WO2014047896A1 - Washing maching including integral filter module and aerator - Google Patents

Washing maching including integral filter module and aerator Download PDF

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Publication number
WO2014047896A1
WO2014047896A1 PCT/CN2012/082373 CN2012082373W WO2014047896A1 WO 2014047896 A1 WO2014047896 A1 WO 2014047896A1 CN 2012082373 W CN2012082373 W CN 2012082373W WO 2014047896 A1 WO2014047896 A1 WO 2014047896A1
Authority
WO
WIPO (PCT)
Prior art keywords
filter module
wash
waste water
stage
washing machine
Prior art date
Application number
PCT/CN2012/082373
Other languages
French (fr)
Inventor
Bin He
Chengfeng WANG
Qixiang CAI
Tong Sun
Peng Gao
Original Assignee
Dow Global Technologies Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Global Technologies Llc filed Critical Dow Global Technologies Llc
Priority to KR1020157010870A priority Critical patent/KR20150064124A/en
Priority to EP12885211.8A priority patent/EP2900859A4/en
Priority to CN201280076026.3A priority patent/CN104854271A/en
Priority to PCT/CN2012/082373 priority patent/WO2014047896A1/en
Priority to US14/422,859 priority patent/US20150246377A1/en
Publication of WO2014047896A1 publication Critical patent/WO2014047896A1/en

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Classifications

    • AHUMAN NECESSITIES
    • A47FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
    • A47LDOMESTIC WASHING OR CLEANING; SUCTION CLEANERS IN GENERAL
    • A47L15/00Washing or rinsing machines for crockery or tableware
    • A47L15/42Details
    • A47L15/4202Water filter means or strainers
    • A47L15/4208Arrangements to prevent clogging of the filters, e.g. self-cleaning
    • AHUMAN NECESSITIES
    • A47FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
    • A47LDOMESTIC WASHING OR CLEANING; SUCTION CLEANERS IN GENERAL
    • A47L15/00Washing or rinsing machines for crockery or tableware
    • A47L15/42Details
    • A47L15/4214Water supply, recirculation or discharge arrangements; Devices therefor
    • A47L15/4219Water recirculation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D61/00Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/58Multistep processes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D65/00Accessories or auxiliary operations, in general, for separation processes or apparatus using semi-permeable membranes
    • B01D65/02Membrane cleaning or sterilisation ; Membrane regeneration
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B08CLEANING
    • B08BCLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
    • B08B3/00Cleaning by methods involving the use or presence of liquid or steam
    • B08B3/04Cleaning involving contact with liquid
    • B08B3/10Cleaning involving contact with liquid with additional treatment of the liquid or of the object being cleaned, e.g. by heat, by electricity or by vibration
    • B08B3/14Removing waste, e.g. labels, from cleaning liquid; Regenerating cleaning liquids
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/44Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06FLAUNDERING, DRYING, IRONING, PRESSING OR FOLDING TEXTILE ARTICLES
    • D06F39/00Details of washing machines not specific to a single type of machines covered by groups D06F9/00 - D06F27/00 
    • D06F39/006Recovery arrangements, e.g. for the recovery of energy or water
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06FLAUNDERING, DRYING, IRONING, PRESSING OR FOLDING TEXTILE ARTICLES
    • D06F39/00Details of washing machines not specific to a single type of machines covered by groups D06F9/00 - D06F27/00 
    • D06F39/20Arrangements for water recovery
    • AHUMAN NECESSITIES
    • A47FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
    • A47LDOMESTIC WASHING OR CLEANING; SUCTION CLEANERS IN GENERAL
    • A47L15/00Washing or rinsing machines for crockery or tableware
    • A47L15/02Washing or rinsing machines for crockery or tableware with circulation and agitation of the cleaning liquid in the cleaning chamber containing a stationary basket
    • A47L15/10Washing or rinsing machines for crockery or tableware with circulation and agitation of the cleaning liquid in the cleaning chamber containing a stationary basket by introducing compressed air or other gas into the liquid
    • AHUMAN NECESSITIES
    • A47FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
    • A47LDOMESTIC WASHING OR CLEANING; SUCTION CLEANERS IN GENERAL
    • A47L2601/00Washing methods characterised by the use of a particular treatment
    • A47L2601/03Pressurised, gaseous medium, also used for delivering of cleaning liquid
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2319/00Membrane assemblies within one housing
    • B01D2319/02Elements in series
    • B01D2319/025Permeate series
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2321/00Details relating to membrane cleaning, regeneration, sterilization or to the prevention of fouling
    • B01D2321/18Use of gases
    • B01D2321/185Aeration
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/002Grey water, e.g. from clothes washers, showers or dishwashers
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06FLAUNDERING, DRYING, IRONING, PRESSING OR FOLDING TEXTILE ARTICLES
    • D06F35/00Washing machines, apparatus, or methods not otherwise provided for
    • D06F35/002Washing machines, apparatus, or methods not otherwise provided for using bubbles
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06FLAUNDERING, DRYING, IRONING, PRESSING OR FOLDING TEXTILE ARTICLES
    • D06F39/00Details of washing machines not specific to a single type of machines covered by groups D06F9/00 - D06F27/00 
    • D06F39/08Liquid supply or discharge arrangements
    • D06F39/083Liquid discharge or recirculation arrangements
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06FLAUNDERING, DRYING, IRONING, PRESSING OR FOLDING TEXTILE ARTICLES
    • D06F39/00Details of washing machines not specific to a single type of machines covered by groups D06F9/00 - D06F27/00 
    • D06F39/10Filtering arrangements

