WO2014028943A8 - Biobased rubber modifiers for polymer blends - Google Patents

Biobased rubber modifiers for polymer blends Download PDF

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Publication number
WO2014028943A8
WO2014028943A8 PCT/US2013/055624 US2013055624W WO2014028943A8 WO 2014028943 A8 WO2014028943 A8 WO 2014028943A8 US 2013055624 W US2013055624 W US 2013055624W WO 2014028943 A8 WO2014028943 A8 WO 2014028943A8
Authority
WO
WIPO (PCT)
Prior art keywords
pha
compositions
hydroxybutyrate
polymer blends
biobased
Prior art date
Application number
PCT/US2013/055624
Other languages
French (fr)
Other versions
WO2014028943A9 (en
WO2014028943A1 (en
Inventor
Roger Weinlein
Yelena Kann
Original Assignee
Metabolix, Inc.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Metabolix, Inc. filed Critical Metabolix, Inc.
Priority to CN201380054588.2A priority Critical patent/CN104755538B/en
Priority to US14/422,135 priority patent/US9475930B2/en
Priority to US14/043,702 priority patent/US9505927B2/en
Priority to US14/094,150 priority patent/US9464187B2/en
Publication of WO2014028943A1 publication Critical patent/WO2014028943A1/en
Publication of WO2014028943A8 publication Critical patent/WO2014028943A8/en
Publication of WO2014028943A9 publication Critical patent/WO2014028943A9/en
Priority to US15/334,047 priority patent/US10030135B2/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18—Manufacture of films or sheets
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08L27/06—Homopolymers or copolymers of vinyl chloride
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04—Homopolymers or copolymers of esters
    • C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
    • C08L33/10—Homopolymers or copolymers of methacrylic acid esters
    • C08L33/12—Homopolymers or copolymers of methyl methacrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
    • C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
    • C08J2327/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08J2327/06—Homopolymers or copolymers of vinyl chloride
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2333/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
    • C08J2333/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters
    • C08J2333/06—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters of esters containing only carbon, hydrogen, and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C08J2333/10—Homopolymers or copolymers of methacrylic acid esters
    • C08J2333/12—Homopolymers or copolymers of methyl methacrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2359/00—Characterised by the use of polyacetals containing polyoxymethylene sequences only
    • C08J2359/02—Copolyoxymethylenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2467/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
    • C08J2467/04—Polyesters derived from hydroxy carboxylic acids, e.g. lactones

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Biological Depolymerization Polymers (AREA)
  • Laminated Bodies (AREA)

Abstract

Compositions of polymer blends of polyvinylchloride (PVC) or polymethylmethacrylate (PMMA) or polyoxymethylene (POM) and polyhydroxyalkanoate (PHA) are described. In certain embodiments, the PHA is a poly-3-hydroxybutyrate-co-4-hydroxybutyrate copolymer having a weight percent 4-hydroxybutyrate of 30-45%. In other embodiments the PHA is a multiphase P3HB-4HB copolymer blend having one phase fully amorphous. The PHA is mixed with the PVC or PMMA or POM to optimize its optical, thermal and mechanical properties. In certain embodiments, the polymer is branched with optionally additives that improve properties. Methods of making the compositions of the invention are also described. The invention also includes articles, films and laminates comprising the compositions.
PCT/US2013/055624 2012-08-17 2013-08-19 Biobased rubber modifiers for polymer blends WO2014028943A1 (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
CN201380054588.2A CN104755538B (en) 2012-08-17 2013-08-19 Bio-rubber modifying agent for blend polymer
US14/422,135 US9475930B2 (en) 2012-08-17 2013-08-19 Biobased rubber modifiers for polymer blends
US14/043,702 US9505927B2 (en) 2012-08-17 2013-10-01 Biobased modifiers for polyvinylchloride blends
US14/094,150 US9464187B2 (en) 2012-08-17 2013-12-02 Biobased modifiers for polyvinylchloride blends
US15/334,047 US10030135B2 (en) 2012-08-17 2016-10-25 Biobased rubber modifiers for polymer blends

