WO2014067495A1 - Encapsulation mold - Google Patents
Encapsulation mold Download PDFInfo
- Publication number
- WO2014067495A1 WO2014067495A1 PCT/CN2013/086561 CN2013086561W WO2014067495A1 WO 2014067495 A1 WO2014067495 A1 WO 2014067495A1 CN 2013086561 W CN2013086561 W CN 2013086561W WO 2014067495 A1 WO2014067495 A1 WO 2014067495A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- rubber anti
- slip block
- rubber
- glass
- slip
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C33/00—Moulds or cores; Details thereof or accessories therefor
- B29C33/20—Opening, closing or clamping
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
- B29C45/14—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor incorporating preformed parts or layers, e.g. injection moulding around inserts or for coating articles
- B29C45/14336—Coating a portion of the article, e.g. the edge of the article
- B29C45/14377—Coating a portion of the article, e.g. the edge of the article using an additional insert, e.g. a fastening element
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
- B29C45/14—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor incorporating preformed parts or layers, e.g. injection moulding around inserts or for coating articles
- B29C45/14336—Coating a portion of the article, e.g. the edge of the article
- B29C45/14434—Coating brittle material, e.g. glass
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
- B29C45/14—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor incorporating preformed parts or layers, e.g. injection moulding around inserts or for coating articles
- B29C45/14778—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor incorporating preformed parts or layers, e.g. injection moulding around inserts or for coating articles the article consisting of a material with particular properties, e.g. porous, brittle
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
- B29L2031/00—Other particular articles
- B29L2031/30—Vehicles, e.g. ships or aircraft, or body parts thereof
- B29L2031/3052—Windscreens
Definitions
- the present disclosure generally relates to an encapsulation mold for encapsulating glass.
- Encapsulated glass is one kind of safety glass, which is widely used in automobiles as front windshield glass, rear windshield glass, skylight glass or quarter window glass.
- Encapsulated glass may have the following advantages: 1, encapsulated glass can be bonded to a car body tightly, which guarantees sealing of the car; 2, glass is combined with encapsulating plastics in one piece, which makes it easy to install, thereby shortening the installation cycle and improving the production efficiency; meanwhile, encapsulated glass may have different types of cross section, which can be designed to make a car more aesthetic.
- Encapsulated glass may be fabricated as follows. First, a piece of normal annealed glass is pre-processed such as by cutting, edging and cleaning. Second, the pre-processed annealed glass is transferred to a production line for toughening treatment, so as to obtain a piece of toughened glass. Then, an encapsulation mold, including an upper mold and a lower mold, is provided. The toughened glass is placed as an insert on a chuck of the lower mold, and is fixed with a positioning device of the lower mold. Then the upper mold and the lower mold are jointed together. Through a sprue gate, molten plastics are injected towards edges of the toughened glass. An encapsulated glass is obtained after the molten plastics are solidified and encapsulate the edges of the toughened glass.
- FIG. 1 schematically illustrates a piece of glass fixed by a movable lifter.
- a glass 1 which is to be encapsulated has a convex surface 11 (namely, an upper surface of the glass 1) and a concave surface 12 (namely, a lower surface of the glass 1), which are disposed opposite to each other.
- a movable lifter 2 is disposed on a lower mold (not shown).
- the glass 1 may be fixed in an encapsulation mold (not shown) according to the following steps.
- the glass 1 is firstly placed on the movable lifter 2, which brings the concave surface 12 into contact with the movable lifter 2. After that, the glass 1 is positioned preliminarily.
- an upper mold (not shown) is pressed against the lower mold.
- the movable lifter 2 applies a first upward force to the concave surface 12, while the upper mold applies a second downward force to the convex surface 11.
- the glass 1 is clamped between the movable lifter 2 and the upper mold, which may prevent the glass 1 from moving during injection molding.
- the position of the movable lifter 2 can be adjusted up and down.
- the movable lifter 2 is made of iron and is hard.
- the movable lifter 2 has a convex surface corresponding to the concave surface 12 of the glass 1. Most part of the concave surface 12 of the glass 1 is propped by the convex surface of the movable lifter 2, when they are brought into contact.
- a chamber of the encapsulation mold needs to be kept in a pressure maintaining state, so as to make the plastic material encapsulate edges of the glass 1 tightly. Under the actions of the pressure, the glass 1 and the movable lifter 2 squeeze each other. Because both the glass 1 and the movable filter 2 are rigid, the glass 1 may get crushed.
- glasses from different batches may have different curvature tolerances. If the glass 1 has a large curvature tolerance, the concave surface 12 of the glass 1 may not match the convex surface of the movable lifter 2 well. In this case, most of pressure may concentrate on a certain point of the glass 1, which thereby may cause the glass 1 to be crushed by the movable lifter 2. Especially, when the glass 1 has a big size, a central region of the glass 1 may have a very large curvature tolerance, which may result in high breakage rate of the glass.
- Embodiments of the present disclosure provide an encapsulation mold for manufacturing encapsulated glass, in order to solve problems, such as that, encapsulated glass is easily to be crushed.
- an encapsulation mold which may include:
- a clamping device which may include a first rubber anti-slip block fixed to a joint surface of the upper mold, and a second rubber anti-slip block fixed to a joint surface of the lower mold, wherein the first rubber anti-slip block has a first surface and the second rubber anti-slip block has a second surface, and when the upper mold is pressed against the lower mold, the first rubber anti-slip block and the second rubber anti-slip block overlap at least in part, and a minimum distance between the first rubber anti-slip block and the second rubber anti-slip block is less than a thickness of a glass to be encapsulated.
- the encapsulation mold has equal numbers of the first and second rubber anti-slip blocks.
- the minimum distance between the first rubber anti-slip block and the second rubber anti-slip block may equal to a distance between the first surface of the first rubber anti-slip block and the second surface of the second rubber anti-slip block, and when the upper mold is pressed against the lower mold, the distance between the first surface of the first rubber anti-slip block and the second surface of the second rubber anti-slip block is about 0.15mm to about 0.25mm less than the thickness of the glass to be encapsulated.