Definitions

  • the present invention is directed toward washing machines for wasiiing laundry or "ware" items such glassware, tableware, flatware, dishware, cookware and the like.
  • Washing machines for cleaning laundry and ware items are well known in the art.
  • a typical washing machine includes a wash tub and an electrically operated pump which are housed in a cabinet.
  • the tub is accessible by way of a sealable door.
  • water and detergent are combined and manipulated about the wash tub during a washing stage, after which time the resulting waste water is discharged.
  • the tub is subsequently refilled with fresh feed water in one or more rinse stages.
  • the repetitive filling and draining of the wash tub takes time and uses a large quantity of water.
  • the present invention reduces water consumption and refilling time associated with washing laundry and ware items.
  • the invention includes a washing machine comprising the following components:
  • the invention includes a method for cleaning items using such a washing machine, including a wash cycle including multiple stages wherein waste water resulting from a stage passes through the filter module and is reused in the same stage or in a subsequent stage.
  • the wash cycle comprises a wash stage followed by a first and second rinse stage, and waste water resulting from the first rinse stage is continuously passed through the filter module and reused in the first rinse stage or separately used in the second rinse stage.
  • Debris including one or more of bacteria, viruses, protozoa and surfactants are at least partially removed from the waste water prior to reuse.
  • Figure 1 is schematic view of an embodiment of a washing machine according to the present invention.
  • the term "ware” refers to items such as glassware (e.g. bottles), tableware, flatware (e.g. cutlery, utensils), dishware (e.g. dishes), cookware, (e.g. pots, pans) and other items for use with food and beverages during their preparation, storage or consumption.
  • the term “laundry” refers to items made from textiles or fabrics including items such as clothing and linens (e.g. tablecloths, bedding, towels, etc.).
  • the invention includes a washing machine designed to clean ware items.
  • the invention includes a washing machine designed to clean laundry items.
  • FIG. 1 A schematic view of a generic embodiment of the invention is provided in Figure 1 wherein a washing machine is generally shown at 10 including a wash tub (12) adapted to temporarily house items to be cleaned. While not particularly limited, the wash tub (12) preferably includes a sealable door that provides convenient access to an inner chamber. In an embodiment designed to clean ware items, the wash tub (12) may include shelves and compartments for securing ware items during cleaning. In an embodiment designed to clean laundry, the wash tub (12) may include cylindrical drum which is capable of spinning about an axis. The wash tub (12) is in fluid communication with at least one water inlet (14) and a waste water outlet (16).
  • the water inlet (14) is adapted to provide a route for liquid to flow into the wash tub (12) while the waste water outlet (16) provides a route for waste water to flow out of the tub (12).
  • the inlet (14) and outlet (16) may include or be connected to valves (14', 16') that selectively control ingress and egress of liquid into and out of the tub (12).
  • the term "waste water” refers to water that has been used to either wash or rinse items within the tub (12).
  • a fluid pathway (18) comprising one or more pipes extends from the waste water outlet (16) to the water inlet (14).
  • a pump (20) provides a driving force for moving water along the fluid pathway (18). As will be described below, one or more pumps may be utilized.
  • a filter module (22) is located along the fluid pathway (18). While shown as a single unit, multiple filter modules may be used in a parallel of serial arrangement.
  • the filter module (22) may include a wide variety of separation mediums including membrane-based modules (e.g. spiral wound, hollow fiber, capillary, flat disks, and tubular membrane modules or "elements").
  • membrane-based modules e.g. spiral wound, hollow fiber, capillary, flat disks, and tubular membrane modules or "elements”
  • Representative semi- permeable membranes include those made from: various ceramics, polysulfones, polyether sulfones, polyvinylidene fluoride, polyamides, polyacrylonitrile, polyolefms, etc.