Applications Claiming Priority (12)

Application Number Priority Date Filing Date Title
US201261684583P 2012-08-17 2012-08-17
US61/684,583 2012-08-17
US201261716858P 2012-10-22 2012-10-22
US61/716,858 2012-10-22
US201261726873P 2012-11-15 2012-11-15
US61/726,873 2012-11-15
US201361754467P 2013-01-18 2013-01-18
US61/754,467 2013-01-18
US201361764180P 2013-02-13 2013-02-13
US61/764,180 2013-02-13
US201361812944P 2013-04-17 2013-04-17
US61/812,944 2013-04-17

Related Child Applications (3)

Application Number Title Priority Date Filing Date
US14/422,135 A-371-Of-International US9475930B2 (en) 2012-08-17 2013-08-19 Biobased rubber modifiers for polymer blends
US14/043,702 Continuation-In-Part US9505927B2 (en) 2012-08-17 2013-10-01 Biobased modifiers for polyvinylchloride blends
US15/334,047 Continuation US10030135B2 (en) 2012-08-17 2016-10-25 Biobased rubber modifiers for polymer blends

Publications (3)

Publication Number Publication Date
WO2014028943A1 WO2014028943A1 (en) 2014-02-20
WO2014028943A8 true WO2014028943A8 (en) 2015-03-12
WO2014028943A9 WO2014028943A9 (en) 2016-05-26

Family

ID=49034279

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2013/055624 WO2014028943A1 (en) 2012-08-17 2013-08-19 Biobased rubber modifiers for polymer blends

Country Status (1)

Country Link
WO (1) WO2014028943A1 (en)

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US11058796B2 (en) 2010-10-20 2021-07-13 206 Ortho, Inc. Method and apparatus for treating bone fractures, and/or for fortifying and/or augmenting bone, including the provision and use of composite implants, and novel composite structures which may be used for medical and non-medical applications
EP2629780A4 (en) 2010-10-20 2014-10-01 206 Ortho Inc Implantable polymer for bone and vascular lesions
US11484627B2 (en) 2010-10-20 2022-11-01 206 Ortho, Inc. Method and apparatus for treating bone fractures, and/or for fortifying and/or augmenting bone, including the provision and use of composite implants, and novel composite structures which may be used for medical and non-medical applications
US11291483B2 (en) 2010-10-20 2022-04-05 206 Ortho, Inc. Method and apparatus for treating bone fractures, and/or for fortifying and/or augmenting bone, including the provision and use of composite implants
US11207109B2 (en) 2010-10-20 2021-12-28 206 Ortho, Inc. Method and apparatus for treating bone fractures, and/or for fortifying and/or augmenting bone, including the provision and use of composite implants, and novel composite structures which may be used for medical and non-medical applications
WO2015095745A1 (en) 2010-10-20 2015-06-25 206 Ortho, Inc. Method and apparatus for treating bone fractures, and/or for fortifying and/or augmenting bone, including the provision and use of composite implants, and novel composite structures which may be used for medical and non-medical applications
US10525169B2 (en) 2010-10-20 2020-01-07 206 Ortho, Inc. Method and apparatus for treating bone fractures, and/or for fortifying and/or augmenting bone, including the provision and use of composite implants, and novel composite structures which may be used for medical and non-medical applications
EP2819620A4 (en) 2012-02-29 2015-11-04 206 Ortho Inc Method and apparatus for treating bone fractures, including the use of composite implants
CN109054254B (en) 2012-08-17 2021-02-02 Cj第一制糖株式会社 Bio-based rubber modifiers for polymer blends
EP2999747B1 (en) 2013-05-23 2020-08-12 206 ORTHO, Inc. Apparatus for treating bone fractures, and/or for fortifying and/or augmenting bone
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US11414517B2 (en) * 2020-04-21 2022-08-16 Cj Cheiljedang Corporation Low-temperature processable aliphatic polyester

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Publication number Publication date
WO2014028943A9 (en) 2016-05-26
WO2014028943A1 (en) 2014-02-20

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