- the first surface of the first rubber anti-slip block is concave, and the second surface of the second rubber anti-slip block is convex; or, the first surface of the first rubber anti-slip block is convex, and the second surface of the second rubber anti-slip block is concave; wherein a concave one of the first and second surfaces is configured to match a convex surface of the glass to be encapsulated, and a convex one of the first and second surfaces is configured to match a concave surface of the glass to be encapsulated.
- the clamping device is provided with three or more first rubber anti-slip blocks and three or more second rubber anti-slip blocks, and the three or more first rubber an ti- slip blocks and the three or more second rubber anti-slip blocks are respectively arranged in a polygon pattern.
- the clamping device may further include a third rubber anti-slip block fixed to the joint surface of the upper mold, and a fourth rubber anti-slip block fixed to the joint surface of the lower mold, and a width of the third rubber anti-slip block and a width of the fourth rubber anti-slip block are less than that of the first rubber anti-slip block and that of the second rubber anti-slip block, respectively;
- the third rubber anti-slip block has a third surface which is adapted for clamping the glass to be encapsulated, and the fourth rubber anti-slip block has a fourth surface which is adapted for clamping the glass to be encapsulated;
- the third rubber anti-slip block has a third groove formed therein and the third groove faces outward from the third surface;
- the fourth rubber anti-slip block has a fourth groove formed therein and the fourth groove faces outward from the fourth surface;
- the distance between the third surface of the third rubber anti-slip block and the fourth surface of the fourth rubber anti-slip block is about 0.15mm to about 0.25mm less than the thickness of the glass to be encapsulated.
- the clamping device is provided with three or more third rubber anti-slip blocks and three or more fourth rubber anti-slip block, and the three or more third rubber anti-slip blocks and the three or more fourth rubber anti-slip blocks are distributed along a circumference of a polygon, respectively.
- the third groove and the fourth groove respectively have a substantially V-shaped, square or W-shaped cross section.
- the first rubber anti-slip block is provided with a rubber bump located on and extending from the first surface
- the second rubber anti-slip block is provided with a rubber bump located on and extending from the second surface
- the minimum distance between the first rubber anti-slip block and the second rubber anti-slip block equals to a distance between the surface of the rubber bump of the first rubber anti-slip block and the surface of the rubber bump of the second rubber anti-slip block.
- the first rubber anti-slip block and the second rubber anti-slip block overlap completely, the rubber bump of the first rubber anti-slip block and the rubber bump of the second rubber anti-slip block overlap at least in part, and the distance between the first surface of the first rubber anti-slip block and the second surface of the second rubber anti-slip block equals to the thickness of the glass to be encapsulated.
- the first rubber anti-slip block has a first groove formed on the first surface
- the second rubber anti-slip block has a second groove formed on the second surface
- the rubber bump of the first rubber anti-slip block is embedded in the first groove and extends higher than the first surface
- the rubber bump of the second anti-slip block is embedded in the second groove and extends higher than the second surface
- the rubber bump embedded in the first groove extends about 0.45mm to about 0.55mm higher than the first surface
- the rubber bump embedded in the second groove extends about 0.45mm to about 0.55mm higher than the second surface
- the encapsulation mold provided in embodiments of the present disclosure includes an upper mold, a lower mold and a clamping device, where the clamping device includes a first rubber anti-slip block fixed to a joint surface of the upper mold, and a second rubber anti-slip block fixed to a joint surface of the lower mold, and both of the first rubber anti-slip block and the second rubber anti-slip block have surfaces for clamping a glass to be encapsulated. Therefore, after the upper mold and the lower mold are pressed against each other, both of the first rubber anti-slip block and the second rubber anti-slip block deform and apply a pair of forces having opposite directions to the glass.
- the glass can be completely fixed in the encapsulation mold, thereby preventing the glass from breakage which is caused by glass moving during injection molding.
- the first and second rubber anti-slip blocks are elastic, they can play a role of buffer, which may prevent the glass from breakage.
- the rubber anti-slip blocks can compensate for the curvature tolerance of the glass to be encapsulated, which enables the encapsulation mold to be suitable for glasses from different batches.
- the clamping device includes a first rubber anti-slip block and a third rubber anti-slip block fixed to a joint surface of the upper mold, and a second rubber anti-slip block and a fourth rubber anti-slip block fixed to a joint surface of the lower mold, wherein grooves are formed in the third rubber anti-slip block and the fourth rubber anti-slip block, the third rubber anti-slip block is more close to an edge of the upper mold than the first rubber anti-slip block, and the fourth rubber anti-slip block is more close to an edge of the lower mold than the second rubber anti-slip block.
- the first rubber anti-slip block and the second rubber anti-slip block may fix a central region of the glass
- the third rubber anti-slip block and the fourth rubber anti-slip block may fix a peripheral region of the glass.
- the first rubber anti-slip block and the second rubber anti-slip block may be provided with a rubber bump respectively, where the rubber bumps extend from the surfaces of the first rubber anti-slip block and the second rubber anti-slip block.
- the glass can be clamped between the rubber bump of the first rubber anti-slip block and the rubber bump of the second rubber anti-slip block. Because the contact area between the rubber bumps with the glass is small, the forces applied by the rubber bumps to the glass are relatively low, which reduces the breakage rate of the glass. As a result, the glass is not easily to be crushed even if the glass of a big size has a great curvature tolerance.