  • the membranes may be suitable in a wide range of appUcations including but not limited to microfiltration (MF), ultrafiltration (UF), nanofiltration (MF) and reverse osmosis (RO).
  • the module includes a plurality of semi-permeable membranes located within an inner chamber of a housing.
  • the average pore size of the hollow fiber membranes utilized within the filter module (22) may be selected so as to preferentially remove debris such as food, grease, proteins, oils and the like, e.g. average pore sizes in the microfiltration range (i.e. 0.1 to 5 micron), hi a preferred embodiment, the average pore size of the membrane is in ultrafiltration range, (i.e.
  • a substantially amount of surfactants can additional be removed by ultrafiltration with mean flow pore size less than 0.05 microns.
  • a plurality of semi-permeable hollow fiber membranes are orientated axially within an inner chamber. The ends of the hollow fibers are sealed from the inner chamber by way of well known "potting" techniques wherein one or both ends of the hollow fibers remain open and in fluid communication one or more outer chambers formed within an end cap assembly.
  • the filter module (22) comprises a tubular-shaped housing, (e.g.
  • the housing may be constructed from a wide variety of materials, e.g. plastics, ceramics, metals, etc., however, in one set of preferred embodiments the housing is made from an injection moldable plastic such as polyvinyl chloride (PVC) or acrylonitrile butadiene styrene (ABS). Representative examples include miniaturized versions of DowTM UF modules SFX 2660 and SFX 2680.
  • PVC polyvinyl chloride
  • ABS acrylonitrile butadiene styrene
  • Representative examples include miniaturized versions of DowTM UF modules SFX 2660 and SFX 2680.
  • the washing machine (10) further includes an aerator (24) in fluid communication with the filter module (22).
  • the aerator provides a source of gas bubbles (e.g. air bubbles) to the inner chamber of the filter module which remove debris from the surface of membrane.
  • the aerator comprises one or more gas nozzles in fluid communication with a source of gas such as ambient air. Gas pressure may be generated by an independent pump or gas blower (not shown). Alternatively, gas bubbles may be generated using the same pump (20) used to move water along the fluid path (18).
  • the aerator (24) may include a valve positioned along the fluid pathway (18) which selectively opens to permit air to be drawn into the fluid pathway as water passes through the pathway, i.e. via a Venturi effect. While not shown, the aerator may also be in direct fluid communication with the wash tub (12) to provide gas bubbles to the tub during cleaning or rinse stages.
  • the washing machine includes a feed water port (26) adapted for connection to a source of water (e.g. tap water), a waste discharge port (28) adapted for connection with an external drain, and a filter discharge port (30) adapted to an external drain.
  • a source of water e.g. tap water
  • the waste discharge port (28) and filter discharge port (30) may be combined into a single port.
  • Each port may include a valve which may be selectively opened or closed during operation.
  • the aforementioned components of washing machine (10) are integrally housed within a cabinet (32).
  • the filter module (22) is relatively small in size as compared with the washing machine, e.g. the volume ratio of the filter module (22) to the cabinet (32) is preferably from 1 :20 to 1 :1000.
  • the preferred method of cleaning includes a wash cycle comprising at least one wash stage followed by at least one and preferably two rinse stages.
  • the method is characterized by at least one stage reusing water from a preceding stage that has passed through the filter module (22), Wash stages are characterized by the combination of water with a detergent or other cleaning composition whereas rinse stages generally include no detergent (although anti-scalants may be used).
  • the wash cycle comprises at least one wash stage comprising the introduction of water and a detergent into the wash tub followed by at least one rinse stage wherein waste water which has passed through the filter module is reintroduced into the wash tub without adding detergent.
  • items to be cleaned are positioned within the wash tub (12) and feed water selectively enters the wash tub (12) by way the feed water port (26).
  • Automated valves and a pump may facilitate this process so that an optimized water level is achieved.
  • Detergent or other cleaning compounds also may also be provided and the resulting wash water is sprayed, agitated or otherwise manipulated about the tub (12) to remove debris from the items.
