WO2014004386A3 - Low-cost method for making lithium transition metal olivines with high energy density - Google Patents

Low-cost method for making lithium transition metal olivines with high energy density Download PDF

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Publication number
WO2014004386A3
WO2014004386A3 PCT/US2013/047357 US2013047357W WO2014004386A3 WO 2014004386 A3 WO2014004386 A3 WO 2014004386A3 US 2013047357 W US2013047357 W US 2013047357W WO 2014004386 A3 WO2014004386 A3 WO 2014004386A3
Authority
WO
WIPO (PCT)
Prior art keywords
transition metal
ions
lithium transition
source
water
Prior art date
Application number
PCT/US2013/047357
Other languages
French (fr)
Other versions
WO2014004386A2 (en
Inventor
Yu-Hua Kao
Towhid HASAN
Robin P. ZEIBARTH
Xindi Yu
Murali G. THEIVANAYAGAM
Lingbo Zhu
Stacie L. SANTHANY
Jui-Ching Lin
Ing-Feng Hu
Original Assignee
Dow Global Technologies Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Global Technologies Llc filed Critical Dow Global Technologies Llc
Priority to CN201380034605.6A priority Critical patent/CN104411627A/en
Priority to KR20147036162A priority patent/KR20150035740A/en
Priority to JP2015520367A priority patent/JP2015522512A/en
Priority to CA2876237A priority patent/CA2876237A1/en
Priority to US14/410,086 priority patent/US20150349343A1/en
Priority to EP13735142.5A priority patent/EP2867161A2/en
Publication of WO2014004386A2 publication Critical patent/WO2014004386A2/en
Publication of WO2014004386A3 publication Critical patent/WO2014004386A3/en

Links

Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/5825—Oxygenated metallic salts or polyanionic structures, e.g. borates, phosphates, silicates, olivines
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B25/00—Phosphorus; Compounds thereof
    • C01B25/16—Oxyacids of phosphorus; Salts thereof
    • C01B25/26—Phosphates
    • C01B25/45—Phosphates containing plural metal, or metal and ammonium
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/40—Electric properties
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M2004/026—Electrodes composed of, or comprising, active material characterised by the polarity
    • H01M2004/028—Positive electrodes
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

Abstract

An inexpensive method for making lithium transition metal olivine particles that have high specific capacities is disclosed. The method includes the steps of: a) combining precursor materials including at least one source of lithium ions, at least one source of transition metal ions, at least one source of HxP04 ions where x is 0-2 and at least one source of carbonate, hydrogen carbonate, formate and/or acetate ions in a mixture of water and a liquid cosolvent which is miscible with water at the relative proportions of water and cosolvent that are present and which liquid cosolvent has a boiling temperature of at least 130°C; wherein the mole ratio of lithium ions to HxP04 ions is from 0.9:1 to 1.2:1, and a lithium transition metal phosphate and at least one of carbonic acid, formic acid or acetic acid are formed, b) heating the resulting mixture at a temperature of up to 120°C to selectively remove the carbonic acid, formic acid, acetic acid and/or carbon-containing decomposition products thereof from the reaction mixture, optionally remove some or all of the water from the reaction mixture and produce lithium transition metal olivine particles, and then c) separating the lithium transition metal olivine particles from the liquid cosolvent.
PCT/US2013/047357 2012-06-27 2013-06-24 Low-cost method for making lithium transition metal olivines with high energy density WO2014004386A2 (en)

Priority Applications (6)

Application Number Priority Date Filing Date Title
CN201380034605.6A CN104411627A (en) 2012-06-27 2013-06-24 Low-cost method for making lithium transition metal olivines with high energy density
KR20147036162A KR20150035740A (en) 2012-06-27 2013-06-24 Low-cost method for making lithium transition metal olivines with high energy density
JP2015520367A JP2015522512A (en) 2012-06-27 2013-06-24 Low cost method for producing lithium transition metal olivine with high energy density
CA2876237A CA2876237A1 (en) 2012-06-27 2013-06-24 Low-cost method for making lithium transition metal olivines with high energy density
US14/410,086 US20150349343A1 (en) 2012-06-27 2013-06-24 Low-Cost Method for Making Lithium Transition Metal Olivines with High Energy Density
EP13735142.5A EP2867161A2 (en) 2012-06-27 2013-06-24 Low-cost method for making lithium transition metal olivines with high energy density