- FIG. 1 schematically illustrates a glass fixed by a movable lifter
- FIG. 2 schematically illustrates a cross- sectional view of an encapsulation mold according to one embodiment of the present disclosure
- FIG. 3 schematically illustrates a layout view of a first rubber anti-slip block and a third rubber anti-slip block disposed on an upper mold, according to one embodiment of the present disclosure
- FIG. 4 schematically illustrates a layout view of a second rubber anti-slip block and a fourth rubber anti-slip block disposed on a lower mold, according to one embodiment of the present disclosure
- FIG. 5 schematically illustrates a partial enlarged view of a glass fixed between the first rubber anti-slip block and the second rubber anti-slip block, according to one embodiment of the present disclosure
- FIG. 6 schematically illustrates a structural diagram of the first rubber anti-slip block or the second rubber anti-slip block, according to one embodiment of the present disclosure
- FIG. 7 schematically illustrates a partial enlarged view of a glass fixed between the third rubber anti-slip block and the fourth rubber anti-slip block, according to one embodiment of the present disclosure
- FIG. 8 schematically illustrates a structural diagram of the third rubber anti-slip block or the fourth rubber anti-slip block , according to one embodiment of the present disclosure
- FIG. 9 schematically illustrates a cross- sectional view of an encapsulation mold, according to another embodiment of the present disclosure
- FIG. 10 schematically illustrates a layout view of a first rubber anti-slip block and a third rubber anti-slip block disposed on an upper mold, according to another embodiment of the present disclosure
- FIG. 11 schematically illustrates a layout view of a second rubber anti-slip block and a fourth rubber anti-slip block disposed on a lower mold, according to another embodiment of the present disclosure
- FIG. 12 schematically illustrates a partial enlarged view of a glass fixed between a rubber bump of the first rubber anti-slip block and a rubber bump of the second rubber anti-slip block, according to one embodiment of the present disclosure
- FIG. 13 schematically illustrates a structural diagram of the first rubber anti-slip block or the second rubber anti-slip block having a rubber bump embedded therein, according to one embodiment of the present disclosure ;
- FIG. 14 schematically illustrates a partial enlarged view of a glass fixed between the third rubber anti-slip block and the fourth rubber anti-slip block, according to another embodiment of the present disclosure.
- FIG. 15 schematically illustrates a structural diagram of the third rubber anti-slip block or the fourth rubber anti-slip block, according to another embodiment of the present disclosure.
- an encapsulation mold 100 may include an upper mold 10, a lower mold 20 and a clamping device.
- the clamping device may include a first rubber an ti- slip block 31 which is fixed to a joint surface of the upper mold 10 and has a first surface 311 for clamping a glass 40 to be encapsulated, and a second rubber anti-slip block 32 which is fixed to a joint surface of the lower mold 20 and has a second surface 321 for clamping the glass 40.
- the clamping device has equal numbers of the first rubber an ti- slip blocks 31 and the second rubber anti-slip blocks 32.
- the first rubber anti-slip block 31 and the second rubber anti-slip block 32 may overlap at least in part. And a distance between the first surface 311 of the first rubber anti-slip block 31 and the second surface 321 of the second rubber anti-slip block 32 is less than a thickness of the glass 40 (namely, a design thickness of the glass 40). If an encapsulation width of an upper surface of the glass 40 equals to that of a lower surface of the glass 40, the first rubber anti-slip block 31 and the second rubber anti-slip block 32 overlap completely. If the encapsulation width of the upper surface of the glass 40 does not equal to that of the lower surface of the glass 40, the first rubber anti-slip block 31 and the second rubber anti-slip block 32 overlap in part.
- the glass 40 may be fixed within the encapsulation mold 100 in the following way. First, the glass 40 is placed on the lower mold 20, so that a concave surface or a convex surface of the glass 40 (namely, the lower surface of the glass 40) is propped by the second surface 321 of the second rubber anti-slip block 32. After that, the glass 40 is positioned preliminarily. Then the upper mold 10 is pressed against the lower mold 20, so that the first surface 311 of the first rubber anti-slip block 31 engages a convex surface or a concave surface of the glass 40 (namely, the upper surface of the glass 40).
- the first rubber anti-slip block 31 and the second rubber anti-slip block 32 deform.
- the first rubber anti-slip block 31 applies a first downward force to the glass 40
- the second rubber anti-slip block 32 applies a second upward force to the glass 40.
- the glass 40 is completely fixed within the encapsulation mold 100, which prevents the glass 40 from moving during injection molding, thereby reducing the breakage rate of the glass.
- the glass 40 may be squeezed with the first rubber anti-slip block 31 and the second rubber anti-slip block 32. Because both the first rubber anti-slip block 31 and the second rubber anti-slip block 32 are elastic, they have a function of buffering, which may prevent the glass 40 from breakage.
- the first rubber anti-slip block 31 and the second rubber anti-slip block 32 can still contact with the glass in large area, owing to deformation of the first rubber anti-slip block 31 and the second rubber anti-slip block 32.
- the forces applied to the glass 40 by the first rubber anti-slip block 31 and the second rubber anti-slip block 32 may distribute on the glass 40 relatively uniformly, which may prevent the glass 40 from breaking.
- the first rubber anti-slip block 31 and the second rubber anti-slip block 32 may compensate for the curvature tolerance of the glass 40.
- screws may be used to mount the first rubber anti-slip block 31 on the upper mold 10 and to mount the second rubber anti-slip block 32 on the lower mold 20.
- a plurality of counter bores 36 are formed on the first surface 311 of the first rubber anti-slip block 31 and a plurality of counter bores 36 are formed on the second surface 321 of the second rubber anti-slip block 32.
- the screws extending through the counter bores 36 fix the first rubber anti-slip block 31 to the upper mold 10, and fix the second rubber anti-slip block 32 to the lower mold 20.
- other components which can be easily disassembled may be used to fix the first rubber anti-slip block 31 to the upper mold 10, and fix the second rubber anti-slip block 32 to the lower mold 20.
- first rubber anti-slip block 31 and the second rubber anti-slip block 32 are worn down after the clamping device has been used for a time period, they can be easily disassembled and be replaced with new ones, thereby extending the service life of the encapsulation mold 100.
