丙烯） K7726: 60 份（燕山石化）， PP K8303: 6份（燕山石化）、 PP T30S: 15份（齐鲁石化）、 SBS YH-792: 9份 （岳阳石化）； 配剂为： 丁基橡胶： 0.2份， 硫酸钡： 8份、 铝酸酯偶联剂 （杭州杰西 卡化工有限公司）： 0.7份，光稳定剂 628 (山西省化工研究所）： 0.12份、抗氧剂 1010 (巴 斯夫）： 0.1份、 抗氧剂 DLTP (佛山市骐邦化工有限公司）： 0.2份， 硬脂酸钙 （CaSt): 0.08份， 光稳定剂 GW-480 (北京加成助剂研究所）： 0.09份， 根据产品颜色要求， 还可 以加入钛白粉 R902: 1份、 红粉： 0.0045份、 黄粉： 0.0095份或炭黑： 0.0023份。 The nano-polypropylene composition is composed of a base material and a compounding agent by mass, the base material is PP (polypropylene) K7726: 60 parts (Yanshan Petrochemical), PP K8303: 6 parts (Yanshan Petrochemical), PP T30S: 15 (Qilu Petrochemical), SBS YH-792: 9 parts (Yueyang Petrochemical); Formulation: Butyl rubber: 0.2 parts, Barium sulfate: 8 parts, aluminate coupling agent (Hangzhou Jessica Chemical Co., Ltd.) : 0.7 parts, light stabilizer 628 (Shanxi Institute of Chemical Industry): 0.12 parts, antioxidant 1010 (BASF): 0.1 parts, antioxidant DLTP (Foshan Yubang Chemical Co., Ltd.): 0.2 parts, stearic acid Calcium (CaSt): 0.08 parts, light stabilizer GW-480 (Beijing Additives Research Institute): 0.09 parts, according to product color requirements, you can also add titanium dioxide R902: 1 part, red powder: 0.0045 parts, yellow powder: 0.0095 Parts or carbon black: 0.0023 parts.
制备工艺为： 将上述物料按比例混合， 在 110°C下热循环除湿 60分钟， 通过挤塑机， 每分钟进料量控制在 7000g， 风冷至室温后， 平行切粒， 最后密封包装。 The preparation process is as follows: The above materials are mixed in proportion, thermally dehumidified at 110 ° C for 60 minutes, and the amount of feed per minute is controlled to 7000 g by an extruder, air-cooled to room temperature, parallel pelletized, and finally sealed.
表 1产品性能检测 Table 1 Product performance testing
Claims
1. 纳米聚丙烯组合物， 其特征在于按质量份由基料和配剂组成， 所述基料为 PP K7726: 60份， PP K8303: 6份、 PP T30S: 15份、 SBS YH-792: 9份; 配剂为： 丁基橡胶： 0.2 份， 硫酸钡： 8份、 铝酸酯偶联剂： 0.7份， 光稳定剂 GW-628: 0.12份、 抗氧剂 1010: 0.1 份、 抗氧剂 DLTP: 0.2 份， 硬脂酸钙 （CaSt): 0.08 份， 光稳定剂 GW-480: 0.09 份。 A nano-polypropylene composition characterized by comprising a base material and a compounding agent in a mass fraction of PP K7726: 60 parts, PP K8303: 6 parts, PP T30S: 15 parts, SBS YH-792: 9 parts; Formulation: Butyl rubber: 0.2 parts, Barium sulfate: 8 parts, Aluminate coupling agent: 0.7 parts, Light stabilizer GW-628: 0.12 parts, Antioxidant 1010: 0.1 parts, Antioxidant Agent DLTP: 0.2 parts, calcium stearate (CaSt): 0.08 parts, light stabilizer GW-480: 0.09 parts.
2. 根据权利要求 1所述的纳米聚丙烯组合物， 其特征在于还包括钛白粉 R902: 1份、 红 粉： 0.0045份、 黄粉： 0.0095份或炭黑: 0.0023份。
The nano-polypropylene composition according to claim 1, which further comprises titanium dioxide R902: 1 part, red powder: 0.0045 part, yellow powder: 0.0095 part or carbon black: 0.0023 part.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210440429.3 | 2012-11-07 | ||
| CN2012104404293A CN102924812A (en) | 2012-11-07 | 2012-11-07 | Nanometer polypropylene composition |
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| WO2014071671A1 true WO2014071671A1 (en) | 2014-05-15 |
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| CN107337855B (en) * | 2017-07-26 | 2018-11-23 | 武汉金发科技有限公司 | A kind of weather-proof color polypropylene composite material and preparation method |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1966559A (en) * | 2005-11-15 | 2007-05-23 | 哈尔滨鑫达高分子材料股份有限公司 | High glaze low shrinkage nano polypropylene modified compound and its preparation method |
| CN102206383A (en) * | 2011-06-30 | 2011-10-05 | 广州市聚赛龙工程塑料有限公司 | Polypropylene composite for automobile bumpers, and preparation method thereof |
| CN102643483A (en) * | 2012-05-20 | 2012-08-22 | 柳州市海达新型材料科技有限公司 | Polypropylene material for automobile carpet hold-down strips and preparation method thereof |
| CN102649854A (en) * | 2011-02-23 | 2012-08-29 | 中国科学院化学研究所 | Polypropylene composition and preparation method thereof |
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- 2012-11-07 CN CN2012104404293A patent/CN102924812A/en active Pending
- 2012-12-26 WO PCT/CN2012/087483 patent/WO2014071671A1/en active Application Filing
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1966559A (en) * | 2005-11-15 | 2007-05-23 | 哈尔滨鑫达高分子材料股份有限公司 | High glaze low shrinkage nano polypropylene modified compound and its preparation method |
| CN102649854A (en) * | 2011-02-23 | 2012-08-29 | 中国科学院化学研究所 | Polypropylene composition and preparation method thereof |
| CN102206383A (en) * | 2011-06-30 | 2011-10-05 | 广州市聚赛龙工程塑料有限公司 | Polypropylene composite for automobile bumpers, and preparation method thereof |
| CN102643483A (en) * | 2012-05-20 | 2012-08-22 | 柳州市海达新型材料科技有限公司 | Polypropylene material for automobile carpet hold-down strips and preparation method thereof |
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