  • the wash stage ends and the resulting waste water is drained from the tub (12) by way of the waste water outlet (16).
  • automated valves and the pump (20) may facilitate this process.
  • the waste water may be removed from the washing machine (10) by opening waste discharge port (28), or the waste water (or portion thereof) may be recycled by passing through the filter module (22).
  • Water comprising feed water from the feed water port (26) or permeate passing through the membrane of the filter module (22), or a combination of both water sources is used as rinse water and is introduced into the wash tub (12) through water inlet (14).
  • a preferred mix ratio is at least 3: 1 permeate to fresh feed water.
  • waste water from the wash stage is disposed of via the waste discharge port (28), but waste water from the first rinse stage is recycled through the filter module (22) and reused.
  • the membrane is cleaned by introducing gas bubbles into the filter module (22) by way of the aerator (24). Bubbles flow upward through the module (22) and dislodge debris that collects upon the surface of the membrane. The bubbles may then selectively exit the module (22) by way of filter discharge port (30). Additionally, feed water may be periodically back-flushed through the membrane and removed from the module (22) by way of the filter discharge port (30). Aeration may be conducted after a wash or rinse stage, or may be continuous throughout one or more stages. Similarly, filtration of waste water may occur continuously through a wash or rinse stages, or be conducted off-line and stored within an interior or exterior holding tank for use in subsequent wash or rinse stage. In a preferred embodiment, filtration occurs continuously during the first rinse stage. Integrated circuitry or similar means may be used to control stage timing and value actuation during the cycle.
  • integrated circuitry may be suitable to implement a separate cleaning stage.
  • aeration may be performed without permeation through the module (22).
  • the cleaning stage may also include aeration and backwash (reverse permeation from normal operation) and/or forward wash from through the module (22). For instance, this may be implemented by redirecting a valve to provide pressurized water from the feed water port (26), the wash tub (12) or pump (20) to the module's inner chamber.
  • This cleaning stage may include continuous or batch removal of debris from the module (22) through the discharge port (30).
  • the cycle time for the cleaning stage may be longer than for either the wash or rinse stages.
  • Example 1 A washing machine (8 kg wash tub capacity) as configured in Figure 1 may be operated with a wash stage followed by two sequential rinse stages with each stage utilizing approximately 20 liters of water. Waste water associated with the wash stage is discharged via the water discharge port. Waste water associated with the first rinse stage is continuously filtered through a filtration module (UF hollow fiber) operating in dead-end mode. The resulting permeate is combined with fresh feed water and reused for the second rinse stage. A preferred mix ratio is at least 3:1 permeate to fresh feed water. Aeration of the filter module is preferably conducted during the rinse stage. This embodiment of the invention reduces total water consumption by approximately 1/3 per cycle and further reduces the total time of the cycle. The filter module (22) removes debris, bacteria and viruses from the waste water so that the items in the wash tub (12) do not become soiled or contaminated.
  • UF hollow fiber UF hollow fiber
  • Example 2 A washing machine (8 kg wash tub capacity) as configured in Figure 1 may be operated with a wash stage followed by a sequential rinse stage utilizing approximately 20 liters of water. Waste water associated with the wash stage is discharged via the water discharge port. Waste water associated with the first rinse stage is continuously filtered through a filtration module (UF hollow fiber) operating in dead-end mode, The resulting permeate is reused for the rinse stage.
  • a filtration module UF hollow fiber
  • Aeration of the filter module is preferably conducted during the rinse stage. This embodiment of the invention reduces total water consumption by approximately 1/3 per cycle and further reduces the total time of the cycle.
  • the filter module (22) removes debris, bacteria and viruses from the waste water so that the items in the wash tub (12) do not become soiled or contaminated.