- the encapsulation mold 100 has at least one first rubber anti-slip block 31 and at least one second rubber anti-slip block 32. In order to completely fix the glass 40 within the encapsulation mold 100, there may be as many the first rubber anti-slip blocks 31 and the second rubber anti-slip blocks 32 as possible in the encapsulation mold 100. The number of the first rubber anti-slip blocks 31 and the second rubber anti-slip blocks 32 may be set according to the size of the glass 40. In some embodiments, the encapsulation mold 100 has at least three first rubber anti-slip blocks 31 and at least three second rubber anti-slip blocks 32 (as an example, there are three first rubber anti-slip blocks and three second rubber anti-slip blocks schematically shown in FIG.
- the at least three first rubber anti-slip blocks 31 are fixed to the upper mold 10 at different positions and arranged in a polygon pattern, and the at least three second rubber anti-slip blocks 32 are fixed to the lower mold 20 at different positions and arranged in a polygon pattern.
- the three first rubber anti-slip blocks 31 are arranged in a triangle pattern.
- the three second rubber anti-slip blocks 32 are arranged in a triangle pattern.
- the widths of the first rubber anti-slip blocks 31 and the second rubber anti-slip blocks 32 may be set according to the size of the glass 40. In order to completely fix the glass 40 within the encapsulation mold 100, the widths of the first rubber anti-slip blocks 31 and the second rubber anti-slip blocks 32 may be set as great as possible. It should be noted that the widths of the first rubber anti-slip blocks 31 and the second rubber anti-slip blocks 32 may not be too great, to avoid breakage of the glass 40 due to a large force.
- the first rubber anti-slip blocks 31 and the second rubber anti-slip blocks 32 may be made of various rubber materials. Taking into account the characteristics of injection molding in which the first rubber anti-slip blocks 31 and the second rubber anti-slip blocks 32 are applied, the first rubber anti-slip blocks 31 and the second rubber anti-slip blocks 32 may be made of Ethylene-Propylene-Diene Monomer (EPDM).
- EPDM Ethylene-Propylene-Diene Monomer
- the first surface 311 of the first rubber anti-slip block 31 may be set to be concave and the second surface 321 of the second rubber anti-slip block 32 may be set to be convex.
- the first surface 311 of the first rubber anti-slip block 31 may be set to be convex and the second surface 321 of the second rubber anti-slip block 32 may be set to be concave.
- the concave surface of the rubber anti-slip blocks matches the convex surface of the glass 40, and the convex surface of the rubber anti-slip blocks matches the concave surface of the glass 40.
- the distance between the first surface 311 of the first rubber anti-slip block 31 and the second surface 321 of the second rubber anti-slip block 32 needs to be suitable. In some embodiments, the distance between the first surface 311 of the first rubber anti-slip block 31 and the second surface 321 of the second rubber anti-slip block 32 is about 0.15mm to about 0.25mm less than the thickness of the glass 40.
- the clamping device may further include a third rubber anti-slip block 33 which is fixed to a joint surface of the upper mold 10 and has a third surface 331 for clamping the glass 40, and a fourth rubber anti-slip block 34 which is fixed to a joint surface of the lower mold 20 and has a fourth surface 341 for clamping the glass 40.
- the clamping device may have equal numbers of the third rubber anti-slip blocks 33 and the fourth rubber anti-slip blocks 34.
- the third rubber anti-slip block 33 and the fourth rubber anti-slip block 34 may overlap at least in part. And a distance between the third surface 331 of the third rubber anti-slip block 33 and the fourth surface 341 of the fourth rubber anti-slip block 34 is less than a thickness of the glass 40. In some embodiments, the distance between the third surface 331 of the third rubber anti-slip block 33 and the fourth surface 341 of the fourth rubber anti-slip block 34 is about 0.15mm to about 0.25mm less than the thickness of the glass 40.
- the third rubber anti-slip block 33 and the fourth rubber anti-slip block 34 overlap completely. If an encapsulation width of an upper surface of the glass 40 does not equal to that of a lower surface of the glass 40, the third rubber anti-slip block 33 and the fourth rubber anti-slip block 34 overlap in part.
- a third groove 3c is formed in a third rubber anti-slip block 33on the third surface 331, and a fourth groove 3d is formed in a fourth rubber anti-slip block 34on the fourth surface 341.
- the third groove 3c and the fourth groove 3d may respectively have a substantially V-shaped, square or W-shaped cross section (the cross section is perpendicular to the third surface 331 and the fourth surface 341), or other shapes.
- the widths of the third rubber anti-slip block 33 and the fourth rubber anti-slip block 34 are respectively less than those of the first rubber anti-slip block 31 and the second rubber anti-slip block 32, so that the contact area between the third rubber anti-slip block 33/ the fourth rubber anti-slip block 34 and the glass 40 can be reduced, thereby preventing the glass 40 from breaking.
- a processing groove (not shown) may be formed in the upper mold 10, and a processing groove (not shown) may be formed in the lower mold 20. Widths of the processing grooves are less than those of the third rubber anti-slip block 33 and the fourth rubber anti-slip block 34. Thus, while placing the third rubber anti-slip block 33 in the processing groove of the upper mold 10, and placing the fourth rubber anti-slip block 34 in the processing groove of the lower mold 20, the third rubber anti-slip block 33 and the fourth rubber anti-slip block 34 deform because of squeezing.
- the third rubber anti-slip block 33 embedded in the processing groove is fixed to the upper mold 10 tightly
- the fourth rubber anti-slip block 34 embedded in the processing groove is fixed to the lower mold 20 tightly.
- the third rubber anti-slip block 33 and the fourth rubber anti-slip block 34 may be fixed to the upper mold 10 and the lower mold 20 in other ways of easy disassembling. In this way, in the event that the third rubber anti-slip block 33 and the fourth rubber anti-slip block 34 are worn down after the clamping device has been used for a time period, they can be easily disassembled and be replaced with new ones, thereby extending the service life of the encapsulation mold 100.