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201261664934P 2012-06-27 2012-06-27
US61/664,934 2012-06-27

Publications (2)

Publication Number Publication Date
WO2014004386A2 WO2014004386A2 (en) 2014-01-03
WO2014004386A3 true WO2014004386A3 (en) 2014-03-06

Family

ID=48771735

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2013/047357 WO2014004386A2 (en) 2012-06-27 2013-06-24 Low-cost method for making lithium transition metal olivines with high energy density

Country Status (7)

Country Link
US (1) US20150349343A1 (en)
EP (1) EP2867161A2 (en)
JP (1) JP2015522512A (en)
KR (1) KR20150035740A (en)
CN (1) CN104411627A (en)
CA (1) CA2876237A1 (en)
WO (1) WO2014004386A2 (en)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FI127782B (en) 2014-12-02 2019-02-15 Keliber Oy Method of Producing Lithium Metal Phosphates
FI128092B (en) 2016-06-01 2019-09-13 Keliber Oy Method of Producing Non-Conductive Lithium Metal Phosphates
RU2684895C1 (en) * 2018-05-15 2019-04-16 Автономная некоммерческая образовательная организация высшего образования "Сколковский институт науки и технологий" METHOD OF PRODUCING HIGH-POWER CATHODE MATERIAL BASED ON LiFe1-X-YMnXCoYPO4 SOLID SOLUTION WITH AN OLIVINE STRUCTURE FOR LITHIUM-ION BATTERIES
CN116409773B (en) * 2023-04-17 2023-11-07 郑州大学 Preparation method of long-cycle battery-level lithium iron phosphate

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1339119A1 (en) * 2000-11-09 2003-08-27 Sony Corporation Positive electrode material and cell comprising the same
WO2007113624A1 (en) * 2006-04-06 2007-10-11 High Power Lithium S.A. Synthesis of nanoparticles of lithium metal phosphate positive material for lithium secondary battery
WO2008077448A1 (en) * 2006-12-22 2008-07-03 Umicore SYNTHESIS OF CRYSTALLINE NANOMETRIC LiFeMPO4

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5344452B2 (en) * 2005-09-21 2013-11-20 関東電化工業株式会社 Positive electrode active material, method for producing the same, and nonaqueous electrolyte battery having a positive electrode containing the positive electrode active material
JP5381024B2 (en) * 2008-11-06 2014-01-08 株式会社Ｇｓユアサ Positive electrode for lithium secondary battery and lithium secondary battery
JP5509918B2 (en) * 2009-03-27 2014-06-04 住友大阪セメント株式会社 Method for producing positive electrode active material for lithium ion battery, positive electrode active material for lithium ion battery, electrode for lithium ion battery, and lithium ion battery

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1339119A1 (en) * 2000-11-09 2003-08-27 Sony Corporation Positive electrode material and cell comprising the same
WO2007113624A1 (en) * 2006-04-06 2007-10-11 High Power Lithium S.A. Synthesis of nanoparticles of lithium metal phosphate positive material for lithium secondary battery
WO2008077448A1 (en) * 2006-12-22 2008-07-03 Umicore SYNTHESIS OF CRYSTALLINE NANOMETRIC LiFeMPO4

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
S. K. MARTHA ET AL: "LiMnPO[sub 4] as an Advanced Cathode Material for Rechargeable Lithium Batteries", JOURNAL OF THE ELECTROCHEMICAL SOCIETY, vol. 156, no. 7, 1 January 2009 (2009-01-01), pages A541 - A552, XP055022062, ISSN: 0013-4651, DOI: 10.1149/1.3125765 *
WANG D ET AL: "High-performance, nano-structured LiMnPO4 synthesized via a polyol method", JOURNAL OF POWER SOURCES, ELSEVIER SA, CH, vol. 189, no. 1, 1 April 2009 (2009-04-01), pages 624 - 628, XP025982763, ISSN: 0378-7753, [retrieved on 20081001], DOI: 10.1016/J.JPOWSOUR.2008.09.077 *

Also Published As

Publication number Publication date
CA2876237A1 (en) 2014-01-03
CN104411627A (en) 2015-03-11
KR20150035740A (en) 2015-04-07
JP2015522512A (en) 2015-08-06
EP2867161A2 (en) 2015-05-06
US20150349343A1 (en) 2015-12-03
WO2014004386A2 (en) 2014-01-03

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