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  • Engineering & Computer Science (AREA)
  • Water Supply & Treatment (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Environmental & Geological Engineering (AREA)
  • Organic Chemistry (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)
  • Cleaning By Liquid Or Steam (AREA)

Abstract

A washing machine and a corresponding method for cleaning ware or laundry items are provided. The machine comprises: a wash tub (12), a water inlet (14) and a waste water outlet (16) in fluid communication with the wash tub, a fluid pathway (18) extending from the waste water outlet to the water inlet, a pump (20) for moving water along the fluid pathway, a filter module (22) located along the fluid pathway, and an aerator (24) in fluid communication with the filter module.

Description

WASHING MACHING INCLUDING INTEGRAL FILTER MODULE AND AERATOR
FIELD
The present invention is directed toward washing machines for wasiiing laundry or "ware" items such glassware, tableware, flatware, dishware, cookware and the like.
INTRODUCTION
Washing machines for cleaning laundry and ware items are well known in the art. A typical washing machine includes a wash tub and an electrically operated pump which are housed in a cabinet. The tub is accessible by way of a sealable door. During a typical wash cycle, water and detergent are combined and manipulated about the wash tub during a washing stage, after which time the resulting waste water is discharged. The tub is subsequently refilled with fresh feed water in one or more rinse stages. The repetitive filling and draining of the wash tub takes time and uses a large quantity of water.
SUMMARY
i a primary embodiment, the present invention reduces water consumption and refilling time associated with washing laundry and ware items. The invention includes a washing machine comprising the following components:
i) a wash tub,
ii) a water inlet and waste water outlet in fluid communication with the wash tub, iii) a fluid pathway extending from the waste water outlet to the water inlet,
iv) a pump for moving water along the fluid pathway,
v) a filter module located along the fluid pathway, and
vi) an aerator in fluid communication with the filter module.
In another embodiment, the invention includes a method for cleaning items using such a washing machine, including a wash cycle including multiple stages wherein waste water resulting from a stage passes through the filter module and is reused in the same stage or in a subsequent stage. For example, in one embodiment, the wash cycle comprises a wash stage followed by a first and second rinse stage, and waste water resulting from the first rinse stage is continuously passed through the filter module and reused in the first rinse stage or separately used in the second rinse stage. Debris including one or more of bacteria, viruses, protozoa and surfactants are at least partially removed from the waste water prior to reuse.
BRIEF DESCRIPTION OF THE DRAWINGS
Figure 1 is schematic view of an embodiment of a washing machine according to the present invention.
DETAILED DESCRIPTION
As used herein, the term "ware" refers to items such as glassware (e.g. bottles), tableware, flatware (e.g. cutlery, utensils), dishware (e.g. dishes), cookware, (e.g. pots, pans) and other items for use with food and beverages during their preparation, storage or consumption. The term "laundry" refers to items made from textiles or fabrics including items such as clothing and linens (e.g. tablecloths, bedding, towels, etc.). In one embodiment, the invention includes a washing machine designed to clean ware items. In another embodiment, the invention includes a washing machine designed to clean laundry items.
A schematic view of a generic embodiment of the invention is provided in Figure 1 wherein a washing machine is generally shown at 10 including a wash tub (12) adapted to temporarily house items to be cleaned. While not particularly limited, the wash tub (12) preferably includes a sealable door that provides convenient access to an inner chamber. In an embodiment designed to clean ware items, the wash tub (12) may include shelves and compartments for securing ware items during cleaning. In an embodiment designed to clean laundry, the wash tub (12) may include cylindrical drum which is capable of spinning about an axis. The wash tub (12) is in fluid communication with at least one water inlet (14) and a waste water outlet (16). The water inlet (14) is adapted to provide a route for liquid to flow into the wash tub (12) while the waste water outlet (16) provides a route for waste water to flow out of the tub (12). The inlet (14) and outlet (16) may include or be connected to valves (14', 16') that selectively control ingress and egress of liquid into and out of the tub (12). For purposes of this description, the term "waste water" refers to water that has been used to either wash or rinse items within the tub (12). A fluid pathway (18) comprising one or more pipes extends from the waste water outlet (16) to the water inlet (14). A pump (20) provides a driving force for moving water along the fluid pathway (18). As will be described below, one or more pumps may be utilized. A filter module (22) is located along the fluid pathway (18). While shown as a single unit, multiple