- the encapsulation mold 100 has at least one third rubber anti-slip blocks 33 and at least one fourth rubber anti-slip blocks 34. In order to completely fix the glass 40 within the encapsulation mold 100, there may be as many the third rubber anti-slip blocks 33 and the fourth rubber anti-slip blocks 34 as possible in the encapsulation mold 100. In some embodiments, the encapsulation mold 100 has at least three third rubber anti-slip blocks 33 and at least three fourth rubber anti-slip blocks 34 (as an example, there are three third anti-slip blocks and three fourth rubber anti-slip blocks schematically shown in FIG. 3 and FIG. 4, respectively).
- the at least three third rubber anti-slip blocks 33 are fixed to the upper mold 10 at different positions and arranged in a polygon pattern, and the at least three fourth rubber anti-slip blocks 34 are fixed to the lower mold 20 at different positions and arranged in a polygon pattern.
- the three third rubber anti-slip blocks 33 are arranged in a quadrilateral pattern.
- the three fourth rubber anti-slip blocks 34 are arranged in a quadrilateral pattern.
- the third rubber anti-slip block 33 and the fourth rubber anti-slip block 34 may be made of various rubber materials. Taking into account the characteristics of injection molding in which the third rubber anti-slip block 33 and the fourth rubber anti-slip block 34 are applied, the third rubber anti-slip block 33 and the fourth rubber anti-slip block 34 may be made of Ethylene-Propylene-Diene Monomer (EPDM).
- EPDM Ethylene-Propylene-Diene Monomer
- the third rubber anti-slip blocks 33 are located closer to an edge of the upper mold 10 compared with the first rubber anti-slip blocks 31, and the fourth rubber anti-slip blocks 34 are located closer to an edge of the lower mold 20 compared with the second rubber anti-slip blocks 32.
- first rubber anti-slip blocks 31 and the second rubber anti-slip blocks 32 may fix a central region of the glass 40
- the third rubber anti-slip blocks 33 and the fourth rubber anti-slip blocks 34 may fix a peripheral region of the glass 40.
- the glass 40 may be fixed within the encapsulation mold 100 having this clamping device in the following way. First, the glass 40 is placed on the lower mold 20, so that a concave surface or a convex surface of the glass 40 (namely, the lower surface of the glass 40) is propped by the second surface 321 of the second rubber anti-slip block 32 and the fourth surface 341 of the fourth rubber anti-slip block 34. After that, the glass 40 is positioned preliminarily.
- the upper mold 10 is pressed against the lower mold 20, so that the first surface 311 of the first rubber anti-slip block 31 and the third surface 331 of the third rubber anti-slip block 33 engages a convex surface or a concave surface of the glass 40 (namely, the upper surface of the glass 40).
- the first rubber anti-slip block 31 deforms and applies a first downward force to the glass 40
- the second rubber anti-slip block 32 deforms and applies a second upward force to the glass 40
- the third rubber anti-slip block 33 deforms and applies a third downward force to the glass 40
- the fourth rubber anti-slip block 34 deforms and applies a fourth upward force to the glass 40.
- the glass 40 Under the combined actions of the first downward force, the second upward force, the third downward force and the fourth upward force, the glass 40 can be completely fixed within the encapsulation mold 100, which prevents the glass 40 from moving during injection molding, thereby reducing the breakage rate of the glass.
- the first rubber anti-slip block 31 and the second rubber anti-slip block 32 may be set to have a relatively large size. In other words, the contact area between the first rubber anti-slip block 31 /the second rubber anti-slip block 32 and the glass 40 is large. However, if there are large variations in the curvature tolerance of the glass 40, the glass 40 is easy to be crushed. [0061] Referring to FIG. 9 to FIG.
- an encapsulation mold 100' may include an upper mold 10', a lower mold 20' and a clamping device.
- the clamping device may include a first rubber anti-slip block 31 ' which is fixed to a joint surface of the upper mold 10' and has a first surface 31 , and a second rubber anti-slip block 32' which is fixed to a joint surface of the lower mold 20' and has a second surface 321 ' .
- a rubber bump 351 is provided on the first surface 311 ' of the first rubber anti-slip block 31 ', which extends higher than the first surface 311 ', and a rubber bump 352 is provided on the second surface 321 ' of the second rubber anti-slip block 32', which extends higher than the second surface 321 '.
- the clamping device may have equal numbers of the first rubber anti-slip blocks 31 ' and the second rubber anti-slip blocks 32'.
- the rubber bump 351 may be integrated with the first rubber anti-slip block 31 ', and the rubber bump 352 may be integrated with the second rubber anti-slip block 32' .
- the first rubber anti-slip block 31 ' has a first groove 3a formed on the first surface 311 ' which has a width less than that of the first rubber anti-slip block 31 '.
- the rubber bump 351 is embedded in the first groove 3a, which extends higher than the first surface 311 ' .
- the second rubber anti-slip block 32' has a second groove 3b formed on the second surface 321 ', which has a width less than that of the second rubber anti-slip block 32'.
- the rubber bump 352 is embedded in the second groove 3b, which extends higher than the second surface 321 ' .
- a processing groove (not shown) may be formed in the first rubber anti-slip block 31 ', and a processing groove (not shown) may be formed in the second rubber anti-slip block 32'. Widths of the processing grooves are less than those of the rubber bump 351 and the rubber bump 352.
- the rubber bumps 351 and 352 deform because of squeezing.
- the rubber bump 351 embedded in the processing groove is fixed to the first rubber anti-slip block 31 ' tightly
- the rubber bump 352 embedded in the processing groove is fixed to the second rubber anti-slip block 32' tightly.
- the first rubber anti-slip block 31 ' and the second rubber anti-slip block 32' overlap completely, and the rubber bump 351 and the rubber bump 352 overlap at least in part.
- a distance between the rubber bump 351 of the first rubber anti-slip block 31 ' and the rubber bump 352 of the second rubber anti-slip block 32' is less than the thickness of the glass 40.
- a distance between the first surface 311 ' of the first rubber anti-slip block 31 ' and the second surface 321 ' of the second rubber anti-slip block 32' equals to the thickness of the glass 40.
- the glass 40 While most portion of the glass 40 is clamped between the rubber bump 351 of the first rubber anti-slip block 31 ' and the rubber bump 352 of the second rubber anti-slip block 32', some portion of the glass may probably also be clamped between the first rubber anti-slip block 31 ' and the second rubber anti-slip block 32' because the glass 40 may have curvature tolerance. However, the forces applied to the glass 40 by the first rubber anti-slip block 31 ' and the second rubber anti-slip block 32' are less than those applied by the first rubber anti-slip block 31 and the second rubber anti-slip block 32 as described in the above embodiments.
- the glass 40 may be fixed within the encapsulation mold 100' in the following way. First, the glass 40 is placed on the lower mold 20', so that a concave surface or a convex surface of the glass 40 (namely, the lower surface of the glass 40) is propped by the rubber bump 352 of the second rubber anti-slip block 32' . After that, the glass 40 is positioned preliminarily. Then the upper mold 10' is pressed against the lower mold 20', so that the rubber bump 351 of the first rubber anti-slip block 31 ' engages a convex surface or a concave surface of the glass 40 (namely, the upper surface of the glass 40).
- the rubber bump 351 of the first rubber anti-slip block 31 ' and the rubber bump 352 of the second rubber anti-slip block 32' deform.
- the first rubber anti-slip block 31 ' deforms under the action of the rubber bump 351
- the second rubber anti-slip block 32' deforms under the action of the rubber bump 352.
- the rubber bump 351 applies a first downward force to the glass 40
- the rubber bump 352 applies a second upward force to the glass 40. Under the combined actions of the first downward force and the second upward force, the glass 40 is completely fixed within the encapsulation mold 100', which prevents the glass 40 from moving during injection molding, thereby reducing the breakage rate of the glass.
- Widths of the rubber bump 351 of the first rubber anti-slip block 31 ' and the rubber bump 352 of the second rubber anti-slip block 32' are respectively less than those of the first rubber anti-slip block 31 ' and the second rubber anti-slip block 32'. Therefore, the rubber bump 351 and the rubber bump 352 have a small contact area with the glass 40. Thus, the forces applied to the glass 40 by the rubber bump 351 and the rubber bump 352 are relatively low. Further, because the first rubber anti-slip block 31 ' may deform under the action of the rubber bump 351, and the second rubber anti-slip block 32' may deform under the action of the rubber bump 352, it is equivalent to enhancing deformability of the rubber bump 351 and the rubber bump 352. Therefore, the breakage rate can be reduced even if the glass 40 has a great size and curvature tolerance.
- the rubber bump 351 of the first rubber anti-slip block 31 ' may extend higher than the first surface 311 ' of the first rubber anti-slip block 31 ' as much as possible
- the rubber bump 352 of the second rubber anti-slip block 32' may extend higher than the second surface 321 ' of the second rubber anti-slip block 32' as much as possible, so as to decrease the distance between the rubber bump 351 of the first rubber anti-slip block 31 ' and the rubber bump 352 of the second rubber anti-slip block 32'.
- the rubber bump 351 of the first rubber anti-slip block 31 ' is about 0.45mm to about 0.55mm higher than the first surface 311 '
- the rubber bump 352 of the second rubber anti-slip block 32' is about 0.45mm to about 0.55mm higher than the second surface 321' .
- the first rubber anti-slip block 31 ' and the second rubber anti-slip block 32' may be made of various rubber materials. Taking into account the characteristics of injection molding in which the first rubber anti-slip block 31 ' and the second rubber anti-slip block 32' are applied, the first rubber anti-slip block 31 ' and the second rubber anti-slip block 32' may be made of Ethylene-Propylene-Diene Monomer (EPDM). Similar to the first rubber anti-slip block 31 ' and the second rubber anti-slip block 32', the rubber bump 351 and the rubber bump 352 may be made of various rubber materials. Taking into account the characteristics of injection molding in which the rubber bump 351 and the rubber bump 352 are applied, the rubber bump 351 and the rubber bump 352 may be made of Ethylene-Propylene-Diene Monomer (EPDM).
- EPDM Ethylene-Propylene-Diene Monomer
- the clamping device may further include a third rubber anti-slip block 33' and a fourth rubber anti-slip block 34', in addition to the first rubber anti-slip block 31 ' and the second rubber anti-slip block 32' .
- the third rubber anti-slip block 33' is fixed to a joint surface of the upper mold 10' and has a third surface 33 for clamping the glass 40.
- the fourth rubber anti-slip block 34' is fixed to a joint surface of the lower mold 20' and has a fourth surface 341 ' for clamping the glass 40.
- the clamping device has equal numbers of the third rubber anti-slip blocks 33' and the fourth rubber anti-slip blocks 34'.
- the third rubber anti-slip block 33' and the fourth rubber anti-slip block 34' may overlap at least in part.
- a distance between the third surface 33 of the third rubber anti-slip block 33' and the fourth surface 341 ' of the fourth rubber anti-slip block 34' is less than the thickness of the glass 40.
- the distance between the third surface 33 of the third rubber anti-slip block 33' and the fourth surface 341 ' of the fourth rubber anti-slip block 34' is about 0.15mm to about 0.25mm less than the thickness of the glass 40.
- the third rubber anti-slip block 33' may be provided with a third groove 3c'on the third surface 33 ; and the fourth rubber anti-slip block 34' may be provided with a fourth groove 3d' on the fourth surface 341 ' . More details may refer to the preceding embodiments, and will not be described in detail herein.
- the encapsulation mold 100' has at least one third rubber anti-slip blocks 33' and at least one fourth rubber anti-slip blocks 34' .
- the encapsulation mold 100' has at least three third rubber anti-slip block 33' and at least three fourth rubber anti-slip blocks 34' (as an example, there are three third anti-slip blocks and three fourth rubber anti-slip blocks schematically shown in FIG. 10 and FIG. 11, respectively).