filter modules may be used in a parallel of serial arrangement. The filter module (22) may include a wide variety of separation mediums including membrane-based modules (e.g. spiral wound, hollow fiber, capillary, flat disks, and tubular membrane modules or "elements"). Representative semi- permeable membranes include those made from: various ceramics, polysulfones, polyether sulfones, polyvinylidene fluoride, polyamides, polyacrylonitrile, polyolefms, etc. The membranes may be suitable in a wide range of appUcations including but not limited to microfiltration (MF), ultrafiltration (UF), nanofiltration (MF) and reverse osmosis (RO). In preferred embodiments, the module includes a plurality of semi-permeable membranes located within an inner chamber of a housing. The average pore size of the hollow fiber membranes utilized within the filter module (22) may be selected so as to preferentially remove debris such as food, grease, proteins, oils and the like, e.g. average pore sizes in the microfiltration range (i.e. 0.1 to 5 micron), hi a preferred embodiment, the average pore size of the membrane is in ultrafiltration range, (i.e. 0.01 to 0.10 micron) such that protozoa, bacteria and viruses are at least partially removed. It has surprisingly been observed that a substantially amount of surfactants (e.g. example) can additional be removed by ultrafiltration with mean flow pore size less than 0.05 microns. In one embodiment, a plurality of semi-permeable hollow fiber membranes are orientated axially within an inner chamber. The ends of the hollow fibers are sealed from the inner chamber by way of well known "potting" techniques wherein one or both ends of the hollow fibers remain open and in fluid communication one or more outer chambers formed within an end cap assembly. In a preferred embodiment, the filter module (22) comprises a tubular-shaped housing, (e.g. an elongated shell having a length greater than its width), extending along an axis between two opposing ends and defining an inner chamber. The outer periphery of the filter module is cylindrically- shaped having a circular cross-section. The housing may be constructed from a wide variety of materials, e.g. plastics, ceramics, metals, etc., however, in one set of preferred embodiments the housing is made from an injection moldable plastic such as polyvinyl chloride (PVC) or acrylonitrile butadiene styrene (ABS). Representative examples include miniaturized versions of Dow™ UF modules SFX 2660 and SFX 2680.
The washing machine (10) further includes an aerator (24) in fluid communication with the filter module (22). The aerator provides a source of gas bubbles (e.g. air bubbles) to the inner chamber of the filter module which remove debris from the surface of membrane. In one embodiment, the aerator comprises one or more gas nozzles in fluid communication with a source of gas such as ambient air. Gas pressure may be generated by an independent pump or gas blower (not shown). Alternatively, gas bubbles may be generated using the same pump (20) used to move water along the fluid path (18). For example, the aerator (24) may include a valve positioned along the fluid pathway (18) which selectively opens to permit air to be drawn into the fluid pathway as water passes through the pathway, i.e. via a Venturi effect. While not shown, the aerator may also be in direct fluid communication with the wash tub (12) to provide gas bubbles to the tub during cleaning or rinse stages.
The washing machine includes a feed water port (26) adapted for connection to a source of water (e.g. tap water), a waste discharge port (28) adapted for connection with an external drain, and a filter discharge port (30) adapted to an external drain. The waste discharge port (28) and filter discharge port (30) may be combined into a single port. Each port may include a valve which may be selectively opened or closed during operation.
In a preferred embodiment the aforementioned components of washing machine (10) are integrally housed within a cabinet (32). In a preferred commercial embodiment, the filter module (22) is relatively small in size as compared with the washing machine, e.g. the volume ratio of the filter module (22) to the cabinet (32) is preferably from 1 :20 to 1 :1000.
The preferred method of cleaning includes a wash cycle comprising at least one wash stage followed by at least one and preferably two rinse stages. The method is characterized by at least one stage reusing water from a preceding stage that has passed through the filter module (22), Wash stages are characterized by the combination of water with a detergent or other cleaning composition whereas rinse stages generally include no detergent (although anti-scalants may be used). That is, in a preferred embodiment, the wash cycle comprises at least one wash stage comprising the introduction of water and a detergent into the wash tub followed by at least one rinse stage wherein waste water which has passed through the filter module is reintroduced into the wash tub without adding detergent.