- the at least three third rubber anti-slip blocks 33' are fixed to the upper mold 10' at different positions and arranged in a polygon pattern, and the at least three fourth rubber anti-slip blocks 34' are fixed to the lower mold 20' at different positions and arranged in a polygon pattern.
- the three third rubber anti-slip blocks 33' are arranged in a quadrilateral pattern.
- the three fourth rubber anti-slip blocks 34' are arranged in a quadrilateral pattern.
- the glass 40 may be fixed within the encapsulation mold 100' having this clamping device in the following way. First, the glass 40 is placed on the lower mold 20', so that a concave surface or a convex surface of the glass 40 (namely, the lower surface of the glass 40) is propped by the second rubber bump 352 of the second rubber anti-slip block 32' and the fourth surface 341 ' of the fourth rubber anti-slip block 34' . After that, the glass 40 is positioned preliminarily.
- the upper mold 10' is pressed against the lower mold 20', so that the rubber bump 351 of the first rubber anti-slip block 31 ' and the third surface 33 of the third rubber anti-slip block 33' engage a convex surface or a concave surface of the glass 40 (namely, the upper surface of the glass 40).
- the rubber bump 351 of the first rubber anti-slip block 31 ' and the rubber bump 352 of the second rubber anti-slip block 32' is less than the thickness of the glass 40
- the distance between the third surface 33 of the third rubber anti-slip block 33' and the fourth surface 341 ' of the fourth rubber anti-slip block 34' is less than the thickness of the glass 40
- the rubber bump 351 of the first rubber anti-slip block 31 ' deforms and applies a first downward force to the glass 40
- the third rubber anti-slip block 33' deforms and applies a third downward force to the glass 40
- the fourth rubber anti-slip block 34' deforms and applies a fourth upward force to the glass 40.
- the glass 40 Under the combined actions of the first downward force, the second upward force, the third downward force and the fourth upward force, the glass 40 can be completely fixed within the encapsulation mold 100', which prevents the glass 40 from moving during injection molding, thereby reducing the breakage rate of the glass. If a glass 40 having a great curvature tolerance is encapsulated, the glass 40 may also be clamped between the first surface 311 ' of the first rubber anti-slip block 31 ' and the second surface 321' of the second rubber anti-slip block 32'. In this case, the first rubber anti-slip block 31 ' and the second rubber anti-slip block 32' also apply forces to the glass 40.
- the clamping device when the glass has a big size, includes a first rubber anti-slip block and a third rubber anti-slip block fixed to a joint surface of the upper mold, and a second rubber anti-slip block and a fourth rubber anti-slip block fixed to a joint surface of the lower mold, wherein grooves are formed in the third rubber anti-slip block and the fourth rubber anti-slip block, the third rubber anti-slip block is closer to an edge of the upper mold than the first rubber anti-slip block, and the fourth rubber anti-slip block is closer to an edge of the lower mold than the second rubber anti-slip block.
- the first rubber anti-slip block and the second rubber anti-slip block may fix a central region of the glass
- the third rubber anti-slip block and the fourth rubber anti-slip block may fix a peripheral region of the glass.
- rubber bumps may be provided on the first rubber anti-slip block and the second rubber anti-slip block, where the rubber bumps extend higher than the surfaces of the first rubber anti-slip block and the second rubber anti-slip block, respectively.
- the glass can be clamped between the rubber bump of the first rubber anti-slip block and the rubber bump of the second rubber anti-slip block. Because the contact area of the rubber bumps with the glass is small, the forces applied by the rubber bumps to the glass are relatively low, which reduces the breakage rate of the glass. As a result, the glass is not easy to be crushed even if the glass of a big size has a great curvature tolerance.
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Moulds For Moulding Plastics Or The Like (AREA)
- Injection Moulding Of Plastics Or The Like (AREA)
Abstract
Description
Claims
Priority Applications (7)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| MX2015004087A MX347367B (en) | 2012-11-05 | 2013-11-05 | Encapsulation mold. |
| KR1020157008397A KR101732828B1 (en) | 2012-11-05 | 2013-11-05 | Encapsulation mold |
| EA201590505A EA031742B1 (en) | 2012-11-05 | 2013-11-05 | Glass encapsulation mold |
| CA2881287A CA2881287C (en) | 2012-11-05 | 2013-11-05 | Encapsulation mold |
| BR112015004108-6A BR112015004108B1 (en) | 2012-11-05 | 2013-11-05 | encapsulation mold |
| US14/424,782 US9352491B2 (en) | 2012-11-05 | 2013-11-05 | Encapsulation mold |
| JP2015540038A JP6059355B2 (en) | 2012-11-05 | 2013-11-05 | Sealing mold |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012205778010U CN202895600U (en) | 2012-11-05 | 2012-11-05 | Edge-cladding mould |
| CN201220577801.0 | 2012-11-05 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO2014067495A1 true WO2014067495A1 (en) | 2014-05-08 |
Family
ID=48116310
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/CN2013/086561 Ceased WO2014067495A1 (en) | 2012-11-05 | 2013-11-05 | Encapsulation mold |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US9352491B2 (en) |
| JP (1) | JP6059355B2 (en) |
| KR (1) | KR101732828B1 (en) |
| CN (1) | CN202895600U (en) |
| BR (1) | BR112015004108B1 (en) |
| CA (1) | CA2881287C (en) |
| EA (1) | EA031742B1 (en) |
| MX (1) | MX347367B (en) |
| WO (1) | WO2014067495A1 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2017190860A1 (en) * | 2016-05-03 | 2017-11-09 | Volkswagen Aktiengesellschaft | Method and device for back-molding a curved glass body |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN202895600U (en) * | 2012-11-05 | 2013-04-24 | 法国圣戈班玻璃公司 | Edge-cladding mould |
| CN105291792B (en) * | 2014-07-04 | 2018-03-16 | 法国圣戈班玻璃公司 | The binding structure and injection molding apparatus of glass |
| CN104476855B (en) * | 2014-12-01 | 2016-01-20 | 福耀玻璃工业集团股份有限公司 | A kind of laminated glass with holes |
| CA3024754C (en) | 2016-12-02 | 2020-03-10 | Mi Integration S.E.N.C. | Apparatus and method for injection molding encapsulation |
| CN107738399B (en) * | 2017-07-08 | 2023-09-08 | 福耀集团(沈阳)汽车玻璃有限公司 | Automatic assembly production line for automobile rear door glass |
| CN111220474B (en) * | 2020-03-09 | 2024-11-22 | 江苏铁锚玻璃股份有限公司 | Glass strength testing device and testing method thereof |
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| CN2478824Y (en) * | 2001-04-20 | 2002-02-27 | 秦荣华 | Special mould structure for block moulding edging of car and ship windscreen |
| US20020132022A1 (en) * | 2001-02-16 | 2002-09-19 | Webasto Vehicle Systems International Gmbh | Device for foaming around a transparent pane for a motor vehicle roof |
| CN2712601Y (en) * | 2004-07-21 | 2005-07-27 | 福耀玻璃工业集团股份有限公司 | Injection moulding dies |
| CN102431123A (en) * | 2011-09-29 | 2012-05-02 | 福建工程学院 | Clamping device for hemming molds |
| CN202895600U (en) * | 2012-11-05 | 2013-04-24 | 法国圣戈班玻璃公司 | Edge-cladding mould |
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| FR2546812B1 (en) * | 1983-05-30 | 1986-04-18 | Saint Gobain Vitrage | |
| US4839122A (en) * | 1983-09-26 | 1989-06-13 | Libbey-Owens-Ford Co. | Reaction injection molding of window gasket |
| CA1259090A (en) | 1983-09-26 | 1989-09-05 | Libbey-Owens-Ford Co. | Preformed window assembly and method of making the same |
| US4951927A (en) * | 1985-03-11 | 1990-08-28 | Libbey-Owens-Ford Co. | Method of making an encapsulated multiple glazed unit |
| US4830804A (en) * | 1987-01-02 | 1989-05-16 | Libbey-Owens-Ford Co. | Method of molding a window assembly |
| US5068076A (en) * | 1988-07-28 | 1991-11-26 | Libbey-Owens-Ford Co. | Method of forming an encapsulated glazing unit |
| JPH0273320U (en) * | 1988-11-23 | 1990-06-05 | ||
| JP2687533B2 (en) * | 1989-01-06 | 1997-12-08 | 旭硝子株式会社 | Method for manufacturing window glass with gasket |
| US5268183A (en) * | 1990-05-04 | 1993-12-07 | Vidrio Plano De Mexico, S.A. | Mold apparatus having an outwardly angled seal for encapsulating a glass sheet |
| US6572355B1 (en) * | 2000-10-03 | 2003-06-03 | Libbey-Owens-Ford Co. | Window sash construction and method and apparatus for manufacture thereof |
| JP4582502B2 (en) | 2004-03-02 | 2010-11-17 | 日本電気硝子株式会社 | Tablet integrated glass tube |
| DE102004056479B4 (en) * | 2004-11-23 | 2014-07-10 | Webasto Ag | Device for foaming and / or encapsulating a substantially plate-shaped workpiece |
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- 2012-11-05 CN CN2012205778010U patent/CN202895600U/en not_active Expired - Lifetime
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- 2013-11-05 WO PCT/CN2013/086561 patent/WO2014067495A1/en not_active Ceased
- 2013-11-05 EA EA201590505A patent/EA031742B1/en not_active IP Right Cessation
- 2013-11-05 JP JP2015540038A patent/JP6059355B2/en active Active
- 2013-11-05 MX MX2015004087A patent/MX347367B/en active IP Right Grant
- 2013-11-05 KR KR1020157008397A patent/KR101732828B1/en active Active
- 2013-11-05 CA CA2881287A patent/CA2881287C/en not_active Expired - Fee Related
- 2013-11-05 US US14/424,782 patent/US9352491B2/en active Active
- 2013-11-05 BR BR112015004108-6A patent/BR112015004108B1/en not_active IP Right Cessation
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| US20020132022A1 (en) * | 2001-02-16 | 2002-09-19 | Webasto Vehicle Systems International Gmbh | Device for foaming around a transparent pane for a motor vehicle roof |
| CN2478824Y (en) * | 2001-04-20 | 2002-02-27 | 秦荣华 | Special mould structure for block moulding edging of car and ship windscreen |
| CN2712601Y (en) * | 2004-07-21 | 2005-07-27 | 福耀玻璃工业集团股份有限公司 | Injection moulding dies |
| CN102431123A (en) * | 2011-09-29 | 2012-05-02 | 福建工程学院 | Clamping device for hemming molds |
| CN202895600U (en) * | 2012-11-05 | 2013-04-24 | 法国圣戈班玻璃公司 | Edge-cladding mould |
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| WO2017190860A1 (en) * | 2016-05-03 | 2017-11-09 | Volkswagen Aktiengesellschaft | Method and device for back-molding a curved glass body |
Also Published As
| Publication number | Publication date |
|---|---|
| CA2881287C (en) | 2017-04-18 |
| CA2881287A1 (en) | 2014-05-08 |
| EA031742B1 (en) | 2019-02-28 |
| KR101732828B1 (en) | 2017-05-04 |
| JP2015536842A (en) | 2015-12-24 |
| CN202895600U (en) | 2013-04-24 |
| JP6059355B2 (en) | 2017-01-11 |
| MX347367B (en) | 2017-04-25 |
| KR20150051233A (en) | 2015-05-11 |
| US20150224677A1 (en) | 2015-08-13 |
| US9352491B2 (en) | 2016-05-31 |
| MX2015004087A (en) | 2015-07-06 |
| BR112015004108B1 (en) | 2021-04-20 |
| BR112015004108A2 (en) | 2017-07-04 |
| EA201590505A1 (en) | 2015-08-31 |
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