In operation, items to be cleaned are positioned within the wash tub (12) and feed water selectively enters the wash tub (12) by way the feed water port (26). Automated valves and a pump may facilitate this process so that an optimized water level is achieved. Detergent or other cleaning compounds also may also be provided and the resulting wash water is sprayed, agitated or otherwise manipulated about the tub (12) to remove debris from the items. Thereafter, i.e. typically 10 to 30 minutes, the wash stage ends and the resulting waste water is drained from the tub (12) by way of the waste water outlet (16). Once again, automated valves and the pump (20) may facilitate this process. The waste water may be removed from the washing machine (10) by opening waste discharge port (28), or the waste water (or portion thereof) may be recycled by passing through the filter module (22).
After the wash stage one or more rinse stages are initiated. Water comprising feed water from the feed water port (26) or permeate passing through the membrane of the filter module (22), or a combination of both water sources is used as rinse water and is introduced into the wash tub (12) through water inlet (14). A preferred mix ratio is at least 3: 1 permeate to fresh feed water. When operated in cross-flow mode, concentrated waste water unable to pass through the membranes may be discharged by way of the filter discharge port (30). When operating in dead end flow mode, debris is collected within the module (22), which may be replaced on a periodic basis. In a preferred
embodiment, waste water from the wash stage is disposed of via the waste discharge port (28), but waste water from the first rinse stage is recycled through the filter module (22) and reused.
The membrane is cleaned by introducing gas bubbles into the filter module (22) by way of the aerator (24). Bubbles flow upward through the module (22) and dislodge debris that collects upon the surface of the membrane. The bubbles may then selectively exit the module (22) by way of filter discharge port (30). Additionally, feed water may be periodically back-flushed through the membrane and removed from the module (22) by way of the filter discharge port (30). Aeration may be conducted after a wash or rinse stage, or may be continuous throughout one or more stages. Similarly, filtration of waste water may occur continuously through a wash or rinse stages, or be conducted off-line and stored within an interior or exterior holding tank for use in subsequent wash or rinse stage. In a preferred embodiment, filtration occurs continuously during the first rinse stage. Integrated circuitry or similar means may be used to control stage timing and value actuation during the cycle.
In addition to wash and rinse stages, integrated circuitry may be suitable to implement a separate cleaning stage. In this cleaning stage, aeration may be performed without permeation through the module (22). Alternatively, the cleaning stage may also include aeration and backwash (reverse permeation from normal operation) and/or forward wash from through the module (22). For instance, this may be implemented by redirecting a valve to provide pressurized water from the feed water port (26), the wash tub (12) or pump (20) to the module's inner chamber. This cleaning stage may include continuous or batch removal of debris from the module (22) through the discharge port (30). The cycle time for the cleaning stage may be longer than for either the wash or rinse stages. Following are non-limited examples of this invention. It should be understood that the reduced total water consumption calculated in the examples depend on the water consumption during the stages, and should not be treated as limitation of the invention.
EXAMPLES
Example 1 : A washing machine (8 kg wash tub capacity) as configured in Figure 1 may be operated with a wash stage followed by two sequential rinse stages with each stage utilizing approximately 20 liters of water. Waste water associated with the wash stage is discharged via the water discharge port. Waste water associated with the first rinse stage is continuously filtered through a filtration module (UF hollow fiber) operating in dead-end mode. The resulting permeate is combined with fresh feed water and reused for the second rinse stage. A preferred mix ratio is at least 3:1 permeate to fresh feed water. Aeration of the filter module is preferably conducted during the rinse stage. This embodiment of the invention reduces total water consumption by approximately 1/3 per cycle and further reduces the total time of the cycle. The filter module (22) removes debris, bacteria and viruses from the waste water so that the items in the wash tub (12) do not become soiled or contaminated.
Example 2: A washing machine (8 kg wash tub capacity) as configured in Figure 1 may be operated with a wash stage followed by a sequential rinse stage utilizing approximately 20 liters of water. Waste water associated with the wash stage is discharged via the water discharge port. Waste water associated with the first rinse stage is continuously filtered through a filtration module (UF hollow fiber) operating in dead-end mode, The resulting permeate is reused for the rinse stage.
Aeration of the filter module is preferably conducted during the rinse stage. This embodiment of the invention reduces total water consumption by approximately 1/3 per cycle and further reduces the total time of the cycle. The filter module (22) removes debris, bacteria and viruses from the waste water so that the items in the wash tub (12) do not become soiled or contaminated.

Claims

WHAT IS CLAIMED IS:
1. A washing machine comprising the following components:
i) a wash tub,
ii) a water inlet and waste water outlet in fluid communication with the wash tub, iii) a fluid pathway extending from the waste water outlet to the water inlet,
iv) a pump for moving water along the fluid pathway,
v) a filter module located along the fluid pathway, and
vi) an aerator in fluid communication with the filter module.
2. The washing machine of claim 1 wherein the components are housed within a cabinet.
3. The washing machine of claim 2 wherein the volumetric ratio of the filter module to the cabinet is from 1 :20 to 1 : 1000.
4. The washing machine of claim 1 wherein the filter module comprises a plurality of hollow fiber membranes.
5. The washing machine of claim 1 wherein the aerator is in fluid communication with the pump.
6. The washing machine of claim 1 wherein the aerator is in fluid communication with a blower.
7. A method for washing ware or laundry items using a washing machine comprising the following components:
i) a wash tub,
ii) a water inlet and waste water outlet in fluid communication with the wash tub, iii) a fluid pathway extending from the waste water outlet to the water inlet,
iv) a pump for moving water along the fluid pathway,
v) a filter module located along the fluid pathway, and
vi) an aerator in fluid communication with the filter module;
wherein the method comprises a wash cycle including multiple stages wherein waste water resulting from a stage passes through the filter module and is reused.
8. The method of claim 7 wherein the filter module is aerated with gas bubbles.
9. The method of claim 7 wherein the wash cycle comprises at least one wash stage comprising the introduction of water and a detergent into the wash tub followed by at least one rinse stage wherein waste water which has passed tlirough the filter module is introduced into the wash tub without adding detergent.
10. The method of claim 7 wherein the wash cycle comprises a wash stage followed by a rinse stage, and wherein waste water resulting from the rinse stage is continuously passed through the filter module and reused in the during the rinse stage.
PCT/CN2012/082373 2012-09-28 2012-09-28 Washing maching including integral filter module and aerator WO2014047896A1 (en)

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KR1020157010870A KR20150064124A (en) 2012-09-28 2012-09-28 Washing machine including integral filter module and aerator
EP12885211.8A EP2900859A4 (en) 2012-09-28 2012-09-28 Washing maching including integral filter module and aerator
CN201280076026.3A CN104854271A (en) 2012-09-28 2012-09-28 Washing maching including integral filter module and aerator
PCT/CN2012/082373 WO2014047896A1 (en) 2012-09-28 2012-09-28 Washing maching including integral filter module and aerator
US14/422,859 US20150246377A1 (en) 2012-09-28 2012-09-28 Washing maching including integral filter module and aerator

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EP2900859A4 (en) 2016-06-01
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US20150246377A1 (en) 2015-09-03
KR20150064124A (en) 2015-06-10

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